Lanthanum Patents (Class 502/303)
  • Publication number: 20110207601
    Abstract: An object of the present invention is to provide an exhaust gas-purifying catalyst containing a composite oxide catalyst and a refractory support and being less prone to cause a decrease in its activity even when used at high temperatures in an atmosphere with high oxygen concentration. An exhaust gas-purifying catalyst includes a composite oxide catalyst containing rare-earth element, alkaline-earth element and precious metal, a part of the rare-earth element and a part of the alkaline-earth element forming composite oxide, and the composite oxide and a part of the precious metal forming solid solution, and a refractory support supporting the composite oxide catalyst and including at least one of a first composite oxide represented by a general formula AB2O4, a second composite oxide having perovskite structure represented by a general formula LMO3, and a third composite oxide having pyrochlore structure represented by a general formula X2Y2O7.
    Type: Application
    Filed: April 21, 2011
    Publication date: August 25, 2011
    Applicant: CATALER CORPORATION
    Inventors: Satoshi MATSUEDA, Mareo Kimura, Keiichi Narita
  • Patent number: 8003565
    Abstract: A method and catalysts for producing a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas contacts a water gas shift (WGS) catalyst, optionally in the presence of water, preferably at a temperature of less than about 450° C. to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst formulated from: a) Pt, its oxides or mixtures thereof; b) Ru, its oxides or mixtures thereof; and c) at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Co, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu. Another disclosed catalyst formulation comprises Pt, its oxides or mixtures thereof; Ru, its oxides or mixtures thereof; Co, its oxides or mixtures thereof; and at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu, their oxides and mixtures thereof.
    Type: Grant
    Filed: April 28, 2006
    Date of Patent: August 23, 2011
    Assignees: Honda Giken Kogyo Kabushiki Kaisha, Freeslate, Inc.
    Inventors: Alfred Hagemeyer, Raymond E. Carhart, Karin Yaccato, Peter Strasser, Robert K. Grasselli, Christopher James Brooks, Cory Bernard Phillips
  • Publication number: 20110201702
    Abstract: A ferrihydrite catalyst composition can comprise a ferrihydrite of a structural promoter metal, a chemical promoter metal and potassium to form an amorphous nanoparticulate. The ferrihydrite catalyst can be formed by dissolving an iron salt, a structural promoter metal salt and a chemical promoter metal salt in water to form an aqueous iron solution. A ferrihydrite solid can be precipitated from the aqueous iron solution by addition of a precipitating agent under conditions such that the ferrihydrite solid is a nanoparticulate. A potassium can be incorporated into the ferrihydrite solid to form a ferrihydrite catalyst precursor. The ferrihydrite catalyst precursor can be calcined to form the ferrihydrite catalyst. A synthesis gas can be readily converted to a fuel product by contacting the ferrihydrite catalyst with the synthesis gas under reaction conditions sufficient to form a fuel product mixture.
    Type: Application
    Filed: August 16, 2010
    Publication date: August 18, 2011
    Inventors: Sumit Bali, Garima Bali, Edward M. Eyring, Richard D. Ernst, Ronald J. Pugmire
  • Patent number: 7994090
    Abstract: Provided is a process for readily producing fine particles of a solid solution having a small particle size, comprising a solid solution of zirconia, ceria and a rare earth oxide in a desired composition, and being highly crystalline. The process for producing the fine particles of the solid solution comprises the following steps in the order named: obtaining a melt comprising, in terms of mol % on an oxide basis, from 5 to 50% ZrO2, CeO2 and RE2O3 (where RE is at least one member selected from rare earth elements other than Ce) in total, from 10 to 50% RO (where R is at least one member selected from the group consisting of Mg, Ca, Sr, Ba and Zn), and from 30 to 75% B2O3; quenching the melt to obtain an amorphous material; heating the amorphous material to obtain precipitates containing crystals of a solid solution with ZrO2, CeO2 and RE2O3; and separating the crystals of the solid solution from the precipitates to obtain fine particles of the solid solution.
    Type: Grant
    Filed: July 21, 2009
    Date of Patent: August 9, 2011
    Assignee: Asahi Glass Company, Limited
    Inventors: Yoshihisa Beppu, Kazuo Sunahara
  • Publication number: 20110189559
    Abstract: The present invention refers to the conversion of gaseous or gasifiable fuels with high methane content, such as natural gas, biogas, synthesis gas or gas originated from various industrial process rejects, with or without prior desulfurization and elimination of other contaminants, in a solid oxide fuel cell (SOFC), with special anodes, based on mixed oxides or metal oxides with a perovskite type structure, either or not nano structured, into light hydrocarbons, primarily ethylene and ethane.
