Abstract: The invention relates to a method for determining polymeric product properties (1), wherein a prediction model (7) is provided for calculating polymeric product properties (1) based on production parameters on a computer system, which production parameters comprise formulation portions (2) specifying raw material portions for polymeric production and comprise processing parameters (3) specifying process properties during polymeric production, wherein user input is provided to the computer system, which user input comprises user production parameters (4) specifying a set of production parameters, user product parameters (5) specifying polymeric product properties and a proximity metric for quantifying conformity with the user product parameters (5), wherein the computer system applies the user production parameters (4) to the prediction model (7) to calculate resultant product properties (8), wherein the computer system applies the proximity metric to the resultant product properties (8) with respect to the us
Type:
Grant
Filed:
June 11, 2019
Date of Patent:
October 8, 2024
Assignee:
Covestro Intellectual Property GmbH & Co. KG
Inventors:
Giuseppe Tabbi, Christian Windeck, Karin Clauberg, Michael Loof, Roger Scholz
Abstract: Devices and methods are described for occluding the left atrial appendage (LAA) to exclude the LAA from blood flow to prevent blood from clotting within the LAA and subsequently embolizing, particularly in patients with atrial fibrillation. An implant is delivered via transcatheter delivery into the LAA. The implant includes a conformable structure comprising a foam body and internal support. The support includes anchors that penetrate the foam body and anchor the implant to the walls of the LAA. The implant provides compliance such that it conforms to the native configuration of the LAA.
Type:
Grant
Filed:
July 29, 2022
Date of Patent:
September 10, 2024
Assignee:
Conformal Medical, Inc.
Inventors:
Aaron V. Kaplan, David Melanson, Carol Devellian, Andy H. Levine, Andres Chamorro
Abstract: The present disclosure describes a flexible polyurethane foam having suspended within its matrix particles of silicon dioxide, SiO2. The particles of silicon dioxide are interspersed within the polyurethane matrix and protrude from the surface of the foam. These particles form an abrasive surface and the produced foam finds use as a cleaning material. The foam includes the use of a pre-polymer polyol formed by the reaction of triol polyol having a molecular weight of from 700 to 8000 with a polyisocyanate and a tin catalyst. The produced foam is much more durable than commercially available melamine foams and is an effective cleaning foam.
Abstract: A packaging material for a power storage device includes a base material layer as an outer layer, a heat fusible resin layer as an inner layer, and a metal foil layer arranged between both the layers. The base material layer and the metal foil layer are adhered via an outer adhesive layer. The outer adhesive layer is formed of a cured film of a two-part curing type urethane adhesive agent including a main agent containing a polyol and a multifunctional isocyanate mixture, wherein a content rate of the polyol is 50 mass % to 95 mass %. The multifunctional isocyanate mixture is composed of a mixture containing an aromatic multifunctional isocyanate and an aliphatic multifunctional isocyanate having an aromatic ring.
Abstract: The present disclosure provides for a polyurethane elastomer foam formed by reacting a mixture that includes 60 to 50 weight percent (wt. %) of a polyol formulation and 40 to 50 wt. % isocyanate pre-polymer (wt. % based on the total weight of the mixture). The polyol formulation includes 85 to 92 wt. % of a polytetramethylene ether glycol (PTMEG) with a weight average molecular weight of 1900 to 2100 and a hydroxyl number of about 53 to about 60; 4 to 10 wt. % of monoethylene glycol; a blowing agent; a catalyst; and a surfactant (wt. % values for the polyol formulation based on the total weight of the polyol formulation). The isocyanate pre-polymer includes 55 to 70 wt. % of a isocyanate blend having at least 90 wt. % of 4,4?-diphenylmethane diisocyanate; and 30 to 45 wt. % of the PTMEG, where the isocyanate pre-polymer has an isocyanate content of 16 to 21 wt.
Type:
Grant
Filed:
March 2, 2018
Date of Patent:
May 17, 2022
Assignees:
Dow Global Technologies LLC, Dow Italia Divisione Commerciale S.R.L.
Abstract: A bag-shaped structure excellent in both creep resistance and flexibility is provided. Provided is a bag-shaped structure (122) including a layer (122a) made of a thermoplastic elastomer foam. Also provided are a cuff for a blood pressure monitor and a blood pressure monitor each including the bag-shaped structure (122).
