Abstract: A composite honeycomb structure in which the honeycomb structure is highly functionalized and adapted to have catalytic function, considering pressure loss is provided. A honeycomb structure having average pore diameter of 5 to 200 ?m and specific surface area of 100 to 1500 m2/g is provided. Further, a translucent honeycomb structure and a photocatalyst-carrying translucent honeycomb structure having a photocatalyst carried on a surface of the translucent honeycomb structure and/or contained in the translucent honeycomb structure are provided. Further, an air cleaner and a water purifier using the honeycomb structure and the photocatalyst-carrying translucent honeycomb structure are provided.

Abstract: An improved particulate filtration system has an inlet, for the fluid to be filtered, connected to a housing containing a filter medium such that the fluid passes through the filter medium, and an outlet for the filtered fluid to exit. The filtration system's improvement is the filter medium being comprised of a porous ceramic of fused platelet grains. In a particular embodiment, the porous ceramic is a celsian porous ceramic, where the celsian grains have a hexagonal morphology and display a continuous volume thermal expansion coefficient from 100° C. to 1000° C.

Abstract: Catalysts, systems and methods for abating emissions in an exhaust stream are provided. Systems comprising a transition metal oxide stabilized oxygen storage catalyst are described. The emissions treatment system is advantageously used for the treatment of exhaust streams from lean burn engines including diesel engines and lean burn gasoline engines.

Abstract: Process for the preparation of a catalytic specie consisting essentially of a metallic support, which is coated with a ceramic active phase layer, mainly compound of the general formula (I): [RhxNiyMglAlm(OH)2]z+(An?z/n)kH2O,??(I) wherein An? is mainly a silicate or a polysilicate anion; 0?x?0.3; 0?y?0.9; 0?l?0.9; 0?m?0.5; 0?k?10; x+y>0; 0.5?y+l?0.9; x+y+l+m=1; and z is the total electrical charge of the cationic element or a compound of the general formula (II): [AzA?1-z][B1-x-yNixRhy]O3-???(II) wherein A and A? are different and are selected from the Lanthanide or the Actinide families or from the group IIa of the Mendeleev's periodical table of elements; B is selected from the transition metal groups of columns IIIb, IVb, Vb, VIb, VIIb, Ib and IIb and group VIIIb of the Mendeleev's periodical table of elements; 0?x?0.7, 0?y?0.5, 0?x+y?0.

Abstract: The present invention provides a catalyst for combustion treatment of suspended particulate matter in diesel exhaust gases, and a combustion catalyst for treating diesel exhaust gases in which a precious metal or an oxide thereof as the catalytic component is loaded on a carrier composed of oxide ceramic particles comprising ceria-zirconia or ceria-praseodymium oxide. In the present invention, depending on the carried precious metal, the carrier is preferably composed of oxide ceramic particles further comprising yttria or lanthanum oxide. The present invention provides a sufficient activity to combust suspended particulate matter in exhaust gases, and can cause combustion at a low temperature of about 300° C. It operates stably for a long period, and can burn suspended particulate matter, especially carbon microparticles.

Abstract: An emission treatment system for a vehicle having an internal combustion engine is disclosed. The emission treatment system has an HC-SCR catalyst including a non-Pt group metal dispersed in a ceramic matrix configured to receive an exhaust gas flow from an engine. The system also has an oxidation catalyst comprising a Pt group metal configured to receive the exhaust gas flow from the HC-SCR catalyst. The system also has a U-SCR catalyst and a diesel particulate filter, one of the U-SCR catalyst or the DPF configured to receive the exhaust gas flow from the oxidation catalyst and the other one of the U-SCR catalyst or the diesel particulate filter configured to receive the exhaust gas flow from the respective one.

