Platinum Or Palladium Patents (Class 502/262)
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Publication number: 20090203520Abstract: A catalyst for selective hydrogenation of acetylenes and diolefins, particularly in a raw gas feed stream for front end selective hydrogenation. The catalyst contains a low surface area carrier with a surface area from about 2-20 m2/g, wherein the pore volume of the pores of the carrier is greater than about 0.4 cc/g, at least 90 percent of the pore volume of the pores is contained within pores having a pore diameter greater than about 500 ? and about 1 to about 2 percent of the total pore volume is contained in pores with a pore diameter from about 500 to about 1,000 ?. The palladium comprises about 0.01 to about 0.1 weight % and a Group IB metal comprises about 0.005 to about 0.06 weight % of the catalyst.Type: ApplicationFiled: April 20, 2009Publication date: August 13, 2009Applicant: Sud-Chemie Inc.Inventors: Steven A. Blankenship, Jennifer A. Boyer, Gary R. Gildert
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Patent number: 7569511Abstract: An alcohol steam reforming catalyst for generating hydrogen contains palladium, yttrium, and at least one of cerium and a metal oxide. The catalyst displays both an improved alcohol conversion rate and improved carbon dioxide selectivity. Methods of making and using the alcohol steam reforming catalyst are described.Type: GrantFiled: May 5, 2006Date of Patent: August 4, 2009Assignee: BASF Catalysts LLCInventors: Christopher R. Castellano, Ye Liu, Ahmad Moini, Gerald Stephen Koermer, Robert Joseph Farrauto
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Patent number: 7566393Abstract: Compounds and methods for sorbing organosulfur compounds from fluids are provided. Generally, compounds according to the present invention comprise mesoporous, nanocrystalline metal oxides. Preferred metal oxide compounds either exhibit soft Lewis acid properties or are impregnated with a material exhibiting soft Lewis acid properties. Methods according to the invention comprise contacting a fluid containing organosulfur contaminants with a mesoporous, nanocrystalline metal oxide. In a preferred embodiment, nanocrystalline metal oxide particles are formed into pellets (14) and placed inside a fuel filter housing (12) for removing organosulfur contaminants from a hydrocarbon fuel stream.Type: GrantFiled: April 26, 2005Date of Patent: July 28, 2009Assignee: NanoScale CorporationInventors: Kenneth Klabunde, Bill R. Sanford, P. Jeevanandam
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Patent number: 7563743Abstract: This invention relates to doped catalysts on an aluminosilicate substrate with a low content of macropores and the hydrocracking/hydroconversion and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by the elements of group VIB and group VIII of the periodic table and a dopant in a controlled quantity that is selected from among phosphorus, boron, and silicon and a non-zeolitic substrate with a silica-alumina base that contains a quantity of more than 15% by weight and of less than or equal to 95% by weight of silica (SiO2).Type: GrantFiled: September 8, 2005Date of Patent: July 21, 2009Assignee: Institute Francais du PetroleInventors: Patrick Euzen, Alexandra Chaumonnot, Carole Bobin, Patrick Bourges, Christophe Gueret, Hugues Dulot
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Patent number: 7563744Abstract: The present invention relates to a catalyst for the purification of exhaust gases from an internal combustion engine, which comprises a catalytically active coating on an inert ceramic or metal honeycomb body, said coating comprising at least one platinum group metal selected from the group consisting of platinum, palladium, rhodium and iridium on a fine, oxidic support material. As an oxidic support material, the catalyst comprises a low-porosity material on the basis of silicon dioxide that comprises aggregates of essentially spherical primary particles having an average particle diameter of between 7 and 60 nm.Type: GrantFiled: August 8, 2002Date of Patent: July 21, 2009Assignee: Umicore AG & Co. KGInventors: Harald Klein, Ulrich Neuhausen, Egbert Lox, Jürgen Gieshoff, Thomas Kreuzer
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Patent number: 7563745Abstract: The invention relates to a shaped catalyst or catalyst precursor containing a catalytically active component or a precursor therefore, the component selected from elements of Group VIII of the Periodic Table of the Elements, supported on a carrier, which catalyst or catalyst precursor is an elongated shaped particle having three protrusions each extending from and attached to a central position, wherein the central position is aligned along the longitudinal axis of the particle, the cross-section of the particle occupying the space encompassed by the outer edges of six circles around a central circle, each of the six circles touching two neighboring circles while three alternating circles are equidistant to the central circle and may be attached to the central circle, minus the space occupied by the three remaining outer circles and including the six interstitial regions.Type: GrantFiled: June 6, 2003Date of Patent: July 21, 2009Assignee: Shell Oil CompanyInventors: Arend Hoek, Hans Michiel Huisman, Carolus Matthias Anna Maria Mesters
