Molybdenum Patents (Class 502/211)
-
Patent number: 11628421Abstract: Catalysts comprising MoP and MoP2 are disclosed, wherein the catalyst is a composite. The catalyst may have a molar ratio of MoP:MoP2 within a range of 5:95 to 95:5. The catalyst may be used as a cathode active material for hydrogen generation from neutral pH solutions, such as wastewater or seawater. Methods of making the catalyst also are disclosed.Type: GrantFiled: October 15, 2019Date of Patent: April 18, 2023Assignee: Battelle Memorial InstituteInventors: Yuyan Shao, Xiaohong Xie
-
Patent number: 10864503Abstract: This invention relates to a process for the preparation of a hydrocracking catalyst and its use. A zeolite Y having specifically defined properties is mixed with an alumina binder component and a first metals-containing solution that is extruded to form an extruded mixture. The extruded mixture is dried and calcined. The dried and calcined mixture is then impregnated with a second metals-containing solution.Type: GrantFiled: September 16, 2013Date of Patent: December 15, 2020Assignee: Shell Oil CompanyInventors: Hermanus Jongkind, Wiebe Sjoerd Kijlstra, Bart Pelgrim, Marcello Stefano Rigutto, Ferry Winter
-
Patent number: 9683180Abstract: A process for the hydrotreatment of a vacuum distillate type hydrocarbon feed containing nitrogen-containing compounds is described, comprising a first step in which the feed is brought into contact with a catalyst in its oxide form, then a second step in which the feed is brought into contact with a dried catalyst comprising at least one organic compound containing oxygen and/or nitrogen.Type: GrantFiled: November 26, 2014Date of Patent: June 20, 2017Assignee: IFP ENERGIES NOUVELLESInventors: Magalie Roy-Auberger, Emmanuelle Guillon, Aline Grezaud
-
Patent number: 9663387Abstract: Described herein is a liquid filtration device is disclosed a vessel for treating an aqueous liquid, wherein the vessel contains a filtration medium and wherein the filtration medium comprises a metal sulfide, wherein the sulfur in the form of a metal sulfide is at least 0.5% by weight of the filtration media.Type: GrantFiled: December 18, 2012Date of Patent: May 30, 2017Assignee: 3M Innovative Properties CompanyInventors: Allen R. Siedle, Meredith McMurdo Doyle, Mark R. Stouffer
-
Patent number: 9399207Abstract: Provided is a preparation method of a denitration catalyst for treating nitrogen oxides contained in exhaust gas discharged from gas turbines for generating plants, coil fired boilers, etc., in which the catalytic activity can be improved, and furthermore, an increase of the cost of producing the catalyst is not involved. The preparation method of a denitration catalyst used when reacting nitrogen oxides with reducing agent ammonia to decompose the nitrogen oxides into nitrogen and water, and including titanium oxide and vanadium as catalytic active ingredients thereof, is characterized in that the vanadium precursor is ammonium metavanadate powder, the ammonium metavanadate powder containing particles having a particle diameter of 10 ?m or less in a cumulative ratio of 20% or more. The ammonium metavanadate powder is preferably a reclaimed product including vanadium recovered from petroleum-based combustion ash such as heavy oil ash.Type: GrantFiled: February 2, 2012Date of Patent: July 26, 2016Assignee: Hitachi Zosen CorporationInventors: Susumu Hikazudani, Naoe Hino
-
Patent number: 9327271Abstract: The present invention relates to catalysts and methods for efficient conversion of carbohydrates into 5-hydroxymethylfurfural (HMF), which shows good activity and high selectivity for HMF preparation from saccharides. The catalyst is stable in aqueous system which makes it as an ideal catalyst for HMF production. High HMF yield was obtained even in mild condition. The catalysts of the invention are advantageous in that they are environment-friendly, easy separation and recovery, can be re-used in subsequent reactions, do not corrode reaction reactors. These features make the catalyst as a suitable catalyst for HMF preparation and have strong industrial application significance.Type: GrantFiled: June 18, 2014Date of Patent: May 3, 2016Assignee: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCESInventors: Qishun Liu, Heng Yin, Yuguang Du, Fengli Yang, Wenxia Wang
-