Abstract: To provide a polycarbodiimide copolymer and a modified polycarbodiimide copolymer each suitable for a curing agent that can allow a cured product of a carboxy group-containing resin composition to be improved in flexibility without any loss of water resistance, as well as a curing agent of a carboxy group-containing resin composition, and a carboxy group-containing resin composition. The present invention enables a cured product to be enhanced in water resistance due to introduction of a predetermined soft segment into a polycarbodiimide molecule, in use for a curing agent, and also enables a carboxy group-containing resin composition to be enhanced in storage stability due to modification with an aliphatic amine or an aromatic heterocyclic amine.
Abstract: An embodiment includes a wound dressing comprising: a shape memory polymer (SMP) foam, including open cells, having first and second states; and a hydrogel (HG) included within the cells; wherein (a) in a first position a composite, including the SMP foam and the HG, is configured to be located proximate a hemorrhagic tissue with the SMP foam in the first state; (b) in a second position the composite is configured to be expanded to the second state against the hemorrhagic tissue when the SMP foam is plasticized at 37° C. depressing a glass transition temperature (Tg) of the SMP foam to below 25° C. Other embodiments are described herein.
Type:
Grant
Filed:
March 14, 2019
Date of Patent:
June 1, 2021
Assignees:
LAWRENCE LIVERMORE NATIONAL SECURITY, LLC, THE TEXAS A&M UNIVERSITY SYSTEM
Inventors:
Duncan J. Maitland, Todd Lawrence Landsman, Tyler Joseph Touchet, Elizabeth L. Cosgriff-Hernandez, Thomas S. Wilson
Abstract: A method of forming a polyisocyanurate foam board includes providing a polyol and adding an isocyanate to the polyol to form a polyisocyanurate foam. A first inner surface of a first facer material is treated with a first flow of hydroxyl containing molecules. A second inner surface of a second facer material is treated with a second flow of hydroxyl containing molecules. The polyisocyanurate foam is coupled to the first treated inner surface and the second treated inner surface such that the polyisocyanurate is sandwiched between the first facer material and the second facer material, thereby exposing opposing outer surfaces of the polyisocyanurate foam to the hydroxyl containing molecules. A density of a medial portion of the polyisocyanurate foam is greater than a density of the polyisocyanurate at the opposing outer surfaces.
Type:
Grant
Filed:
March 26, 2018
Date of Patent:
May 25, 2021
Assignee:
Johns Manville
Inventors:
Richard Gombar, Carine Machaalani, John M Dodi
Abstract: Provided is a foamed urethane containing a cushion material, the foamed urethane containing a hard segment and a soft segment, in which the foamed urethane is a reaction cured product formed using an isocyanate component of an MDI compound. In a first aspect, a spin-spin relaxation time (T2) of the hard segment in the foamed urethane is from 20 ?sec to 40 ?sec, and a volume abundance ratio of the hard segment is from 5% to 40%. In a second aspect, a foamed urethane includes: a first region in which T2 of the hard segment is from 30 ?sec to 40 ?sec, and a volume abundance ratio of the hard segment is from 10% to 40%, and a second region in which T2 of the hard segment is from 20 ?sec to less than 30 ?sec, and a volume abundance ratio of the hard segment is from 5% to 40% in a H1 solid-state pulse NMR measurement, and which is adjacent to the first region.
Abstract: The present invention relates to a process for hydrogenating a mixture (G1) in the presence of a catalyst, where the mixture (G1) comprises at least one colorless amine and at least one color-imparting component. As a result of the hydrogenation step, the at least one color-imparting component is firstly partially, preferably fully, hydrogenated, while the colorless amine, in particular aniline, is not hydrogenated or hydrogenated to only a very small extent. The color-imparting components which cause the discoloration of the amine which is itself in principle colorless are thus removed by hydrogenation, as a result of which purification of the colorless amine or the mixture (G1) is achieved.
Type:
Grant
Filed:
August 31, 2017
Date of Patent:
February 23, 2021
Assignee:
BASF SE
Inventors:
Andreas Weickgenannt, Silvia Tauro, Alexander Duefert, Viktor Ladnak, Kai Thiele
Abstract: Polyurethane foams including a polyurethane prepolymer composition, a catalyst, and a propellant are provided. The polyurethane prepolymer composition is produced from a formulation that includes an isocyanate reactive component in an amount of from about 1% to about 70% by weight based on the polyurethane prepolymer composition and an isocyanate component in an amount of from about 1% to about 70% by weight based on the polyurethane prepolymer composition. The isocyanate component includes toluene diisocyanate biuret in an amount of from about 1 to about 100% by weight based on the isocyanate component. The isocyanate reactive component includes one or more polyols. The polyurethane prepolymer composition has a viscosity of less than about 10,000 mPa*s at 50° C. and is substantially free of monofunctional reactive components. The polyurethane prepolymer composition also includes a free isocyanate monomer content of the toluene diisocyanate biuret of less than about 1% by weight.
