And Specified Adde Active Sorbent Material Patents (Class 502/417)
  • Publication number: 20020100367
    Abstract: The invention is directed to an adsorbent comprising: a) 20-30% porous carbon with incorporated organic nitrogen species; and b) 70-80% inorganic matter. The invention is directed to a method of making an adsorbent which comprises: a) thermally drying dewatered sewage sludge to form granulated organic fertilizer; and b) pyrolyzing said the organic fertilizer at temperatures between 600 and 1000° C. The invention is additionally directed to the process of removing acidic gases from wet air streams comprising putting an adsorbent in contact with the wet air stream and allowing the adsorbent to adsorb the acidic gases.
    Type: Application
    Filed: November 29, 2001
    Publication date: August 1, 2002
    Applicant: The Research Foundation of the City Universtiy of New York
    Inventors: Teresa J. Bandosz, Andriy Bahryeyev, David C. Locke
  • Patent number: 6395678
    Abstract: A bead is provided which comprises or consists essentially of activated carbon immobilized by crosslinked poly(carboxylic acid) binder, sodium silicate binder, or polyamine binder. The bead is effective to remove metal and other ionic contaminants from dilute aqueous solutions. A method of making metal-ion sorbing beads is provided, comprising combining activated carbon, and binder solution (preferably in a pin mixer where it is whipped), forming wet beads, and heating and drying the beads. The binder solution is preferably poly(acrylic acid) and glycerol dissolved in water and the wet beads formed from such binder solution are preferably heated and crosslinked in a convection oven.
    Type: Grant
    Filed: September 1, 1999
    Date of Patent: May 28, 2002
    Assignee: Aero-Terra-Aqua Technologies Corporation
    Inventors: Bobby L. Summers, Jr., Karen L. Bennett, Scott A. Foster
  • Publication number: 20020052291
    Abstract: A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200° C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.
    Type: Application
    Filed: September 30, 1999
    Publication date: May 2, 2002
    Inventor: RANJANI SIRIWARDANE
  • Patent number: 6352956
    Abstract: A powder comprises a mixture of up to 40 weight percent activated cokes and inert materials. In the mixture, at least one of the inert material components is matched in terms of its grain size distribution to the grain size distribution of the activated coke component so that in a gas medium at rest, the speed of vertical descent of the coarse grain of the inert material component is substantially equal to the speed of vertical descent of the coarse grain of the activated coke component.
    Type: Grant
    Filed: July 19, 1999
    Date of Patent: March 5, 2002
    Assignee: Rheinkalk GmbH & Co. KG
    Inventors: Ekkehard Kienow, Bernd Morun, Thomas Schwertmann, Heinz Hoberg
  • Patent number: 6297187
    Abstract: The present invention provides a method of making a catalyst for improving the performance of liquid hydrocarbon fuel. The treating agent for improving the performance of liquid hydrocarbon fuel is made by preparing a resin or a rubber composition having 100 parts by weight of a resin or a rubber component, 15 to 60 parts by weight of a carbon source having a particle size of not more than 0.5 mm and containing anthracite in amount not less than 62.5%, to 85 parts by weight of a silicon dioxide source having a particle size of not more 0,5 mm and containing quartz sand in an amount not less than 8-% and 5 to 15 parts by weight of glass fiber having an average fiber length of 6 to 12 &mgr;m, press molding the composition to obtain a molded article, and aging the molded article.
    Type: Grant
    Filed: February 16, 2000
    Date of Patent: October 2, 2001
    Inventor: Katsuyoshi Yamagata
  • Publication number: 20010023232
    Abstract: An oxygen-absorbing composition containing particulate annealed electrolytically reduced iron of between about 100 mesh and 325 mesh in an amount of about up to 63% by weight, a salt such as sodium chloride in an amount by weight of about up to 3.5%, and a water-supplying component comprising activated carbon with liquid water therein of a mesh size of between about 20 mesh and 50 mesh in an amount by weight of up to about 85% in an envelope which will resist the passage of liquid water out of the envelope but will permit flow of oxygen into the envelope at a satisfactory rate.
    Type: Application
    Filed: May 2, 2001
    Publication date: September 20, 2001
    Inventor: George E. McKedy
  • Patent number: 6287468
    Abstract: The present invention relates to a granular carrier and a method for producing the same, and to an apparatus for treating sewage or waste water by using the granular carriers. The granular carrier comprises a tire powder of 100 parts by weight, an EVA or its derivative of 30 to 50 parts by weight, and an activated carbon or inorganic micropowder equivalent thereto of 5 to 15 parts by weight. The granular carriers producing method comprises the steps of: mixing a tire powder of 100 parts by weight and an EVA or resin of 30 to 50 parts by weight, resolving the EVA or its derivative of the mixture at a temperature of 100 to 250° C., bonding an activated carbon to the tire powder, extruding the mixture, cutting the mixture extruded, and attaching the activated carbon powder to the EVA or its derivative dissolved on the surface of the cut part of the mixture. The sewage or waste water treatment apparatus is also disclosed.
