Organic Patents (Class 502/401)
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Patent number: 6087301Abstract: A composition for a granular solid possessing superior absorbancy for absorbing oils. The composition includes perlite plaster aggregate, corn starch, and sodium bicarbonate, all being dry and powdered. Proportions of the constituent materials is nine parts by volume perlite aggregate, two parts by volume corn starch, and one part by volume sodium bicarbonate.Type: GrantFiled: March 26, 1999Date of Patent: July 11, 2000Inventor: Janice N. McNary
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Patent number: 6077809Abstract: A novel high-porosity adsorbent material for selective adsorption of fluoride ions, arsenic ions and phosphate ions as well as a method for the preparation thereof are disclosed. The adsorbent material consists of a porous carrier material such as crosslinked polyacrylate resin beads and a crystalline hydrous zirconium oxide impregnating the pores of the carrier in the monoclinic or cubic crystal form.Type: GrantFiled: June 30, 1998Date of Patent: June 20, 2000Assignee: Japan as represented by Director General of Agency of Industrial Science and TechnologyInventors: Toshishige Suzuki, Hideyuki Matsunaga, Toshiro Yokoyama
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Patent number: 6071416Abstract: A method and composition for the concentration and removal of desired metal ions from a source solution by contacting the solution with an N-cyclic aromatic hydrocarbon-containing ligand covalently bonded to a solid support through a hydrophilic spacer of the formula SS--A--X--(L).sub.n where SS is a solid support, A is covalent linkage mechanism, X is a hydrophilic spacer grouping, L is an N-cyclic aromatic containing ligand group and n is an integer of 1 to 6. X or L combined will not contain more than two amine nitrogen atoms. There will preferably be at least four N-cyclic groups present of which pyridine, pyrimidine, pyraxine, imidazole, quinoline, isoquinoline, naphthyridine, pyridopyridine, phenanthroline are representative.Type: GrantFiled: December 14, 1998Date of Patent: June 6, 2000Assignee: IBC Advanced Technologies, Inc.Inventors: Ronald L. Bruening, Krzysztof E. Krakowiak, Reed M. Izatt, Jerald S. Bradshaw
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Patent number: 6042743Abstract: A method of processing peat for use in treating a contaminated aqueous solution, especially storm water runoff entering a sewer system. The method includes mixing raw peat with heated sulfuric acid to produce a slurry. The slurry is dried and then mixed with a binder medium to produce an aggregate material. The aggregate material is extruded to form a plurality of pellets. The plurality of pellets are then baked in an oven at a temperature in the range of approximately 900-1000 degree F. Peat processed in accordance with the present invention serves as both an ion exchange material as well as an organic retention material. A filter canister for maintaining pelletized peat is also disclosed.Type: GrantFiled: August 3, 1998Date of Patent: March 28, 2000Assignee: Enviromental Filtration, Inc.Inventor: Lyle J. Clemenson
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Patent number: 6040032Abstract: An absorbent article for collecting non-aqueous liquids such as oil-based products, comprising a low density, structurally integral board of peat moss material manifesting an affinity for non-aqueous liquids while being hydrophobic in order to block undesirable water penetration in the absorbent medium. The invention also extends to a method for manufacturing the absorbent article.Type: GrantFiled: April 28, 1993Date of Patent: March 21, 2000Inventors: Joseph Israel, Yvon Levesque
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Patent number: 6011196Abstract: An absorbent material with substantially improved liquid permeability such that it is not subject to gel blocking while maintaining a preferred absorbent capacity is disclosed. The absorbent material is in particulate form and is the reaction product of a water-insoluble, absorbent, hydrogel-forming polymer and a polycationic polymer, the reaction forming a covalent bond between the polymers. After the reaction, the absorbent material has a Saline Flow Conductivity greater than (500-11.5.multidot.GV)(10.sup.-7) cm.sup.3 sec/g where GV is the gel volume of the absorbent material.Type: GrantFiled: April 16, 1998Date of Patent: January 4, 2000Assignee: The Procter & Gamble CompanyInventors: Lin Wang, Ebrahim Rezai, Yumiko Hayashi, Eui-Boo Cho
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Patent number: 6001769Abstract: Compositions and methods for decreasing chemical contamination in subsurface water bearing geological formations, comprising an oxidized form of lignitic coal, or its derivatives, preferably leonardite, and at least one surface active agent. The compositions can be applied to an affected water bearing formation by conventional groundwater management methods, e.g., injection wells and groundwater extraction systems.Type: GrantFiled: September 25, 1997Date of Patent: December 14, 1999Assignee: Correctivaction, LLCInventors: John Michael Citterbart, Sam Kumar