    Type: Application
    Filed: June 29, 2009
    Publication date: August 4, 2011
    Applicants: OXITENO S.A. INDÚSTRIA E COMÉRCIO, INSTITUTO ALBERTO LUIZ COIMBRA DE PÓS-GRADUAÇÃO E PESQUISA DE ENGENHARIA - COPPE/UFRJ
    Inventors: Paulo Emílio Valadão De Miranda, Luís Guilherme Desá, Taísa Eva Fuziger Gutierres, Selma Aparecida Venâncio, Isabela Caldeira Leite Leocádio, Maria Auxiliadora Scaramelo Baldanza, Martin Schmal, Valéria Perfeito Vicentini
  • Publication number: 20110185625
    Abstract: Solid mixed catalysts and methods for use in conversion of triglycerides and free fatty acids to biodiesel are described. A batch or continuous process may be used with the catalysts for transesterification of triglycerides with an alkyl alcohol to produce corresponding mono carboxylic acid esters and glycerol in high yields and purity. Similarly, alkyl and aryl carboxylic acids and free fatty acids are also converted to corresponding alkyl esters. The described catalysts are thermostable, long lasting, and highly active.
    Type: Application
    Filed: August 20, 2009
    Publication date: August 4, 2011
    Applicant: SBI Fine Chemicals Inc.
    Inventors: Inder Pal Singh, Shradha Singh, Ritesh Patel, Bharat Mistry, Manish Mehta, Peter Omolo Otieno
  • Publication number: 20110183840
    Abstract: An improved method for the formation of composite hydroxides or oxides comprising, on an oxide basis, Al2O3 and ZrO2, and optionally CeO2, La2O3, Nd2O3, Pr6O11, Sm2O3, Y2O3, and other rare earth oxides, comprising the steps of preparing an aqueous metal salt solution and forming a hydroxide precipitate slurry by combining the aqueous metal salt solution with an aqueous solution of a caustic alkali at a pH greater than 8.5 to precipitate out all the metal species. The variation in pH during the precipitation reaction is ±1. The invention also relates to composites formed by this method comprising 20-70 wt % Al2O3, 10-77 wt % ZrO2, 0-34 wt % CeO2 and 0-22 wt % REOs other than CeO2, and to composites per se comprising, on an oxide basis, 42-70 wt % Al2O3, 10-48 wt % ZrO2, 2-34 wt % CeO2 and 0-9 wt % REOs other than CeO2 and having the following properties after heating to 850° C. over four hours and holding at 850° C.
    Type: Application
    Filed: April 6, 2011
    Publication date: July 28, 2011
    Applicant: MAGNESIUM ELEKTRON LIMITED
    Inventor: John G. DARAB
  • Publication number: 20110183221
    Abstract: The present invention relates to a catalytic porous layer for oxygen activation that can be used in solid oxide fuel cells (SOFC) and dense ceramic membranes for oxygen separation at a high temperature. This porous layer is mainly composed of an electron and oxygen ion mixed conductive material and has a structure selected from simple perovskite-type structures, double perovskite-type structures or perovskite-related structures, i.e. structures such as the Ruddlesden-Popper, Dion-Jacobson and Aurivillius type.
    Type: Application
    Filed: June 25, 2009
    Publication date: July 28, 2011
    Inventors: José Manuel Serra Alfaro, Vicente Bernardo Vert Belenguer, Sonia Escolástico Rozalén
  • Patent number: 7985709
    Abstract: The invention described herein involves a novel approach to the production of oxidation/reduction catalytic systems. The present invention serves to stabilize the tin oxide reducible metal-oxide coating by co-incorporating at least another metal-oxide species, such as zirconium. In one embodiment, a third metal-oxide species is incorporated, selected from the group consisting of cerium, lanthanum, hafnium, and ruthenium. The incorporation of the additional metal oxide components serves to stabilize the active tin-oxide layer in the catalytic process during high-temperature operation in a reducing environment (e.g., automobile exhaust). Moreover, the additional metal oxides are active components due to their oxygen-retention capabilities. Together, these features provide a mechanism to extend the range of operation of the tin-oxide-based catalyst system for automotive applications, while maintaining the existing advantages.
    Type: Grant
    Filed: September 28, 2004
    Date of Patent: July 26, 2011
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Jeffrey D. Jordan, David R. Schryer, Patricia P. Davis, Bradley D. Leighty, Anthony N. Watkins, Jacqueline L. Schryer, Donald M. Oglesby, Suresh T. Gulati, Jerry C. Summers
  • Publication number: 20110176988
    Abstract: The ammonia decomposition catalyst of the present invention is a catalyst for decomposing ammonia into nitrogen and hydrogen, including a catalytically active component containing at least one kind of transition metal selected from the group consisting of molybdenum, tungsten, vanadium, chromium, manganese, iron, cobalt, and nickel, preferably including: (I) a catalytically active component containing: at least one kind selected from the group consisting of molybdenum, tungsten, and vanadium; (II) a catalytically active component containing a nitride of at least one kind of transition metal selected from the group consisting of molybdenum, tungsten, vanadium, chromium, manganese, iron, cobalt, and nickel; or (III) a catalytically active component containing at least one kind of iron group metal selected from the group consisting of iron, cobalt, and nickel, and at least one metal oxide, thereby making it possible to effectively decompose ammonia into nitrogen and hydrogen at relatively low temperatures and at
    Type: Application
    Filed: September 17, 2009
    Publication date: July 21, 2011
    Inventors: Junji Okamura, Masaru Kirishiki, Masanori Yoshimune, Hideaki Tsuneki
  • Publication number: 20110178350
    Abstract: The object of the present invention is to provide the catalyst used in a process for preparation of alkenylaromatic compounds by dehydrogenating alkyl aromatic compounds by means of steam as a diluent, wherein the catalyst prevents the block and corrosion caused by the alkali metal component migrated from the catalyst, and the process for producing same, and the dehydrogenation method using it. The solid catalyst which has the high redox ability and comprises no alkali metal component migrated from the catalyst in the presence of steam with high temperature is used.
