And Rare Earth Metal (sc, Y Or Lanthanide)containing Patents (Class 502/65)
  • Patent number: 6093866
    Abstract: An alkylation catalyst comprises from 50 to 70 wt % of hydrogen type ZSM-SM-11 co-crystaline zeolite containing rare earth element and the rest amount of porous inorganic oxide matrix material. The zeolite has particular chemical composition and X-ray diffraction lines. This catalyst has higher activity, selectivity and stability in alkylation process than that of the prior art. With this catalyst the process for preparing ethyl benzene by alkylation of benzene with ethylene has higher ethylene conversion and ethyl benzene selectivity.
    Type: Grant
    Filed: June 23, 1997
    Date of Patent: July 25, 2000
    Assignees: China Petro-Chemical Corporation, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Fushun Petrochemical Company of Sinopec
    Inventors: Qingxia Wang, Shurong Zhang, Guangyu Cai, Feng Li, Longya Xu, Zuxian Huang, Yuying Li
  • Patent number: 6090738
    Abstract: This invention relates to the manufacture of a molecular sieve adsorbent for selectively separating methane from its gaseous mixture with nitrogen. More particularly, the invention relates to the manufacture of novel molecular sieve adsorbents useful for the separation of methane-nitrogen gaseous mixture.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: July 18, 2000
    Assignee: Indian Petrochemical Corp. Ltd.
    Inventors: Nettem Venkateshwarlu Choudary, Raksh Vir Jasra, Sodankoor Garadi Thirumaleshwar Bhat
  • Patent number: 6087289
    Abstract: The invention relates to the manufacture of novel molecular sieve adsorbents which are selective towards oxygen from its gaseous mixture with argon and/or nitrogen. More particularly, this invention relates to the manufacture of novel molecular sieve adsorbents useful for the separation of oxygen-argon-nitrogen gaseous mixture.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: July 11, 2000
    Assignee: Indian Petrochemical Corporation Limited
    Inventors: Nettem Venkateshwarlu Choudary, Raksh Vir Jasra, Sodankoor Garadi Thirumaleshwar Bhat
  • Patent number: 6069106
    Abstract: An improved manganese and/or chromium-promoted catalytic process, catalyst and method of manufacture for heavy hydrocarbon conversion, optionally in the presence of nickel and vanadium on the catalyst and in the feed stock, to produce lighter molecular weight fractions, including lower olefins and higher isobutane than normally produced. This process is based on the discovery that two "magnetic hook" elements, namely manganese and chromium, previously employed as magnetic enhancement agents to facilitate removal of old catalyst, or to selectively retain expensive catalysts, can also themselves function as selective cracking catalysts, particularly when operating on feeds containing significant amounts of nickel and vanadium, and especially where economics require operating with high nickel- and vanadium-contaminated and containing catalysts.
    Type: Grant
    Filed: October 21, 1996
    Date of Patent: May 30, 2000
    Inventor: William P Hettinger, Jr.
  • Patent number: 6063724
    Abstract: A catalytic material is provided which effectuates the aromatization, reformation, and dehydrogenation of aliphatic, cycloaliphatic, and mixtures of aliphatic and cycloaliphatic hydrocarbons. The catalyst comprises an L-zeolite associated with a Group VIII metal such as platinum and having a rare earth metal ion incorporated therein. A method of using the catalytic material is also provided.
    Type: Grant
    Filed: April 6, 1998
    Date of Patent: May 16, 2000
    Assignee: The Board of Regents of the University of Oklahoma
    Inventors: Daniel E. Resasco, Cristina L. Padro, Gary Jacobs, Haiyang Liu
  • Patent number: 6030916
    Abstract: This invention relates to the manufacture of novel molecular sieve adsorbents useful for the separation of a gaseous mixture of oxygen and nitrogen. The adsorbent is useful for the separation of oxygen and/or nitrogen from air. More particularly, the invention relates to the manufacture of a molecular sieve adsorbent which is selective towards nitrogen from its gaseous mixture with oxygen and/or an inert gas such as argon or helium.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: February 29, 2000
    Assignee: Indian Petrochemicals Corp. Ltd.
    Inventors: Nettem Venkateshwarlu Choudary, Raksh Vir Jasra, Sodankoor Garadi Thirumaleshwar Bhat
  • Patent number: 6027707
    Abstract: The invention concerns NU-88 zeolite, characterized by:i) a chemical composition with the following formula, expressed in terms of the mole ratios of the oxides for the anhydrous state:100 XO.sub.2, mY.sub.2 O.sub.3, pR.sub.2/n Owherem is 10 or less;p is 20 or less;R represents one or more cations with valency n;X represents silicon and/or germanium;Y represents one or more of the following elements: aluminium, iron, gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese; andii) an X ray diffraction diagram, in its as synthesized state, which comprises the results shown in Table 1 of the description.The invention also concerns the preparation of the zeolite, any catalyst containing the zeolite and any catalytic process using such a catalyst.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: February 22, 2000
    Assignee: Institut Francais du Petrole
    Inventors: John Leonello Casci, Sheena Maberly, Eric Benazzi, Loic Rouleau, Roland Patrick Henney
  • Patent number: 6028232
    Abstract: The present invention relates to a catalyst for preparing para-chloro aromatic compounds by the liquid-phase chlorination method. The catalyst is prepared by loading transition metal salts, rare earth metal salts or a mixture thereof, and alkali metal or alkaline earth metal chlorides having a melting point of 300.degree. C. or more, by solid-state method or impregnation method, into zeolite L being ion-exchanged by alkali metal. The present invention also relates to a process for preparing para-isomers of the chlorinated compounds by using the catalyst.