Patent number: 9314772Abstract: Disclosed are a catalyst and preparation method and use thereof. The catalyst has a constitution represented as the formula below, wherein, D represents at least one element selected from the group consisting of copper, magnesium, manganese, stibium and zinc; E represents at least one element selected from the group consisting of tungsten, silicon, nickel, palladium, ferrum and plumbum; Z is selected from the group consisting of SiC, MoO3, WO3, TiO2 and ZrO2; y/x=11.1-50:100; a=0.1-3; b=0.01-5; c=0.01-5; d=0.01-3; e=0.01-2; f is the proportion of oxygen atom balancing the valence. The method comprises: (i) formulating Solution A with molybdenum, phosphorus, and vanadium compounds; formulating Solution B with dissolve potassium compound and a D-containing compound; formulating Solution C with an E-containing compound; (ii) mix Solutions A, B and C under a temperature of ?5-10° C.Type: GrantFiled: November 21, 2013Date of Patent: April 19, 2016Assignee: Shanghai HuaYi Acrylic Acid Co. Ltd.Inventors: Xin Wen, Ge Luo, Xinlei Jin, Tonghao Wu, Yan Zhuang, Xiaodong Chu, Jinghua Ji
-
Patent number: 9186658Abstract: The hydrocracking catalyst of the present invention is a hydrocracking catalyst comprising a catalyst support comprising a zeolite and an amorphous composite metal oxide having solid acidity, and at least one active metal supported by the catalyst support and selected from noble metals of Group 8 to Group 10 in the periodic table, wherein the hydrocracking catalyst contains a carbonaceous substance comprising a carbon atom, and the content of the carbonaceous substance in the hydrocracking catalyst is 0.05 to 1% by mass in terms of the carbon atom.Type: GrantFiled: March 26, 2012Date of Patent: November 17, 2015Assignees: JAPAN OIL, GAS AND METALS NATIONAL CORPORATION, INPEX CORPORATION, JX NIPPON OIL & ENERGY CORPORATION, JAPAN PETROLEUM EXPLORATION CO., LTD., COSMO OIL CO., LTD., NIPPON STEEL & SUMIKIN ENGINEERING CO., LTD.Inventors: Yuichi Tanaka, Takuya Niitsuma, Kazuhiko Tasaka, Marie Iwama
-
Publication number: 20150148578Abstract: The present invention relates to unsupported metal (e.g., cesium) substituted heteropolyacid catalyst compositions useful for the production of butene dimers and/or oligomers from a mixed butenes feed, in which, under mild conditions, all isomers of mixed butenes produce highly branched C8 and C8+ olefins, useful as octane enhancers.Type: ApplicationFiled: November 26, 2013Publication date: May 28, 2015Applicant: Saudi Arabian Oil CompanyInventors: Miao Sun, Wei Xu
-
Publication number: 20150144531Abstract: An improved process for the hydroconversion of micro carbon residue content of heavy hydrocarbon feedstocks by the use of a catalyst composition that is especially useful in the conversion of micro carbon residue of such feedstocks. The catalyst composition is a low surface area composition that further has a specifically define pore structure the combination of which provides for its enhance micro carbon residue conversion property.Type: ApplicationFiled: November 20, 2014Publication date: May 28, 2015Inventors: Josiane Marie-Rose GINSTRA, David Edward SHERWOOD, David Andrew KOMAR
-
Publication number: 20150144532Abstract: Improved catalyst supports, supported catalyst, and method of preparing and using the catalysts for the hydrodesulfurization of a residuum hydrocarbon feedstock are disclosed. The catalyst supports comprise titania alumina having 5 wt % or less titania and have greater than 70% of their pore volume in pores having a diameter between 70 and 130 and less than 2% in pores having a diameter above 1000. Catalysts prepared from the supports contain Groups 6, 9 and 10 metals or metal compounds, and optionally phosphorus, supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved sulfur and MCR conversion in hydrotreating processes.Type: ApplicationFiled: June 20, 2013Publication date: May 28, 2015Applicant: Advanced Refining Technologies LLCInventors: Rong He, Stanislaw Plecha, Meenakshi S. Krishnamoorthy, Bharat M. Patel
-
Publication number: 20150141667Abstract: The present invention provides catalysts, methods, and reactor systems for converting oxygenated hydrocarbons to oxygenated compounds. The invention includes methods for producing cyclic ethers, monooxygenates, dioxygenates, ketones, aldehydes, carboxylic acids, and alcohols from oxygenated hydrocarbons, such as carbohydrates, sugars, sugar alcohols, sugar degradation products, and the like, using catalysts containing palladium, molybdenum, tin, and tungsten. The oxygenated compounds produced are useful in the production of liquid fuels, chemicals, and other products.Type: ApplicationFiled: December 30, 2014Publication date: May 21, 2015Inventors: Brian Blank, Randy Cortright, Taylor Beck, Elizabeth Woods, Mike Jehring
-
Publication number: 20150111726Abstract: An ultra-stable catalyst composition for hydroprocessing hydrocarbon feedstocks and a method of making and use of the ultra-stable catalyst composition. The catalyst composition of the invention comprises a calcined mixture made by calcining a formed particle of a mixture comprising an inorganic oxide material, molybdenum trioxide, and a nickel compound; wherein the calcined mixture is further overlaid with a cobalt component and a molybdenum component to thereby provide the catalyst composition.Type: ApplicationFiled: October 15, 2014Publication date: April 23, 2015Inventors: Opinder Kishan BHAN, David Andrew KOMAR
