Polymerizing In The Presence Of Water And In The Presence Of A Solid Polymer Derived From Ethylenic Reactants Only Patents (Class 524/458)
  • Publication number: 20090020036
    Abstract: A latex particle for use in ink-jet inks can comprise a latex polymer core and a latex polymer shell such that the latex polymer shell has a Tg that is at least 10° C. greater than the Tg of the latex polymer core. The latex polymer core can comprise at least one polymerized core monomer. The latex polymer shell can comprise at least two polymerized shell monomers including a urethane acrylate monomer.
    Type: Application
    Filed: July 17, 2007
    Publication date: January 22, 2009
    Inventor: Sivapackia Ganapathiappan
  • Publication number: 20080255289
    Abstract: The invention relates to a dried emulsion. In particular, the invention relates to a dried emulsion containing a liquid hydrophobic phase and a water-soluble or water-dispersible polymeric matrix whose hydrophobic phase content is high. The invention also relates to a method for producing the dried emulsion and to uses of this emulsion. The utilized water-soluble matrix contains block copolymers.
    Type: Application
    Filed: March 15, 2005
    Publication date: October 16, 2008
    Inventors: Sophie Deroo, Alain Senechal, Jean-Michel Mercier, Nadia Martin
  • Patent number: 7435773
    Abstract: A resin composite having excellent tensile strength and a process for producing the composite are provided. The resin composite comprises a resin and aluminum hydroxide having an average primary-particle diameter of about 100 nm or smaller and has an index Y/X of 0.1 or less provided that the value X is an average intensity of intensities of aluminum characteristic X-ray measured by scanning a beam on a straight line on the composite with an electron-probe X-ray microanalyzer and the value Y is a standard deviation of the intensities.
    Type: Grant
    Filed: November 9, 2000
    Date of Patent: October 14, 2008
    Assignee: Sumitomo Chemical Company, Limited
    Inventor: Satoru Nippa
  • Publication number: 20080249226
    Abstract: A water based coating composition containing 2-40 wt% resin, 0.015-30 wt% mixed solution including a filler modified by Si coinpound/surfactant/polymer and 0.05-10 wt% additives can be used for the production of an optical-usc polyester film. The described resin contains about: a. 20-50 wt, based on the weight of the coated layer, of composition A which is polyester resin; b. 10-40 wt%, based on the weight of the coated layer, of composition B which is alkylated melamine formaldehyde crosslinking resin; c. 20-80 wt%, based on the weight of the coated layer, of composition C which is acrylic resin. The coated polyester film has some superior properties such as high transparency, low haze value, good adhesion and anti-blocking property. It is suitable for optical applications such as a base film of the brightness enhance film or a base film for the light diffusing plate in a LCD.
    Type: Application
    Filed: April 9, 2007
    Publication date: October 9, 2008
    Inventors: Sung-Yueh Shieh, Dein-Run. Fung, Ying-Te Huang, Chao-Hsien Lin
  • Patent number: 7432320
    Abstract: There is provided a vinyl chloride resin composition, which is excellent in processability and can produce a processed article having excellent physical property or a formed molding having excellent property. A processing aid having specific viscosity of at least 0.5 is combined with a vinyl chloride resin, wherein the aid is obtained by polymerizing 1 to 50 parts by weight of a monomer mixture (B) comprising 0 to 49% by weight of methyl methacrylate, 51 to 100% by weight of at least one monomer selected from the group consisting of a methacrylate ester except methyl methacrylate and an acrylate ester, and 0 to 20% by weight of a vinyl monomer copolymerizable therewith, in the presence of a latex of a (co)polymer having specific viscosity of at least ?sp 0.
    Type: Grant
    Filed: December 10, 2003
    Date of Patent: October 7, 2008
    Assignee: Kaneka Corporation
    Inventors: Noriko Sakashita, Yasuhiro Miki, Akira Takaki
  • Publication number: 20080242790
    Abstract: The invention relates to aqueous polymer dispersions, obtained by the emulsion polymerisation of ethylenically unsaturated monomers in an aqueous medium in the presence of polymerisation initiators and stabilisers that form radicals. According to the invention, amphiphilic polymers are used as stabilisers prior to, during or after polymerisation, said polymers containing one or more hydrophobic units (A) and one or more hydrophilic units (B), the hydrophobic units (A) being formed from a polyisobutene block, wherein at least 50 mol % of the polyisobutene macro-molecules have terminal double bonds. The invention also relates to a method for producing the aqueous polymer dispersions by the polymerisation of ethylenically unsaturated monomers in the presence of initiators that form radicals and the aforementioned amphiphilic polymers, which are used prior to, during or after polymerisation.
