Abstract: A process for preparing an aqueous dispersion of composite particles composed of addition polymer and finely divided inorganic solid is described.

Abstract: A bone cement mixture comprised of a polymer component containing an x-ray contrast medium and a monomer component, wherein the x-ray contrast medium is a polymer or copolymer having compounds of radio-opaque elements bonded thereto, or is in the form of substantially spherical polymer or copolymer particles with radio-opaque inorganic nano-particles dispersed therein.

Abstract: Particulate composite material with an average particle size of 20 to 50 ?m and a maximum content of particles with a size of <10 ?m of 10 wt.-% and its use for the preparation of dental materials.

Abstract: The polylactic acid composite material of the present invention comprises a polylactic acid, a low molecular weight compound which has an amide group, and a layered clay mineral that is organically modified by means of an organic onium salt. As a result, a polylactic acid composite material that has a sufficiently rapid crystallization rate, and that is superior in terms of heat resistance, moldability and mold release characteristics can be obtained.

Abstract: A coating containing pigment particles and a polymer matrix is provided. The coating contains pigment particles that have a scattering coefficient with a linear or quasi-linear relationship to the pigment volume concentration of those pigment particles. The coating has improved hiding and is useful as a protective coating or an aesthetic coating on an underlying substrate. Also provided are compositions useful for preparing the coating, including covalently bonded composite particles and aqueous dispersions containing composite particles. The composite particles each contain a pigment particle with a plurality of polymer particles attached by adsorption on the outer surface of the pigment particle or by covalent bonding to the pigment particle through a coupling agent. Methods to prepare the composite particles and coating compositions containing the composite particles are also provided.

Abstract: Provided are ink jet ink excellent in dispersion stability and ejection stability and capable of forming images with fastness, abrasion resistance, color developability, and high density with little feathering; a microencapsulated pigment (MCP) providing the ink and a process of making the same; and an aqueous dispersion of the MCP. The MCP comprises pigment particles having a hydrophilic group on their surface (hydrophilized pigment particles) and coated with a polymer by emulsion polymerization. The process comprises emulsion polymerization in the presence of the hydrophilized pigment particles. The ink essentially contains the MCP and water.

Abstract: This invention is related to a polyester resin composition comprising: a thermoplastic polyester resin and a polyether compound-treated layered material having layers respectively exfoliated by one another, which satisfies at least one of the conditions (i) to (v) given below: (i) That said polyether compound has a hydroxyl value of not more than 30 mg KOH/g; (ii) That said polyether compound has a cyclic hydrocarbon group: (iii) That said polyester resin composition comprises a phosphorus-containing compound; (iv) That said polyester resin composition comprises an epoxy-containing compound; (v) That said polyester resin composition is obtainable by melt-kneading the thermoplastic polyester resin and the polyether compound-treated layered material having layers respectively exfoliated by one another and then treating the mixture for increasing the molecular weight of the polyester resin.

Abstract: Various modified pigment products are described which are preferably capable of being dispersed in a variety of materials such as coatings, inks, toners, films, plastics, polymers, elastomers, and the like. The modified pigments are pigments having attached groups, such as polymeric groups, onto the pigment by means other than adsorption. A modified pigment product is described comprising a pigment having attached at least one group comprising the formula: —X—[NIon]pR wherein X comprises an aromatic group or an alkyl group, NIon comprises at least one type of non-ionic group, R represents hydrogen or comprises an aromatic group or an alkyl group, and p represents an integer of from 1 to 500. Modified pigment products are also described comprising a pigment having attached at least one alkylene oxide group or at least one polymeric group.

Abstract: A method of self-healing cracks in a cured epoxy base underfill material between an I/C chip and a substrate is provided. A plurality of capsules is dispersed in the epoxy base. Each capsule has a curable thermosetting adhesive encapsulated in a rupturable shell to disperse the thermosetting adhesive in a crack in the epoxy base when the shell ruptures. Each capsule is less than 25 microns in diameter. A curing agent that will cause a reaction of the thermosetting adhesive on contact is dispersed in the epoxy to form a cured adhesive in a crack in said epoxy base. The shell will rupture when encountering a crack being propagated in the underfill material, which will at least partially fill the crack with the adhesive, and cure the adhesive with the curing agent to bond the edges of the crack together. The invention also includes the structure for crack self-healing.