    Type: Grant
    Filed: September 23, 1997
    Date of Patent: February 22, 2000
    Assignee: Korea Research Institute of Chemical Technology
    Inventors: Sang Eon Park, Jung Whan Yoo, Poong Man Lee
  • Patent number: 6025294
    Abstract: A catalyst composition, a process for producing the composition and a hydrocarbon conversion process for converting a C.sub.9 + aromatic compound to a C.sub.6 to C.sub.8 aromatic hydrocarbon such as a xylene are disclosed. The composition comprises a zeolite having impregnated thereon a activity promoter selected from the group consisting of molybdenum, molybdenum oxides, lanthanum, lanthanum oxides, and combinations of two or more thereof. The composition can be produced by incorporating the activity promoter into the zeolite. The hydrocarbon conversion process comprises contacting a fluid which comprises a C.sub.9 + aromatic compound with the catalyst composition under a condition sufficient to effect the conversion of a C.sub.9 + aromatic compound to a C.sub.6 to C.sub.8 aromatic hydrocarbon.
    Type: Grant
    Filed: September 3, 1998
    Date of Patent: February 15, 2000
    Assignee: Phillips Petroleum Company
    Inventors: An-hsiang Wu, Charles A. Drake
  • Patent number: 6022471
    Abstract: A FCC catalyst having improved coke selectivity and a FCC process for converting hydrocarbon feedstocks to lower boiling products. The catalyst comprises a crystalline aluminosilicate zeolite, gibbsite, rare earth metal compound and a silica matrix prepared from at least one of a silica sol made by an ion-exchange process and an acidic silica sol prepared by mixing sodium silicate, an acid and an aluminum salt of an acid.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: February 8, 2000
    Assignee: Exxon Research and Engineering Company
    Inventors: William A. Wachter, Vinh T. Nguyen
  • Patent number: 5990032
    Abstract: A catalyst composition, a process for producing the catalyst composition, and a hydroconversion process for converting a fluid stream comprising at least one saturated hydrocarbon to C.sub.6 to C.sub.8 aromatic hydrocarbons such as benzene, toluene, and xylenes are disclosed. The catalyst composition comprises a zeolite and a promoter. The process for producing the composition comprises the steps of: (1) combining a zeolite with a complexing ligand and a promoter compound under a condition sufficient to produce a modified zeolite; and (2) heating the modified zeolite to produce a promoted zeolite. The hydroconversion process comprises contacting a fluid stream with the catalyst composition under a condition sufficient to effect the conversion of a saturated hydrocarbon to a C.sub.6 to C.sub.8 aromatic hydrocarbon.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: November 23, 1999
    Assignee: Phillips Petroleum Company
    Inventors: An-hsiang Wu, Charles A. Drake
  • Patent number: 5972832
    Abstract: The present invention relates to a hydrocracking catalyst containing nickel, tungsten, fluorine, zeolite as well as alumina, said catalyst is composed of, based on the total weight of the catalyst, 0.5-5.0 wt % fluorine, 2.5-6.0 wt % nickel oxide, 10-38 wt % tungsten oxide, and a catalyst carrier. Said carrier is composed of 20-90 wt % alumina and 10-90 wt % zeolite wherein the zeolite is mesopore or macropore zeolite of an acidity strength value 1.0-2.0 mmol/g determined by NH.sub.3 -TPD, the alumina is the alumina of an acidity strength value 0.5-0.8 mmol/g determined by NH.sub.3 -TPD. Said catalyst possesses good desulfurization activity, denitrogenation activity, and higher selectivity with respect to middle distillates than that of the prior art.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: October 26, 1999
    Assignees: Research Institute of Petroleum Proc., China Petrochemical Corporation
    Inventors: Jianwen Shi, Hong Nie, Yahua Shi, Yulin Shi, Yanping Zhang, Dadong Li
  • Patent number: 5968463
    Abstract: The invention is a selective reduction catalyst useful for converting exhaust gases generated by a lean-burn engine where the atmosphere is oxidizing. The catalyst comprises zeolite containing two forms or rhodium, small metal particles and ion-exchanged into the zeolite, the latter being in significant excess. In addition, the catalyst contains a rare-earth metal having primarily a +3 or higher valence such as lanthanum in a significantly higher amount relative the total amount of rhodium.
    Type: Grant
    Filed: June 12, 1998
    Date of Patent: October 19, 1999
    Assignee: Ford Global Technologies, Inc.