    Type: Application
    Filed: February 8, 2005
    Publication date: October 2, 2008
    Applicant: BASF Aktiengesellschaft
    Inventors: Reinhold J. Leyrer, Ingolf Kuehn, Darijo Mijolovic
  • Publication number: 20080234415
    Abstract: The present invention provides methods of conducting emulsion polymerizations and dispersion resulting therefrom. The present invention additionally provides substrates coated or treated with polymeric dispersions.
    Type: Application
    Filed: March 23, 2007
    Publication date: September 25, 2008
    Inventors: Michael S. Williams, Michael Grigat, Robert S. Jackson
  • Publication number: 20080221253
    Abstract: The lipophilic properties of an ethylenically unsaturated water-soluble polymerizable sulfonic acids are improved by forming a salt thereof with a lipophilic amine. Such salts are readily polymerized in an emulsion or solution process.
    Type: Application
    Filed: February 9, 2005
    Publication date: September 11, 2008
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Joseph G. Seebauer, Kathleen O. Havelka, Richard M. Lange
  • Publication number: 20080220176
    Abstract: Disclosed are Pickering emulsions, related aqueous dispersions, and methods for their preparation, both of which include the use of a water insoluble promoter. Also disclosed are coatings and particle networks formed therefrom.
    Type: Application
    Filed: February 27, 2007
    Publication date: September 11, 2008
    Applicant: PPG INDUSTRIES OHIO, INC.
    Inventors: Leland H. Carlblom, Terri L. Ziegler, Mary Ann M. Fuhry
  • Publication number: 20080206558
    Abstract: A water-based pressure sensitive adhesive dispersion is provided. The dispersion is a reaction product of a monomer solution and an aqueous phase. The monomer solution contains from about 40 to 70 parts water-insoluble monomer selected from the group consisting of alkyl acrylate, methacrylate, vinyl ester, and combinations thereof and from about 0.01 to 0.2 parts monomer soluble free radical initiator. The aqueous phase includes from about 1 to 20 parts latex binder, from about 0.1 to 2 parts surfactant, from about 0.02 to 1 parts polymeric suspension stabilizer, and water as a remaining balance. All parts are given as parts by weight per 100 parts of the dispersion. The dispersion has a solid phase of at least 60 weight percent, a viscosity of less than about 300 centipoise, measured at about 23° C., and a bimodal particle size distribution.
    Type: Application
    Filed: February 22, 2007
    Publication date: August 28, 2008
    Inventors: Chi-Ming Tseng, Margaret M. Sheridan, Chih C. Hsu, Chung I. Young
  • Patent number: 7408004
    Abstract: The present invention relates to a water-soluble polymer dispersion comprising: a dispersed polymer made up of at least one water-soluble monomer A and at least one water-soluble cationic monomer B, at least one stabiliser C, and at least one cationic polyelectrolyte as co-stabiliser D. It also relates to a method of producing a polymer dispersion and to a paper-making process.
    Type: Grant
    Filed: May 15, 2003
    Date of Patent: August 5, 2008
    Assignee: Akzo Nobel N.V.
    Inventors: Oliver Struck, Christian Przybyla, Werner Jaeger, Mathias Hahn, Dirk Ruppelt
  • Patent number: 7393891
    Abstract: The present invention is related to a method of manufacture of a graft copolymer latex and its dried powder including a step of manufacture of a latex using a reactive surfactant for a surfactant in manufacturing of the graft copolymer latex containing acrylic polymers and a step of manufacture of dried powder in which the graft copolymer latex manufactured in the above step of manufacture of a latex is sprayed and dried. The method according to the present invention is effective in that it is possible to provide for dried powder of a graft copolymer latex having a low moisture content and a high powder density and to provide for a thermoplastic resin composition containing the above latex having superior luster, tensile strength, and thermal stability.
    Type: Grant
    Filed: June 9, 2004
    Date of Patent: July 1, 2008
    Assignee: LG Chem, Ltd.