-
Publication number: 20150108039Abstract: Disclosed is a method of hydrotreating a heavy hydrocarbon feedstock using a hydrotreating catalyst having specific properties that make it effective in converting nitrogen, sulfur and micro-carbon residue of a heavy hydrocarbon feedstock. The catalyst comprises a calcined support particle impregnated with a Group 6 metal component (e.g., molybdenum), a nickel component, and a phosphorus component present at concentrations in the catalyst such that the atomic ratio of the Group 6 metal-to nickel metal are within a specified range. The nickel metal acid extractability property of the catalyst is at least 50 percent.Type: ApplicationFiled: October 15, 2014Publication date: April 23, 2015Inventor: Opinder Kishan BHAN
-
Patent number: 9012349Abstract: A method for synthesizing catalyst beads of bulk transmission metal carbides, nitrides and phosphides is provided. The method includes providing an aqueous suspension of transition metal oxide particles in a gel forming base, dropping the suspension into an aqueous solution to form a gel bead matrix, heating the bead to remove the binder, and carburizing, nitriding or phosphiding the bead to form a transition metal carbide, nitride, or phosphide catalyst bead. The method can be tuned for control of porosity, mechanical strength, and dopant content of the beads. The produced catalyst beads are catalytically active, mechanically robust, and suitable for packed-bed reactor applications. The produced catalyst beads are suitable for biomass conversion, petrochemistry, petroleum refining, electrocatalysis, and other applications.Type: GrantFiled: November 1, 2013Date of Patent: April 21, 2015Assignee: UT-Battelle LLCInventors: Jae Soon Choi, Beth L. Armstrong, Viviane Schwartz
-
Patent number: 8993473Abstract: Embodiments of the present invention include improved shaped catalyst structures containing catalytic material comprised of mixed oxides of vanadium and phosphorus and using such shaped catalyst structures for the production of maleic anhydride.Type: GrantFiled: October 7, 2009Date of Patent: March 31, 2015Assignee: Huntsman Petrochemical LLCInventors: Larry E. Melde, William A. Smith
-
Patent number: 8962905Abstract: Process for the continuous hydrogenation of triglyceride containing raw materials in a fixed bed reactor system having several catalyst beds arranged in series and comprising at least one hydrogenation catalyst comprising an active phase constituted by a nickel and molybdenum element. The raw material feed, hydrogen containing gas and diluting agent are passed together through the catalyst beds at hydrogenation conditions. The raw material feed stream as well as the stream of hydrogen containing gas are divided into an equal number of different partial streams. These are each passed to one catalyst bed in such a manner that the weight ratio of diluting agent to raw material feed is essentially the same at the entrance of all catalyst beds and does not exceed 4:1. The claimed process is preferably conducted at low temperatures and allows the utilization of existing units due to the low recycle ratio.Type: GrantFiled: September 7, 2011Date of Patent: February 24, 2015Assignee: IFP Energies NouvellesInventors: Thierry Chapus, Nathalie Dupassieux, Antoine Daudin
-
Patent number: 8962514Abstract: A hydrotreating catalyst that exhibits excellent levels of both desulfurization activity and denitrification activity. The hydrotreating catalyst is prepared by supporting molybdenum, cobalt and nickel on a carrier comprising aluminum, silicon, phosphorus and boron, and then performing a presulfiding treatment, and has an average stacking number for molybdenum sulfide slab that is greater than 1.0 but not more than 1.9. Also, a process for producing a hydrotreating catalyst that enables a hydrotreating catalyst having excellent levels of both desulfurization activity and denitrification activity to be produced with comparative ease. The process includes a first step of mixing an acidic aluminum salt aqueous solution and a basic aluminum salt aqueous solution in the presence of phosphate ions and silicate ions to achieve a pH of 6.5 to 9.Type: GrantFiled: March 18, 2010Date of Patent: February 24, 2015Assignee: JX Nippon Oil & Energy CorporationInventors: Hiroyuki Seki, Yoshiaki Fukui, Masanori Yoshida
-
