Of Group Iv (i.e., Ti, Zr, Hf, Ge, Sn Or Pb) Patents (Class 502/349)
  • Patent number: 7674744
    Abstract: A method of producing catalyst powder of the present invention has a step of precipitating a carrier in a reversed micelle, and a step of precipitating at least one of a noble metal particle and a transition metal particle in the reversed micelle in which the carrier is precipitated. By this method, it is possible to obtain catalyst powder excellent in heat resistance and high in the catalytic activity.
    Type: Grant
    Filed: March 15, 2005
    Date of Patent: March 9, 2010
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Kazuyuki Shiratori, Toru Sekiba, Katsuo Suga, Masanori Nakamura, Hironori Wakamatsu, Hirofumi Yasuda
  • Publication number: 20100056839
    Abstract: A process for the production of propylene, the process including: contacting ethylene and a hydrocarbon stream comprising 1-butene and 2-butene with a bifunctional isomerization-metathesis catalyst to concurrently isomerizes 1-butene to 2-butene and to form a metathesis product comprising propylene; wherein the bifunctional isomerization-metathesis catalyst comprises: a catalyst compound may include at least one element selected from tungsten, tantalum, niobium, molybdenum, nickel, palladium, osmium, iridium, rhodium, vanadium, ruthenium, and rhenium for providing metathesis activity on a support comprising at least one element from Group IA, IIA, IIB, and IIIA of the Periodic Table of the Elements; wherein an exposed surface area of the support provides both isomerization activity for the isomerization of 1-butene to 2-butene; and reactive sites for the adsorption of catalyst compound poisons.
    Type: Application
    Filed: September 4, 2009
    Publication date: March 4, 2010
    Applicants: LUMMUS TECHNOLOGY INC., BASF CATALYSTS LLC
    Inventors: Bala Ramachandran, Sukwon Choi, Robert J. Gartside, Shane Kleindienst, Wolfgang Ruettinger, Saeed Alerasool
  • Patent number: 7662743
    Abstract: The present invention provides an NOx purifying catalyst that removes NOx with sufficient efficiency even under low temperature operation such as diesel engine automobiles. An NOx purifying catalyst for processing NOx in exhaust gas by rich/lean control of the air-fuel ratio of the exhaust gas, includes a first catalytic layer containing ?-zeolite having iron and/or cerium elements, and a second catalytic layer including a noble metal and cerium oxide-based material; in which the second and the first catalytic layers are coated on a support in that order so that the first catalytic layer is the uppermost layer. The NOx purifying catalyst purifies NOx as showed in Reaction Formulations (1) to (4). Lean condition 1: NO+½O2?NO2??(1) Rich condition: CO+H2O?CO2??(2) NOx+H2?NH3??(3) Lean condition 2: NOx+NH3+O2?N2+H2O??(4).
    Type: Grant
    Filed: July 12, 2007
    Date of Patent: February 16, 2010
    Assignee: Honda Motor Co., Ltd.
    Inventors: Naohiro Satoh, Osami Yamamoto, Koichi Inaba
  • Patent number: 7662744
    Abstract: In a process for producing an SCR catalyst for the selective reduction of NOx in NOx-containing exhaust gases of internal combustion engines, a support layer is applied to a substrate body. An iron salt dissolved in a liquid is applied to the support layer in such an amount that no excess of iron salt is present.
    Type: Grant
    Filed: January 19, 2007
    Date of Patent: February 16, 2010
    Assignee: Universitaet Karlsruhe
    Inventors: Sven Kureti, Peter Balle, Bastian Geiger
  • Patent number: 7659432
    Abstract: Mixed ketones are prepared from a mixture of carboxylic acids in a process with high selectivity by using an improved catalyst. The catalyst contains zirconium dioxide or zirconium dioxide and titanium dioxide, and a Group 1 or 2 metal silicate or phosphate salt. The new catalyst is more selective toward the formation of the mixed ketone, as opposed to a symmetrical ketone.
    Type: Grant
    Filed: July 1, 2008
    Date of Patent: February 9, 2010
    Assignee: Eastman Chemical Company
    Inventors: Alexey V. Ignatchenko, Michelle Manichanh King, Zhufang Liu, Calvin W. Whiddon
  • Patent number: 7655749
    Abstract: Methods for synthesizing dimeric or higher polymeric reaction products of nitrogen aromatics comprise contacting a composition comprising the nitrogen aromatic with a catalyst composition. The catalyst is in particulate form and comprises a first metal substrate having a second reduced metal coated on the substrate.
    Type: Grant
    Filed: September 19, 2005
    Date of Patent: February 2, 2010
    Assignee: GM Global Technology Operations, Inc.
    Inventors: Andrew M. Mance, Tao Xie, Belabbes Merzougui, Charlene A. Hayden
  • Patent number: 7655595
    Abstract: An oxidation catalyst system is formed by particles of an oxidation catalyst dispersed in a porous sol-gel binder. The oxidation catalyst system can be applied by brush or spray painting while the sol-gel binder is in its sol state.