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Publication number: 20090176053Abstract: There are disclosed a honeycomb structure capable of providing a honeycomb catalytic body which is excellent in purification efficiency with a small pressure loss and which can be mounted even in a limited space, a honeycomb catalytic body which is excellent in purification efficiency with a small pressure loss and which can be mounted even in a limited space, and a manufacturing method of the same. A honeycomb catalytic body 50 of the present invention is a honeycomb catalytic body of a flow-through type through which cells as through channels extend from an inlet to an outlet, both the surfaces of partition walls 4 of a honeycomb structure 1 and the inner surfaces of pores 25 carry a catalyst to form catalyst layers 5, and the catalyst carrying partition walls have a permeability of 1×10?12 [m2] or more, preferably 1×10?9 [m2] or less.Type: ApplicationFiled: November 28, 2008Publication date: July 9, 2009Applicant: NGK INSULATORS, LTD.Inventors: Yukio MIYAIRI, Yoshihiro YAMAMOTO, Shogo HIROSE
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Patent number: 7541012Abstract: The present invention features a catalytic material which includes a metal catalyst anchored to a nano-sized crystal containing a metal oxide. Furthermore, the present invention features a method of producing the catalytic material described herein. Finally, the present invention features using the catalytic material for removing contaminants and for getting the desired products.Type: GrantFiled: July 7, 2004Date of Patent: June 2, 2009Assignee: The Hong Kong University of Science and TechnologyInventors: King Lun Yeung, Nan Yao, Ka Yee Ho
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Publication number: 20090137386Abstract: The invention proposes a particulate filter having a catalytic coating which contains two catalysts arranged one behind the other. The first catalyst is located in the gas inlet region of the filter and contains a palladium/platinum catalyst. The second catalyst is arranged downstream of the first catalyst and preferably contains platinum alone as catalytically active component. The combination of these two catalysts provides the coated filter with a good ageing stability and resistance to sulphur poisoning.Type: ApplicationFiled: August 13, 2005Publication date: May 28, 2009Applicant: UMICORE AG & CO. KGInventors: Marcus Pfeifer, Markus Koegel, Roger Staab, Pascal Adolph, Yvonne Demel, Tobias Kuhl, Egbert Lox, Thomas Kreuzer, Frank-Walter Schuetze
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Patent number: 7538065Abstract: An improved noble metal-containing catalyst containing a specific ratio of silica to aluminum in the framework suitable for use in the hydroprocessing of hydrocarbonaceous feeds, which is directed at a catalyst comprising a hydrogenation-dehydrogenation component selected from the Group VIII noble metals and mixtures thereof on a mesoporous support having aluminum incorporated into its framework and an average pore diameter of about 15 to less than about 40 ?.Type: GrantFiled: August 17, 2005Date of Patent: May 26, 2009Assignee: International Business Machines CorporationInventors: Stephen J. McCarthy, Wenyih F. Lai, Sylvain S. Hantzer, Ian A. Cody
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Publication number: 20090118119Abstract: A water gas shift catalyst comprising a precious metal deposited on a support, wherein the support is prepared from a mixture comprising a low surface area material, such as an aluminate, particularly a hexaaluminate, and a high surface area material, such as a mixed metal oxide, particularly a mixture of zirconia and ceria, to which may be added one or more of a high surface area transitional alumina, an alkali or alkaline earth metal dopant and an additional dopant selected from Ga, Nd, Pr, W, Ge, Au, Ag, Fe, oxides thereof and mixtures thereof.Type: ApplicationFiled: November 1, 2007Publication date: May 7, 2009Applicant: SUD-CHEMIE INC.Inventors: Chandra Ratnasamy, Jon P. Wagner
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Publication number: 20090108238Abstract: A catalyst for reforming hydrocarbons comprising a precious metal, preferably selected from the group consisting of rhodium, platinum, palladium, osmium, iridium, ruthenium, rhenium, and combinations thereof deposited on a support, wherein the support is produced from a mixture of a low surface area material and a high surface area material.Type: ApplicationFiled: October 31, 2007Publication date: April 30, 2009Applicant: SUD-CHEMIE INC.Inventors: Jon P. Wagner, Chandra Ratnasamy, Charles D. Faulk
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Publication number: 20090088317Abstract: A reduction catalyst having a first metal component comprising one of Co, Os, Fe, Re, Rh and Ru. The first metal component is present in the catalyst at from 0.5 percent to 20 percent, by weight. A second metal component differing from the first metal component present in the catalyst with the second metal component being selected from the group consisting of Fe, Mn, Ru, Os, Rh, Ir, Ni, Pd, Pt, Ag, Au, Zn, Co, Re, Cu, Pb, Cr, W, Mo, Sn, Nb, Cd, Te, V, Bi, Ga and Na. A hydrogenation catalyst comprising one or both of Ni and Co and one or more elements selected from the group consisting of Mn, Fe, Ag, Au, Mo and Rh.Type: ApplicationFiled: September 28, 2007Publication date: April 2, 2009Inventors: John G. Frye, JR., Johnathan E. Holladay, Danielle S. Muzatko, James F. White, Alan H. Zacher
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Publication number: 20090054683Abstract: The invention relates to a synthesis reactor and to a method for producing vinyl acetate, in which gaseous ethylene and acetic acid, in addition to oxygen or gases containing oxygen, react catalytically. The inventive synthesis reactor is a wall reactor, in which the catalytic synthesis takes place in a plurality of reaction chambers, whose free flow cross sections measure less than 2000 ?m, preferably 1000 ?m and whose indirectly cooled walls are coated with a palladium-gold catalyst.Type: ApplicationFiled: October 10, 2005Publication date: February 26, 2009Inventors: Karsten Bueker, Steffen Schirrmeister, Bernd Langanke, Georg Markowz, Ralf Hausmann, Andreas Geisselmann