    Inventors: Mordecai Shelef, Woosang Chun
  • Patent number: 5965474
    Abstract: A composition for passivating metal contaminants in catalytic cracking of hydrocarbons includes a non-layered, ultra-large pore crystalline material with at least one peak at a position greater than about 18 Angstrom Units d-spacing with a relative intensity of 100, and a benzene adsorption capacity of greater than about 15 grams benzene per 100 grams anhydrous crystal at 50 torr and 25.degree. C., and a metal passivator incorporated within the crystalline material. A method for passivating contaminating metals uses the composition during catalytic cracking as an additive or as a component of the catalyst.
    Type: Grant
    Filed: April 29, 1997
    Date of Patent: October 12, 1999
    Assignee: Mobil Oil Corporation
    Inventors: Jeffrey William Balko, Arthur W. Chester, Augusto Rodolfo Quinones
  • Patent number: 5961817
    Abstract: A FCC catalyst having improved coke selectivity and greater catalyst strength, and a FCC process for converting hydrocarbon feedstocks to lower boiling products. The catalyst comprises a crystalline aluminosilicate zeolite, gibbsite, and a silica matrix prepared from at least one of a silica sol made by an ion-exchange process and an acidic silica sol prepared by mixing sodium silicate, an acid and an aluminum salt of an acid.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: October 5, 1999
    Assignee: Exxon Research and Engineering Company
    Inventors: William A. Wachter, Stuart L. Soled, Nikos J. Maris, Mark P. Lapinski, Carol P. Fitzpatrick
  • Patent number: 5948719
    Abstract: Ferrierite is ion exchanged with trivalent rare earth metals by a hydrothermal ion exchange method. The ion exchange is carried out by contacting ferrierite, in which its cation exchange positions are occupied by hydrogen or a hydrogen precursor, with an aqueous solution of one or more rare earth metal cations at a temperature above the boiling point of the solution. After the ion exchange, preferably at least 10% and more preferably at least 15% of the ferrierite cation exchange capacity is occupied by a trivalent rare earth metal cation. When combined with a catalytic metal, such as a Group VIII noble metal, the trivalent rare earth metal ion exchanged ferrierite is useful as a dewaxing catalyst having good selectivity for lubricating oil fractions, particularly when dewaxing a Fischer-Tropsch wax hydroisomerate.
    Type: Grant
    Filed: February 3, 1998
    Date of Patent: September 7, 1999
    Assignee: Exxon Research and Engineering Co.
    Inventors: Jack W. Johnson, Bruce R. Cook, Guang Cao, Rich A. McEvoy, Richard H. Ernst
  • Patent number: 5932509
    Abstract: Zeolites in particulate form that are uniformly exchanged with both lithium ions and trivalent cations are produced by first partially ion-exchanging the zeolite in powdered form with one or more selected trivalent ions, then agglomerating and calcining the partially trivalent cation-exchanged zeolite, then ion-exchanging the calcined agglomerate with lithium ions, and finally activating the trivalent cation- and lithium ion-exchanged zeolite.
    Type: Grant
    Filed: June 18, 1996
    Date of Patent: August 3, 1999
    Assignee: The BOC Group, Inc.
    Inventors: Vijay Ramanand Balse, Martin Bulow, Philip Connolly, Frank Fitch, Adeola Florence Ojo
  • Patent number: 5879645
    Abstract: The present invention provides a catalyst for reduction of nitrogen oxides represented by the formula (A.sub.a O.sub.x.B.sub.b O.sub.y).(C.sub.c O.sub.z.C'.sub.c' O.sub.z')/S which is produced by supporting mixed metal oxides represented by the formula (A.sub.z O.sub.x.B.sub.b O.sub.y).(C.sub.c O.sub.z.C'.sub.c' O.sub.z') in amorphous state on aluminum or silicon-containing support at calcination temperature of 400.degree. to 700.degree. C. in a molar ratio of 0.01:1 to 5:1, anda method for removing nitrogen oxides through selective catalytic reduction which comprises converting 50 to 50,000 ppm of nitrogen oxides in exhaust gas from automobile or from fixed source such as plant turbine and boiler, and other industry in a state of having 0.1 to 20% of excessive oxygen over (A.sub.a O.sub.x.B.sub.b O.sub.y).(C.sub.c O.sub.z.C'.sub.c' O.sub.z')/S catalyst by using 100 to 100,000 ppm of hydrocarbon reducing agent having 1 to 5 carbons under the reaction condition of 200.degree. to 800.degree. C.
    Type: Grant
    Filed: November 3, 1995
    Date of Patent: March 9, 1999
    Assignee: Korea Research Institute of Chemical Technology
    Inventors: Sang-Eon Park, Gyung-Mi Kim, Yun-Jo Lee, Jong-San Chang, Seong-Hee Han
  • Patent number: 5877109
    Abstract: Catalysts comprisingA) a rare earth alkoxide, a rare earth carboxylate and/or a rare earth coordination compound with diketones,B) an alumoxane andC) an inert, particulate, inorganic solid with a specific surface area of greater than 10 m.sup.2 /g and a pore volume of 0.3 to 15 ml/gare excellently suited to the polymerisation of conjugated dienes, in particular butadiene, in the gas phase.
