Zinc Patents (Class 502/307)
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Patent number: 11623204Abstract: A method for preparing a modified cellulose aerogel for glycoprotein separation is provided. In this method, cellulose aerogel is employed as a substrate. The cellulose aerogel is known to have a three-dimensional network structure with extremely high porosity and specific surface area and extremely low density. So, by using the cellulose aerogel as a substrate, it is possible to provide the glycoproteins to be separated with more binding sites. PEI dendrimer has abundant functional groups and can easily be modified. By modifying the cellulose aerogel substrate with the PEI dendrimer, it is possible to improve the density of the phenylboronic acid bound to the substrate, thereby leading to higher affinity toward the glycoproteins to be separated.Type: GrantFiled: September 9, 2021Date of Patent: April 11, 2023Assignee: Shaanxi University of Science & TechnologyInventors: Sufeng Zhang, Xue Yao, Liwei Qian, Chen Hua, Ning Wei, Quansheng Wang
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Patent number: 11420917Abstract: The invention relates to a new process for the manufacture of fluoroaryl compounds and derivatives thereof, in particular of fluorobenzenes and derivatives thereof, and especially wherein said manufacture relates to an environmentally friendly production of the said compounds. Thus, the present invention overcomes the disadvantages of the prior art processes, and in a surprisingly simple and beneficial manner, and as compared to the prior art processes, in particular, the invention provides a more efficient and energy saving processes, and also provides a more environmentally friendly process, for the manufacture of nuclear fluorinated aromatics, and preferably of nuclear fluorinated fluorobenzenes. Accordingly, in one aspect of the invention, an industrially beneficial process for preparing fluorobenzenes from halobenzene precursors using HF to form hydrogen halide is provided by the present invention.Type: GrantFiled: July 20, 2019Date of Patent: August 23, 2022Inventors: Hongjun Du, Wenting Wu
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Patent number: 11254880Abstract: The present invention relates to the use of adsorbents comprising zinc oxide nanowires decorated with catalytically active metal particles for the removal of sulfur from hydrocarbon feedstocks, including the desulfurization of diesel fuels and the deep desulfurization of natural gas, and to the use of decorated zinc oxide nanowire adsorbents for the hydrogenation of naphthalene selectively to tetralin in the presence of sulfur compounds. The adsorbent comprises nickel metal particles or nickel-zinc alloy particles deposited on zinc oxide nanowires.Type: GrantFiled: April 6, 2020Date of Patent: February 22, 2022Assignee: Advanced Energy Materials, LLCInventors: Mahendra Sunkara, Sivakumar Vasireddy, Juan He
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Patent number: 11148123Abstract: Disclosed is a catalyst for producing the olefin. The catalyst includes a support including alumina and a sub-support component, and a metal oxide impregnated on the support. The metal oxide includes anyone selected from an oxide of chromium, vanadium, manganese, iron, cobalt, molybdenum, copper, zinc, cerium and nickel; and the sub-support component includes anyone selected from zirconium, zinc and platinum.Type: GrantFiled: December 28, 2017Date of Patent: October 19, 2021Assignees: SK GAS CO., LTD., KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGYInventors: Won Choon Choi, Yong Ki Park, Su Jin Gong, Seo Hyun Shim, Deuk Soo Park, Ung Gi Hong
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Patent number: 11045793Abstract: Set forth herein is a Fischer-Tropsch catalytic system that allows for the efficient and selective conversion of syngas to useful hydrocarbons (nC4-nC24) as well as heavy alcohols (nC1-nC9) under ambient conditions. The instantly disclosed catalytic system is more practical and scalable than other known Fischer-Tropsch catalytic systems. Also set forth herein new catalysts which comprise supported metal-oxide-based catalysts. These catalysts are useful for the conversion of syngas into liquid hydrocarbon fuels under ambient reaction conditions. The instantly disclosed catalytic system can be made in a one-pot high mass production method, which is commercially practical and scalable. A variety of reaction products can be produced by making minor adjustments to the processes disclosed herein, e.g., by adjusting catalyst composition, reaction temperature and/or reaction pressure. The instantly disclosed process(es) produce Fischer-Tropsch products, heavy hydrocarbons (e.g.Type: GrantFiled: July 24, 2020Date of Patent: June 29, 2021Assignee: QATAR UNIVERSITYInventors: Ahmed Mohamed Shehata Soliman, Kamel Abdelmoniem Mohamed Eid, Aboubakr Moustafa Abdullah, Ahmed Abdelfattah Ahmed Mohamed Elzatahry