Abstract: The present invention provides a decolorized red phosphorus composition capable of inhibiting coloring in dark red peculiar to red phosphorus even when kneaded with a resin or the like, modified red phosphorus used for the decolorized red phosphorus composition and a production method therefor, and a flame-retardant polymer composition using the decolorized red phosphorus composition. The modified red phosphorus includes red phosphorus particles (A) whose surfaces are coated with a modified resin film (F) containing white particles (B) having a whiteness of 70 or more, color particles (C) having a hue H of 30 to 80 in the Munsell color-system hue circle, and a binder resin (D). The decolorized red phosphorus composition includes a mixed powder containing the modified red phosphorus and white particles (B) having a whiteness of 70 or more. The flame-retardant polymer composition contains the decolorized red phosphorus composition and a polymer compound (I).

Abstract: An electromagnetic wave-absorbing composition is obtained by dispersing in a base polymer a magnetic powder coated with electrically insulating inorganic fines and optionally, a heat conductive powder. The composition has a high breakdown voltage, and can be applied to any adequate site within electronic equipment without a need to pay substantial attention to short-circuits.

Abstract: An ink set for ink jet recording and an ink jet recording process, which can provide not only high weather resistance but also images having a high printed density by using pigment inks, and have a wide color reproducing range. Also, an ink jet recording process capable of performing text printing at a high printing density and with excellent abrasion resistance. Furthermore, recorded matter having images formed at a high printed density and over a wide color reproducing range, and text printed matter (recorded matter) having a high printed density and being excellent in abrasion resistance The ink set for ink jet recording includes a black ink containing at least “carbon black dispersible in an aqueous medium without a dispersing agent”, at least one color ink containing at least “a colorant enclosing a color pigment with a polymer”, a glycol ether compound and water. Also, an ink jet recording process using the ink set, and recorded matter printed by the recording process.

Abstract: A process for producing a fiber-reinforced molded article and the resulting article such as a cantilevered battery tray. In the process, thermoplastic material in its solid state having a melt flow index above 25 g/10 minutes is fed into a suitable processing machine simultaneous with the addition of reinforcing fibers having a length of at least 0.375 inch or greater and sized with a material such as polyurethane, polyurea, and isocyanate derivatives thereof. The introduced materials are subjected to orientational agitation such that the reinforcing fibers are filamentized in an essentially homogeneous dispersion throughout the solid polymeric material. Once filamentization and dispersion are achieved, the resulting admixture is subjected to knead melting operations for an interval sufficient to achieve melting of the polymeric material introduced into a suitable plasticizing apparatus where the introduced material can be subjected to suitable knead melting operations.

Abstract: Concentrates and method of making concentrates are disclosed. The concentrates may be incorporated into thermoformable articles as a concentrate powder or as a paste. Thermoformable articles, such as fibers, containing the concentrates and methods of making the thermoformable articles are also disclosed.

Abstract: Compositions, methods, devices and kits utilizing water-based hydrophilic coating formulations on medical implements. The composition for applying a coating comprises a sulfonated polyester, water, and a surface active agent. Methods for coating a medical implement comprise providing an aqueous dispersion comprising sulfonated polyester and surface active agent, contacting the medical implement with the aqueous dispersion, and drying the medical implement. Methods for acquiring a sample of bodily fluid from a patient comprise coating a needle with a sulfonated polyester, penetrating the needle into the patient, and drawing bodily fluid through the needle.

Abstract: The invention relates to modified inorganic particles with a layer structure with an average particle diameter of 5 nm to 20000 nm, comprising an outer shell consisting of aminoplasts which contain, interlamellarly, multifunctional C1–C30 amino compounds of the melamine, melamine derivative, urea, urea derivative, guanidine, guanidine derivative, cyanamide, dicyandiamide, sulphonamide and/or aniline-type. The invention also relates to the production of said modified inorganic particles and to their use in thermoplastics and duroplastics.