Abstract: Systems and methods related to polymer foams for the treatment of blood vessel dissections are generally described. Some embodiments relate to compositions and methods for the preparation of polymer foams, and methods for using the polymer foams. The polymer foams can be applied to or within a dissection caused by an intimal tear in a blood vessel, sealing the dissection and preventing further perfusion thereof. In some embodiments, the polymer foam can be formed within a body cavity (i.e., in-situ foam formation). The foam may be used to fill the dissection as a thrombosing agent. In addition, the foam may be used in conjunction with medical devices such as stents, stent-grafts, balloons, and catheters.
Abstract: A novel phosphate polyol formulation is described, comprising a polyester polyol, a flame retardant comprising a phosphate polyol, a blowing agent, a catalyst, a surfactant, and a fire-retardant aromatic isocyanate. A further embodiment includes a phosphorus compound, such as a phosphate, a phosphate ester, or an alkyl phosphate such as triethyl phosphate.
Type:
Grant
Filed:
October 24, 2017
Date of Patent:
May 19, 2020
Assignee:
ELÉ CORPORATION
Inventors:
Yogi Patel, Floy Pelletier, Edward L Eubank, Mark Listemann
Abstract: The present disclosure relates to a method of making polyurethane foam, the method comprising providing a polyol mixture comprising polyether polyol and unmodified vegetable oil having a hydroxyl number of less than 10; and reacting isocyanate with the polyol mixture to form a polyurethane foam, wherein the unmodified vegetable oil does not react and does not form part of the polyurethane foam. The present disclosure also relates to polyurethane formed by the method and polyurethane compositions.
Type:
Grant
Filed:
March 13, 2014
Date of Patent:
April 14, 2020
Assignee:
LEAR CORPORATION
Inventors:
Robert D. Dawe, Edmund J. Madaj, Ashford A. Galbreath, Asad S. Ali
Abstract: The present invention relates to expanded thermoplastic polyurethane beads, a preparation method for same, and an application thereof. The expanded thermoplastic polyurethane beads consists of components of the following parts by weight: 100 parts of a thermoplastic polyurethane, 1-10 parts of a cell size stabilizer, and 1-35 parts of a melt viscosity modifier. The preparation method for the expanded thermoplastic polyurethane beads is also disclosed. The bead is produced by employing a volatile blowing agent to immerse the thermoplastic polyurethane, comprising the pore size stabilizer and the melt viscosity modifier, in an aqueous suspension, and is then followed by the foaming process. Utilization of the expanded thermoplastic polyurethane beads of the present invention allows for preparation of a foam product. The expanded thermoplastic polyurethane beads prepared per the present invention has uniform cell sizes and a high product yield.
Type:
Grant
Filed:
July 21, 2014
Date of Patent:
December 31, 2019
Assignee:
Miracll Chemicals Co., Ltd.
Inventors:
Bo Huang, Renhong Wang, Guangfu Wang, Sheng Zhang, Qijun Sun
Abstract: The invention relates to a crystallization stable polyester prepolymers for producing HDI- and PDI-based, solvent free two component (2K)-polyurethane- and/or polyurea coating agents.
Abstract: An embodiment includes a wound dressing comprising: a shape memory polymer (SMP) foam, including open cells, having first and second states; and a hydrogel (HG) included within the cells; wherein (a) in a first position a composite, including the SMP foam and the HG, is configured to be located proximate a hemorrhagic tissue with the SMP foam in the first state; (b) in a second position the composite is configured to be expanded to the second state against the hemorrhagic tissue when the SMP foam is plasticized at 37° C. depressing a glass transition temperature (Tg) of the SMP foam to below 25° C. Other embodiments are described herein.
