Of Platinum Patents (Class 502/334)
  • Patent number: 7446076
    Abstract: Catalytic converter comprises a carrier having exhaust gas passages therein, a lower catalytic layer coated over the carrier and comprising hollow oxide powder loaded with catalytic metal, and an upper catalytic layer coated over the lower catalytic layer, directly exposed to exhaust gas flowing in the exhaust gas passages and comprising solid oxide powder loaded with catalytic metal. The hollow oxide powder may be ceria or alumina base oxide. Further it may be mixed oxide such as Ce—Zr mixed oxide or La contained alumina as well.
    Type: Grant
    Filed: November 29, 2005
    Date of Patent: November 4, 2008
    Assignee: Mazda Motor Corporation
    Inventors: Seiji Miyoshi, Akihide Takami, Hiroshi Yamada, Masaaki Akamine, Hideharu Iwakuni, Koichiro Harada
  • Publication number: 20080262281
    Abstract: A catalyst for the oxidation of hydrogen in a process for the dehydrogenation of hydrocarbons, wherein the catalyst comprises, supported on ?-aluminum oxide, from 0.01 to 0.1% by weight of platinum and from 0.01 to 0.1% by weight of tin, based on the total weight of the catalyst, a process for the oxidation of hydrogen and a process for the dehydrogenation of hydrocarbons with an integrated oxidation process using the catalyst described.
    Type: Application
    Filed: March 22, 2005
    Publication date: October 23, 2008
    Applicant: BASF Aktiengesellschaft
    Inventors: Christian Walsdorff, Falk Simon, Gerald Vorberg, Gotz-Peter Schindler, Michael Hesse
  • Publication number: 20080234125
    Abstract: A catalyst and a method for selective hydrogenation of acetylene and dienes in light olefin feedstreams are provided. The catalyst retains higher activity and selectivity after regeneration than conventional selective hydrogenation catalysts. The catalyst contains a first component and a second component supported on an inorganic support. The inorganic support contains at least one salt or oxide of zirconium, a lanthanide, or an alkaline earth.
    Type: Application
    Filed: June 2, 2008
    Publication date: September 25, 2008
    Inventors: Yongqing Zhang, Stephen J. Golden
  • Patent number: 7425647
    Abstract: A process for preparing a catalyst by (a) selecting a carrier which is a silica based carrier which has been subjected to a series of washings with one or more aqueous liquids consisting of aqueous liquids which have a pH of least 3, when measured at 20° C., or which is a silica based carrier which is formed from materials one or more of which have been subjected to this series of washings, (b) precipitating a Group 8 metal compound onto the carrier, (c) converting the precipitated Group 8 metal compound into metallic species, and (d) subjecting the Group 8 metal/carrier composition to a purification treatment, before or after step (c); a catalyst which is obtainable by this process; and a process for preparing an alkenyl carboxylate by reacting a mixture comprising an olefin, a carboxylic acid and oxygen in the presence of the catalyst.
    Type: Grant
    Filed: March 28, 2002
    Date of Patent: September 16, 2008
    Assignee: Shell Oil Company
    Inventors: Michael Francis Lemanski, John Robert Lockemeyer
  • Publication number: 20080219918
    Abstract: A catalyst for fuel reforming including a metal catalyst that includes at least one active component A selected from the group consisting of Pt, Pd, Ir, Rh and Ru; and an active component B that is at least one metal selected from the group consisting of Mo, V, W, Cr, Re, Co, Ce and Fe, oxides thereof, alloys thereof, or mixtures thereof, and a carrier impregnated with the metal catalyst, and a method of producing hydrogen by performing a fuel reforming reaction using the catalyst for fuel reforming. The catalyst for fuel reforming has excellent catalytic activity at a low temperature and improved hydrogen purity. Therefore, when the catalyst for fuel reforming is used, high-purity hydrogen, which can be used as a fuel of a fuel cell, can be produced with high purity.
    Type: Application
    Filed: September 14, 2007
    Publication date: September 11, 2008
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Doo-hwan Lee, Yulia Potapova, Soon-ho Kim, Hyun-chul Lee, Kang-hee Lee
  • Publication number: 20080207437
    Abstract: A description is given of a catalyst comprising at least one porous support, at least some platinum, and at least a second group VIII metal which is different from platinum and iridium, said catalyst having been prepared in accordance with a process comprising a) impregnation of the support with at least one solution containing a platinum precursor, b) activation in a neutral or oxidising atmosphere, at a temperature of between 120 and 800° C., c) activation in a reducing medium, at a temperature of between 0 and 800° C., d1) impregnation with an aqueous solution and d2) treatment with at least one hydrogen donor compound, at a temperature of less than 200° C., e) the impregnation of the support, which has already been impregnated with the platinum, with at least one solution containing a precursor of said second group VIII metal, and f) activation in a neutral, reducing, or oxidising atmosphere, at a temperature of between 100 and 800° C.