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Patent number: 11014864Abstract: The invention relates to a process for producing copper-containing catalysts, in particular shaped catalyst bodies having increased mechanical strength and a low volume shrinkage, and also the shaped catalyst bodies produced by the process of the invention and the use thereof as catalysts or as precursors and components for catalysts. The catalysts of the invention are particularly suitable for the synthesis of methanol and for the low-temperature conversion of CO into CO2.Type: GrantFiled: March 19, 2015Date of Patent: May 25, 2021Assignee: Clariant International Ltd.Inventors: Patrick Kurr, Benjamin Kniep, Andrea Blindhuber, Verena Pritscher
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Patent number: 10926246Abstract: The present invention relates to a method of preparing a catalyst for oxidative dehydrogenation. More particularly, the present invention provides a method of preparing a catalyst for oxidative dehydrogenation providing superior selectivity and yield for a conjugated diene according to oxidative dehydrogenation by constantly maintaining pH of a coprecipitation solution using a drip-type double precipitation method to adjust an ?-iron oxide content in a catalyst in a predetermined range.Type: GrantFiled: March 15, 2017Date of Patent: February 23, 2021Assignee: LG CHEM, LTD.Inventors: Jun Kyu Han, Dong Hyun Ko, Kyong Yong Cha, Myung Ji Suh, Sun Hwan Hwang, Seong Min Kim
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Patent number: 10464046Abstract: The present invention relates to an aqueous gas-converting catalyst composition comprising: an active component; a support; an inorganic binder; at least one accelerator selected from the group consisting of cobalt oxide, molybdenum oxide, nickel oxide, calcium oxide, barium oxide, strontium oxide, magnesium oxide, zirconium oxide, manganese oxide and barium titania; and at least one stabilizer selected from the group consisting of magnesium oxide, zirconium oxide, stabilized zirconia, and hydrotalcite. The catalyst according to the present invention can effectively capture and separate carbon dioxide due to the excellent physical properties thereof such as packing density and abrasion resistance, and high CO conversion. Also, according to the present invention, mass production is facilitated by applying a spraying technique, and overall costs are lowered because of high yield.Type: GrantFiled: June 11, 2012Date of Patent: November 5, 2019Assignee: Korea Electric Power CorporationInventors: Joong Beom Lee, Chong Kul Ryu, Tae Hyoung Eom, Dong Hyeok Choi, Jeom In Baek, Seong Jeagarl, Seok Ran Yang
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Patent number: 10202553Abstract: The hydroprocessing catalyst for a heavy hydrocarbon oil, includes, as a carrier, a phosphorus-silica-containing alumina carrier containing 0.1% by mass to 4% by mass of phosphorus in terms of oxide based on the carrier, and 0.1% by mass to 1.5% by mass of silica based on the carrier, the carrier supporting 8% by mass to 20% by mass of at least one selected from metals in Group 6 of the periodic table in terms of oxide based on the catalyst and 2% by mass to 6% by mass of at least one selected from metals in Groups 8 to 10 of the periodic table in terms of oxide based on the catalyst.Type: GrantFiled: September 25, 2014Date of Patent: February 12, 2019Assignee: COSMO OIL CO., LTD.Inventors: Takayuki Osaki, Nobumasa Nakajima
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Patent number: 9597659Abstract: A catalyst with a mixed zinc and aluminum oxide base having a spinel structure surstoichiometric in zinc, in which part of the Zn atoms are in the octahedral position, a process for preparation of the same and use of the same in a process for preparation of a compound of linear monocarboxylic acid alcohol esters with 6-26 carbon atoms from a vegetable or animal oil, neutral or acid, virgin or recycled, with monoalcohols of 1-18 carbon atoms allowing an ester that can be used as a motor fuel or a heating fuel and a pure glycerine to be obtained directly in one or more steps.Type: GrantFiled: October 13, 2010Date of Patent: March 21, 2017Assignee: IFB Energies nouvellesInventors: Delphine Bazer-Bachi, Vincent Coupard, Sylvie Maury, Veronique Pugnet, Isabelle Clemencon, Anne-Agathe Quoineaud
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Publication number: 20150148221Abstract: The disclosure provides molybdenum and/or tungsten containing catalyst materials useful for the sour gas shift reactions and methods for using such catalyst materials, for example, for converting carbon monoxide and steam to carbon dioxide and hydrogen.Type: ApplicationFiled: November 25, 2013Publication date: May 28, 2015Applicant: Clariant CorporationInventors: Justin X. Wang, William M. Faris, Yeping Cai
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Publication number: 20150112109Abstract: A layered multimetallic mixed oxide (LMMO) is characterized by one or more diffraction peaks at 5<2?<15, preferably between 10<2?<15. The catalysts can be represented by the general formula: M1 M2 M3 O? wherein M1 is selected from the group of Ag, Au, Zn, Sn, Rh, Pd, Pt, Cu, Ni, Fe, Co, an alkaline metal, an alkaline earth metal, a rare earth metal, or mixtures thereof. M2 is selected from the group of Ti, Hf, Zr, Sn, Bi, Sb, V, Nb, Ta and P, or mixtures thereof. M3 is selected from the group of Mo, W and Cr, or mixtures thereof. ? depends on the amount and oxidation state or valence of the other components, also it depends on the starting materials, preparation method and the activation process, and where the catalyst exhibits at least one X-ray diffraction peak between 5<2?<15.Type: ApplicationFiled: December 23, 2014Publication date: April 23, 2015Inventors: Jaime SANCHEZ VALENTE, Enelio TORRES GARCIA, Hector ARMENDARIZ HERRERA, Maria de Lourdes Alejandra GUZMAN CASTILLO, Andrea RODRIGUEZ HERNANDEZ, Roberto QUINTANA SOLORZANO, Maiby VALLE ORTA, Jose Manuel LOPEZ NIETO
