Of Group Iv (i.e., Ti, Zr, Hf, Ge, Sn Or Pb) Patents (Class 502/349)
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Patent number: 7674744Abstract: A method of producing catalyst powder of the present invention has a step of precipitating a carrier in a reversed micelle, and a step of precipitating at least one of a noble metal particle and a transition metal particle in the reversed micelle in which the carrier is precipitated. By this method, it is possible to obtain catalyst powder excellent in heat resistance and high in the catalytic activity.Type: GrantFiled: March 15, 2005Date of Patent: March 9, 2010Assignee: Nissan Motor Co., Ltd.Inventors: Kazuyuki Shiratori, Toru Sekiba, Katsuo Suga, Masanori Nakamura, Hironori Wakamatsu, Hirofumi Yasuda
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Publication number: 20100056839Abstract: A process for the production of propylene, the process including: contacting ethylene and a hydrocarbon stream comprising 1-butene and 2-butene with a bifunctional isomerization-metathesis catalyst to concurrently isomerizes 1-butene to 2-butene and to form a metathesis product comprising propylene; wherein the bifunctional isomerization-metathesis catalyst comprises: a catalyst compound may include at least one element selected from tungsten, tantalum, niobium, molybdenum, nickel, palladium, osmium, iridium, rhodium, vanadium, ruthenium, and rhenium for providing metathesis activity on a support comprising at least one element from Group IA, IIA, IIB, and IIIA of the Periodic Table of the Elements; wherein an exposed surface area of the support provides both isomerization activity for the isomerization of 1-butene to 2-butene; and reactive sites for the adsorption of catalyst compound poisons.Type: ApplicationFiled: September 4, 2009Publication date: March 4, 2010Applicants: LUMMUS TECHNOLOGY INC., BASF CATALYSTS LLCInventors: Bala Ramachandran, Sukwon Choi, Robert J. Gartside, Shane Kleindienst, Wolfgang Ruettinger, Saeed Alerasool
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Patent number: 7662743Abstract: The present invention provides an NOx purifying catalyst that removes NOx with sufficient efficiency even under low temperature operation such as diesel engine automobiles. An NOx purifying catalyst for processing NOx in exhaust gas by rich/lean control of the air-fuel ratio of the exhaust gas, includes a first catalytic layer containing ?-zeolite having iron and/or cerium elements, and a second catalytic layer including a noble metal and cerium oxide-based material; in which the second and the first catalytic layers are coated on a support in that order so that the first catalytic layer is the uppermost layer. The NOx purifying catalyst purifies NOx as showed in Reaction Formulations (1) to (4). Lean condition 1: NO+½O2?NO2??(1) Rich condition: CO+H2O?CO2??(2) NOx+H2?NH3??(3) Lean condition 2: NOx+NH3+O2?N2+H2O??(4).Type: GrantFiled: July 12, 2007Date of Patent: February 16, 2010Assignee: Honda Motor Co., Ltd.Inventors: Naohiro Satoh, Osami Yamamoto, Koichi Inaba
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Patent number: 7662744Abstract: In a process for producing an SCR catalyst for the selective reduction of NOx in NOx-containing exhaust gases of internal combustion engines, a support layer is applied to a substrate body. An iron salt dissolved in a liquid is applied to the support layer in such an amount that no excess of iron salt is present.Type: GrantFiled: January 19, 2007Date of Patent: February 16, 2010Assignee: Universitaet KarlsruheInventors: Sven Kureti, Peter Balle, Bastian Geiger
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Patent number: 7659432Abstract: Mixed ketones are prepared from a mixture of carboxylic acids in a process with high selectivity by using an improved catalyst. The catalyst contains zirconium dioxide or zirconium dioxide and titanium dioxide, and a Group 1 or 2 metal silicate or phosphate salt. The new catalyst is more selective toward the formation of the mixed ketone, as opposed to a symmetrical ketone.Type: GrantFiled: July 1, 2008Date of Patent: February 9, 2010Assignee: Eastman Chemical CompanyInventors: Alexey V. Ignatchenko, Michelle Manichanh King, Zhufang Liu, Calvin W. Whiddon
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Patent number: 7655749Abstract: Methods for synthesizing dimeric or higher polymeric reaction products of nitrogen aromatics comprise contacting a composition comprising the nitrogen aromatic with a catalyst composition. The catalyst is in particulate form and comprises a first metal substrate having a second reduced metal coated on the substrate.Type: GrantFiled: September 19, 2005Date of Patent: February 2, 2010Assignee: GM Global Technology Operations, Inc.Inventors: Andrew M. Mance, Tao Xie, Belabbes Merzougui, Charlene A. Hayden
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Patent number: 7655595Abstract: An oxidation catalyst system is formed by particles of an oxidation catalyst dispersed in a porous sol-gel binder. The oxidation catalyst system can be applied by brush or spray painting while the sol-gel binder is in its sol state.Type: GrantFiled: June 2, 2006Date of Patent: February 2, 2010Assignee: United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Anthony N. Watkins, Bradley D. Leighty, Donald M. Oglesby, JoAnne L. Ingram, Jacqueline L. Schryer