Patent number: 8900536Abstract: Catalyst support materials, catalysts, methods of making such and uses thereof are described. Methods of making catalyst support material include combining anatase titania slurry with i) a low molecular weight form of silica; and ii) a source of Mo to form a TiO2—MoO3—SiO2 mixture. Catalyst support material include from about 86% to about 94% weight anatase titanium dioxide; from about 0.1% to about 10% weight MoO3; and from about 0.1% to about 10% weight SiO2. Low molecular weight forms of silica include forms of silica having a volume weighted median size of less than 4 nm and average molecular weight of less than 44,000, either individually or in a combination of two or more thereof. Catalyst include such catalyst support material with from about 0.1 to about 3% weight of V2O5 and optionally from about 0.01% to about 2.5% weight P.Type: GrantFiled: August 23, 2013Date of Patent: December 2, 2014Assignee: Cristal USA Inc.Inventors: Steve M. Augustine, David M. Chapman, Dennis F. Clark
-
Publication number: 20140329666Abstract: A catalyst comprising NiO, a metal mixture comprising at least one of MoO3 or WO3, a mixture comprising at least one of SiO2 and Al2O3, and P2O5. In this embodiment the metal sites on the catalyst are sulfided and the catalyst is capable of removing tar from a synthesis gas while performing methanation and water gas shift reactions at a temperature range from 300° C. to 600° C.Type: ApplicationFiled: July 21, 2014Publication date: November 6, 2014Inventors: Sourabh S. Pansare, Joe D. Allison, Steven E. Lusk, Albert C. Tsang
-
Publication number: 20140323778Abstract: A catalytic adsorbent, comprising at least cobalt and molybdenum deposited on a porous substrate in which the content of cobalt, expressed in terms of CoO oxide, is between 11 and 30% by weight relative to the total weight of said adsorbent and the content of molybdenum, expressed in terms of MoO3 oxide, is between 3 and 30% by weight relative to the total weight of said adsorbent, is described. This invention also relates to a process for hydrotreatment using said catalytic adsorbent.Type: ApplicationFiled: April 23, 2014Publication date: October 30, 2014Applicant: IFP ENERGIES NOUVELLESInventors: Philibert LEFLAIVE, Marie Claire MARION, Antoine DAUDIN
-
Patent number: 8865614Abstract: A process for producing a ringlike oxidic shaped body by mechanically compacting a pulverulent aggregate introduced into the fill chamber of a die, wherein the outer face of the resulting compact corresponds to that of a frustocone.Type: GrantFiled: February 28, 2013Date of Patent: October 21, 2014Assignee: BASF SEInventors: Knut Eger, Jens Uwe Faust, Holger Borchert, Ralf Streibert, Klaus Joachim Mueller-Engel, Andreas Raichle
-
Patent number: 8772551Abstract: Disclosed herein are mixed oxide catalysts for the catalytic gas phase oxidation of alkanes, or mixtures of alkanes and olefins, for the production of aldehydes and carboxylic acids with air or oxygen in the presence of inert gases at elevated temperatures and pressure, and a method for the production of catalysts.Type: GrantFiled: July 6, 2011Date of Patent: July 8, 2014Assignee: Evonik Degussa GmbHInventors: Achim Fischer, Weimin Lu, Christoph Weckbecker, Klaus Huthmacher
-
Patent number: 8772196Abstract: Disclosed is a composition useful in the saturation of aromatics contained in a hydrocarbon feedstock. The composition includes a support composition having a high macroporosity of greater than 51 percent. The support composition comprises an amorphous silica-alumina having unique properties.Type: GrantFiled: August 25, 2008Date of Patent: July 8, 2014Assignee: Shell Oil CompanyInventors: Russell Craig Ackerman, Christian Gabriel Michel, John Anthony Smegal, Johannes Anthonius Robert Van Veen
-
Patent number: 8702973Abstract: One exemplary embodiment can be a process for upgrading one or more hydrocarbons boiling in a naphtha range including less than about 5%, by weight, one or more alkenes and about 2,000-about 5,000 wppm, S, comprised in one or more sulfur-containing compounds, based on the weight of the one or more hydrocarbons. The process can include contacting the one or more hydrocarbons with a catalyst. The catalyst may include about 0.1-about 10%, by weight, NiO, about 5-about 50%, by weight, MoO3, and about 0.1-about 10%, by weight, P, with the balance of the catalyst comprising Al2O3. The process can obtain an upgraded one or more hydrocarbons having a thiol concentration of no more than about 20 wppm, S, based on the sulfur comprised in one or more thiol compounds divided by the weight of the upgraded one or more hydrocarbons.Type: GrantFiled: March 15, 2011Date of Patent: April 22, 2014Assignee: UOP LLCInventors: Colleen Costello, Suheil F. Abdo, Keith Adrian Holder, Ashley James Austin, Willie J. Morrissette, Jr.