    Inventors: Hyun-taek O, Tae-bin Ahn, Jung-tae Park, Keon-hoon Yoo
  • Publication number: 20080146448
    Abstract: Aqueous polymer dispersions comprising effect substances with a mean particle size of the dispersed particles of <1000 nm, in which the polymer particles comprise a polymer matrix of at least one ethylenically unsaturated monomer, at least 0.
    Type: Application
    Filed: March 10, 2005
    Publication date: June 19, 2008
    Applicant: Basf Aktiengesellschaft
    Inventors: Rainer Dyllick-Brenzinger, Alban Glaser, Matthias Bratz, Felix Christian Gorth, Christian Kruger, Gunter Oetter
  • Patent number: 7375161
    Abstract: A process for producing an emulsion pressure-sensitive adhesive comprises (co)polymerizing a main monomer in the presence of a protective colloid, the protective colloid being an acrylic copolymer comprising (A-1) at least one hydrophilic monomer selected from the group consisting of acrylamide, methacrylamide, hydroxyethyl acrylate and hydroxyethyl methacrylate and (B-1) an alkyl (meth)acrylate that is copolymerizable with the hydrophilic monomer (A-1) and whose alkyl group has 4 to 18 carbon atoms, or (A-2) a hydrophilic monomer being acrylic acid and/or methacrylic acid and (B-2) an alkyl (meth)acrylate that is copolymerizable with the hydrophilic monomer (A-2) and whose alkyl group has 4 to 9 carbon atoms; the hydrophilic monomer and the alkyl (meth)acrylate being copolymerized in a weight ratio in the range of 40-70:60-30; the acrylic copolymer having a weight-average molecular weight in the range of 500 to 50000.
    Type: Grant
    Filed: February 27, 2004
    Date of Patent: May 20, 2008
    Assignee: Soken Chemical & Engineering Co., Ltd.
    Inventor: Kiyokuni Takashima
  • Publication number: 20080058457
    Abstract: An aqueous dispersion of polymeric particles and process for making the aqueous dispersion are disclosed. The polymeric particles have at least one ethylenically unsaturated monomer and a copolymerized macromer with a number average molecular weight of between 1,000 and 50,000 and a cloud point in water of between 25° C. and 90° C.
    Type: Application
    Filed: July 20, 2007
    Publication date: March 6, 2008
    Inventors: Marc Bompart, Ward T. Brown, Rosemarie P. Lauer
  • Patent number: 7332565
    Abstract: A method for reducing the amount of residual monomer in aqueous polymer dispersions by aftertreatment with an initiator system comprises aftertreating the aqueous polymer dispersion with addition of an initiator system essentially comprising a) from 0.001 to 5% by weight, based on the total monomer amount used to prepare the polymer dispersion, of an inorganic salt of persulfuric acid, b) from 0.005 to 5% by weight, based on the total monomer amount used to prepare the polymer dispersion, of a methyl ketone, and c) optionally, catalytic amounts of a metal ion which is able to exist in a plurality of valence states.
    Type: Grant
    Filed: April 13, 2004
    Date of Patent: February 19, 2008
    Assignee: BASF Aktiengesellschaft
    Inventors: Mubarik Mahmood Chowdhry, Wolfgang Gaschler
  • Patent number: 7323510
    Abstract: The invention relates to methods for manufacturing a water-in-water polymer dispersion containing polymer A and at least one polymer dispersant B, according to which monomers, which are dispersed in an aqueous phase containing water-soluble dispersant B, are subjected to radical polymerization, possibly following the addition of a water-soluble salt, and, after polymerisation, a water-soluble acid is added to the water-soluble and/or water-swellable polymer A obtained in this way, where the acid is added in quantities of 0.1 to 5% by weight and the salt in quantities of up to a maximum of 3% by weight, each referred to the total dispersion, and the total quantity of salt and acid amounts to a maximum of 5% by weight, referred to the total dispersion.
    Type: Grant
    Filed: December 1, 2001
    Date of Patent: January 29, 2008
    Assignee: Ashland Licensing and Intellectual Property LLC
    Inventors: Ulrich Fischer, Otto Schroers, Wolfgang Woebel
  • Patent number: 7304124
    Abstract: A stripping process is provided which continuously strips volatile substances from a dispersion containing a polymer particles through stripping the volatile substances from a dispersion by blowing an inert gas into the dispersion to draw the volatile substances into the inert gas, removing the volatile substances from the gas mixture of the inert gas and the stripped volatile substances and circulating the purified inert gas obtained by removing the volatile substances from the gas mixture, and blowing the purified inert gas into the dispersion. Also provided is a production process for a toner which uses this stripping process.