    Type: Application
    Filed: November 6, 2007
    Publication date: August 28, 2008
    Inventors: Gil Mabilon, Patrice Marecot, Denis Uzio, Catherine Especel, Florence Epron
  • Publication number: 20080193370
    Abstract: Materials that are useful for absorption enhanced reforming (AER) of a fuel, including absorbent materials and catalyst materials and methods for using the materials. The materials can be fabricated by spray processing. The use of the materials in AER can produce a H2 product gas having a high H2 content and a low level of carbon oxides.
    Type: Application
    Filed: August 31, 2007
    Publication date: August 14, 2008
    Applicant: CABOT CORPORATION
    Inventors: Mark J. Hampden-Smith, Paolina Atanassova, Jian-Ping Shen, James Brewster, Paul Napolitano
  • Patent number: 7410626
    Abstract: The invention pertains to a layered ammonia oxidation catalyst. The layered catalyst causes ammonia to be selectively oxidized in the presence of an oxidant such as air, while minimizing the formation of nitrogen oxides (NOx). The layered catalyst comprises a refractory oxide support such as gamma alumina upon which a platinum component is deposited and a vanadia component is deposited on the platinum. The catalyst is preferably disposed on a substrate such as a metal foil whose surface contains a “herringbone” pattern.
    Type: Grant
    Filed: September 10, 2003
    Date of Patent: August 12, 2008
    Assignee: BASF Catalysts LLC
    Inventors: Pascaline Harrison Tran, James Mon-Her Chen, Gerard Diomede Lapadula, Marc Thomas Blute
  • Patent number: 7402612
    Abstract: This invention relates to methods for making a stabilized transition alumina of enhanced hydrothermal stability, which include the introduction of at least one structural stabilizer; a steaming step before or after the introduction step, wherein steaming is effective in transforming a transition alumina at least partially to boehmite and/or pseudoboehmite; and a calcining step to create a stabilized transition alumina. The combination of the structural stabilizer and the steaming step is believed to impart high hydrothermal stability to the alumina crystal lattice. Particularly preferred structural stabilizers include boron, cobalt, and zirconium. The stabilized transition alumina is useful as a catalyst support for high water partial pressure environments, and is particularly useful for making a catalyst having improved hydrothermal stability. The invention more specifically discloses Fischer-Tropsch catalysts and processes for the production of hydrocarbons from synthesis gas.
    Type: Grant
    Filed: October 16, 2003
    Date of Patent: July 22, 2008
    Assignee: ConocoPhillips Company
    Inventors: Yaming Jin, Rafael L. Espinoza, Nithya Srinivasan, Olga P. Ionkina
  • Patent number: 7393809
    Abstract: This invention provides a new catalyst for purification of diesel engine exhaust gas comprising a carrier of at least one sulfur-resistant refractory oxide and at least one catalytic metal, wherein at least one solid acid and/or sulfuric acid is carried on the carrier by adding at least one precursor of said solid acid and/or sulfuric acid during the preparation of the carrier, and preparation thereof. The catalyst of this invention is thermally and chemically durable and can effectively remove particulate matters, hydrocarbons and nitrogen oxides contained in the diesel engine exhaust gas at low temperatures.
    Type: Grant
    Filed: September 7, 2004
    Date of Patent: July 1, 2008
    Assignee: KH Chemicals Co., Ltd.
    Inventor: Young-Nam Kim
  • Patent number: 7390770
    Abstract: A catalyst for purifying an exhaust gas containing carbon monoxide and volatile organic compounds, which has a coat layer of a carrier composed of a porous inorganic compound, wherein the coat layer is a single layer, the porous inorganic compound has a BET specific surface area of 50 m2/g or greater, and the coat layer has, within a 50 ?m depth from the surface thereof, an active metal having a particle size of 15 nm or less and composed of at least one noble metal.
    Type: Grant
    Filed: April 14, 2006
    Date of Patent: June 24, 2008
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Katsumi Nochi, Masanao Yonemura, Yoshiaki Obayashi, Toshiyuki Onishi
  • Publication number: 20080141660
    Abstract: The present invention relates to a novel catalyst composition for use in a nitrogen oxide removal unit (DeNOx), a diesel particulate filter (DPF) and a diesel oxidation catalyst (DOC) unit, as well as a diesel exhaust after-treatment system comprising the same. In the diesel exhaust after-treatment system, the catalyzed ceramic filter ha s a low balance point temperature, and thus it can be operated even at low temperatures without an increase in back pressure. At a lower temperature, it can be continuously regenerated by the injection of heated light oil without applying excessive load to engines. Also, it can efficiently remove carbon monoxide and hydrocarbon with a high efficiency at low temperatures.
    Type: Application
    Filed: January 26, 2006
    Publication date: June 19, 2008
    Applicant: END SOLUTIONS INC.
    Inventors: Min-Yong Kim, Hae-Soo Lee, Jae-Hoon Chung
  • Patent number: 7384889
    Abstract: An exhaust gas purifying catalyst of the present invention contains alumina, and ceria loading palladium and platinum, and the ratio of palladium (IV) oxide to palladium (II) oxide by peak separation of the 3d orbital of palladium in X-ray photoelectron spectroscopy is within a range from 70:30 to 99:1. Thereby, the catalyst is capable of reducing the CO concentration and increasing the H2 concentration in an exhaust gas even after durability at high temperature.