-
Patent number: 8697598Abstract: The present invention provides a hydrogenation catalyst, containing a carrier, metal components of nickel, molybdenum and tungsten supported thereon, and an adjuvant component selected from the group consisting of fluorine and phosphor and combination thereof. In another embodiment, the present invention provides a hydrogenation catalyst, containing a carrier and metal components of nickel, molybdenum and tungsten supported thereon, wherein said carrier contains a molecular sieve. The present invention provides further use of said catalyst in the process for hydrogenating hydrocarbon oil. In comparison with a hydrogenation catalyst according to the prior art, the catalyst according to the present invention has a much higher activity.Type: GrantFiled: April 20, 2006Date of Patent: April 15, 2014Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SINOPECInventors: Xiangyun Long, Xuefen Liu, Hong Nie, Kui Wang, Jing Xin, Qinghe Liu, Xiaodong Gao, Zhihai Hu, Yahua Shi, Dadong Li
-
Patent number: 8685354Abstract: The present invention concerns the selective removal of nitrogen oxides (NOx) from gases. In particular, the invention concerns a process, a highly alkali metal resistant heteropoly acid promoted catalyst and the use of said catalyst for removal of NOx from exhaust or flue gases, said gases comprising alkali or earth alkali metals. Such gases comprise for example flue gases arising from the burning of biomass, combined biomass and fossil fuel, and from waste incineration units. The process comprises the selective catalytic reduction (SCR) of NOx, such as nitrogen dioxide (NO2) and nitrogen oxide (NO) with ammonia (NH3) or a nitrogen containing compound selected from ammonium salts, urea or a urea derivative or a solution thereof as reductant.Type: GrantFiled: August 29, 2011Date of Patent: April 1, 2014Assignee: Danmarks Tekniske UniversitetInventors: Siva Sankar Reddy Putluru, Anders Riisager, Rasmus Fehrmann
-
Publication number: 20140076783Abstract: A method of making a high activity catalyst composition suitable for use in the hydrodesulfurization of a middle distillate feed, such as diesel fuel, having a high concentration of sulfur, to thereby provide a low sulfur middle distillate product. The method comprises heat treating aluminum hydroxide under controlled temperature conditions thereby converting the aluminum hydroxide to gamma-alumina to give a converted aluminum hydroxide, and controlling the fraction of converted aluminum hydroxide that is gamma-alumina. A catalytic component is incorporated into the converted aluminum hydroxide to provide an intermediate, which is heat treated to provide the high activity catalyst composition. The high activity catalyst composition can suitably be used in the hydrodesulfurization of a middle distillate feed containing a high sulfur concentration.Type: ApplicationFiled: November 18, 2013Publication date: March 20, 2014Applicant: Shell Oil CompanyInventor: Opinder Kishan BHAN
-
Patent number: 8658558Abstract: In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant. In the present disclosure, the metals can be recovered in an electro-coagulation reactor, wherein portion of the metal residuals in the supernatant reacts with the electrodes to form a slurry containing insoluble metal compounds. The insoluble metal compounds are isolated and recovered, forming an effluent stream. The insoluble metal compounds and/or the effluent stream can be further treated to form at least a metal precursor feed which can be used in the co-precipitation reaction.Type: GrantFiled: October 18, 2011Date of Patent: February 25, 2014Assignee: Chevron U.S.A. Inc.Inventors: Theodorus Maesen, Alexander E. Kuperman, Dennis Dykstra
-
Patent number: 8658557Abstract: A process for the preparation of a promoted VPO catalyst, wherein the catalyst comprises the mixed oxides of vanadium and phosphorus and wherein the catalyst is promoted with at least one of niobium, cobalt, iron, zinc, molybdenum or titanium, said process comprising the steps of (i) preparing a VPO catalyst comprising vanadyl pyrophosphate as the major component and containing less than 5 wt % of vanadyl phosphate, (ii) contacting the VPO catalyst with a solution comprising a metal source compound of at least one metal selected from the group consisting of niobium, cobalt, iron, zinc, molybdenum or titanium to form a metal impregnated VPO catalyst, and (iii) drying the metal impregnated VPO catalyst to form the promoted VPO catalyst. In one embodiment, a niobium promoted VPO catalyst is prepared.Type: GrantFiled: October 25, 2011Date of Patent: February 25, 2014Assignee: INEOS USA LLCInventors: Muin S. Haddad, Robert A. Gustaferro
-
Publication number: 20140024861Abstract: [Problem] Catalyst for use in selective reduction of propionaldehyde in acrolein and/or acrylic acid and/or acrylonitrile containing propionaldehyde and/or propionic acid and/or propionitrile at low concentration. In particular, a novel catalyst for selectively reducing propionaldehyde from acrolein containing the propionaldehyde. [Solution] Catalyst for use in selective reduction of propionaldehyde in acrolein containing the propionaldehyde, characterized in that the catalyst contains Mo as an indispensable component, and at least one element selected from a group comprising P, Si, W, Ti, Zr, V, Nb, Ta, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, In, Tl, Sn, Ag, As, Ge, B, Bi, La, Ba, Sb, Te, Ce, Pb, Mg, K, Rb, Cs and Al.Type: ApplicationFiled: January 26, 2012Publication date: January 23, 2014Applicant: NIPPON KAYAKU KABUSHIKI KAISHAInventors: Kimito Okumura, Toru Kawaguchi, Yasushi Kobayashi
