Of Silver Patents (Class 502/347)
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Patent number: 7488462Abstract: Catalyst systems and methods provide benefits in reducing the content of nitrogen oxides in a gaseous stream containing nitric oxide (NO), hydrocarbons, carbon monoxide (CO), and oxygen (O2). The catalyst system comprises an oxidation catalyst comprising a first metal supported on a first inorganic oxide for catalyzing the oxidation of NO to nitrogen dioxide (NO2), and a reduction catalyst comprising a second metal supported on a second inorganic oxide for catalyzing the reduction of NO2 to nitrogen (N2).Type: GrantFiled: April 26, 2006Date of Patent: February 10, 2009Assignee: The Ohio State UniversityInventors: Umit S. Ozkan, Erik M. Holmgreen, Matthew M. Yung
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Patent number: 7485597Abstract: A method for improving the selectivity of a supported highly selective epoxidation catalyst comprising silver in a quantity of at most 0.17 g per m2 surface area of the support, which method comprises contacting the catalyst, or a precursor of the catalyst comprising the silver in cationic form, with a feed comprising oxygen at a catalyst temperature above 250° C. for a duration of up to 150 hours, and subsequently decreasing the catalyst temperature to a value of at most 250° C.; and a process for the epoxidation of an olefin, which process comprises contacting a supported highly selective epoxidation catalyst comprising silver in a quantity of at most 0.17 g per m2 surface area of the support, or a precursor of the catalyst comprising the silver in cationic form, with a feed comprising oxygen at a catalyst temperature above 250° C. for a duration of up to 150 hours, and subsequently decreasing the catalyst temperature to a value of at most 250° C.Type: GrantFiled: June 26, 2003Date of Patent: February 3, 2009Assignee: Shell Oil CompanyInventors: John Robert Lockemeyer, Randall Clayton Yeates, Donald Reinalda
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Patent number: 7479565Abstract: A process is provided for the epoxidation of an olefin comprising the steps of: contacting a feed comprising an olefin and oxygen with a catalyst comprising a silver component deposited on a fluoride-mineralized carrier; and producing a product mix comprising an olefin oxide, wherein the partial pressure of olefin oxide in the product mix is greater than about 60 kPa. A process is provided for the epoxidation of an olefin comprising the steps of: contacting a feed comprising an olefin and oxygen with a catalyst comprising a silver component and a high-selectivity dopant deposited on a fluoride-mineralized carrier; and producing a product mix comprising an olefin oxide, wherein the partial pressure of olefin oxide in the product mix is greater than about 20 kPa.Type: GrantFiled: June 16, 2005Date of Patent: January 20, 2009Assignee: Shell Oil CompanyInventors: Randall Clayton Yeates, Leonid Isaakovich Rubinstein
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Publication number: 20090011925Abstract: A catalytically active glass-ceramic and method for producing a catalytically active multi-phase glass-ceramic in which at least one catalyst precursor is mixed with a glass-ceramic precursor formulation to form a catalyst precursor/glass-ceramic precursor mixture. The catalyst precursor/glass-ceramic precursor mixture is then melted to form an amorphous glass material which, in turn, is devitrified to form a polycrystalline ceramic. The polycrystalline ceramic is then activated, forming a catalytically active multi-phase glass-ceramic.Type: ApplicationFiled: July 6, 2007Publication date: January 8, 2009Inventors: Larry Gordon Felix, David Morrissey Rue, Thomas Philip Seward, III, Logan Edwin Weast
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Publication number: 20080318769Abstract: A catalyst (1) for use in exhaust emission control that improves catalytic activity and reduces the amount of noble metal used and method for making such a catalyst (1). The catalyst (1) includes a noble metal first constituent (2); a transition metal compound second constituent (3), part or all of which forms a complex with the noble metal; a third constituent element (4) that is in contact with the complex and has an electronegativity of 1.5 or less; and a porous carrier (5) that supports the noble metal, the transition metal compound and the third constituent element (4), and that is such that part or all of which forms a complex oxide with the third constituent element (4).Type: ApplicationFiled: August 4, 2005Publication date: December 25, 2008Inventors: Hironori Wakamatsu, Hirofumi Yasuda, Kazuyuki Shiratori, Masanori Nakamura, Toru Sekiba, Katsuo Suga
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Publication number: 20080307779Abstract: Provided are improved regenerable SOx trap formulations for on-board vehicle applications. The regenerable sulfur trap formulations reduce the rate of sulfur poisoning of a downstream nitrogen storage reduction (NSR) catalyst trap in exhaust gas cleaning systems for combustion engines by adsorbing SOx as metal sulfate under lean exhaust conditions and desorbing the accumulated SOx under rich exhaust conditions. The regenerable sulfur oxides trap catalyst compositions include a metal (M) oxide, wherein M is selected from Cu, Fe, Mn, Ag, Co and combinations thereof and a metal (M)-La—Zr oxide, wherein M is selected from Cu, Fe, Mn, Ag, Co and combinations thereof. In addition, provided are improved exhaust gas cleaning systems and methods for treating exhaust gas from a combustion source that include a hydrogen generation system, a regenerable sulfur oxides trap, and a regenerable nitrogen storage reduction (NSR) catalyst trap.Type: ApplicationFiled: April 10, 2008Publication date: December 18, 2008Inventors: El-Mekki El-Malki, Walter Weissman, Paul J. Polini