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Patent number: 7655137Abstract: The reforming catalysts include a halogen promoter and a plurality of nanocatalyst particles supported on a support material. The nanocatalyst particles have a controlled crystal face exposure of predominately (110). The controlled coordination structure is manufactured by reacting a plurality of catalyst atoms with a control agent such as polyacrylic acid and causing or allowing the catalyst atoms to form nanocatalyst particles. The catalysts are used in a reforming reaction to improve the octane number of gasoline feedstock. The reforming catalysts show improved C5+ hydrocarbon production and improved octane barrel number increases as compared to commercially available reforming catalysts.Type: GrantFiled: May 16, 2006Date of Patent: February 2, 2010Assignee: Headwaters Technology Innovation, LLCInventors: Bing Zhou, Horacio Trevino, Zhihua Wu
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Publication number: 20100022796Abstract: Especially physically stable metal oxide catalyst supports are prepared by suspending a metal oxide in a continuous phase, activating by fine dispersion, coagulation to a viscoelastic mass, shaping, drying, and calcining. The catalyst support thus prepared may be treated with catalytic agents to produce supported catalysts for olefin oxidation.Type: ApplicationFiled: December 6, 2007Publication date: January 28, 2010Applicant: WACKER CHEMIE AGInventors: Roland Heidenreich, Hans-Jurgen Eberle, Johann Weis
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Publication number: 20100009844Abstract: Processes for purifying silicon tetrafluoride source gas by subjecting the source gas to one or more purification processes including: contacting the silicon tetrafluoride source gas with an ion exchange resin to remove acidic contaminants, contacting the silicon tetrafluoride source gas with a catalyst to remove carbon monoxide, by removal of carbon dioxide by use of an absorption liquid, and by removal of inert compounds by cryogenic distillation; catalysts suitable for removal of carbon monoxide from silicon tetrafluoride source gas and processes for producing such catalysts.Type: ApplicationFiled: September 21, 2009Publication date: January 14, 2010Applicant: MEMC ELECTRONIC MATERIALS, INC.Inventors: Vithal Revankar, Jameel Ibrahim
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Publication number: 20090325791Abstract: A method for obtaining an olefin is disclosed, the method comprising subjecting a paraffin to dehydrogenation in the absence of oxygen and in the presence of a catalyst comprising a crystalline substrate, to obtain an olefin. The catalyst includes an inert stabilizing agent for maintaining the catalyst crystal structure. The catalyst may be regenerated by being subjected, in air, to a temperature between about 550° C. and about 750° C., for a period of time between about 15 minutes and about 4 hours.Type: ApplicationFiled: June 22, 2009Publication date: December 31, 2009Inventors: Wei Pan, Stephen M. Casey, Bryan K. Glover, Feng Xu
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Publication number: 20090324468Abstract: The present invention pertains to catalyst systems for nitrogen oxide, carbon monoxide, hydrocarbon, and sulfur reactions that are free or substantially free of platinum group metals. The catalyst system of the present invention comprise a substrate and a washcoat, wherein the washcoat comprises at least one oxide solid, wherein the oxide solid comprises one or more selected from the group consisting of a carrier material oxide, a catalyst, and mixtures thereof. The catalyst system may optionally have an overcoat, wherein the overcoat comprises at least one oxide solid, wherein the oxide solid comprises one or more selected from the group consisting of a carrier material oxide, a catalyst, and mixtures thereof. The catalyst comprises one or more selected from the group consisting of a ZPGM transition metal catalyst, a mixed metal oxide catalyst, a zeolite catalysts, or mixtures thereof.Type: ApplicationFiled: June 27, 2008Publication date: December 31, 2009Inventors: Stephen J. Golden, Randal Hatfield, Jason Pless, Johnny Ngo, Mann Sakbodin
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Patent number: 7638459Abstract: A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.Type: GrantFiled: May 25, 2005Date of Patent: December 29, 2009Assignee: UOP LLCInventors: Dean E. Rende, James E. Rekoske, Jeffery C. Bricker, Jeffrey L. Boike, Masao Takayama, Kouji Hara, Nobuyuki Aoi
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Patent number: 7638460Abstract: An exhaust gas purifying catalyst of the present invention has a substrate, and a catalyst layer formed on an inner wall of the substrate and composed of at least a single layer. The catalyst layer contains a carrier supporting noble metal. Further, a maximum height of profile of a surface of a top layer in the catalyst layer is not less than 2 ?m and not more than 50 ?m, and the top layer contains the carrier supporting noble metal.Type: GrantFiled: October 26, 2006Date of Patent: December 29, 2009Assignee: Nissan Motor Co., Ltd.Inventors: Masanori Nakamura, Katsuo Suga, Kiyoshi Miyazaki, Jun Ikezawa