Type:
Grant
Filed:
March 18, 2015
Date of Patent:
April 23, 2019
Assignees:
Lawrence Livermore National Security, LLC, The Texas A&M University System
Inventors:
Duncan J. Maitland, Todd Lawrence Landsman, Tyler Joseph Touchet, Elizabeth L. Cosgriff-Hernandez, Thomas S. Wilson
Abstract: A cardanol modified epoxy polyol may be used for forming a polyurethane resin system for use in applications such as coatings and composites formed by filament winding. The polyurethane resin system includes an isocyanate-reactive component that has a first cardanol component and the cardanol-modified epoxy polyol, and includes an isocyanate component that includes at least one polyisocyanate. The cardanol-modified epoxy polyol is a reaction product of an epoxy component and an epoxy-reactive component at a ratio of epoxy groups to epoxy reactive groups from 1:0.95 to 1:5, and the epoxy-reactive component includes a second cardanol component.
Type:
Grant
Filed:
November 27, 2013
Date of Patent:
December 4, 2018
Assignee:
Dow Global Technologies LLc
Inventors:
Jiang Li, Yi Zhang, Wei Li, Beilei Wang, Paolo Diena
Abstract: Disclosed are a colored TPU foam material, a preparation method and a use thereof, as we as a method for preparing a shaped body, a sheet and a shoe material by using same. The colored TPU foam material is composed of colored foam particles or colored foam sheets; the concentration of a pigment in the colored foam particles or the colored foam sheets is 0.01-5 wt %; the pigment has the same concentration inside and outside the colored TPU foam material, and the colored TPU foam material has a hardness of shore A 5-65, a density of 0.05-0.5 g/cm3, and an average cell size of less than 100 ?m. The present invention has features such as a good internal and external color uniformity, no wrinkles being present on the surface, etc.
Abstract: Foamed thermoplastic elastomeric polyurethane and ethylene-vinyl acetate copolymer articles are made with from about 0.1 to about 4 weight percent of supercritical fluid nitrogen based on polymer weight and from about 0.1 to about 5 weight percent of a supercritical fluid carbon dioxide based on polymer weight, with the supercritical fluid nitrogen and the supercritical fluid carbon dioxide being separately added to the molten polymer.
Abstract: A metal cap has an outer surface with a coating film including a coating composition containing thermally expandable hollow particles in a paint, the curing initiation temperature TA (° C.) of the paint, expressed as a temperature where an attenuation rate by a rigid pendulum viscoelasticity test reaches an inflection point, satisfies TA?Ta+25 Ta being the expansion initiation temperature (° C.) of the thermally expandable hollow particles, and the maximum curing temperature TB (° C.) of the paint, expressed as a temperature where the attenuation rate by the rigid pendulum viscoelasticity test reaches a peak, satisfies Tb?10?TB?Tb+10 Tb being the maximum expansion temperature (° C.) of the thermally expandable hollow particles. Because of these features, a metal cap is excellent in grip and openability even when dew condensation occurs, and is also excellent in scratch resistance, is provided with high efficiency.
Abstract: A chemical mechanical polishing pad is provided, comprising: a chemical mechanical polishing layer having a polishing surface; wherein the chemical mechanical polishing layer is formed by combining (a) a poly side (P) liquid component, comprising: an amine-carbon dioxide adduct; and, at least one of a polyol, a polyamine and a alcohol amine; and (b) an iso side (I) liquid component, comprising: polyfunctional isocyanate; wherein the chemical mechanical polishing layer has a porosity of ?10 vol %; wherein the chemical mechanical polishing layer has a Shore D hardness of <40; and, wherein the polishing surface is adapted for polishing a substrate. Methods of making and using the same are also provided.
Type:
Grant
Filed:
May 24, 2016
Date of Patent:
October 3, 2017
Assignees:
Rohm and Haas Electronic Materials CMP Holdings Inc., Dow Global Technologies LLC
Inventors:
Bainian Qian, Julia Kozhukh, Teresa Brugarolas Brufau, David Michael Veneziale, Yuhua Tong, Diego Lugo, Jeffrey B. Miller, George C. Jacob, Marty W. DeGroot, Tony Quan Tran, Marc R. Stack, Andrew Wank, Fengji Yeh
Abstract: A polyester polyol is formed in a polycondensation reaction between an aromatic dicarboxylic acid, a polyol, and an epoxy compound having a straight chain alkyl or alkenyl group having at least six carbon atoms. The polyester polyol exhibits excellent compatibility with hydrocarbon blowing agents. As such, it is a useful component in rigid polyurethane foam formulations that are contain hydrocarbon blowing agents.