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Publication number: 20080312070Abstract: The invention relates to a method for forming a material of a metal oxide supported on a support particle by the steps of. a) providing a precursor mixture comprising a solution containing one or more metal cations and (i) a surfactant; or (ii) a hydrophilic polymer; with the precursor mixture further including support particles; and b) treating the precursor mixture from (a) above by heating to remove the surfactant or hydrophilic polymer and form metal oxide having nano-sized grains, wherein at least some of the metal oxide formed in step (b) is deposited on or supported by the support particles and the metal oxide has an oxide matrix that includes metal atoms derived solely from sources other than the support particles.Type: ApplicationFiled: May 5, 2006Publication date: December 18, 2008Inventors: Peter Cade Talbot, Geoffrey Alan Edwards, Jose Antonio Alarco
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Publication number: 20080305948Abstract: A method for producing a catalytically-active material having at least one base component and at least one catalytically-active component in which the at least one base component is heated to a softening or melting temperature to form a softened or molten base component. While the base component is in the softened or molten state, at least one catalytically-active component is incorporated into or onto the base component, forming the catalytically-active material. In accordance with one embodiment, a catalyst precursor is introduced into the base component and subsequently transformed to a catalytically-active component.Type: ApplicationFiled: August 13, 2008Publication date: December 11, 2008Applicant: GAS TECHNOLOGY INSTITUTEInventors: Larry Gordon Felix, David M. Rue, Rachid B. Slimane
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Publication number: 20080306289Abstract: A catalyst composition comprising a support having a surface area of at least 500 m2/kg, and deposited on the support: silver metal, a metal or component comprising rhenium, tungsten, molybdenum or a nitrate- or nitrite-forming compound, and a Group IA metal or component comprising a Group IA metal having an atomic number of at least 37, and in addition potassium, wherein the value of the expression (QK/R)+QHIA is in the range of from 1.5 to 30 mmole/kg, wherein QHIA and QK represent the quantities in mmole/kg of the Group IA metal having an atomic number of at least 37 and potassium, respectively, present in the catalyst composition, the ratio of QHIA to QK is at least 1:1, the value of QK is at least 0.01 mmole/kg, and R is a dimensionless number in the range of from 1.5 to 5, the units mmole/kg being relative to the weight of the catalyst composition.Type: ApplicationFiled: August 14, 2008Publication date: December 11, 2008Inventors: Marek MATUSZ, Michael Alan Richard, Martin Lysle Hess
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Patent number: 7462727Abstract: A multimetal oxide of the formula I, Aga-cQbMcV2Od*e H2O,??I where a is from 0.3 to 1.9, Q is an element selected from among P, As, Sb and/or Bi, is from 0 to 0.3, M is a metal selected from among Nb, Ce, W, Mn, Ta, Pd, Pt, Ru and/or Rh, c is from 0.001 to 0.5, with the proviso that (a-c)?0.1, d is a number which is determined by the valence and abundance of the elements other than oxygen in the formula I and e is from 0 to 20, and also precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are described.Type: GrantFiled: July 23, 2004Date of Patent: December 9, 2008Assignee: BASF AktiengesellschaftInventors: Samuel Neto, Hartmut Hibst, Frank Rosowski, Sebastian Storck
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Publication number: 20080286176Abstract: Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 ?m in at least two dimensions or having cross-sectional areas of at least 10 ?m2. The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.Type: ApplicationFiled: April 18, 2006Publication date: November 20, 2008Applicants: Uhde GmbH, Evonik Degussa GmbHInventors: Steffen Schirmeister, Karsten Bueker, Martin Schmitz-Niederau, Bernd Langanke, Andreas Geisselmann, Georg Markowz, Klaus Thomas Schwarz, Elias Johannes Klemm, Frank Becker, Reinhard Machnik
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Patent number: 7427581Abstract: Novel sorbent systems for the desulfurization of cracked-gasoline and diesel fuels are provided which are comprised of a bimetallic promotor on a particulate support such as that formed of zinc oxide and an inorganic or organic carrier. Such bimetallic promotors are formed of at least two metals of the group consisting of nickel, cobalt, iron, manganese, copper, zinc, molybdenum, tungsten, silver, tin, antimony and vanadium with the valence of same being reduced, preferably to zero. Processes for the production of such sorbents are provided wherein the sorbent is prepared from impregnated particulate supports or admixed to the support composite prior to particulation, drying, and calcination. Further disclosed is the use of such novel sorbents in the desulfurization of cracked-gasoline and diesel fuels whereby there is achieved not only removal of sulfur but also an increase in the olefin retention in the desulfurized product.Type: GrantFiled: January 21, 2003Date of Patent: September 23, 2008Assignee: China Petroleum & Chemical CorporationInventor: Gyanesh P. Khare