Abstract: The present invention relates to an aqueous ink, particularly an aqueous ink suitable for ink jet recording. The ink is an aqueous ink comprising a modified pigment having organic groups chemically attached to the surface of a particle of the pigment and an aqueous medium which is a dispersant of the pigment, wherein the above-described organic group includes a reaction product of a functional group chemically attached to the surface of the pigment directly or via another atomic group with a copolymer of an ionic monomer and a hydrophobic monomer.

Abstract: Multi-functional microcapsules comprising a core material including a major portion of one or more functional additives and a shell material including at least one functional additive, a method of manufacturing such multifunctional microcapsules and polymeric products incorporating such multifunctional microcapsules are provided.

Abstract: In the present invention, an inorganic reactant is, or reactants are, localized with respect to a dendritic polymer by physical constraint within or by a non-covalent conjugation to the dendritic polymer. The localized inorganic reactant or reactants is/are subsequently transformed to form a reaction product which is immobilized with respect to the dendritic polymer. This immobilization occurs on a nanoscopic scale as a consequence of the combined effects of structural, chemical and physical changes without having covalent bonds between the product(s) and the dendritic container and results in new compositions of matter called dendritic nanocomposites. The resulting nanocomposite material can be used to produce revolutionary products such as water soluble elemental metals, with specific applications including magnetic resonance imaging, catalytic, magnetic, optical, photolytic and electroactive applications.

Abstract: A thermoplastic resin composition, comprises a thermoplastic resin (A) and thermoplastic resin fine particles (C) carrying a colloidal inorganic substance (B), and contains the colloidal inorganic substance (B) in a proportion of 0.01–0.8 wt. % of the total of the thermoplastic resin (A), the colloidal inorganic substance (B) and the thermoplastic resin fine particles (C). The thermoplastic resin composition effectively prevents the plateout without impairing inherent properties of the base thermoplastic resin, by containing the colloidal inorganic substance (B) showing a plateout-prevention effect in a small amount and in a good dispersion state.

Abstract: A pressure sensitively adhesive polyacrylate according to a composition known per se, characterized by crosslinked and functionalized polymer particles which on the basis of their chemical nature are suitable for assisting a crosslinking reaction of the pressure sensitive adhesive.

Abstract: An ink set comprising at least two color inks containing water-insoluble colorants for color inks having a different color with each other, wherein the ink set has at least one combination of two color inks satisfying that the difference in the average particle diameter of the particles contained in the colorant between these two color inks is at least 55 nm. The ink set can be suitably used for printers for inkjet printing.

Abstract: Disclosed are a colorant which can realize an ink compositions possessing excellent lightfastness, waterfastness, color development, and rubbing/scratch resistance, and an ink composition containing the same. The ink composition comprises at least a colorant, a polymer covering the colorant and having, in its molecular chain, sites possessing ultraviolet absorbing activity and/or photostabilizing activity, water, and a water-soluble organic solvent. The ink composition according to the present invention include two preferred embodiments. In the ink composition according to the first preferred embodiment, the polymer functions as a dispersant and covers the colorant. In the ink composition according to the second preferred embodiment, the polymer is in the form of fine particles covering the colorant.

Abstract: The invention relates to a method of conducting polymerization in nonaqueous miniemulsions.

Abstract: An ink set comprising (A) a black ink comprising a water-insoluble colorant for black ink and (B) a color ink comprising a water-insoluble colorant for color ink, wherein the difference between the maximum average particle diameter and the minimum average particle diameter of the colorants contained in the water-insoluble colorant for black ink and the water-insoluble colorant for color ink is at most 45 nm. The ink set can be suitably used for an ink set for inkjet recording.

Abstract: An uncured epoxy adhesive comprising a resin component, a hardener component, and a microencapsulated accelerator component. The microencapsulated accelerator component comprises an infrared absorber, an accelerator and a wall that covers substantially the entire surface of the accelerator. The epoxy adhesive is cured by exposing it to infrared energy. The infrared energy is absorbed by the infrared absorber which disintegrates the wall and allows the accelerator to come into contact with the other adhesive components and initiate the curing polymerization reaction.