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Publication number: 20090041646Abstract: Provided is a catalyst for reducing and decomposing oxygen in gas, highly efficiently and stably in from a low temperature region to a relatively high temperature region, in the presence of a reducing substance, containing at least one kind of a metal oxide selected from the group consisting of Ti, Si, W, Mo, Zr and Fe, as a catalyst component A; and at least one kind of a metal selected from the group consisting of Pt, Pd, Rh, Ir, Ru, Ni and Co, and/or a metal oxide thereof, as a catalyst component B; in removing oxygen, presence of a reducing substance in gas is effective.Type: ApplicationFiled: March 15, 2006Publication date: February 12, 2009Applicant: NIPPON SHOKUBAI CO., LTD.Inventors: Mitsuaki Ikeda, Kazunori Yoshino, Toshikatsu Ikenogami, Atsushi Morita
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Publication number: 20090022641Abstract: A layered, three-way conversion catalyst having the capability of simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides is disclosed. Methods of making and using the same are also provided. In one or more embodiments, the catalyst comprises three layers of catalytic material in conjunction with a carrier. A first layer comprises a platinum component on a first support; a second layer comprises a rhodium component on a second support; and a third layer comprises a palladium component and a third support. The palladium, rhodium, and/or platinum can independently be deposited on a support of high surface area refractory metal oxide, or of an oxygen storage component, or both.Type: ApplicationFiled: July 19, 2007Publication date: January 22, 2009Inventors: Shau-Lin Franklin Chen, Jin Sakakibara, Tian Luo, Harold Rabinowitz
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Publication number: 20090011925Abstract: A catalytically active glass-ceramic and method for producing a catalytically active multi-phase glass-ceramic in which at least one catalyst precursor is mixed with a glass-ceramic precursor formulation to form a catalyst precursor/glass-ceramic precursor mixture. The catalyst precursor/glass-ceramic precursor mixture is then melted to form an amorphous glass material which, in turn, is devitrified to form a polycrystalline ceramic. The polycrystalline ceramic is then activated, forming a catalytically active multi-phase glass-ceramic.Type: ApplicationFiled: July 6, 2007Publication date: January 8, 2009Inventors: Larry Gordon Felix, David Morrissey Rue, Thomas Philip Seward, III, Logan Edwin Weast
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Publication number: 20080318765Abstract: There is disclosed a composition comprising an alloy represented by the following generic formula Aa)n(Bb)n(Cc)n(Dd)n(ee)n( . . . )n; wherein A is an oxygen storage agent; B is an anti-sintering agent; C is an oxidation catalyst; D is a reduction catalyst; and E is a NOx absorbing agent; wherein each subscript letter represents compositional stoichiometry; wherein n is greater than or equal to zero; wherein the sum of the n's is equal to or greater than 2, and wherein the alloy comprises at least two different metals. There is also disclosed a washcoat composition; a catalyst support; methods of making the alloy, the washcoat composition, and the catalyst support.Type: ApplicationFiled: June 19, 2007Publication date: December 25, 2008Inventors: Allen A. Aradi, C. S. Warren Huang
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Publication number: 20080305033Abstract: A catalyst effective for the direct reaction of hydrogen and oxygen to form hydrogen peroxide includes particles of gold, palladium or, preferably, gold and palladium deposited upon an acid-washed support. High selectivity to and production of hydrogen peroxide is observed, with low hydrogen peroxide decomposition. The catalysts have extended lifespan.Type: ApplicationFiled: July 10, 2006Publication date: December 11, 2008Applicant: UNIVERSITY COLLEGE CARDIFF CONSULTANTS LIMITEDInventors: Albert Frederick Carley, Jennifer Kelly Edwards, Graham John Hutchings, Benjamin Eduardo Solsona Espriu
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Publication number: 20080299034Abstract: The present invention relates to a process for preparing hydrogen peroxide by reacting hydrogen and oxygen in the presence of a solvent and of a catalyst, wherein the catalyst comprises at least one noble or semi-noble metal supported on an inorganic material functionalized with acid groups. The invention also refers to the catalyst used in this process.Type: ApplicationFiled: May 30, 2008Publication date: December 4, 2008Applicant: Repsol YPF, S.A.Inventors: Pilar De Frutos Escrig, Jose Manuel Riesco Garcia, Jose Miguel Campos Martin, Jose Luis Garcia Fierro, Encarnacion Cano Serrano, Gema Blanco Brieva