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Publication number: 20080206562Abstract: The disclosure relates to metal nanoparticle compositions and methods of making such nanoparticle compositions that are useful for the production of electrically conductive features and catalysts.Type: ApplicationFiled: January 12, 2008Publication date: August 28, 2008Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIAInventors: Galen D. Stucky, Nanfeng Zheng
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Publication number: 20080199762Abstract: A platinum alloy catalyst can be used as a fuel cell catalyst. The platinum alloy is a PtAuX alloy wherein X is one or more metals chosen from the group consisting of transition metals, and wherein the alloy contains 40-97% Pt, 1-40% Au and 2-20% X. Electrodes, catalysed membranes and membrane electrode assemblies comprising the catalyst are also disclosed.Type: ApplicationFiled: July 27, 2005Publication date: August 21, 2008Applicant: Johnson Matthey Public Limited CompanyInventors: Brian Elliott Hayden, Christopher Edward Lee, Claire Mormiche, David Thompsett
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Publication number: 20080187477Abstract: To provide a catalyst for treating exhaust gases containing nitrogen monoxide, carbon monoxide and volatile organic compounds whose oxidation power has been enhanced without increasing the amount of precious metal supported thereon; a method for producing the same; and a method for treating exhaust gases. A catalyst for treating exhaust gases, including coat layers made up of a plurality of layers, an upper layer of which has an active component contained uniformly therein and a lower layer of which has no active component contained therein, can be obtained through the steps of: forming the lower layer by coating the surface of substrate with a slurry of a porous inorganic compound, followed by drying; and forming the upper layer, which is to be the top surface of the catalyst, by coating the surface of the lower layer with a slurry of a porous inorganic compound that has the active component composed of one or more precious metals supported thereon, followed by drying.Type: ApplicationFiled: September 28, 2007Publication date: August 7, 2008Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Katsumi NOCHI, Masanao YONEMURA, Yoshiaki OBAYASHI, Hitoshi NAKAMURA
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Publication number: 20080176742Abstract: An object of the present invention is to provide a method for producing a catalyst for treating exhaust gas, enabling a smaller amount of a noble metal to be supported and reducing the production cost thereof. There is provided a method for producing a catalyst for treating an exhaust gas containing carbon monoxide and volatile organic compounds, wherein the method comprises: preparing, as a pH buffer solution, an aqueous metal salt solution in which at least one metal salt is dissolved; reductively-treating the aqueous metal salt solution while keeping the pH constant to prepare a metal colloid solution; and immersing a carrier in the metal colloid solution to support the metal on the carrier. The supported amount of metal may be 0.7 g/L or less per one of the metals.Type: ApplicationFiled: March 4, 2005Publication date: July 24, 2008Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Katsumi Nochi, Masanao Yonemura, Kozo Iida, Yoshiaki Obayashi, Shigeru Nojima, Toshiyuki Onishi
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Patent number: 7402612Abstract: This invention relates to methods for making a stabilized transition alumina of enhanced hydrothermal stability, which include the introduction of at least one structural stabilizer; a steaming step before or after the introduction step, wherein steaming is effective in transforming a transition alumina at least partially to boehmite and/or pseudoboehmite; and a calcining step to create a stabilized transition alumina. The combination of the structural stabilizer and the steaming step is believed to impart high hydrothermal stability to the alumina crystal lattice. Particularly preferred structural stabilizers include boron, cobalt, and zirconium. The stabilized transition alumina is useful as a catalyst support for high water partial pressure environments, and is particularly useful for making a catalyst having improved hydrothermal stability. The invention more specifically discloses Fischer-Tropsch catalysts and processes for the production of hydrocarbons from synthesis gas.Type: GrantFiled: October 16, 2003Date of Patent: July 22, 2008Assignee: ConocoPhillips CompanyInventors: Yaming Jin, Rafael L. Espinoza, Nithya Srinivasan, Olga P. Ionkina
