N=c=x Reactant Having At Least Two C-nh-c(=x)- Groups, E.g., Prepolymers, Etc. Patents (Class 521/159)
  • Patent number: 11970564
    Abstract: A structural flame retardant high strength low exothermic polymer grouting material for consolidating, belonging to a technical field of polyurethane material, is produced by combined the polyether polyol and the modified isocyanate in a weight ratio of 100:(100-160), leading to internal reaction temperature ?100° C., strength ?60 mPa, bonding ?3 mPa, oxygen index ?28% while no halogen and no effect on water quality, odor level (80° C.) ?3.5, and fog test ?5 mg (which means no physical additive flame retardant is diffused into the environment). In particular, with no halogen, which is known as environmental hormones, in the plasticizers, there will be less combustion smoke, wherein the present invention will not release corrosive or irritating hydrogen halide gas, nor produce toxic carcinogens polybrominated benzoxins and polybrominated dibenzofurans, thereby avoiding the long-term impact of the material on the environment.
    Type: Grant
    Filed: September 20, 2022
    Date of Patent: April 30, 2024
    Assignees: SAFEKEY Engineering Technology (Zhengzhou), Ltd., Huizhou Mingsheng Chemical Materials Co., LTD., WELEAD Infrastructure Engineering Technology (Zhengzhou), Ltd.
    Inventors: Peng Zhao, Hongyuan Fang, Lei Wang, Chengchao Guo, Mingrui Du, Chao Zhang, Guobin Qiao
  • Patent number: 11795349
    Abstract: The disclosed adhesive sheet exhibits high anchoring performance and where separation between the substrate and the adhesive layer substantially does not occur when unwinding or re-peeling in actual applications. The adhesive sheet comprises a substrate including a urethane polymer component at least at a portion of a surface and a silicone adhesive layer that is in contact with the urethane polymer component, wherein the urethane polymer having a chain extender-derived hard segment and a polyoxyalkylene polyol-derived soft segment.
    Type: Grant
    Filed: January 3, 2019
    Date of Patent: October 24, 2023
    Assignee: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Yoshiteru Kakinuma, Aizoh Sakurai
  • Patent number: 11759368
    Abstract: A wound therapy device and method includes a skin contacting element, a reactor, and a reactor housing element. The skin contacting element is configured for covering an associated tissue site, the reactor for creating a pressure condition at the associated tissue site upon actuation thereof, and the reactor housing element for accommodating the reactor. The skin contacting element has a skin contacting side and an interface side, which is opposite the skin contacting side. The reactor housing element has a lower affixing side and an upper side, which is opposite the lower affixing side.
    Type: Grant
    Filed: June 18, 2021
    Date of Patent: September 19, 2023
    Assignee: AATRU MEDICAL, LLC
    Inventors: Russell S. Donda, Sundar Manickam, Richard L. Middaugh, Thomas E. Lash, Timothy Wojciechowski, John D. Wolter, John Buan
  • Patent number: 11738487
    Abstract: Processes for making a molded flexible foam. The processes include: (a) depositing a foam-forming reaction mixture onto a surface of a mold cavity, and (b) allowing the foam-forming reaction mixture to react in the mold cavity. The foam-forming reaction mixture comprises: (1) a polyisocyanate present in an amount of less than 45% by weight, based on the total weight of the foam-forming reaction mixture; (2) an isocyanate-reactive composition comprising at least 50% by weight, based on the total weight of polyol in the isocyanate-reactive composition, of a polyether polyol having a functionality of greater than 2, an oxyethylene content of 0 to 50% by weight, based on the total weight of the polyether polyol, more than 50 mol % of primary OH groups, and an OH number of 8 to 112 mg KOH/g; (3) a blowing agent comprising water present in an amount of at least 0.
    Type: Grant
    Filed: January 22, 2021
    Date of Patent: August 29, 2023
    Assignee: Covestro LLC
    Inventors: Michelle L. Montgomery, Brandon W. Parks
  • Patent number: 11518841
    Abstract: A crosslinked biobased hydrophilic foam comprising a reaction product of: a cleaned biobased polyoxyalkylene glycol polyol with an ethylene oxide content of at least 40 mole percent, constituting 31.80 to 67.95 percent biogenic carbon content by weight, constituting less than 15 ppm combined sodium and potassium metals, and comprising less than 0.5% water by weight; an isocyanate, wherein the isocyanate and the cleaned biobased polyoxyalkylene glycol polyol are premixed to create a prepolymer mixture with the cleaned biobased polyoxyalkylene glycol polyol of the prepolymer mixture; and water, wherein the water is admixed with the prepolymer mixture to yield the crosslinked biobased hydrophilic foam.