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Patent number: 5993653Abstract: An alkyl-phenyl bonded a stationary phase for use in reversed-phase liquid chromatography, having five to ten carbon atoms in the alkyl group, is disclosed. The alkyl-phenyl bonded phase has its unique selectivity, and it is chemically stable in both acidic and basic environments as well as having high retention capacity, hence high resolution. A method for preparing the alkyl-phenyl bonded phase and a column inside of which the alkyl-phenyl bonded phase is packed with are also disclosed. Additionally, a method for performing liquid chromatography and a mixed stationary phase which has more than one alkyl-phenyl phases are disclosed.Type: GrantFiled: August 11, 1997Date of Patent: November 30, 1999Assignee: PhenomenexInventors: Faizy Ahmed, Toshihiko Hanai
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Patent number: 5977014Abstract: An absorbent composite structure suitable for absorbing aqueous body fluids is provided which includes a substrate having two surfaces, a plurality of hydrogel-forming polymer particles and a chemical cross-linking agent capable of bonding to both the substrate and the hydrogel-forming particles. In at least a substantial portion of the structure, the majority of the hydrogel-forming polymer particles are connected by the chemical cross-linking agent directly to at least one of the substrate surfaces. The absorbent composite structure can be incorporated into an absorbent article. A method of making the absorbent composite structure is also disclosed.Type: GrantFiled: March 10, 1997Date of Patent: November 2, 1999Assignee: The Procter & Gamble CompanyInventors: Manfred Plischke, Mattias Schmidt, Ebrahim Rezai
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Patent number: 5948398Abstract: A metal oxide-carrying activated carbon having an oxidation catalytic activity comprises a treated activated carbon obtained by carbonizing a carbon material, activating the obtained carbon with an activating gas comprising carbon dioxide and water vapor, said activating gas containing not more than 15% by volume of water vapor, and then cooling the activated carbon down to a temperature of not more than 300.degree. C. under the same atmosphere; and, carried thereon, 0.1 to 20% by weight as converted into metal of an oxide of at least one metal selected from the group consisting of iron, chromium, nickel, cobalt, manganese, zinc, copper, magnesium and calcium. A deodorant is obtained by adding 1 to 50 parts by weight of a plastic powder having an average particle diameter of 1 to 50 .mu.m to 100 parts by weight of the above metal oxide-carrying activated carbon. The above.Type: GrantFiled: September 14, 1994Date of Patent: September 7, 1999Assignee: Kuraray Chemical Co., Ltd.Inventors: Tetsuya Hanamoto, Yukihito Ohta, Eiji Tanaka, Hong Sang Eui, Park Young Min, Choi Yong Bok, Lee Chang Woo
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Patent number: 5945373Abstract: A method for treating silica to render its surface non-polar, especially for use as a chromatography medium in "reverse phase" chromatography. The silica is treated with a solution of a complex in which a hydrocarbon chain is coordinated, e.g. through a carboxylic group, with a metal ion such as chromium. The complex also has halide ligands, which on hydrolysis give rise to cationic charging and hydroxyl-bridging of the complex molecules with the silica surface and with one another. Elimination of water binds the molecules onto the silica surface where their hydrocarbon chains give the desired non-polar properties.Type: GrantFiled: July 22, 1997Date of Patent: August 31, 1999Assignee: Downstream Media LimitedInventor: Martin J Hofmann
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Patent number: 5922449Abstract: A bonded phase material useful with a chromatographic separation process. The bonded phase material includes a hydroxyl bearing porous material, a first controlled stoichiometric amount of a first interactive silane covalently bonded to the surface of the hydroxyl bearing porous material and at least one additional interactive silane covalently bonded to the surface of the hydroxyl bearing porous material to provide the porous material with a gradient of functionality of varied polarity creates a unique overall polarity which is not obtainable by the separate interactive silanes themselves. The method of silating the porous material includes sequential application of controlled stoichiometric amounts of the interactive silanes.Type: GrantFiled: November 5, 1997Date of Patent: July 13, 1999Assignee: Diazem CorporationInventor: Anthony Revis