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Publication number: 20080161182Abstract: Plasma modifications of catalyst supports before and after impregnation of metal precursors improve the activity, selectivity and stability of catalysts, e.g. Ni catalysts for benzene hydrogenation and Pd catalysts for selective hydrogenation of acetylene. Plasma modification of the support before impregnation is slightly more effective than the plasma modification after impregnation. However, plasma modifications after impregnation increase the stability and selectivity of catalysts more effectively. The economic benefit of much improved stability of Ni catalysts for hydrogenation of benzene and the enhanced activity and selectivity of Pd catalysts for acetylene hydrogenation, e.g., is significant. Similar benefits for various catalysts and other industrial processes via RF plasma techniques are expected.Type: ApplicationFiled: August 31, 2007Publication date: July 3, 2008Inventors: Wen-Long Jang, Chalita Ratanatawanate
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Patent number: 7390768Abstract: The invention described herein involves a novel approach to the production of oxidation/reduction catalytic systems. The present invention serves to stabilize the tin oxide reducible metal-oxide coating by co-incorporating at least another metal-oxide species, such as zirconium. In one embodiment, a third metal-oxide species is incorporated, selected from the group consisting of cerium, lanthanum, hafnium, and ruthenium. The incorporation of the additional metal oxide components serves to stabilize the active tin-oxide layer in the catalytic process during high-temperature operation in a reducing environment (e.g., automobile exhaust). Moreover, the additional metal oxides are active components due to their oxygen-retention capabilities. Together, these features provide a mechanism to extend the range of operation of the tin-oxide-based catalyst system for automotive applications, while maintaining the existing advantages.Type: GrantFiled: January 22, 2002Date of Patent: June 24, 2008Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Jeffrey D. Jordan, David R. Schryer, Patricia P. Davis, Bradley D. Leighty, Anthony Neal Watkins, Jacqueline L. Schryer, Donald M. Oglesby, Suresh T. Gulati, Jerry C. Summers
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Publication number: 20080139382Abstract: A catalyst for purifying exhaust gas that provides a superior catalytic performance even at a high temperature by increasing the durability of the promoter. The catalyst for purifying exhaust gas includes a promoter clathrate wherein a promoter component particle is covered with a high heat-resistant oxide. A promoter active species is contained in the promoter clathrate. The catalytic active species are located adjacent to the promoter clathrates. The catalytic active species has a precious metallic particle having a catalyst activity, a metallic oxide particle for bearing the precious metallic particle and a metallic oxide placed around the metallic oxide particle and the precious metallic particle.Type: ApplicationFiled: September 26, 2007Publication date: June 12, 2008Applicant: NISSAN MOTOR CO., LTD.Inventors: Hideaki Morisaka, Hironori Wakamatsu, Masanori Nakamaura, Kazuyuki Shiratori, Hirofumi Yasuda, Katsuo Suga
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Publication number: 20080132410Abstract: Chemical vapor deposition (CVD) is used to synthesize single-wall carbon nanotubes by a catalytic reaction, and a method of preparing the catalyst is also provided. A transition metal catalyzing growth of carbon nanotubes, an oxide of a precursor metal preventing agglomeration of catalyst particles, and a precious metal are essentially consisted in the catalyst. The catalyst particles can be further dispersed by quasi-explosive effect occurred when the oxidized precious metal is reduced.Type: ApplicationFiled: May 16, 2007Publication date: June 5, 2008Applicant: RITEK CORPORATIONInventors: Wei-Hsiang WANG, Cheng-Tzu KUO, Tsai-Hau HONG
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Patent number: 7381683Abstract: Supported catalysts are produced with nanometer sized particles comprised of different metals dispersed throughout the catalyst support material. The supported catalysts reduce substantially or completely the amount of platinum that is required without sacrificing catalytic performance. In place of platinum, the supported catalysts employ palladium, silver, or copper, all of which costs significantly less than platinum.Type: GrantFiled: October 28, 2005Date of Patent: June 3, 2008Assignee: NanoStellar, Inc.Inventors: Jian Wang, Xianghong Hao, Jifei Jia, Jonathan W. Woo
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Publication number: 20080125610Abstract: A process for treating a carrier, or a precursor thereof, to at least partly remove impurities comprising contacting the carrier, or the precursor thereof, with a treatment solution comprising a salt; a process for preparing a catalyst; the catalyst; a process for preparing an olefin oxide by reacting an olefin with oxygen in the presence of the catalyst; and a process for preparing a 1,2-diol, a 1,2-diol ether or an alkanolamine.Type: ApplicationFiled: November 15, 2007Publication date: May 29, 2008Inventors: John Robert Lockemeyer, Randall Clayton Yeates