    Type: Grant
    Filed: October 25, 1996
    Date of Patent: September 11, 2001
    Assignee: Sam Kwang Aqua-Clear, Inc.
    Inventor: Hai-Soo Kim
  • Patent number: 6284705
    Abstract: An adsorptive monolith made by extruding a mixture of activated carbon, a ceramic forming material, a flux material, and water, drying the extruded monolith, and firing the dried monolith at a temperature and for a time period sufficient to react the ceramic material together and form a ceramic matrix. The extrudable mixture may also comprise a wet binder. The monolith has a shape with at least one passage therethrough and desirably has a plurality of passages therethrough to form a honeycomb. The monolith may be dried by vacuum drying, freeze drying, or control humidity drying. The monolith is useful for removing volatile organic compounds and other chemical agents such as ozone from fluid streams. Particularly useful applications include adsorptive filters for removing ozone from xerographic devices and other appropriate office machines and volatile organic compounds from automobile engine air intake systems.
    Type: Grant
    Filed: March 27, 2000
    Date of Patent: September 4, 2001
    Assignee: Westvaco Corporation
    Inventors: Minwoo Park, Frank R. Rhodes, Jack H. L'Amoreaux, Frederick S. Baker, Robert K. Beckler, John C. McCue
  • Patent number: 6277783
    Abstract: A method is provided for purifying a crude N-acetyl-para-aminophenol (APAP) containing color bodies or their precursors, the method comprising: a) forming a hot aqueous solution of the crude APAP; and b) subsequently contacting the hot solution with an acid washed adsorbent carbon, e.g., an activated carbon, which acid washed carbon, prior to such contact, has been pretreated by contacting it with an aqueous solution of a reducing sulfite.
    Type: Grant
    Filed: July 30, 1999
    Date of Patent: August 21, 2001
    Assignee: BASF Corporation
    Inventors: Olan Stanley Fruchey, Edward G. Zey, Larry O. Wheeler
  • Patent number: 6277780
    Abstract: Disclosed is a method for preparing a phosphorus treated activated carbon composition suitable for use as a catalyst support, a catalyst, and an adsorbent. The invention method involves treating (e., mixing or impregnating) an activated carbon material having a surface area greater than 100 m2/g with a phosphorus-containing compound, drying, and heating to a temperature of from 450° C. to about 1200° C., wherein the resulting composition is characterized by a phosphorus compound combined with the carbon in an amount of from above 2.5% to about 10% phosphorus, based on the weight of the composition.
    Type: Grant
    Filed: August 9, 1994
    Date of Patent: August 21, 2001
    Assignee: Westvaco Corporation
    Inventors: Robert K. Beckler, James R. Miller
  • Patent number: 6257242
    Abstract: A filter element for reducing or eliminating the harmful vapor phase components of air or smoke. The filter element includes a first section and a second section. The first section is positioned relative to and in fluid communication with the second section and contains an activated carbon fabric. The second section contains a mixture of catalytic activated carbon and coconut activated carbon.
    Type: Grant
    Filed: October 18, 1999
    Date of Patent: July 10, 2001
    Inventor: Ioannis C. Stavridis
  • Patent number: 6248690
    Abstract: An oxygen-absorbing composition containing particulate annealed electrolytically reduced iron of between about 100 mesh and 325 mesh in an amount of about up to 63% by weight, a salt such as sodium chloride in an amount by weight of about up to 3.5%, and a water-supplying component comprising activated carbon with liquid water therein of a mesh size of between about 20 mesh and 50 mesh in an amount by weight of up to about 85% in an envelope which will resist the passage of liquid water out of the envelope but will permit flow of oxygen into the envelope at a satisfactory rate.
    Type: Grant
    Filed: October 27, 1994
    Date of Patent: June 19, 2001
    Assignee: Multisorb Technologies, Inc.
    Inventor: George E. McKedy
  • Publication number: 20010002387
    Abstract: A bromine-impregnated activated carbon wherein the contents of any alkali metal, any alkali earth metal and iron are not higher than 0.3 wt % and the content of bromine is not lower than 3 wt %, with respect to the weight of a material activated carbon. The bromine-impregnated activated carbon has improved adsorption characteristics to the alkyl sulfides, which have not been sufficiently removed by activated carbons prepared by the conventional techniques. Further, variations in the absorption characteristics can be reduced and the activated carbon can exhibit a stable performance in removing the alkyl sulfides.
    Type: Application
    Filed: July 24, 1998
    Publication date: May 31, 2001
    Applicant: Yoshio Tsutsumi
    Inventors: YOSHIO TSUTSUMI, TERUO FUKUI, KATSUYA NOGUCHI, TAKASHI KOBAYASHI, AYAKO KOBAYASHI, TSUYOSHI YOSHIDOME
  • Patent number: 6180738
    Abstract: There is provided a polymerization, especially a gas phase polymerization, of a sticky polymer in the presence of a catalyst under polymerization conditions using carbon black as an inert particulate material, the improvement comprises conducting said polymerization in the presence of a carbon black having a sugar-containing or sugar-derived binder, which carbon black is prepared by heating the carbon black to a temperature of at least about 280° C. for a time sufficient to decompose said sugar-containing or sugar-derived binder prior to polymerization.