    Type: Grant
    Filed: June 8, 2004
    Date of Patent: June 10, 2008
    Assignee: Nissan Motor Co., Ltd.
    Inventor: Junji Ito
  • Patent number: 7381683
    Abstract: Supported catalysts are produced with nanometer sized particles comprised of different metals dispersed throughout the catalyst support material. The supported catalysts reduce substantially or completely the amount of platinum that is required without sacrificing catalytic performance. In place of platinum, the supported catalysts employ palladium, silver, or copper, all of which costs significantly less than platinum.
    Type: Grant
    Filed: October 28, 2005
    Date of Patent: June 3, 2008
    Assignee: NanoStellar, Inc.
    Inventors: Jian Wang, Xianghong Hao, Jifei Jia, Jonathan W. Woo
  • Patent number: 7381682
    Abstract: A method for producing highly dispersed catalysts is disclosed. The method includes contacting a support material with a solvent for a period of time, adding a metal salt to the solvent and support mixture, and then adding a reducing agent to the solution to reduce the metal salt to nanometer sized metal particles on the surface of the support. Excess solvent is used in the process, the volume of solvent being greater than two times the pore volume of the support.
    Type: Grant
    Filed: October 28, 2005
    Date of Patent: June 3, 2008
    Assignee: NanoStellar, Inc.
    Inventors: Jifei Jia, Jonathan W. Woo, Jian Wang, Xianghong Hao
  • Patent number: 7378370
    Abstract: A promoted calcium-alumina supported reforming catalyst that is particularly useful for reforming reactions where low H2/CO ratio synthesis gas, such as less than 2.3 is generated directly is disclosed. The catalyst comprises from about 25 wt % to about 98 wt % alumina, from about 0.5 wt % to about 35 wt % calcium oxide, from about 0.01 wt % to about 35 wt % of a promoter, and from about 0.05 wt % to about 30 wt % of an active metal. The promoter is selected from the group consisting of titanium, zirconium, yttrium, niobium, elements of the lanthanum-series, such as, without limitation, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, ytterbium, and combinations thereof. The active metal is selected from the group consisting of nickel, cobalt, rhodium, ruthenium, palladium, platinum, iridium and combinations thereof as active metal, wherein the calcium oxide is combined with the alumina to form aluminum-rich calcium aluminates.
    Type: Grant
    Filed: October 13, 2004
    Date of Patent: May 27, 2008
    Assignee: Süd-Chemie Inc
    Inventors: Yeping Cai, William M. Faris, Jeffery E. Riley, Robert E. Riley, David P. Tolle, Jon P. Wagner, Shizhong Zhao
  • Patent number: 7375053
    Abstract: Novel nickel and/or cobalt plated sponge based catalysts are disclosed. The catalyst have an activity and/or selectivity comparable to conventional nickel and/or cobalt sponge catalysts, e.g., Raney® nickel or Raney® cobalt catalysts, but require a reduced content of nickel and/or cobalt. Catalysts in accordance with the invention comprise nickel and/or cobalt coated on at least a portion of the surface of a sponge support. Preferably, the sponge support comprises at least one metal other than or different from the metal(s) contained in the coating. The method of preparing the plated catalysts, and the method of using the catalysts in the preparation of organic compounds are also disclosed.
    Type: Grant
    Filed: April 7, 2003
    Date of Patent: May 20, 2008
    Assignee: W. R. Grace & Co.- Conn.
    Inventor: Stephen Raymond Schmidt
  • Patent number: 7374729
    Abstract: Provided are an exhaust treatment catalyst and an exhaust article containing the catalyst. The catalyst comprises: (a) a carrier; (b) a first layer deposited on the carrier, said first layer comprising substantially only at least one refractive metal oxide; (c) a second layer deposited on the first layer, said second layer comprising substantially only at least one oxygen storage component and at least one binder therefor; and (d) a third layer deposited on the second layer, said third layer comprising at least one layer of one or more platinum group metal components supported on a refractory metal oxide support. Optionally, a fourth layer is deposited on the third layer wherein the fourth layer comprises one or more platinum group metal components supported on a refractory metal oxide support. As a further option, an overcoat layer may be deposited on the third or fourth layer wherein the overcoat layer comprises a catalyst poison sorbent.
    Type: Grant
    Filed: March 30, 2004
    Date of Patent: May 20, 2008
    Assignee: BASF Catalysts LLC
    Inventors: Shau-Lin Franklin Chen, Zhicheng Hu
  • Patent number: 7371358
    Abstract: The present invention utilizes two precious metals with two to five different metal-oxides in a layered matrix to convert CO, HCs, and NOx to CO2, and N2 by oxidation of two components and reduction of the other in a moderately high temperature gaseous environment containing excess oxygen.