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Publication number: 20150105580Abstract: The present invention relates to a device for treatment of material transported through the device comprising at least one porous element consisting of specific solid metallic structure which allows cross-flow of the material through the porous element and wherein the porous element is coated by a non-acidic metal oxide which is impregnated by palladium (Pd).Type: ApplicationFiled: April 17, 2013Publication date: April 16, 2015Inventor: Werner Bonrath
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Publication number: 20150025267Abstract: The present invention is related to a new metal powder catalytic system (catalyst) comprising a Fe-alloy as a carrier, its production and its use in hydrogenation processes.Type: ApplicationFiled: February 22, 2013Publication date: January 22, 2015Inventors: Werner Bonrath, Axel Buss
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Patent number: 8937203Abstract: The present invention relates to catalysts, to processes for making catalysts and to chemical processes employing such catalysts. The multifunctional catalysts are preferably used for converting acetic acid and ethyl acetate to ethanol. The catalyst is effective for providing an acetic acid conversion greater than 20% and an ethyl acetate conversion greater than 0%. The catalyst comprises a precious metal and one or more active metals on a modified support. The modified support includes a metal selected from the group consisting of tungsten, vanadium, and tantalum, provided that the modified support does not contain phosphorous.Type: GrantFiled: August 27, 2012Date of Patent: January 20, 2015Assignee: Celanese International CorporationInventors: Zhenhua Zhou, Heiko Weiner, Radmila Wollrab
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Publication number: 20150018585Abstract: The present invention is related to a new metal powder catalytic system (catalyst) comprising a cobalt/chrome-alloy as a carrier, its production and its use in hydrogenation processes.Type: ApplicationFiled: February 22, 2013Publication date: January 15, 2015Applicant: DSM IP ASSETS B.V.Inventors: Werner Bonrath, Axel Buss
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Publication number: 20150011791Abstract: The present invention is related to a new metal powder catalytic system (catalyst) comprising a Fe-alloy as a carrier, its production and its use in hydrogenation processes.Type: ApplicationFiled: February 22, 2013Publication date: January 8, 2015Inventors: Werner Bonrath, Axel Buss
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Publication number: 20150005535Abstract: The present invention relates to a structured catalyst based on sintered metal fibers (SMF) coated by a non-acidic metal oxide layer impregnated with Pd and Agnanopartides, characterized in that the ratio of the Pd:Ag is 1:1 to 10:1, as well as the use of such a catalyst in selective catalytic hydrogenations of organic compounds.Type: ApplicationFiled: October 26, 2012Publication date: January 1, 2015Applicant: DSM IP ASSETS B.V.Inventors: Werner Bonrath, Lioubov Kiwi-Minsker, Igor Iouranov
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Patent number: 8889078Abstract: A porous oxide catalyst includes porous oxide, and an oxygen vacancy-inducing metal which induces an oxygen vacancy in a lattice structure of a porous metal oxide.Type: GrantFiled: March 15, 2011Date of Patent: November 18, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Sang-min Ji, Hyun-chul Lee, Doo-hwan Lee, Seon-ah Jin
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Publication number: 20140275685Abstract: A layered multimetallic mixed oxide (LMMO) is characterized by one or more diffraction peaks at 5<2?<15, preferably between 10<2?<15. The catalysts can be represented by the general formula: M1M2M3O? wherein M1 is selected from the group of Ag, Au, Zn, Sn, Rh, Pd, Pt, Cu, Ni, Fe, Co, an alkaline metal, an alkaline earth metal, a rare earth metal, or mixtures thereof. M2 is selected from the group of Ti, Hf, Zr, Sn, Bi, Sb, V, Nb, Ta and P, or mixtures thereof. M3 is selected from the group of Mo, W and Cr, or mixtures thereof. ? depends on the amount and oxidation state or valence of the other components, also it depends on the starting materials, preparation method and the activation process, and where the catalyst exhibits at least one X-ray diffraction peak between 5<2?<15.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Inventors: Jaime SANCHEZ VALENTE, Enelio TORRES GARCIA, Hector ARMENDARIZ HERRERA, Maria de Lourdes Alejandra GUZMAN CASTILLO, Andrea RODRIGUEZ HERNANDEZ, Roberto QUINTANA SOLORZANO, Maiby VALLE ORTA, Jose Manuel LOPEZ NIETO