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Patent number: 5922640Abstract: Disclosed are an adsorbent for CO, comprising a composite comprised of a porous inorganic carrier and, carried thereon, a binary complex of a nitrogen-containing compound and a copper(I) halide, the nitrogen-containing compound being at least one member selected from at least one pyridine compound and a diamine represented by R.sup.1 R.sup.2 N(CH.sub.2).sub.n --NR.sup.3 R.sup.4, wherein n is 2 or 3 and each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group, with the proviso that when n is 2, each of at least two of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents a C.sub.1 -C.sub.4 alkyl group atoms and that when n is 3, at least one of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents a C.sub.1 -C.sub.4 alkyl group, and a method for separating carbon monoxide by adsorption using the adsorbent.Type: GrantFiled: February 27, 1997Date of Patent: July 13, 1999Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Hidefumi Hirai, Nobutoshi Ootsuka, Kenji Sakai, Toshiyuki Shimazawa
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Patent number: 5914044Abstract: A solid phase ligand removes metal cations from solution. The ligand is a branched polyalkyleneimine having a molecular weight of at least about 400, covalently bound to an inorganic support.Type: GrantFiled: December 20, 1996Date of Patent: June 22, 1999Assignee: Metre-International Inc.Inventors: Leonard Francis Lindoy, Peter Lewis Eaglen, Robert Louis Alldredge
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Patent number: 5909718Abstract: A paper based particulate absorbent material and method of manufacture using shredded paper along with water and a binder mixture. In the first step of the process the waste paper is subjected to a size reduction treatment. In the second step, the paper is mixed with water and optionally a binder. The material exits the mixing apparatus which can be fully dried to produce a particulate absorbent material. This material can be used for litter material, box packing material, caulking filler and floor sweep. The product can be made to be similar in appearance to commercially available litter materials but is lighter, dust-free, biodegradable and extremely absorbent. The packing material can be made to bend but not crease. Further, the product is extremely economical since it is made out of waste paper.Type: GrantFiled: June 3, 1997Date of Patent: June 8, 1999Assignee: Absorbent Paper Company, Inc.Inventor: Richard W. Sheehan
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Patent number: 5906960Abstract: An adsorbent that can be used to remove environmental contaminants such as organics, cations and anions in a single process step is prepared from humic acid. The adsorbent can be a soluble humic acid in liquid form (e.g., in aqueous solution) or the humic acid can be insolubilized and/or immobilized on a solid support. The adsorbent can also be used to recover agriculturally desirable metals in chelated form from contaminated water. The liquid form of the adsorbent can be used to wash solids to remove contaminants.Type: GrantFiled: August 15, 1996Date of Patent: May 25, 1999Assignee: Arctech, Inc.Inventors: Hyderabad G. Sanjay, Kailash C. Srivastava, Daman S. Walia
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Patent number: 5858910Abstract: A set of chiral stationary phases is based on yohimbine and its derivatives. In particular, the hydroxyl functionality of yohimbine and its analogs is covalently bonded via a urethane linkage to a polymethylenesilyl chain attached to the bound hydroxyl groups of a refractory inorganic oxide by Si-O bonds. The resulting chiral stationary phases have multiple chiral recognition sites and can be used with a broad spectrum of materials as eluents without leaching.Type: GrantFiled: November 25, 1997Date of Patent: January 12, 1999Assignee: UOP LLCInventor: David W. House
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Patent number: 5821193Abstract: An adsorbent for removing ketoamine-containing protein, which comprises carrying a compound having a terminal functional group of the formula: ##STR1## wherein each of R.sup.1 and R.sup.2 is an organic group and X is 0 or 1, on a porous water-insoluble carrier, a process for removing ketoamine-containing protein by employing the above adsorbent, a process for preventing or treating for diabetic complication by removing ketoamine-containing protein with the above adsorbent and an adsorber for removing ketoamine-containing protein.Type: GrantFiled: December 6, 1995Date of Patent: October 13, 1998Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Nobutaka Tani, Eiji Ogino
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Patent number: 5807482Abstract: A set of chiral stationary phases is based on yohimbine and its derivatives. One set of chiral stationary phases is based on a coating of yohimbine and yohimbine derivatives, and another set is based on covalent linkage of the chiral organic material to the underlying support. Both sets are effective in resolving enantiomeric mixtures.Type: GrantFiled: October 31, 1997Date of Patent: September 15, 1998Assignee: UOP LLCInventor: David W. House