Abstract: A high efficiency catalyst for use in a catalytic partial oxidation process for the production of hydrogen or syngas gas from hydrocarbons is disclosed. The catalyst comprises rhenium in combination with a second metal selected from the group of rhenium to second metal of 25:1 to 1:1. the process comprises reacting a feed containing hydrocarbons with an oxygen source at a C/O ratio of about 0.9 to 1.1 in the presence of the catalyst, and wherein the gas hourly space velocity of the feed over the catalyst ranges from about 1,000 hr?1 to about 2,000,000 hr ?1. In the process, the catalyst is maintained as a temperature of from about 500° C. to about 1,500° C. as the feed makes contact with the catalyst.

Abstract: An exhaust system includes a particulate filter (PF) that is disposed downstream from an engine. The PF filters particulates within an exhaust from the engine. A heating element heats particulate matter in the PF. A catalyst substrate or a flow converter is disposed upstream from said heating element. The catalyst substrate oxidizes the exhaust prior to reception by the heating element. The flow converter converts turbulent exhaust flow to laminar exhaust flow prior to reception by the heating element.

Abstract: Disclosed is a catalyst, including a catalyst particle containing at least one component selected from the group consisting of gold, platinum and an gold alloy, the gold alloy containing gold and at least one element selected from transition metal elements of the fourth period, fifth period and sixth period of the Periodic Table, and a catalyst carrier carrying the catalyst particle and containing a perovskite type oxide represented by general formula (1) given below: A(1-x)BxTiOy??(1) where the element A is at least one element selected from the group consisting of Ca, Sr and Ba, the element B is at least one element selected from the group consisting of La, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, and Lu, the molar ratio x satisfies 0<x<1, and the molar ratio y satisfies 2.7?y?3.

Abstract: The mixed oxide of the invention mainly consists of cerium oxide and of at least one oxide of another rare earth. It has a specific surface area of at least 20 m2/g after calcining at 1000° C. for 5 hours. It is obtained by forming a liquid medium comprising a cerium compound; by heating this medium; by adding to the precipitate obtained a compound of the other rare earth, by heating the medium thus obtained and by bringing its pH to a basic value and by calcining the precipitate. The mixed oxide may be used as a catalyst support.

Abstract: A selective hydrogenation catalyst, with alumina as carrier, and palladium as active component that distributed on the surface of the carrier in an egg-shell form, characterized in that: provided that the catalyst is weighed 100%, it comprises 0.2-0.5 wt % active component Pd, 2-8 wt % aids lanthanum and/or cerium, and 2-8 wt % alkaline earth metal. The specific surface area of the catalyst is 70-150 m2/g, the pore volume is 0.3-0.6 ml/g, and the crystal form of the carrier may be ? form or ?, ? mixed form mainly composed of ? form. The catalyst is suitable for the selective hydrogenation of medium or low distillate oil, especially for the first stage selective hydrogenation of pyrolysis gasoline. The catalyst has good hydrogenation performance, and can keep good hydrogenation activity and stability especially under the condition that the feed contains a small quantity of water, and the content of colloid, arsenic, and diolefin is higher.

Abstract: A catalyst includes: (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

Abstract: An exhaust gas purifying catalyst that includes noble metal particles, first compounds which support the noble metal particles and suppress movement of the noble metal particles, and second compounds which encapsulate the noble metal particles and the first compounds. The second compounds suppress the movement of the noble metal particles and suppress coagulation of the first compounds following mutual contact of the first compounds.

Abstract: Catalyst in form of solid particles, wherein the particles—have a specific surface area of less than 20 m2/g, comprise a transition metal compound which is selected from one of the groups 4 to 10 of the periodic table (IUPAC) or a compound of actinide or lanthanide, comprise a metal compound which is selected from one of the groups 1 to 3 of the periodic table (IUPAC), and—comprise solid material, wherein the solid material • does not comprise catalytically active sites, • has a specific surface area below 500 m2/g, and • has a mean particle size below 100.