    Type: Application
    Filed: September 22, 2008
    Publication date: July 21, 2011
    Applicants: WASEDA UNIVERSITY, SUED-CHEMIE CATALYSTS JAPAN, INC.
    Inventors: Eiichi Kikuchi, Yasushi Sekine, Yuji Mishima
  • Patent number: 7981274
    Abstract: A catalytic element useful for promoting catalytic gas phase reactions is provided, comprising a porous ceramic body comprising a multiplicity of open pores having a coating comprising a basic oxide material and a catalyst material selected from transition metal and noble metal compounds.
    Type: Grant
    Filed: July 21, 2008
    Date of Patent: July 19, 2011
    Assignee: Pall Corporation
    Inventors: Manfred Nacken, Steffen Heidenreich
  • Patent number: 7981188
    Abstract: A porous ceramic honeycomb filter manufactured from an oxide-based ceramic material having a pore size distribution with d1?7.0 microns. Preferably, the oxide-based material is cordierite or aluminum titanate. Alternatively, the filter contains a cordierite-containing ceramic body with a narrow pore size distribution with db?1.00, wherein db=(d90?d10)/d50. Also disclosed is a batch mixture, method and honeycomb green body made from mixture of inorganic source materials selected from the group of magnesia sources, alumina sources, and silica sources, and a pore former having a narrow particle size distribution with dps?0.90, wherein dps={(dp90?dp10)/dp50}. The pore former is preferably selected from a group consisting of canna starch, sago palm starch, green mung bean starch, and single-mode potato starch.
    Type: Grant
    Filed: May 19, 2010
    Date of Patent: July 19, 2011
    Assignee: Corning Incorporated
    Inventors: Weiguo Miao, Paul John Shustack, Jennifer Lynn Skolny, Jianguo Wang, Yuming Xie
  • Patent number: 7981390
    Abstract: Catalyst articles comprising substantially only a palladium precious metal component and related methods of preparation and use are disclosed. Disclosed is a catalyst article comprising a first layer formed on a carrier substrate, wherein the first layer comprises a refractory metal oxide and has a surface that is substantially uniform; and a second layer formed on the first layer, wherein the second layer comprises i) an oxygen storage component that is about 50-90% by weight of the second layer and ii) a palladium component in an amount of about 10-150 g/ft3 of palladium, wherein the palladium component is substantially the only platinum group metal component. One or more improved properties are exhibited by the catalyst article.
    Type: Grant
    Filed: December 22, 2009
    Date of Patent: July 19, 2011
    Assignee: BASF Corporation
    Inventors: Michael P. Galligan, Xinsheng Liu, Pascaline H. Tran, Young Gin Kim, Ye Liu
  • Patent number: 7981829
    Abstract: An exhaust gas purifying catalyst includes: a composite oxide represented by: (Aa-w-xMwM?x) (Si6-yNy)O27-z. A is a cation of at least one of La and Pr; M is a cation of at least one of Ba, Ca, and Sr; M? is a cation of at least one of Nd, Y, Al, Pr, Ce, Sr, Li, and Ca; N is a cation of at least one of Fe, Cu, and Al. The following are satisfied: 6?a?10, 0<w<5, 0?x<5, 0<w+x?5, 0?y?3, 0?z?3, A?M?, and x?0 when A is a cation of La. A noble metal ingredient which forms a solid solution with the composite oxide or is supported on the composite oxide, and an exhaust gas purifying catalyst product formed of a carrier made of a ceramic or metallic material, and a layer of the exhaust gas purifying catalyst supported on the carrier.
    Type: Grant
    Filed: May 12, 2010
    Date of Patent: July 19, 2011
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Takashi Wakabayashi, Yuunosuke Nakahara
  • Publication number: 20110172086
    Abstract: A catalyst unit is described comprising a cylinder with a length C and a diameter D, wherein said unit has five holes arranged in a pentagonal pattern extending longitudinally therethrough, with five flutes running along the length of the unit, said flutes positioned equidistant adjacent holes of said pentagonal pattern. The catalyst may be used particularly in steam reforming reactors.
    Type: Application
    Filed: August 24, 2009
    Publication date: July 14, 2011
    Applicant: JOHNSON MATTHEY PLC
    Inventors: David James Birdsall, Mileta Babovic, Mikael Per Uno Carlsson, Samuel Arthur French, Michiel Nijemeisland, William Maurice Sengelow, Edmund Hugh Stitt
  • Patent number: 7976804
    Abstract: A catalyst for the decomposition of N2O under the conditions of the Ostwald process, comprising a carrier and a coating made of rhodium, rhodium/palladium or rhodium oxide applied thereto, ensures to yield NO with a particularly low content of laughing gas as the first process product.