    Type: Grant
    Filed: June 12, 2020
    Date of Patent: December 6, 2022
    Assignee: BIONANOFOAM LLC
    Inventor: John I. Nanos
  • Patent number: 11479650
    Abstract: Polyurethane foams are made by curing a reaction mixture that contains an aromatic polyisocyanate, at least one isocyanate-reactive material having an average functionality of at least 2 and an equivalent weight of at least 200 per isocyanate-reactive group, at least one blowing agent, at least one surfactant and at least one catalyst, at least one cyclic 1,3-diketone compound, at least one aminoalcohol or alkylhydroxylamine and an alkali metal, phosphonium or ammonium sulfite. Foams so produced emit low levels of formaldehyde, acetaldehyde, acrolein and propionaldehyde.
    Type: Grant
    Filed: August 2, 2018
    Date of Patent: October 25, 2022
    Assignee: Dow Global Technologies LLC
    Inventors: Zhengming Tang, Jian Zou, Shaoguang Feng, Yuji Sasaki, Hongliang Chen, Degang Zhang, Ping Zhang
  • Patent number: 11447596
    Abstract: The present invention relates to a thermoplastic polyurethane obtainable or obtained by reacting a polyisocyanate composition, a chain extender, and a polyol composition, wherein the polyol composition comprises a polyol (P1) which has a molecular weight Mw in the range from 1500 to 2500 g/mol and has at least one aromatic polyester block (B1). The present invention further relates to a process for producing a shaped body comprising such a thermoplastic polyurethane, and to shaped bodies obtainable or obtained by a process of the invention.
    Type: Grant
    Filed: December 22, 2017
    Date of Patent: September 20, 2022
    Assignee: BASF SE
    Inventors: Sebastian Richter, Zeljko Tomovic, Kathrin Cohen
  • Patent number: 11312810
    Abstract: The invention relates to a thermoplastic polyurethane matrix resin composition, comprising at least one C3-8 alkane diol, at least one alkoxylated aromatic diol and at least one polyisocyanate. Furthermore, the present invention relates to a fiber-reinforced composite comprising a cured thermoplastic polyurethane polymer matrix according to the present invention and a fiber material. Moreover, a method for the manufacture of the fiber-reinforced composite according to the present invention and use of the composition or the fiber-reinforced composite in railway vehicles, automotive vehicles, aircraft vehicles, boats, space vehicles, motorbikes, bicycles, sporting goods, helmets, functional clothing, shoes, construction parts in bridges and buildings or wind turbine blades are described.
    Type: Grant
    Filed: June 3, 2019
    Date of Patent: April 26, 2022
    Assignee: Henkel AG & Co. KGaA
    Inventors: Andreas Niegemeier, Andreas Ferencz, Tamara Schmidt, Wolfgang Lupp
  • Patent number: 11168176
    Abstract: A composition for forming polyurethane foams is provided using epoxidized triglycerides with unopened rings. The composition further includes a polyol, a blowing agent, and a catalyst that catalyzes the reaction of polyols with isocyanates to form polyurethanes. The polyol is a polyoxyalklylene and the epoxidized triglyceride is an epoxidized soybean oil. A method for forming polyurethane foam using the aforementioned composition is also provided.
    Type: Grant
    Filed: September 27, 2018
    Date of Patent: November 9, 2021
    Assignee: Lear Corporation
    Inventors: Asad S. Ali, Paul Fielding, Virgil Kowalski, Matthew Phillips, Zhijie Zhang, Robert D. Dawe, Calton B. Spivey
  • Patent number: 11028295
    Abstract: The invention relates to a formulation comprising: —a first component which is formed from at least one isocyanate and at least one amino resin, wherein said amino resin is the condensation product of an aldehyde with a compound selected from the group comprising urea, melamine, benzoguanamine, glycoluril, acetoguanamine and mixtures thereof; and —a second component comprising at least one polyether, wherein said polyether comprises at least one ethylene oxide moiety and at least one isocyanate reactive group selected from the group comprising hydroxyl, amino, epoxy, and thiol, preferably hydroxyl.
    Type: Grant
    Filed: January 8, 2013
    Date of Patent: June 8, 2021
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventors: Servaas Holvoet, Daniele Pratelli, Christopher Phanopoulos
  • Patent number: 11021564
    Abstract: Disclosed are high strength polyurethane foam compositions and methods of making them. In one aspect, the inventive polyurethane foams include strength enhancing additives comprising one or more polycarbonate polyols derived from the copolymerization of CO2 and one or more epoxides. In one aspect, the inventive methods include the step of substituting a portion of the polyether polyol in the B-side of a foam formulation with one or more polycarbonate polyols derived from the copolymerization of CO2 and one or more epoxides.