-
Patent number: 8633128Abstract: The invention describes a heteropolycompound constituted by a nickel salt of a lacunary Keggin type heteropolyanion comprising tungsten in its structure, with formula: Nix+y/2AW11-yO39-5/2y, zH2O wherein Ni is nickel, A is selected from phosphorus, silicon and boron, W is tungsten, O is oxygen, y=0 or 2, x=3.5 if A is phosphorus, x=4 if A is silicon, x=4.5 if A is boron, and x=m/2+2 for the rest, and z is a number in the range 0 to 36, in which said heteropolycompound has no nickel atom in substitution for a tungsten atom in its structure, said nickel atoms being placed in the counter-ion position in the structure of said compound.Type: GrantFiled: July 29, 2009Date of Patent: January 21, 2014Assignee: IFP Energies NouvellesInventors: Audrey Bonduelle, Fabrice Bertoncini, Karima Ben Tayeb, Carole Lamonier, Michel Fournier, Edmond Payen
-
Publication number: 20140005031Abstract: Inorganic material having at least two elementary spherical particles, each of said spherical metallic particles: a polyoxometallate with formula (XxMmOyHh)q?, where H is hydrogen, O is oxygen, X is phosphorus, silicon, boron, nickel or cobalt and M is one or more vanadium, niobium, tantalum, molybdenum, tungsten, iron, copper, zinc, cobalt and nickel, x is 0, 1, 2 or 4, m is 5, 6, 7, 8, 9, 10, 11, 12 or 18, y is 17 to 72, h is 0 to 12 and q is 1 to 20.Type: ApplicationFiled: December 15, 2011Publication date: January 2, 2014Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, IFP ENERGIES NOUVELLES, UNIVERSITE PIERRE ET MARIE CURIEInventors: Alexandra Chaumonnot, Clement Sanchez, Cedric Boissiere, Frederic Colbeau-Justin, Karin Marchand, Elodie Devers, Audrey Bonduelle, Denis Uzio, Antoine Daudin, Bertrand Guichard, Denis Uzio, Antoine Daudin
-
Patent number: 8618015Abstract: A method of making a high activity catalyst composition suitable for use in the hydrodesulfurization of a middle distillate feed, such as diesel fuel, having a high concentration of sulfur, to thereby provide a low sulfur middle distillate product. The method comprises heat treating aluminum hydroxide under controlled temperature conditions thereby converting the aluminum hydroxide to gamma-alumina to give a converted aluminum hydroxide, and controlling the fraction of converted aluminum hydroxide that is gamma-alumina. A catalytic component is incorporated into the converted aluminum hydroxide to provide an intermediate, which is heat treated to provide the high activity catalyst composition. The high activity catalyst composition can suitably be used in the hydrodesulfurization of a middle distillate feed containing a high sulfur concentration.Type: GrantFiled: July 25, 2012Date of Patent: December 31, 2013Assignee: Shell Oil CompanyInventor: Opinder Kishan Bhan
-
Publication number: 20130306517Abstract: A hydroconversion catalyst comprising a Group VIB metal component, a Group VIII metal component and a carrier material is disclosed wherein said catalyst has a total surface area of 240 to 360 m2/g; a total pore volume of 0.5 to 0.9 cc/g; and a pore volume distribution such that greater than 60% of pore volume are in pores present as micropores of diameter between 55 and 115 ?, less than 0.12 cc/g of pore volume are in pores present at pores of diameter greater than 160 ? and less than 10% of pore volume are in pores present as macropores of diameters greater than 250 ?.Type: ApplicationFiled: May 20, 2013Publication date: November 21, 2013Inventors: John George KESTER, David Andrew KOMAR, David Edward SHERWOOD
-
Patent number: 8586499Abstract: A method for producing a catalyst for the preparation of methacrylic acid comprising a heteropolyacid compound containing phosphorus, molybdenum and an element X selected from the group consisting of potassium, rubidium, cesium and thallium and having an atomic ratio of the element X to molybdenum of 0.5:12 to 2:12, which method comprises the steps of mixing aqueous slurry A containing starting compounds of the heteropolyacid compound in which an atomic ratio of the element X to molybdenum is from 2:12 to 4:12, and aqueous slurry B containing starting compounds of the heteropolyacid compound in which an atomic ratio of the element X to molybdenum is from 0:12 to 0.5:12 to form a slurry mixture; heat-treating the slurry mixture at a temperature of 100° C. or higher; drying the slurry mixture; and calcining the dried mixture.Type: GrantFiled: October 26, 2010Date of Patent: November 19, 2013Assignee: Sumitomo Chemical Company, LimitedInventors: Toshiaki Miyatake, Junji Shibata, Eiichi Shiraishi
-