    Type: Grant
    Filed: January 9, 2009
    Date of Patent: July 12, 2011
    Assignee: W.C. Heraeus GmbH
    Inventors: Uwe Jantsch, Jonathan Lund, Marek Gorywoda, Marcus Kraus
  • Patent number: 7977276
    Abstract: Disclosed is an exhaust gas purifying catalyst exhibiting excellent purification performance for a long period of time by suppressing coagulation of a noble metal. A catalyst powder comprises a noble metal and first and second compounds. In the catalyst powder, the first compound carries the noble metal and is separated from another first compound carrying a noble metal by the second compound. At least one catalyst layer comprising the catalyst powder is formed on an inner surface of a substrate. The catalyst layer has fine pores. A fine pore volume of fine pores having a fine pore diameter of greater than 0.1 ?m to less than or equal to 1 ?m is 10% to 60% of the fine pore volume of fine pores having a pore diameter of 1.0 ?m or less.
    Type: Grant
    Filed: April 4, 2008
    Date of Patent: July 12, 2011
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Hiroto Kikuchi, Katsuo Suga, Masanori Nakamura, Hironori Wakamatsu, Kazuyuki Shiratori, Toshiharu Miyamura, Jun Ikezawa
  • Publication number: 20110165045
    Abstract: An exhaust gas purification catalyst of the present invention contains at least a precious metal coated with lanthanum-containing alumina. In at least one embodiment, it is possible to provide: an exhaust gas purification catalyst which can (i) have an increase in heat resistance, and (ii) inhibit the precious metal from being mixed in alumina and therefore inhibit the precious metal from forming a solid solution in combination with alumina; and a method for efficiently purifying, by use of the catalyst, an exhaust gas emitted from an internal-combustion engine.
    Type: Application
    Filed: August 27, 2009
    Publication date: July 7, 2011
    Inventors: Masanori Ikeda, Kosuke Mikita, Takahiro Ikegami, Yuji Ogino, Hideki Goto
  • Publication number: 20110154807
    Abstract: A NOx trap comprises components comprising at least one platinum group metal, at least one NOx storage material and bulk ceria or a bulk cerium-containing mixed oxide deposited uniformly in a first layer on a honeycombed substrate monolith, the components in the first layer having a first, upstream, zone having increased activity relative to a second, downstream zone for oxidising hydrocarbons and carbon monoxide, and a second, downstream, zone having increased activity to generate heat during a desulphation event, relative to the first zone, wherein the second zone comprises a dispersion of rare earth oxide, wherein the rare earth oxide loading in the second zone is greater than the loading in the first zone. An exhaust system for a lean burn internal combustion engine, a vehicle comprising a lean burn internal combustion engine and the exhaust system and methods of making the NOx trap are also disclosed.
    Type: Application
    Filed: December 21, 2010
    Publication date: June 30, 2011
    Applicant: Johnson Matthey Public Limited Company
    Inventors: Guy Richard CHANDLER, Elizabeth Hazel MOUNTSTEVENS, Paul Richard PHILLIPS, Daniel SWALLOW
  • Publication number: 20110160049
    Abstract: An exhaust gas purifying catalyst includes: rhodium; a zirconium-containing oxide which supports rhodium, and comprises: at least one element selected from the group consisting of calcium, lanthanum, cerium, neodymium and yttrium; and zirconium; and a NOx absorbing material comprising at least one selected from the group consisting of magnesium, barium, sodium, potassium and cesium. A degree of dispersion of rhodium is 20% or more after baking at 900° C. in air for three hours. A method for manufacturing the exhaust gas purifying catalyst includes: mixing the zirconium-containing oxide with water, thereby preparing an aqueous liquid of the zirconium-containing oxide; and supporting rhodium on the zirconium-containing oxide by mixing the aqueous liquid of the zirconium-containing oxide with an aqueous solution of a rhodium salt. A pH of a mixed liquid of the aqueous solution of the rhodium salt and the aqueous liquid of the zirconium-containing oxide is adjusted to 7 or more.
    Type: Application
    Filed: June 8, 2009
    Publication date: June 30, 2011
    Inventors: Tetsuro Naito, Masanori Nakamura, Hironori Wakamatsu
  • Patent number: 7967887
    Abstract: An exhaust aftertreatment filter and method is provided for filtering engine exhaust, and reduces the maximum temperature experienced by the filter including during regeneration including during burn-off of trapped contaminant particulate including carbon oxidation combustion.
    Type: Grant
    Filed: November 3, 2006
    Date of Patent: June 28, 2011
    Assignee: Cummins Filtration IP, Inc.
    Inventors: Thomas M. Yonushonis, Conrad J. Simon, III, Bryan E. Blackwell, Matthew L. Anderson, Gary Salemme
  • Patent number: 7968490
    Abstract: A porous substance producing method for producing a porous substance; by holding particles for precursors of the porous substance in micelles or inverse micelles kept in a dispersed state in a solvent with a surfactant; by agglomerating the particles of the micelles or inverse micelles to each other; and by baking the agglomerated particles. The method comprises the step of agglomerating the particles of the micelles or inverse micelles to each other by performing a treatment to resolve the dispersed state of the micelles or inverse micelles containing the particles for the precursors, with the surfactant.