    Type: Grant
    Filed: October 25, 2004
    Date of Patent: May 13, 2008
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Wilhelmina H. Upchurch, legal representative, David R. Schryer, Billy T. Upchurch
  • Patent number: 7361625
    Abstract: A carrier supporting titania thereon is further caused to carry a metal compound thereon. This metal compound is hydrogen reduced in a heating atmosphere at a first treatment temperature, then oxidized in a heating atmosphere at a second treatment temperature not higher than the first treatment temperature to thereby obtain a photocatalyst. In this event, metal is released from an extremely strong reduction state and thus highly dispersed on the catalyst in the form of fine particles so that high activity of the catalyst can be obtained. Then, by purifying gas while feeding light and heat to the photocatalyst by, for example, blacklights, a volatile organic compound such as acetaldehyde can be decomposed at a high decomposition rate through cooperation between photocatalytic activity and thermal catalytic activity of the photocatalyst.
    Type: Grant
    Filed: February 23, 2004
    Date of Patent: April 22, 2008
    Assignee: Sundecor Co., Ltd
    Inventors: Katsuyuki Nakano, Eiko Higashi, Masanori Nanri
  • Patent number: 7351382
    Abstract: The present invention is directed to a particle filter to remove soot from the exhaust gas of a diesel engine. The particle filter contains a catalytically active coating on a filter body to accelerate bum-off during a regeneration phase of the soot particles collected on the filter. The particle filter comprises a catalytic coating containing compounds of barium, compounds of magnesium, and at least one element of the platinum group metals. The invention is further directed to a process for accelerated combustion of soot particles collected on the filter from lean exhaust gas of a diesel engine in which the soot particles have a soot ignition temperature and the particle filter is actively regenerated from time to time by raising the temperature of the particle filter above the soot ignition temperature and burning off the soot particles.
    Type: Grant
    Filed: March 26, 2003
    Date of Patent: April 1, 2008
    Assignee: Umicore AG & Co. KG
    Inventors: Marcus Pfeifer, Barry van Stetten, Christian Kühn, Roger Staab, Lutz Marc Ruwisch, Peter Kattwinkel, Jürgen Geishoff, Egbert Lox, Thomas Kreuzer
  • Patent number: 7351679
    Abstract: Embodiments include a catalyst for use in a Fischer-Tropsch synthesis reaction which comprises cobalt supported on alumina. In some embodiments, the alumina support may have specific surface area of less than 50 m2/g and/or may be least 10% ?-alumina.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: April 1, 2008
    Assignee: Statoil ASA
    Inventors: Sigrid Eri, Keijo J. Kinnari, Dag Schanke, Anne-Mette Hilmen
  • Patent number: 7345007
    Abstract: A catalyst for selectively oxidizing carbon monoxide in reformed gas by oxygen gas is disclosed. The catalyst for selective oxidation of carbon monoxide comprises ruthenium and/or platinum carried by a porous carrier, this porous carrier contains ?-alumna, and purity of this alumna is not less than 99.95%. A particle diameter of the ruthenium and/or platinum is not larger than 200 ?. According to this catalyst for selective oxidation of carbon monoxide, it is possible to provide the catalyst, which reduces the carbon monoxide in the reformed gas by oxidizing it selectively, and possible to realize excellent efficiency of fuel utilization and favorable generation efficiency.
    Type: Grant
    Filed: June 24, 2002
    Date of Patent: March 18, 2008
    Assignee: Tanaka Kikinzoku Kogyo K.K.
    Inventor: Masaru Kagawa
  • Patent number: 7345214
    Abstract: A catalyst for opening naphthenic rings has been developed. The catalyst comprises ruthenium and platinum as the active catalytic metals and a modifier with cerium being a preferred modifier. At least 50% of the platinum and ruthenium components are present as particles wherein more ruthenium is present on the surface of the particles than in the center. All of these components are dispersed on a metal oxide support such as aluminas. A ring opening process using the catalyst is also described.
    Type: Grant
    Filed: October 3, 2005
    Date of Patent: March 18, 2008
    Assignee: UOP LLC
    Inventors: Feng Xu, Lorenz J. Bauer, Ralph D. Gillespie, Maureen L. Bricker, Steven A. Bradley
  • Publication number: 20080064770
    Abstract: A catalyst for use in a Fischer-Tropsch synthesis reaction which comprises cobalt supported on alumina, in which: the catalyst average particle size is in the range 20 to 100 ?m; the specific surface area of the impregnated and calcined catalyst particles is greater than 80 m2/g; the average pore size of the impregnated and calcined catalyst is at least 90 ? (9 nm); and the pore volume of the impregnated and calcined catalyst is greater than 0.35 cm3g.
    Type: Application
    Filed: November 10, 2003
    Publication date: March 13, 2008
    Inventors: Erling Rytter, Sigrid Eri, Dag Schanke
  • Patent number: 7341975
    Abstract: The present invention relates to an exhaust gas purification catalytic material containing: (a) a mixed oxide containing Ce and Zr for storing and releasing oxygen; and (b) a precious metal catalyst made of one or more kinds of precious metals. The precious metal catalyst comprises a first precious metal catalyst component placed between atoms, at crystal lattice points and/or at oxygen defect sites of the mixed oxide and a second precious metal catalyst component loaded on the surface of the mixed oxide, thereby improving the thermal resistance, oxygen storage capacity and exhaust gas conversion performance of the catalytic material.