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Patent number: 5801238Abstract: A method for producing a water absorbent resin comprising the step of radically polymerizing a water-soluble radically polymerizable monomer having an acid group or a group of the salt thereof and optionally a polysaccharide in the presence of water using a crosslinking agent (C), wherein 0.0001 to 1 weight % of a thiol compound (D) having a radically polymerizable double bond, based on the above mentioned water-soluble radically polymerizable monomer (A), is used as the copolymerizing component to provide a water absorbent resin having a high absorbency and a good gel stability after absorbing body fluid, and a water absorbent comprising the water absorbent resin produced thereby.Type: GrantFiled: September 10, 1996Date of Patent: September 1, 1998Assignee: Sanyo Chemical Industries, Ltd.Inventors: Keiji Tanaka, Masashi Date, Kenjiro Tsubota, Tsuyoshi Yuki, Satoshi Tamabuchi
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Patent number: 5801116Abstract: A solid composition of matter comprising one or more polysaccharides which has a coarse particle size is provided. The composition demonstrates absorbent properties and is useful in absorbent articles of manufacture. Also provided is a method for preparing the compositions.Type: GrantFiled: June 20, 1997Date of Patent: September 1, 1998Assignee: Rhodia Inc.Inventors: Ian William Cottrell, Animesh Goswami, Manjit Singh Chowdhary
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Patent number: 5780385Abstract: A cat litter which comprises a plurality of lightweight, resilient paper strips treated with a pH-indicator and/or an occult blood indicator and folded transversely into generally zig-zag shapes, enables early detection of feline urological syndrome. When wetted with alkaline urine secreted by the cat, the paper strips treated with pH indicator exhibit a noticeable color change. When wetted with cat urine containing occult or gross blood, the paper strips treated with occult blood indicator exhibit a noticeable color change. A mixture of pH indicator treated strips and occult blood indicator strips in the cat litter enables the detection of both alkaline pH and occult blood in the same urine sample. The color changes are easily visible to the observer without requiring unsanitary contact with the cat litter.Type: GrantFiled: May 19, 1995Date of Patent: July 14, 1998Assignee: Ranpak Corp.Inventors: Carl V. Santioemmo, James P. Humphries
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Patent number: 5777058Abstract: Scavengers for removing acidic or corrosive gaseous components from semiconductor process effluents comprising a metallic macromer comprising a coordinated complex of (i) metal coordination atoms linked to (ii) oxomeric moieties selected from the group consisting of carbonate, sulfite, carboxylate, and silicate, and methods for synthesizing these scavengers. A method for cleaning an exhaust gas containing least one corrosive or acidic gaseous component selected from the group consisting of hydrogen halide, chlorine, boron trihalide, thionyl chloride, and tungsten hexafluoride, which comprises contacting the exhaust gas with the metallic macromer scavenger compositions.Type: GrantFiled: May 29, 1996Date of Patent: July 7, 1998Assignee: ATMI Ecosys CorporationInventor: H. Eric Fischer
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Patent number: 5759404Abstract: The present invention is directed towards a separation method comprising the steps: (i) contacting an aqueous liquid that contains a dissolved substance that is to be enriched with a polymer under conditions allowing selective partition of said substance to said polymer, whereafter (ii) said polymer containing said substance is removed from said aqueous liquid. The polymer employed is a poly(vinyl ether) having different or identical vinyl ether subunits (1) where X et Y are selected among hydrogen and methyl; and R is selected among organic groups. A plurality of R are equal to a hydrophilic organic group. One or more R comprise a bioaffinity ligand; an ion exchange group, etc. The method may be applied to bioseparations such as gel, affinity, ion exchange and covalent chromatography and corresponding batch procedures. Also disclosed are vinyl ether polymers that can be employed in the method.Type: GrantFiled: July 8, 1996Date of Patent: June 2, 1998Assignee: Pharmacia Biotech ABInventors: Jan Ericsson, Eva Berggren, Liselotte Lundh
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Patent number: 5738623Abstract: This invention relates to the use of activated charcoal granule compositions which, when dry spread and "watered-in" to a site, reduces undesirable biological activity of deleterious organic compounds. When wet, these granules disperse very rapidly with a large dispersion area to original granule diameter ratio. The granules have high loadings of charcoal, i.e., from about 60 to about 95 weight percent and contain from about 5 to about 40 weight percent of a surfactant system which exhibits excellent dispersing; rewetting; and binding properties.Type: GrantFiled: May 22, 1996Date of Patent: April 14, 1998Assignees: Aquatrols Corporation of America, Inc., Rhone-Poulenc Inc.Inventors: Stanley John Kostka, Patrick Michael Holroyd, Mark David Einziger, Edward G. Fu, Alan Joseph Stern