    Type: Grant
    Filed: August 15, 2019
    Date of Patent: June 1, 2021
    Assignee: Saudi Aramco Technologies Company
    Inventors: Scott D. Allen, Vahid Sendijarevic, Aisa Sendijarevic
  • Patent number: 11007738
    Abstract: The present invention relates to a mold for manufacturing a sole from a plurality of particles.
    Type: Grant
    Filed: August 7, 2018
    Date of Patent: May 18, 2021
    Assignee: WERKZEUGBAU SIEGFRIED HOFMANN GMBH
    Inventors: Rene Hubert, Huu Minh Tru Le, Christopher Robertson, Christopher Edward Holmes, Maximilian Philipp Kurtz, Christian Richardt
  • Patent number: 10975190
    Abstract: A bio-based polyurethane foam manufactured by a process that involves cleaning a bio-based polyoxyalkylene glycol polyol by a method comprising the steps of adding an adsorbent to the bio-based polyoxyalkylene glycol polyol to create a mixture in the ratio of 0.5% to 5.0% adsorbent to bio-based polyoxyalkylene glycol polyol by weight, stirring the mixture in a gaseous nitrogen environment, replacing the gaseous nitrogen environment with a gaseous carbon dioxide environment, and filtering the mixture to separate impurities from the mixture and create a cleaned bio-based polyoxyalkylene glycol polyol; then mixing the cleaned bio-based polyoxyalkylene glycol polyol with a polyfunctional isocyanate to create a bio-based polyurethane prepolymer; and then foaming the bio-based polyurethane prepolymer by admixing with an excess of water to make the bio-based polyurethane foam.
    Type: Grant
    Filed: July 20, 2017
    Date of Patent: April 13, 2021
    Assignee: BioNanoFoam LLC
    Inventor: John I. Nanos
  • Patent number: 10947187
    Abstract: The invention relates to a method for producing methylene-diphenylene-diisocyanate and optionally a mixture of methylene-diphenylene-diisocyanate and polymethylene-polyphenylene-polyisocyanate, wherein, in a step ?), a fraction (142) containing a methylene-diphenylene-diisocyanate and secondary components is provided, optionally via a step ?.1), the separating of methylene-diphenylene-diisocyanate and secondary components from a fraction (100) containing methylene-diphenylene-diisocyanate and polymethylene-polyphenylene-polyisocyanate, and wherein, in a step ?), the fraction (142) containing methylene-diphenylene-diisocyanate and secondary components is subjected to a purification comprising an isomer separation by distillation and/or crystallization in two or more sub-steps (a, b, . . . ), obtaining two or more methylene-diphenylene-diisocyanate-reinfractions (140-1, 140-2, . . .
    Type: Grant
    Filed: January 2, 2019
    Date of Patent: March 16, 2021
    Assignee: Covestro Intellectual Property GmbH & Co. KG
    Inventors: Thomas Knauf, Peter Plathen, Dirk Manzel, Stefan Wershofen
  • Patent number: 10907008
    Abstract: The invention provides highly functional epoxy resins that may be used themselves in coating formulations and applications but which may be further functionalized via ring-opening reactions of the epoxy groups yielding derivative resins with other useful functionalities. The highly functional epoxy resins are synthesized from the epoxidation of vegetable or seed oil esters of polyols having 4 or more hydroxyl groups/molecule. In one embodiment, the polyol is sucrose and the vegetable or seed oil is selected from corn oil, castor oil, soybean oil, safflower oil, sunflower oil, linseed oil, tall oil fatty acid, tung oil, vernonia oil, and mixtures thereof. Methods of making of the epoxy resin and each of its derivative resins are disclosed as are coating compositions and coated objects using each of the resins.
    Type: Grant
    Filed: April 26, 2019
    Date of Patent: February 2, 2021
    Assignee: NDSU RESEARCH FOUNDATION
    Inventors: Dean C. Webster, Partha Pratim Sengupta, Zhigang Chen, Xiao Pan, Adlina Paramarta
  • Patent number: 10907012
    Abstract: A novel polycarbonate diol is useful as a raw material for producing a polycarbonate diol-based polyurethane with a high degree of hardness, superior abrasion resistance, and superior hydrophilicity. The polyurethane is useful in paints, coating agents, synthetic leathers, artificial leathers, and highly-functional elastomers, or the like. The polycarbonate diol is also useful for producing an active-energy radiation curable polymer composition giving a cured film having superior contamination resistance and high degree of hardness. The curable polymer composition contains a urethane(meth)acrylate oligomer obtained from the polycarbonate diol. The polycarbonate diol is obtained, for example, by reacting two specific types of diols with diester carbonate in the presence of a transesterification catalyst. The catalyst has a metal of Group 1 or 2 on the periodic table. A metal content of the transesterification catalyst is 100 weight ppm or less.