    Type: Grant
    Filed: June 2, 2006
    Date of Patent: February 2, 2010
    Assignee: United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Anthony N. Watkins, Bradley D. Leighty, Donald M. Oglesby, JoAnne L. Ingram, Jacqueline L. Schryer
  • Patent number: 7655137
    Abstract: The reforming catalysts include a halogen promoter and a plurality of nanocatalyst particles supported on a support material. The nanocatalyst particles have a controlled crystal face exposure of predominately (110). The controlled coordination structure is manufactured by reacting a plurality of catalyst atoms with a control agent such as polyacrylic acid and causing or allowing the catalyst atoms to form nanocatalyst particles. The catalysts are used in a reforming reaction to improve the octane number of gasoline feedstock. The reforming catalysts show improved C5+ hydrocarbon production and improved octane barrel number increases as compared to commercially available reforming catalysts.
    Type: Grant
    Filed: May 16, 2006
    Date of Patent: February 2, 2010
    Assignee: Headwaters Technology Innovation, LLC
    Inventors: Bing Zhou, Horacio Trevino, Zhihua Wu
  • Publication number: 20100022796
    Abstract: Especially physically stable metal oxide catalyst supports are prepared by suspending a metal oxide in a continuous phase, activating by fine dispersion, coagulation to a viscoelastic mass, shaping, drying, and calcining. The catalyst support thus prepared may be treated with catalytic agents to produce supported catalysts for olefin oxidation.
    Type: Application
    Filed: December 6, 2007
    Publication date: January 28, 2010
    Applicant: WACKER CHEMIE AG
    Inventors: Roland Heidenreich, Hans-Jurgen Eberle, Johann Weis
  • Publication number: 20100009844
    Abstract: Processes for purifying silicon tetrafluoride source gas by subjecting the source gas to one or more purification processes including: contacting the silicon tetrafluoride source gas with an ion exchange resin to remove acidic contaminants, contacting the silicon tetrafluoride source gas with a catalyst to remove carbon monoxide, by removal of carbon dioxide by use of an absorption liquid, and by removal of inert compounds by cryogenic distillation; catalysts suitable for removal of carbon monoxide from silicon tetrafluoride source gas and processes for producing such catalysts.
    Type: Application
    Filed: September 21, 2009
    Publication date: January 14, 2010
    Applicant: MEMC ELECTRONIC MATERIALS, INC.
    Inventors: Vithal Revankar, Jameel Ibrahim
  • Publication number: 20090325791
    Abstract: A method for obtaining an olefin is disclosed, the method comprising subjecting a paraffin to dehydrogenation in the absence of oxygen and in the presence of a catalyst comprising a crystalline substrate, to obtain an olefin. The catalyst includes an inert stabilizing agent for maintaining the catalyst crystal structure. The catalyst may be regenerated by being subjected, in air, to a temperature between about 550° C. and about 750° C., for a period of time between about 15 minutes and about 4 hours.
    Type: Application
    Filed: June 22, 2009
    Publication date: December 31, 2009
    Inventors: Wei Pan, Stephen M. Casey, Bryan K. Glover, Feng Xu
  • Publication number: 20090324468
    Abstract: The present invention pertains to catalyst systems for nitrogen oxide, carbon monoxide, hydrocarbon, and sulfur reactions that are free or substantially free of platinum group metals. The catalyst system of the present invention comprise a substrate and a washcoat, wherein the washcoat comprises at least one oxide solid, wherein the oxide solid comprises one or more selected from the group consisting of a carrier material oxide, a catalyst, and mixtures thereof. The catalyst system may optionally have an overcoat, wherein the overcoat comprises at least one oxide solid, wherein the oxide solid comprises one or more selected from the group consisting of a carrier material oxide, a catalyst, and mixtures thereof. The catalyst comprises one or more selected from the group consisting of a ZPGM transition metal catalyst, a mixed metal oxide catalyst, a zeolite catalysts, or mixtures thereof.
    Type: Application
    Filed: June 27, 2008
    Publication date: December 31, 2009
    Inventors: Stephen J. Golden, Randal Hatfield, Jason Pless, Johnny Ngo, Mann Sakbodin
  • Patent number: 7638459
    Abstract: A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.
    Type: Grant
    Filed: May 25, 2005
    Date of Patent: December 29, 2009
    Assignee: UOP LLC
    Inventors: Dean E. Rende, James E. Rekoske, Jeffery C. Bricker, Jeffrey L. Boike, Masao Takayama, Kouji Hara, Nobuyuki Aoi
  • Patent number: 7638460
    Abstract: An exhaust gas purifying catalyst of the present invention has a substrate, and a catalyst layer formed on an inner wall of the substrate and composed of at least a single layer. The catalyst layer contains a carrier supporting noble metal. Further, a maximum height of profile of a surface of a top layer in the catalyst layer is not less than 2 ?m and not more than 50 ?m, and the top layer contains the carrier supporting noble metal.