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Patent number: 5721187Abstract: An oxygen absorber comprising an active carbon material layer and an oxygen absorbing layer comprising 15-80% by weight of a thermoplastic resin and 85-20% by weight of an oxygen absorbing agent, wherein the amount of the active carbon material is 0.2-15% by weight based on the oxygen absorbing agent. The oxygen absorber is easy to handle and excellent in oxygen absorbing performance, and does not deteriorate the flavor of foods and the like.Type: GrantFiled: December 27, 1995Date of Patent: February 24, 1998Assignee: Sumitomo Chemical Company, LimitedInventors: Tadatoshi Ogawa, Takanori Kume
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Patent number: 5719269Abstract: A pseudobioaffinity chromatography adsorbent adapted for use in selectively adsorbing immunoglobulins. In one embodiment, the adsorbent includes: (a) a solid support material; and (b) a ligand immobilized on the surface of the solid support material, said ligand being a compound of the formula ##STR1## wherein Y.sub.1 is selected from the group of S, SCH.sub.3.sup.+, O, NH, NCH.sub.3, CH.sub.2 and CR.sub.1 R.sub.2 wherein at least one of R.sub.1 and R.sub.2 is not hydrogen; wherein each of Y.sub.2, Y.sub.3 and Y.sub.4 is selected from the group of N, NCH.sub.3.sup.+, CH, and CR wherein R is not hydrogen; and wherein at least two of Y.sub.1, Y.sub.2, Y.sub.3 and Y.sub.4 are neither CH.sub.2, CH, CR nor CR.sub.1 R.sub.2.Type: GrantFiled: December 22, 1995Date of Patent: February 17, 1998Assignee: BioSepra, Inc.Inventors: Alexander Schwarz, Meir Wilchek
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Patent number: 5716898Abstract: Process for the production of a microspheroidal powder of low dispersity, according to which a hydrogel is prepared, an aqueous suspension of the ground hydrogel is subjected to atomisation in a stream of gas, gelled particles containing moisture are collected from the atomisation, the particles are brought into contact with an organic liquid in order to remove at least some of the moisture and the particles are then subjected to drying.The process applies to the production of silica powders intended to serve as support for chromium oxide catalysts which may contain titanium oxide and are suitable for the polymerisation of ethylene.Type: GrantFiled: March 8, 1993Date of Patent: February 10, 1998Assignee: Solvay (Societe Anonyme)Inventors: Helmut Derleth, Abel Grosjean
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Patent number: 5714445Abstract: The present invention relates to compositions and articles such as catamenials, diapers, pantiliners, paper towels, tissues, underarm shields, etc., which minimize odor caused from body fluids through the incorporation of an effective amount of cyclodextrin, having a particle size of less than 12 microns. Combinations of small particle size cyclodextrins with other odor-controlling materials are also disclosed.Type: GrantFiled: September 12, 1996Date of Patent: February 3, 1998Assignee: The Procter & Gamble CompanyInventors: Toan Trinh, Dean Van Phan
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Patent number: 5695882Abstract: A process for removing ions of dissolved heavy metals and complex heavy metals comprises provides a treatment zone in which is contained an extraction material having an activated surface that has an affinity for heavy metal ions and complex heavy metal ions. The activated surface is the reaction product of a polyamine with a covalently anchored trifunctional hydrocarbyl silyl that yields non-crosslinked amino groups to which functional chelator groups can be covalently attached. The activated surface of the extraction material is formed by first hydrating the extraction material surface and then silanizing the hydrated surface with a short chain trifunctional silane having a hydrocarbon substituent containing 1-6 carbon atoms and a terminal leaving group, and then reacting a polyamine with the hydrocarbylsilyl from the silanization of the hydrated surface so as to form an aminohydrocarbyl polymer covalently bound to the extraction material surface.Type: GrantFiled: August 17, 1995Date of Patent: December 9, 1997Assignee: The University of MontanaInventor: Edward Rosenberg
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Patent number: 5690052Abstract: The present invention provides an improved method for sorbing aqueous fluids through the use of a biodegradable, clumping, low odor, low attrition, low swelling ground grain litter. The ground grain litter is composed of a ground grain selected such that when the ground grain is wetted it tends to swell in volume less than 50-100%. In a preferred embodiment, the ground grain litter comprises ground hard red spring wheat used to sorb pet urine and fecal liquids voided by a pet into the litter.Type: GrantFiled: September 16, 1996Date of Patent: November 25, 1997Assignee: Pet Care Systems, Inc.Inventor: James H. Sladek
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Patent number: 5686555Abstract: The present invention relates to absorbents for aqueous acids or lyes comprising cross-linked, polycationic homopolymers and topolymers of quaternized, monoethylenically unsaturated carboxylic acid amino esters and/or carboxylic acid amides of the formula?CH.sub.2 =C(--R.sub.1)--CO--X--(CH.sub.2).sub.n --C(--R.sub.2, --R.sub.3)--CH.sub.2 --N(--R.sub.4,--R.sub.5,--R.sub.6)!.sup..sym. Y,(A),whereinR.sub.1 represents hydrogen or the methyl group,R.sub.2 and R.sub.3 represent hydrogen or the same or different alkyl groups having 1 to 4 C-atoms,R.sub.4, R.sub.5 and R.sub.6 represent the same or different alkyl groups having 1 to 4 C-atoms,n stands for 0 or 1,X stands for --O-- or --NH--, andY represents an anionic acid residue.Type: GrantFiled: April 7, 1995Date of Patent: November 11, 1997Assignee: Chemische Fabrik Stockhausen GmbHInventors: Kurt Dahmen, Reinmar Peppmoller, Uwe Gunther
