Abstract: A cured cement article containing therein an organic polymer treated with an isocyanate compound has a high flexural strength and high water resistance. The cured cement can be prepared by impregnating a cured cement article containing therein a water-soluble polymer or a water-dispersible polymer with an isocyanate compound.

Abstract: A cementing composition useful in cementing oil, gas and water wells, comprising water, hydraulic cement and an effective amount of water soluble fluid loss additive comprised of a copolymer of acrylamide/vinyl imidazole and derivatives thereof in a weight percent ratio of from about 95:5 to 5:95, said copolymer having a molecular weight range of from about 100,000 to 3,000,000. The composition can also optionally include a dispersant such as sodium or potassium salts or a sulfonated naphthalene formaldehyde condensate.

Abstract: A cementing composition useful in cementing oil, gas and water wells, comprising water, hydraulic cement and an effective amount of water soluble fluid loss additive comprised of a copolymer of acrylamide/vinyl imidazole and derivatives thereof in a weight percent ratio of from about 95:5 to 5:95, said copolymer having a molecular weight range of from about 100,000 to 3,000,000. The composition can also optionally include a dispersant such as sodium or potassium salts or a sulfonated naphthalene formaldehyde condensate.

Abstract: A shapable material is disclosed which contains:(a) an aluminum fluorosilicate glass;(b) at least one polycarboxylic acid having an average molecular weight greater than 500;(c) a carbonate and/or hydrogen carbonate in an amount of at least 0.1% by weight, based on (a);(d) optionally a chelating agent; and(e) optionally water.Said material is especially suited as bone replacement material and can be shaped into porous articles.

Abstract: A cement dispersant having as a main component thereof at least one polymer selected from the group consisting of polymers obtained from (A) 0.1 to 100 mol % of a sulfonic acid type monomer represented by the formula I: ##STR1## wherein R stands for hydrogen atom or methyl group, X stands for hydrogen atom, a monovalent metallic atom, a divalent metallic atom, ammonium group, or an organic amine group, A and B independently stand for an alkylene group of 2 to 4 carbon atoms, m stands for 0 or an integer of the value of 1 to 100, and the alkylene oxide group of 2 to 4 carbon atoms in the portion, (AO).sub.m may be bound in any desired sequence, and (B) 99.9 to 0 mol % of other monomer copolymerizable with said sulfonic acid type monomer, and polymers obtained by neutralizing said polymers with an alkaline substance, a cement composition containing the dispersant and a method for dispersing a cement.

Abstract: The invention is specifically concerned with an improvement in the process of manufacturing reinforced materials. The reinforced materials are conceived to include a wide variety of materials, the most notable being high density compressed gaskets. The improvement comprises mixing a cut solid (generally a cut fiber) with a body material to produce the reinforced materials. The solid is cut into particulates of highly variable size, the range in the size of the particulates being adjusted to optimize the characteristics of the resulting reinforced material. The cut solid is produced utilizing comminuting machines previously used for the recycle of waste products.

Abstract: This invention relates to improved aluminous cement/gypsum compositions that contain polymer latex emulsions or compounds to produce self-curing, crack-free, fast-setting, high early strength, high bonding, water resistant, durable, cementitious mixtures for finishing, coating, plastering, stucco, rigid insulation protection, topping, resurfacing, patching, mortaring, tile grouting, concrete, and the like. In addition, this invention discloses a method for improving the properties and performance of aluminous cement/gypsum compositions by adding certain types, amounts and/or combinations of polymer latex emulsions or compounds with or without the addition of wet expansion and drying shrinkage inhibitors.

