Plural Component System Comprising A - Group I To Iv Metal Hydride Or Organometallic Compound - And B - Group Iv To Viii Metal, Lanthanide Or Actinde Compound - (i.e., Alkali Metal, Ag, Au, Cu, Alkaline Earth Metal, Be, Mg, Zn, Cd, Hg, Sc, Y, Al, Ga, In, Tl, Ti, Zn, Hf, Ge, Sn Or Pb Hydride Or Organometallic Compound And Ti, Zr, Hf, Ge, Sn, Pb, V, Nb, Ta, As, Sb, Bi, Cr, Mo, W, Po, Mn, Tc, Re, Iron Group, Platinum Group, Atomic Number 57 To 71 Inclusive Or Atomic Number 89 Or Higher Compound) Patents (Class 502/102)
  • Patent number: 4544718
    Abstract: A process for producing a novel-highly active lanthanide containing catalyst comprising the product formed by admixing a lanthanide hydroxyhalide and an electron donor bidentate organic ligand chosen from among diamines, dihydric alcohols, and diketones with an organoaluminum cocatalyst component and its use in the polymerization of olefins, especially olefins such as ethylene and 1,3-butadiene.
    Type: Grant
    Filed: September 13, 1984
    Date of Patent: October 1, 1985
    Assignee: Phillips Petroleum Company
    Inventors: Gene H. C. Yeh, Joel L. Martin, Henry L. Hsieh
  • Patent number: 4507494
    Abstract: In a process for preparing a diester of oxalic acid by the vapor phase catalytic reaction of carbon monoxide with an ester of nitrous acid in the presence of a catalyst composed of a solid carrier and a catalyst component supported on the carrier, the improvement wherein said catalyst component is composed of(a) a platinum-group metal or a salt thereof, and(b) at least one member selected from the group consisting of Ti and an oxide thereof.
    Type: Grant
    Filed: January 24, 1983
    Date of Patent: March 26, 1985
    Assignee: Ube Industries, Ltd.
    Inventors: Haruhiko Miyazaki, Yasushi Shiomi, Satoru Fujitus, Katsuro Masunaga, Hiroshi Yanagisawa
  • Patent number: 4482691
    Abstract: Air-drying fatty acid-modified acrylic resins and oxidizable resinous vehicles containing same, and a novel drier system comprising a coordination complex of titanium and cobalt are herein disclosed.
    Type: Grant
    Filed: September 22, 1983
    Date of Patent: November 13, 1984
    Assignee: PPG Industries, Inc.
    Inventors: John B. Saunders, Jr., Karl F. Schimmel, Rostyslaw Dowbenko
  • Patent number: 4461883
    Abstract: A process for producing a conjugated diene polymer, characterized by polymerizing at least one conjugated diene with a catalyst consisting of (A) a reaction product of a Lewis base and a carboxylate of a rare earth element of the lanthanum series represented by Ln(R.sup.1 CO.sub.2).sub.3 wherein Ln is a rare earth element of the lanthanum series having an atomic number of 57 to 71 and R.sup.1 is a hydrocarbon substituent having 1 to 20 carbon atoms, (B) an organic aluminum compound represented by AlR.sup.2 R.sup.3 R.sup.4 wherein R.sup.2, R.sup.3 and R.sup.4, which may be identical or different, represent hydrogen atoms or hydrocarbon substituents having 1 to 8 carbon atoms, excluding the case where all of R.sup.2, R.sup.3 and R.sup.4 are hydrogen atoms at the same time, and (C) an (alkyl)aluminum halide represented by AlX.sub.n R.sup.5.sub.3-n wherein X is Cl, Br, F or I; R.sup.5 is a hydrocarbon substituent having 1 to 8 carbon atoms; and n has a value of 1, 1.
    Type: Grant
    Filed: June 14, 1982
    Date of Patent: July 24, 1984
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Yasumasa Takeuchi, Mitsuhiko Sakakibara, Tooru Shibata
  • Patent number: 4454363
    Abstract: A process for preparing a metal oxygen composition capable of dehydrocoupling toluene wherein metal oxides such as Sb.sub.2 O.sub.3, PbO, and Bi.sub.2 O.sub.3 are admixed with an organic media such as isobutanol and heated to form a metal oxygen precursor composition which is recovered and calcined is disclosed.
    Type: Grant
    Filed: June 11, 1982
    Date of Patent: June 12, 1984
    Assignee: Exxon Research & Engineering Co.
    Inventors: Harry H. Teng, I-Der Huang, Hsuan L. Labowsky
  • Patent number: 4444903
    Abstract: An improved process is described for preparing conjugate diolefin polymers or copolymers having a high content of 1,4-cis units and high chain linearity, the process using a particular catalytic system prepared from a compound of a metal chosen from those of Group III B of the Periodic System which have an atomic number of between 21 and 103, preferably neodymium, an organic halogen derivative, and an aluminium alkylhydride or trialkyl.
    Type: Grant
    Filed: September 2, 1982
    Date of Patent: April 24, 1984
    Assignee: Enoxy Chimica, S.p.A.
    Inventors: Antonio Carbonaro, Domenico Ferraro, Mario Bruzzone
  • Patent number: 4410670
    Abstract: This invention provides a process for preparing polyolefins using a new catalyst. According to this invention, .alpha.-olefins can be polymerized or copolymerized to have good stereoregularity and at a high activity by the use of such new catalyst. The new catalyst used in this invention consists of [A] a solid component obtained by contacting (1) a magnesium oxide, (2) an aluminum trihalide, (3) a hydroxy compound represented by the general formula ROH wherein R is an organic radical having 1 to 20 carbon atoms and (4) a titanium halide and/or an addition product of a titanium halide and an aromatic carboxylic acid ester, and [B] an organometallic compound and/or an addition product of an organometallic compound and an aromatic carboxylic acid ester; or it consists of the solid component of the above [A], the organometallic compound and/or the addition product of an organometallic compound and an aromatic carboxylic acid ester of the above [B], and [C] an aromatic carboxylic acid ester.
    Type: Grant
    Filed: June 6, 1979
    Date of Patent: October 18, 1983
    Assignee: Nippon Oil Company, Limited
    Inventors: Yoshio Tajima, Kazuo Matsuura, Nobuyuki Kuroda, Mituji Miyoshi