Abstract: (1) An adsorbent comprising a styrene polymer, which is producing by dissolving a substantially syndiotactic styrene polymer in an organic compound having an affinity for the polymer, followed by shaping it, and thereafter removing the organic compound from the shaped article. (2) For producing the adsorbent (1), the polymer solution is melt-cast into the shaped article. (3) For producing the adsorbent (1) or (2), the organic compound is removed from the shaped article through evaporation under reduced pressure. The adsorbent provided herein is effective for selectively and efficiently adsorbing an organic compound in gases or liquids.

Abstract: A storage medium for gas molecules has a nanowire core and a number of organic molecules attached to the exterior surface of the nanowire. The organic molecules attached to the exterior of the nanowire are adapted to releasably hold gas molecules. Methods for making and using the invention, including the use of a silicon nanowire, are disclosed.

Abstract: The present invention relates to a solid and method useful in separating chemical components in a complex mixture when at least one of the chemical components of the mixture is capable of being selectively adsorbed. The solid of the present invention comprises an inorganic substance and moieties (R10) located on at least one surface of the inorganic substance, wherein said inorganic substance is an inorganic oxide and the surface moiety is selected from the group consisting of —CH2OH, —CH(OH)2, —CH(OH)CH3, —CH2CH2OH, —C(OH)2CH3, —CH2CH(OH)2 and —CH(OH)CH2(OH). Binding moiety, optionally attached to the inorganic substance via a linker, can also be located on the surface of the solid.

Abstract: A reagent composition for removing a contaminant from a gas. The reagent composition contains (1) a silicate compound; (2) a sequestrant; and optionally a surfactant. The reagent composition may be used in methods to remove contaminants from gases. The reagent composition in combination with micro/miniature mechanical structures provides for reduced back pressure and reduced volume of the reaction chamber.

Abstract: A separating agent that serves as an optical resolution agent is composed of a novel, useful optically active polymer. The separating agent is obtained through anionic polymerization of a novel maleimide and serves to separate optically active compounds.

Abstract: The invention describes supersuperabsorbent polymers composed of surface-post crosslinked polycarboxypolysaccharides having excellent age-stable absorption properties, even under load, high attrition resistance and biodegradability and their use for absorbing water, aqueous or serous fluids and also blood. Also disclosed is a method of making which is impervious to changes in raw material quality and which provides consistent product quality.

Abstract: The compositions of the present invention comprise one or more palladium bound ligands that are covalently bonded to inorganic or organic solid supports. These palladium bound ligands bonded to solid supports can be used for single heterocyclic amine base separation, or can be used to separate nucleotide chain containing specific sequences from other nucleotides or nucleotide chains. In one aspect of the invention, each ligand present is individually complexed to a single Pd(II) ion. If there are from 2 to 4 ligands present in the composition, then each ligand present must be separated from the other ligands by at least 3 atoms, preferably from 3 to 20 carbon atoms or equivalent spacing.

Abstract: An apparatus and method for removing mercury, and in particular elemental mercury, from a fluid stream by exposing the fluid stream to a polyethersulfone or filter-coated with anion exchange resin, or anion exchange resin-coated surface onto which has been loaded elemental iodine. Elemental iodine is loaded onto the PES or anion exchange resin-coated surface by immersing the PES or anion exchange resin-coated substrate in an iodine/pentane solution, then removing the substrate from the iodine/pentane solution and rinsing in pentane.

Abstract: The invention relates to novel inorganic absorbent composite consisting of an open-pore, solid, inorganic matrix, comprising cucurbiturils of general formula (I), which are chemically linked in the matrix. Said cucurbiturils form a macrocycle having a cage structure, consisting of n repeating units, wherein n is a whole number 5, 6, 7 or 8, R represents hydrogen or C1-C5 alkyl, and X represents O, S or N. X and R can be the same or different. Said composites are produced by reacting cucurbituril with an inorganic matrix-forming agent, such as silica gel, at 15 to 90° C. in a liquid medium. The inventive composites can be used as absorption materials and catalyst supports.