    Type: Grant
    Filed: July 11, 2005
    Date of Patent: June 28, 2011
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama
  • Patent number: 7964527
    Abstract: Catalytic compositions useful, e.g., for the treatment of internal combustion engine exhaust gases, are based on zirconium oxide in a weight proportion of at least 25%, from 15% to 60% of cerium oxide, from 10% to 25% of yttrium oxide, from 2% to 10% of lanthanum oxide and from 2% to 15% of another rare earth oxide, have a specific surface of at least 15 m2/g and a cubic phase, and are prepared from a mixture of zirconium, cerium, yttrium, lanthanum and the additional rare earth, by precipitating such mixture with a base, heating the precipitate in an aqueous medium, adding thereto a surfactant and calcining the precipitate.
    Type: Grant
    Filed: February 13, 2007
    Date of Patent: June 21, 2011
    Assignee: Rhodia Operations
    Inventors: Olivier Larcher, Stephan Verdier, Emmanuel Rohart, Aimin Huang
  • Patent number: 7960307
    Abstract: A sulfur reduction catalyst useful to reduce the levels of sulfur in a cracked gasoline product comprises a metal vanadate compound. The metal vanadate compound can be supported on a molecular sieve such as a zeolite in which the metal vanadate compound is primarily located on the exterior surface of the pore structure of the zeolite and on the surface of any matrix material used to bind or support the zeolite.
    Type: Grant
    Filed: March 6, 2007
    Date of Patent: June 14, 2011
    Assignee: BASF Corporation
    Inventors: Xingtao Gao, James Fu
  • Publication number: 20110137029
    Abstract: A process for preparing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of ammonia and primary and secondary amines, in the presence of a supported copper-, nickel- and cobalt-containing catalyst, wherein the catalytically active material of the catalyst, before the reduction thereof with hydrogen, comprises oxygen compounds of aluminum, of copper, of nickel, of cobalt and of tin, and in the range from 0.2 to 5.0% by weight of oxygen compounds of yttrium, of lanthanum, of cerium and/or of hafnium, each calculated as Y2O3, La2O3, Ce2O3 and Hf2O3 respectively, and catalysts as defined above.
    Type: Application
    Filed: December 2, 2010
    Publication date: June 9, 2011
    Applicant: BASF SE
    Inventors: PETR KUBANEK, Wolfgang Mägerlein, Johann-Peter Melder, Thomas Heidemann
  • Patent number: 7956005
    Abstract: An object of the present invention is to provide an exhaust gas-purifying catalyst containing a composite oxide catalyst and a refractory support and being less prone to cause a decrease in its activity even when used at high temperatures in an atmosphere with high oxygen concentration. An exhaust gas-purifying catalyst includes a composite oxide catalyst containing rare-earth element, alkaline-earth element and precious metal, a part of the rare-earth element and a part of the alkaline-earth element forming composite oxide, and the composite oxide and a part of the precious metal forming solid solution, and a refractory support supporting the composite oxide catalyst and including at least one of a first composite oxide represented by a general formula AB2O4, a second composite oxide having perovskite structure represented by a general formula LMO3, and a third composite oxide having pyrochlore structure represented by a general formula X2Y2O7.
    Type: Grant
    Filed: March 28, 2008
    Date of Patent: June 7, 2011
    Assignee: Cataler Corporation
    Inventors: Satoshi Matsueda, Mareo Kimura, Keiichi Narita
  • Patent number: 7955529
    Abstract: This invention discloses the synthesis of a bifunctional La0.6Ca0.4Co1-xIrxO3 (x=0˜1) perovskite compound with a superb bifunctional catalytic ability for the oxygen reduction and generation in alkaline electrolytes. Synthetic routes demonstrated include solid state reaction, amorphous citrate precursor, and mechanical alloying. The interested compound demonstrates notable enhancements over commercially available La0.6Ca0.4CoO3.
    Type: Grant
    Filed: May 6, 2009
    Date of Patent: June 7, 2011
    Assignee: National Chiao Tung University
    Inventors: Pu-Wei Wu, Yun-Min Chang
  • Publication number: 20110111949
    Abstract: Provided is an exhaust gas-purifying catalyst excelling in an exhaust gas-purifying performance. The exhaust gas-purifying catalyst contains a substrate, and a catalyst layer formed on the substrate and containing a precious metal and praseodymium.
    Type: Application
    Filed: January 13, 2011
    Publication date: May 12, 2011
    Applicant: CATALER CORPORATION
    Inventors: Ichiro KITAMURA, Akimasa HIRAI, Kenichi TAKI
  • Publication number: 20110111952
    Abstract: An exhaust gas purifying catalyst (1) is composed of: a noble metal (2); a first compound (3); and a second compound (4). The noble metal (2) is supported on the first compound (3). The exhaust gas purifying catalyst (1) includes units having a structure in which the first compound (3) supporting the noble metal (2) is surrounded by the second compound (4), and the first compound (3) supporting the noble metal (2) is isolated from one another by the second compound (4). The noble metal (2) is one or more selected from [Pt, Pd and Rh], the first compound (3) contains Ti as a main component, and the second compound (4) contains, as a main component, one or more selected from [Al and Si].