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Publication number: 20080125312Abstract: The present teachings are directed toward methods of modifying the properties of a composition by providing particles of a first composition having dimensions of less than about 3 nanometers and a substrate of a second composition. The particles of the first composition are placed on the substrate, whereby the particles of the first composition and the substrate interact to modify at least one property of the particles of the first composition relative to the same property of particles of the first composition having dimensions greater than about 10 nanometers placed on a substrate of the second composition.Type: ApplicationFiled: November 16, 2007Publication date: May 29, 2008Applicant: Honda Motor Co., Ltd.Inventor: Avetik Harutyunyan
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Publication number: 20080112870Abstract: Catalysts, catalyst systems, and methods for removing ammonia and/or carbon monoxide in flue gases are provided where ammonia is used with a selective catalytic reduction catalyst for reducing oxides of nitrogen. A dual oxidation catalyst generally comprises an alkali component, a transition metal, and a metal oxide support. This catalyst is also substantially free from precious metal components and effective for substantially simultaneously oxidizing ammonia (NH3) and carbon monoxide (CO) when placed in an exhaust gas stream. The catalyst is effective to provide low ammonia to nitrogen oxides selectivity.Type: ApplicationFiled: November 15, 2006Publication date: May 15, 2008Inventors: Ahmad Moini, Gerald S. Koermer, Pascaline Harrison Tran, Jacqueline S. Curran
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Patent number: 7358212Abstract: The invention relates to a method for producing a one-part, multinary metal oxide power which is suitable for producing high-temperature superconductors. To this end, a mixture of the corresponding metal salts and/or metal oxides and/or metals in the requisite stoichiometric ratio is introduced into a pulsed reactor with a pulsed gas flow resulting from flameless combustion and is partially or completely converted into the multinary metal oxide.Type: GrantFiled: March 6, 2002Date of Patent: April 15, 2008Assignee: Merck Patent GmbHInventors: Stefan Remke, Bernd Mueller, Guenter Riedel, Stefan Ambrosius, Bernd Dahm
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Patent number: 7348444Abstract: A process for the production of an olefin oxide, which process comprises reacting a feed comprising an olefin and oxygen in the presence of a silver-containing catalyst, wherein before the catalyst has reached an advanced stage of ageing the reaction temperature is above 255° C. and the olefin content of the feed is above 25 mole-%, relative to the total feed.Type: GrantFiled: April 1, 2004Date of Patent: March 25, 2008Assignee: Shell Oil CompanyInventors: Wayne Errol Evans, Marek Matusz
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Publication number: 20080069743Abstract: Catalysts, systems and methods are described to reduce NOx emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having an SCR catalyst comprising silver tungstate on an alumina support. The emissions treatment system may be used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines. An emissions treatment system may further comprise an injection device operative to dispense a hydrocarbon reducing agent upstream of the catalyst.Type: ApplicationFiled: September 20, 2006Publication date: March 20, 2008Inventors: Christopher R. Castellano, Ahmad Moini, Gerald S. Koermer, Howard Furbeck
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Patent number: 7338918Abstract: A catalyst is described which has a catalytically active composition which contains a phase A and a phase B in the form of three-dimensional delimited regions, wherein phase A is a silver-vanadium oxide bronze and phase B a mixed oxide phase based on titanium dioxide and vanadium pentoxide. The catalyst serves to prepare aldehydes, carboxylic acids and/or carboxylic anhydrides from aromatic or heteroaromatic hydrocarbons by gas phase oxidation.Type: GrantFiled: March 24, 2005Date of Patent: March 4, 2008Assignee: BASF AktiengesellschaftInventors: Samuel Neto, Frank Rosowski, Sebastian Storck, Stefan Bauer
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Patent number: 7335620Abstract: An object of the present invention is to provide a photocatalytic powder containing titanium dioxide fine particles containing an anionically active substance, where the electrokinetic potential of the fine particle is from about ?100 to 0 mV in an aqueous environment at pH 5. Another object of the present invention is to provide a photocatalytic slurry containing the powder, and a polymer composition, a coating agent, a photocatalytic functional molded article and a photocatalytic functional structure using the powder.Type: GrantFiled: December 2, 2003Date of Patent: February 26, 2008Assignee: Showa Denko K.K.Inventors: Katsura Ito, Hiroyuki Hagihara
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Publication number: 20080039316Abstract: The invention relates to an improved process for producing a catalyst useful for the epoxidation of ethylene to ethylene oxide. In forming the catalyst, a silver-impregnated support is subjected to two calcinations. The support is subjected to a first calcination in a first atmosphere comprising air. Next the support is subjected to a second calcination in a second atmosphere which is substantially entirely comprised of inert gas, and which second atmosphere is substantially absent of hydrogen. This two-stage calcination produces an improved catalyst which contains fewer organics left over under standard conditions of air calcination alone, while costing less than calcination in an inert gas alone.Type: ApplicationFiled: August 8, 2006Publication date: February 14, 2008Inventors: Vijay S. Bhise, Arie Bortinger, Stephen R. Allen