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Publication number: 20090317308Abstract: Catalysts are formulated to resemble a direct ammonia/air fuel cell at short circuit at the nanoscale level to convert ammonia in aqueous solution directly and spontaneously to nitrogen at near or above ambient temperature. The catalyst particle contains a type-A catalyst subparticles for ammonia oxidation to nitrogen, and a type-C catalyst subparticles for oxygen reduction, with the type-A and type-C catalyst subparticles electrically shorted. Advantages realized at the nanoscale level are enhanced conductances for electrons and hydroxyl anions between the neighboring type-A and type-C catalyst subparticles. With the catalysts packed and confined in a catalyst bed in a chemical reactor, the direct conversion of ammonia in an aqueous phase to nitrogen can be carried out continuously for ammonia removal from a water stream in a compact package, and without the high cost arising from constructing and maintaining a bulk electrochemical device, and without the step of exacting the ammonia into gas phase.Type: ApplicationFiled: June 18, 2009Publication date: December 24, 2009Inventor: Xiaoming Ren
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Patent number: 7635461Abstract: Composite combustion catalyst particles are described and disclosed. A metal core of a combustible metal can be coated with a metal oxide coating. Additionally, a catalyst coating can at least partially surround the metal oxide coating to form a composite catalyst particle. The composite catalyst particles can be dispersed in a variety of fuels such as propulsion fuels and the like to form an enhanced fuel. During initial stages of combustion, the catalyst coating acts to increase combustion of the fuel. As combustion proceeds, the metal core heats sufficiently to disturb the metal oxide coating. The metal core then combusts in highly exothermic reactions with an oxidizer and the catalyst coating to provide improved energy densities to the enhanced fuel.Type: GrantFiled: June 7, 2004Date of Patent: December 22, 2009Assignee: University of Utah Research FoundationInventor: Scott L. Anderson
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Patent number: 7632778Abstract: An apparatus for producing hydrogen, which comprises: a. a heated steam reforming stage (1) with a reforming catalyst to convert gaseous or vaporizable hydrocarbons and water into hydrogen, carbon monoxide and further reformer products; b. at least one stage downstream of the steam reforming stage for the catalytic conversion of the mixture of hydrogen, carbon monoxide and excess steam leaving the steam reforming stage (shift stage) (2); and c. a fine purification stage (3) downstream of the shift stage(s) for the catalytic lowering of the residual carbon monoxide content of the conversion products by selective methanization, is described. In the apparatus, the shift stage (2) and the fine purification stage (3) are configured as a unitary hollow body (exothermic catalyst stage).Type: GrantFiled: January 17, 2005Date of Patent: December 15, 2009Assignee: Süd-Chemie AGInventors: Klaus Wanninger, Peter Britz, Nicolas Zartenar
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Publication number: 20090305872Abstract: Fluid catalytic cracking process comprising the steps of (a) preparing a physical 5 mixture comprising (i) aluminium trihydrate and/or flash-calcined aluminium trihydrate and (ii) a divalent metal oxide, hydroxide, carbonate, or hydroxycarbonate, (b) shaping the physical mixture of step a) to form fluidisable particles, and (c) adding the fluidisable particles obtained from step b) or step c) to a fluid catalytic cracking unit. In this FCC process, active sites of the catalyst composition are formed in-situ, i.e. in the FCC unit, without requiring peptisation, aging, or calcination steps prior to the addition of the composition to the hydrocarbon conversion unit.Type: ApplicationFiled: November 19, 2005Publication date: December 10, 2009Applicant: ALBEMARLE NETHERLANDS BVInventors: Dennis Stamires, Paul O'Connor
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Patent number: 7628968Abstract: The present invention is directed to high activity titanium oxide DeNOx catalysts. In preferred embodinents, by depositing vanadium oxide on a titania supported metal oxide such as tungsten oxide, an improved catalyst may be generated. This catalyst may be used in the treatment of exhaust from sources such as automobiles and industrial plants.Type: GrantFiled: May 23, 2008Date of Patent: December 8, 2009Assignee: Millenium Inorganic Chemicals, Inc.Inventors: Steven M Augustine, Guoyi Fu