    Type: Application
    Filed: June 4, 2009
    Publication date: May 12, 2011
    Inventors: Kazuyuki Shiratori, Masanori Nakamura, Hironori Wakamatsu, Katsuo Suga
  • Publication number: 20110104047
    Abstract: Provided herein is a modified cobalt oxide based catalyst that includes cobalt oxide and lanthanum. The lanthanum is dispersed within the cobalt oxide, wherein the lanthanum is about 5-20% by weight of the modified cobalt oxide based catalyst. The method of producing the lanthanum modified cobalt oxide based catalyst and its use in producing hydrogen are also disclosed.
    Type: Application
    Filed: January 26, 2010
    Publication date: May 5, 2011
    Applicant: NATIONAL DEFENSE UNIVERSITY
    Inventors: Chuin-Tih YEH, Chen-Bin WANG, Chia-Chan LEE
  • Publication number: 20110105304
    Abstract: Architecture comprising ceramic or metallic foam, characterized in that the foam has a constant axial and radial porosity between 10 to 90% with a pore size between 2 to 60 ppi, and at least one continuous and/or discontinuous, axial and/or radial concentration of catalytic active(s) phase(s) from 0.01 wt % to 100 wt %, preferentially from 0.1 to 20 wt. %, and in that the architecture has a microstructure comprising specific area ranging between 0.1 to 30 m2/g, a grain size between 100 nm and 20 microns and a skeleton densification above 95%.
    Type: Application
    Filed: June 15, 2009
    Publication date: May 5, 2011
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Ex ploitation Des Procedes Georges Claude
    Inventors: Pascal Del-Gallo, Thierry Chartier, Mathieu Cornillac, Raphael Faure, Daniel Gary, Fabrice Rossignol
  • Publication number: 20110105305
    Abstract: An architecture made of a ceramic or a metallic foam has at least one continuous and/or discontinuous, axial and/or radial porosity gradient ranging from 10 to 90% associated to a pore size range from 2 to 60 ppi, at least one continuous and/or discontinuous, axial and/or radial concentration gradient of catalytic active(s) phase(s) from 0.01 wt % to 100 wt % preferentially from 0.1 wt % to 20 wt %, and a microstructure with a specific area ranging between 0.1 to 30 m2/g, a grain size between 100 nm and 20 microns and a skeleton densification above 95%.
    Type: Application
    Filed: June 16, 2009
    Publication date: May 5, 2011
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Pascal Del-Gallo, Daniel Gary, Thierry Chartier, Mathieu Cornillac, Raphael Faure, Fabrice Rossingnol
  • Publication number: 20110097252
    Abstract: The inventive composition, according to a first embodiment, consists essentially of a cerium oxide and a zirconium oxide in an atomic ratio Ce/Zr of at least 1. According to a second embodiment, said composition is based on cerium oxide, zirconium oxide with an atomic ratio Ce/Zr of at least 1 and at least one rare earth oxide other than cerium. After calcination at 1100° C., said composition has a specific surface of at least 9 m2/g in the second embodiment. The inventive composition can be used as a catalyst especially for the treatment of waste gases from internal combustion engines.
    Type: Application
    Filed: December 23, 2010
    Publication date: April 28, 2011
    Applicant: RHODIA ELECTRONICS AND CATALYSIS
    Inventors: Olivier LARCHER, Emmanuel Rohart
  • Patent number: 7928035
    Abstract: A modified catalyst support exhibiting attrition resistance and/or deaggregation resistance is provided. A catalyst composition including the modified catalyst support is also provided. A process to produce a modified catalyst support including treatment of a support slurry with a solution of monosilicic acid is provided. A process to use a catalyst including the modified catalyst support in a Fischer-Tropsch synthesis is provided.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: April 19, 2011
    Assignee: Syntroleum Corporation
    Inventors: Heinz J. Robota, Shelly Goodman
  • Patent number: 7923408
    Abstract: Diesel particulate filter that can lower the particulate matter (PM) combustion start temperature and use material containing silicon (Si) for a carrier. The carrier, which has a filter function, is allowed to support a perovskite-type complex oxide expressed by formula (1) as follows, wherein 0<x<0.7 and 0?y?1: formula (1)=La1-xBaxMnyFe1-yO3.
    Type: Grant
    Filed: February 20, 2007
    Date of Patent: April 12, 2011
    Assignees: Mitsubishi Jidosha Kogyo Kabushiki Kaisha, Dowa Electronics Materials Co., Ltd.
    Inventors: Masashi Takahashi, Hiroshi Tanada, Takuya Yano
  • Publication number: 20110082030
    Abstract: Precursor cations of A and B elements of an ABO3 perovskite in aqueous solution are formed as an ionic complex gel with citric acid or other suitable polybasic carboxylic acid. The aqueous gel is coated onto a desired catalyst substrate and calcined to form, in-situ, particles of the crystalline perovskite as, for example, an oxidation catalyst on the substrate. In one embodiment, a perovskite catalyst such as LaCoO3 is formed on catalyst supporting cell walls of an extruded ceramic monolith for oxidation of NO in the exhaust gas of a lean burn vehicle engine.