    Type: Grant
    Filed: November 10, 1997
    Date of Patent: March 2, 1999
    Assignee: Bayer AG
    Inventors: Karl-Heinz Reichert, Peter Marquardt, Christopher Eberstein, Birgit Garmatter, Gerd Sylvester
  • Patent number: 5849258
    Abstract: The invention relates to a synthetic crystalline material and its use in catalytic conversion of organic compounds and as a sorbent. The crystalline material contains one or more microporous crystalline phases, having a micropore volume greater than or equal to about 0.15 cc/g distributed in channels between about 3 to about 15 .ANG. in average diameter which is rendered accessible by a mesopore volume of greater than or equal to about 0.1 cc/g distributed in channels between about 20 to about 100 .ANG. in average diameter. A process is also provided for preparing the crystalline material of the present invention.
    Type: Grant
    Filed: June 6, 1996
    Date of Patent: December 15, 1998
    Assignee: Intevep, S.A.
    Inventors: Juan Lujano, Yilda Romero, Jose Carrazza
  • Patent number: 5834395
    Abstract: Catalyst for controlling emissions of the present invention is comprised of at least one kind of transition metal atoms and at least one of Al or Si, wherein said transition metal atoms form a part of the surface of the catalyst for purifying exhaust gas. Accordingly, the catalyst for purifying exhaust gas has both high performance for purifying NO.sub.x and high heat resistance, because monoatomic active metal disperses in the catalyst structure, active metal is taken firmly in the structure, and said transition metal forms a part of the surface of the surface.
    Type: Grant
    Filed: March 11, 1996
    Date of Patent: November 10, 1998
    Assignee: Next Generation Catalyst Research Institute, Co., Ltd.
    Inventor: Takashi Honda
  • Patent number: 5804526
    Abstract: An adsorbent exhibiting an excellent adsorption ability to nitrogen oxides (NO) is made from an oxide-based ceramics having an average crystallite grain size D in a range of D<500 .ANG., e.g., CeO.sub.2. A catalyst is formed from, for example, an cerium oxide (CeO.sub.2) and a zeolite. A content C of CeO.sub.2 in the catalyst is set in a range of 10% by weight .ltoreq.CA.ltoreq.80% by weight. The zeolite adsorbs hydrocarbon (HC). The hydrocarbon (HC) adsorbed is oxidized into active CHO which acts to reduce the nitrogen oxides (NO) adsorbed by the CeO.sub.2.
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: September 8, 1998
    Assignee: Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Naohiro Satoh, Kazuhide Terada, Takeshi Narishige, Yoshikazu Fujisawa
  • Patent number: 5744674
    Abstract: A catalyst for the preparation of benzene, toluene and xylene from C.sub.9.sup.+ heavy aromatics consists of zeolite ZSM-5 and .gamma.- or .eta.-Al.sub.2 O.sub.3 as carrier, Re, Sn and Pt or Pd supported on the carrier. Under the conditions of 350.degree.-450.degree. C., 0.5-3.5 MPa, a WHSV of 1-5 h.sup.-1 and a H.sub.2 /HC ratio (v/v) of 500-1200, the catalyst achieves high activity and stability as well as low hydrogen consumption.
    Type: Grant
    Filed: February 6, 1996
    Date of Patent: April 28, 1998
    Assignees: China Petrochemical Corporation, Research Institute of Petroleum Processing
    Inventors: Shouxi Gui, Yuzhi Hao, Yanqing Li, Zhenhua Jing, Haohui Gu, Zhanqiao Liang, Baoyu Cheng
  • Patent number: 5733837
    Abstract: A catalyst for catalytic reduction of nitrogen oxides using a hydrocarbon and/or a oxygen-containing organic compound as a reducing agent is disclosed, which comprises a cerium oxide supported on a solid acid carrier.Also, a catalyst for catalytic reduction of nitrogen oxides using a hydrocarbon and/or an oxygen-containing organic compound as a reducing agent is disclosed, which comprises:(a) at least one element selected from the elements of Group Ib, Group IIa, Group IIb, Group IIIa, Group IIIb, Group IVa, Group IVb, Group Va, Group VIa, Group VIIa, and Group VIII in the Periodic Table (hereinafter referred to as the elements belonging to group (a)); and(b) a cerium oxide, supported on a solid acid carrier.
    Type: Grant
    Filed: April 5, 1996
    Date of Patent: March 31, 1998
    Assignees: Sakai Chemical Industry Co., Ltd., Petroleum Energy Center, Cosmo Oil Co., Ltd.
    Inventors: Tadao Nakatsuji, Hiromitsu Shimizu, Ritsu Yasukawa, Katsumi Miyamoto, Hiroshi Tsuchida
  • Patent number: 5705142
    Abstract: The present invention disclosed a crystalline aluminosilicate which has the following characteristics:(A) an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio as determined by chemical analysis of from 5 to 11;(B) a unit cell dimension of from 24.45 to 24.55(C) a molar ratio of the Al contained in the zeolite framework to the total A1 contained in the aluminosilicate of from 0.3 to 0.9 calculated by the equations specified in the specification;(D) an alkali metal content, in terms of oxide, of from 0.02 to 1.5% by weight;(E) an X-ray diffraction pattern having peaks characteristic of zeolite Y; and(F) an ignition loss of from 0.5 to 20% by weight; anda process for producing the same, and a catalyst employing the same for the catalytic cracking of a hydrocarbon oil and the said catalyst which contains at least one metal selected from rare earth metals and alkaline earth metals.