    Type: Grant
    Filed: November 1, 2002
    Date of Patent: December 4, 2007
    Assignee: Zeon Corporation
    Inventors: Takeo Fujino, Kazuhiro Sato
  • Patent number: 7300989
    Abstract: The present invention provides a method of preparing an aqueous dispersion of poly(perfluorovinyl ether) homopolymers. The present invention further relates to a method of making an aqueous fluoropolymer dispersion comprising bicomponent particles of poly(perfluorovinyl ether) homopolymers and a second fluoropolymer. The dispersions of the present invention may be used for rendering fibrous substrates oil repellent, water repellent and/or stain repellent without altering the looks and feel of the substrate.
    Type: Grant
    Filed: November 1, 2004
    Date of Patent: November 27, 2007
    Assignee: 3M Innovative Properties Company
    Inventors: Richard S. Buckanin, Lian S. Tan, E. Steven McAlister
  • Publication number: 20070225422
    Abstract: The present invention provides a highly productive method for manufacturing a water-absorbing resin, the amounts of fine powder and dust of which are small, the amount of residual monomer of which is small, and whose absorption rate is high. That is, the method for manufacturing the water-absorbing resin of the present invention is a method for crosslinking and polymerizing an aqueous solution of an acid-group containing unsaturated monomer, and is characterized in that stationary polymerization is carried out in such a manner that a solid matter is added to the monomer aqueous solution, and an initiation temperature of the polymerization is adjusted to 40° C. or more or a maximum temperature of the polymerization is adjusted to 100° C. or more.
    Type: Application
    Filed: March 22, 2007
    Publication date: September 27, 2007
    Inventors: Shigeru Sakamoto, Hiroyuki Ikeuchi, Sayaka Machida
  • Patent number: 7250462
    Abstract: The invention relates to an amphoteric water-soluble polymer dispersion containing polymer particles with particle diameters of 100 ?m or smaller and produced by dispersion-copolymerization of a monomer mixture comprising a methacrylate monomer containing a quaternary ammonium salt group, an acrylate monomer containing a quaternary ammonium salt group, an anionic monomer, and a (meth)acrylamide in respectively ratios specified in an aqueous salt solution in the presence of a polymer dispersant soluble in the aqueous salt solution and the invention also relates to a dewatering agent for organic sludge, a pretreatment agent or yield improver for paper making raw materials, and/or a drainage properties-enhancing agent using the amphoteric water-soluble polymer.
    Type: Grant
    Filed: May 28, 2002
    Date of Patent: July 31, 2007
    Assignee: Hymo Corporation
    Inventors: Isamu Kubota, Hiroyuki Koshio
  • Patent number: 7247671
    Abstract: Aqueous crosslinkable coating composition suitable for anti-graffiti and heavy duty applications comprising: (A) an aqueous polymer emulsion comprising at least one vinyl fluoropolymer which comprises as a polymerized constituent monomer thereof (i) a fluoromonomer(s) having the formula (1) wherein R1 is CH3 or H, R2 is a per-fluorinated C1-5 alkyl group and n is 1, 2, 3 or 4, (ii) a hydroxyl functional monomer(s) and (iii) a carboxylic acid-functional monomer(s) where the vinyl fluoropolymer has a glass transition temperature Tg within the range of from ?50 to 90° C.
    Type: Grant
    Filed: July 22, 2002
    Date of Patent: July 24, 2007
    Assignee: DSM IP Assets B.V.
    Inventors: Gerardus Cornelis Overbeek, Jurgen Scheerder, Tijs Nabuurs
  • Patent number: 7244812
    Abstract: The invention relates to a method for reducing the amount of residual monomers in aqueous polymer dispersions means of chemical post-treatment. Post-treatment in the aqueous polymer dispersion is carried out by adding a redox system which contains a) 0.005-5 wt. % of an oxidation agent which contains an organic peroxide. and b) 0.005-5 wt. % of a reduction agent which contains sulfinic acids or salts thereof. Additionally the redox system can, optionally, contain catalytic amounts of a polyvalent metallic ion which can be treated in several valent stages. Post-treatment can be carried out at a temperature ranging from 20-100.degree. C. and at a PH-value ranging from 2-9. The invention also relates to the use of the inventive post-treated polymer dispersion for producing adhesives, coatings, powders, constructive chemical products or for refining textiles or paper.