    Type: Grant
    Filed: June 29, 1999
    Date of Patent: January 30, 2001
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Weidong Wang, Kevin Joseph Cann
  • Patent number: 6117810
    Abstract: The present invention relates to a manufacturing method of molecular sieve compound and in particular, to a manufacturing method whereas crystalline aluminosilicate salt is formed in the pores of activated carbon and thereby possessing both hydrophilic and hydrophobic adsorption capacity, therefore the molecular sieve compound manufactured according to this present invention is in use for treatment agent of wastewater, deodorizing agent, antibacterial and disinfectant agent, adsorbent of organic matter and water, removal agent of harmful gas of cigarette, separable agent of air and many other applications.
    Type: Grant
    Filed: May 4, 1999
    Date of Patent: September 12, 2000
    Assignee: Korea Research Institute of Chemical Technology
    Inventors: Jung Min Lee, Jeong Kwon Suh, Soon Yong Jeong, Chun Hee Park, Jeong Hwan Park
  • Patent number: 6114273
    Abstract: An improved process is provided for the removal of sulfur oxides from gas or vapor media containing oxygen and H.sub.2 O by contacting the media with a catalytically-active carbonaceous char. The improvement is provided by the use of a catalytically-active carbonaceous char prepared by low-temperature carbonization and oxidation of a bituminous coal or bituminous material at temperatures below 700.degree. C., followed by contact of the carbonized, oxidized char with one or more nitrogen-containing compounds at a temperature which is stable at, or is increasing to, temperatures less than 700.degree. C., and then increasing the temperature of the resultant material to or above 700.degree. C.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: September 5, 2000
    Assignee: Calgon Carbon Corporation
    Inventor: Richard A. Hayden
  • Patent number: 6074974
    Abstract: The present invention relates to a manufacturing method of granulated complex molecular sieve composition having multifunction and useful for removal agent of harmful gas of cigarette or treatment agent of water purification etc. as having multifunctioned adsorption capacity and excellent anti-abrasion property, and convenient process, in particular, to a manufacturing method which is comprised of granulating by mixing alkali metal silicate aqueous solution to mixture of zeolites of various types and active carbon and treating it with water solution of alkali earth metal salt without calcination, and drying.
    Type: Grant
    Filed: August 14, 1998
    Date of Patent: June 13, 2000
    Assignee: Korea Research Institute of Chemical Technology
    Inventors: Jung-Min Lee, Jeong-Kwon Suh, Soon-Yong Jeong, Hang-Kyo Jin, Byung-Ki Park, Chun-Hee Park, Jeong-Hwan Park, Si-Wang Kim, Jong-An Kim, Yeoun-Kee Park, Chang-Whan Lim
  • Patent number: 6066591
    Abstract: A method for forming a reactive medium for removing homogenous and heterogeneous impurities from a fluid is provided which includes forming a uniform oxide layer on all exposed surfaces of a porous metal substrate, depositing at least one layer of carbon on substantially all of the oxide layer formed on the porous metal substrate, depositing a precursor metal species on the carbon layer, and heating the porous metal substrate containing the carbon layer to form active sites on the carbon layer, wherein the active sites include at least partially deoxygenated metal species chemically bonded to the carbon layer. Also provided is a reactive medium for purifying a fluid, the reactive medium comprising a porous inorganic substrate, a layer including carbon and an oxide layer between the porous inorganic substrate and the layer including carbon. The reactive medium further comprises active sites including at least partially deoxygenated metal species, the active sites being bonded to the layer including carbon.
    Type: Grant
    Filed: November 2, 1998
    Date of Patent: May 23, 2000
    Assignee: Pall Corporation
    Inventors: William L. Murphy, Bruce A. Wilson
  • Patent number: 6060032
    Abstract: A process is set forth for the production of a carbon monoxide stream from a feed stream comprising carbon monoxide, hydrogen, carbon dioxide, methane, nitrogen and moisture. The process comprises contacting the feed stream at elevated pressure with a layered adsorbent bed comprising (i) a pretreatment adsorbent in order to adsorb moisture preferentially over methane, nitrogen and carbon dioxide and (ii) a main adsorbent in order to adsorb carbon monoxide preferentially over hydrogen, carbon dioxide, methane and nitrogen. A key to the present invention is that a carbon-based adsorbent is used as the pretreatment adsorbent.