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Patent number: 7318915Abstract: This invention relates generally to a ruthenium stabilized oxidation-reduction catalyst useful for oxidizing carbon monoxide, and volatile organic compounds, and reducing nitrogen oxide species in oxidizing environments, substantially without the formation of toxic and volatile ruthenium oxide species upon said oxidizing environment being at high temperatures.Type: GrantFiled: January 13, 2003Date of Patent: January 15, 2008Assignee: United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Jeffrey D. Jordan, Anthony Neal Watkins, Jacqueline L. Schryer, Donald M. Oglesby
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Patent number: 7319156Abstract: There is disclosed a process for producing an olefin oxide, which is characterized by reacting an olefin with oxygen in the presence of a silver catalyst and 0.2 mole or more of water per mol of the olefin.Type: GrantFiled: March 19, 2004Date of Patent: January 15, 2008Assignee: Sumitomo Chemical Company, LimitedInventors: Makoto Yako, Michio Yamamoto
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Patent number: 7304013Abstract: Bulk and supported catalysts are prepared from an aqueous slurry containing a catalytically active material and a binder. The slurry is either coated onto a support and dried to form a porous, high surface area phase containing the catalytically active material, or reduced to a paste-like consistency, molded and dried to form a bulk catalyst. The processes and catalysts may be employed in various catalytic chemical processes to achieve high effectiveness factor of the catalytically active material while achieving a lower pressure drop.Type: GrantFiled: June 30, 2003Date of Patent: December 4, 2007Assignee: Corning IncorporatedInventors: William P. Addiego, Charles M. Sorensen, Jr.
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Publication number: 20070265159Abstract: The invention provides a method for depositing catalytic clusters on a surface, the method comprising confining the surface to a controlled atmosphere; contacting the surface with catalyst containing vapor for a first period of time; removing the vapor from the controlled atmosphere; and contacting the surface with a reducing agent for a second period of time so as to produce catalyst-containing nucleation sites.Type: ApplicationFiled: March 5, 2007Publication date: November 15, 2007Inventors: Jeffrey W. Elam, Michael J. Pellin, Peter C. Stair
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Patent number: 7268097Abstract: A desulfurizing agent comprising a silica-alumina carrier having an Si/Al mole ratio of 10 or less and nickel carried thereon; a desulfurizing agent for hydrocarbons derived from petroleum which comprises a carrier and a metal component carried thereon and has a specific surface area of pores having a pore diameter of 3 nm or less of 100 m2/g or more; an Ni-Cu based desulfurizing agent comprising a carrier and, carried thereon, (A) nickel, (B) copper, and (C) an alkali metal or another metal; a desulfurizing agent for hydrocarbons derived from petroleum which comprises a carrier and a metal component carried thereon and has a hydrogen adsorption capacity of 0.4 mmol/g or more; and methods for producing these nickel-based and nickel-copper-based desulfurizing agents. The above desulfurizing agents are capable of adsorbing and removing with good efficiency the sulfur contained in hydrocarbons derived from petroleum to a content of 0.2 wt. ppm or less and have a long service life.Type: GrantFiled: April 2, 2001Date of Patent: September 11, 2007Assignee: Idemitsu Kosan Co., Ltd.Inventors: Hisashi Katsuno, Satoshi Matsuda, Kazuhito Saito, Masahiro Yoshinaka
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Patent number: 7259129Abstract: A high activity and high selectivity silver catalyst comprising silver and, optionally, one or more promoters supported on a suitable support material having the form of a shaped agglomerate. The structure of the shaped agglomerate is that of a hollow cylinder having a relatively small inside (bore) diameter. The catalyst is made by providing the shaped material of a particular geometry and incorporating the catalytic components therein. The catalyst is useful in the epoxidation of ethylene.Type: GrantFiled: April 1, 2004Date of Patent: August 21, 2007Assignee: Shell Oil CompanyInventors: Marek Matusz, Michael Alan Richard, John Robert Lockemeyer, Alouisius Nicolaas Renee Bos, Dominicus Maria Rekers, Donald Reinalda, Randall Clayton Yeates
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Patent number: 7247600Abstract: There is provided a catalyst carrier comprising a refractory inorganic material having a sodium solubilization rate no greater than 5 ppmw/5 minutes. There is further a catalyst comprising a refractory inorganic material carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and one or more catalytically reactive metals deposited on said carrier. There is also provided a catalyst suitable for the vapor phase production of alkylene oxide from olefins and oxygen comprising an alumina-based carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and catalytically reactive silver deposited on said carrier.Type: GrantFiled: November 6, 2001Date of Patent: July 24, 2007Assignee: Shell Oil CompanyInventor: John Robert Lockemeyer