    Type: Grant
    Filed: July 26, 2003
    Date of Patent: July 17, 2007
    Assignee: Celanese Emulsions GmbH
    Inventors: Harmin Müller, Martin Jakob, Carsten Heldmann, Thomas Wirth
  • Patent number: 7238149
    Abstract: This invention relates to an improvement in a process for forming a carton from paperboard stock comprising the steps: applying an aqueous based adhesive to select parts of a paperboard carton blank obtained from a paperboard feedstock; drying the aqueous based adhesive; folding the select parts of the adhesive coated carton blank onto cooperating parts of the paperboard blank; and, heat sealing the select and cooperating parts thereby forming the carton; wherein the aqueous based adhesive is comprised of a vinyl acetate/ethylene polymer formed by emulsion polymerization and having (a) a crystalline melting point (Tm) ranging from 35 to 110° C., preferably 50 to 90° C.; measured at a heat rate of 20° C./minute and, (b) a tensile storage modulus of at least 1×104 dynes/cm2 at 115° C. measured at 6.28 rad/sec.
    Type: Grant
    Filed: January 5, 2005
    Date of Patent: July 3, 2007
    Assignee: Air Products Polymers, L.P.
    Inventors: Randolph John Lorenz, Christian Leonard Daniels, John Joseph Rabasco
  • Patent number: 7232857
    Abstract: An adhesive composition comprising natural rubber based particles uniformly dispersed in a radiation setting compound is cured by radiation to make a pressure-sensitive adhesive layer on a substrate, thereby: sufficient adhesiveness is obtained; different fillers sufficiently charged; drying time after application is short; both overall application and pattern application are readily performed; application can be performed on different substrates; and sufficient adhesive strength between the substrate and the pressure-sensitive adhesive layer can be realizes. This adhesive composition may be manufactured by: mixing aqueous emulsion 31 containing the natural rubber based particles 30 and the radiation setting compound 32; elevating a temperature of the mixture while stirring; removing vaporized water in the aqueous emulsion; and replacing the water as the medium wherein the natural rubber based particles are dispersed with the radiation setting compound.
    Type: Grant
    Filed: March 26, 2003
    Date of Patent: June 19, 2007
    Assignee: Toppan Forms Co., Ltd.
    Inventor: Akira Hirasawa
  • Patent number: 7220339
    Abstract: The present invention relates to a process for preparing an aqueous polymer dispersion comprising: preparing a dispersant co-polymer of a monomer mixture (M) by polymerising the monomer mixture (M) in a reaction medium which is substantially free from organic solvents and/or substantially free from monomers which are not soluble in water, the monomer mixture (M) comprises at least one cationic vinyl monomer (m3) and at least one monomer (m4) which is tetrahydrofurfuryl acrylate, tetrahydrofurfuryl methacrylate, or a monomer of the general formula (I): wherein R1 is hydrogen or methyl, R2 is hydrogen or C1-C2 alkyl, R3 is hydrogen, C1-C4 alkyl, phenyl, or benzyl, n=1 to 4, and x=1 to 50, and then, polymerising one or more water-soluble monomers (m) in an aqueous solution of a salt in the presence of the obtained dispersant polymer. The invention also relates to an aqueous polymer dispersion, use of the dispersion and a process for the production of paper.
    Type: Grant
    Filed: June 12, 2006
    Date of Patent: May 22, 2007
    Assignee: Akzo Nobel N.V.
    Inventors: Oliver Struck, Christian Przybyla, Achim Sieger, Mathias Hahn, Dirk Ruppelt, Werner Jaeger
  • Patent number: 7199178
    Abstract: A process for preparing copolymer dispersions that includes subjecting A) one or more vinyl monomer mixtures containing a) OH-free (meth)acrylic esters and/or vinylaromatics, b) hydroxy-functional vinyl monomers and/or hydroxy-functional (meth)acrylic esters, c) ionic and/or potentially ionic monomers capable of free-radical copolymerization, and d)optionally further monomers, other than the compounds of components a)–c), capable of free-radical copolymerization; to free-radical polymerization in the presence of e) compounds according to formula (I) where R1 is an aliphatic, araliphatic or aromatic radical having 1 to 18 carbon atoms, R2 is H or CH3, R3, R4 are identical or different aliphatc radicals having 1 to 7 carbon atoms and n is 1 to 4; and subsequently dispersing the resultant copolymer B) before or after addition of a neutralizing agent C) in water. The resulting dispersions can be used to coat substrates.