    Type: Grant
    Filed: October 15, 2012
    Date of Patent: February 2, 2021
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Haruhiko Kusaka, Kazuki Wakabayashi, Masanori Yamamoto, Kazunao Kusano, Hiroto Ito, Takashi Komaya, Teruhiko Ohara, Kentaro Uchino, Haruo Iiduka
  • Patent number: 10865269
    Abstract: A polyisocyanate composition contains a modified product of xylylene diisocyanate and a modified product of pentamethylene diisocyanate, and/or a modified product of the xylylene diisocyanate and the pentamethylene diisocyanate. The ratio of the pentamethylene diisocyanate with respect to the total amount of the xylylene diisocyanate and the pentamethylene diisocyanate is 30 mol % or more and 80 mol % or less.
    Type: Grant
    Filed: June 8, 2016
    Date of Patent: December 15, 2020
    Assignee: MITSUI CHEMICALS, INC.
    Inventors: Toshihiko Nakagawa, Aya Nakagawa, Shinji Kiyono, Hirokazu Morita, Satoshi Yamasaki
  • Patent number: 10774172
    Abstract: A crystalline non-reinforced thermoplastic polyurethane composition having a high flexural modulus comprises 5% to 25% of a hydroxyl-functional polyol intermediate having a weight average molecular weight of 250 to 3000 and 75% to 95% hard segment comprising an unbranched, unsubstituted, linear chain diol and an aromatic isocyanate.
    Type: Grant
    Filed: November 1, 2016
    Date of Patent: September 15, 2020
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventors: Qiwei Lu, Julius Farkas, Chetan M. Makadia, Alexander Jiaokai Jing
  • Patent number: 10710410
    Abstract: Polyurethane elastomeric compositions for making tires, methods for making said tires and tires made of said polyurethane elastomers. Said tires are in particular suitable for use as tires for low speed vehicles such as bicycle tires.
    Type: Grant
    Filed: September 15, 2014
    Date of Patent: July 14, 2020
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventors: Johan Van Dyck, Dieter Niclaes, Siddharth Sahu
  • Patent number: 10703847
    Abstract: A polyether having a functional group that is reactive to isocyanate with at least one polyisocyanate, which has an average isocyanate functionality in the range of 2.4 to 3.5, and at least one vinyl compound, which has a functional group that is reactive to isocyanate, wherein the molar ratio of polyether to vinyl compound lies in the range of 3:1 to 1:3 and the ratio of the sum of the molar quantities of polyether and vinyl compounds to isocyanate groups lies in the range of 1.5:1 to U.5. Corresponding vinylterminated prepolymers have the advantage of low visocity together with good water solubility and therefore can be used advantageously for applications as injection agents.
    Type: Grant
    Filed: June 1, 2016
    Date of Patent: July 7, 2020
    Assignee: SIKA TECHNOLOGY AG
    Inventors: Markus Haufe, Max Hug
  • Patent number: 10689481
    Abstract: A polyisocyanate composition contains a modified product of xylylene diisocyanate and a modified product of pentamethylene diisocyanate, and/or a modified product of the xylylene diisocyanate and the pentamethylene diisocyanate. The ratio of the pentamethylene diisocyanate with respect to the total amount of the xylylene diisocyanate and the pentamethylene diisocyanate is 60 mol % or more and 95 mol % or less.
    Type: Grant
    Filed: June 8, 2016
    Date of Patent: June 23, 2020
    Assignee: MITSUI CHEMICALS, INC.
    Inventors: Toshihiko Nakagawa, Aya Nakagawa, Shinji Kiyono, Hirokazu Morita, Satoshi Yamasaki
  • Patent number: 10639861
    Abstract: A sole mold for manufacturing a sole from a plurality of particles includes at least one first opening for supplying the particles, and at least two second openings for supplying a gaseous and/or liquid medium to bond and/or fuse the particles together. At least a portion of the sole mold is manufactured by an additive manufacturing method.
    Type: Grant
    Filed: May 23, 2017
    Date of Patent: May 5, 2020
    Assignee: adidas AG
    Inventors: Tru Huu Minh Le, Christopher Robertson, Christopher Edward Holmes, Norbert Reuber, Maximilian Philipp Kurtz, Rene Hubert, Christian Richardt
  • Patent number: 10442884
    Abstract: A polyurethane dispersant is described that comprises a reaction product of a polyisocyanate with a) a component supplying a anchoring imide group wherein the carbonyl groups of the imide are bonded to a fused or non-fused aromatic ring, b) at least one solvent-solubilizing chain, and other optional components to build molecular weight or modify the interaction of the dispersant with various particulates or continuous media.