    Type: Grant
    Filed: November 18, 1996
    Date of Patent: January 6, 1998
    Assignees: Cosmo Research Institute, Cosmo Oil Co., Ltd.
    Inventors: Masaki Tan-no, Seiichi Harima, Mitsugu Tsujii, Mitsuru Ohi
  • Patent number: 5688975
    Abstract: Molecular sieve compositions have been synthesized which are resistant to the loss of framework atoms. Specifically, the molecular sieves of the invention have the empirical formulamA: (M.sub.w Al.sub.x Si.sub.y)O.sub.2where A is at least one rare earth metal, M is chromium or titanium and "m", "w", "x" and "y" are the mole fractions of A, M, Al and Si respectively. Applicants have discovered that the rare earth metals prevent loss of chromium and titanium from the framework and degradation of the molecular sieve. Along with the composition, a process for preparing the composition and processes using the composition are disclosed and claimed.
    Type: Grant
    Filed: April 10, 1996
    Date of Patent: November 18, 1997
    Assignee: UOP
    Inventors: Vinayan Nair, Deng-Yang Jan, Robert Lyle Patton, Ben A. Wilson, Donald F. Best
  • Patent number: 5681788
    Abstract: A catalyst for the purification of exhaust gas comprises a first coat layer of a palladium-carried activated alumina containing Ce, Zr and La formed on a honeycomb carrier, a second coat layer of an activated alumina containing Ce, Zr and La formed on the first coat layer, and a third coat layer of copper ion-exchanged zeolite powder formed on the second coat layer and efficiently purifies NOx, HC and CO in the exhaust gas under conditions from theoretical air-fuel ratio to excessive oxygen atmosphere.
    Type: Grant
    Filed: April 10, 1996
    Date of Patent: October 28, 1997
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Hiroyuki Kanesaka, Hiroshi Akama, Maki Kamikubo
  • Patent number: 5677254
    Abstract: This invention relates to a catalyst for purifying an exhaust gas, which has a denitrification property in the lean atmosphere and good durability and is hardly deteriorated even in a high temperature rich atmosphere. The feature thereof consists in a catalyst for purifying an exhaust gas, comprising a crystalline silicate having the specified X-ray diffraction pattern and a chemical composition represented by the following chemical formula in the term of mole ratios of oxides under dehydrated state,(1.+-.0.8)R.sub.2 O.?aM.sub.2 O.sub.3.bM'O.cAl.sub.2 O.sub.3 !.ySiO.sub.2in which R is at least one of alkali metal ions and hydrogen ion, M is at least one elementary ion selected from the group consisting of Group VIII elements of Periodic Table, rare earth elements, titanium, vanadium, chromium, niobium, antimony and gallium, M' is an alkaline earth metal ion selected from magnesium, calcium, strontium and barium ions, a>0, 20>b.gtoreq.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: October 14, 1997
    Assignee: Mitsubishi Jukogyo Kabushiki Kaisha
    Inventors: Shigeru Nojima, Kozo Iida, Norihisa Kobayashi, Satoru Serizawa, Atsushi Morii
  • Patent number: 5646082
    Abstract: The present invention disclosed a crystalline aluminosilicate which has the following characteristics:(A) an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio as determined by chemical analysis of from 5 to 11;(B) a unit cell dimension of from 24.45 to 24.55 .ANG.;(C) a molar ratio of the Al contained in the zeolite framework to the total Al contained in the aluminosilicate of from 0.3 to 0.9 calculated by the equations specified in the specification;(D) an alkali metal content, in terms of oxide, of from 0.02 to 1.5% by weight;(E) an X-ray diffraction pattern having peaks characteristic of zeolite Y; and(F) an ignition loss of from 0.5 to 20% by weight; anda process for producing the same, and a catalyst employing the same for the catalytic cracking of a hydrocarbon oil and the said catalyst which contains at least one metal selected from rare earth metals and alkaline earth metals.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: July 8, 1997
    Assignees: Cosmo Research Institute, Cosmo Oil Co., Ltd.
    Inventors: Masaki Tan-no, Seiichi Harima, Mitsugu Tsujii, Mitsuru Ohi
  • Patent number: 5641393
    Abstract: A crystalline zeolite high-silica SSZ-37 is prepared using a N,N-dimethyl-4-azoniatricyclo [5.2.2.0.sup.(2,6) ] undec-8-ene cation as a template wherein said zeolite is used in hydrocarbon conversion processes.
    Type: Grant
    Filed: August 8, 1995
    Date of Patent: June 24, 1997
    Assignee: Chevron U.S.A. Inc.
    Inventor: Yumi Nakagawa
  • Patent number: 5616170
    Abstract: Chabazite, offretite, erionite, levyne, mordenite, gmelinite, zeolite A, zeolite T, EMC-2, ZSM-3, ZSM-18, ZK-5, zeolite L, and beta zeolite whose exchangeable cations are composed of 95 to 50% lithium ions, 4 to 50% of one or more of aluminum, cerium, lanthanum and mixed lanthanides and 0 to 15% of other ions are prepared by ion-exchanging the base zeolite with water-soluble trivalent ion salts and with water soluble lithium salts. The zeolites preferentially adsorb nitrogen from gas mixtures.