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Patent number: 8779014Abstract: The present invention provides a slurry catalyst and a method for preparing the same, and belongs to the technical field of preparing catalyst. Particularly, the present invention provides a slurry catalyst directly used in a slurry bed reactor for synthesizing methanol and dimethyl ether and a method for preparing the same, which uses the complete liquid phase preparation from solution to slurry without the conventional slurry-producing process of firstly forming a solid catalyst and dispersing it into an inert medium after crushing and milling. This catalyst mainly comprises Cu, Zn, Al and Zr, wherein atomic ratios of each of components are Cu/Zn/(Al+Zr)=1/0.1-5/0.15-15 and Zr/Al=1:1.0-1:30, and one or two selected from the group consisting of lanthanide metals, Mn, Mo, Si, V, W, Cr, Mg, Ni, K, Pd, Rh, Ru, Re, Pt and Sr is used a promoter.Type: GrantFiled: October 25, 2007Date of Patent: July 15, 2014Assignee: Taiyuan University of TechnologyInventors: Wei Huang, Zhihua Gao, Lihua Yin, Kechang Xie
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Patent number: 8772551Abstract: Disclosed herein are mixed oxide catalysts for the catalytic gas phase oxidation of alkanes, or mixtures of alkanes and olefins, for the production of aldehydes and carboxylic acids with air or oxygen in the presence of inert gases at elevated temperatures and pressure, and a method for the production of catalysts.Type: GrantFiled: July 6, 2011Date of Patent: July 8, 2014Assignee: Evonik Degussa GmbHInventors: Achim Fischer, Weimin Lu, Christoph Weckbecker, Klaus Huthmacher
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High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
Patent number: 8722940Abstract: A catalyst for the oxidation of an olefin to an unsaturated aldehyde comprising a mixed metal oxide having the formula (I): MoaWbMcM?dM?eZfOg??(I) where M represents trivalent metals, M? represents divalent metals, M? represents monovalent metals, Z represents elements in the form of an oxide, a, b, c, d, e, f and g are numbers, and where the catalyst has an anion to cation molar (ACM) ratio greater than 1.00 and less than 2.00 and an M? to M molar ratio between 1.95 and 2.15.Type: GrantFiled: March 1, 2012Date of Patent: May 13, 2014Assignee: Saudi Basic Industries CorporationInventors: James W. Kauffman, David L. Sullivan, Joe D. Dostal -
Patent number: 8703641Abstract: In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds end up in the supernatant. The metals can be recovered via any of chemical precipitation, ion exchange, electro-coagulation, and combinations thereof to generate an effluent stream containing less than 50 mole % of metal ions in at least one of the metal residuals, and for at least one of the metal residuals recovered as a metal precursor feed for use in the co-precipitation reaction. In one embodiment, the resin functions as an anion exchange resin with an acidic supernatant to recover Group VIB metal residuals, and a cation exchange resin with a basic supernatant to recover Promoter metal residuals. An effluent stream from the process to waste treatment contains less than 50 ppm metals.Type: GrantFiled: October 18, 2011Date of Patent: April 22, 2014Assignee: Chevron U.S.A. Inc.Inventors: Alexander E. Kuperman, Theodorus Maesen, Dennis Dykstra, Ping Wang, Soy Uckung
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Patent number: 8691723Abstract: The sequential production of a library of N different solids, in particular heterogeneous catalysts, where N within a day is an integer of at least 2, is performed by a) producing at least two different sprayable solutions, emulsions and/or dispersions of elements and/or element compounds of the chemical elements present in the catalyst and optionally of dispersions of inorganic support materials, b) continuously metering the at least two different solutions, emulsions and/or dispersions in a predefined ratio into a mixing apparatus in which the solutions, emulsions and/or dispersions are homogeneously mixed, c) continuously drying the mixture removed from the mixing apparatus and recovering the dried mixture, d) changing the ratios in step b) and repeating steps b), c) and d) (N?1) times until N different dried mixtures are obtained, e) optionally shaping and optionally calcining the mixtures to give the solids.Type: GrantFiled: July 30, 2004Date of Patent: April 8, 2014Assignee: BASF AktiengesellschaftInventors: Hartmut Hibst, Frieder Borgmeier, Martin Dieterle
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Publication number: 20140073828Abstract: A catalyst for converting methane to aromatic hydrocarbons is described herein. The catalyst comprises an active metal or a compound thereof, zinc or a compound thereof and an inorganic oxide support wherein the active metal is added to the support as a metal oxalate. A method of making the catalyst and a method of using the catalyst are also described.Type: ApplicationFiled: January 24, 2012Publication date: March 13, 2014Inventors: Armin Lange De Oliveira, Larry Lanier Marshall, Peter Tanev Tanev