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Patent number: 7625840Abstract: A nanoporous catalytic membrane which displays several unique features including pores which can go through the entire thickness of the membrane. The membrane has a higher catalytic and product selectivity than conventional catalysts. Anodic aluminum oxide (AAO) membranes serve as the catalyst substrate. This substrate is then subjected to Atomic Layer Deposition (ALD), which allows the controlled narrowing of the pores from 40 nm to 10 nm in the substrate by deposition of a preparatory material. Subsequent deposition of a catalytic layer on the inner surfaces of the pores reduces pore sizes to less than 10 nm and allows for a higher degree of reaction selectivity. The small pore sizes allow control over which molecules enter the pores, and the flow-through feature can allow for partial oxidation of reactant species as opposed to complete oxidation. A nanoporous separation membrane, produced by ALD is also provided for use in gaseous and liquid separations.Type: GrantFiled: September 14, 2004Date of Patent: December 1, 2009Assignee: UChicago Argonne, LLC.Inventors: Michael J. Pellin, John N. Hryn, Jeffrey W. Elam
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Patent number: 7625836Abstract: To provide a heat-resistant oxide which is excellent in heat resistance and durability at high temperature and has high activity, a heat-resistant oxide which has an oxide crystal structure and in which a rate of a solid solution of a noble metal in the oxide crystal structure is 50% or more is obtained by heat-treating (secondarily baking) a precursor composition comprising zirconia, at least one coordinative element selected from the group consisting of rare earth elements, alkaline earth elements, aluminum and silicon, and at least one noble metal selected from the group consisting of platinum, rhodium and palladium at 650° C. or higher.Type: GrantFiled: December 13, 2005Date of Patent: December 1, 2009Assignees: Cataler Corporation, Daihatsu Motor Co., Ltd.Inventors: Satoshi Matsueda, Mareo Kimura, Naoto Miyoshi, Yoshinori Ishii, Hirohisa Tanaka, Isao Tan, Mari Uenishi, Masashi Taniguchi
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Patent number: 7622419Abstract: To provide a filter catalyst in which the closure of ventilation holes by a catalytic layer is inhibited. A filter catalyst of the present invention is characterized in that it has pores of 1-20 ?m in a porosity of 11% or more. The filter catalyst of the present invention has an effect of being capable of inhibiting the rise of pressure loss when sufficient particulates deposit.Type: GrantFiled: February 10, 2005Date of Patent: November 24, 2009Assignees: Cataler Corporation, Toyota Jidosha Kabushiki KaishaInventors: Makoto Tsuji, Daisuke Oki, Seiji Okawara
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Patent number: 7618919Abstract: A method of producing a catalyst support comprising a substrate, and coating formed on the surface of the substrate and including powder of a first metal oxide of at least one member selected from the group consisting of alumina, zirconia, titania, iron oxides, oxides of rare earth elements, alkali metal oxides and alkali earth metal oxides, wherein the coating is obtained by heat treating the substrate after applied with a coating composition obtained by mixing the first metal oxide powder together with a fluid raw material composition containing raw material of a second metal oxide of at least one member selected from the group consisting of alumina, zirconia, titania, iron oxides, oxides of rare earth elements, alkali metal oxides and alkali earth metal oxides, at a shear rate of 1000 sec?1 or higher.Type: GrantFiled: January 30, 2006Date of Patent: November 17, 2009Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Takashi Shimazu, Ryusuke Tsuji, Hideo Sobukawa
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Patent number: 7615512Abstract: The invention relates to a titanium dioxide-based photocatalyst containing carbon that is highly photoactive in visible light (vlp-TiO2) and to a method of manufacture. The vlp-TiO2 is manufactured by mixing a fine grained titanium compount (BET?50 m2/g) with an organic carbon compound and subsequent thermal treatment at temperatures up to 350° C. The carbon content amounts to 0.05 to 4% by weight, preferably 0.4 to 0.8% by weight. The product is characterized by an ESR spectrum which displays only one significant signal in the g value range from 1.97 to 2.05 at g about 2.003. The inventive photocatalyst can be used for to degrade contaminants and pollutants in liquids and gases.Type: GrantFiled: April 1, 2005Date of Patent: November 10, 2009Assignee: Kronos International IncInventors: Jürgen Orth-Gerber, Horst Kisch
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Publication number: 20090275463Abstract: A method for making a catalyst includes providing a sol that sol includes a catalyst and a catalyst substrate; drying the sol via freeze-drying, spray drying, freeze granulation, or supercritical fluid drying to form a powder; mixing the powder with a solvent to form a slurry; and washcoating the slurry onto a catalyst support. Another method for making a catalyst includes providing a sol, wherein the sol includes a catalyst substrate; drying the sol via freeze-drying, spray drying, freeze granulation, or supercritical fluid drying to form a powder; mixing the powder with a solvent to form a slurry; washcoating the slurry onto a catalyst support; and depositing a catalyst onto the catalyst substrate.Type: ApplicationFiled: May 1, 2008Publication date: November 5, 2009Applicant: GENERAL ELECTRIC COMPANYInventors: Hrishikesh Keshavan, Robert Joseph Lyons, Larry Neil Lewis, Dan Hancu