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Patent number: 7232786Abstract: There is provided a catalyst carrier comprising a refractory inorganic material having a sodium solubilization rate no greater than 5 ppmw/5 minutes. There is further a catalyst comprising a refractory inorganic material carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and one or more catalytically reactive metals deposited on said carrier. There is also provided a catalyst suitable for the vapor phase production of alkylene oxide from olefins and oxygen comprising an alumina-based carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and catalytically reactive silver deposited on said carrier.Type: GrantFiled: September 8, 2004Date of Patent: June 19, 2007Assignee: Shell Oil CompanyInventor: John Robert Lockemeyer
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Patent number: 7220701Abstract: A selective hydrogenation catalyst composition comprises a rhodium component present in an amount such that the catalyst composition comprises less than 3.0% of rhodium by weight of the total catalyst composition; and an indium component present in an amount such that the catalyst composition comprises at least 0.3% and less than 5.0% of indium by weight of the total catalyst composition.Type: GrantFiled: November 24, 2003Date of Patent: May 22, 2007Assignee: ExxonMobil Chemical Patents Inc.Inventors: David M. Lowe, Michel Molinier, John D. Y. Ou, Michael A. Risch, Anthony F. Volpe, Jr., Jeffrey C. Yoder
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Patent number: 7169735Abstract: The object of the present invention is to provide a catalyst that is highly active and capable of maintaining its activity for a long period of time even in a high-temperature environment. The present invention is a catalyst including: a porous carrier which is comprised of one kind of or two or more kinds of metal oxides; and catalyst particles which are comprised of precious metals or precious metal oxides and supported on the above porous carrier, characterized in that the catalyst particles include: clustered particles formed by the aggregation of first precious metal atoms; and second precious metal ions bound to the above clustered particles. Preferably, the first precious metal and the second precious metal are different metal species which are selected from the group consisting of platinum, palladium, rhodium, ruthenium, silver, gold, iridium and osmium.Type: GrantFiled: May 3, 2005Date of Patent: January 30, 2007Assignee: Tanaka Kikinzoku Kogyo K.K.Inventor: Takeyuki Sagae
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Patent number: 7153987Abstract: The invention relates to a process for preparing a catalyst which involves (a) preparing a paste having a uniform mixture of at least one alkaline earth metal carbonate; a liquid medium; a silver bonding additive; and, at least one extrusion aid and/or optionally a burnout additive; (b) forming one or more shaped particles from the paste; (c) drying and calcining the particles; and, (e) impregnating the dried and calcined particles with a solution containing a silver compound. The invention also relates to a process for preparing an olefin oxide comprising reacting a gas composition containing an olefin having at least two carbon atoms with oxygen in the presence of the catalyst composition obtained by the process of this invention.Type: GrantFiled: September 30, 2003Date of Patent: December 26, 2006Assignee: Shell Oil CompanyInventors: Leonid Isaakovich Rubinstein, Candido Gutierrez
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Patent number: 7153810Abstract: A method of making an exhaust treatment catalyst includes dispersing a metal-based material in a first solvent to form a first slurry and allowing polymerization of the first slurry to occur. Polymerization of the first slurry may be quenched and the first slurry may be allowed to harden into a solid. This solid may be redistributed in a second solvent to form a second slurry. The second slurry may be loaded with a silver-based material, and a silver-loaded powder may be formed from the second slurry.Type: GrantFiled: June 24, 2004Date of Patent: December 26, 2006Assignee: Caterpillar IncInventors: Paul Worn Park, Carrie L. Boyer
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Patent number: 7109145Abstract: The invention provides a noble metal-containing supported catalyst which contains one of the noble metals from the group Au, Ag, Pt, Pd, Rh, Ru, Ir, Os or alloys of one or more of these noble metals in the form of noble metal particles on a powdered support material. The particles deposited on the support material have a degree of crystallinity, determined by X-ray diffraction, of more than 2 and an average particle size between 2 and 10 nm. The high crystallinity and the small particle size of the noble metal particles lead to high catalytic activity for the catalyst. It is particularly suitable for use in fuel cells and for the treatment of exhaust gases from internal combustion engines.Type: GrantFiled: December 10, 2004Date of Patent: September 19, 2006Assignee: Umicore AG & Co. KGInventors: Karsten Ruth, Peter Biberbach, Karl-Anton Starz