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Patent number: 8664146Abstract: A bulk metal oxide catalyst composition of the general formula (X)b(M)c(Z)d(O)e??(I) wherein X represents at least one non-noble Group VIII metal; M represents at least one non-noble Group VIb metal; Z represents one or more elements selected from aluminum, silicon, magnesium, titanium, zirconium, boron, and zinc; one of b and c is the integer 1; and d and e and the other of b and c each are a number greater than 0 such that the molar ratio of b:c is in the range of from 0.5:1 to 5:1, the molar ratio of d:c is in the range of from 0.2:1 to 50:1, and the molar ratio of e:c is in the range of from 3.7:1 to 108:1; is prepared by controlled (co)precipitation of component metal compounds, refractory oxide material, and alkali compound in protic liquid. Resulting compositions find use in hydrotreatment processes involving particularly hydrodesulphurization and hydrodenitrification.Type: GrantFiled: November 17, 2011Date of Patent: March 4, 2014Assignee: Shell Oil CompanyInventors: Laszlo Domokos, Hermanus Jongkind, Johannes Anthonius Robert Van Veen
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Patent number: 8609575Abstract: A catalyst of one or more complex oxides having a nominal composition as set out in formula (1): AxB1-y-zMyPzOn (1) wherein A is selected from one or more group III elements including the lanthanide elements or one or more divalent or monovalent cations; B is selected from one or more elements with atomic number 22 to 24, 40 to 42 and 72 to 75; M is selected from one or more elements with atomic number 25 to 30; P is selected from one or more elements with atomic number 44 to 50 and 76 to 83; x is defined as a number where 0<x?1; y is defined as a number where 0?y<0.5; and z is defined as a number where 0<z<0.2.Type: GrantFiled: April 12, 2007Date of Patent: December 17, 2013Assignee: Very Small Particle Company LimitedInventors: Peter Cade Talbot, Jose Antonio Alarco, Geoffrey Alan Edwards
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Publication number: 20130324393Abstract: To provide a novel visible light-responsive photocatalyst or tungsten oxide visible light-responsive semiconductor improved in environmental resistance under an alkaline condition. The tungsten oxide visible light-responsive semiconductor unstable under an alkaline condition is improved in environmental resistance without losing photocatalytic function thereof by adding thereto at least one element selected from the group consisting of copper, tantalum, niobium, lanthanum, bismuth, calcium, chromium, manganese and zinc. The obtained environmental resistant visible light-responsive photocatalyst is subjected to an alkaline treatment to thereby be improved in photocatalytic activity.Type: ApplicationFiled: February 15, 2012Publication date: December 5, 2013Inventors: Kazuhiro Sayama, Yoshinari Konishi
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Patent number: 8586786Abstract: A catalyst for use in the production of an unsaturated aldehyde and/or an unsaturated carboxylic acid, the catalyst comparing (or, preferably, being composed of) a mixed oxide containing molybdenum, bismuth and iron, which has improved methanical strength, is produced by a method including the steps of (1) drying an aqueous solution or an aqueous slurry containing raw materials of the catalyst and then firstly calcining a dried product in a molecular oxygen-containing gas atmosphere to obtain a calcined product; (2) heating the calcined product obtained in Step (1) in the presence of a reducing material to obtain a reduced product having a mass loss of 0.05 to 6%; and (3) secondly calcining the reduced product obtained in Step (2) in a molecular oxygen-containing gas atmosphere.Type: GrantFiled: July 23, 2012Date of Patent: November 19, 2013Assignee: Sumitomo Chemical Company, LimitedInventors: Naoki Miura, Eiichi Shiraishi, Koichi Nagai
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HIGH MOLYBDENUM MIXED METAL OXIDE CATALYSTS FOR THE PRODUCTION OF UNSATURATED ALDEHYDES FROM OLEFINS
Publication number: 20130231507Abstract: A catalyst for the oxidation of an olefin to an unsaturated aldehyde comprising a mixed metal oxide having the formula (I): MoaWbMcM?dM?eZfOg??(I) where M represents trivalent metals, M? represents divalent metals, M? represents monovalent metals, Z represents elements in the form of an oxide, a, b, c, d, e, f and g are numbers, and where the catalyst has an anion to cation molar (ACM) ratio greater than 1.00 and less than 2.00 and an M? to M molar ratio between 1.95 and 2.15.Type: ApplicationFiled: March 1, 2012Publication date: September 5, 2013Inventors: James W. Kauffman, David L. Sullivan, Joe D. Dostal -
Patent number: 8507403Abstract: A process is described for producing a powder batch comprises a plurality of particles, wherein the particles include (a) a first catalytically active component comprising at least one transition metal or a compound thereof; (b) a second component different from said first component and capable of removing oxygen from, or releasing oxygen to, an exhaust gas stream; and (c) a third component different from said first and second components and comprising a refractory support. The process comprises providing a precursor medium comprising a liquid vehicle and a precursor to al least one of said components (a) to (c) and heating droplets of said precursor medium carried in a gas stream to remove at least part of the liquid vehicle and chemically convert said precursor to said at least one component.Type: GrantFiled: June 27, 2008Date of Patent: August 13, 2013Assignee: Cabot CorporationInventors: Miodrag Oljaca, Toivo T. Kodas, Ranko P. Bontchev, Klaus Kunze, Kenneth C. Koehlert