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Publication number: 20090272943Abstract: A catalytic composition comprising a catalytically active metal and a solid support, characterized in that said catalytically active metal is included into the core structure of said solid support, and said solid support is a refractory and ionic conductive oxide, process for their preparation and its use as a catalyst in synthesis gas production.Type: ApplicationFiled: May 8, 2009Publication date: November 5, 2009Applicant: L Air Liquide Societe Anonyme Pour L Etude Et L Exploitation Des Procedes Georges ClaudeInventors: Thierry Chartier, Cédric Delbos, Fabrice Rossignol, Pascal Del-Gallo, Daniel Gary, Nicolas Richet
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Patent number: 7612015Abstract: A photocatalyst layer (TiO2) is formed on the surface of a substrate (glass plate) through the intermediary of a monoclinic undercoat layer (ZrO2), and no dead layer is substantially present between the photocatalyst layer and the undercoat layer. Also, by providing a peel preventing layer between the substrate and the undercoat layer, it is possible to eliminate film peeling between the photocatalyst layer and the substrate, defects and discoloration. A metal element may be doped in the photocatalyst layer, and it is preferable that the metal element is at least one of Sn, Zn, Mo and Fe. The phrase “no dead layer is substantially present” means that the thickness of the dead layer is 20 nm or less. The thickness of the photocatalyst layer is preferably from 1 nm to 1,000 nm, more preferably from 1 nm to 500 nm.Type: GrantFiled: December 24, 2002Date of Patent: November 3, 2009Assignee: Nippon Sheet Glass Company, LimitedInventors: Toshiaki Anzaki, Yoshifumi Kijima, Kenji Mori
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Patent number: 7608561Abstract: An exhaust gas purifying catalyst comprising: a honeycomb-like substrate disposed in an exhaust passage for an engine; and a catalytic layer formed on a cell wall of said substrate, said catalytic layer including a mixed oxide which contains Ce (cerium) and Zr (zirconium), and retains a catalytic noble metal in such a manner that said noble metal atoms are located at crystal lattice points or between the lattice points of the mixed oxide, wherein said mixed oxide includes a first mixed oxide containing CeO2 in a mass greater than that of ZrO2, and a second mixed oxide containing ZrO2 in a mass greater than that of CeO2.Type: GrantFiled: October 12, 2006Date of Patent: October 27, 2009Assignee: Mazda Motor CorporationInventors: Seiji Miyoshi, Hiroshi Yamada, Koji Minoshima, Akihide Takami, Hideharu Iwakuni
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Patent number: 7608562Abstract: A method of producing a photocatalyst according to the invention comprises forming an amorphous titanium oxide and heat-treating it in an atmosphere containing oxygen, whereby a photocatalyst having a good photocatalysis can be obtained. In particular, the amorphous titanium oxide is obtained by using the reactive sputtering method and via deposition at a low temperature and at a high film formation rate. This apparatus can be provided with cooling means to allow enhancement of the throughput of the film formation process.Type: GrantFiled: November 20, 2008Date of Patent: October 27, 2009Assignee: Shibaura Mechatronics CorporationInventors: Junji Hiraoka, Minoru Takashio, Tetsuya Fukushima, Daisuke Noguchi, Yoshio Kawamata
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Patent number: 7605108Abstract: A catalyst which suppresses aggregation of metal particles and which has superior heat resistance. In the catalyst, metal particles are supported by a surface of a carrier while being partially embedded therein.Type: GrantFiled: July 5, 2005Date of Patent: October 20, 2009Assignee: Nissan Motor Co., Ltd.Inventors: Hironori Wakamatsu, Hirofumi Yasuda, Kazuyuki Shiratori, Masanori Nakamura, Katsuo Suga, Toru Sekiba
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Patent number: 7601670Abstract: A method of producing catalyst powder of the present invention has a step of precipitating any one of a noble metal particle (5) and a transition metal particle (10) in a reversed micelle (1); a step of precipitating, in the reversed micelle (1) in which any one of the noble metal particle (5) and the transition metal particle (10) is precipitated, a porous support material (7) which supports the noble metal particle (5) and the transition metal particle (10); and a step of precipitating the other of the noble metal particle (5) and the transition metal particle (10) in the reversed micelle (1) in which any one of the noble metal particle (5).Type: GrantFiled: February 8, 2005Date of Patent: October 13, 2009Assignee: Nissan Motor Co., Ltd.Inventors: Hirofumi Yasuda, Katsuo Suga, Masanori Nakamura, Hironori Wakamatsu, Kazuyuki Shiratori, Toru Sekiba