Abstract: An exhaust gas purifying catalyst comprises a substrate having a through hole serving as a passage for exhaust gas; and a catalyst coating layer formed on an internal surface of the through hole. The catalyst coating layer contains: a component (i): a precious metal; and a component (ii): at least one of a Zr oxide, a Ce oxide and a ZrCe mixed oxide. On an upstream portion of the passage, an oxide equivalent weight of Zr is within a range of 51-100 wt % of an oxide equivalent weight of Zr and Ce contained in the component (ii). On a downstream portion of the passage, the component (ii) includes at least one of a Ce oxide and a ZrCe mixed oxide in which an oxide equivalent weight of Ce is within a range of 58-100 wt % of an oxide equivalent weight of Zr and Ce contained in the ZrCe mixed oxide.

Abstract: The catalyst carrier in accordance with the present invention is a catalyst carrier comprising a support containing an oxide and an element in group 3A of the periodic table, and a coating part covering at least a part of a surface of the support; wherein the coating part contains an element in group 3A of the periodic table; and wherein the element in group 3A contained in the coating part has a concentration higher than that of the element in group 3A contained in the support. In this case, even when a catalyst in which rhodium is supported by the catalyst carrier is used for a long time in a high temperature environment, the grain growth of rhodium particles can be suppressed, and the catalyst can fully be prevented from lowering its activity.

Abstract: An exhaust gas purifying catalyst exhibiting high catalytic performance and restraining an amount of noble metals used is provided. An exhaust gas purifying catalyst has a catalyst substrate and a catalyst coating layer formed on the catalyst substrate. The catalyst coating layer has a layered structure including an inside layer containing (a-1) Pd, (a-2) Pt, and (a-3) an inorganic oxide, and an outside layer containing (b-1) a noble metal and (b-2) an inorganic oxide. A part of (a-3) the inorganic oxide carries Pd and Pt so that a weight ratio Pd/Pt is within a range of 8 to 12, whereas the other part of (a-3) the inorganic oxide carries Pd and Pt so that a weight ratio Pd/Pt is within a range of 4 to 6 or within a range of 18 to 22.

Abstract: The present invention relates to a novel catalyst for producing N-substituted carbamates, the preparation of the catalyst and an improved method for producing N-substituted carbamates from these novel catalysts. The active component of the catalyst is a heteropoly acid and the catalyst support comprises a metal oxide or a metalloid oxide. The catalyst can be used to promote the reaction of carbamate and amine, thereby generating N-substituted carbamates with high yield. In the presence of the catalyst, the reaction conditions are relatively mild, the catalytic activity and selectivity of the reaction are high, and the reaction time is relatively short. Furthermore, the catalyst can be conveniently separated from the reaction system and recycled. therefore, the catalyst can be used to facilitate the further scale-up test and commercial application.

Abstract: Provided in the present invention is a catalyst for an ATR (autothermal reforming) process of hydrogen production, as well as the methods to prepare and use it. The catalyst comprises a precious metal of the platinum family (e.g., Pt, Pd, Ru, Rh, Ir) and combinations and mixtures thereof as the active component, an alkali metal oxide and/or alkaline metal oxide as the first additive, and a CeO2-based composite oxide as the second additive. The catalyst can be used in pellet form, or may be formed into a monolithic form with all the catalytic active components and additives loaded on a support with a regular structure, such as a ceramic honeycomb, a metal honeycomb, or a metal foam.

Abstract: The present invention is related to single and/or multiple-wall carbon nanotubes which may contain interstitial metals obtainable by a preparation process, comprising a catalytic step using a catalytic system, said catalytic system comprising a catalyst and a support, said support comprising hydroxides and/or carbonates or mixtures thereof with or without metal oxides. The present invention is also related to carbon fibers obtainable by said preparation process. The present invention also pertains in particular to said catalytic system and to said preparation process. Another aspect concerns the use of the nanotubes and of the catalytic system according to the invention.

Abstract: A nanoporous metal oxide material comprising two or more metal oxides, wherein the nanoporous metal oxide material has ceria content of 10 to 60 weight %, zirconia content of 20 to 90 weight %, and alumina content of 70 weight % or less, and has nanopores whose diameters are 10 nm or less, and the metal oxides are homogeneously dispersed in a wall constituting the nanopores.