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Publication number: 20080299433Abstract: The use of fuel cells to produce electricity are known as an environmentally clean and reliable source of energy, and show promise as an automotive power source if the polymer electrolyte membrane fuel cell can be made less expensive, more durable, reduce or eliminate humidification of the reactive gases, and operate at temperatures encountered during automotive operating conditions. The use of an electro-catalyst formed from heteropoly acids immobilized by a conductive material, such as carbon or platinum black, and stabilizing a metallic black with the immobilized conductive material addressed these automotive fuel cell needs. Coating the fuel cell electrode, polymer electrolyte assembly with a nano-particle catalyst derived from a heteropoly acid provided anodic carbon monoxide tolerance at anodic overpotentials and an active cathodic oxygen reduction. The heteropoly acids can also function as supercapacitor electrode films.Type: ApplicationFiled: May 16, 2008Publication date: December 4, 2008Inventors: Ronald Justin Stanis, Andrew Michael Herring, Mei-Chen Kuo, Jack Richard Ferrell, III
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Patent number: 7452844Abstract: The Fischer-Tropsch catalyst of the present invention is a transition metal-based catalyst having a high surface area, a smooth, homogeneous surface morphology, an essentially uniform distribution of cobalt throughout the support, and a small metal crystallite size. In a first embodiment, the catalyst has a surface area of from about 100 m2/g to about 250 m2/g; an essentially smooth, homogeneous surface morphology; an essentially uniform distribution of metal throughout an essentially inert support; and a metal oxide crystallite size of from about 40 ? to about 200 ?. In a second embodiment, the Fischer-Tropsch catalyst is a cobalt-based catalyst with a first precious metal promoter and a second metal promoter on an aluminum oxide support, the catalyst having from about 5 wt % to about 60 wt % cobalt; from about 0.0001 wt % to about 1 wt % of the first promoter, and from about 0.01 wt % to about 5 wt % of the second promoter.Type: GrantFiled: May 8, 2001Date of Patent: November 18, 2008Assignee: Süd-Chemie IncInventors: X. D. Hu, Patrick J. Loi, Robert J. O'Brien
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Patent number: 7453017Abstract: The present invention describes a Pd-catalyst which further contains La, Ti, Nb, K or Si. The Pd-catalyst has a high ethylene selectivity even after a low temperature reduction in the selective hydrogenation of acetylene to ethylene. The invention also relates to the production of the catalyst. A catalyst of the invention consists essentially of 0.05 to 2.0% by weight, based on the supported catalyst, of palladium and one or two metals chosen form the group consisting of lanthanum, niobium, titanium, potassium and silicon. The catalyst can be prepared by the following procedure. (1) Impregnating a support in aqueous solution of tetra amine palladium hydroxide, followed by drying and calcination; (2) The second and, if necessary, a third metal is impregnated by impregnating the Pd-catalyst in the solution of the metal precursor followed by drying and calcination; (3) The catalyst according to step (2) is then reduced in hydrogen at 200° C. to 600° C. for 1 to 5 hours.Type: GrantFiled: March 26, 2004Date of Patent: November 18, 2008Assignee: BASF AGInventors: Sang Heup Moon, Woo Jae Kim, Jung Hwa Kang, In Young Ahn
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Publication number: 20080249331Abstract: A microspheroidal support for the manufacture of a vinyl acetate catalyst which support comprises substantially inert microspheroidal particles of a mixture of silica and 0.5 to 5 wt % (based on the total weight of the support) of aluminium oxide. A vinyl acetate catalyst comprising the microspheroidal support, palladium, at least one metal, M, selected from the group consisting of gold, cerium, copper and mixtures thereof and at least one metal. A, selected from the group consisting of Group I, Group II, lanthanide and transition metal promoters.Type: ApplicationFiled: June 8, 2006Publication date: October 9, 2008Inventors: Robert Edward Allan, John William Couves, George Frederick Salem, Bruce Leo Williams
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Publication number: 20080241639Abstract: There is provided a catalyst for a fuel cell, which simultaneously realizes excellent catalytic activity and catalytic stability. The catalyst for a fuel cell comprises a fine particle of a metal represented by formula: PtxRuySizT1u wherein T1 represents at least one element selected from the group consisting of nickel (Ni), tungsten (W), vanadium (V), and molybdenum (Mo); x=30 to 90 atomic %; y=0 to 50 atomic %; z=0.5 to 20 atomic %; and u=0.5 to 40 atomic %, or comprises a fine particle of a metal represented by formula: PtxRuySizT2u wherein T2 represents at least one element selected from the group consisting of hafnium (Hf), tin (Sn), zirconium (Zr), niobium (Nb), titanium (Ti), tantalum (Ta), chromium (Cr), and aluminum (Al); x=30 to 90 atomic %; y=0 to 50 atomic %; z=0.5 to 20 atomic %; and u=0.5 to 40 atomic %.Type: ApplicationFiled: March 17, 2008Publication date: October 2, 2008Applicant: KABUSHIKI KAISHA TOSHIBAInventors: Wu MEI, Taishi Fukazawa, Takahiro Sato, Itsuko Mizutani, Yoshihiko Nakano
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Publication number: 20080234125Abstract: A catalyst and a method for selective hydrogenation of acetylene and dienes in light olefin feedstreams are provided. The catalyst retains higher activity and selectivity after regeneration than conventional selective hydrogenation catalysts. The catalyst contains a first component and a second component supported on an inorganic support. The inorganic support contains at least one salt or oxide of zirconium, a lanthanide, or an alkaline earth.Type: ApplicationFiled: June 2, 2008Publication date: September 25, 2008Inventors: Yongqing Zhang, Stephen J. Golden