    Type: Grant
    Filed: July 27, 1998
    Date of Patent: May 9, 2000
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Christopher Thomas Hable, Timothy Christopher Golden, Wilbur Clymer Kratz
  • Patent number: 6010666
    Abstract: Hydrogen sulfide is dehydrogenated to generate a HS group and an S group. The HS group is oxidized to generate sulfuric acid, which is bonded to a metal. The S group is polymerized with a CH.sub.3 S group to generate methyl trisulfide or methyl tetrasulfide, which is adsorbed to an adsorbent. Methyl mercaptan is dehydrogenated, for example, to generate a CH.sub.3 S group. A portion of the CH.sub.3 S group is oxidized to generate methanesulfonic acid, which is bonded to a metal. Another portion of the CH.sub.3 S group is polymerized with the CH.sub.3 S group itself to generate methyl disulfide, at least a portion of which is adsorbed to an adsorbent. Still another portion of the CH.sub.3 S group is polymerized with the S group to generate methyl trisulfide or methyl tetrasulfide, which is physically adsorbed to an adsorbent. In this manner, malodor components including hydrogen sulfide and methyl mercaptan can efficiently be removed without producing or release of harmful secondary products.
    Type: Grant
    Filed: November 15, 1996
    Date of Patent: January 4, 2000
    Assignee: Toto, Ltd.
    Inventors: Tetsuya Kurokawa, Chihiro Kobayashi, Tomonori Tokumoto, Masahiro Yamamoto, Takashi Tsuchida
  • Patent number: 6001769
    Abstract: Compositions and methods for decreasing chemical contamination in subsurface water bearing geological formations, comprising an oxidized form of lignitic coal, or its derivatives, preferably leonardite, and at least one surface active agent. The compositions can be applied to an affected water bearing formation by conventional groundwater management methods, e.g., injection wells and groundwater extraction systems.
    Type: Grant
    Filed: September 25, 1997
    Date of Patent: December 14, 1999
    Assignee: Correctivaction, LLC
    Inventors: John Michael Citterbart, Sam Kumar
  • Patent number: 5997829
    Abstract: The present invention is directed to a sheet-form environment purifying material comprising particles of metal and/or metal oxide consisting essentially of at least one member being selected from the group consisting of manganese, copper, zinc, iron, vanadium, nickel, titanium, palladium, platinum, manganese oxide, copper oxide, zinc oxide, iron oxide, vanadium oxide, nickel oxide, titanium oxide, palladium oxide, and platinum oxide, adsorbent particles consisting essentially of at least one member selected from the group consisting of activated carbon, zeolite, silica gel, sepiolite, activated alumina and activated clay, thermoplastic resin particles being selected from ultrahigh-molecular weight polyethylene, polyethylene, polycarbonate, polyamide acrylonitrile-butadiene-styrene resins, polyimide, polyvinyl chloride, cellulose acetate, polysulfone, polystyrene phthalate and polypropylene, and an air-permeable sheet of fibrous.
    Type: Grant
    Filed: November 26, 1997
    Date of Patent: December 7, 1999
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Yoshika Sekine, Kenji Tonoki, Tatsuya Uchida, Yasuo Miyadera, Hiroyuki Kawada, Takayuki Senda
  • Patent number: 5985112
    Abstract: The general area of this invention relates to porous materials made from nanofiber packed beds. More particularly, the invention relates to altering the porosity or packing structure of a nanofiber packed bed structure by blending nanofibers with scaffold particulates having larger dimensions. For example, adding large diameter fibers to a nanotube packed bed to serve as a scaffolding to hold the smaller nanofibers apart and prevent the nanofiber bed structure from collapsing. This increases the average pore size of the mass by changing the pore size distribution and alters the packing structure of the packed bed. The increase in average pore size is caused by the creation of larger channels which improves the flow of liquids or gasses through these materials.
    Type: Grant
    Filed: April 6, 1998
    Date of Patent: November 16, 1999
    Assignee: Hyperion Catalysis International, Inc.
    Inventor: Alan B. Fischer
  • Patent number: 5965479
    Abstract: The present invention relates to an activated carbon comprising an activated carbon particle and titanium dioxide fine particles present at least on the surface thereof, which activated carbon contains substantially no carbon precursor on the surface thereof and has the lightness L value thereof of not more than 50.
    Type: Grant
    Filed: August 1, 1997
    Date of Patent: October 12, 1999
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Mitsuo Suzuki, Hiroyuki Aikyo, Satoshi Hirahara, Kazushi Matsuura, Kohei Okuyama
  • Patent number: 5948398
    Abstract: A metal oxide-carrying activated carbon having an oxidation catalytic activity comprises a treated activated carbon obtained by carbonizing a carbon material, activating the obtained carbon with an activating gas comprising carbon dioxide and water vapor, said activating gas containing not more than 15% by volume of water vapor, and then cooling the activated carbon down to a temperature of not more than 300.degree. C. under the same atmosphere; and, carried thereon, 0.1 to 20% by weight as converted into metal of an oxide of at least one metal selected from the group consisting of iron, chromium, nickel, cobalt, manganese, zinc, copper, magnesium and calcium. A deodorant is obtained by adding 1 to 50 parts by weight of a plastic powder having an average particle diameter of 1 to 50 .mu.m to 100 parts by weight of the above metal oxide-carrying activated carbon. The above.
    Type: Grant
    Filed: September 14, 1994
    Date of Patent: September 7, 1999
    Assignee: Kuraray Chemical Co., Ltd.