Abstract: A rigid foam having increased flame retardance comprises the reaction product of an isocyanate component and an isocyanate-reactive component. The isocyanate component and an isocyanate-reactive component are reacted in the presence of an isocyanurate catalyst component and a carbodiimide catalyst component. The isocyanurate catalyst component comprises 1,3,5-tris(3-(dimethylamino)propyl)-hexahydro-s-triazine and the carbodiimide catalyst component comprises 3-methyl-1-phenyl-2-phospholene-1-oxide. A method of forming the rigid foam on a surface comprises the steps of providing the isocyanate component, providing the isocyanate-reactive component, providing the isocyanurate catalyst component, providing the carbodiimide catalyst component, and spraying the isocyanate component, isocyanate-reactive component, isocyanurate catalyst component, and carbodiimide catalyst component onto the surface to form the rigid foam on the surface.
Type:
Grant
Filed:
January 14, 2014
Date of Patent:
August 29, 2017
Assignee:
BASF SE
Inventors:
Charles Elwood Jones, Todd William Wishneski
Abstract: Disclosed is a semiconductor device that is configured to contain a sealing layer for sealing a semiconductor element supported on a base, the sealing layer being configured to have a nanocomposite structure that comprises a large number of nanometer-sized (1 ?m or smaller) insulating nanoparticles composed of SiO2, and an amorphous silica matrix that fills up the space around the insulating nanoparticles without voids and gaps.
Abstract: The invention relates to metastable polymer compositions, use thereof for manufacturing medical devices or medical device components having a slippery surface as well as the devices with slippery surfaces resulting from these metastable polymer compositions, in particular in the field of ophthalmic injectors.
Abstract: A chemical mechanical polishing pad is provided containing: a polishing layer having a polishing surface; wherein the polishing layer comprises a first continuous non-fugitive polymeric phase and a second non-fugitive polymeric phase; wherein the first continuous non-fugitive polymeric phase has a plurality of periodic recesses; wherein the plurality of periodic recesses are occupied with the second non-fugitive polymeric phase; wherein the first continuous non-fugitive polymeric phase has an open cell porosity of ?6 vol %; wherein the second non-fugitive polymeric phase contains an open cell porosity of ?10 vol %; and, wherein the polishing surface is adapted for polishing a substrate.
Type:
Grant
Filed:
June 26, 2015
Date of Patent:
April 25, 2017
Assignees:
Rohm and Haas Electronic Materials CMP Holdings, Inc., Dow Global Technologies LLC
Inventors:
Bainian Qian, Julia Kozhukh, Teresa Brugarolas Brufau, Diego Lugo, George C. Jacob, Jeffrey B. Miller, Tony Quan Tran, Marc R. Stack, Jeffrey James Hendron
Abstract: The present invention relates to a polyurethane foam obtained from a polyurethane raw material containing polyol, isocyanate, a foam stabilizer, a catalyst and a foam-forming gas by a mechanical froth method, wherein the polyol contains a castor oil-based polyol having a viscosity at 25° C. of 2,000 mPa·s or less, and a polyether-based polyol, the castor oil-based polyol is contained in an amount of from 20 to 80 parts by weight per 100 parts by weight of the polyol, the polyether-based polyol is contained in an amount of from 20 to 80 parts by weight per 100 parts by weight of the polyol, the polyurethane foam has an apparent density of from 100 to 700 kg/m3, and compressive residual strain at 100° C. of 20% or less, and the polyurethane foam can be preferably used as a sealing material in a neighboring region of a heat source.
Abstract: A system for occluding a physical anomaly. One embodiment comprises a shape memory material body wherein the shape memory material body fits within the physical anomaly occluding the physical anomaly. The shape memory material body has a primary shape for occluding the physical anomaly and a secondary shape for being positioned in the physical anomaly.
Type:
Grant
Filed:
May 20, 2015
Date of Patent:
March 21, 2017
Assignee:
Lawrence Livermore National Security, LLC
Abstract: A chemical mechanical polishing pad is provided, comprising: a chemical mechanical polishing layer having a polishing surface; wherein the chemical mechanical polishing layer is formed by combining (a) a poly side (P) liquid component, comprising: an amine-carbon dioxide adduct; and, at least one of a polyol, a polyamine and a alcohol amine; and (b) an iso side (I) liquid component, comprising: polyfunctional isocyanate; wherein the chemical mechanical polishing layer has a porosity of ?10 vol %; wherein the chemical mechanical polishing layer has a Shore D hardness of <40; and, wherein the polishing surface is adapted for polishing a substrate. Methods of making and using the same are also provided.