    Type: Grant
    Filed: October 26, 2006
    Date of Patent: December 29, 2009
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Masanori Nakamura, Katsuo Suga, Kiyoshi Miyazaki, Jun Ikezawa
  • Publication number: 20090317308
    Abstract: Catalysts are formulated to resemble a direct ammonia/air fuel cell at short circuit at the nanoscale level to convert ammonia in aqueous solution directly and spontaneously to nitrogen at near or above ambient temperature. The catalyst particle contains a type-A catalyst subparticles for ammonia oxidation to nitrogen, and a type-C catalyst subparticles for oxygen reduction, with the type-A and type-C catalyst subparticles electrically shorted. Advantages realized at the nanoscale level are enhanced conductances for electrons and hydroxyl anions between the neighboring type-A and type-C catalyst subparticles. With the catalysts packed and confined in a catalyst bed in a chemical reactor, the direct conversion of ammonia in an aqueous phase to nitrogen can be carried out continuously for ammonia removal from a water stream in a compact package, and without the high cost arising from constructing and maintaining a bulk electrochemical device, and without the step of exacting the ammonia into gas phase.
    Type: Application
    Filed: June 18, 2009
    Publication date: December 24, 2009
    Inventor: Xiaoming Ren
  • Patent number: 7635461
    Abstract: Composite combustion catalyst particles are described and disclosed. A metal core of a combustible metal can be coated with a metal oxide coating. Additionally, a catalyst coating can at least partially surround the metal oxide coating to form a composite catalyst particle. The composite catalyst particles can be dispersed in a variety of fuels such as propulsion fuels and the like to form an enhanced fuel. During initial stages of combustion, the catalyst coating acts to increase combustion of the fuel. As combustion proceeds, the metal core heats sufficiently to disturb the metal oxide coating. The metal core then combusts in highly exothermic reactions with an oxidizer and the catalyst coating to provide improved energy densities to the enhanced fuel.
    Type: Grant
    Filed: June 7, 2004
    Date of Patent: December 22, 2009
    Assignee: University of Utah Research Foundation
    Inventor: Scott L. Anderson
  • Patent number: 7632778
    Abstract: An apparatus for producing hydrogen, which comprises: a. a heated steam reforming stage (1) with a reforming catalyst to convert gaseous or vaporizable hydrocarbons and water into hydrogen, carbon monoxide and further reformer products; b. at least one stage downstream of the steam reforming stage for the catalytic conversion of the mixture of hydrogen, carbon monoxide and excess steam leaving the steam reforming stage (shift stage) (2); and c. a fine purification stage (3) downstream of the shift stage(s) for the catalytic lowering of the residual carbon monoxide content of the conversion products by selective methanization, is described. In the apparatus, the shift stage (2) and the fine purification stage (3) are configured as a unitary hollow body (exothermic catalyst stage).
    Type: Grant
    Filed: January 17, 2005
    Date of Patent: December 15, 2009
    Assignee: Süd-Chemie AG
    Inventors: Klaus Wanninger, Peter Britz, Nicolas Zartenar
  • Publication number: 20090305872
    Abstract: Fluid catalytic cracking process comprising the steps of (a) preparing a physical 5 mixture comprising (i) aluminium trihydrate and/or flash-calcined aluminium trihydrate and (ii) a divalent metal oxide, hydroxide, carbonate, or hydroxycarbonate, (b) shaping the physical mixture of step a) to form fluidisable particles, and (c) adding the fluidisable particles obtained from step b) or step c) to a fluid catalytic cracking unit. In this FCC process, active sites of the catalyst composition are formed in-situ, i.e. in the FCC unit, without requiring peptisation, aging, or calcination steps prior to the addition of the composition to the hydrocarbon conversion unit.
    Type: Application
    Filed: November 19, 2005
    Publication date: December 10, 2009
    Applicant: ALBEMARLE NETHERLANDS BV
    Inventors: Dennis Stamires, Paul O'Connor
  • Patent number: 7628968
    Abstract: The present invention is directed to high activity titanium oxide DeNOx catalysts. In preferred embodinents, by depositing vanadium oxide on a titania supported metal oxide such as tungsten oxide, an improved catalyst may be generated. This catalyst may be used in the treatment of exhaust from sources such as automobiles and industrial plants.
    Type: Grant
    Filed: May 23, 2008
    Date of Patent: December 8, 2009
    Assignee: Millenium Inorganic Chemicals, Inc.