Abstract: An approach for beneficially incorporating both a solid organic impregnant and a fluid impregnant into filter media particles without the presence or addition of one unduly affecting the performance of the other. The present invention achieves impregnation by combining sublimation and non-bulk absorption techniques. These techniques may be carried out in sequential, simultaneous, overlapping, and/or alternating fashion, or the like. The invention is especially suitable when the filter media particles already contain or are to contain one or more other impregnants, whose function or presence might be adversely affected when conventional methods are used to add the solid organic and fluid materials.

Abstract: A channelized sorbent material comprises porous sorbent particles characterized by an average pore diameter. Each sorbent particle has at least one interior channel of an average transverse dimension (i.e. transverse diameter) that is at least ten times larger than the average pore diameter of the porous sorbent particle. The interior channel may constitute a single cylindrical through-bore in the sorbent particle, or alternatively, an array of intersecting or non-intersecting channels. The porous sorbent particles preferably comprise bead activated carbon particles. Such channelized sorbent material is particular useful as sorbent media in an adsorption-desorption apparatus for storage and dispensing of a sorbable fluid.

Abstract: The present invention provides compositions for the separation of metals or biomolecules such as polypeptides, nucleic acids, or endotoxins using modified solid supports.

Abstract: An approach for beneficially incorporating both a solid organic impregnant and a fluid impregnant into filter media particles without the presence or addition of one unduly affecting the performance of the other. The present invention achieves impregnation by combining sublimation and non-bulk absorption techniques. These techniques may be carried out in sequential, simultaneous, overlapping, and/or alternating fashion, or the like. The invention is especially suitable when the filter media particles already contain or are to contain one or more other impregnants, whose function or presence might be adversely affected when conventional methods are used to add the solid organic and fluid materials.

Abstract: For certain mixed mode resins having anionic character, a ligand is joined to a solid support via a linkage that includes a mercapto-, ether- or amino-containing moiety. A suitable ligand comprises an aromatic group, a heteroaromatic group, or a heterocyclic group, optionally fused, that is sulfate-, sulfonate-, phosphonate- or phosphate-substituted and that is linked to such a moiety. These resins possess an anionic character under conditions prescribed for their use. Separation of a biological substance, such as a peptide or protein, can be accomplished with a resin of this type via a change in the pH of eluants, thereby effecting adsorption and desorption.

Abstract: Packing materials useful in applications such as liquid chromatography and solid phase extraction, as well as processes for producing such packing materials are described. The packing materials are based on chemically modified diamond powders. The surfaces of the diamond powders are attached with hydrocarbon, amino, carboxylic acid, or sulfonic acid groups through C—C, C—N, or C—S single bonds. The residual groups can be solely hydroxyl groups or solely hydrogen atoms. The stability of the packing materials allows regeneration of columns at pH>14 for protein separation. With hydrogen atoms as the residual groups for reverse phase diamond packings, the non-specific interaction associated with silica, polymeric, or graphitic packings can be largely eliminated. With hydroxyl groups as the residual groups for ion exchangers based on diamond powders, the non-specific interaction associated with hydrophobic sites can be largely eliminated.

Abstract: The invention concerns a method for preparing organic-inorganic hybrid materials with controlled porosity and functionality, comprising hydrolysis and condensation polymerisation of at least a compound of formula (I): Z—R1—Si(OR)(OR′)(OR″), wherein: Z represents either an atom selected among chlorine, bromine or iodine atoms, or an amino or phosphino group; R, R′ and R″, independently of one another, represent an alkyl radical comprising on to four carbon atoms; R1 represents a divalent radical derived from an aliphatic hydrocarbon chain comprising 1 to 30 carbon atoms, wherein are optionally interspersed one or several arylene; —O—, —S—, —O—C(═O), —N(R6)—C(═O)— or N(R6), with at least an alkaline or alkaline-earth silicate of (II) in a mol ratio (I)/(II)=1/9 in the presence of at least a non-ionic surfactant in micellar concentration, to form a mesoporous silica represented by formula (III): Z—R1&