    Type: Grant
    Filed: January 24, 2005
    Date of Patent: April 3, 2007
    Inventors: Martin Melchiors, Thomas Münzmay, Thomas Stingl, Hartmut Ottensmann, Heinz-Dietmar Gewiss
  • Patent number: 7189461
    Abstract: This invention is directed to aqueous-based ethylene-vinyl acetate (EVA) polymer emulsions suited for use in heat seal applications. The EVA polymers of this invention are produced by a relatively low-pressure process, i.e., less than 2000 psig, preferably from about 1000 to about 2000 psig. The aqueous-based EVA based polymer emulsions contain crystalline segments resulting from ethylene linkages and are prepared by emulsion polymerizing ethylene and vinyl acetate, preferably with a carboxylic monomer, in the presence of a stabilizing system containing surfactant or a cellulosic protective colloid in combination with surfactant.
    Type: Grant
    Filed: March 4, 2003
    Date of Patent: March 13, 2007
    Assignee: Air Products Polymers, L.P.
    Inventors: John Joseph Rabasco, Christian Leonard Daniels, David William Horwat, Menas Spyros Vratsanos, Richard Henry Bott
  • Patent number: 7186774
    Abstract: The invention provides water-soluble or water-swellable copolymers obtained by free-radical copolymerization of A) acryloyldimethyltaurine and/or acryloyldimethyltaurates, B) optionally, one or more olefinically unsaturated, optionally crosslinking comonomers containing at least one oxygen, nitrogen, sulfur or phosphorus atom and possessing a molecular weight of less than 500 g/mol, C) one or more at least monofunctional, silicon-containing components capable of free-radical polymerization, the copolymerization D) taking place in the presence of at least one polymeric additive having number-average molecular weights of from 200 g/mol to 109 g/mol. The water-soluble or water-swellable copolymers of the present invention are useful in paper processing, laundry detergents, textile processing, petroleum extraction and formulating cosmetics.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: March 6, 2007
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Roman Morschhäuser, Jan Glauder, Matthias Löffler, Susan Rudloff, Sonja Klein
  • Patent number: 7179852
    Abstract: The invention relates to a novel impact-resistance modifier, constructed from a core-shell 1 and a shell 2, whereby the core is plastically deformable. The invention is characterised by excellent mechanical properties obtained by a low content of impact-resistance modifier.
    Type: Grant
    Filed: July 26, 2001
    Date of Patent: February 20, 2007
    Assignee: Roehm GmbH & Co. KG
    Inventors: Klaus Schultes, Thomas Suefke, Reiner Mueller, Thomas Arndt, Goerg Michler, Joachim Laatsch
  • Patent number: 7179531
    Abstract: Polymer particles having select functional or absorbing groups are provided. The polymer particles are useful for preparing organic-inorganic composite particles that are suitable for providing dried coatings with improved hiding. Aqueous compositions containing these composite particles are also provided. The select absorbing groups include phosphorus acid groups, phosphorus acid full-ester groups, polyacid sidechain groups, and salts thereof. The select functional groups are capable of forming covalently bonded composite particles. The composite particles formed from the multistage polymer particles having the select functional or absorbing groups are useful for preparing dried coatings with a combination of improved hiding, increased gloss, and good film properties.
    Type: Grant
    Filed: August 18, 2003
    Date of Patent: February 20, 2007
    Assignee: Rohm and Haas Company
    Inventors: Ward Thomas Brown, James Keith Bardman
  • Patent number: 7173082
    Abstract: The invention relates to an acrylic impact modifier having a core-shell structure that provides an acrylic impact modifier composition comprising (a) a rubber core containing an alkyl acrylate polymer comprising at least two layers having different cross-linking densities, and (b) a shell containing an alkyl methacrylate polymer; to a process for the preparation of the acrylic impact modifier; and to a poly(vinyl chloride) composition comprising it. The acrylic impact modifier imparting excellent impact resistance was invented by employing multi-stage polymerization and at the same time by controlling the swelling index of rubber particles by changing the degree of cross-linking from stage to stage. And the poly(vinyl chloride) comprising the impact modifier of the present invention has good weatherability as well as excellent impact strength.
    Type: Grant
    Filed: January 14, 2003
    Date of Patent: February 6, 2007
    Assignee: LG Chem, Ltd.