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Patent number: 7081433Abstract: Gold-titania (Au—TiO2) composite aerogels and ambigles were synthesized, characterized, and tested as ambient temperature catalysts for carbon monoxide. Adding alkanethiolate-monolayers-protected gold clusters (with ˜2 nm Au cores) directly to titania sol before gelation yields uniformly dispersed guests in the composite aerogel. The Au guests aggregate to 5 to 10 nm upon calcination to remove alkanethiolate and crystallize amorphous titania to anatase. The resulting composite aerogel exhibits high catalytic activity toward CO oxidation at room temperature at Au particle sizes that are essentially inactive in prior Au—TiO2 catalysts. Transmission electron microscopy illustrates the three-dimensional nature of the catalytic nanoarchitecture in which gold guests contact multiple anatase nanocrystallites.Type: GrantFiled: March 12, 2003Date of Patent: July 25, 2006Assignee: The United States of America as represented by the Secretary of the NavyInventors: Debra Rolison, Jeremy Pietron, Rhonda Stroud
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Patent number: 7071363Abstract: The invention relates to a novel structured catalyst bed which optionally comprises at least one part bed comprising at least one catalytically active mixture of oxides of the main group metals and transition metals and additionally comprises at least one catalytically active part bed comprising at least silver, at least one alkali metal and a porous support material and finally and necessarily at least one catalytically active part bed comprising at least one alkali metal phosphate and at least one sheet silicate.Type: GrantFiled: July 14, 2003Date of Patent: July 4, 2006Assignee: BASF AktiengesellschaftInventors: Hartmut Hibst, Sebastian Storck, Dirk Demuth, Wolfram Stichert, Jens Klein, Stephan A. Schunk, Andreas Sundermann
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Patent number: 7060651Abstract: A silica-rich support and a catalyst containing the silica-rich support and a catalytic component. The support has a specific structure characterized by a set of claimed physicochemical properties: in the 29Si MAS NMR spectrum the state of silicon is characterized by the presence of lines with chemical shifts ?100±3 ppm (line Q3) and ?110±3 ppm (line Q4), with the ratio of the integral intensities of the lines Q3/Q4 of from 0.7 to 1.2 (FIG. 1); in the IR spectrum there is an absorption band of hydroxyl groups with the wave number 3620–3650 cm?1 and half-width 65–75 cm?1 (FIG. 2); the carrier has a specific surface area, as measured by the BET techniques from the thermal desorption of argon, SAR=0.5–30 m2/g and the surface, as measured by alkali titration techniques, SNa=10–250 m2/g, with SNa/SAr=5–30.Type: GrantFiled: December 4, 2000Date of Patent: June 13, 2006Assignee: Zakrytoe Aktsionernoe Obschestvo “Kholdingovaya Katalizatornaya Kompania”Inventors: Viktor Vladimirovich Barelko, Bair Sydypovich Balzhinimaev, Sergei Petrovich Kildyashev, Mikhail Grigorievich Makarenko, Anatoly Nikolaevich Parfenov, Ljudmila Grigorievna Simonova, Alexandr Viktorovich Toktarev
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Patent number: 7049451Abstract: A carrier for use in the catalyst for the production of an epoxide is obtained by preparing a carrier precursor containing (a) ?-alumina, (b) silicon or a compound thereof, and (c) at least one element selected from the class consisting of germanium, tin, lead, phosphorus, antimony, and bismuth or a compound thereof and subsequently heat-treating the precursor in non-oxidative gas. The catalyst for the production of the epoxide is obtained by having silver deposited on this carrier and the epoxide is obtained from a corresponding unsaturated hydrocarbon of 2–4 carbon atoms with a high selectivity by using the catalyst.Type: GrantFiled: April 3, 2003Date of Patent: May 23, 2006Assignee: Nippon Shokubai, Co., Ltd.Inventors: Toshiya Ehara, Hitoshi Takada
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Patent number: 7045485Abstract: A composition for controlling NOx emissions during FCC processes comprises (i) an acidic oxide support, (ii) cerium oxide, (iii) a lanthanide oxide other than ceria such as praseodymium oxide, and (iv), optionally, an oxide of a metal from Groups Ib and IIb such as copper, silver and zinc.Type: GrantFiled: January 13, 2004Date of Patent: May 16, 2006Assignee: Engelhard CorporationInventors: Chandrashekhar Pandurang Kelkar, David Stockwell, Samuel Tauster
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Patent number: 7037878Abstract: An aircraft environmental control system includes a catalytic converter having ozone-destroying capability. A surface of the catalytic converter is anodized to form an anodized layer, and the metal oxide layer is washcoated to form a washcoat layer. An ozone destroying catalyst is impregnated in the anodized and washcoat layers. The catalyst may include one or more metals. For example, a bimetallic catalyst may include a precious metal and a transition metal.Type: GrantFiled: May 7, 2003Date of Patent: May 2, 2006Assignee: Honeywell International Inc.Inventors: Di-Jia Liu, Daniel R. Winstead, Peter M. Michalakos