    Inventors: Tetsuya Hanamoto, Yukihito Ohta, Eiji Tanaka, Hong Sang Eui, Park Young Min, Choi Yong Bok, Lee Chang Woo
  • Patent number: 5948265
    Abstract: An ion-exchanger is provided which comprises zirconium hydroxide supported on active carbon. The process for producing the ion-exchanger, and a process for removing a multiply charged anion are also provided which employ the ion-exchanger. The ion-exchanger of the present invention has high chemical resistance, high heat resistance, high mechanical strength, and excellent ion exchange characteristics.
    Type: Grant
    Filed: July 3, 1997
    Date of Patent: September 7, 1999
    Assignee: Tosoh Corporation
    Inventors: Hidetoshi Wakamatsu, Manabu Sakurai, Tsugio Murakami, Sadakatsu Kumoi
  • Patent number: 5922640
    Abstract: Disclosed are an adsorbent for CO, comprising a composite comprised of a porous inorganic carrier and, carried thereon, a binary complex of a nitrogen-containing compound and a copper(I) halide, the nitrogen-containing compound being at least one member selected from at least one pyridine compound and a diamine represented by R.sup.1 R.sup.2 N(CH.sub.2).sub.n --NR.sup.3 R.sup.4, wherein n is 2 or 3 and each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group, with the proviso that when n is 2, each of at least two of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents a C.sub.1 -C.sub.4 alkyl group atoms and that when n is 3, at least one of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents a C.sub.1 -C.sub.4 alkyl group, and a method for separating carbon monoxide by adsorption using the adsorbent.
    Type: Grant
    Filed: February 27, 1997
    Date of Patent: July 13, 1999
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Hidefumi Hirai, Nobutoshi Ootsuka, Kenji Sakai, Toshiyuki Shimazawa
  • Patent number: 5914294
    Abstract: An adsorptive monolith made by extruding a mixture of activated carbon, a ceramic forming material, a flux material, and water, drying the extruded monolith, and firing the dried monolith at a temperature and for a time period sufficient to react the ceramic material together and form a ceramic matrix. The extrudable mixture may also comprise a wet binder. The monolith has a shape with at least one passage therethrough and desirably has a plurality of passages therethrough to form a honeycomb. The monolith may be dried by vacuum drying, freeze drying, or control humidity drying. The monolith is useful for removing volatile organic compounds and other chemical agents such as ozone from fluid streams. Particularly useful applications include adsorptive filters for removing ozone from xerographic devices and other appropriate office machines and volatile organic compounds from automobile engine air intake systems.
    Type: Grant
    Filed: April 23, 1996
    Date of Patent: June 22, 1999
    Assignees: Applied Ceramics, Inc., Westvaco Corporation
    Inventors: Minwoo Park, Frank R. Rhodes, Jack H. L'Amoreaux, Frederick S. Baker, Robert K. Beckler, John C. McCue
  • Patent number: 5891324
    Abstract: An activated carbon based adsorbent carrying an acid is provided for eliminating mercury or mercury compounds contained in hydrocarbons. Preferably the activated carbon base is provided with more than 80 ml/g micropore volume having radii less than 8 angstroms. Preferably the acid carried on the activated carbon is hydrochloric acid, sulfuric acid, or phosphoric acid. Hydrochloric acid is most preferred. The active carbon base is preferably manufactured by activating a carbonaceous material in an atmosphere comprising less than 30 vol. % water vapor. The adsorbent can be used to eliminate mercury or mercury compounds contained in hydrocarbons by contacting the adsorbent with the hydrocarbons in liquid phase. Particular hydrocarbons include naphtha and intermediates of oil products or petrochemical products. Minimal amounts of carried acid are desorbed from the adsorbent to the hydrocarbons.
    Type: Grant
    Filed: February 27, 1997
    Date of Patent: April 6, 1999
    Assignee: Kuraray Chemical Co., Ltd.
    Inventor: Kiyoto Ohtsuka
  • Patent number: 5880061
    Abstract: Active carbon having a pore size distribution obtained from a nitrogen adsorption isothermal line such that the volume of pores having a pore diameter of less than 15 .ANG. is at least 0.25 ml/g and constitutes at least 40% of the total volume of pores having a pore diameter of at most 300 .ANG., and the volume of pores having a pore diameter of from 100 to 300 .ANG. constitutes at least 10% of the total volume of pores having a pore diameter of at most 300 .ANG..
    Type: Grant
    Filed: June 12, 1996
    Date of Patent: March 9, 1999
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yoshio Yoshino, Atsushi Matsumoto, Kimitoshi Ohishi, Akihide Yoshida
  • Patent number: 5861207
    Abstract: Active composite consisting of a compressed support and of at least one agent which is active towards a gas, the compressed support including recompressed expanded graphite which has a density of between 0.02 and 1.5. According to the invention the active composite is made up of a series of sheets superposed one above the other, the active agent being dispersed in the flakes.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: January 19, 1999
    Assignees: Elf Aquitaine, Le Carbone Lorraine
    Inventors: Pierre Bou, Michel Moreau, Philippe Prades
  • Patent number: 5854173
    Abstract: A method for removing vapor phase contaminants from a gas stream. Sorbent particles are injected into the gas stream to react with vapor phase contaminants in the gas stream. Each sorbent particle is made from a support particle of a material coated with a layer of sorbent material different than the material of the support particle. The gas stream is directed through a particulate control device to remove the sorbent particles from the gas stream. A sorbent particle for use in the method and a method for manufacture of the sorbent particle are provided.