    Inventors: Jeong-Heon Ahn, Chang-Sun Han, Yong-Hun Lee, Seon-Hee Han, Kwang-Jin Lee, Hyung-Jun Son
  • Patent number: 7160944
    Abstract: A process for making an aqueous emulsion of polyolefin employs a functionalized emulsification facilitating compound. The aqueous emulsion can be used to prepare a hybrid polyolefin-polyurethane dispersion useful, inter alia, as an adhesion-promoting coating for polymers such as the polyolefins.
    Type: Grant
    Filed: June 17, 2003
    Date of Patent: January 9, 2007
    Assignee: Crompton Corporation
    Inventors: Ibrahim Bechara, Pavel Ilmenev, Oleg Tselnik
  • Patent number: 7112368
    Abstract: The present invention is directed to poly(dioxythiophene)/poly(acrylamidoalkylsulfonic acid) complexes and the oxidative polymerization process for making them. Aqueous dispersions of these poly(dioxythiophene)/poly(acrylamidoalkylsulfonic acid) complexes are useful for forming transparent electrically conductive organic layers comprised of such complexes.
    Type: Grant
    Filed: October 29, 2002
    Date of Patent: September 26, 2006
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Che-Hsiung Hsu
  • Patent number: 7109262
    Abstract: An aqueous effect coating material, comprising (A) at least one water-soluble, -dilutable and/or -dispersible binder, (B) at least one effect pigment, and (C) at least one silicon compound of the general formula I [(E)nL]Si(R1)(R2)(R3)??(I) in which the index and the variables are defined as follows: n is an integer from 1 to 5; E is a reactive functional group; L is an at least divalent, linking, organic group; R1 is a substituted or unsubstituted cycloalkoxy, alkoxy, aryloxy, cycloalkyl, alkyl or aryl radical; and R2 and R3 independently of one another are substituted or unsubstituted cycloalkoxy, alkoxy or aryloxy radicals or hydroxyl groups; preparation process, and its use.
    Type: Grant
    Filed: October 21, 2002
    Date of Patent: September 19, 2006
    Assignee: BASF Coatings AG
    Inventor: Ekkehard Sapper
  • Patent number: 7105593
    Abstract: An aqueous polymer blend composition containing particles of a first polymer and particles of a second polymer with preferred molecular weight ranges is provided. Coatings prepared from the aqueous polymer blend composition may be employed as coatings which have water whitening resistance and provide resistance to efflorescence to cementitious substrates, such as roof tiles. A method of preparing a coated cementitious substrate with the aqueous polymer blend composition and an article containing the coated cementitious substrate are also provided.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: September 12, 2006
    Assignee: Rohm and Haas Company
    Inventors: Robert David Solomon, Mary Anne Regina Matthews
  • Patent number: 7101925
    Abstract: A process to substantially remove the fluorinated anionic surfactants comprising the following steps: a) addition to a fluoropolymer dispersion of a nonionic surfactant, in an amount in the range 1.5%–25% by weight, referred to the fluoropolymer weight; b) addition to the dispersion of a salt, soluble in water and not giving precipitates in the dispersion under the use conditions; c) contact of the dispersion with a basic anionic exchanger; d) separation of the dispersion from the basic anionic exchanger; before step d) the dispersion being filterable on a 180 micrometer net and successively on a 10 micrometer net.
    Type: Grant
    Filed: January 12, 2005
    Date of Patent: September 5, 2006
    Assignee: Solvay Solexis, S.p.A.
    Inventors: Marco Malvasi, Valeri Kapeliouchko
  • Patent number: 7101921
    Abstract: A polymer composition including polymer particles containing a first polymer and a second polymer is disclosed. The first polymer has a crosslinked core and has a glass transition temperature in the range of ?30° C. to 100° C. The second polymer containing select crosslinking groups and has a glass transition temperature in the range of ?10° C. to less than 18° C. A process to prepare the polymer composition is provided. Also provided are a coated article containing a coating prepared from the polymer composition and a method of preparing the coated article. The polymer composition has good low temperature film formation and provides a film with an acceptable level of hardness.