    Inventors: Steven M Augustine, Guoyi Fu
  • Patent number: 7625840
    Abstract: A nanoporous catalytic membrane which displays several unique features including pores which can go through the entire thickness of the membrane. The membrane has a higher catalytic and product selectivity than conventional catalysts. Anodic aluminum oxide (AAO) membranes serve as the catalyst substrate. This substrate is then subjected to Atomic Layer Deposition (ALD), which allows the controlled narrowing of the pores from 40 nm to 10 nm in the substrate by deposition of a preparatory material. Subsequent deposition of a catalytic layer on the inner surfaces of the pores reduces pore sizes to less than 10 nm and allows for a higher degree of reaction selectivity. The small pore sizes allow control over which molecules enter the pores, and the flow-through feature can allow for partial oxidation of reactant species as opposed to complete oxidation. A nanoporous separation membrane, produced by ALD is also provided for use in gaseous and liquid separations.
    Type: Grant
    Filed: September 14, 2004
    Date of Patent: December 1, 2009
    Assignee: UChicago Argonne, LLC.
    Inventors: Michael J. Pellin, John N. Hryn, Jeffrey W. Elam
  • Patent number: 7625836
    Abstract: To provide a heat-resistant oxide which is excellent in heat resistance and durability at high temperature and has high activity, a heat-resistant oxide which has an oxide crystal structure and in which a rate of a solid solution of a noble metal in the oxide crystal structure is 50% or more is obtained by heat-treating (secondarily baking) a precursor composition comprising zirconia, at least one coordinative element selected from the group consisting of rare earth elements, alkaline earth elements, aluminum and silicon, and at least one noble metal selected from the group consisting of platinum, rhodium and palladium at 650° C. or higher.
    Type: Grant
    Filed: December 13, 2005
    Date of Patent: December 1, 2009
    Assignees: Cataler Corporation, Daihatsu Motor Co., Ltd.
    Inventors: Satoshi Matsueda, Mareo Kimura, Naoto Miyoshi, Yoshinori Ishii, Hirohisa Tanaka, Isao Tan, Mari Uenishi, Masashi Taniguchi
  • Patent number: 7622419
    Abstract: To provide a filter catalyst in which the closure of ventilation holes by a catalytic layer is inhibited. A filter catalyst of the present invention is characterized in that it has pores of 1-20 ?m in a porosity of 11% or more. The filter catalyst of the present invention has an effect of being capable of inhibiting the rise of pressure loss when sufficient particulates deposit.
    Type: Grant
    Filed: February 10, 2005
    Date of Patent: November 24, 2009
    Assignees: Cataler Corporation, Toyota Jidosha Kabushiki Kaisha
    Inventors: Makoto Tsuji, Daisuke Oki, Seiji Okawara
  • Patent number: 7618919
    Abstract: A method of producing a catalyst support comprising a substrate, and coating formed on the surface of the substrate and including powder of a first metal oxide of at least one member selected from the group consisting of alumina, zirconia, titania, iron oxides, oxides of rare earth elements, alkali metal oxides and alkali earth metal oxides, wherein the coating is obtained by heat treating the substrate after applied with a coating composition obtained by mixing the first metal oxide powder together with a fluid raw material composition containing raw material of a second metal oxide of at least one member selected from the group consisting of alumina, zirconia, titania, iron oxides, oxides of rare earth elements, alkali metal oxides and alkali earth metal oxides, at a shear rate of 1000 sec?1 or higher.
    Type: Grant
    Filed: January 30, 2006
    Date of Patent: November 17, 2009
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Takashi Shimazu, Ryusuke Tsuji, Hideo Sobukawa
  • Patent number: 7615512
    Abstract: The invention relates to a titanium dioxide-based photocatalyst containing carbon that is highly photoactive in visible light (vlp-TiO2) and to a method of manufacture. The vlp-TiO2 is manufactured by mixing a fine grained titanium compount (BET?50 m2/g) with an organic carbon compound and subsequent thermal treatment at temperatures up to 350° C. The carbon content amounts to 0.05 to 4% by weight, preferably 0.4 to 0.8% by weight. The product is characterized by an ESR spectrum which displays only one significant signal in the g value range from 1.97 to 2.05 at g about 2.003. The inventive photocatalyst can be used for to degrade contaminants and pollutants in liquids and gases.
    Type: Grant
    Filed: April 1, 2005
    Date of Patent: November 10, 2009
    Assignee: Kronos International Inc
    Inventors: Jürgen Orth-Gerber, Horst Kisch
  • Publication number: 20090275463
    Abstract: A method for making a catalyst includes providing a sol that sol includes a catalyst and a catalyst substrate; drying the sol via freeze-drying, spray drying, freeze granulation, or supercritical fluid drying to form a powder; mixing the powder with a solvent to form a slurry; and washcoating the slurry onto a catalyst support. Another method for making a catalyst includes providing a sol, wherein the sol includes a catalyst substrate; drying the sol via freeze-drying, spray drying, freeze granulation, or supercritical fluid drying to form a powder; mixing the powder with a solvent to form a slurry; washcoating the slurry onto a catalyst support; and depositing a catalyst onto the catalyst substrate.