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: December 29, 1998
    Assignee: Electric Power Research Institute, Inc.
    Inventors: Ramsay Chang, Massoud Rostam-Abadi
  • Patent number: 5853690
    Abstract: Activated carbon is effective as a catalyst for water decomposition when it is coated with a heat-resistant, oxidation-resistant film. The heat-resistant, oxidation-resistant film is formed from an inorganic material such as ceramic or metal, and/or an organic material such as an organic ion-exchange resin, a silicone resin or a fluororesin, and preferably contains oxide capable of decomposing hypohalogenous acid. Water can be chemically decomposed to give hydrogen by the use of the activated carbon.
    Type: Grant
    Filed: February 24, 1997
    Date of Patent: December 29, 1998
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Kouetsu Hibino, Kyoichi Tange
  • Patent number: 5837741
    Abstract: A method of making a microporous carbon material which includes providing a precursor selected from the group consisting of crystalline salts of aromatic sulfonates and nonporous polymeric salts. Prior to carbonization, the precursor is treated by ion exchange or other conventional processes to introduce a metal such as iron, nickel and cobalt into the precursor. Heat treatment of such composite precursors in the temperature range of 350.degree. to 850.degree. C. in an inert oxygen free atmosphere for a sufficient time promotes thermally induced hydrogen abstraction and rearrangement of BSUs which result in the formation of a composite, carbonaceous microporous material which contains a metal component, and has a pore size distribution in the range of about 4-15 .ANG. A. The structural and storage characteristics of the microporous carbon materials are also disclosed.
    Type: Grant
    Filed: August 19, 1996
    Date of Patent: November 17, 1998
    Assignee: Syracuse University
    Inventors: James A. Schwarz, Karol Putyera, Teresa J. Bandosz, Jacek Jagiello, Kwabena A. G. Amankwah
  • Patent number: 5820927
    Abstract: An open-pore polyurethane foam support body (20) is impregnated in a single step with a solution of a thermoplastic adhesive dissolved in a solvent that is also a foam expander, or in two sequential steps first with a foam expanding solution and then, after the foam has expanded, with a solution of a thermoplastic adhesive, to form an adhesive layer (40) on the surfaces (25) within the pores (22) and passages (24) of the foam body (20). Sorbent particles (30) of activated carbon are introduced into the expanded pores until the expanded foam is packed to the desired density of carbon particle loading. The impregnated and loaded foam is then air dried at room temperature to evaporate the foam expanding solution until the foam body contracts to substantially its original volume.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: October 13, 1998
    Assignee: Carrier Corporation
    Inventors: William F. Oehler, Timothy N. Obee, Philip J. Birbara
  • Patent number: 5792720
    Abstract: A method and an apparatus using a fluidized bed type adsorbing tower for manufacturing a TEDA-impregnated active carbon which is used for removing toxic materials from a fluid. A base active carbon is dried to remove the water component, and the dried active carbon is filled into the fluidizing type adsorbing tower and to above a sieve plate. A TEDA reagent is injected into a TEDA vapor generating vessel. A heated air is supplied into the TEDA vapor generating vessel so as to generate a TEDA vapor mixed with the heated air. The heated air mixed with the TEDA vapor is supplied into the lower portion of the fluidized bed type adsorbing tower so as to make the base active carbon fluidized. Thus the TEDA vapor is impregnated into the active carbon within the fluidized carbon bed.
    Type: Grant
    Filed: December 14, 1995
    Date of Patent: August 11, 1998
    Assignee: Korea Atomic Energy Research Institute
    Inventors: Seung-Gy Ro, Hoo-Kun Lee
  • Patent number: 5759943
    Abstract: This invention relates to activated charcoal granule compositions which can be dry spread and "watered-in" to a site to reduce undesirable biological activity of deleterious organic compounds. When wet, these granules disperse very rapidly with a large dispersion area to original granule diameter ratio. The granules have high loadings of charcoal, i.e., from about 60 to about 95 weight percent and contain from about 5 to about 40 weight percent of a surfactant system which exhibits excellent dispersing; rewetting; and binding properties.
    Type: Grant
    Filed: May 22, 1996
    Date of Patent: June 2, 1998
    Assignee: Rhone-Poulenc Inc.
    Inventors: Mark David Einziger, Edward G. Fu, Alan Joseph Stern, Stanley John Kostka, Patrick Michael Holroyd
  • Patent number: 5726118
    Abstract: An activated carbon composition of matter is disclosed comprising a mixture of: (a) a first activated carbon having a plurality of pore sizes, pore volumes and pore surface areas sufficient to selectively adsorb fluids having molecular diameters from about 4 Angstroms to about 4,000 Angstroms; and (b) a second activated carbon having a plurality of pore sizes, pore volumes, and pore surface areas to selectively adsorb fluids having molecular diameters from about 4 Angstroms to about 4,000 Angstroms. The pore size distribution of pores in the second activated carbon that adsorbs fluids having molecular diameters from about 4 Angstroms to about 15 Angstroms is greater than that of the first activated carbon. The second activated carbon is present in an amount sufficient to provide a methane working capacity of the mixture greater than the methane working capacity of the first activated carbon.