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Patent number: 7425647Abstract: A process for preparing a catalyst by (a) selecting a carrier which is a silica based carrier which has been subjected to a series of washings with one or more aqueous liquids consisting of aqueous liquids which have a pH of least 3, when measured at 20° C., or which is a silica based carrier which is formed from materials one or more of which have been subjected to this series of washings, (b) precipitating a Group 8 metal compound onto the carrier, (c) converting the precipitated Group 8 metal compound into metallic species, and (d) subjecting the Group 8 metal/carrier composition to a purification treatment, before or after step (c); a catalyst which is obtainable by this process; and a process for preparing an alkenyl carboxylate by reacting a mixture comprising an olefin, a carboxylic acid and oxygen in the presence of the catalyst.Type: GrantFiled: March 28, 2002Date of Patent: September 16, 2008Assignee: Shell Oil CompanyInventors: Michael Francis Lemanski, John Robert Lockemeyer
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Publication number: 20080219918Abstract: A catalyst for fuel reforming including a metal catalyst that includes at least one active component A selected from the group consisting of Pt, Pd, Ir, Rh and Ru; and an active component B that is at least one metal selected from the group consisting of Mo, V, W, Cr, Re, Co, Ce and Fe, oxides thereof, alloys thereof, or mixtures thereof, and a carrier impregnated with the metal catalyst, and a method of producing hydrogen by performing a fuel reforming reaction using the catalyst for fuel reforming. The catalyst for fuel reforming has excellent catalytic activity at a low temperature and improved hydrogen purity. Therefore, when the catalyst for fuel reforming is used, high-purity hydrogen, which can be used as a fuel of a fuel cell, can be produced with high purity.Type: ApplicationFiled: September 14, 2007Publication date: September 11, 2008Applicant: Samsung SDI Co., Ltd.Inventors: Doo-hwan Lee, Yulia Potapova, Soon-ho Kim, Hyun-chul Lee, Kang-hee Lee
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Publication number: 20080219906Abstract: A multilayered, three-way conversion catalyst having the capability of simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides is disclosed. Provided is a catalytic material of at least four layers in conjunction with a carrier, where each of the layers includes a support, at least three layers comprise a precious metal component, and at least one layer comprises an oxygen storage component (OSC). The catalytic material can further comprise a fifth layer, where at least four layers comprise a precious metal component, at least one layer comprises an oxygen storage component, and at least one layer is substantially free of an oxygen storage component.Type: ApplicationFiled: January 9, 2008Publication date: September 11, 2008Inventors: Shau-Lin F. Chen, Knut Wassermann, Stephan Siemund, Tian Luo, Torsten Neubauer, Jin Sakakibara, Harold Rabinowitz
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Publication number: 20080193370Abstract: Materials that are useful for absorption enhanced reforming (AER) of a fuel, including absorbent materials and catalyst materials and methods for using the materials. The materials can be fabricated by spray processing. The use of the materials in AER can produce a H2 product gas having a high H2 content and a low level of carbon oxides.Type: ApplicationFiled: August 31, 2007Publication date: August 14, 2008Applicant: CABOT CORPORATIONInventors: Mark J. Hampden-Smith, Paolina Atanassova, Jian-Ping Shen, James Brewster, Paul Napolitano
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Patent number: 7361625Abstract: A carrier supporting titania thereon is further caused to carry a metal compound thereon. This metal compound is hydrogen reduced in a heating atmosphere at a first treatment temperature, then oxidized in a heating atmosphere at a second treatment temperature not higher than the first treatment temperature to thereby obtain a photocatalyst. In this event, metal is released from an extremely strong reduction state and thus highly dispersed on the catalyst in the form of fine particles so that high activity of the catalyst can be obtained. Then, by purifying gas while feeding light and heat to the photocatalyst by, for example, blacklights, a volatile organic compound such as acetaldehyde can be decomposed at a high decomposition rate through cooperation between photocatalytic activity and thermal catalytic activity of the photocatalyst.Type: GrantFiled: February 23, 2004Date of Patent: April 22, 2008Assignee: Sundecor Co., LtdInventors: Katsuyuki Nakano, Eiko Higashi, Masanori Nanri
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Patent number: 7345214Abstract: A catalyst for opening naphthenic rings has been developed. The catalyst comprises ruthenium and platinum as the active catalytic metals and a modifier with cerium being a preferred modifier. At least 50% of the platinum and ruthenium components are present as particles wherein more ruthenium is present on the surface of the particles than in the center. All of these components are dispersed on a metal oxide support such as aluminas. A ring opening process using the catalyst is also described.Type: GrantFiled: October 3, 2005Date of Patent: March 18, 2008Assignee: UOP LLCInventors: Feng Xu, Lorenz J. Bauer, Ralph D. Gillespie, Maureen L. Bricker, Steven A. Bradley