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Publication number: 20130184148Abstract: A process for the selective production of ethanol by vapor phase reaction of acetic acid over a hydrogenating catalyst composition to form ethanol is disclosed and claimed. In an embodiment of this invention reaction of acetic acid and hydrogen over either cobalt and palladium supported on graphite or cobalt and platinum supported on silica selectively produces ethanol in a vapor phase at a temperature of about 250° C.Type: ApplicationFiled: March 6, 2013Publication date: July 18, 2013Applicant: CELANESE INTERNATIONAL CORPORATIONInventor: CELANESE INTERNATIONAL CORPORATION
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Publication number: 20130178670Abstract: The present invention relates to catalysts, to processes for making catalysts and to chemical processes employing such catalysts. The catalysts are preferably used for converting acetic acid and ethyl acetate to ethanol. The catalyst comprises an extruded modified support, and a precious metal. The processes for making the catalysts comprises modifying the catalyst, extruding the catalyst, and impregnating the precious metal onto the catalyst.Type: ApplicationFiled: January 4, 2013Publication date: July 11, 2013Applicant: Celanese International CorporationInventor: Celanese International Corporation
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Patent number: 8481448Abstract: The invention is a heteropoly acid compound catalyst composition, a method of making the catalyst composition and a process for the oxidation of saturated and/or unsaturated aldehydes to unsaturated carboxylic acids using the catalyst composition. The catalyst composition is a heteropoly acid compound containing molybdenum, vanadium, phosphorus, cesium, bismuth, copper and antimony. Thermal stability is achieved with higher cesium content (up to less than 3.0) but antimony, copper and bismuth must be present to maintain good activity. The catalyst is made by dissolving compounds of the components of each of the heteropoly acid compounds in a solution, precipitating the heteropoly acid compounds, obtaining a catalyst precursor and calcining the catalyst precursor to form a heteropoly acid compound catalyst. Unsaturated aldehydes, such as methacrolein, may be oxidized in the presence of the heteropoly acid compound catalyst to produce an unsaturated carboxylic acid, such as methacrylic acid.Type: GrantFiled: July 19, 2010Date of Patent: July 9, 2013Assignee: Saudi Basic Industries CorporationInventors: Wugeng Liang, David Sullivan, James W. Kauffman, Clark Rea, Joe Linzer, Shahid Shaikh
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Publication number: 20130118912Abstract: Compositions, electrodes, systems, and/or methods for water electrolysis and other electrochemical techniques are provided. In some cases, the compositions, electrodes, systems, and/or methods are for electrolysis which can be used for energy storage, particularly in the area of energy conversion, and/or production of oxygen, hydrogen, and/or oxygen and/or hydrogen containing species. In some embodiments, the water for electrolysis comprises at least one impurity and/or at least one additive which has little or no substantially affect on the performance of the electrode.Type: ApplicationFiled: December 26, 2012Publication date: May 16, 2013Applicant: SUN CATALYTIX CORPORATIONInventor: Sun Catalytix Corporation
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Patent number: 8435923Abstract: Compositions, materials incorporating the compositions, and methods of use thereof, for the protection and/or decontamination of contaminants are disclosed.Type: GrantFiled: March 29, 2007Date of Patent: May 7, 2013Assignee: Emory UniversityInventors: Nelya Okun, Craig Hill, Zhen Luo
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Patent number: 8409543Abstract: A pyrochlore-type oxide represented by a general formula A2B2O7-Z is prepared by precipitate formation, where A and B each represent a metal element, where Z represents a number of at least 0 and at most 1, where A contains at least one element selected from a group consisting of Pb, Sn, and Zn, and where B contains at least one element selected from a group consisting of Ru, W, Mo, Ir, Rh, Mn, Cr, and Re. Impurities are then sufficiently removed through washing and drying processes, and the pyrochlore-type oxide is calcined under controlled conditions. This allows the crystallinity of the pyrochlore-type oxide, which contained amorphous parts immediately after the production of the precipitate, to be increased so that the resistance to acid can be improved while preventing particle aggregation.Type: GrantFiled: August 30, 2011Date of Patent: April 2, 2013Assignee: JX Nippon Oil & Energy CorporationInventors: Yasushi Sato, Keitaro Fujii