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Patent number: 7601671Abstract: A method for preparing an exhaust gas catalyst includes preparing a washcoat comprising a catalytically effective amount of at least one catalytically active metal disposed upon an oxide support; disposing the catalytically active metal-oxide support washcoat upon a catalyst substrate; drying the washcoated catalyst substrate using microwave energy to affix the precious metals to the oxide support; and conventionally calcining the dried washcoated catalyst substrate. The catalysts comprising a substrate having dispersed thereon an inorganic oxide washcoat, the washcoat having been affixed to the substrate by microwave drying, exhibit high exhaust gas purifying performance and long durability. The catalysts thus produced further provide a long in-service lifetime for reforming organic fuel species into hydrogen, carbon monoxide and light hydrocarbons used in the nitrogen oxides reduction process.Type: GrantFiled: October 28, 2004Date of Patent: October 13, 2009Assignee: Umicore AG & Co. KGInventor: William J. LaBarge
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Patent number: 7598204Abstract: A reagent suitable for use as a catalyst comprises a first metal species substrate having a second reduced metal species coated thereon, the second reduced metal species being less electropositive than the first metal. Methods of manufacture are also provided.Type: GrantFiled: September 19, 2005Date of Patent: October 6, 2009Assignee: General Motors CorporationInventors: Andrew M. Mance, Tao Xie, Belabbes Merzougui
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Patent number: 7598205Abstract: In a three-way catalyst for purifying exhaust gases from internal combustion engines, scattering of bismuth components can be suppressed by employing a Bi—Ti composite oxide at a predetermined ratio. Accordingly, the effect of suppressing hydrogen sulfide emissions can be retained for a long time. This catalyst comprises a support substrate, and a catalyst layer formed on the support substrate and including a noble metal, a porous oxide, and a Bi—Ti composite oxide, and satisfies 0.3?R?1.5, where R is the molar ratio of the Bi content to the Ti content per unit volume of the support substrate.Type: GrantFiled: January 27, 2006Date of Patent: October 6, 2009Assignee: Toyota Jidosha Kabushiki KaishaInventor: Hiromasa Suzuki
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Publication number: 20090239739Abstract: A catalyst 1 has a heat-resistant support 2 selected from among Al2O3, SiO2, ZrO2, and TiO2, and a first metal 4 supported on an outer surface of the support 2, and included by an inclusion material 3 containing a component of the support 2.Type: ApplicationFiled: December 5, 2005Publication date: September 24, 2009Inventors: Hirofumi Yasuda, Katsuo Suga, Makoto Aoyama, Toshiharu Miyamura
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Publication number: 20090238733Abstract: A honeycomb structure includes at least one honeycomb member including inorganic fibers and having walls extending along a longitudinal direction to define cells. A catalyst is provided on the wall in an amount of at least about 100 g and at most about 400 g per liter of volume of the honeycomb structure. The honeycomb member has a pore distribution measured using mercury porosimetry in which a pore distribution curve has a first peak in a range from about 0.005 ?m to about 0.03 ?m of a pore diameter, a second peak in a range from about 1 ?m to about 15 ?m of the pore diameter, and a third peak in a range from about 15 ?m to about 50 ?m of the pore diameter, where the curve is drawn by plotting the pore diameter (?m) on an X-axis and a log differential pore volume (mL/g) on a Y-axis.Type: ApplicationFiled: December 30, 2008Publication date: September 24, 2009Applicant: IBIDEN CO., LTD.Inventors: Kazushige OHNO, Kazutake Ogyu, Yusuke Kondo
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Patent number: 7592290Abstract: The invention relates to supported catalysts and a process for the production of these catalysts. These supported catalysts may be used in various reactions such as reforming reactions (e.g. steam methane reforming (SMR) reactions and autothermal reforming (ATR) reactions). In one aspect of the invention, the supported catalyst comprises a transition metal oxide; optionally a rare-earth metal oxide; and a transition metal aluminate.Type: GrantFiled: April 7, 2005Date of Patent: September 22, 2009Assignee: Sulzer Metco(Canada) Inc.Inventors: Syed Tajammul Hussain, Eugene Stelmack
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Publication number: 20090232728Abstract: A water gas shift catalyst for use at temperatures above about 450° C. up to about 900° C. or so comprising rhenium deposited on a support, preferably without a precious metal, wherein the support is prepared from a high surface area material, such as a mixed metal oxide, particularly a mixture of zirconia and ceria, to which may be added one or more of a high surface area transitional alumina, an alkali or alkaline earth metal dopant and/or an additional dopant selected from Ga, Nd, Pr, W, Ge, Fe, oxides thereof and mixtures thereof.Type: ApplicationFiled: March 14, 2008Publication date: September 17, 2009Applicant: Sud-Chemie Inc.Inventors: Jon P. Wagner, Michael W. Balakos, Chandra Ratnasamy