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Publication number: 20080045408Abstract: An embodiment of the present invention comprises a ceramic catalyst comprising a porous ceramic/silica glass substrate having substantially interconnecting pores with an average pore size of approximately 2 micron or less and particles comprising one or more noble metals on the surface of the substantially interconnecting pores. The noble metal particles may be either amorphous and/or crystalline nano-particles. The noble metals preferably may comprise silver, gold, rhodium, and/or palladium. The average pore size may be approximately 1 micron or less, 0.5 microns or less, 0.3 microns or less, 0.2 microns or less, 100 nanometers or less, 50 nanometers or less, or between 50 nanometers and 150 nanometers. Other embodiments of the present invention are directed to methods of manufacturing the ceramic catalyst and novel glass compositions used to manufacture the ceramic catalyst and using the ceramic catalyst at temperatures above 200° C. to produce hydrogen gas and to store hydrogen gas.Type: ApplicationFiled: August 14, 2007Publication date: February 21, 2008Inventor: Pedro M. Buarque de Macedo
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Patent number: 7323432Abstract: A catalyst assembly comprising a substrate, nanofilaments which have a nanometer-size diameter and are formed on the substrate, and particles which have a nanometer-size diameter, at least one of the nanofilaments and the particles having a catalytic function, is provided to use a catalyst more efficiently and to provide a catalytic function more efficiently. Interstices between the nanofilaments serve as distribution channels of a reactive gas, and the reactive gas spreads sufficiently not only around the ends of nanofilaments but also inside a catalyst assembly. A combination of nanofilaments and particles enables dispersion of a catalyst at a distance of not more than about 100 nanometers.Type: GrantFiled: August 21, 2003Date of Patent: January 29, 2008Assignees: DENSO Corporation, Koichi Niihara, Tadachika NakayamaInventors: Koichi Niihara, Tadachika Nakayama, Jun Hasegawa, Miho Ito
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Patent number: 7294604Abstract: A process for hydrogenating unsaturations in petrochemical feedstocks, the process comprising contacting the petrochemical feedstock, including at least one component having unsaturations, and hydrogen with a catalyst comprising at least one Group Ia, Ib, IIb, VIb, VIIb or VIII metal on a support of a crystalline calcium silicate having a surface area of at least 30 m2/g, the support being in the form of substantially spherical particles having a mean diameter of from 10 to 200 microns and pores in the particles having a diameter of from 100 to 2000 Angstroms, at a temperature of from 0 to 550° C. and a pressure of from 3 to 150 barg.Type: GrantFiled: July 16, 2002Date of Patent: November 13, 2007Assignee: Total Petrochemicals Research FeluyInventors: Jean-Pierre Dath, Walter Vermeiren
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Patent number: 7270738Abstract: This invention relates to silico-aluminum substrates, catalysts, and the hydrocracking and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by elements of group VIB and group VIII of the periodic table and a non-zeolitic silica-alumina-based substrate that contains an amount of more than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and has the following characteristics: A mean pore diameter, measured by mercury porosimetry, encompassed between 20 and 140 ?, a total pore volume, measured by mercury porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a total pore volume, measured by nitrogen porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a BET specific surface area encompassed between 100 and 550 m2/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 140 ?, of less than 0.Type: GrantFiled: October 30, 2003Date of Patent: September 18, 2007Assignee: Institut Francais du PetroleInventors: Patrick Euzen, Carole Bobin, Magalie Roy-Auberger, Eric Benazzi, Patrick Bourges, Christophe Gueret
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Patent number: 7256153Abstract: A catalyst for the selective hydrogenation of alkynes and dienes in C2-C5+-olefin mixtures is described. These catalysts contain (a) a metal of the tenth group of the Periodic Table, (b) a metal of the eleventh group of the Periodic Table and (c) if required, a compound of a metal of the first or second group of the Periodic Table, these metals being applied to a support which is selected from the group consisting of silica, titanium dioxide, zirconium oxides, spinels, zinc aluminates, zinc titanates or mixtures of these substances, and the metal of the eleventh group being distributed homogeneously over the cross section of the catalyst particle and the metal of the tenth group being present in the edge layer close to the surface of the catalyst particle. Such a catalyst is prepared by applying the metal of the eleventh group, preferably during the preparation of the support itself, by impregnation with a solution of a suitable metal salt.Type: GrantFiled: December 6, 2000Date of Patent: August 14, 2007Assignee: BASF AktiengesellschaftInventors: Andrea Frenzel, Michael Hesse, Andreas Ansmann, Ekkehard Schwab
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Patent number: 7256154Abstract: The present invention relates to a structured catalyst for reforming of gasoline and a method of preparing the same, more particularly to a structured catalyst for reforming of gasoline for fuel-cell powered vehicles prepared by wash-coating the transition metal based reforming catalyst on the surface of the ceramic honeycomb support wash-coated with sub-micron sized alumina or its precursor to sufficiently increase the effective surface area and the performance of the catalyst and a method of preparing the same.Type: GrantFiled: April 23, 2004Date of Patent: August 14, 2007Assignee: Korea Institute of Science and TechnologyInventors: Dong Ju Moon, Jong Woo Ryu, Dong Min Kang, Byung Gwon Lee, Byoung Sung Ahn, Sang Deuk Lee