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Patent number: 8404204Abstract: The present invention is directed to a granulate having photocatalytic activity, comprising particles of an inorganic particulate material coated with a photocatalytically active compound for introducing photocatalytic activity into or on building materials. The invention is further related to the manufacture of such a granulate and its use into or on building materials such as cement, concrete, gypsum and/or limestone and water-based coatings or paints for reducing an accumulation and growth of microorganisms and environmental polluting substances on these materials and thus reducing the tendency of fouling, while the brilliance of the color is maintained and the quality of the air is improved.Type: GrantFiled: March 31, 2008Date of Patent: March 26, 2013Assignee: Rockwood Italia SpAInventors: Marino Sergi, Christian Egger
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Patent number: 8362302Abstract: Isopropyl alcohol is a very useful chemical that is widely used in the industry as a solvent. Economical and easy process to make ispopropyl alcohol using novel composite catalyst is described in the instant application. Production of isopropyl alcohol (IPA) from dimehtyl ketone (DMK) and hydrogen (H2) in gas-phase using a ruthenium nano-particle-supported on activated charcoal/nano-zinc oxide composite catalyst is described. Gas phase production of isopropyl alcohol using DMK and hydrogen is also described using optimal time on stream, temperature, catalyst ratio and DMK/H2 ratio. Ruthenium nano-zinc oxide composite catalyst is formulated using different ratios of ruthenium activated charcoal and n-ZnO is described. CAT-IV is shown to be the best performer for the efficient production of isopropyl alcohol.Type: GrantFiled: April 16, 2012Date of Patent: January 29, 2013Assignee: King Abdulaziz City for Science and Technology (KACST)Inventors: Abdulaziz A Bagabas, Mohamed Mokhtar Mohamed Mostafa, Abdulrahman A Al-Rabiah, Vagif Malik Akhmedov
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Patent number: 8361923Abstract: A process is provided for producing a complex oxide catalyst which exhibits superior catalytic activity in a vapor phase catalytic oxidation reaction, particularly in production of unsaturated aldehyde and unsaturated carboxylic acid. The process is characterized by the steps of preparing an aqueous slurry by mixing a complex oxide containing molybdenum and cobalt with an acid and water; drying the aqueous slurry; and calcining the resulting dried solid. Preferably, the complex oxide is obtained as follows: a molybdenum- and cobalt-containing complex oxide catalyst which has been used in a vapor phase catalytic oxidation reaction is mixed with an aqueous extracting solution obtained by dissolving at least one of ammonia and an organic base in water, to thereby extract molybdenum and cobalt into the aqueous phase; and the aqueous phase is dried and is then calcined under an atmosphere of an oxidizing gas.Type: GrantFiled: September 29, 2010Date of Patent: January 29, 2013Assignee: Sumitomo Chemical Company, LimitedInventors: Hirotsugu Kano, Eiichi Shiraishi
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Patent number: 8288309Abstract: A highly durable mercury oxidation catalyst contains V2O5 and MoO3 as active components, and is capable of preventing volatilization of MoO3 in the mercury oxidation catalyst. A method of producing the mercury oxidation catalyst is provided. A mercury oxidation catalyst oxidizing mercury in an exhaust gas into mercury oxide includes: TiO2 as a carrier, V2O5 and MoO3 supported on the carrier as active components, and at least one kind of element or compound selected from the group consisting of W, Cu, Co, Ni, and Zn or the compounds thereof supported on the carrier as a MoO3 volatilization preventing component.Type: GrantFiled: September 30, 2010Date of Patent: October 16, 2012Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Katsumi Nochi, Masanao Yonemura, Masashi Kiyosawa
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Patent number: 8278241Abstract: Described is a novel amorphous silica-alumina composition having a high ratio of pore volume contained in large pores to pore volume contained in medium to small pores. The amorphous silica-alumina composition also may have the characteristic of a strong aluminum-NMR penta-coordinated peak representing greater than 30% of the total aluminum and a method of making such novel amorphous silica-alumina composition using a pH swing preparation method.Type: GrantFiled: February 25, 2010Date of Patent: October 2, 2012Assignee: Shell Oil CompanyInventors: Russell Craig Ackerman, Christian Gabriel Michel, John Anthony Smegal, Johannes Anthonius Robert Van Veen
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Patent number: 8252714Abstract: A catalyst for use in the production of an unsaturated aldehyde and/or an unsaturated carboxylic acid, the catalyst comparing (or, preferably, being composed of) a mixed oxide containing molybdenum, bismuth and iron, which has improved mechanical strength, is produced by a method including the steps of (1) drying an aqueous solution or an aqueous slurry containing raw materials of the catalyst and then firstly calcining a dried product in a molecular oxygen-containing gas atmosphere to obtain a calcined product; (2) heating the calcined product obtained in Step (1) in the presence of a reducing material to obtain a reduced product having a mass loss of 0.05 to 6%; and (3) secondly calcining the reduced product obtained in Step (2) in a molecular oxygen-containing gas atmosphere.Type: GrantFiled: May 15, 2009Date of Patent: August 28, 2012Assignee: Sumitomo Chemical Company, LimitedInventors: Naoki Miura, Eiichi Shiraishi, Koichi Nagai