    Type: Application
    Filed: October 1, 2009
    Publication date: April 7, 2011
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
    Inventors: Chang H. Kim, Wei Li, Kevin A. Dahlberg
  • Patent number: 7915196
    Abstract: A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.
    Type: Grant
    Filed: October 7, 2005
    Date of Patent: March 29, 2011
    Assignee: Alliance for Sustainable Energy, LLC
    Inventors: Yves O. Parent, Kim Magrini, Steven M. Landin, Marcus A. Ritland
  • Publication number: 20110071017
    Abstract: The present invention provides a cerium oxide-zirconium oxide-based mixed oxide having superior platinum dispersibility and a suitable OSC, and a simple production process thereof. The cerium oxide-zirconium oxide-based mixed oxide comprises cerium oxide and zirconium oxide, wherein (1) the weight ratio of CeO2:ZrO2 is 60:40 to 90:10, and (2) the cerium oxide and the zirconium oxide are present as a mixture, the zirconium oxide being composed of a solid solution in which tetragonal or cubic zirconium oxide contains cerium.
    Type: Application
    Filed: September 21, 2010
    Publication date: March 24, 2011
    Applicant: DAIICHI KIGENSO KAGAKU KOGYO CO., LTD.
    Inventors: Hiroshi Okamoto, Masatoshi Maruki
  • Publication number: 20110070139
    Abstract: One embodiment of the invention may include a product comprising a catalyst combination comprising a perovskite catalyst and a second catalyst that is not a perovskite catalyst.
    Type: Application
    Filed: October 19, 2010
    Publication date: March 24, 2011
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
    Inventors: Chang H. Kim, David B. Brown, Wei Li, Steven J. Schmieg, Gongshin Qi
  • Patent number: 7909986
    Abstract: Reduced emissions of gas phase reduced nitrogen species in the off gas of an FCC regenerator operated in a partial or incomplete mode of combustion is achieved by contacting the off gas with an oxidative catalyst/additive composition having the ability to reduce gas phase nitrogen species to molecular nitrogen and to oxidize CO under catalytic cracking conditions. The oxidative catalyst/additive composition is used in an amount less than the amount necessary to prevent afterburn. Fluidizable particles of the oxidative catalyst/additives are circulated throughout the partial or incomplete burn FCC unit along with the FCC catalyst inventory. The flue gas having a reduced content of gas phase reduced nitrogen species and NOx is passed to a downstream CO boiler, preferably a low NOx CO boiler. In the CO boiler, as CO is oxidized to CO2, a reduced amount of gas phase reduced nitrogen species is oxidized to NOx, thereby providing an increase in the overall reduction of NOx emitted into the environment.
    Type: Grant
    Filed: May 6, 2009
    Date of Patent: March 22, 2011
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: George Yaluris, John Allen Rudesill
  • Patent number: 7910514
    Abstract: An inorganic fiber catalyst includes an alumina-silica fiber base material, and a plurality of catalyst component particles contained in the alumina-silica fiber base material. A mean particle diameter of the catalyst component particles contained in at least a surface portion of the alumina-silica fiber base material is 50 nm or less, and a standard deviation of particle diameters of the catalyst component particles is 30 or less.
    Type: Grant
    Filed: July 10, 2008
    Date of Patent: March 22, 2011
    Assignees: Nissan Motor Co., Ltd., Nitivy Co., Ltd.
    Inventors: Hideaki Morisaka, Masahiro Takaya, Yasunari Hanaki, Kouji Masuda, Michiaki Sagesaka, Naoki Harakawa
  • Patent number: 7909904
    Abstract: A method for producing a ceramic honeycomb structure comprises providing a honeycomb body having a side surface, a first cut end surface, a second cut end surface opposite the first end surface, and a maximum width (W), and removing material from at least one of the cut end surfaces of the honeycomb body to reduce the length (L), wherein the step of removing material comprises abrasively removing material from at least one of the ends with a rotating abrasive tool, such as by grinding, and wherein L/W is greater than 0.75. The method may achieve end flatness, parallelism, surface roughness and length accuracy, or combinations thereof which heretofore, were unachievable. Face finished ceramic honeycomb structures having low surface roughness (Ra), high degree of parallelism and accurate lengths are also disclosed.
    Type: Grant
    Filed: March 19, 2007
    Date of Patent: March 22, 2011
    Assignee: Corning Incorporated
    Inventor: Bruce Patrick Allen
  • Patent number: 7906015
    Abstract: Reduced emissions of gas phase reduced nitrogen species in the off gas of an FCC regenerator operated in a partial or incomplete mode of combustion is achieved by contacting the off gas with an oxidative catalyst/additive composition having the ability to reduce gas phase nitrogen species to molecular nitrogen and to oxidize CO under catalytic cracking conditions. The oxidative catalyst/additive composition is used in an amount less than the amount necessary to prevent afterburn. Fluidizable particles of the oxidative catalyst/additives are circulated throughout the partial or incomplete burn FCC unit along with the FCC catalyst inventory. The flue gas having a reduced content of gas phase reduced nitrogen species and NOx is passed to a downstream CO boiler, preferably a low NOx CO boiler. In the CO boiler, as CO is oxidized to CO2, a reduced amount of gas phase reduced nitrogen species is oxidized to NOx, thereby providing an increase in the overall reduction of NOx emitted into the environment.