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Patent number: 5674387Abstract: The invention relates to a chiral selector useful in separating underivatized enantiomers of nonsteroidal anti-inflammatory agents, particularly naproxen and other arylacetic acid compounds, and relates to a process for achieving such separation utilizing the chiral selector, which is also useful in achieving the enantiomeric separation of amines, alcohol derivatives, epoxides and sulfoxides. The invention is also directed to an apparatus which comprises the chiral selectors.Type: GrantFiled: June 6, 1995Date of Patent: October 7, 1997Assignee: Research Corporation Technologies, Inc.Inventors: William H. Pirkle, Christopher J. Welch, Bo Robert Lamm
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Patent number: 5667684Abstract: A material for removing human immunodeficiency virus (HIV) and its related substances from blood, plasma, or other body fluids is provided. The material comprises a porous substrate on which sulfuric group substantially in the form of a salt is immobilized. A convenient removal of HIV and its related substances at a high efficiency is enabled by the use of the material.Type: GrantFiled: April 26, 1995Date of Patent: September 16, 1997Assignee: Terumo Kabushiki KaishaInventors: Tadahiro Motomura, Yuko Miyashita, Takashi Ohwada, Makoto Onishi, Naoki Yamamoto
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Patent number: 5648313Abstract: Preparing an adsorption material for treating waste water containing heavy metals. Brown algae is crushed, separated from an alginate, crushed and ground to form particles about 500-1000 um and then rinsed with seawater and fresh water and thereafter dried to form the adsorption material.Type: GrantFiled: December 26, 1995Date of Patent: July 15, 1997Inventor: Peter Pohl
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Patent number: 5620940Abstract: The supported amine-polyol sorbent of the present invention comprises about 1 wt % to about 25 wt % amine, about 1 wt % to about 25 wt % polyol, with the balance being support. This sorbent is capable of absorbing and desorbing carbon dioxide at relatively high rates at ambient temperatures, thereby improving carbon dioxide sorption capacity.Type: GrantFiled: December 18, 1995Date of Patent: April 15, 1997Assignee: United Technologies CorporationInventors: Philip J. Birbara, Timothy A. Nalette
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Patent number: 5614458Abstract: A method for conditioning sludge is disclosed which includes adding a treatment material to the sludge, the treatment material including pieces of cellulose with a hydrophobic agent applied thereto. A method for conditioning sludge is disclosed which includes adding a treatment material to the sludge, and the treatment material including pieces of cellulose with wax applied thereto, the pieces of cellulose ranging in size between one-eighth inch and seven-sixteenths inch in a largest dimension and having about 0.5% to about 3% wax by weight, and at least ninety percent of surface area of the pieces of cellulose covered with wax.Type: GrantFiled: June 30, 1995Date of Patent: March 25, 1997Assignee: Ecosorb International, Inc.Inventors: John L. Webb, W. William Coe, Robert D. Kilgore, Shitalprasad N. Patil
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Patent number: 5602071Abstract: A bead is provided which consists essentially of peat moss immobilized by crosslinked neutralized poly(carboxylic acid) binder, sodium silicate binder, or polysulfone binder. The bead is effective to remove metal contaminants from dilute aqueous solutions. A method of making metal-ion-sorbing beads is provided, comprising combining peat moss or other nonliving biomass and binder solution (preferably in a pin mixer where it is whipped), forming wet beads, and heating and drying the beads. The binder solution is preferably poly(acrylic acid) and glycerol dissolved in water and the wet beads formed from such binder solution are preferably heated and crosslinked by radio frequency heating.Type: GrantFiled: May 17, 1995Date of Patent: February 11, 1997Assignee: Aero-Terra-Aqua Technologies CorporationInventors: Bobby L. Summers, Jr., Lester B. Gress, Warren H. Philipp, Scott B. Eastep