Abstract: This invention is a polymer blend useful in thin-bed mortar compositions comprising a water-soluble cellulose ether and a water-insoluble, but water-dispersible, polymer. The water insoluble, but water-dispersible polymer can include an unneutralized polyacrylic acid that is lightly crosslinked or methylcellulose with a viscosity from about 50 cps to about 150,000 cps, provided the polymeric blend containing methylcellulose is employed in a medium that has a pH of about 12 or greater, although a pH of less than 12 is workable, but is dependent upon the methoxyl content of the methylcellulose. The polymeric blend extends the working time of the composition in which it is employed and because the blend has sag binding characteristics, it also functions as a sag resistance aid.

Abstract: Lightweight insulating boards in accordance with the present invention comprise Portland cement, fibers and fillers including:(a) 50-75% by weight of cement,(b) 0-5% by weight of cellulose fibers,(c) 0.5-4% by weight of alkali-resistant fiber material,(d) 5-20% by weight of mica,(e) 5-20% by weight of light filler and(f) 8-25% by weight of hydrated lime.They are shaped into boards from a suspension and are set at least 15 days, and preferably 28 days. The insulating boards of the present invention meet all of the requirements set for such materials regarding flexural strength, incombustibility, and the like.

Abstract: An aqueous slurry of gypsum plaster is stabilized by an organic, polymeric, hydrophilic stabilizer for more than 30 days without setting.Upon activation with a Lewis acid the slurry becomes hydrated. The plaster form or the hydrated form may be employed to impregnate a substrate to form insulating sheeting. The substrate may be fabric, felt, paper, nonwoven, or sponge.Open-cell, foamed gypsum may be used alone or molded to shaped articles such as bricks for a firewall.

Abstract: A hydraulic cement composition is effectively dispersed with the use as a dispersion agent of a reaction product obtained by oxidizing and polymerizing a condensate of formaldehyde with a naphthalenesulfonic acid salt and/or an alkylnaphthalenesulfonic acid salt to produce a constitutional unit which is derived by elimination of a methylene group, hydroxyzation and condensation polmerization, or oxidation and ring-opening of the naphthalene ring.

Abstract: A hardenable composition which comprises (i) a poly(carboxylic acid) or precursor thereof (as herein defined); (ii) a particulate ion-leachable silicate, aluminosilicate or metal oxide reactable with (i) in the presence of water to set to a hardened composition; and (iii) a compound comprising at least one phosphorus-carbon or phosphorus-boron covalent bond, in an amount effective in service to extend the working time of the composition.

Abstract: A soldified and particulated resin and a substantially solidified-state-maintained water are mixed with cement and after the mixing is finished, the solidified resin and water are liquefied and the cement is hydrated with the liquefied water. Since the resin maintains the solidified and particulated state and the water also maintains the solidified state during mixing, the mixing work of cement, water and resin is uniformly performed.

Abstract: A concrete composition for underwater use contains about 0.1 to 4% by weight based on cement content of a water soluble vinyl polymer containing vinyl units having sulfonic groups. The concrete composition is easy to mix and prevents separation of concrete composition constituents as it is laid under water.

Abstract: Low fluid loss salt saturated cement slurries, liquid fluid loss reducing additives for preparing slurries and methods of using the slurries in oil and gas well cementing operations are provided. The low fluid loss aqueous salt saturated cement slurries are comprised of hydraulic cement, salt saturated water and the reaction product of polyethyleneimine and one or more sulfonated organic compounds.

Abstract: A dry composition including Portland cement, sand, fly ash Type F, with or without glass fiber, vinyl acetate-ethylene copolymer or equivalent powder form bonding agent, sodium salts of polymerized substituted benzoid alkyl sulfonic acids, or equivalent dispersing or emulsifying agent, and defoamer or antifoam agent or equivalent defoamer or antifoam agent, which is completely dry and controlled inplant.