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Publication number: 20120208695Abstract: A supported catalyst composition suitable for use in converting synthesis gas to alcohols comprises a catalytic metal, a catalyst promoter and a catalyst support.Type: ApplicationFiled: November 2, 2010Publication date: August 16, 2012Applicant: Dow Global Technologies LLCInventors: Billy B. Bardin, David G. Barton, Adam Chojecki, Howard W. Clark, Daniela Ferrari, Robert J. Gulotty, JR., Yu Liu, Mark H. McAdon, Dean M. Millar, Neelesh Rane, Hendrik E. Tuinstra
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Publication number: 20120202681Abstract: A carbon oxides conversion process includes reacting a carbon oxide containing process gas containing hydrogen and/or steam and containing at least one of hydrogen and carbon monoxide in the presence of a catalyst including shaped units formed from a reduced and passivated catalyst powder, the powder including copper in the range 10-80% by weight, zinc oxide in the range 20-90% by weight, alumina in the range 5-60% by weight and optionally one or more oxidic promoter compounds selected from compounds of Mg, Cr, Mn, V, Ti, Zr, Ta, Mo, W, Si and rare earths in the range 0.01-10% by weight, wherein said shaped units have a reduced to as-made mean horizontal crush strength ratio of ?0.5:1 and a copper surface area above 60 m2/g Cu.Type: ApplicationFiled: May 24, 2010Publication date: August 9, 2012Applicant: JOHNSON MATTHEY PLCInventors: Colin William Park, Brian Peter Williams, Graeme Douglas Campbell, David Allan Buckworth
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Publication number: 20120142522Abstract: A carbonaceous feedstock to alcohol conversion process in which carbon dioxide is removed from the syngas stream issuing from a feedstock reformer, to yield a carbon dioxide depleted syngas stream including hydrogen, carbon monoxide and methane. This carbon dioxide depleted syngas stream is then passed through a Fischer-Tropsch reactor ultimately yielding a mixed alcohol product which is preferably largely ethanol. The removed carbon dioxide stream is passed through a methane reformer along with methane, which is produced in or has passed through a Fischer-Tropsch reactor, to yield primarily carbon monoxide and hydrogen. The carbon monoxide and hydrogen stream from the methane reformer are passed through the alcohol reactor. Also disclosed are a unique catalyst, a method for controlling the content of the syngas formed in the feedstock reformer, and a feedstock handling system.Type: ApplicationFiled: February 8, 2012Publication date: June 7, 2012Applicant: Pearson Technologies, Inc.Inventor: Stanley R. PEARSON
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Patent number: 8188328Abstract: The present invention is an improved cyclic, endothermic hydrocarbon conversion process and a catalyst bed system for accomplishing the same. Specifically, the improved process comprises reacting a hydrocarbon with a multi-component catalyst bed in such a manner that the temperature within the catalyst bed remains within controlled temperature ranges throughout all stages of the process. The multi-component catalyst bed comprises a reaction-specific catalyst physically mixed with a heat-generating material.Type: GrantFiled: June 27, 2011Date of Patent: May 29, 2012Assignee: Sud-Chemie Inc.Inventors: Vladimir Fridman, Michael A. Urbancic
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Publication number: 20120116131Abstract: A new chromium-containing fluorination catalyst is described. The catalyst comprises an amount of zinc that promotes activity. The zinc is contained in aggregates which have a size across their largest dimension of up to 1 micron. The aggregates are distributed throughout at least the surface region of the catalyst and greater than 40 weight % of the aggregates contain a concentration of zinc that is within ±1 weight % of the modal concentration of zinc in those aggregates.Type: ApplicationFiled: September 4, 2009Publication date: May 10, 2012Applicant: Mexichem Amanco Holdings S.A. DE C.V.Inventor: Andrew P. Sharratt
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Patent number: 8158841Abstract: To provide a method for hydrotreating a synthetic hydrocarbon oil, which removes olefins and oxygen-containing compounds by hydrotreatment with the gasification rate restrained and can efficiently convert the synthetic hydrocarbon oil generated by the FT process to a liquid fuel suitable as a fuel for diesel-powered vehicles. A hydrotreating method is disclosed in which a synthetic hydrocarbon oil generated by FT synthesis is hydrotreated using a catalyst in which a definite catalytic metal is allowed to be carried on a support, under definite reaction conditions, with the gasification rate restrained to a definite value or less, thereby removing the olefins and the oxygen-containing compounds.Type: GrantFiled: September 22, 2005Date of Patent: April 17, 2012Assignees: Japan Oil, Gas and Metals National Corporation, Japan Petroleum Exploration Co., Ltd., Cosmo Oil Co., Ltd., Nippon Steel Engineering Corporation, Inpex CorporationInventors: Hiroaki Hara, Toshio Shimizu, Yutaka Miyata