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Patent number: 5591690Abstract: The present invention relates to a gettering material that may be used as a filtration medium to remove pollutants from the environment. The gettering material comprises a high surface area material having a metal surface that chemically bonds n-alkanethiols in an organized manner thereby forming a molecular monolayer over the metal surface. The n-alkanethiols have a free functional group that interacts with the environment thereby binding specific pollutants that may be present. The gettering material may be exposed to streams of air in heating, ventilation, and air conditioning systems or streams of water to remove specific pollutants from either medium.Type: GrantFiled: June 29, 1994Date of Patent: January 7, 1997Assignee: Midwest Research InstituteInventors: David E. King, Gregory C. Herdt, Alvin W. Czanderna
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Patent number: 5578547Abstract: A bead is provided which consists essentially of peat moss or other nonliving biomass immobilized by sodium silicate or polysulfone binder. The bead is effective to remove metal contaminants from dilute aqueous solutions. A method of making metal-ion-sorbing beads is provided, comprising combining peat moss or other nonliving biomass and liquid binder (preferably in a pin mixer where it is whipped), forming wet beads, and drying the beads. The liquid binder is preferably sodium silicate dissolved in water or polysulfone dissolved in methylene chloride.Type: GrantFiled: May 26, 1994Date of Patent: November 26, 1996Assignee: Aero-Terra-Aqua Technologies Corp.Inventors: Bobby L. Summers, Jr., Lester B. Gress
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Patent number: 5565139Abstract: A vapor extraction apparatus includes a gel sorbent capable of absorbing vapor directly into the liquid state and capable of disgorging the absorbed liquid in a phase-transition. The apparatus includes a housing adapted for movement from a first position, where it is exposed to a vapor-containing gas stream and a first environmental condition, and capable of moving to a second position, where it is exposed to a second environmental condition. A gel sorbent is disposed on at least one surface of the housing. The gel sorbs vapor from the gas stream as liquid when the sorbent is in its first position. The sorbent disgorges the liquid during phase-transition collapse when it is in the second position. A method of extracting vapor from a process gas stream includes contacting a phase transition gel sorbent with vapor under conditions sufficient for the gel sorbent to undergo a phase transition and absorb vapor as liquid inside the gel sorbent.Type: GrantFiled: June 2, 1995Date of Patent: October 15, 1996Assignee: Gel Sciences, Inc.Inventors: David H. Walker, Harris Gold, George W. McKinney, III, John F. McCoy, III, Xiaohong Yu
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Patent number: 5561097Abstract: A method is disclosed for controlling the coupling low molecular weight ligands to activated sites on a support in competition with a quencher of the activated sites. Derivatized supports produced by the method have optimal ligate binding without overly dense binding sites or stearic effects. Azlactone-functional supports, especially porous supports such as porous particles, benefit from control of ligand density. A linear relationship exists between the molar ratio of ligand and quencher and the coupled ligand density. Optionally, hydrophilicity of the derivatized support can be determined by selection of quencher relative to selection of ligand.Type: GrantFiled: April 28, 1994Date of Patent: October 1, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Raymond M. Gleason, Jerald K. Rasmussen
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Patent number: 5545317Abstract: Packing materials for liquid chromatographic or catalytic columns are prepared by contacting a porous protein-adsorptive particulate or membranous support, such as a porous silica particulate support, with an aqueous solution into which a protein has been dissolved to form a saturated coating of protein on the external surfaces of the porous protein-adsorptive support, removing excess protein that remains in solution by washing, and, then crosslinking the protein in the coating. The result is a packing material which resists further adsorption by many different proteins but which continues to provide the adsorptive or catalytic properties of the groups on the internal surfaces of the porous protein-adsorptive support for separations, analysis, or alteration of small molecules. The packing material of the present invention is particularly useful in HPLC or solid phase extraction columns for direct injection drug analysis in plasma, serum, and urine.Type: GrantFiled: April 17, 1995Date of Patent: August 13, 1996Assignee: Dow Corning CorporationInventor: Dwight E. Williams
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Patent number: 5534186Abstract: A vapor extraction apparatus includes a gel sorbent capable of absorbing vapor directly into the liquid state and capable of disgorging the absorbed liquid in a phase-transition. The apparatus includes a housing adapted for movement from a first position, where it is exposed to a vapor-containing gas stream and a first environmental condition, and capable of moving to a second position, where it is exposed to a second environmental condition. A gel sorbent is disposed on at least one surface of the housing. The gel sorbs vapor from the gas stream as liquid when the sorbent is in its first position. The sorbent disgorges the liquid during phase-transition collapse when it is in the second position. A method of extracting vapor from a process gas stream includes contacting a phase transition gel sorbent with vapor under conditions sufficient for the gel sorbent to undergo a phase transition and absorb vapor as liquid inside the gel sorbent.Type: GrantFiled: December 15, 1993Date of Patent: July 9, 1996Assignee: Gel Sciences, Inc.Inventors: David H. Walker, Harris Gold, George W. McKinney, III, John F. McCoy, III, Xiaohong Yu