    Type: Application
    Filed: May 1, 2008
    Publication date: November 5, 2009
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Hrishikesh Keshavan, Robert Joseph Lyons, Larry Neil Lewis, Dan Hancu
  • Publication number: 20090272943
    Abstract: A catalytic composition comprising a catalytically active metal and a solid support, characterized in that said catalytically active metal is included into the core structure of said solid support, and said solid support is a refractory and ionic conductive oxide, process for their preparation and its use as a catalyst in synthesis gas production.
    Type: Application
    Filed: May 8, 2009
    Publication date: November 5, 2009
    Applicant: L Air Liquide Societe Anonyme Pour L Etude Et L Exploitation Des Procedes Georges Claude
    Inventors: Thierry Chartier, Cédric Delbos, Fabrice Rossignol, Pascal Del-Gallo, Daniel Gary, Nicolas Richet
  • Patent number: 7612015
    Abstract: A photocatalyst layer (TiO2) is formed on the surface of a substrate (glass plate) through the intermediary of a monoclinic undercoat layer (ZrO2), and no dead layer is substantially present between the photocatalyst layer and the undercoat layer. Also, by providing a peel preventing layer between the substrate and the undercoat layer, it is possible to eliminate film peeling between the photocatalyst layer and the substrate, defects and discoloration. A metal element may be doped in the photocatalyst layer, and it is preferable that the metal element is at least one of Sn, Zn, Mo and Fe. The phrase “no dead layer is substantially present” means that the thickness of the dead layer is 20 nm or less. The thickness of the photocatalyst layer is preferably from 1 nm to 1,000 nm, more preferably from 1 nm to 500 nm.
    Type: Grant
    Filed: December 24, 2002
    Date of Patent: November 3, 2009
    Assignee: Nippon Sheet Glass Company, Limited
    Inventors: Toshiaki Anzaki, Yoshifumi Kijima, Kenji Mori
  • Patent number: 7608561
    Abstract: An exhaust gas purifying catalyst comprising: a honeycomb-like substrate disposed in an exhaust passage for an engine; and a catalytic layer formed on a cell wall of said substrate, said catalytic layer including a mixed oxide which contains Ce (cerium) and Zr (zirconium), and retains a catalytic noble metal in such a manner that said noble metal atoms are located at crystal lattice points or between the lattice points of the mixed oxide, wherein said mixed oxide includes a first mixed oxide containing CeO2 in a mass greater than that of ZrO2, and a second mixed oxide containing ZrO2 in a mass greater than that of CeO2.
    Type: Grant
    Filed: October 12, 2006
    Date of Patent: October 27, 2009
    Assignee: Mazda Motor Corporation
    Inventors: Seiji Miyoshi, Hiroshi Yamada, Koji Minoshima, Akihide Takami, Hideharu Iwakuni
  • Patent number: 7608562
    Abstract: A method of producing a photocatalyst according to the invention comprises forming an amorphous titanium oxide and heat-treating it in an atmosphere containing oxygen, whereby a photocatalyst having a good photocatalysis can be obtained. In particular, the amorphous titanium oxide is obtained by using the reactive sputtering method and via deposition at a low temperature and at a high film formation rate. This apparatus can be provided with cooling means to allow enhancement of the throughput of the film formation process.
    Type: Grant
    Filed: November 20, 2008
    Date of Patent: October 27, 2009
    Assignee: Shibaura Mechatronics Corporation
    Inventors: Junji Hiraoka, Minoru Takashio, Tetsuya Fukushima, Daisuke Noguchi, Yoshio Kawamata
  • Patent number: 7605108
    Abstract: A catalyst which suppresses aggregation of metal particles and which has superior heat resistance. In the catalyst, metal particles are supported by a surface of a carrier while being partially embedded therein.
    Type: Grant
    Filed: July 5, 2005
    Date of Patent: October 20, 2009
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Hironori Wakamatsu, Hirofumi Yasuda, Kazuyuki Shiratori, Masanori Nakamura, Katsuo Suga, Toru Sekiba
  • Patent number: 7601670
    Abstract: A method of producing catalyst powder of the present invention has a step of precipitating any one of a noble metal particle (5) and a transition metal particle (10) in a reversed micelle (1); a step of precipitating, in the reversed micelle (1) in which any one of the noble metal particle (5) and the transition metal particle (10) is precipitated, a porous support material (7) which supports the noble metal particle (5) and the transition metal particle (10); and a step of precipitating the other of the noble metal particle (5) and the transition metal particle (10) in the reversed micelle (1) in which any one of the noble metal particle (5).