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Patent number: 7585811Abstract: A method of producing catalyst powder of the present invention has a step of precipitating a noble metal particle (2) and a porous carrier (1) in a reversed micelle substantially simultaneously; and a step of precipitating a transition metal particle (3) in the reversed micelle. By this method, it is possible to obtain catalyst powder which restricts an aggregation of the noble metal particles even at a high temperature and is excellent in a catalytic activity.Type: GrantFiled: February 10, 2005Date of Patent: September 8, 2009Assignee: Nissan Motor Co., Ltd.Inventors: Masanori Nakamura, Katsuo Suga, Toru Sekiba, Hironori Wakamatsu, Kazuyuki Shiratori, Hirofumi Yasuda
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Patent number: 7585477Abstract: The invention provides a catalyst for catalytic reduction of nitrogen oxides contained in exhaust gases wherein fuel is supplied and subjected to combustion under periodic rich/lean conditions and the resulting exhaust gases are brought into contact therewith, which catalyst comprises: (A) a catalyst component A comprising (c) ceria or (d) praseodymium oxide or (e) an oxide and/or a composite oxide of at least two elements selected from the group consisting of cerium, zirconium, praseodymium, neodymium, terbium, samarium, gadolinium and lanthanum; (B) a catalyst component B comprising (d) a noble metal catalyst component selected from the group consisting of platinum, rhodium, palladium and oxides thereof and (e) a carrier; and (C) a catalyst component C comprising (f) a solid acid, and (g) a solid acid supporting an oxide of at least one element selected from the group consisting of vanadium, tungsten, molybdenum, copper, iron, cobalt, nickel and manganese.Type: GrantFiled: November 8, 2004Date of Patent: September 8, 2009Assignee: Honda Motor Co., Ltd.Inventors: Tadao Nakatsuji, Norio Suzuki, Hiroshi Ohno, Naohiro Sato, Tomoko Morita, Katsuji Wada
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Publication number: 20090217922Abstract: A catalyst for cellulose hydrolysis and/or the reduction of hydrolysis products, in which a transition metal of group 8 to 11 is supported on a solid support. A method of producing sugar alcohols comprising: hydrolyzing cellulose in the presence of the catalyst in a hydrogen-containing atmosphere with pressurization; and reducing the hydrolysis product of cellulose. Provided are a catalyst for use in the production of sugar alcohols by the hydrolysis and hydrogenation of cellulose that affords easy separation of catalyst and product, and that does not require pH adjustment, acid or alkali neutralization, or activation of the catalyst during reuse, and a method of producing sugar alcohols from cellulose employing this catalyst.Type: ApplicationFiled: March 1, 2007Publication date: September 3, 2009Inventors: Atsushi Fukuoka, Paresh Dhepe
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Patent number: 7582586Abstract: There is disclosed a process for producing a catalyst. The process includes the steps of: a) combining a dendrimer polymer and metal salt in solution forming a metal ion complex; b) exposing the metal ion complex to a reducing environment forming a dendrimer metal nanocomposite; c) depositing the dendrimer metal nanocomposite onto a catalyst support material; d) removing a solvent from the dendrimer metal nanocomposite forming metal clusters; and e) removing the dendrimer polymer forming a catalyst. Additionally, there is disclosed a catalyst having a catalytic metal deposited on a substrate. The catalytic metal is formed in clusters having a size of from 2 to 150 atoms. In another aspect, the clusters may have a spacing of from 2 to 100 nanometers between adjacent metal clusters. Further, in another aspect, the metal clusters which comprise the catalyst have a size distribution in which 70% of the clusters are within 0.6 nm of the average diameter and 99% of the particles are within 1.Type: GrantFiled: August 24, 2006Date of Patent: September 1, 2009Assignees: Toyota Motor Corporation, Toyotal Motor Engineering & Manufacturing North America, Inc.Inventors: Paul T. Fanson, Hirohito Hirata, Michael D. Amiridis, Christopher T. Williams, David S. Deutsch, Attilio Siani, Shinichi Matsumoto
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Patent number: 7582276Abstract: The invention relates to nanoscale rutile or oxide powder that is obtained by producing amorphous TiO2 by mixing an alcoholic solution with a titanium alcoholate and with an aluminum alcohalate and adding water and acid. The amorphous, aluminum-containing TiO2 is isolated by removing the solvent, and is redispersed in water in the presence of a tin salt. Thermal or hydrothermal post-processing yields rutile or oxide that can be redispersed to primary particle size. The n-rutile or the obtained oxide having a primary particle size ranging between 5 and 20 nm can be incorporated into all organic matrices so that they remain transparent. Photocatalytic activity is suppressed by lattice doping with trivalent ions. If the amorphous precursor is redispersed in alcohol, or not isolated, but immediately crystallized, an anatase is obtained that can be redispersed to primary particle size.Type: GrantFiled: August 30, 2002Date of Patent: September 1, 2009Assignee: ITN Nanovation AGInventor: Ralph Nonninger