    Type: Grant
    Filed: April 28, 2016
    Date of Patent: October 15, 2019
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventors: Andrew J. Shooter, Dean Thetford, Stuart N Richards, Robert A. Jennings
  • Patent number: 10427505
    Abstract: A roof module for a motor vehicle comprises an RTM frame and a Class-A covering layer, which at least partially covers the frame and is made of polyurethane. A method for manufacturing a roof module comprises the following steps: Initially, a fiber mat is put into a first mold. Then, a reactive resin system is introduced into the closed mold and the resin cures, so that a blank is formed. The blank is put into a second mold, into which subsequently polyurethane is introduced in the open condition. The polyurethane expands, wherein it at least partially forms a Class-A surface.
    Type: Grant
    Filed: June 8, 2017
    Date of Patent: October 1, 2019
    Assignee: ROOF SYSTEMS GERMANY GMBH
    Inventors: Maximilian Kirchner, Matthias Ludwig, Joachim Röder, Markus Waroch
  • Patent number: 10428173
    Abstract: Disclosed are high strength polyurethane foam compositions and methods of making them. In one aspect, the inventive polyurethane foams include strength enhancing additives comprising one or more polycarbonate polyols derived from the copolymerization of CO2 and one or more epoxides. In one aspect, the inventive methods include the step of substituting a portion of the polyether polyol in the B-side of a foam formulation with one or more polycarbonate polyols derived from the copolymerization of CO2 and one or more epoxides.
    Type: Grant
    Filed: May 23, 2018
    Date of Patent: October 1, 2019
    Inventors: Scott D. Allen, Vahid Sendijarevic, Aisa Sendijarevic
  • Patent number: 10344123
    Abstract: A polycarbonate diol is provided, including three kinds of repeating diol units, wherein one of the repeating diol units is chosen from an alkoxylated diol monomer.
    Type: Grant
    Filed: August 17, 2016
    Date of Patent: July 9, 2019
    Assignee: Dairen Chemical Corporation
    Inventors: Fu-Shen Lin, June-Yen Chou, Hsing-Yun Wang, Chih-Jung Chen, Wei-Lun Hsieh
  • Patent number: 10308836
    Abstract: Polymeric dispersants are disclosed that include a urethane backbone at least one pendantly attached imide group, wherein the carbonyl of the imide are chemically bonded to a single or fused aromatic ring. The aromatic ring can be substituted with various electron withdrawing or releasing groups. The dispersant also includes solvent-solubilizing chains of polyether, polyester, polyacrylate, and or polyolefin Desirably, the imide groups are derived from an imide that has two isocyanate reactive groups such that the imide is attached to the urethane backbone at two separate locations.
    Type: Grant
    Filed: October 24, 2014
    Date of Patent: June 4, 2019
    Inventors: Andrew J. Shooter, Dean Thetford, Robert A. Jennings, Stuart N. Richards
  • Patent number: 10308898
    Abstract: The present invention discloses a method of imparting water repellency and optionally stain release to fibrous substrates by contacting a fibrous substrate with a non-fluorinated laundry treatment composition inside a laundry machine. The laundry treatment composition contains a hydrophobic organic urethane compound having a urethane linkage and the residue of a substituted cyclic or acyclic sugar alcohol. Laundry additive compositions containing a first laundry treatment composition, having a hydrophobic organic urethane compound, and a second laundry treatment composition are also included.
    Type: Grant
    Filed: September 11, 2015
    Date of Patent: June 4, 2019
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: John Christopher Sworen, Gerald Oronde Brown, Sara Lyons, Ewa Kohler
  • Patent number: 10246608
    Abstract: The present invention is an aqueous composition comprising at least one hydrophobic compound having at least one linkage of Formula I: —NHC(O)—X—??(I) wherein X is the residue of a cyclic or acyclic sugar alcohol which is substituted with at least one —R1; —C(O)R1; —(CH2CH2O)n(CH(CH3)CH2O)mR2; —(CH2CH2O)n(CH(CH3)CH2O)mC(O)R1; or mixtures thereof; where the cyclic or acyclic sugar alcohol is selected from a saccharide, reduced sugar, aminosaccharide, aldonic acid, or aldonic acid lactone; wherein each n is independently 0 to 20; each m is independently 0 to 20; m+n is greater than 0; each R1 is independently a linear or branched alkyl group having 5 to 29 carbons optionally comprising at least 1 unsaturated bond; each R2 is independently —H, a linear or branched alkyl group having 6 to 30 carbons optionally comprising at least 1 unsaturated bond, or mixtures thereof.