Abstract: The present invention refers to a continuous process for the manufacture of methyl mercaptan using Mo—O—K-based catalysts. It is further described that the total selectivity of methylmercaptan can be increased by at least 1% by lowering the total gas hourly space velocity. The invention further refers to a process for the preparation of a solid, preformed catalyst system.

Abstract: This invention is related to a preparation method of a supported catalyst Mo—O—K-MexOy for the synthesis of methanethiol from H2S-containing syngas. The catalyst comprises of an active component of Mo—O—K-based species, an active promoter and a support denoted as metal (or metals)-carrier. The support is prepared by electroless plating method in such a way that the metal or metals chosen are plated onto the surface of the carrier. Transition metal, especially Fe, Co or Ni are selected to be the plating metal, while SiO2, Al2O3 or TiO2 are selected to be carrier. The catalyst thus prepared is found to be efficient for the synthesis of methanethiol from H2S-containing syngasor carbon oxides/hydrogen mixtures, especially regarding a minor formation of the by-product CO2.

Abstract: The present invention provides a catalyst for production of nitric oxide from ammonia and oxygen. The catalyst has the composition A((n+1)?x)BxC(n(1?y))DnyO(3n+1)+d, wherein A is a lanthanide (La, Gd, Nd, Sm) or yttrium, B is an alkaline-earth cation (Ca, Sr or Ba), C is Fe and D is Cr, Mn, Ni, Ce, Ti, Co or Mg, wherein A, B, C and D are selected independent of each other. The catalyst has a high selectivity towards nitric oxide and a low ignition temperature in the reactor. Further the present invention relates to a method for the production of gas comprising nitric oxide by the catalyst of the present invention. The produced gas has a very low content of nitrous oxide.

Abstract: The present invention relates to catalysts for the production of hydrogen using the water gas shift reaction and the carbon dioxide reforming of hydrocarbon-containing fuels. The catalysts nickel and/or copper on a ceria/zirconia support, where the support is prepared using a surfactant templating method. The invention also includes processes for producing hydrogen, reactors and hydrogen production systems utilizing these catalysts.

Abstract: The inventive system for evaluating the charged state of depollution means integrated into the exhaust line of a motor vehicle engine is characterised in that it comprises means (7) for determining a pressure in the depollution means, means (8) for determining the volume gas flowrate upstream said depollution means (10) and means for comparing the depollution means state defined by the thus determined pressure and the volume flowrate with a predetermined diagram (11) of the absent, overcharged and clogged states of the depollution means in order to evaluate the state thereof.

Abstract: The present invention relates to a process for producing an aliphatic amine, comprising the step of contacting a linear or branched, or cyclic aliphatic alcohol having 6 to 22 carbon atoms with ammonia and hydrogen in the presence of a catalyst formed by supporting at least (A) a ruthenium component produced by hydrolysis of a ruthenium compound on a carrier, or by further supporting, in addition to the component (A), a specific second metal component or a specific third metal component on the carrier. According to the process of the present invention, an aliphatic primary amine can be produced from an aliphatic alcohol with a high catalytic activity and a high selectivity.

Abstract: A purifying catalyst includes catalyst powder composed of a transition metal oxide of which an average particle diameter is within 1 nm to 2 ?m and in which an electron binding energy of oxygen is shifted to an energy side lower than 531.3 eV. The purifying catalyst shows good purification performance even when noble metal is not contained as an essential component.

Abstract: The invention concerns a composition based on zirconium and cerium oxides in an atomic ratio Zr/Ce>1, and further comprising lanthanum oxide or an oxide of a rare earth other than cerium and lanthanum. The invention is characterized in that after calcination for 6 hours at 1150 .C it has a specific surface area of not less than 10 m;/g. The composition is obtained by forming a mixture containing a sol of a zirconium compound and cerium, lanthanum, said rare earth compounds, contacting said mixture with a basic compound solution, while heating and calcining the resulting precipitate. The composition can be used as catalyst.