Type:
Grant
Filed:
June 26, 2015
Date of Patent:
March 7, 2017
Assignees:
Rohm and Haas Electronic Materials CMP Holdings, Inc., Dow Global Technologies LLC
Inventors:
Bainian Qian, Julia Kozhukh, Teresa Brugarolas Brufau, David Michael Veneziale, Yuhua Tong, Diego Lugo, Jeffrey B. Miller, George C. Jacob, Marty W. DeGroot, Tony Quan Tran, Marc R. Stack, Andrew Wank, Fengji Yeh
Abstract: The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a non-amine catalyst used alone or in combination with an amine catalyst.
Type:
Grant
Filed:
February 20, 2012
Date of Patent:
January 31, 2017
Assignee:
HONEYWELL INTERNATIONAL INC.
Inventors:
Michael A. Ross, Ronald Grossman, David J. Williams, Clifford P. Gittere
Abstract: An additive composition for inhibiting scorch in a polyurethane foam composition, the additive comprising a derivatized hydroquinone; a derivatized lactone; and a derivatized phenolic compound. A polyurethane foam composition contains the additive composition.
Abstract: Polyurethane cushions are formed on the surface of a textile such as carpet. The polyurethane is made in the reaction of a polyurethane forming composition that is frothed, and contains water as a blowing agent. The polyurethane forming composition is cured between the substrate and a containment layer, both of which prevent the blowing gasses from escaping during the curing process. The process allows low density attached cushions to be formed controllably.
Type:
Grant
Filed:
January 19, 2007
Date of Patent:
October 18, 2016
Assignee:
Dow Global Technologies LLC
Inventors:
James K. Jennings, Thomas H. Perry, Randall C. Jenkines, Allen L. Atkinson
Abstract: An object of the present invention is to provide a moisture-curable polyurethane hot-melt resin composition with superior properties such as water resistance, fast-curing properties, and flexibility. The present invention provides a moisture-curable polyurethane hot-melt resin composition containing an isocyanate-containing urethane prepolymer (i) that is a reaction product of polyols (A) including a polyether polyol (A-1), a crystalline polyester polyol (A-2), an amorphous polyester polyol (A-3), and an acrylic polyol (A-4) with a polyisocyanate (B); and a curing catalyst (ii) represented by general formula (1) below, and also provides an adhesive and article produced using the resin composition. The adhesive produced using the moisture-curable polyurethane hot-melt resin composition according to the present invention is suitable not only for the bonding of fibers and the lamination of construction materials, but also for the lamination of optical elements.
Abstract: A vaso-occlusive device delivery assembly includes a pusher assembly and a vaso-occlusive device detachably coupled to the pusher assembly by an attachment member is frictionally secured within a lumen of the pusher assembly. A heat generating member is disposed in the pusher assembly lumen, along with a pressure generating material, such that, when heat is generated by the heat generative device, the pressure generating material increases a pressure in the pusher assembly lumen, thereby dislodging the attachment member from the pusher assembly and detaching the vaso-occlusive device from the pusher assembly.
Type:
Grant
Filed:
March 12, 2014
Date of Patent:
September 27, 2016
Assignees:
Stryker Corporation, Stryker European Holdings I, LLC
Inventors:
Lantao Guo, Hancun Chen, Richard Murphy
Abstract: A housing component of a handheld electronic device, the housing component comprising a cellular material which has a density of from 0.02 to 0.6 g/cc and a Young's modulus of from 32 to 5500 Mpa, the cellular material being three-dimensionally shaped to form a substantially resilient body. There is also disclosed a method of manufacturing a housing component of a handheld electronic device, the method comprising the steps of: a. providing a cellular material; and b. three-dimensionally shaping the cellular material to form a substantially resilient body in the form of a housing component of a handheld electronic device.
Type:
Grant
Filed:
December 21, 2012
Date of Patent:
September 20, 2016
Assignee:
Gurit (USA) Inc.
Inventors:
Garry Christopher Jolliffe, Chai Zachary Pocknett, Sam Shehyee Ang, Richard Alden Downs-Honey, Matthew Evan Bodoff
Abstract: Embodiments of the invention provide for viscoelastic polyurethane foams. The foams are made from reaction system which includes (a) an isocyanate reactive component, (b) a isocyanate component, (c) one or more blowing agents, (d) a catalyst component, and (e) a silicone based surfactant. The isocyanate reactive component includes at least (i) from 25 to 80% by weight of at least one polyoxyethylene capped polyoxypropylene/polyoxyethylene polyol having a combined number average equivalent weight from 1300 to 1700, a polyoxyethylene percentage of between 75% and 95% by weight of the combined amounts of polyoxypropylene and polyoxyethylene, and a primary OH percentage of between 80 and 95% of the total number of OH groups of the polyoxyethylene capped polyoxypropylene/polyoxyethylene polyol, and (ii) from 5 to 30% by weight of the isocyanate reactive component of at least one low functionality polyol having a functionality of between 1.5 and 2.