Abstract: The objectives of this invention are to provide a filler for separating optical isomers, capable of efficiently carrying out optical resolution of optical isomer mixtures, and to provide a process for separating optical isomers by a simulated moving bed chromatography utilizing the filler. This invention provides a filler made of a carrier supporting a specific amount of an optically active high molecular weight compound. Separation by the simulated moving bed chromatography using the filler is carried out under the condition that the capacity factors have specific values.

Abstract: This invention relates to filterable composite adsorbents comprising one or more adsorbent components and one or more filtration components, and methods for preparing and using same. More particularly, this invention pertains to filterable composite adsorbents and filterable composite adsorbent products which are suitable for use in filtration applications, and which comprise one or more microparticulate or colloidal adsorbent components selected from the group consisting of silica gel, fumed silica, neutral clay, alkaline clay, zeolite, solid catalyst, alumina, adsorbent polymer, alkaline earth silicate hydrate, and combinations thereof, which bear the property of adsorption, which are intimately bound to one or more functional filtration components selected from the group consisting of biogenic silica (e.g., diatomite, rice hull ash, sponge spicules), natural glass (e.g.

Abstract: Mesostructured and microporous to mesoporous organofunctionalized silica compositions are described. The compositions incorporate the organofunctional group L as part of a LSiO3 unit in the framework of the compositions. In addition the compositions incorporate the organofunctional group R as part of a O3Si—R—siO3 unit in the framework of the compositions. The compositions are useful as molecular sieves, supports for catalysts and numerous other applications requiring an organo group on surfaces of a silica.

Abstract: A new shaped activated carbon and the method of its manufacture are disclosed. The invention resides in the crosslinking of a polymeric cellulose, such as sodium carboxymethylcellulose (CMC), within the carbon bodies after they are shaped, employing the CMC as a binder for the activated carbon. The approach to attain product mechanical strength and water stability by crosslinking rather than high temperature heat treatment is not obvious from the prior art teaching. The crosslinking reaction occurs at temperatures below 270° C. In addition, this new binder technology produces shaped carbon bodies having key properties beyond the best level that has been accomplished with other binders.

Abstract: A process for making a fiber composite involving: (a) providing a natural fiber; (b) providing a matrix material produced by a radical polymerization reaction of: (i) a monomer selected from the group consisting of ring opening products of epoxidized fatty compounds with olefinically unsaturated carboxylic acids, and (ii) a comonomer selected from the group consisting of olefinically unsaturated carboxylic acids; (c) providing a radical initiator; and (d) conducting the radical polymerization reaction of (i) and (ii) in the presence of the natural fiber so that the matrix material envelops the natural fiber, thus producing the fiber composite.

Abstract: An adsorbent for cardiac glycoside contained in body fluid, comprising a compound having a log P value of at least 6 immobilized on a water-insoluble carrier is provided. A process for adsorbing and removing cardiac glycoside contained in body fluid efficiently, which comprises contacting body fluid with this adsorbent for cardiac glycoside is provided.

Abstract: The present invention relates to a bound metal oxide particle comprised of metal oxide and a binder, with the binder preferably being a starch solution. The present invention also relates to a method for forming a bound metal oxide particle, with the preferred method including extruding and pelletizing a metal oxide and binder composition to form pelletized metal oxide particles.

Abstract: A synthetic, semi-crystalline, porous inorganic oxide composition containing a reactive organic silane moiety which on the surface of pore walls. The composition is prepared from a poly(oxyalkylene) based surfactant and a hydrolyzable organic silane. The surfactant is preferably a poly (ethylene) oxide, a poly(propylene) oxide polymer or mixtures thereof. The organic silane is preferably mercaptopropylsilane. The compositions are particularly useful as adsorbents, and catalysts.