Abstract: A catalyst for exhaust gas purification is provided that can not only efficiently and simultaneously purify nitrogen oxides, hydrocarbons and carbon monoxide in exhaust gas emitted from internal combustion engines such as those of automobiles even at lower temperatures, but also exhibits higher durability. The coexistence of a complex oxide that includes a rare earth element and palladium, a rare earth oxide, and a perovskite-type complex oxide that is expressed by the general formula LnAlO3, in which Ln is a rare earth element, may provide a catalyst that not only efficiently purifies the exhaust gas emitted from internal combustion engines such as those of automobiles even at lower temperatures, but also exhibits higher durability.

Abstract: The present invention relates to novel catalyst compositions and their use in a process for the catalytic conversion of ethanol to a reaction product comprising 1-butanol. The catalysts comprise Group II metal salts selected from the group consisting of oxides, carbonates, bicarbonates, hydroxides, and mixtures thereof, supported on a lanthanum-promoted oxide containing alumina.

Abstract: Modified exhaust aftertreatment filters for filtering engine exhaust are provided as are methods of design and manufacturing modified exhaust aftertreatment filters. The modified filters are subject to reduced back pressure and reduced thermal gradients experienced during regeneration as compared to unmodified filters. The modified filters include flow-through channels obtained by unplugging channels which normally are plugged in an unmodified filter.

Abstract: The present invention pertains to catalyst systems for nitrogen oxide, carbon monoxide, hydrocarbon, and sulfur reactions that are free or substantially free of platinum group metals. The catalyst system of the present invention comprise a substrate and a washcoat, wherein the washcoat comprises at least one oxide solid, wherein the oxide solid comprises one or more selected from the group consisting of a carrier material oxide, a catalyst, and mixtures thereof. The catalyst system may optionally have an overcoat, wherein the overcoat comprises at least one oxide solid, wherein the oxide solid comprises one or more selected from the group consisting of a carrier material oxide, a catalyst, and mixtures thereof. The catalyst comprises one or more selected from the group consisting of a ZPGM transition metal catalyst, a mixed metal oxide catalyst, a zeolite catalysts, or mixtures thereof.

Abstract: A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.

Abstract: A catalyst composition is provided for use on a diesel particulate filter which facilitates the oxidation of soot from diesel engine exhaust and which generates low NO2 emissions during regeneration of the filter. The catalyst composition includes a catalytic metal comprising a platinum group metal selected from Pt, Pd, Pt—Pd, or combinations thereof, an active metal oxide component containing Cu and La; and an oxide component selected from oxides of Co, Fe, or combinations thereof. The catalyst composition includes a support selected from alumina, silica, zirconia, or combinations thereof. The catalyst composition may be provided on a diesel particulate filter by impregnating the filter with an alumina, silica or zirconia sol solution modified with glycerol and/or saccharose, impregnating the filter with a stabilizing solution, and impregnating the filter with a solution containing the catalyst metal precursor(s), the active metal oxide precursor(s) and the Co or Fe oxide(s).

Abstract: A sulfur tolerant oxidation catalyst with appreciable NO and HC oxidation capabilities has been developed for use in any component of an exhaust aftertreatment system for a lean-burn engine where the oxidation of at least NO is desired. Several non-exclusive examples of such components where the oxidation catalyst may be employed include a DOC and a LNT. The oxidation catalyst may comprise perovskite oxide particles that support palladium particles. The ability of the palladium supported perovskite oxide particles to concurrently oxidize NO and HC's can significantly diminish or altogether eliminate the use of platinum in the exhaust aftertreatment system for at least NO oxidation. The oxidation catalyst, moreover, may exhibit superior thermal durability and better NO and HC oxidation activities than platinum in some instances.