Type:
Grant
Filed:
September 20, 2012
Date of Patent:
September 13, 2016
Assignee:
Dow Global Technologies LLC
Inventors:
Elisa Corinti, Andrea Benvenuti, Alessio Sabadini, Jean-Paul Masy, Francois M. Casati, Brian Dickie
Abstract: Disclosed are a polyol with a molecular weight distribution Mw/Mn of 4 or more, obtained by reacting a compound comprising an alkylene oxide compound (II) having a hydroxyl group in a base polyol (I) with a molecular weight of 2000 or more; and a polyol composition for a flexible polyurethane foam, comprising a polyol compound and a crosslinker, wherein the crosslinker comprises a polyol (a) with a hydroxyl value of 50 to 1100 mgKOH/g and with a primary hydroxylate ratio of 25% or more and 60% or less, which is obtained by an addition of a compound comprising alkylene oxide compound (ii) having a hydroxyl group to active hydrogen compound (i).
Type:
Grant
Filed:
August 8, 2011
Date of Patent:
July 5, 2016
Assignee:
MITSUI CHEMICALS & SKC POLYURETHANES INC.
Abstract: Embodiments of the invention provide for low density flexible polyurethane foams are reaction products of reaction systems including at least one polyol and at least one isocyanate including at least 50% by weight of an MDI based isocyanate. The flexible polyurethane foam has a density of less than about 33 kg/m3 as determined according to ASTM D 3574-01, a tear strength of more than about 160 N/m as determined according to NBR 8515:2003 and a resiliency of at least 45% as measured according to ASTM D-3574-H.
Type:
Grant
Filed:
February 13, 2012
Date of Patent:
January 5, 2016
Assignees:
Dow Global Technologies LLC, Dow Brasil Sudeste Industrial LTDA.
Inventors:
Bruno Cesar Silva Motta, Venkat S. Minnikanti, Rogelio R. Gamboa
Abstract: A reactor includes a reaction part and a removal part. The reaction part is configured to generate at least two products as a result of a reaction of an unreacted material. The removal part is configured to selectively occlude at least one product from the at least two products so as to separate and remove the at least one product. The removal part includes an absorbent and a cooling unit. The absorbent releases heat at time of the selective occlusion of the at least one product. The cooling unit is configured to remove the heat released by the absorbent.
Abstract: A process for producing high resilience flexible polyurethane foams. The process includes forming a mixture of (a) isocyanate prepolymer, (b) polymeric compounds having isocyanate-reactive groups, (c) castor oil, (d) optionally chain-extending and/or crosslinking agents, (e) catalysts, (f) blowing agents, and optionally (g) additives, and reacting the mixture to form the flexible polyurethane foam. More than 5 wt % of (c) is used, based on the total weight of components (b) to (g), and (a) is obtained by mixing diphenylmethane diisocyanate (a1) and polyol 1 (a2) and also optionally further polyols, chain extenders and/or crosslinkers, where (a2) includes a polyalkylene oxide polyol having a hydroxyl number of 30 to 60, an average functionality of 2.3 to 3.2 and a propylene oxide fraction, based on the alkylene oxide content, of 70 to 100 wt %. A polyurethane foam obtained by the process, and the use of such a foam as an auto seat.
Type:
Grant
Filed:
May 23, 2012
Date of Patent:
October 6, 2015
Assignee:
BASF SE
Inventors:
Andre Meyer, Heinz-Dieter Lutter, Christoph Leseberg, Annika Johann-Krone
Abstract: The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a non-amine catalyst used alone or in combination with an amine catalyst.
Type:
Grant
Filed:
February 20, 2012
Date of Patent:
June 9, 2015
Assignee:
HONEYWELL INTERNATIONAL INC.
Inventors:
David J. Williams, Mary C. Bogdan, Clifford P. Gittere, Andrew J. Poss
Abstract: Polyurethane foams are made using a biuret-modified MDI and/or PMDI as the isocyanate component. The isocyanate is characterized by having a high content of biuret-containing oligomers and, preferably, a low proportion (if any) of biuret-urea oligomers. Flexible, resilient foams made using this biuret-modified isocyanate perform well on flammability tests such as the UNI 9175 CS. E. RF4 test, even without added flame retardants.