    Type: Grant
    Filed: November 10, 2004
    Date of Patent: March 11, 2008
    Assignee: Mazda Motor Corporation
    Inventors: Hideharu Iwakuni, Masaaki Akamine, Seiji Miyoshi, Hiroshi Yamada, Akihide Takami, Yuki Murakami
  • Publication number: 20080045404
    Abstract: Disclosed herein is a three-way conversion (TWC) catalyst containing little or no rhodium for purifying exhaust gases of an internal combustion engine, having a multi-layers structure, including a lower layer including an alumina support and an oxygen storage material; an intermediate layer including alumina support impregnated only with palladium and a zirconia-rich oxygen storage material; and an upper layer including alumina support impregnated with platinum, minimum rhodium and platinum, or platinum-palladium and a ceria-rich oxygen storage material.
    Type: Application
    Filed: August 15, 2007
    Publication date: February 21, 2008
    Applicant: HEESUNG CATALYST CORPORATION
    Inventors: Hyun-Sik Han, Jin-Woo Song, Jae-Au Ha, Kwi-Yeon Lee
  • Patent number: 7326669
    Abstract: A bi-laterally surfaced substrate in which the first surface consists of one or more than one of cerium oxide, aluminum oxide, tin oxide manganese oxide, copper oxide, cobalt oxide, nickel oxide, praseodymium oxide, terbium oxide, ruthenium, rhodium, palladium, silver, iridium, platinum and gold and the second surface consists of one or more than one of ruthenium, rhodium, palladium, silver, iridium, platinum and gold and micro channel micro component reactors including such substrates in a predetermined formed shape and methods for making the same utilizing a thermal spray on one side and a physical deposition process on the other side.
    Type: Grant
    Filed: September 20, 2001
    Date of Patent: February 5, 2008
    Assignee: Honda Motor Co., Ltd.
    Inventors: Ting He, Eisuke Kimura, Tadashi Nomura
  • Patent number: 7323432
    Abstract: A catalyst assembly comprising a substrate, nanofilaments which have a nanometer-size diameter and are formed on the substrate, and particles which have a nanometer-size diameter, at least one of the nanofilaments and the particles having a catalytic function, is provided to use a catalyst more efficiently and to provide a catalytic function more efficiently. Interstices between the nanofilaments serve as distribution channels of a reactive gas, and the reactive gas spreads sufficiently not only around the ends of nanofilaments but also inside a catalyst assembly. A combination of nanofilaments and particles enables dispersion of a catalyst at a distance of not more than about 100 nanometers.
    Type: Grant
    Filed: August 21, 2003
    Date of Patent: January 29, 2008
    Assignees: DENSO Corporation, Koichi Niihara, Tadachika Nakayama
    Inventors: Koichi Niihara, Tadachika Nakayama, Jun Hasegawa, Miho Ito
  • Patent number: 7316806
    Abstract: A reforming catalyst for partial oxidation to reform hydrocarbon compound including a sulfur-containing compound includes platinum and rhodium. Even in reforming a hydrocarbon compound including a sulfur-containing compound such as, for example, a town gas, the catalyst effectively prevents poisoning and elongates catalyst life.
    Type: Grant
    Filed: October 22, 2004
    Date of Patent: January 8, 2008
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Masaaki Okuno, Akiyoshi Nakajima
  • Publication number: 20080003155
    Abstract: An engine exhaust catalyst containing precious metal nanoparticles is promoted with bismuth. The bismuth promotion improves the catalyst's CO oxidation performance. Also, by varying the amount of bismuth that is added, the NO conversion rate that can be realized with the catalyst can be controlled. The control over the NO conversion rate is important because the passive regenerative performance of a particulate filter used in engine exhaust systems is based on the amount NO2 that is present in the exhaust stream that reaches the particulate filter. The amount of NO2 being produced needs to be optimized (not necessarily maximized) so that adequate particulate filter regeneration performance can be maintained while avoiding unused, toxic NO2 from being exhausted into the atmosphere.
    Type: Application
    Filed: January 9, 2007
    Publication date: January 3, 2008
    Inventors: Jifei Jia, Kyle L. Fujdala, Timothy J. Truex
  • Patent number: 7307039
    Abstract: In an exhaust gas purification catalyst comprising a honeycomb support and a catalytic layer that is formed on wall surfaces of each cell of the honeycomb support and contains active alumina and a mixed oxide containing Ce, Zr and Nd and doped with catalytic precious metal, the mixed oxide has a CeO2/ZrO2 mass ratio of 1.4 or more and the ratio of Nd2O3/(CeO2+ZrO2+Nd2O3) in the mixed oxide is 20 mass % or less.