    Type: Grant
    Filed: September 29, 2005
    Date of Patent: March 15, 2011
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: George Yaluris, John Allen Rudesill
  • Publication number: 20110053763
    Abstract: Catalyst compositions include finely divided nanoscale particles of at least one supported oxide selected from among zirconium oxide, titanium oxide or a mixed zirconium/titanium oxide deposited onto an alumina-based or aluminum-oxyhydroxide-based support, wherein, after calcination for 4 hours at 900° C., the at least one support oxide is in the form of nanoscale particles deposited onto the support, the size of said particles being at most 10 nm when the at least one supported oxide is based is zirconium oxide and being at most 15 nm when the at least one supported oxide is titanium oxide or a mixed zirconium/titanium oxide; such catalyst compositions are especially useful for the selective reduction of NOx.
    Type: Application
    Filed: February 23, 2009
    Publication date: March 3, 2011
    Applicant: RHODIA OPERATIONS
    Inventors: Stephan Verdier, Guillaume Criniere, Simon Ifrah, Rui Jorge Coelho Marques
  • Publication number: 20110045968
    Abstract: A catalyst layer includes: a first mixed oxide particle component 4 which contains Ce and Rh 8 and in which Rh is partially exposed at particle surfaces; and a second mixed oxide particle component 5 containing Ce, Zr, and a rare earth metal except Ce. The particle size distribution of the first mixed oxide particle component 4 has a peak in the particle size range from 100 nm to 300 nm, both inclusive. The particle size distribution of the second mixed oxide particle component 5 has a peak in a particle size range larger than the particle size range in which the first mixed oxide particle component 4 has the peak. At least part of particles of the first mixed oxide particle component 4 is attached to at least part of particles of the second mixed oxide particle component 5.
    Type: Application
    Filed: July 29, 2010
    Publication date: February 24, 2011
    Applicant: MAZDA MOTOR CORPORATION
    Inventors: Masaaki AKAMINE, Hideharu IWAKUNI, Hisaya KAWABATA, Yasuhiro OCHI, Yuki MURAKAMI, Susumu MINEOI, Akihide TAKAMI, Masahiko SHIGETSU
  • Publication number: 20110044874
    Abstract: An oxidation catalyst deposited on a substrate is described for the destruction of CO and volatile organic compounds, in particular halogenated organic compounds, from an emissions stream at temperatures from 250° C. to 450° C. The oxidation catalyst includes at least two platinum group metals, one of which is either platinum or ruthenium, supported on refractory oxides, such as a solid solution of CeO2 and ZrO2, and tin oxide and/or silica.
    Type: Application
    Filed: August 21, 2009
    Publication date: February 24, 2011
    Applicant: SUD-CHEMIE INC.
    Inventors: Zhongyuan Dang, Nirmal Singh, Martin Morrill, Greg Cullen
  • Publication number: 20110039691
    Abstract: An object of the present invention is to provide a catalyst support which can maintain the purifying ability of HC, CO and NO even after being exposed to a high temperature atmosphere such as about 1000° C. for a long term and a method which can easily produce the catalyst support. According to the present invention there is provided a method for producing a catalyst support of porous alumina formed with pores within which magneto-plumbite type complex oxide ((La.
    Type: Application
    Filed: August 20, 2010
    Publication date: February 17, 2011
    Applicant: KABUSHIKI KAISHA F.C.C.
    Inventors: Akihiko Tomoda, Ryou Suzuki, Shintaro Yagi
  • Publication number: 20110034331
    Abstract: An exhaust gas purifying catalyst including: a plurality of first compounds 5 which have precious metal particles 3 supported thereon and are formed into a particle shape; and second compounds 7 which are arranged among the plurality of first compounds 5 and separate the first compounds 5 from one another, wherein pore volumes of the precious metal particles 3, the first compounds 5 and the second compounds 7 are 0.24 to 0.8 cm3/g.
    Type: Application
    Filed: October 13, 2010
    Publication date: February 10, 2011
    Inventors: Hiroto KIKUCHI, Masanori Nakamura, Hironori Wakamatsu, Hideaki Morisaka, Hirofumi Yasuda, Katsuo Suga, Kazuyuki Shiratori, Kenji Uesugi, Toshiharu Miyamura
  • Patent number: 7884046
    Abstract: A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is hydrogenated in the presence of a shaped article which contains (i) an oxidic material comprising copper oxide, aluminum oxide and lanthanum oxide, and (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof, is provided.
    Type: Grant
    Filed: October 29, 2009
    Date of Patent: February 8, 2011
    Assignee: BASF SE
    Inventors: Sylvia Huber-Dirr, Michael Hesse, Andrea Haunert, Henrik Junicke