Type:
Grant
Filed:
December 16, 2010
Date of Patent:
May 19, 2015
Assignee:
Dow Global Technologies LLC
Inventors:
Alessia Battistini, Gianluca Casagrande, Luigi Bertucelli, Alessio Sabadini
Abstract: A method of manufacturing polyurethane (PU) foam toys with no restriction on playing environment comprises steps as follows: (1) Placing the prefabricated flexible cover into the foaming mold, and then vacuuming to firmly attach the cover to the inner wall of the mold; (2) Spraying adhesives at the periphery and the interior of the flexible cover while maintaining the continuous vacuum pressure; (3) Injecting the mixed polyurethane into the foaming mold; (4) Closing the mold and performing condensation reaction; (5) Opening the mold to get the product. The present invention is about the production of polyurethane form toys by formulating polyurethanes and binding the interior polyurethane body and flexible cover with adhesives. Because of its resilient and sturdy characteristics, the thermoplastic flexible cover provides protection to the interior polyurethane foam body, effectively eliminating problems like mildew growth, difficulties of cleaning and preventing damage.
Abstract: A reaction system comprising (a) a polyisocyanate component and (b) an isocyanate reactive component for preparation of a polyurethane foam having high air flow with low compression set is provided. The isocyanate reactive component comprises (i) from 45 to 70% by weight of one or more PO-rich polyols having a combined number average equivalent weight from 210 to 510, (ii) from 20 to 30% by weight of one or more ethylene oxide polyols having a combined number average equivalent weight from 200 to 500, (iii) from 10 to 25% by weight of one or more ethylene oxide-alkylene oxide polyethers having a combined number average equivalent weight from 300 to 800; and (iv) from 0.5 to 15% by weight of one or more PO-rich polyols having a functionality of 1 to 4 and a combined number average equivalent weight of 2,000 to 6,000.
Type:
Grant
Filed:
August 29, 2011
Date of Patent:
May 12, 2015
Assignee:
Dow Global Technologies LLC
Inventors:
Kaoru Aou, Rogelio R. Gamboa, Hongming Ma
Abstract: Flexible polyurethane foam is made by mixing prepolymer with foam-forming ingredients comprising isocyanate and water which react to give carbon dioxide. The prepolymer is hydroxyl-tipped, being made by reacting polyol with less than the theoretical proportion of isocyanate required to react with available hydroxyl groups of the polyol. The prepolymer is a new storage stable starting material for use in making flexible polyurethane foam, and the foam produced with the prepolymer has advantageous properties with regard to hydrolysis resistance. The prepolymer may be made with low or high viscosity by appropriate selection of the proportion of isocyanate which reacts with the polyol. At high viscosities cell structure can be advantageously controlled by appropriate gasification or degasification during foaming.
Type:
Grant
Filed:
May 12, 2005
Date of Patent:
May 5, 2015
Assignee:
Fritz Nauer AG
Inventors:
Hans Frei, Henri Mispreuve, Reinold Naescher, Kurt Schoenenberger, Stefano Tenzi
Abstract: Embodiments of the invention provide for polyurethane flexible foams that do not require a post production crushing step. These “self crushing” flexible foams neither collapse, skin peel, nor form voids upon demolding, and yet maintain excellent physical properties such as uniform cell sizes, high quality surface appearance, compression set, resistance to fatigue, etc.
Abstract: A polyurethane foam article comprises a first lift, a second lift, and a pass-line therebetween. The polyurethane foam article comprises the reaction product of an isocyanate-reactive resin composition, an isocyanate, and an indicator dye in the presence of a blowing agent. The indicator dye imparts a color in the first and second lifts and at the pass-line at a first temperature below a decomposition temperature of the indicator dye. The indicator dye chemically decomposes to impart a change in color in the first and second lifts and at the pass-line at a second temperature which is at or above the decomposition temperature of the indicator dye.
Type:
Grant
Filed:
June 17, 2011
Date of Patent:
April 21, 2015
Assignee:
BASF SE
Inventors:
Kevin Burgess, Greg Gardin, Jian Ying Zang, Chris Janzen
Abstract: The present invention relates to poured-in place polyurethane foams and polyol premixes comprising 1-chloro-3,3,3-trifluoropropene (HFCO-1233zd) and one or more additional co-blowing agents.