Abstract: A polymer of monoallylamine, preferably a water-soluble polymer of monoallylamine, whether in free (i.e., unneutralized) form or in salt (i.e., partially or completely neutralized) form is used in conjunction with a sulfonated polymer such as a water-soluble lignosulfonate, condensed naphthalene sulfonate, or sulfonated vinyl aromatic polymer, to minimize fluid loss from the slurry during subterranean well cementing operations. The polymer of monoallyl amine may be a homopolymer or a copolymer, and may be crosslinked or uncrosslinked. These components interact with each other in the presence of water to produce a gelatinous material that tends to plug porous zones and minimize premature water loss from the well cement slurry when present in the subterranean well formation. In addition, the gelatinous material so formed prevents de-stabilization of the slurry in the well formation.

Abstract: The invention provides an insulation material in the form of a cured composition comprising as components:(a) 10 to 30% w magnesium chloride,(b) 0 to 15% w of an organic resin,(c) 0 to 0.5% w of a mould-release agent,(d) 0.1 to 1% w of a surfactant,(e) 6 to 8% w of a sodium polyphosphate glass,(f) 6 to 20% w magnesium oxide,(g) 4 to 20% w inorganic filler,(h) 15 to 30% w cenospheres,(i) 1 to 3 % w orthophosphoric acid,(j) 0 to 12 % w inorganic fibres,in overall proportions to total 100%, having a density in the range 200 to 500 kg/m.sup.3 ; and its preparation.

Abstract: A concrete mix comprises a cementing agent and aggregate, the aggregate comprising vesiculated beads of cross-linked resin which beads contain an average of at least 2 thin-walled foraminous cells to provide communication between the vesicles within said bead and the exterior of said beads to allow water to move into and out of said beads. This reduces the density of the concrete and the beads hold water to help control the cure.

Abstract: An additive for cementitious compositions is provided comprised of a cellulose ether, a starch ether and a polyacrylamide. This additive, when added to cementitious compositions, improves the workability of the resulting cementitious composition when used as a tile grout or mortar.

Abstract: A mortar for waterproof and protective coverings to be employed for building and road construction. The mortar comprises a mixture of an acrylic emulsion and finely ground clay which has been baked at a temperature range between 600.degree. C. and 1400.degree. C.

Abstract: A refractory containing refractory aggregate, clay binder, finely divided metallic powder and short length organic fibers.

Abstract: Crosslinked copolymers wherein crosslinking is effected with crosslinking bridge members of the formula ##STR1## wherein R.sup.1 and R.sup.2 independently of one another are each hydrogen or alkyl with 1 to 4 carbon atoms and m represents a number from 0 to 6 are prepared by copolymerization of monomers with vinylphosphonic acid (ester)-anhydrides and the new crosslinked polymers according to the invention are suitable for the preparation of acid-soluble coatings and encapsulation materials.

Abstract: The present invention concerns our discovery that aqueous cellulosic slurries comprising primary binder, newsprint, sulfite pulp, and vegetable shell flour can be prepared and formed as desired into various configurations. The materials thus formed are usable for a variety of purposes including furniture, paneling and flooring structures.

Abstract: The invention relates to a method of making concrete used in hydrotechnical structures weather-resistant as regards the freezing of water absorbed into the pores of the concrete. The problem in this connection consists of the expansion of freezing water and the consequent state of tension in the concrete. According to the invention, a small amount of micro-sized rubber powder is mixed with the concrete mix, the rubber particles forming even-surfaced, closed buffers into which the water expanding when it freezes can expand without producing states of tension in the concrete. The rubber particles are ground from the rubber parts of used automobile tires.

Abstract: At least substantially, if not entirely, undried comminutated fibrous plant cellulosic materials, particularly "wet" sawdust, is made into integrally bonded composition and shaped and fabricated articles therefrom using an inexpensive, exceptionally and adequately hydrophylic binder which under certain conditions and in particularized situations may be prepared with minimized (and sometimes even no or essentially no) artificially-induced thermal drying requirements in or for the production of cohesively-resultant, particulate-containing artificial wood and equivalent products capable of replacing natural stock; the binder constituent for the accomplishment of same being, for example and without limitation(s), ordinary household bleach (i.e., aqueous sodium hypochlorite) composition(s) and its like, more-strongly-concentrated preparations and/or possible equivalents thereof and substitutes therefor such as bleach powder (i.e.