Abstract: Provided is a process for the preparation of a pigment dispersion which comprises a pigment surface treatment step of introducing at least one hydrophilic dispersibility-providing group onto the surface of a pigment directly and/or with the interposition of a polyvalent group, and a dispersion step of dispersing a surface-treated pigment obtained at the surface treatment step in an aqueous medium, characterized in that the dispersion step involves the dispersion of the surface-treated pigment in admixture with a wetting agent and water and a resin for providing dispersibility and/or fixability is added during and/or after the dispersion step.

Abstract: A crosslinkable fluororubber composition comprising (A) a liquid perfluoro compound having alkenyl groups and a divalent perfluorolakylene or perfluoropolyether structure, (B) a reinforcing filler, (C) a surface treating agent having a fluoroalkyl or fluoropolyalkyl ether group and a silanol group, (D) an addition reactive compound having hydrosilyl groups, and (E) a hydrosilyl or peroxide crosslinker is prepared by mixing components (A) to (C) to form a liquid or paste composition, adding component (D) thereto to form a millable composition, and mixing component (E) therewith. The composition is effectively roll workable and cures into products having excellent physical properties.

Abstract: A water dispersible polymer particle stabilized by a hydrophobically capped oligomeric acrylamide dispersant or a heterogeneous method for forming polymer particles comprising providing a water immiscible organic phase comprising at least one monomer dispersed in a continuous water phase and a hydrophobically capped oligomeric acrylamide, and polymerizing the organic phase to yield polymer particles stabilized with hydrophobically capped oligomeric acrylamide. Also, a heterogeneous method for forming polymer particles comprising providing a water immiscible organic dispersed in a continuous water phase, polymerizing the organic phase, and adding hydrophobically capped oligomeric acrylamide to yield polymer particles stabilized with hydrophobically capped oligomeric acrylamide.

Abstract: A process for producing thermo-expansive microcapsules wherein a polymerizing mixture containing ethylenic unsaturated monomer and a blowing agent is suspend-polymerized to microencapsulate the blowing agent with the resultant polymer. The above-mentioned suspension-polymerization is performed with the presence of at least one compound selected from the group consisting of polypeptides and derivatives thereof as a suspension stabilizer. The process can control the particle size of microcapsules easily, attain stable reaction system and produce thermo-expansive microcapsules that disperse well in medium such as paint or inks.

Abstract: The present invention relates to anaerobic adhesive compositions which have been optimized using experimental design techniques to produce desired physical properties. A simplified cure system is disclosed which permits enhanced fixture and cure times.

Abstract: The present invention teaches an improved process for preparing a population of microcapsules having a substantially uniform size distribution, especially useful for manufacture of carbonless paper. The improved process teaches use of membrane material having a pre-selected pore size in the capsule manufacture process. A core material is provided along with a receiving solution for receiving the core material. The receiving solution is a nonsolvent for the core material. The core material is passed under pressure through the membrane into a moving or turbulent receiving solution forming uniform droplets of core material dispersed in the receiving solution. Wall-forming material is added to the receiving solution for coating the core material droplets. The coating on the droplets is polymerized forming microcapsules. This novel process also lends itself to microcapsule formation in a continuous process.

Abstract: A polymer with a hemocompatible film or coating is manufactured by a one-step method comprising polymerizing monomer droplets comprising at least one crosslinking agent to form a polymer and simultaneously coating the resulting polymer using at least one dispersing agent to thereby form a hemocompatible coated polymer.

Abstract: The present invention provides a process, which includes: a) suspending: at least one filler selected from the group including silicatic filler, oxidic filler, and a mixture thereof, 0.5 to 7% by weight, based on the weight of the filler, of at least one polysiloxane hydrophobicizing agent, and 0.1 to 2% by weight, based on the weight of the filler, of at least one non-ionic surfactant, in water at a temperature of 10 to 60° C., to prepare a suspension having a solids content of 0.5 to 15% by weight, based on the weight of the suspension; b) contacting a rubber latex emulsion and the suspension, to prepare a mixture; c) contacting the mixture with at least one acid to lower the pH of the mixture to 2.