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Patent number: 7582588Abstract: A method of manufacturing a catalyst, a catalyst precursor, or a catalyst support comprising: (a) mixing a refractory metal oxide or precursor thereof with a liquid to form a paste; (b) adding said paste to an extruder, the extruder having a die plate comprising one or more dies, each die having a plurality of apertures, the outlet of each aperture having a cross sectional area of 6 mm2 or less; (c) extruding the paste through the apertures to form catalyst support extrudates; wherein the inlet of the apertures has a greater cross sectional area than the outlet of said apertures; and wherein for at least one die the combined cross sectional area of all apertures at the inlet relative to the total cross sectional area of the die at the inlet is higher than 50%.Type: GrantFiled: October 25, 2007Date of Patent: September 1, 2009Assignee: Shell Oil CompanyInventors: Peter John Van Den Brink, Ronald Jan Dogterom, Carolus Matthias Anna Maria Mesters
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Publication number: 20090215613Abstract: The present invention is directed to yttrium compositions and methods for making such metal oxide compositions, specifically, metal oxide compositions having high surface area, high metal/metal oxide content, and/or thermal stability with inexpensive and easy to handle materials.Type: ApplicationFiled: November 1, 2007Publication date: August 27, 2009Applicant: Symyx Technologies, Inc.Inventor: Alfred Hagemeyer
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Patent number: 7576035Abstract: A pillar-shaped honeycomb structure has a plurality of cells longitudinally placed in parallel with one another with a wall portion therebetween, wherein the honeycomb structure mainly includes inorganic fibers which form the honeycomb structure without lamination interfaces.Type: GrantFiled: April 7, 2008Date of Patent: August 18, 2009Assignee: Ibiden Co., Ltd.Inventors: Kazushige Ohno, Tomokazu Oya
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Patent number: 7576033Abstract: An alkaline solution of an alkali-soluble compound, which is selected from the group consisting of an alkali-soluble silicon compound and an alkali-soluble germanium compound, is prepared. Also, a water-soluble bismuth compound solution is prepared. The alkaline solution and the water-soluble bismuth compound solution are subjected to mixing processing with agitation at a temperature of at least 80° C. by use of a shearing type agitator and are thereby allowed to react with each other. Thus Bi12MO20 particles, in which M represents an element selected from the group consisting of Si and Ge, are produced. The produced Bi12MO20 particles have small particle diameters and uniform composition.Type: GrantFiled: March 9, 2006Date of Patent: August 18, 2009Assignee: FUJIFILM CorporationInventor: Shigeru Nakamura
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Patent number: 7572543Abstract: A supported catalyst includes an oxide carrier, catalyst particles supported on the oxide carrier, and catalyst layers which locate among the catalyst particles, with interface portions among the oxide carrier, the catalyst particles and the catalyst layers. The catalyst layers have a melting point lower than 1,500° C. and contain an oxide or a composite oxide which includes at least one element selected from the group consisting of Mo, W, Sn and Ru.Type: GrantFiled: August 30, 2006Date of Patent: August 11, 2009Assignee: Kabushiki Kaisha ToshibaInventors: Wu Mei, Jun Tamura, Yoshihiko Nakano
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Patent number: 7572427Abstract: The present invention is related to single and/or multiple-wall carbon nanotubes which may contain interstitial metals obtainable by a preparation process. The process includes a catalytic step using a catalytic system which includes a catalyst and a support. The support comprises hydroxides and/or carbonates or mixtures thereof with or without metal oxides. The present invention is also related to carbon fibers obtainable by said preparation process. The present invention also pertains in particular to said catalytic system and to said preparation process. Another aspect concerns the use of the nanotubes and of the catalytic system according to the invention.Type: GrantFiled: July 3, 2002Date of Patent: August 11, 2009Assignee: Facultes Universitaires Notre-Dame De La PaixInventors: Janos B. Nagy, Narasimaiah Nagaraju, Isabelle Willems, Antonio Fonseca
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Patent number: 7569511Abstract: An alcohol steam reforming catalyst for generating hydrogen contains palladium, yttrium, and at least one of cerium and a metal oxide. The catalyst displays both an improved alcohol conversion rate and improved carbon dioxide selectivity. Methods of making and using the alcohol steam reforming catalyst are described.Type: GrantFiled: May 5, 2006Date of Patent: August 4, 2009Assignee: BASF Catalysts LLCInventors: Christopher R. Castellano, Ye Liu, Ahmad Moini, Gerald Stephen Koermer, Robert Joseph Farrauto