    Type: Grant
    Filed: August 11, 1995
    Date of Patent: April 1, 1997
    Assignee: The BOC Group, Inc.
    Inventors: Adeola F. Ojo, Frank R. Fitch, Martin Bulow
  • Patent number: 5573990
    Abstract: A zeolite catalyst from ZSM-5 modified with phosphorus, rare earth elements and pore structure regulator is used for methanol/dimethyl ether conversion to light olefins.High temperature, non-recycling, continuous-running process is realized in the reactor system, comprising a dehydration reactor and several (2-n) adiabatic, fixed bed cracking reactors, loaded with the catalyst in multi-stage packing and operated in reaction regeneration cycles. The catalyst possesses high activity, high selectivity, good hydrothermal stability and long reaction life time.Operation of 100% methanol conversion and >85% C.sub.2 -C.sub.4 selectivity has been performed in a reactor system of the scale 0.7-1 ton CH.sub.3 OH/day for >600 hours on stream and with reaction time of single cycle >24 hours.
    Type: Grant
    Filed: August 9, 1994
    Date of Patent: November 12, 1996
    Assignee: Dalian Institute of Chemical Physics
    Inventors: Gongwei Wang, Muliang Ying, Xingchun Wang, Guoquan Chen
  • Patent number: 5559067
    Abstract: An in situ process for making improved zeolitic fluid cracking catalyst by spray drying a mixture of hydrous kaolin, gibbsite and spinel, essentially free from metakaolin, calcining the resulting microspheres to convert the hydrous kaolin to metakaolin whereby the gibbsite is hydrothermally converted to a transitional alumina, and reacting the microspheres composed of a mixture of spinel, transitional alumina and metakaolin with a seeded alkaline sodium silicate solution.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: September 24, 1996
    Assignee: Engelhard Corporation
    Inventors: Bruce A. Lerner, David M. Stockwell, Rostam J. Madon
  • Patent number: 5552076
    Abstract: An electrorheological fluid that includes a dispersed particulate phase of anhydrous amorphous ceramic particles. The anhydrous amorphous ceramic particles can be of a very precisely tailored composition that is unavailable in crystalline form, for obtaining enhanced electrorheological response. The amorphous particles are substantially free of water when used, and have reduced tendency to absorb water in use. Accordingly, the electrorheological fluid containing anhydrous amorphous electrorheologically responsive ceramic particles has wide applicability for use, and enhanced durability in such use.
    Type: Grant
    Filed: June 8, 1994
    Date of Patent: September 3, 1996
    Assignee: The Regents of the University of Michigan
    Inventors: Daniel R. Gamota, Brian L. Mueller, Frank E. Filisko
  • Patent number: 5468700
    Abstract: A hydrocarbon conversion catalyst useful for converting hydrocarbon feeds to midbarrel products is prepared by extruding a mixture of an inorganic refractory oxide component and a crystalline aluminosilicate zeolite having cracking activity to form extrudates which are broken into particles normally ranging in length between 1/16 and 1/2 inch. The extruded particles are then calcined in the presence of steam at a water vapor partial pressure greater than about 2.0 p.s.i.a., preferably greater than about 5.0 p.s.i.a. The calcination step is carried out in the presence of sufficient steam for a sufficient amount of time at a sufficient temperature to convert the crystalline aluminosilicate zeolite in the extrudates into an ultrahydrophobic zeolite having a unit cell size between about 24.20 and about 24.45 Angstroms and a sorptive capacity for water vapor less than about 5 weight percent of the zeolite at 25.degree. C. and a p/p.degree. value of 0.10.
    Type: Grant
    Filed: November 2, 1993
    Date of Patent: November 21, 1995
    Assignee: UOP
    Inventor: John W. Ward
  • Patent number: 5464467
    Abstract: Type X zeolites whose charge-compensating cations are composed of 95 to 50% lithium ions, 4 to 50% of one or more of aluminum, cerium, lanthanum and mixed lanthanides and 0 to 15% of other ions. The zeolites preferentially adsorb nitrogen from gas mixtures.
    Type: Grant
    Filed: August 8, 1994
    Date of Patent: November 7, 1995
    Assignee: The BOC Group, Inc.
    Inventors: Frank R. Fitch, Martin Bulow, Adeola F. Ojo
  • Patent number: 5464799
    Abstract: A zeolite, designated NU-85, is an intergrowth of zeolites EU-1 and NU-87. The zeolite is a useful catalyst in a wide variety of hydrocarbon conversion reactions including isomerization and alkylation.
    Type: Grant
    Filed: November 9, 1994
    Date of Patent: November 7, 1995
    Assignee: Imperial Chemical Industries PLC
    Inventors: John L. Casci, Mervyn D. Shannon, Ivan J. S. Lake
  • Patent number: 5464527
    Abstract: The selectivity of a midbarrel hydrocracking process for middle distillates is significantly increased by using a catalyst containing a Y zeolite that has been exchanged with rare earth cations. The rare earth-exchanged Y zeolite has a unit cell size below 24.45 angstroms and/or a water vapor sorptive capacity less than 10 weight percent at 25.degree. C. and a p/p.sub.o value of 0.1.