Abstract: A modified silica support having a polar phase bound to its surface and suitable for use for chromatographic separations, having the following formula: wherein, m=0-20; n=0-20; p=1-50; X is sulfonyl, carbonyl, carbamoyl, or oxycarbonyl; R1=H, alkyl, substituted alkyl, aryl or substituted aryl groups; R2=alkyl, substituted alkyl, aryl or substituted aryl groups; and R3 and R4 are alkyl, aryl, hydroxyl, or alkoxyl groups or groups including oxygen atoms cross-linked to silicon atoms. Also, a polar silane intermediate to make this support.

Abstract: A matrix including: a) a polymeric base matrix including macropores (pore system 1) and b) an interior material, possibly porous (pore system 2), retained within the macropores. The matrix is characterized in that there is a continuous free volume between the interior material and the pore walls of the macropores. A method for manufacturing a matrix including a base matrix having macropores in which an interior material is located. The method is characterized in including the steps: (I) providing a base matrix having macropores; (ii) filling the macropores with a soluble form of the interior material; (iii) transforming the insoluble from to an insoluble form; (iv) shrinking the insoluble form; and (v) irreversibly stabilizing the material in its shrunken form. The matrix can be used in separation methods, cell culturing, solid phase synthesis of organic molecules, and in catalytic reactions (such as enzyme reactions) and other uses in which porous support matrices are used.

Abstract: The current invention describes organoclay compositions and methods of using them for removing impurities from contaminated liquids. The compositions are formed by contacting an attapulgite, sepiolite, or zeolite clay mineral with an alkylamine base. The method of use involves contacting the organoclay composition with a contaminated liquid, such as oil in water, allowing the organoclay to absorb the contaminants. The organoclay can be in the form of a granular solid for inline filter applications, or it can be a finely divided powder for other applications.

Abstract: The present invention provides an adsorbent, that includes a pulverulent rubber, which contains at least one filler selected from the group including natural filler, synthetic filler, organic filler, inorganic filler, and mixtures thereof. Another embodiment of the invention relates to an article or apparatus selected from the group including a cushion, hose, suction boom, stationary bed column, suspension reactor, and fluidized bed reactor, that contain the above-noted adsorbent. Another embodiment of the invention provides a process, that includes adsorbing at least one organic compound with the above-noted adsorbent. The present invention is a readily usable and effective adsorbent, and has a high capacity, permits an efficient mass transport in the individual adsorbent particles, and has a resistance to fouling by adsorption of higher molecular weight substances or by swelling processes, and is resistant to being wetted by water and to coadsorption of water.

Abstract: A pseudobioaffinity chromatography adsorbent adapted for use in selectively adsorbing immunoglobulins. In one embodiment, the adsorbent includes: (a) a solid support material; and (b) a ligand immobilized on the surface of the solid support material, said ligand being a compound of the formula wherein Y1 is selected from the group consisting of S, SCH3+, O, NH, NCH3, CH2 and CR1R2 wherein at least one of R1 and R2 is not hydrogen; wherein each of Y2, Y3 and Y4 is selected from the group consisting of N, NCH3+, CH, and CR wherein R is not hydrogen; and wherein at least two of Y1, Y2, Y3 and Y4 are neither CH2, CH, CR nor CR1R2.

Abstract: The present invention relates to a cellulosic particle body comprising interconnected cellulosic small particles with small interparticle spaces and to a method of producing said cellulosic particle body which comprises dispersing cellulosic small particles in an alkaline medium and contacting the resulting suspension with a coagulating solution. In this specification, the above technology will be referred to as the first invention.

Abstract: A water insoluble, water swellable absorbent composition exhibiting a free swell absorbency of at least 15 g/g and an Absorbency Change of greater than or equal to 15% upon saturation. The absorbent composition includes both permanent crosslinking points and transitional crosslinking points. The absorbent composition has a high free swell capacity as well as a high absorbency under load.