    Type: Grant
    Filed: August 8, 1995
    Date of Patent: March 10, 1998
    Assignee: Norit Americas, Inc.
    Inventors: Don C. Ivey, Timothy C. Hoffman
  • Patent number: 5721186
    Abstract: A method for producing catalysts from coal is provided comprising mixing an aqueous alkali solution with the coal, heating the aqueous mixture to treat the coal, drying the now-heated aqueous mixture, reheating the mixture to form carbonized material, cooling the mixture, removing excess alkali from the carbonized material, and recovering the carbonized material, wherein the entire process is carried out in controlled atmospheres, and the carbonized material is a hydrocracking or hydrodehalogenation catalyst for liquid phase reactions. The invention also provides for a one-step method for producing catalysts from coal comprising mixing an aqueous alkali solution with the coal to create a mixture, heating the aqueous mixture from an ambient temperature to a predetermined temperature at a predetermined rate, cooling the mixture, and washing the mixture to remove excess alkali from the treated and carbonized material, wherein the entire process is carried out in a controlled atmosphere.
    Type: Grant
    Filed: September 6, 1996
    Date of Patent: February 24, 1998
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Malvina Farcasiu, Frank Derbyshire, Phillip B. Kaufman, Marit Jagtoyen
  • Patent number: 5721187
    Abstract: An oxygen absorber comprising an active carbon material layer and an oxygen absorbing layer comprising 15-80% by weight of a thermoplastic resin and 85-20% by weight of an oxygen absorbing agent, wherein the amount of the active carbon material is 0.2-15% by weight based on the oxygen absorbing agent. The oxygen absorber is easy to handle and excellent in oxygen absorbing performance, and does not deteriorate the flavor of foods and the like.
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: February 24, 1998
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tadatoshi Ogawa, Takanori Kume
  • Patent number: 5719101
    Abstract: The porous granular material according to the invention comprises carbon, silica, water-soluble mineral salts and water-insoluble mineral salts, does not disintegrate in the presence of water and has a particle size of approximately 1 to 5 mm, preferably from 1 to 3 mm, in particular from 1 to 2 mm; a crushing strength, or mechanical strength, in the range of 0.75 to 1 MPa; a density of between 0.7 and 0.8; a BET specific surface area of between 100 and 200 m.sup.2 /g; a microporous volume of between 0.25 and 1 cm.sup.3 /g; and a carbon content of 8 to 11 weight %, the balance being essentially made up by a mineral matrix of base nature, comprising a crystalline phase of insoluble aluminosilicates.Application, in particular, to the purification of liquids, as a catalyst in oxidation reactions and in the manufacture of composite catalysts, in particular in petrochemistry.
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: February 17, 1998
    Assignee: Peignage Amedee
    Inventor: Bernard Leman
  • Patent number: 5719100
    Abstract: Advantageous water treatment compositions are provided, which remain stable prior to their intended use in an aqueous environment. The compositions comprise sodium chlorite and an acid activator. Preferred as an acid activator is citric acid, anhydrous. The composition may also comprise, if desired, activated carbon, which may optionally be ion-impregnated. A method of treating water utilizing the compositions is disclosed, and water treatment kits are also provided.
    Type: Grant
    Filed: March 20, 1992
    Date of Patent: February 17, 1998
    Inventors: Rudolf Zahradnik, Bruce Barber
  • Patent number: 5716899
    Abstract: A body made up of substantially continuous high strength multicellular support having porous cell walls, and pores in the cell walls having an average pore diameter of which have active material embedded therein, and an outer surface. The body is made of material which can be ceramics, glass, glass-ceramic, cermet, metal, oxides, and combinations of these. The active material can be molecular sieve, activated carbon, and combinations these. A method for producing a pore-impregnated body which involves providing the substrate having a wall porosity greater than about 45% by volume, and an average pore diameter of about 15 to 30 micrometers, providing a slurry of active material dispersed in a medium, contacting the support with the slurry at subatmospheric pressure to substantially fill the open pores of the substrate with the active material, removing excess slurry from the outer surface and the non-pore surfaces of the cell walls, followed by drying.