Abstract: The invention describes a process for the preparation of a particulate polymer, said process comprising: i) forming an aqueous dispersion comprising a particulate polymer seed material and a first organic compound; ii) allowing said first organic compound to diffuse into said seed material to produce a pre-swollen seed material; iii) contacting said pre-swollen seed material in aqueous dispersion with said first organic compound and a second organic compound, preferably one which is soluble in said first organic compound; iv) allowing or causing said first and second organic compounds to pass into said pre-swollen seed material to produce an activated seed material; v) contacting said activated seed material with a monomer and effecting suspension polymerization thereof.

Abstract: An ink jet recording method comprising a step of bringing a first ink composition into contact with a second ink composition on a recording medium to form an aggregate, wherein the first ink composition comprises at least a water-soluble organic solvent, water and a coloring agent comprising a coloring material enclosed with a polymer having an anionic group, and wherein the second ink composition comprising at least a water-soluble organic solvent, water and a coloring agent comprising a coloring material enclosed with a polymer having a cationic group. Also disclosed are ink sets suitable for the ink jet recording method.

Abstract: A composite material, contains a polymer, a polymerizer, a corresponding catalyst for the polymerizer, and a plurality of capsules. The polymerizer is in the capsules. The composite material is self-healing.

Abstract: The red phosphorus base flame retardant for an epoxy resin is provided, which has red phosphorus particles coated with a thermosetting resin containing an anhydrous zinc compound. The coated red phosphorus has properties that a slurry having the coated red phosphorus dispersed in 10% by weight into water at 20° C. has an electric conductivity of 30 ?s/cm or below, the slurry having been left standing at 80° C. for 20 hours has an electric conductivity of 150 ?s/cm or below, and when 80 ml of water is added to 8 g of the coated red phosphorus and heated at 80° C. for 20 hours, a concentration of PO4 ions eluted is 10 ppm or below.

Abstract: A method for preparing encapsulated red phosphorus is disclosed. The method entails obtaining a material system that contains dispersed particulate red phosphorus having a mean particle size of 0.1 to 100 ?m in an aqueous phase that comprise urea, formaldehyde and a water-soluble silicon dioxide precursor, adding to the material system a sufficient amount of acid to lower the pH to 0 to 5 and maintaining the resulting acidic system at a temperature of 80 to 120° C. for a period longer than one hour. The encapsulated red phosphorus of the invention is suitable for using as a flame retarding agent for plastics molding compositions.

Abstract: High concentration drag reducing agents may be prepared by microencapsulating and/or macroencapsulating polymer drag reducing agent. The encapsulation may be performed prior to, during, or after the polymerization of monomer into effective drag reducing polymer. If encapsulation is done before or during polymerization, a catalyst may be present, but little or no solvent is required. The result is very small scale bulk polymerization within the capsule. The inert capsule or shell may be removed before, during or after introduction of the encapsulated drag reducer into a flowing liquid. No injection probes or other special equipment is expected to be required to introduce the drag reducing slurry into the liquid stream, nor is grinding (cryogenic or otherwise) of the polymer necessary to form a suitable drag reducing agent.

Abstract: A method for stabilizing a dye in an ink comprising the dye and a vehicle is provided. The ink is intended for printing on a print medium, which may comprise a variety of surfaces. The method comprises: (a) providing at least one dye moiety (molecule or monomer); (b) encapsulating the dye moiety in a transparent polymeric matrix to form an encapsulated dye particle that provides a barrier to protect the dye moiety; and (c) incorporating the encapsulated dye particle in the ink. The dye moiety is substantially water-insoluble. Consequently, the method of the present invention enables the use of hydrophobic colorants in a hydrophilic vehicle. A hydrophobic film thus forms on the print medium upon drying.