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Patent number: 5531971Abstract: Scavenger compositions useful for purifying process gas streams, such as process gas streams, such as hydrogen, nitrogen, noble gases, diborane, and hydride gases from Groups IVA-VIA of the Periodic Table, such as arsine, phosphine, silane, germane, hydrogen selenide, and hydrogen telluride, and mixtures thereof, to remove water, oxygen, and other oxidant and Lewis acid impurities therefrom, such scavenger comprising a porous, high surface area inert support having thereon an active scavenging species, formed by the deposition on the support of a Group IA metal and pyrolysis thereof at a selected elevated temperature on said support.Type: GrantFiled: October 13, 1994Date of Patent: July 2, 1996Assignee: Millipore Investment Holdings LimitedInventors: Glenn M. Tom, James V. McManus
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Patent number: 5516745Abstract: Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.Type: GrantFiled: May 24, 1994Date of Patent: May 14, 1996Assignee: Bend Research, Inc.Inventors: Dwayne T. Friesen, Walter C. Babcock, David J. Edlund, Warren K. Miller
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Patent number: 5510310Abstract: A floor dry material and method of manufacturing same in which waste cellulosic fibrous material, such as waste paper, is finely shredded after which any metal component is removed and the shredded material is then thoroughly mixed with a biodegradable surfactant, calcium oxide, and water until a temperature about 140.degree. F. to 150.degree. F. is achieved after which a natural citric-based solvent degreaser and a material selected from the group comprising silica diatomite plankton and non-swelling clay are added to obtain a finished floor dry material.Type: GrantFiled: October 26, 1993Date of Patent: April 23, 1996Assignee: Cerad Industries, Inc.Inventor: Harold J. Manning
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Patent number: 5502022Abstract: A pseudobioaffinity chromatography adsorbent adapted for use in selectively adsorbing immunoglobulins. In one embodiment, the adsorbent comprises: (a) a solid support material; and (b) a ligand immobilized on the surface of the solid support material, said ligand being a compound of the formula ##STR1## wherein Y.sub.1 is selected from the group consisting of S, SCH.sub.3.sup.+, O, NH, NCH.sub.3, CH.sub.2 and CR.sub.1 R.sub.2 wherein at least one of R.sub.1 and R.sub.2 is not hydrogen; wherein each of Y.sub.2, Y.sub.3 and Y.sub.4 is selected from the group consisting of N, NCH.sub.3.sup.+, CH, and CR wherein R is not hydrogen; and wherein at least two of Y.sub.1, Y.sub.2, Y.sub.3 and Y.sub.4 are neither CH.sub.2, CH, CR nor CR.sub.1 R.sub.2.Type: GrantFiled: May 16, 1994Date of Patent: March 26, 1996Assignee: BioSepra, Inc.Inventors: Alexander Schwarz, Meir Wilchek
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Patent number: 5501977Abstract: A biofilter composition of leonardite, clay, lime, and an inorganic salt mixture and a process for controlling air quality by contacting an air stream with the biofilter composition are provided wherein the composition supports microbial growth. The inorganic salt mixture comprises a nitrogen source and a phosphorus source. The air stream generally contains at least one volatile organic compound.Type: GrantFiled: July 7, 1994Date of Patent: March 26, 1996Assignee: Phillips Petroleum CompanyInventor: John A. Cruze
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Patent number: 5496397Abstract: Desiccant-coated substrates, regeneratable rotary dehumidification wheels and other devices for gas (e.g., air) treatment using those substrates, and processes for making them are disclosed. The substrates may have coatings in thicknesses of from about 2 to about 10 mils containing particles of one or more adsorbent desiccants and an organic water-based binder. The desiccant particles retain a high fraction of their original adsorption capacity because the pores of the desiccant particles contain a pore-clearing agent prior to the binder setting and the pore-clearing agent leaves the pores during the manufacturing process to prevent the binder from blocking the pores. In preferred embodiments a mixture of different desiccants is used and a particle suspending agent keeps the particles well-mixed so that the desiccant particles in the coated substrate will be as well-mixed as possible. The suspending agent may also function as the pore-clearing agent.Type: GrantFiled: December 7, 1994Date of Patent: March 5, 1996Assignee: Semco IncorporatedInventors: John C. Fischer, Kirk T. Mescher