Abstract: A personal care absorbent article, such as a sanitary pad or napkin, wound dressing, and the like having one or more layers of absorbent material treated with a red blood cell lysing agent and a gelling agent. The effect of combining a lysing agent that thins menses or other blood-containing bodily fluids with a gelling agent that thickens menses or other blood-containing bodily fluids is enhanced agglomeration and increased viscosity of the blood-containing bodily fluids that come in contact with the treated material.

Abstract: A process of manufacturing of a chromatography material comprising the steps of

Abstract: A silica-polyamine based extraction material removes selected transition metal ions from solution in the presence of iron ions. The silica-polyamine base is a reaction product of a polyamine and a covalently anchored trifunctional hydrocarbylsilyl that yields non-crosslinked amino groups to which a pyridine function group is attached. The extraction material is particularly useful in selectively removing copper from low concentration, low pH leach solutions separating copper from ferric iron or chloride ions. The product is a durable, high capacity extraction material that selectively captures copper at high flow rates and releases that copper into highly concentrated solutions.

Abstract: The present invention provides compositions including a mixture containing sulfides and/or polysulfides of ammonium, sodium, potassium, lithium, etc.

Abstract: An adsorbent which desorbs water by being heated and adsorbs water by being chilled, comprising a porous body having a pore volume of not less than 0.2 cm3/g and a pore size from 0.6-1.6 nm. This adsorbent is good for an adsorptive-type refrigeration apparatus, used in an automotive air conditioner, which has an adsorbing core.

Abstract: Solid materials have been developed to remove contaminating metals and organic compounds from aqueous media. The contaminants are removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the metals and the organics leaving a purified aqueous stream. The materials are sol-gel and or sol-gel and granulated activated carbon (GAC) mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards the contaminant(s). The contaminated solid materials can then be disposed of or the contaminant can be removed and the solids recycled.

Abstract: A material for introducing inorganic elements into water, the material including a carrier and a plurality of inorganic compounds that are sparingly soluble in water, wherein the carrier is an organic ion-exchanger having a porous structure in the air-dry state. The organic ion-exchanger reacts with the sparingly soluble compounds such that the sparingly soluble inorganic compounds are contained in pores of the organic ion-exchanger with a ratio of the ion-exchanger to the sparingly soluble inorganic compounds being 35-90:10-65 percent by weight.

Abstract: Compositions and methods for selectively binding specific metal ions, such as Ca2+and Cd2+, contained in a source solution are disclosed and described. This is accomplished by the use of a composition comprised of an EGTA ligand covalently bonded to a particulate solid supports through a hydrophilic spacer. The composition formula of the present invention is SS—A—X—L where SS is a particulate solid support such as silica or a polymeric bead, A is a covalent linkage mechanism, X is a hydrophilic spacer grouping, L is an EGTA ligand with the proviso that when SS is a particulate organic polymer, A—X may be combined as a single covalent linkage.

Abstract: A primary object of the invention is to provide an adsorbent capable of efficiently eliminating lower aldehydes at ordinary temperature for a prolonged period of time and excellent in rate of elimination, heat resistance and safety.

Abstract: An extractant medium for extracting alkaline earth cations from an aqueous acidic sample solution is described as are a method and apparatus for using the same. The separation medium is free of diluent, free-flowing and particulate, and comprises a Crown ether that is a 4,4′(5′)[C4-C8-alkylcyclohexano]18-Crown-6 dispersed on an inert substrate material.

Abstract: Provided is bamboo charcoal-mixed composition 6 having an increased adsorbability in comparison with bamboo charcoal by dispersing at least bamboo charcoal powder 8 and tourmaline powder 10 into binder 14. Also provided is carrier 2 having reodorizing and antibacterial effects by holding bamboo charcoal-mixed composition 6 on base material 4 such as nonwoven fabric and pulp. Bamboo charcoal-mixed composition 6 and carrier 2 are used for various purposes such as food preservation, deodorization, antibacteria and absorption of volatile components included in building materials.