    Type: Grant
    Filed: June 27, 1995
    Date of Patent: February 10, 1998
    Assignee: Corning Incorporated
    Inventors: Donald L. Guile, Jimmie L. Williams
  • Patent number: 5714126
    Abstract: The present invention provides a respirator filter system suitable for filtering toxic agents, including organic vapors, acid gases, formaldehyde, ammonia, and methylamine as well as pesticides, CS and CN tear gases, dusts, mists, fumes and radionuclides from environmental air to be respired by a user of the filter system. In general, the filter system of the present invention includes a cartridge containing a layer of an unimpregnated activated carbon, a layer of an activated carbon impregnated with sulfate, molybdenum and at least one impregnate selected from the group consisting of copper and zinc, and a HEPA filter. Cartridges containing these adsorbents or adsorbents similar to them (in carbon tetrachloride activity and chemistry) have been discovered to be uniquely capable of filtering a broad range of toxic agents.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: February 3, 1998
    Assignee: Mine Safety Appliances Company
    Inventor: Zane N. Frund
  • Patent number: 5710092
    Abstract: A highly microporous activated carbon is disclosed which is prepared by activation of an active carbon precursor material with a potassium hydroxide solution, pre-drying the blend to below 25% moisture content, activating this blend at from about 650.degree. to about 1100.degree. C., and acid washing and drying the microporous activated carbon product and which is characterized by greater than 50% of its total pore volume comprising pores of from above 8 .ANG. to 20 .ANG. in width and greater than 70% of its total pore volume comprising pores of less than 20 .ANG. in width and greater than 95% of its total pore volume comprising pores of less than 50 .ANG. in width.
    Type: Grant
    Filed: March 14, 1995
    Date of Patent: January 20, 1998
    Assignee: Westvaco Corporation
    Inventor: Frederick S. Baker
  • Patent number: 5637544
    Abstract: A reactive membrane for removing impurities, such as water, oxygen and organic compounds, from a gas is provided. The reactive membrane includes a porous inorganic substrate having exposed surfaces and at least one carbon layer, which is modified to present active sites, deposited on the exposed surfaces. The active sites include metal species which are at least partially deoxygenated and are chemically bonded to the carbon layer. Methods of forming the reactive membrane and of removing impurities from a gas with the membrane are also provided.
    Type: Grant
    Filed: February 19, 1995
    Date of Patent: June 10, 1997
    Assignee: Arizona Board of Regents on Behalf of the University of Arizona
    Inventor: Farhang F. Shadman
  • Patent number: 5626637
    Abstract: A process is disclosed for storing gaseous hydrocarbon fuel in storage containers under relatively low pressure by including in the cylinders highly microporous carbons prepared by further chemical activation of activated carbon comprising activation an active carbon precursor material with an alkali solution, predrying the blend to below about 25% moisture content, heat treating this blend at from about 652.degree. to about 1100.degree. C., and acid washing and drying the microporous activated carbon product, which is characterized by greater than 50% of its total pore volume comprising pores of from above 8 .ANG. to 20 .ANG. in width and greater than 70% of its total pore volume comprising pores of less than 20 .ANG. in width and greater than 95% of its total pore volume comprising pores of less than 50 .ANG. in width.
    Type: Grant
    Filed: March 14, 1995
    Date of Patent: May 6, 1997
    Assignee: Westvaco Corporation
    Inventor: Frederick S. Baker
  • Patent number: 5614459
    Abstract: An improved process is provided for the preparation of activated carbon, which comprises swelling a carbonaceous material in a polar organic solvent containing an activating agent, removing the solvent, carbonizing the material, and removing the activating agent from the product. The activated carbon is produced in a short time with a high yield, and has a high surface area with a very narrow pore size distribution. Both the solvent and activating agents may be recovered and recycled.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 25, 1997
    Assignee: Universidad de Antioquia
    Inventors: Fanor Mondragon, John Fernandez, Alfredo Jaramillo, Gustavo Quintero
  • Patent number: 5599764
    Abstract: The present invention relates to an adsorbent formed by the pyrolysis of a hydrophobic silica with a pore size greater than 5 .ANG., such as SILICALITE.TM., with a molecular sieving polymer precursor such as polyfurfuryl alcohol, polyacrylonitrile, polyvinylidene chloride, phenol-formaldehyde resin, polyvinylidene difluoride and mixtures thereof. Polyfurfuryl alcohol is the most preferred. The adsorbent produced by the pyrolysis has a silicon to carbon mole ratio of between about 10:1 and 1:3, and preferably about 2:1 to 1:2, most preferably 1:1. The pyrolysis is performed as a ramped temperature program between about 100.degree. and 800.degree. C., and preferably between about 100.degree. and 600.degree. C.The present invention also relates to a method for selectively adsorbing organic molecules having a molecular size (mean molecular diameter) of between about 3 and 6 .ANG.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: February 4, 1997
    Assignee: California Institute of Technology
    Inventors: Pramod K. Sharma, Gregory S. Hickey
  • Patent number: 5569534
    Abstract: Reactant for thermochemical systems, including a support which is, for example, recompressed expanded graphite or vermiculite, and an active agent, for example a salt. According to the invention, the support is in the form of granules of graphite having a density of between 0.20 and 0.5 g/cm.sup.3 and whose diameter lies between 0.2 cm and 2.5 cm.
    Type: Grant
    Filed: January 19, 1995
    Date of Patent: October 29, 1996
    Assignee: Elf Aquitaine
    Inventors: Benoit Lambotte, Bernard Spinner, Charles Timoney, Jacques Prosdocimi