    Type: Grant
    Filed: June 3, 1994
    Date of Patent: November 7, 1995
    Assignee: UOP
    Inventor: John W. Ward
  • Patent number: 5409671
    Abstract: A catalytic convertor for treating exhaust gas includes a first catalyst layer formed on a base material and a second catalyst layer formed on the first catalyst layer. The first catalyst layer is composed of metal-containing silicate provided with transition metal by ion exchange and at least one precious metal borne on the silicate, and the second catalyst layer is composed of metal-containing silicate provided with transition metal by ion exchange and at least one metal borne on the silicate which is selected from the group consisting of Zr, Co, Cu, Cr, Mn, Y, Fe, Ni, V, Ti, Zn, Ga, Ba, Mg, La, Ce, Pr, Nd, Sm and Tb and differs from the transition metal provided on the silicate by ion exchange.
    Type: Grant
    Filed: March 21, 1994
    Date of Patent: April 25, 1995
    Assignee: Mazda Motor Corporation
    Inventors: Takashi Takemoto, Yasuto Watanabe, Masahiko Shigetsu, Kazunari Komatsu, Makoto Kyogoku
  • Patent number: 5407878
    Abstract: A composition comprising a coprecipitated magnesia-lanthana-alumina (MgO--La.sub.2 O.sub.3 --Al.sub.2 O.sub.3) wherein the MgO component is present as microcrystalline phase, having a BET (N.sub.2) surface area of at least 130 m.sup.2 /g, preferably part of which contains a catalytic oxidation and/or reducing promoter metal such as ceria, vanadia, iron and/or titania, is combined with an FCC catalyst which is used to catalytically crack a hydrocarbon feedstock that contains metal and/or sulfur.
    Type: Grant
    Filed: September 28, 1993
    Date of Patent: April 18, 1995
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Gwan Kim
  • Patent number: 5395809
    Abstract: An in situ process for making improved zeolitic fluid cracking catalyst by spray drying a mixture of hydrous kaolin and spinel, essentially free from metakaolin, calcining the resulting microspheres to convert the hydrous kaolin to metakaolin, and reacting microspheres composed of a mixture of spinel and metakaolin forms of calcined clay with a seeded alkaline sodium silicate solution. The weight percent of hydrous kaolin in the starting (uncalcined) microspheres is greater than the spinel content.
    Type: Grant
    Filed: November 1, 1993
    Date of Patent: March 7, 1995
    Assignee: Engelhard Corporation
    Inventors: Rostam J. Madon, Gerald S. Koermer, John M. Macaoay
  • Patent number: 5389358
    Abstract: A synthetic zeolite, designated zeolite GZS-11, is made having a molar composition expressed by the formula:[x M.sub.2/n O+(1.0.+-.0.2-x)R.sub.2/n O]:Y.sub.2 O.sub.3 :y XO.sub.2 :w H.sub.2 Owhere M is an inorganic cation of valance n, R is an organic cation of valence n, "x" has a value of less than 1.0, Y is one or more of +3 valence elements, such as aluminum, boron, gallium, iron, chromium, vanadium, molybdenum, or manganese, X is one or more of +4 valence elements, such as silicon, germanium, or titanium, "y" has a value of between 6 to 25, "w" has a value of up to 4 depending upon the degree of hydration of the zeolite, and having an X-ray diffraction pattern of the assynthesized zeolite substantially as in Table 1. The method for making the low ratio of XO.sub.2 /Y.sub.2 O.sub.3 such as SiO.sub.2 /Al.sub.2 O.sub.3 is achieved by adjusting the synthesis mixture composition during the aging stage through the addition of one or more of the solutions containing the reactive sources of zeolitic components.
    Type: Grant
    Filed: July 16, 1993
    Date of Patent: February 14, 1995
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Jianxin Wu, Robert R. Gatte, Terry G. Roberie
  • Patent number: 5380690
    Abstract: A cracking catalyst for the production of light olefins comprises 0-70% (based on the weight of the catalyst) of clay, 5-99% of inorganic oxides, and 1-50% of zeolite. The zeolite in the catalyst is a mixture of 0-25 wt % of REY or high silica Y zeolite and 75-100 wt % of phosphorus and rare earth containing high silica zeolite having a structure of pentasil. The catalyst exhibits higher hydrothermal activity-stability, conversion level, and C.sub.2 -C.sub.4 olefin yields in cracking reaction, comparing with the catalyst using HZSM-5 zeolite as active component.
    Type: Grant
    Filed: June 7, 1993
    Date of Patent: January 10, 1995
    Assignee: China Petro-Chemical Corporation
    Inventors: Shi Zhicheng, Shi Wenyuan, Ye Yifang, Ge Xingpin, Cao Ping, Liu Shunhua, Xie Chaogang, Li Zaiting, Shu Xingtian, Yang Xiaoming, Fu Wei, Zhou Meng, He Mingyuan
  • Patent number: 5376608
    Abstract: Zeolite catalytic cracking catalyst compositions and additives that contain a Lewis acid supported upon alumina are useful for to process hydrocarbon feedstocks. The compositions are especially useful for the production of reduced sulfur gasoline.