    Type: Grant
    Filed: February 8, 2005
    Date of Patent: October 13, 2009
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Hirofumi Yasuda, Katsuo Suga, Masanori Nakamura, Hironori Wakamatsu, Kazuyuki Shiratori, Toru Sekiba
  • Patent number: 7601671
    Abstract: A method for preparing an exhaust gas catalyst includes preparing a washcoat comprising a catalytically effective amount of at least one catalytically active metal disposed upon an oxide support; disposing the catalytically active metal-oxide support washcoat upon a catalyst substrate; drying the washcoated catalyst substrate using microwave energy to affix the precious metals to the oxide support; and conventionally calcining the dried washcoated catalyst substrate. The catalysts comprising a substrate having dispersed thereon an inorganic oxide washcoat, the washcoat having been affixed to the substrate by microwave drying, exhibit high exhaust gas purifying performance and long durability. The catalysts thus produced further provide a long in-service lifetime for reforming organic fuel species into hydrogen, carbon monoxide and light hydrocarbons used in the nitrogen oxides reduction process.
    Type: Grant
    Filed: October 28, 2004
    Date of Patent: October 13, 2009
    Assignee: Umicore AG & Co. KG
    Inventor: William J. LaBarge
  • Patent number: 7598204
    Abstract: A reagent suitable for use as a catalyst comprises a first metal species substrate having a second reduced metal species coated thereon, the second reduced metal species being less electropositive than the first metal. Methods of manufacture are also provided.
    Type: Grant
    Filed: September 19, 2005
    Date of Patent: October 6, 2009
    Assignee: General Motors Corporation
    Inventors: Andrew M. Mance, Tao Xie, Belabbes Merzougui
  • Patent number: 7598205
    Abstract: In a three-way catalyst for purifying exhaust gases from internal combustion engines, scattering of bismuth components can be suppressed by employing a Bi—Ti composite oxide at a predetermined ratio. Accordingly, the effect of suppressing hydrogen sulfide emissions can be retained for a long time. This catalyst comprises a support substrate, and a catalyst layer formed on the support substrate and including a noble metal, a porous oxide, and a Bi—Ti composite oxide, and satisfies 0.3?R?1.5, where R is the molar ratio of the Bi content to the Ti content per unit volume of the support substrate.
    Type: Grant
    Filed: January 27, 2006
    Date of Patent: October 6, 2009
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Hiromasa Suzuki
  • Publication number: 20090239739
    Abstract: A catalyst 1 has a heat-resistant support 2 selected from among Al2O3, SiO2, ZrO2, and TiO2, and a first metal 4 supported on an outer surface of the support 2, and included by an inclusion material 3 containing a component of the support 2.
    Type: Application
    Filed: December 5, 2005
    Publication date: September 24, 2009
    Inventors: Hirofumi Yasuda, Katsuo Suga, Makoto Aoyama, Toshiharu Miyamura
  • Publication number: 20090238733
    Abstract: A honeycomb structure includes at least one honeycomb member including inorganic fibers and having walls extending along a longitudinal direction to define cells. A catalyst is provided on the wall in an amount of at least about 100 g and at most about 400 g per liter of volume of the honeycomb structure. The honeycomb member has a pore distribution measured using mercury porosimetry in which a pore distribution curve has a first peak in a range from about 0.005 ?m to about 0.03 ?m of a pore diameter, a second peak in a range from about 1 ?m to about 15 ?m of the pore diameter, and a third peak in a range from about 15 ?m to about 50 ?m of the pore diameter, where the curve is drawn by plotting the pore diameter (?m) on an X-axis and a log differential pore volume (mL/g) on a Y-axis.
    Type: Application
    Filed: December 30, 2008
    Publication date: September 24, 2009
    Applicant: IBIDEN CO., LTD.
    Inventors: Kazushige OHNO, Kazutake Ogyu, Yusuke Kondo
  • Patent number: 7592290
    Abstract: The invention relates to supported catalysts and a process for the production of these catalysts. These supported catalysts may be used in various reactions such as reforming reactions (e.g. steam methane reforming (SMR) reactions and autothermal reforming (ATR) reactions). In one aspect of the invention, the supported catalyst comprises a transition metal oxide; optionally a rare-earth metal oxide; and a transition metal aluminate.
    Type: Grant
    Filed: April 7, 2005
    Date of Patent: September 22, 2009
    Assignee: Sulzer Metco(Canada) Inc.
    Inventors: Syed Tajammul Hussain, Eugene Stelmack
  • Publication number: 20090232728
    Abstract: A water gas shift catalyst for use at temperatures above about 450° C. up to about 900° C. or so comprising rhenium deposited on a support, preferably without a precious metal, wherein the support is prepared from a high surface area material, such as a mixed metal oxide, particularly a mixture of zirconia and ceria, to which may be added one or more of a high surface area transitional alumina, an alkali or alkaline earth metal dopant and/or an additional dopant selected from Ga, Nd, Pr, W, Ge, Fe, oxides thereof and mixtures thereof.
    Type: Application
    Filed: March 14, 2008
    Publication date: September 17, 2009
    Applicant: Sud-Chemie Inc.