    Type: Grant
    Filed: September 24, 2015
    Date of Patent: April 2, 2019
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: John Christopher Sworen, Gerald Oronde Brown, Mario Vincenzini, Flemming Vang Sparsoe, Ewa Kohler
  • Patent number: 10059794
    Abstract: Disclosed is a polyurethane foam composition based on polyisocyanates comprising initially at least 20 wt % mMDI and at most 24.5 wt % mTDI, a towards isocyanate polyfunctional and a towards isocyanate monofunctional compound, which composition contains a) less than 1.00 wt % residual free mMDI, b) at least 0.4 wt % total of mMDI of which at least one isocyanate group has been reacted with a monofunctional compound, c) wherein the polyurethane prepolymer composition is having an isocyanate index of at least 105 and at most 350, d) wherein the equivalents ratio of functional groups of the monofunctional compounds relative to the amount of the isocyanate functional groups initially present is at least 6.5%, and e) wherein the equivalents ratio of towards isocyanate tri- and higher functional reactive compounds relative to the isocyanate functional groups initially present is at most 6.50%. Further disclosed is a suitable prepolymer, production methods and uses.
    Type: Grant
    Filed: November 14, 2012
    Date of Patent: August 28, 2018
    Assignee: SOUDAL
    Inventors: John Verstegen, Bart Vervoort, Peter Geboes
  • Patent number: 9994690
    Abstract: A method for producing polyHIPE porous monoliths, of the polyHIPE type or in the form of a rigid foam, by hardening solutions of condensed tannins in the presence of oil and/or air or in the presence of a non-water-miscible volatile solvent and/or air. Also disclosed is the use of these materials in the areas of catalysis, chromatography, heat and sound insulation, tissue engineering and medication release and as a floral foam.
    Type: Grant
    Filed: August 27, 2013
    Date of Patent: June 12, 2018
    Assignees: UNIVERSITE DE LORRAINE, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: Alain Celzard, Andrzej Szczurek, Vanessa Fierro, Antonio Pizzi
  • Patent number: 9988563
    Abstract: The invention relates to a composition obtained by simultaneously mixing at least one isocyanate, at least one polyether and at least one amino resin, wherein said polyether comprises at least one ethylene oxide moiety and at least one isocyanate reactive group selected from the group comprising hydroxyl, amino, epoxy, and thiol, and wherein said amino resin is the condensation product of an aldehyde with a compound selected from the group comprising urea, melamine, benzoguanamine, glycoluril, acetoguanamine and mixtures thereof.
    Type: Grant
    Filed: January 8, 2013
    Date of Patent: June 5, 2018
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventors: Servaas Holvoet, Daniele Pratelli, Christopher Phanopoulos
  • Patent number: 9908984
    Abstract: A polyurethane foam having an initial UL 94 vertical flame classification of V-0 and maintaining a UL 94 vertical flame classification of V-0 after one week of heat aging at 150° C. is formed as the reaction product of an isocyanate component and an isocyanate-reactive component in the presence of a blowing agent. The isocyanate component includes an isocyanate-containing compound and a non-reactive phosphorous compound that is present in an amount ranging from 1 to 20 weight percent based on the total weight of the polyurethane foam. The isocyanate-reactive component includes a polyether polyol and expandable graphite that is present in an amount ranging from 3 to 30 weight percent based on the total weight of the polyurethane foam.
    Type: Grant
    Filed: March 5, 2014
    Date of Patent: March 6, 2018
    Assignee: BASF SE
    Inventors: Raymond Neff, Liying Wang, Alexander Gershanovich
  • Patent number: 9814187
    Abstract: Process for making a foam suitable as plant growth medium by reacting a polyisocyanate, a polyether polyol mixture and water at an isocyanate index of 90-150 wherein the polyol mixture used comprises at least 2 polyols and wherein the polyol mixture comprises less than 50% by weight oxyethylene calculated on the weight of the polyol mixture.
    Type: Grant
    Filed: October 25, 2012
    Date of Patent: November 14, 2017
    Assignee: HUNTSMAN INTERNATIONAL LLC
    Inventors: Johan Antoine Stefaan Macken, Loredana Moro, Johannes Eduward Irene Marie Josefa Clerinx, Annelies Vandevelde
  • Patent number: 9738747
    Abstract: A one component isocyanate prepolymer mixture for formulating a polyurethane product in a single step process, with monomeric methylene diphenyl diisocyanate (MDI) content in the mixture not exceeding 3%, preferably less than 2%, more preferably less than 1% of the total weight. The mixture contains monofunctional alcohol, an isocyanate component or isocyanate mixture component, propellant, catalyst, stabiliser, and one or more polyols. The monofunctional alcohol constitutes ethylene glycol ethers or propylene glycol ethers. A method for formulating a one component polyurethane foam on the basis of the mixture is disclosed.
    Type: Grant
    Filed: October 22, 2014
    Date of Patent: August 22, 2017
    Assignee: Selena Labs Sp. z o.o.
    Inventors: Przemyslaw Dwornicki, Marek Barth, Tomasz Pawlus
  • Patent number: 9695266
    Abstract: A wettable, high strength, ether foam, particularly suited for ink holders, that includes a prepolymer that is formed before adding it to other components in the foam formulation.