    Type: Grant
    Filed: January 27, 1993
    Date of Patent: December 27, 1994
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Richard F. Wormsbecher, Gwan Kim
  • Patent number: 5376610
    Abstract: A catalyst for exhaust gas purification has at least one monolith carrier, at least one first catalyst layer having a three-way catalytic activity, provided on the carrier, and a second catalyst layer having a hydrocarbon purification activity, provided on the first catalyst layer. In a gasoline engine automobile provided with the above catalyst for exhaust gas purification in the exhaust gas system, the hydrocarbons present in the exhaust gas can be converted at a high efficiency by introducing secondary air into the exhaust gas in front of the catalyst to make the exhaust gas lean, at the engine start when a large amount of unburnt hydrocarbons are present in the exhaust gas. Further, the engine warm-up property of the automobile can be improved by the heat generated by the catalytic reaction of the hydrocarbons. The catalyst further exhibits a three-way catalytic activity even during the steady state engine operation after warm-up.
    Type: Grant
    Filed: April 12, 1993
    Date of Patent: December 27, 1994
    Assignees: Nissan Motor Co., Ltd., NGK Insulators, Ltd.
    Inventors: Toshio Takahata, Hideharu Ehara, Fuminori Yamanashi, Katsuhiro Shibata, Fumio Abe, Tomoharu Kondo, Junichi Suzuki, Naomi Noda
  • Patent number: 5371055
    Abstract: An FCC catalyst system and a process using the catalyst system are disclosed. The catalyst system comprises a metal trap component, such as bastnaesite or barium titanate, and a sulfur oxide acceptor such as a magnesium spinel in addition to a zeolite. The metal trap and sulfur oxide components are preferably in separate particles. The catalyst formulation results in improved activity believed to result from the sulfur oxide acceptor protecting the metal trap component from the harmful effects of sulfur oxides such as the formation of stable metal oxides.
    Type: Grant
    Filed: February 18, 1994
    Date of Patent: December 6, 1994
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: William E. Cormier, Gerald M. Woltermann, John S. Magee, Fred J. Baars, Lawrence L. Upson
  • Patent number: 5367100
    Abstract: A zeolite catalyst from ZSM-5 modified with phosphorus, rare earth elements and pore structure regulator is used for methanol/dimethyl ether conversion to light olefins.High temperature, non-recycling, continuous-running process is realized in the reactor system, comprising a dehydration reactor and several (2-n) adiabatic, fixed bed cracking reactors, loaded with the catalyst in multi-stage packing and operated in reaction regeneration cycles. The catalyst possesses high activity, high selectivity, good hydrothermal stability and long reaction life time.Operation of 100% methanol conversion and >85% C.sub.2 -C.sub.4 selectivity has been performed in a reactor system of the scale 0.7-1 ton CH.sub.3 OH/day for >600 hours on stream and with reaction time of single cycle >24 hours.
    Type: Grant
    Filed: April 29, 1993
    Date of Patent: November 22, 1994
    Assignee: Dalian Institute of Chemical Physics
    Inventors: Wang Gongwei, Ying Muliang, Wang Xingchun, Chen Guoquan
  • Patent number: 5366945
    Abstract: There is provided a catalyst comprising a heteropoly acid, such as phosphotungstic acid, supported on a mesoporous crystalline material, such as M41S. A particular form of this M41S support is designated as MCM-41. There is also provided a method for preparing this catalyst by impregnating the heteropoly acid on the support. There is also provided a process for using this catalyst to catalyze acid catalyzed reactions, such as the isomerization of paraffins and the alkylation of aromatics.
    Type: Grant
    Filed: December 22, 1992
    Date of Patent: November 22, 1994
    Assignee: Mobil Oil Corp.
    Inventors: Charles T. Kresge, David O. Marler, Gayatri S. Rav, Brenda H. Rose
  • Patent number: 5358917
    Abstract: An improved hydroconversion process, particularly a hydrocracking process, employs a supported catalyst containing metals of Group VI and/or VIII. The catalyst support comprises a crystalline aluminosilicate of the zeolite Y type, a binder and a dispersion of silica-alumina in an alumina matrix. The catalyst support composition comprises less than 25% by weight of the zeolite material, more than 25% by weight of the binder and at least 30% by weight of the dispersion.
    Type: Grant
    Filed: October 29, 1992
    Date of Patent: October 25, 1994
    Assignee: Shell Oil Company
    Inventors: Johannes A. R. Van Veen, Johannes K. Minderhoud, Willem H. J. Stork
  • Patent number: RE35406
    Abstract: A cracking catalyst composition comprising a zeolitic, crystalline aluminosilicate, a matrix material and a barium titanium oxide. The catalyst composition is particularly suitable for cracking metal-containing hydrocarbon feedstocks.
    Type: Grant
    Filed: August 15, 1991
    Date of Patent: December 17, 1996
    Assignee: Akzo N.V.
    Inventor: Cornelis J. Groenenboom