Abstract: Compositions and methods for selectively binding metal ions from source solutions are disclosed. The composition is comprised of a polyamide-containing ligand covalently bonded to a particulate solid support through a hydrophilic spacer having the formula SS—A—X—L. In this formula, SS is a particulate solid support such as silica or a polymeric bead, A is a covalent linkage mechanism, X is a hydrophilic spacer grouping, and L is a polyamide-containing ligand having three or more amide groups and two or more amine nitrogens separated by at least two carbons with the proviso that when SS is a particulate organic polymer, A—X may be combined as a single covalent linkage.

Abstract: Novel polymer-supported quenching reagents of Formula I, P—L—Q  I wherein P is a polymer of low chemical reactivity which is soluble or insoluble; Q is one or more quenching reagents, or an acid or base addition salts thereof, that are capable of selective covalent reaction with unwanted byproducts, or excess reagents; and L is one or more chemically robust linkers that join P and Q; are described, as well as methods for their preparation and methods for their use in the rapid purification of synthetic intermediates and products in organic synthesis, combinatorial chemistry and automated organic synthesis.

Abstract: The present invention provides for methods and compositions for gas separation and purification utilizing a metallo-organic polymer adsorbent in processes for separating carbon dioxide, water, nitrogen oxides and hydrocarbons from gas streams.

Abstract: Methods, compositions and devices for purifying polypeptides and/or proteins using metal loaded ligand bound membranes by metal ion affinity chromatography are described.

Abstract: A crystal substance formed by precipitating as fibrous aggregates by making a metal aliphatic carboxylate dissolve completely in pure water, stirring, and gradually cooling the resulting solution. A method of preparing the fibrous crystal aggregates. A material for recovering flowing oil and method of recovering flowing oil by using the fibrous crystal aggregates. A material for solidifying liquid hydrocarbon, waste tempura oil and edible oil and method of solidifying liquid hydrocarbon, waste tempura oil and edible oil by using the fibrous crystal aggregates. A method of preparing the solidifying material.

Abstract: A new shaped activated carbon and the method of its manufacture are disclosed. The invention resides in the crosslinking of a polymeric cellulose, such as sodium carboxymethylcellulose (CMC), within the carbon bodies after they are shaped, employing the CMC as a binder for the activated carbon. The approach to attain product mechanical strength and water stability by crosslinking rather than high temperature heat treatment is not obvious from the prior art teaching. The crosslinking reaction occurs at temperatures below 270° C. In addition, this new binder technology produces shaped carbon bodies having key properties beyond the best level that has been accomplished with other binders.

Abstract: A method for preparing synthetic, semi-crystalline, porous inorganic oxide composition containing a reactive organic silane moiety which is on the surface of pore walls. The composition is prepared from a poly(oxyalkylene) based surfactant and a hydrolyzable organic silane. The surfactant is preferably a poly(ethylene) oxide, a poly(propylene) oxide polymer or mixtures thereof. The organic silane is preferably mercaptopropylsilane. The compositions are particularly useful as adsorbents, and catalysts.

Abstract: The invention provides a solid sorbent composition for removal of carbon dioxide and other acidic components from a gaseous stream, said composition being a product of a reaction of a mixture of at least one liquid absorbent material selected from the group consisting of amino alcohols and amino alcohols in combination with a sodium carbonate, a sodium bicarbonate, a potassium carbonate, a potassium bicarbonate and mixtures thereof, with at least one hardener selected from the group consisting of at least one metal oxide, wherein said metal is selected from the group consisting of zinc, aluminum, magnesium, alkaline earth metal oxides and mixtures thereof, said absorbent being capable of absorbing carbon dioxide and other acidic components and said reaction product being formed by heating the above mixture to effect a chemical reaction between the components of the above mixture with formation of a reaction product wherein said liquid absorbent material and said hardener combine upon heating to form said soli