    Inventors: Jon P. Wagner, Michael W. Balakos, Chandra Ratnasamy
  • Patent number: 7585811
    Abstract: A method of producing catalyst powder of the present invention has a step of precipitating a noble metal particle (2) and a porous carrier (1) in a reversed micelle substantially simultaneously; and a step of precipitating a transition metal particle (3) in the reversed micelle. By this method, it is possible to obtain catalyst powder which restricts an aggregation of the noble metal particles even at a high temperature and is excellent in a catalytic activity.
    Type: Grant
    Filed: February 10, 2005
    Date of Patent: September 8, 2009
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Masanori Nakamura, Katsuo Suga, Toru Sekiba, Hironori Wakamatsu, Kazuyuki Shiratori, Hirofumi Yasuda
  • Patent number: 7585477
    Abstract: The invention provides a catalyst for catalytic reduction of nitrogen oxides contained in exhaust gases wherein fuel is supplied and subjected to combustion under periodic rich/lean conditions and the resulting exhaust gases are brought into contact therewith, which catalyst comprises: (A) a catalyst component A comprising (c) ceria or (d) praseodymium oxide or (e) an oxide and/or a composite oxide of at least two elements selected from the group consisting of cerium, zirconium, praseodymium, neodymium, terbium, samarium, gadolinium and lanthanum; (B) a catalyst component B comprising (d) a noble metal catalyst component selected from the group consisting of platinum, rhodium, palladium and oxides thereof and (e) a carrier; and (C) a catalyst component C comprising (f) a solid acid, and (g) a solid acid supporting an oxide of at least one element selected from the group consisting of vanadium, tungsten, molybdenum, copper, iron, cobalt, nickel and manganese.
    Type: Grant
    Filed: November 8, 2004
    Date of Patent: September 8, 2009
    Assignee: Honda Motor Co., Ltd.
    Inventors: Tadao Nakatsuji, Norio Suzuki, Hiroshi Ohno, Naohiro Sato, Tomoko Morita, Katsuji Wada
  • Publication number: 20090217922
    Abstract: A catalyst for cellulose hydrolysis and/or the reduction of hydrolysis products, in which a transition metal of group 8 to 11 is supported on a solid support. A method of producing sugar alcohols comprising: hydrolyzing cellulose in the presence of the catalyst in a hydrogen-containing atmosphere with pressurization; and reducing the hydrolysis product of cellulose. Provided are a catalyst for use in the production of sugar alcohols by the hydrolysis and hydrogenation of cellulose that affords easy separation of catalyst and product, and that does not require pH adjustment, acid or alkali neutralization, or activation of the catalyst during reuse, and a method of producing sugar alcohols from cellulose employing this catalyst.
    Type: Application
    Filed: March 1, 2007
    Publication date: September 3, 2009
    Inventors: Atsushi Fukuoka, Paresh Dhepe
  • Patent number: 7582586
    Abstract: There is disclosed a process for producing a catalyst. The process includes the steps of: a) combining a dendrimer polymer and metal salt in solution forming a metal ion complex; b) exposing the metal ion complex to a reducing environment forming a dendrimer metal nanocomposite; c) depositing the dendrimer metal nanocomposite onto a catalyst support material; d) removing a solvent from the dendrimer metal nanocomposite forming metal clusters; and e) removing the dendrimer polymer forming a catalyst. Additionally, there is disclosed a catalyst having a catalytic metal deposited on a substrate. The catalytic metal is formed in clusters having a size of from 2 to 150 atoms. In another aspect, the clusters may have a spacing of from 2 to 100 nanometers between adjacent metal clusters. Further, in another aspect, the metal clusters which comprise the catalyst have a size distribution in which 70% of the clusters are within 0.6 nm of the average diameter and 99% of the particles are within 1.
    Type: Grant
    Filed: August 24, 2006
    Date of Patent: September 1, 2009
    Assignees: Toyota Motor Corporation, Toyotal Motor Engineering & Manufacturing North America, Inc.
    Inventors: Paul T. Fanson, Hirohito Hirata, Michael D. Amiridis, Christopher T. Williams, David S. Deutsch, Attilio Siani, Shinichi Matsumoto
  • Patent number: 7582276
    Abstract: The invention relates to nanoscale rutile or oxide powder that is obtained by producing amorphous TiO2 by mixing an alcoholic solution with a titanium alcoholate and with an aluminum alcohalate and adding water and acid. The amorphous, aluminum-containing TiO2 is isolated by removing the solvent, and is redispersed in water in the presence of a tin salt. Thermal or hydrothermal post-processing yields rutile or oxide that can be redispersed to primary particle size. The n-rutile or the obtained oxide having a primary particle size ranging between 5 and 20 nm can be incorporated into all organic matrices so that they remain transparent. Photocatalytic activity is suppressed by lattice doping with trivalent ions. If the amorphous precursor is redispersed in alcohol, or not isolated, but immediately crystallized, an anatase is obtained that can be redispersed to primary particle size.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: September 1, 2009
    Assignee: ITN Nanovation AG
    Inventor: Ralph Nonninger
  • Patent number: 7582588
    Abstract: A method of manufacturing a catalyst, a catalyst precursor, or a catalyst support comprising: (a) mixing a refractory metal oxide or precursor thereof with a liquid to form a paste; (b) adding said paste to an extruder, the extruder having a die plate comprising one or more dies, each die having a plurality of apertures, the outlet of each aperture having a cross sectional area of 6 mm2 or less; (c) extruding the paste through the apertures to form catalyst support extrudates; wherein the inlet of the apertures has a greater cross sectional area than the outlet of said apertures; and wherein for at least one die the combined cross sectional area of all apertures at the inlet relative to the total cross sectional area of the die at the inlet is higher than 50%.