Abstract: Nitrogen oxide storage catalysts are used to remove nitrogen oxides from the exhaust gas of internal combustion engines operated predominantly under lean burn conditions. When these catalysts are used in diesel vehicles, the increased sulfur content in the fuel during operation results in poisoning of the catalyst, which is reversible at high temperatures under reduced exhaust gas conditions. In the case of conventional nitrogen oxide storage catalysts, temperatures of more than 600° C. have to be obtained for desulfurization. This is not always possible in diesel vehicles with a nitrogen oxide storage catalyst in the underbody area. The invention presents a process whose application allows the desulfurization temperature of conventional nitrogen oxide storage catalysts which comprise a platinum component and at least one nitrogen oxide storage material to be lowered. The basicity of the chemical environment of the platinum is lowered, while the nitrogen oxide storage material can remain unchanged as such.

Abstract: A catalyst composition and a process for using it to decompose nitrous oxide into nitrogen and oxygen are disclosed. The catalyst composition has surface area of about 1 to about 200 m2/g after exposure to a calcination temperature of between about 400° C. and about 900° C., or about 1 to about 100 m2/g after exposure to a calcination temperature of between about 400° C. and about 950° C.

Abstract: A layered exhaust treatment catalyst comprising: (a) a carrier such as cordierite; (b) a first layer deposited on the carrier comprising a palladium metal component, a platinum metal component and an oxygen storage component such as ceria supported on a refractory metal oxide such as gamma-alumina; and (c) a second layer deposited on the first layer comprising a rhodium metal component, a platinum metal component and an oxygen storage component such as ceria supported on a refractory metal oxide such as gamma-alumina. Preferably, the catalyst also includes a bottom layer interposed between the carrier and the first layer. The bottom layer comprises an oxygen storage component such as ceria supported on a refractory metal oxide such as gamma-alumina. The amount of the oxygen storage component of the catalyst may be “tuned”, i.e., adjusted, to meet the needs of a vehicle's on-board diagnostic (“OBD”) catalyst efficiency monitoring system, without adversely affecting the performance of the catalyst.

Abstract: An alumina-based perovskite is formed by mixing a lanthanide source with a transitional alumina to form a dual-phase composition comprising in situ formed LnAlO3 dispersed in alumina. A second metal can be also included to form LaMO3 perovskite on alumina. The lanthanide content of the composition may range from about 6 to 35 wt. %, and the second metal from about 0.5 to 20 wt. %, to yield a high surface area composition which is useful as a catalyst or catalyst support such as for precious metals.

Abstract: A particulate inorganic mixed oxide comprising: aluminum; zirconium; cerium; and first and second additional elements each selected from the group consisting of rare earth elements other than cerium and alkaline earth elements, wherein a content of aluminum in the inorganic mixed oxide is 60 to 90 at %, in terms of element content, relative to a total amount of elements which form cations in the inorganic mixed oxide ; a content of cerium in the inorganic mixed oxide is 0.

Abstract: The invention provides a composite metal oxide adsorbent for fluoride removal and the preparation method thereof. Said composite metal oxide adsorbent for fluoride removal comprises: 0.05-0.15 molar parts of transition metal, 0.2-0.6 molar parts of Al and/or Mg, and 0.05-0.15 molar parts of rare earth metal. The composite metal oxide adsorbent for fluoride removal has a saturation adsorption capacity on fluorine in water of up to 229 mg/g, under a neutral condition.

Abstract: A method is provided for the thermo-neutral reforming of liquid hydrocarbon fuels which employs a Ni,Ce2O3, La2O3, Pt?ZrO2, Rh and Re catalyst having dual functionalities to achieve both combustion and steam reforming.

Abstract: A mesoporous, transition metal oxide material having an average pore diameter ranging from 2 to 20 nm, a basic surface character defined by an isoelectric point>pH 7, and a specific surface area greater than 50 m2/g can be incorporated into a NOx sensing device as a NOx film. The mesoporous, transition metal oxide material includes an oxide of yttrium, lanthanum and/or cerium, and can be formed using a surfactant-templated self-assembly process.