Abstract: A modified particle or aggregate is disclosed wherein a particle has an attached group having the formula: 1

Abstract: Excellent tracking index as well as flame-resistant properties are achieved with other desirable characteristics of LCPs in a resin composition consisting essentially of: a) a wholly aromatic polyester which is melt processible and which displays anisotropy in the molten state; b) a non-conductive filler material having a diameter of less than about 3 m, with said non-conductive filler material being present in an amount sufficient to increase the comparative tracking index (CTI) rating of said composition to above 220 volts and render the composition non-burning. Optionally, an extraordinarily small amount of non-volatile fluorescent brightener can be added to the resin composition. In combination with the non-conductive filler, the fluorescent brightener is found to surprisingly and significantly improves the flame-retardant property of the resin. Such compositions are advantageously employed in electrical and electronic apparatuses.

Abstract: The present invention relates to a composition containing silico-organic nanohybrid and/or microhybrid capsules for scratch-resistant and/or abrasion-resistant coatings, wherein the silico-organic nanohybrid and/or microhybrid system includes one or more small metal oxide cores A and a substantially complete, silico-organic shell B, and the composition can be obtained by a reaction performed in situ, in a synthetic resin or in a synthetic-resin precursor compound, between metal oxide particles (KA-O) and at least one organofunctional silicon compound which contains an organofunctional group and at least one hydrolyzable group or at least one hydroxy group. The present invention also relates to the use of such compositions as the base for lacquers for producing a scratch-resistant and abrasion-resistant coating on a substrate as well as articles provided with corresponding scratch-resistant as well as abrasion-resistant coatings.

Abstract: A unique treatment for pigments is provided. This treatment, which uses certain organo-acid phosphate molecules, imparts improved physical and chemical qualities including lacing resistance, improved dispersion and decreased chemical reactivity when these treated pigments are incorporated into polymeric matrices.

Abstract: Modified silica fillers are prepared by contacting silica with blends or mixtures containing diorganodihalosilanes and tetrahalosilanes in weight ratios of 1:0.1 to 1:2, respectively. While dialkyldichlorosilanes and tetrahalosilanes such as dimethyldichlorosilane and silicon tetrachloride, respectively, are most preferred, the blends or mixtures may also comprise compositions containing other silanes such as mercaptopropyltriethoxysilane.

Abstract: The present invention is directed, in part, to improved polymer compositions and processes for preparing same. Specifically, in one embodiment, there is provided a process for preparing a polymer, wherein the process comprises: providing a reaction mixture comprising a portion of at least one polar monomer and at least one multivalent cation; adding the remaining portion of the polar monomer to the reaction mixture; and polymerizing the monomer to form the polymer. In certain embodiments, the reaction mixture in the providing step comprises at least two molar equivalents or greater of the total amount of polar monomer with respect to one molar equivalent of multivalent cation.

Abstract: The coating composition comprises inorganic oxide, e.g., silica, in combination with a binder system comprising a mixture of a water soluble polymer and non-ionic latex polymer. The composition may contain optional dye mordant (e.g., cationic polymer). It is found that the combinations of these components result in relatively high solids formulations (e.g., greater than 20% by weight) with relatively low viscosity (less than 5000 centipose), do not exhibit coating dusting, and give exceptional ink-jet printability. These formulations are especially suitable for preparing on-line formulations because they can be formulated to have a viscosity less than 2000 centipose. Preferable embodiments for online coatings have a viscosity less than 1000 centipose.

Abstract: A nonstaining coating composition which comprises as essential components (A) a specific aliphatic sulfonic acid compound or amine salt thereof, (B) a compound having per molecule at least one functional group selected among carboxly, a carboxly anhydride group, and a carboxyl group blocked with an alkyl vinyl ether, (C) a specific organosilicate and/or a condensate thereof, and (D) a resin having epoxy groups and/or alkoxysilyl groups in the molecule; and a method of finish coating. They give a cured coating film which has nonstaining properties based on a high degree of hydrophilicity from immediately after the formation thereof and has satisfactory long-term weatherability, water resistance, and chemical resistance.

Abstract: A coupler is described for use in carbon black filled rubber compositions. The coupler includes an amine group and a thiol group or a polysulfidic linkage. The coupler improves the interaction of the carbon black with the rubber as measured by a decrease in the tan delta at 60° C. while substantially maintaining the tan delta at 0° C.