    Type: Grant
    Filed: August 10, 2005
    Date of Patent: December 11, 2007
    Assignee: Mazda Motor Corporation
    Inventors: Hideharu Iwakuni, Asako Sadai, Masaaki Akamine, Seiji Miyoshi, Hiroshi Yamada, Akihide Takami
  • Patent number: 7297654
    Abstract: An exhaust gas-purifying catalyst includes a carrier, and an active component formed of a noble metal, carried by the carrier. The carrier has a core portion comprising a cubic or tetragonal stabilized zirconia-based composite oxide containing at least one stabilizing element, and a surface layer portion including a heat resistant zirconia-based composite oxide formed on a surface of the core portion. The surface layer has a specific surface area which is larger than a specific surface area of the core portion. A part of the noble metal is solid-solutioned into the zirconia-based composite oxide of the surface layer portion, and the balance of the noble metal is carried on a surface of the surface layer portion.
    Type: Grant
    Filed: September 7, 2006
    Date of Patent: November 20, 2007
    Assignees: Cataler Corporation, Daihatsu Motor Co., Ltd.
    Inventors: Mareo Kimura, Naoto Miyoshi, Hirohisa Tanaka, Isao Tan
  • Patent number: 7270738
    Abstract: This invention relates to silico-aluminum substrates, catalysts, and the hydrocracking and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by elements of group VIB and group VIII of the periodic table and a non-zeolitic silica-alumina-based substrate that contains an amount of more than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and has the following characteristics: A mean pore diameter, measured by mercury porosimetry, encompassed between 20 and 140 ?, a total pore volume, measured by mercury porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a total pore volume, measured by nitrogen porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a BET specific surface area encompassed between 100 and 550 m2/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 140 ?, of less than 0.
    Type: Grant
    Filed: October 30, 2003
    Date of Patent: September 18, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Patrick Euzen, Carole Bobin, Magalie Roy-Auberger, Eric Benazzi, Patrick Bourges, Christophe Gueret
  • Patent number: 7271126
    Abstract: A method for producing a catalyst for use in the dehydrogenation of ethylbenzene to styrene is disclosed. The catalyst of the present invention comprises a high purity metal and at least one promoter in the form of solid oxides, oxide hydrates, hydroxides, hydroxycarbonates or metals. The catalyst is prepared via a method which comprises the preparation of at least one high purity iron precursor with or without an additional support material and which uses a nominal amount of water in the catalyst production. The catalyst pellets prepared with the high purity metal precursor are essentially free of sulfur and chloride contaminants.
    Type: Grant
    Filed: June 24, 2004
    Date of Patent: September 18, 2007
    Assignee: Sud-Chemie Inc.
    Inventors: Dennis J. Smith, Robert J. O'Brien, X. D. Hu
  • Patent number: 7271127
    Abstract: Disclosed is a catalyst for a partial oxidation reforming reaction of fuel in the form of disk having through-hole. In addition, according to the invention, there is provided a fuel reforming apparatus and method using the catalyst. The catalyst for a partial oxidation reforming reaction of fuel according to the invention makes it possible to progress the partial oxidation reforming reaction of fuel smoothly, to improve the efficiency when reforming the fuel and to simplify the fuel reforming reactor. According to the fuel reforming apparatus and method, since the heat of reaction is efficiently controlled and used, a simple on-off operation, reduction of starting time and a stable operational condition are accomplished, which are indispensably required for a fuel reforming system in fuel cells, such as household, portable and car fuel cells.
    Type: Grant
    Filed: December 13, 2004
    Date of Patent: September 18, 2007
    Assignee: Korea Institute of Science and Technology
    Inventors: Suk-Woo Nam, Sang Jun Kong, Seong-Ahn Hong, In-Hwan Oh, Tae-Hoon Lim, Heung Yong Ha, Sung Pil Yoon, Jonghee Han, EunAe Cho
  • Patent number: 7268097
    Abstract: A desulfurizing agent comprising a silica-alumina carrier having an Si/Al mole ratio of 10 or less and nickel carried thereon; a desulfurizing agent for hydrocarbons derived from petroleum which comprises a carrier and a metal component carried thereon and has a specific surface area of pores having a pore diameter of 3 nm or less of 100 m2/g or more; an Ni-Cu based desulfurizing agent comprising a carrier and, carried thereon, (A) nickel, (B) copper, and (C) an alkali metal or another metal; a desulfurizing agent for hydrocarbons derived from petroleum which comprises a carrier and a metal component carried thereon and has a hydrogen adsorption capacity of 0.4 mmol/g or more; and methods for producing these nickel-based and nickel-copper-based desulfurizing agents. The above desulfurizing agents are capable of adsorbing and removing with good efficiency the sulfur contained in hydrocarbons derived from petroleum to a content of 0.2 wt. ppm or less and have a long service life.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: September 11, 2007
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Hisashi Katsuno, Satoshi Matsuda, Kazuhito Saito, Masahiro Yoshinaka
  • Patent number: 7253137
    Abstract: A catalyst for preferentially reducing carbon monoxide in a hydrogen stream. The catalyst is formed from a chemical composition including a hexaaluminate, a metal hydroxide and a precious metal. The composition may be disposed on a support or may be extruded or cast into or onto a support. Incorporation of hexaaluminates allows inclusion of metal hydroxides that flux the active precious metal surface at higher temperatures than can aluminum oxide-based catalytic compositions, thereby enhancing resistance of the catalyst and monolithic support and increasing the durability and thermal range of the PROX catalyst. An additional advantage is that lesser amounts of precious metal oxides need be deposited onto the hexaaluminate, while retaining activity similar to aluminum oxide compositions.