Abstract: Water-soluble carbohydrate polymers are modified with crosslinked water-swellable organic polymers. The modified carbohydrate polymer compositions are useful as improved water retention aids for tile adhesive compositions, and as additives in spray plasters, wall finishing compounds, tape joint cements, wall paper adhesives, and the like.

Abstract: An aqueous hydraulic cement slurry is disclosed which comprises water, a hydraulic cement, a surfactant and, as a fluid loss additive, epihalohydrin derivatives of polyalkylenepolyamines.

Abstract: A process for making a lightweight structural member or insulating coating uses an initial mixture of hydrated lime, a dispersible additive, rock wool and, optionally an aggregate. This mixture has added to it water, and the water/solids mixture is agitated at high speed to produce a castable slurry having 60-80 volume percent air bubbles. The mixing is desirably conducted in a mixer having a cylindrical chamber and using paddles which rotate about their own axis and wherein there is movement of the chamber wall relative thereto, and the blades desirably scrape the chamber wall during such relative rotation.

Abstract: Aqueous acidic compositions which contain a combination of an organic polymer having a bound latent source of thiolate ions, such as isothiouronium groups and an organic polymer having bound cationic onium groups, such as sulfonium groups, or a polymer containing both kinds of groups can be cured in the wet state by raising the pH to above about 9 at a temperature from about 0.degree. C. to about 100.degree. C.

Abstract: Delayed action setting of a composition comprising an anionic latex of a film forming polymer by addition of a delayed action setting agent characterized in that the setting agent is a compound containing a multivalent metal cation having defined solubility characteristics in a quantity not greater than 2.5% wt/wt on total composition and not greater than 11% wt/wt based on film forming polymer solids in the composition.

Abstract: Rust preventing synthetic resin compositions to be added to cement or mortar, which have high strength, adhesion and waterproof, contain 0.05.about.5 parts by weight of a primary alkanol-amine having 2 to 8 carbon atoms based on 100 parts by weight of resin solid content in a synthetic resin emulsion.

Abstract: A settable molding composition comprising a mix of synthetic plaster with an extraneous water source, including a "wet" synthetic gypsum or a mixture of same and free water, is readily pressure compacted or molded into a plurality of useful shaped articles, e.g., strong, modular building materials. The plaster can comprise from about 30% to about 99% by weight of the mix and has a Blaine surface area ranging between 2,500 and 7,000 cm.sup.2 /g, with the amount of water in the mix from the water source being in excess of that amount stoichiometrically required for ultimate complete setting of the mix, said excess of water being in an amount no greater than 15% of the total weight of said mix. The resulting shaped articles are effectively set, even in the absence of any drying step.

Abstract: Asbestos-free, fiber-reinforced, hydraulically setting compositions can be processed to fiber-reinforced shaped articles. The compositions are obtained by mixing fibers, hydraulic binders and water-soluble or water-emulsifiable polymers and by adding a metallic compound, particularly a metal salt or hydroxide. The composition can be processed in the equipment conventionally used in the asbestos cement industry.

Abstract: An asbestos-free gasket is produced from a composition which comprises from about 5% to about 20% of an organic latex binder, from about 5% to about 35% of a cellulosic fibrous material, from about 0% to about 30% of mineral wool, at least about 50% of an inorganic filler, and from about 0 to about 5% of a coloring additive. The percentages being on a dry weight basis of the gasket. The organic materials are present in an amount no greater than 40% of the total dry weight of the gasket and preferably no greater than 30%. The inorganic filler is an inactive additive, stable at a temperature greater than 1700.degree. F., such as Portland Cement, diatomaceous earth, silicates, carbonates, barytes and mixtures thereof. Preferably the inorganic filler is a mixture of barytes and talc in a ratio of from about 1 to 0, to 3 to 1.