Abstract: Provided are catalyst composites that can be used in methods for treating exhaust gas from internal combustion engines, including diesel and gasoline engines, systems including such catalyst composites and methods of using the catalyst composites to treat internal combustion engine exhaust. The catalyst composites may provide diesel oxidation catalysts and three-way catalysts. A catalyst composite is provided which a catalytic material on a carrier, the catalytic material including a palladium component dispersed on a first support comprising at least 60% by weight of a zirconia component, and one or more rare earth oxides selected from the group consisting of lanthana, neodymia, praseodymia, yttria, the first support optionally containing no more than 15% by weight ceria, and being free of alumina. Layered catalyst composites having one or more washcoats on the carrier are also provided.

Abstract: A process for the conversion of hydrocarbons to hydrogen and one or more oxides of carbon, comprising contacting the hydrocarbon with steam and/or oxygen in the presence of a spinel-phase crystalline catalyst comprising a catalytically active metal. There is also described a method for making a catalyst suitable for the conversion of hydrocarbons to hydrogen and one or more oxides of carbon comprising adding a precipitant to a solution or suspension of a refractory oxide or precursor thereof and a catalyst metal-containing compound to form a precipitate which is calcined in an oxygen-containing atmosphere to produce a crystalline phase with a high dispersion of catalyst metal. There is further described a crystalline catalyst comprising the elements nickel, magnesium, aluminium and a lanthanide element, in which the crystalline phase is a spinel phase.

Abstract: The present invention provides honeycomb ceramic articles and methods of manufacturing such articles having few or no defects in the outer skin. Methods for minimizing and/or eliminating cracks in thin-wall and ultra-thin-wall cordierite honeycomb articles are disclosed. Advantageously, the present invention prevents skin cracks from forming during the production of thin-wall and ultra-thin-wall cordierite honeycomb articles by optimizing skin properties such as porosity, thickness and pore size distribution.

Abstract: The present invention provides a zirconia-based mixed oxide which, together with improving the heat resistance of specific surface area at a high temperature (1000° C. for 3 hours), has a ceria reduction rate of 80% or more, or in other words, improves the heat resistance of specific surface area and the reduction rate of ceria. The zirconia-based mixed oxide has zirconia for the main component thereof and contains 5% or more of ceria and 1 to 30% of a rare earth metal oxide other than ceria, wherein the specific surface area after heat treating for 3 hours at 1000° C. is 50 m2/g or more, the reduction rate of the ceria contained in the mixed oxide is 80% or more, and preferably the specific surface area after heat treating for 3 hours at 1100° C. is 20 m2/g or more.

Abstract: A catalyst carrier and exhaust gas purification catalyst superior in sintering inhibiting effect of precious metal catalyst particles are provided, that is, a catalyst carrier for carrying a precious metal comprised of a composite oxide of an electron accepting element (La) having an electron accepting property of accepting electrons from a precious metal element by approach or contact with the precious metal element (Pt) and not changing in atomic valence in an oxidation reduction reaction and of another element (Si) and, further, an exhaust gas purification catalyst comprised of this catalyst carrier on which precious metal catalyst particles are carried.

Abstract: A hydrodesulfurization catalyst used for hydrodesulfurization of catalytically cracked gasoline comprises a support composed mainly of alumina modified with an oxide of at least one metal selected from the group consisting of iron, chromium, cobalt, nickel, copper, zinc, yttrium, scandium and lanthanoid-based metals, with at least one metal selected from the group consisting of Group 6A and Group 8 metals loaded as an active metal on the support. Hydrogenation of olefins generated as by-products during hydrodesulfurization of the catalytically cracked gasoline fraction, as an important constituent base of gasoline, can be adequately inhibited to maintain the octane number, while sufficiently reducing the sulfur content of the hydrodesulfurized catalytically cracked gasoline fraction.