    Type: Grant
    Filed: July 14, 2006
    Date of Patent: August 7, 2007
    Assignee: Delphi Technologies, Inc.
    Inventors: William J. LaBarge, Robert J. Svoboda, Joseph M. Keller
  • Patent number: 7247599
    Abstract: Disclosed is a process for preparing a stable PROX reaction catalyst, comprising the steps of (a) preparing a catalyst platinum supported on alumina; (b) calcinating the catalyst from step (a) at 300˜600° C. for 2˜4 hours; (c) contacting the catalyst obtained from step (b) with hydrogen at 300° C.˜600° C. for 2˜4 hours to reduce the catalyst; and (d) dropping the temperature in the reduced catalyst from step (c) to less than 100° C. and then contacting the catalyst with a predetermined solvent and/or gas while elevating the temperature to 300° C.–600° C. The catalyst has Pt—Al arrangement, the content of Pt being 0.5˜7% by weight and has an overall shape of an oval.
    Type: Grant
    Filed: September 3, 2004
    Date of Patent: July 24, 2007
    Inventors: Moon Chan Kim, In Hyuk Son
  • Patent number: 7241717
    Abstract: It is an object of the present invention to provide a cathode catalyst for fuel cells containing platinum and iron which can maintain the durability of a battery and can make a battery high output. The cathode catalyst for fuel cells comprises a supporting layer which consists of an alloy containing platinum and iron and further containing the third component which has an affinity for iron including one or more sorts of elements selected from the group consisting of tungsten, titanium, molybdenum, rhenium, zinc, manganese, tin, tantalum and rhodium, and a support on which the supporting layer is loaded. A catalyst using an alloy containing platinum and iron enables the batteries to become high output. By alloying one or more sorts of elements of the third component which has an affinity for iron with an alloy containing platinum and iron, it is possible to prevent eluting of the iron into the electrolyte.
    Type: Grant
    Filed: October 19, 2004
    Date of Patent: July 10, 2007
    Assignees: Cataler Corporation, Toyota Jidosha Kabushiki Kaisha
    Inventors: Tetsuo Ito, Tomoaki Terada, Hisao Kato, Tetsuo Nagami
  • Patent number: 7238640
    Abstract: The present invention provides a catalyst for use in a NOx trap that has reduced NOx release during rich purges, increased NO conversion efficiency under stoichiometric conditions, and improved sulfur tolerance. The catalyst of this embodiment includes a precious metal, an oxygen storage component in contact with the precious metal, and a NOx storage material. The oxygen storage component in contact with the precious metal is present in an amount that provides sufficient oxygen storage capacity to reduce the NOx release from the NOx trap during rich purges to less than 20% of the NOx that is stored in the NOx trap across the operating temperature window of the NOx trap, increase the NOx conversion efficiency under stoichiometric conditions to a value greater than 70%, and increase the sulfur tolerance of the NOx trap.
    Type: Grant
    Filed: December 30, 2003
    Date of Patent: July 3, 2007
    Assignee: Ford Global Technologies, LLC
    Inventors: Hungwen Jen, Gopichandra Surnilla, Christian Goralski, Jr., Joseph Theis, Justin Ura
  • Patent number: 7235511
    Abstract: An exhaust gas purifying catalyst includes a carrier and a catalyst layer provided on the carrier. The catalyst layer includes active Al2O3 on which a noble metal is carried, an oxygen storage agent on which Rh is carried, Al2O3 coated with ZrO2 on which Rh is carried, and a binder material.
    Type: Grant
    Filed: September 3, 2004
    Date of Patent: June 26, 2007
    Assignees: Tokyo Roki Co., Ltd., Mazda Motor Corporation
    Inventors: Tomohiko Kawamoto, Katsuyuki Fujita, Tadashi Tokuyama, Masahiko Shigetsu, Masaaki Akamine, Hisaya Kawabata, Hideharu Iwakuni, Akihide Takami
  • Patent number: 7229948
    Abstract: The present invention involves an exhaust gas catalyst and method of manufacturing same. The invention provides for a cost-effective material which lowers the cold-start emissions from the exhaust of vehicles. The invention is a passive system which accelerates the light-off temperature of catalyst in a cost-effective fashion. The invention includes a method of manufacturing an exhaust gas catalyst capable of lowering cold-start emissions including the steps of providing an oxide mixture having praseodymium and cerium, doping about 0–10% weight zirconium and about 0–10% weight yttrium to the oxide mixture, adding about 0–2% weight metal including palladium, platinum, or rhodium to the oxide mixture, mixing gamma aluminum to the oxide mixture for washcoating and washcoating the oxide mixture onto a monolithic substrate.