    Type: Grant
    Filed: March 6, 2013
    Date of Patent: July 4, 2017
    Assignee: Foamtec International Co., Ltd.
    Inventors: Joseph W. Lovette, Saranya Maungnoi
  • Patent number: 9562181
    Abstract: The present invention relates to two-component polyurethane compositions which on the one hand have a long open time and, even after extended exposure to a climate with high atmospheric humidity (e.g., 70% relative humidity), even after 40 minutes and in particular even after 60 minutes, can still be glued and cured to form polymers having high mechanical strength. The composition comprises castor oil, at least one polyol having 5-8 hydroxyl groups, a mixture of two different polyether alcohols and/or polyester polyols on the basis of castor oil or soybean oil and at least one polyisocyanate. The two-component polyurethane compositions are suitable in particular for non-positive filling joints or gaps that are joined by large-surface area structural gluing, in particular of vane half shells of rotor blades for wind power plants.
    Type: Grant
    Filed: December 20, 2011
    Date of Patent: February 7, 2017
    Assignee: SIKA TECHNOLOGY AG
    Inventors: Martin Pind, Bodil Olsen
  • Patent number: 9512260
    Abstract: The invention relates to a storage-stable resin film based on polyurethane systems having a very high characteristic number and fiber-composite components (composite components, molded bodies) produced therefrom by compressing the resin film, in combination with fiber-reinforced materials such as woven fabrics and fleece, at high temperatures and under pressure, and to a method for the production thereof.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: December 6, 2016
    Assignee: Covestro Deutschland AG
    Inventors: Florian Hupka, Marcel Schornstein, Dirk Wegener, Harald Rasselnberg
  • Patent number: 9458300
    Abstract: The invention relates to a method for producing hydrophilic, aliphatic polyurethane foams. The invention further relates to special compositions for producing polyurethane foams either using the method according to the invention or using the polyurethane foams obtained from the compositions according to the invention, and to the use of the polyurethane foams as a wound dressing, cosmetic item, or incontinence product.
    Type: Grant
    Filed: October 25, 2011
    Date of Patent: October 4, 2016
    Assignee: Covestro Deutschland AG
    Inventors: Sebastian Dörr, Meike Niesten
  • Patent number: 9382704
    Abstract: A protective air barrier air barrier sealant and methods of applying the same, including a high density polyurethane chemistry provided in an amount, volume, and density effective for providing a protective air barrier for an enclosure, wherein the polyurethane material is combined with at least one UV, fire and antimicrobial protectant for providing UV protection to UV-exposed surfaces.
    Type: Grant
    Filed: June 17, 2015
    Date of Patent: July 5, 2016
    Inventor: William Davis Collins
  • Patent number: 9364577
    Abstract: The invention relates to a specific composition comprising A) isocyanate-functional prepolymers obtainable by reaction of A1) aliphatic diisocyanates with A2) di- to hexa-functional polyalkylene oxides having an ethylene oxide content of 50 to 100 mol %, based on the total amount of the oxyalkylene groups present, B) an aqueous polyurethane suspension, an aqueous polyacrylate suspension or aqueous silica sols, especially for production of hydrophilic, aliphatic polyurethane foams. The invention further provides a process for producing a hydrophilic, aliphatic polyurethane foam, based on the inventive composition, a polyurethane foam obtainable by the process and a wound dressing comprising the polyurethane foam.
    Type: Grant
    Filed: April 30, 2012
    Date of Patent: June 14, 2016
    Assignee: Covestro Deutschland AG
    Inventors: Meike Niesten, Sebastian Dörr, Sascha Plug, Jan Schönberger
  • Patent number: 9279054
    Abstract: The present invention relates to a novel sound-absorbent foam system in the form of an open-cell mineral-organic material, which can even attain building material class B1 according to DIN 1402 and is used for reducing sound levels, in particular in interior spaces. The material is distinguished by containing lignosulphonate.
    Type: Grant
    Filed: February 4, 2009
    Date of Patent: March 8, 2016
    Assignee: Preform GmbH
    Inventors: Uwe Schoenfeld, Klaus Dippon
  • Patent number: 9228048
    Abstract: An odor-absorbing foam composition comprising a cyclodextrin crosslinked with a polyurethane prepolymer. In one embodiment, the foam includes a ratio of the cyclodextrin to the polyurethane prepolymer selected to result in formation of the foam. The odor-absorbing foam may be used in a personal care product or wound care. A process for preparing a foam, including providing a cyclodextrin; providing a polyurethane prepolymer; combining the cyclodextrin with the polyurethane prepolymer; and allowing the polyurethane prepolymer to react with water and crosslink the cyclodextrin to form the foam. A process for preparing an odor-absorbing foam article such as a personal care product, including preparing the foam and applying it or the components thereof to a suitable substrate.