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Patent number: 7220699Abstract: A method and device for loading a catalyst into a chamber. The catalyst loading is well suited for production of hydrogen producing microreactors. The catalyst is coated onto a strip which is mountable within the chamber.Type: GrantFiled: March 31, 2003Date of Patent: May 22, 2007Assignee: Intelligent Energy, Inc.Inventor: Anand Chellappa
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Patent number: 7179366Abstract: A catalyst contains at least one group VIII element and at least molybdenum and/or tungsten, said elements being present at least in part in the catalyst in the dry state in the form of at least one heteropolyanion with formula MxAB6O24H6C(3-2x), tH2O; MxAB6O24H6C(4-2x), tH2O; MxA2B10O38H4C(6-2x), tH2O; MxA2B10O38H4C(8-2x), tH2O; or MxA2B10O38H4C(7-2x), tH2O, in which M is cobalt and/or nickel and/or iron and/or copper and/or zinc, A is one or two elements from group VIII of the periodic table, B is molybdenum and/or tungsten and C is an H+ ion and/or a (NR1R2R3R4)+ type ammonium ion, in which R1, R2, R3 and R4, which may be identical or different, correspond either to a hydrogen atom or to an alkyl group and/or caesium and/or potassium and/or sodium, t is a number between 0 and 15 and x takes a value in the range 0 to 4 depending on the formula.Type: GrantFiled: August 1, 2003Date of Patent: February 20, 2007Assignee: Institut Francais du PetroleInventors: Virginie Harle, Catherine Martin, Edmond Payen, Carole Lamonier, Pascal Blanchard
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Patent number: 7169735Abstract: The object of the present invention is to provide a catalyst that is highly active and capable of maintaining its activity for a long period of time even in a high-temperature environment. The present invention is a catalyst including: a porous carrier which is comprised of one kind of or two or more kinds of metal oxides; and catalyst particles which are comprised of precious metals or precious metal oxides and supported on the above porous carrier, characterized in that the catalyst particles include: clustered particles formed by the aggregation of first precious metal atoms; and second precious metal ions bound to the above clustered particles. Preferably, the first precious metal and the second precious metal are different metal species which are selected from the group consisting of platinum, palladium, rhodium, ruthenium, silver, gold, iridium and osmium.Type: GrantFiled: May 3, 2005Date of Patent: January 30, 2007Assignee: Tanaka Kikinzoku Kogyo K.K.Inventor: Takeyuki Sagae
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Patent number: 7150866Abstract: The invention relates to a catalyst and a process for the autothermal, catalytic steam reforming of hydrocarbons using the catalyst. The catalyst has a multilayer structure and comprises a lower catalyst layer located directly on a support body and an upper catalyst layer located on the lower catalyst layer, with the lower catalyst layer preferentially catalysing the partial oxidation and the upper catalyst layer preferentially catalysing steam reforming. In a further embodiment, a three-layer catalyst having a further catalyst layer for the carbon monoxide conversion (water gas shift reaction) is described. Each catalyst layer comprises at least one platinum group metal on an oxidic support material. The steam reforming process is carried out in an adiabatic process by passing a feed mixture of hydrocarbons, oxygen and water or water vapour which has been heated to a preheating temperature over the multilayer catalyst.Type: GrantFiled: August 20, 2003Date of Patent: December 19, 2006Assignee: Umicore AG & Co. KGInventors: Stefan Wieland, Frank Baumann
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Patent number: 7138358Abstract: A catalyzed diesel particulate matter exhaust filter with improved diesel particulate matter oxidation activity and thermal stability including a porous filter substrate for filtering the diesel particulate matter washcoated with high surface area support alumina, titania, silica and zirconia promoted with one of ceria, lanthanum oxide, tungsten oxide, molybdem oxide, tin oxide for catalytic materials which includes an alkaline earth metal vanadate, and a precious metalType: GrantFiled: August 29, 2003Date of Patent: November 21, 2006Assignee: Sud-Chemie Inc.Inventors: Yinyan Huang, Zhongyuan Dang, Amiram Bar-llan
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Patent number: 7138353Abstract: There is provided a particulate matter combustion catalyst which allows easy combustion of particulate matter collected on the particulate matter filter of a diesel vehicle, at a much lower temperature than by the prior art. The particulate matter combustion catalyst has a construction characterized by an NO oxidation catalyst wherein the catalyst component is carried on an acidic first carrier, and an NO2 decomposition catalyst wherein the catalyst component is carried on a second carrier. Preferably, the NO oxidation catalyst has a precious metal such as platinum carried on an acidic first carrier such as tungstic acid/zirconia, and the NO2 decomposition catalyst has a catalyst component selected from the transition metals carried on a second carrier such as titania, or alternatively, the NO2 decomposition catalyst has at least one metal selected from among alkali metals and alkaline earth metals and a precious metal such as platinum carried on a second carrier such as titania.Type: GrantFiled: July 23, 2001Date of Patent: November 21, 2006Assignee: Toyota Jidosha Kabushiki KaishaInventors: Shinichi Takeshima, Tetsuya Yamashita