    Type: Grant
    Filed: January 24, 2005
    Date of Patent: June 12, 2007
    Assignee: Ford Global Technologies, LLC
    Inventors: Albert Nazipovich Chigapov, George Wade Graham, Haren Sakaral Gandhi, Hung-Wen Jen
  • Patent number: 7229947
    Abstract: An NOx sorption-and-reduction type catalyst is made which includes a hydrogen generating catalyst in which Rh is loaded on a support including an Al2O3—ZrO2 composite oxide. Since the Al2O3—ZrO2 composite oxide exhibits a basicity lower than ZrO2, SOx are less likely to approach so that it is possible to suppress the sulfur poisoning of Rh. Moreover, the Al2O3—ZrO2 composite oxide exhibits higher heat resistance than ZrO2, and it has a function of improving the steam reforming reaction activity of Rh in the same manner as ZrO2. Therefore, the post-durability NOx purifying ability of the NOx sorption-and-reduction type catalyst is improved.
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: June 12, 2007
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Naoyuki Hara, Ichiro Hachisuka
  • Patent number: 7220702
    Abstract: A noble metal and an NOx sorption member are loaded on a support which includes composite particles having a structure including a core portion in which ZrO2 is a major component and a superficial portion formed on a surface of the core portion and including an oxide, whose basicity is lower than ZrO2, more than the core portion. The composite particles exhibit a high basicity at the inside and a low basicity on the surface by Al2O3 or TiO2 which exists more in the surface. Accordingly, the sulfur-poisoning resistance is improved, and, at the same time, the post-durability NOx purifying ability is improved.
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: May 22, 2007
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Naoyuki Hara, Ichiro Hachisuka
  • Patent number: 7220699
    Abstract: A method and device for loading a catalyst into a chamber. The catalyst loading is well suited for production of hydrogen producing microreactors. The catalyst is coated onto a strip which is mountable within the chamber.
    Type: Grant
    Filed: March 31, 2003
    Date of Patent: May 22, 2007
    Assignee: Intelligent Energy, Inc.
    Inventor: Anand Chellappa
  • Patent number: 7205257
    Abstract: To provide an exhaust gas purifying catalyst which can maintain the catalytic activity at a high level over a long time and can achieve satisfactory emission control performance, an exhaust gas purifying catalyst is prepared so as to contain a noble metal, a perovskite-type composite oxide represented by the following general formula (3), and theta-alumina and/or alpha-alumina: AB1-mNmO3??(3) wherein A represents at least one element selected from rare-earth elements and alkaline earth metals; B represents at least one element selected from Al and transition elements excluding rare-earth elements and noble metals; N represents a noble metal; and m represents an atomic ratio of N satisfying the following relation: 0<m<0.5.
    Type: Grant
    Filed: July 3, 2003
    Date of Patent: April 17, 2007
    Assignees: Daihatsu Motor Co., Ltd., Cataler Corporation
    Inventors: Hirohisa Tanaka, Isao Tan, Mari Uenishi, Nobuhiko Kajita, Masashi Taniguchi, Yasunori Sato, Keiichi Narita, Noboru Sato
  • Patent number: 7186668
    Abstract: A textured catalyst having a hydrothermally-stable support, a metal oxide and a catalyst component is described. Methods of conducting aqueous phase reactions that are catalyzed by a textured catalyst are also described. The invention also provides methods of making textured catalysts and methods of making chemical products using a textured catalyst.
    Type: Grant
    Filed: September 25, 2003
    Date of Patent: March 6, 2007
    Assignee: Battele Memorial Institute
    Inventors: Todd Werpy, John G. Frye, Jr., Yong Wang, Alan H. Zacher
  • Patent number: 7176159
    Abstract: A catalyst and sorbent is disclosed which comprises pellets with an absorbent core and a protective shell with a catalyst in the shell. Such material is especially well suited for steam reforming of hydrocarbons to produce hydrogen since a reforming catalyst can be incorporated in the shell and a sorbent for the by-product carbon dioxide can be used for the core. It is also well suited for producing hydrogen from carbon monoxide by means of the water gas shift reaction. The shell can be made sufficiently strong and durable for moving bed applications as well as fixed bed applications.
    Type: Grant
    Filed: August 14, 2002
    Date of Patent: February 13, 2007
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Thomas D. Wheelock, Brent H. Shanks
  • Patent number: 7169735
    Abstract: The object of the present invention is to provide a catalyst that is highly active and capable of maintaining its activity for a long period of time even in a high-temperature environment. The present invention is a catalyst including: a porous carrier which is comprised of one kind of or two or more kinds of metal oxides; and catalyst particles which are comprised of precious metals or precious metal oxides and supported on the above porous carrier, characterized in that the catalyst particles include: clustered particles formed by the aggregation of first precious metal atoms; and second precious metal ions bound to the above clustered particles. Preferably, the first precious metal and the second precious metal are different metal species which are selected from the group consisting of platinum, palladium, rhodium, ruthenium, silver, gold, iridium and osmium.
    Type: Grant
    Filed: May 3, 2005
    Date of Patent: January 30, 2007
    Assignee: Tanaka Kikinzoku Kogyo K.K.
    Inventor: Takeyuki Sagae