    Type: Grant
    Filed: April 24, 2014
    Date of Patent: January 5, 2016
    Assignee: Avery Dennison Corporation
    Inventors: Anne Marie Wibaux, Bert Paesen
  • Patent number: 9163109
    Abstract: The invention relates to a method for producing hydrophilic, aliphatic polyurethane foams having a low bulk density. The invention also relates to a hydrophilic, aliphatic polyurethane foam which can be obtained according to said method and to the use thereof as a wound dressing, incontinence product or as a cosmetic article.
    Type: Grant
    Filed: June 20, 2011
    Date of Patent: October 20, 2015
    Assignee: Bayer Intellectual Property GmbH
    Inventors: Meike Niesten, Sebastian Dörr
  • Patent number: 9150715
    Abstract: Exterior automotive article comprising a composition comprising a polypropylene, an elastomeric copolymer, and a mineral filler, wherein said polypropylene (PP) has a comonomer content of equal or below 1.0 wt.-%, the comonomers are ethylene and/or at least one C4 to C20 a-olefin, and <2,1> erythro regiodefects of equal or more than 0.4 mol.-%, said elastomeric copolymer (EC) comprises units derived from ethylene and at least one C3 to C10 a-olefin, said composition (C) has a melt flow rate MFR2 (230° C.) in the range of 5 to 80 g/10 min.
    Type: Grant
    Filed: March 1, 2012
    Date of Patent: October 6, 2015
    Assignee: BOREALIS AG
    Inventors: Michael Tranninger, Klaus Lederer
  • Patent number: 9062149
    Abstract: The present invention relates to high-value polyurethane (PUR) and polyurethaneurea elastomers, which can be processed in a particularly simple manner by use of low-viscosity prepolymers based on naphthalene 1,5-diisocyanate, and to a process for production thereof.
    Type: Grant
    Filed: June 26, 2012
    Date of Patent: June 23, 2015
    Assignee: BAYER INTELLECTUAL PROPERTY GMBH
    Inventors: Florian Hupka, Stephan Reiter, Hartmut Nefzger, Jens Krause
  • Patent number: 9023908
    Abstract: The present invention relates to a method for adsorbing and/or absorbing oil, by bringing oil into contact with a polyurethane sponge with excellent mechanical properties.
    Type: Grant
    Filed: May 24, 2011
    Date of Patent: May 5, 2015
    Assignee: BASF SE
    Inventors: Nils Mohmeyer, Ralf Fritz, Bernd Bruchmann, Anna Cristadoro, Marcus Leberfinger, Antje van der Net
  • Patent number: 9018271
    Abstract: Embodiments of the invention provide for polyurethane flexible foams that do not require a post production crushing step. These “self crushing” flexible foams neither collapse, skin peel, nor form voids upon demolding, and yet maintain excellent physical properties such as uniform cell sizes, high quality surface appearance, compression set, resistance to fatigue, etc.
    Type: Grant
    Filed: November 2, 2011
    Date of Patent: April 28, 2015
    Assignee: Dow Global Technologies LLC
    Inventor: Alessia Battistini
  • Patent number: 9006304
    Abstract: The present invention relates to aqueous polyurethane-polyurea dispersions which stabilize a foam—produced by mechanical expansion—without addition of further foam-stabilizing components in such a way that aqueous foams are obtainable which are stable both during temporary storage and during processing, so that they can be applied in the form of foam also by customary application methods and substantially retain the foam structure even after drying.
    Type: Grant
    Filed: May 19, 2009
    Date of Patent: April 14, 2015
    Assignee: Stahl International B.V.
    Inventor: Juergen Muenter
  • Patent number: 8993648
    Abstract: A polishing pad capable of maintaining a high level of dimensional stability during absorption of moisture or water includes a polishing layer including a polyurethane foam having fine cells, wherein the polyurethane foam includes a cured product of a reaction of an isocyanate-terminated prepolymer (A), a polymerized diisocyanate, and a chain extender, and the isocyanate-terminated prepolymer (A) includes an isocyanate monomer, a high molecular weight polyol (a), and a low molecular weight polyol. A method for manufacturing such a polishing pad includes mixing a first component containing an isocyanate-terminated prepolymer with a second component containing a chain extender and curing the mixture to form a polyurethane foam. The pad so made is used in the manufacture of semiconductor devices.
    Type: Grant
    Filed: August 16, 2007
    Date of Patent: March 31, 2015
    Assignee: Toyo Tire & Rubber Co., Ltd.
    Inventors: Yoshiyuki Nakai, Tsuyoshi Kimura, Atsushi Kazuno, Kazuyuki Ogawa, Tetsuo Shimomura