    Type: Grant
    Filed: October 25, 2007
    Date of Patent: September 1, 2009
    Assignee: Shell Oil Company
    Inventors: Peter John Van Den Brink, Ronald Jan Dogterom, Carolus Matthias Anna Maria Mesters
  • Publication number: 20090215613
    Abstract: The present invention is directed to yttrium compositions and methods for making such metal oxide compositions, specifically, metal oxide compositions having high surface area, high metal/metal oxide content, and/or thermal stability with inexpensive and easy to handle materials.
    Type: Application
    Filed: November 1, 2007
    Publication date: August 27, 2009
    Applicant: Symyx Technologies, Inc.
    Inventor: Alfred Hagemeyer
  • Patent number: 7576035
    Abstract: A pillar-shaped honeycomb structure has a plurality of cells longitudinally placed in parallel with one another with a wall portion therebetween, wherein the honeycomb structure mainly includes inorganic fibers which form the honeycomb structure without lamination interfaces.
    Type: Grant
    Filed: April 7, 2008
    Date of Patent: August 18, 2009
    Assignee: Ibiden Co., Ltd.
    Inventors: Kazushige Ohno, Tomokazu Oya
  • Patent number: 7576033
    Abstract: An alkaline solution of an alkali-soluble compound, which is selected from the group consisting of an alkali-soluble silicon compound and an alkali-soluble germanium compound, is prepared. Also, a water-soluble bismuth compound solution is prepared. The alkaline solution and the water-soluble bismuth compound solution are subjected to mixing processing with agitation at a temperature of at least 80° C. by use of a shearing type agitator and are thereby allowed to react with each other. Thus Bi12MO20 particles, in which M represents an element selected from the group consisting of Si and Ge, are produced. The produced Bi12MO20 particles have small particle diameters and uniform composition.
    Type: Grant
    Filed: March 9, 2006
    Date of Patent: August 18, 2009
    Assignee: FUJIFILM Corporation
    Inventor: Shigeru Nakamura
  • Patent number: 7572543
    Abstract: A supported catalyst includes an oxide carrier, catalyst particles supported on the oxide carrier, and catalyst layers which locate among the catalyst particles, with interface portions among the oxide carrier, the catalyst particles and the catalyst layers. The catalyst layers have a melting point lower than 1,500° C. and contain an oxide or a composite oxide which includes at least one element selected from the group consisting of Mo, W, Sn and Ru.
    Type: Grant
    Filed: August 30, 2006
    Date of Patent: August 11, 2009
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Wu Mei, Jun Tamura, Yoshihiko Nakano
  • Patent number: 7572427
    Abstract: The present invention is related to single and/or multiple-wall carbon nanotubes which may contain interstitial metals obtainable by a preparation process. The process includes a catalytic step using a catalytic system which includes a catalyst and a support. The support comprises hydroxides and/or carbonates or mixtures thereof with or without metal oxides. The present invention is also related to carbon fibers obtainable by said preparation process. The present invention also pertains in particular to said catalytic system and to said preparation process. Another aspect concerns the use of the nanotubes and of the catalytic system according to the invention.
    Type: Grant
    Filed: July 3, 2002
    Date of Patent: August 11, 2009
    Assignee: Facultes Universitaires Notre-Dame De La Paix
    Inventors: Janos B. Nagy, Narasimaiah Nagaraju, Isabelle Willems, Antonio Fonseca
  • Patent number: 7569511
    Abstract: An alcohol steam reforming catalyst for generating hydrogen contains palladium, yttrium, and at least one of cerium and a metal oxide. The catalyst displays both an improved alcohol conversion rate and improved carbon dioxide selectivity. Methods of making and using the alcohol steam reforming catalyst are described.
    Type: Grant
    Filed: May 5, 2006
    Date of Patent: August 4, 2009
    Assignee: BASF Catalysts LLC
    Inventors: Christopher R. Castellano, Ye Liu, Ahmad Moini, Gerald Stephen Koermer, Robert Joseph Farrauto