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Patent number: 7109145Abstract: The invention provides a noble metal-containing supported catalyst which contains one of the noble metals from the group Au, Ag, Pt, Pd, Rh, Ru, Ir, Os or alloys of one or more of these noble metals in the form of noble metal particles on a powdered support material. The particles deposited on the support material have a degree of crystallinity, determined by X-ray diffraction, of more than 2 and an average particle size between 2 and 10 nm. The high crystallinity and the small particle size of the noble metal particles lead to high catalytic activity for the catalyst. It is particularly suitable for use in fuel cells and for the treatment of exhaust gases from internal combustion engines.Type: GrantFiled: December 10, 2004Date of Patent: September 19, 2006Assignee: Umicore AG & Co. KGInventors: Karsten Ruth, Peter Biberbach, Karl-Anton Starz
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Patent number: 7060652Abstract: A liquid electrode mixture for use in a gas sensor having from about 60 to about 240 milligrams of platinum black catalyst; from about 900 to about 1100 milligrams of water; from about 300 to about 400 microliters of 1-propanol; and from about 100 microliters to about 150 microliters of a polymer mixture comprising from about 40% to about 80% PTFE by weight and water.Type: GrantFiled: November 15, 2005Date of Patent: June 13, 2006Assignees: OmegaPoint Systems, LLC, Transducer Technology, Inc.Inventors: Edward L. Gollar, III, Joseph R. Stetter, Nathan Schattke
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Patent number: 7060651Abstract: A silica-rich support and a catalyst containing the silica-rich support and a catalytic component. The support has a specific structure characterized by a set of claimed physicochemical properties: in the 29Si MAS NMR spectrum the state of silicon is characterized by the presence of lines with chemical shifts ?100±3 ppm (line Q3) and ?110±3 ppm (line Q4), with the ratio of the integral intensities of the lines Q3/Q4 of from 0.7 to 1.2 (FIG. 1); in the IR spectrum there is an absorption band of hydroxyl groups with the wave number 3620–3650 cm?1 and half-width 65–75 cm?1 (FIG. 2); the carrier has a specific surface area, as measured by the BET techniques from the thermal desorption of argon, SAR=0.5–30 m2/g and the surface, as measured by alkali titration techniques, SNa=10–250 m2/g, with SNa/SAr=5–30.Type: GrantFiled: December 4, 2000Date of Patent: June 13, 2006Assignee: Zakrytoe Aktsionernoe Obschestvo “Kholdingovaya Katalizatornaya Kompania”Inventors: Viktor Vladimirovich Barelko, Bair Sydypovich Balzhinimaev, Sergei Petrovich Kildyashev, Mikhail Grigorievich Makarenko, Anatoly Nikolaevich Parfenov, Ljudmila Grigorievna Simonova, Alexandr Viktorovich Toktarev
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Patent number: 7049266Abstract: Processes for the preparation of nanopalladium (0) catalysts are disclosed. In some embodiments, the nanopalladium (0) catalysts may be reusable. In some embodiments, the nanopalladium (0) catalysts may be heterogeneous. Nanopalladium (0) catalysts may be employed for preparing coupling products by C—C bond formation through reaction of haloarenes in the presence of base. Haloarenes used in the coupling reaction may include chloroarenes that are typically unreactive. The use of heterogeneous nanopalladium catalyst may preclude the presence of trace amounts of palladium in the final coupling product.Type: GrantFiled: March 31, 2003Date of Patent: May 23, 2006Assignee: Indian Institute of Chemical TechnologyInventors: Boyapati Manoranjan Choudary, Madhi Sateesh, Naidu Sreenivasa Chowdari, Mannepalli Lakshmi Kantam, Bojja Sreedhar
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Patent number: 7037878Abstract: An aircraft environmental control system includes a catalytic converter having ozone-destroying capability. A surface of the catalytic converter is anodized to form an anodized layer, and the metal oxide layer is washcoated to form a washcoat layer. An ozone destroying catalyst is impregnated in the anodized and washcoat layers. The catalyst may include one or more metals. For example, a bimetallic catalyst may include a precious metal and a transition metal.Type: GrantFiled: May 7, 2003Date of Patent: May 2, 2006Assignee: Honeywell International Inc.Inventors: Di-Jia Liu, Daniel R. Winstead, Peter M. Michalakos
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Patent number: 7030056Abstract: A process for preparing a catalyst which process comprises the steps of: (a) introducing a Group 8 metal compound onto a carrier, (b) converting a first portion of the Group 8 metal compound on the carrier into metallic species in a liquid phase reaction, and (c) subsequently converting a further portion of the Group 8 metal compound on the carrier into metallic species in a gas phase reaction; a catalyst which is obtainable by this process; and a process for preparing an alkenyl carboxylate comprising reacting a mixture comprising an olefin, a carboxylic acid and oxygen in the presence of the catalyst.Type: GrantFiled: March 24, 2003Date of Patent: April 18, 2006Assignee: Shell Oil CompanyInventors: Peter Birke, Hans-Dieter Neubauer, Rainer Schubert