Publication number: 20130303362Abstract: Catalytic processes to produce a reaction product comprising 1-butanol by contacting a reactant comprising ethanol with a catalyst composition under suitable reaction conditions are provided. The catalyst composition may comprise a hydroxyapatite of the Formula (MwM?xM?yM??z)5(PO4)3(OH), wherein M is Mg; M? is Ca; M? is Sr; M?? is Ba; w is any number between 0 and 1 inclusive; x is any number from 0 to less than 0.5; y is any number between 0 and 1 inclusive; z is any number between 0 and 1 inclusive; and w+x+y+z=1. Base-treated catalyst compositions may be used. Also provided are processes for contacting an initial catalyst composition comprising the hydroxyapatite with a base to produce a base-treated catalyst composition, and the base-treated catalyst compositions so obtained.Type: ApplicationFiled: July 16, 2013Publication date: November 14, 2013Inventors: Paul Joseph Fagan, Thomas G. Calvarese, Ronald James Davis, Ronnie Ozer
-
Publication number: 20130296163Abstract: Described is a catalyst and process useful in the hydrodesulfurization of a distillate feedstock to manufacture a low-sulfur distillate product. The catalyst comprises a calcined mixture of inorganic oxide material, a high concentration of a molybdenum component, and a high concentration of a Group VIII metal component. The mixture that is calcined to form the calcined mixture comprises molybdenum trioxide in the form of finely divided particles, a Group VIII metal compound, and an inorganic oxide material. The catalyst is made by mixing the aforementioned starting materials and forming therefrom an agglomerate that is calcined to yield the calcined mixture that may be used as the catalyst or catalyst precursor.Type: ApplicationFiled: July 1, 2013Publication date: November 7, 2013Inventor: Opinder Kishan BHAN
-
Publication number: 20130284640Abstract: A catalyst for treating heavy hydrocarbon feedstocks. The catalyst comprises a calcined particle comprising a co-mulled mixture made by co-mulling inorganic oxide powder, molybdenum trioxide powder, and a nickel compound or cobalt compound, or both compounds, and then forming the co-mulled mixture into a particle that is calcined to provide the calcined particle. The calcination is conducted at a temperature such that at least 20% of the pore volume of the calcined particle is in pores of greater than 5,000 ? and less than 70% of the pore volume of the calcined particle is in the pores having a pore size in the range of from 70 to 250 ?.Type: ApplicationFiled: April 24, 2013Publication date: October 31, 2013Applicant: SHELL OIL COMPANYInventor: Opinder Kishan BHAN
-
Patent number: 8557449Abstract: An air cathode for a metal-air battery is disclosed which contains a catalyst chosen to make the metal air battery more easily rechargeable. This catalyst is based on cobalt phosphate, cobalt borate mixed metal cobalt phosphates, mixed metal cobalt borates, or mixed metal cobalt phosphate borates.Type: GrantFiled: June 24, 2011Date of Patent: October 15, 2013Inventors: Wilson Hago, Ivan Marc Lorkovic
-
Publication number: 20130255153Abstract: Disclosed is a method of gas purification, a coal gasification plant, and a shift catalyst, each of which enables an inexpensive treatment of condensed water derived from steam used in a CO shift reaction. A CO shift reaction is performed using a shift catalyst less causing side reactions (e.g., a P—Mo—Ni-supported shift catalyst), and condensed water derived from steam used in the CO shift reaction is reused or treated. The method includes a cleaning step of removing water-soluble substances from a gasified gas containing CO and H2S; a CO shift step of allowing CO in a gas after the cleaning step to react with steam by the catalysis of the shift catalyst to convert CO into CO2 and H2; and a recovery step of removing CO2 and H2S from a gas after the CO shift step, in which post-shift condensed water formed after the CO shift step is recycled.Type: ApplicationFiled: February 20, 2013Publication date: October 3, 2013Applicant: HITACHI, LTD.Inventors: Takashi SASAKI, Tomoko AKIYAMA
-
Patent number: 8481448Abstract: The invention is a heteropoly acid compound catalyst composition, a method of making the catalyst composition and a process for the oxidation of saturated and/or unsaturated aldehydes to unsaturated carboxylic acids using the catalyst composition. The catalyst composition is a heteropoly acid compound containing molybdenum, vanadium, phosphorus, cesium, bismuth, copper and antimony. Thermal stability is achieved with higher cesium content (up to less than 3.0) but antimony, copper and bismuth must be present to maintain good activity. The catalyst is made by dissolving compounds of the components of each of the heteropoly acid compounds in a solution, precipitating the heteropoly acid compounds, obtaining a catalyst precursor and calcining the catalyst precursor to form a heteropoly acid compound catalyst. Unsaturated aldehydes, such as methacrolein, may be oxidized in the presence of the heteropoly acid compound catalyst to produce an unsaturated carboxylic acid, such as methacrylic acid.Type: GrantFiled: July 19, 2010Date of Patent: July 9, 2013Assignee: Saudi Basic Industries CorporationInventors: Wugeng Liang, David Sullivan, James W. Kauffman, Clark Rea, Joe Linzer, Shahid Shaikh
-
Patent number: 8476181Abstract: The present invention relates to catalyst systems and a process for the simultaneous trimerization and tetramerization of olefinic monomers using those ligands.Type: GrantFiled: March 21, 2012Date of Patent: July 2, 2013Assignee: Shell Oil CompanyInventors: Eric Johannes Maria De Boer, Harry Van Der Heijden, Quoc An On, Johan Paul Smit, Arie Van Zon
-
Publication number: 20130164205Abstract: The present invention concerns the selective removal of nitrogen oxides (NOx) from gases. In particular, the invention concerns a process, a highly alkali metal resistant heteropoly acid promoted catalyst and the use of said catalyst for removal of NOx from exhaust or flue gases, said gases comprising alkali or earth alkali metals. Such gases comprise for example flue gases arising from the burning of biomass, combined biomass and fossil fuel, and from waste incineration units. The process comprises the selective catalytic reduction (SCR) of NOx, such as nitrogen dioxide (NO2) and nitrogen oxide (NO) with ammonia (NH3) or a nitrogen containing compound selected from ammonium salts, urea or a urea derivative or a solution thereof as reductant.Type: ApplicationFiled: August 29, 2011Publication date: June 27, 2013Applicant: DANMARKS TEKNISKE UNIVERSITETInventors: Siva, Sankar, Reddy Putluru, Anders Riisager, Rasmus Fehrmann
-
Patent number: 8470728Abstract: To overcome the problem of a conventional catalyst and to provide an exhaust gas purifying catalyst that meets the requirement concerning Hg oxidation activity and SO2 oxidation activity; i.e., an exhaust gas purifying catalyst which specifically reduces percent SO2 oxidation, while maintaining percent Hg oxidation at a high level. The invention provides an exhaust gas purifying catalyst which comprises a composition containing oxides of (i) titanium (Ti), (ii) molybdenum (Mo) and/or tungsten (W), (iii) vanadium (V), and (iv) phosphorus (P), wherein the catalyst contains Ti, Mo and/or W, and V in atomic proportions of 85 to 97.5:2 to 10:0.5 to 10, and has an atomic ratio of P/(sum of V and Mo and/or W) of 0.5 to 1.Type: GrantFiled: September 7, 2007Date of Patent: June 25, 2013Assignee: Babcock Hitachi Kabushiki KaishaInventors: Yasuyoshi Kato, Keiichiro Kai, Naomi Imada
-
Publication number: 20130116345Abstract: A catalyst comprising NiO, a metal mixture comprising at least one of MoO3 or WO3, a mixture comprising at least one of SiO2 and Al2O3, and P2O5. In this embodiment the metal sites on the catalyst are sulfided and the catalyst is capable of removing tar from a synthesis gas while performing methanation and water gas shift reactions at a temperature range from 300° C. to 600° C.Type: ApplicationFiled: September 13, 2011Publication date: May 9, 2013Applicant: PHILLIPS 66 COMPANYInventors: Sourabh S. Pansare, Joe D. Allison, Steven E. Lusk, Albert C. Tsang
-
Publication number: 20130105364Abstract: A catalyst for hydrotreating heavy hydrocarbon feedstocks that comprises a calcined particle comprising a co-mulled mixture made by co-mulling an inorganic oxide material, molybdenum trioxide, a nickel compound and phosphorus pentoxide (P2O5) solid, forming said co-mulled mixture into a particle, and calcining said particle to thereby provide said calcined particle.Type: ApplicationFiled: October 27, 2011Publication date: May 2, 2013Applicant: SHELL OIL COMPANYInventor: Opinder K. BHAN
-
Patent number: 8415268Abstract: A process for producing a ringlike oxidic shaped body by mechanically compacting a pulverulent aggregate introduced into the fill chamber of a die, wherein the outer face of the resulting compact corresponds to that of a frustocone.Type: GrantFiled: June 30, 2009Date of Patent: April 9, 2013Assignee: BASF SEInventors: Knut Eger, Jens Uwe Faust, Holger Borchert, Ralf Streibert, Klaus Joachim Mueller-Engel, Andreas Raichle
-
Patent number: 8410013Abstract: Provided is a catalyst for treating exhaust gas capable of reducing the amount of a highly corrosive mercury-chlorinating agent to be added while keeping the mercury oxidation efficiency high in an exhaust gas treatment. By the catalyst for treating exhaust gas, nitrogen oxide in the exhaust gas is removed upon contact with ammonia serving as a reducing agent, and mercury is oxidized using a halogen serving as an oxidant. The catalyst includes: TiO2 as a support; an oxide of at least one selected from the group consisting of V, W and Mo, which is supported as an active component on the support; and at least one selected from the group consisting of Bi, P, and compounds containing Bi and/or P, which is supported as a co-catalyst component on the support.Type: GrantFiled: February 26, 2009Date of Patent: April 2, 2013Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Katsumi Nochi, Yoshiaki Obayashi, Masashi Kiyosawa
-
Publication number: 20130072735Abstract: The present invention relates to solid phosphoric acid (SPA) catalysts, processes for making the catalysts, and processes for conversion of hydrocarbons using the catalysts, such as oligomerization of propylene. In an exemplary embodiment, the catalyst comprises a calcined extrudate of phosphoric acid, diatomaceous earth, and niobic acid. Methods for converting hydrocarbons to olefins comprise contacting a hydrocarbon feedstock with the catalyst at hydrocarbon conversion conditions.Type: ApplicationFiled: September 21, 2011Publication date: March 21, 2013Inventors: Wayne Turbeville, Greg Korynta