    Type: Grant
    Filed: October 11, 2002
    Date of Patent: September 5, 2006
    Assignee: Rohm and Haas Company
    Inventors: Steven Scott Edwards, Matthew Stewart Gebhard, Allen Philip Marks, Alvin Michael Maurice
  • Patent number: 7094831
    Abstract: An aqueous polymer dispersion prepared by free-radical polymerization of vinyl acetate in the presence of at least one ionic emulsifier, at least one free-radical initiator and at least one protective colloid, wherein the polymerization is carried out in the presence of a polymerization regulator and wherein the ratio by weight of protective colloid to ionic emulsifier is at least 4:1 and wherein the ratio by weight of vinyl acetate monomer to protective colloid is between 19:1 and 4:1.
    Type: Grant
    Filed: September 25, 2001
    Date of Patent: August 22, 2006
    Assignee: BASF Aktiengellsellschaft
    Inventors: Karl Kolter, Maximilian Angel, Katrin Zeitz
  • Patent number: 7094824
    Abstract: The present invention discloses a rubbery polymer having improved properties, which is comprised of repeat units which are comprised of (a) butyl acrylate, or optionally a mixture of butyl acrylate and 2-ethylhexyl acrylate containing up to about 40 percent 2-ethylhexyl acrylate, (b) at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate, and ethyl acrylate, (c) optionally, about 0% to about 40% of an alkoxy ethyl acrylate or an alkoxy ethyl methacrylate, (d) acrylonitrile, (e) styrene, and (f) a crosslinking agent; wherein about 1% to about 10% of a monomer containing reactive cure sites selected from the group consisting of hydroxyl groups, glycidyl groups, carboxylic acid groups, and unsaturated cure sites is incorporated into the rubbery polymer.
    Type: Grant
    Filed: June 3, 2005
    Date of Patent: August 22, 2006
    Assignee: Eliokem S.A.S.
    Inventor: Hung Dang Ngoc
  • Patent number: 7091273
    Abstract: The present invention relates to a process for preparing an aqueous polymer dispersion comprising: preparing a dispersant co-polymer of a monomer mixture (M) by polymerising the monomer mixture (M) in a reaction medium which is substantially free from organic solvents and/or substantially free from monomers which are not soluble in water, the monomer mixture (M) comprises at least one cationic vinyl monomer (m3) and at least one monomer (m4) which is tetrahydrofurfuryl acrylate, tetrahydrofurfuryl methacrylate, or a monomer of the general formula (I): wherein R1 is hydrogen or methyl, R2 is hydrogen or C1–C2 alkyl, R3 is hydrogen, C1–C4 alkyl, phenyl, or benzyl, n=1 to 4, and x=1 to 50, and then, polymerising one or more water-soluble monomers (m) in an aqueous solution of a salt in the presence of the obtained dispersant polymer. The invention also relates to an aqueous polymer dispersion, use of the dispersion and a process for the production of paper.
    Type: Grant
    Filed: May 7, 2003
    Date of Patent: August 15, 2006
    Assignee: Akzo Nobel N.V.
    Inventors: Oliver Struck, Christian Przybyla, Achim Sieger, Mathias Hahn, Dirk Ruppelt, Werner Jaeger
  • Patent number: 7084200
    Abstract: Aqueous dispersions of water-soluble polymers of N-vinylcarboxamides, which contain, as a stabilizer, water-soluble, crosslinked graft polymers which are obtainable by free radical polymerization of compounds having at least two ethylenically unsaturated double bonds in the presence of polyalkylene glycols, are prepared by free radical polymerization of N-vinylcarboxamides in an aqueous medium in the presence of said stabilizers and are used as drainage aids, flocculants and retention aids, as wet and dry strength agents and as fixing agents in papermaking.
    Type: Grant
    Filed: November 19, 2002
    Date of Patent: August 1, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: Marc Leduc, Stefan Frenzel, Norbert Mahr
  • Patent number: 7081507
    Abstract: The invention provides water-soluble or water-swellable copolymers obtained by free-radical copolymerization of A) acryloyldimethyltaurine and/or acryloyldimethyltaurates, B) optionally, one or more other olefinically unsaturated, noncationic, optionally crosslinking comonomers containing at least one oxygen, nitrogen, sulfur or phosphorus atom and possessing a molecular weight of less than 500 g/mol, C) one or more mono- or polyolefinically unsaturated, optionally crosslinking macromonomers each possessing at least one oxygen, nitrogen, sulfur or phosphorus atom and having a number-average molecular weight of greater than or equal to 200 g/mol, and D) one or more olefinically unsaturated, cationic comonomers containing at least one oxygen, nitrogen, sulfur or phosphorus atom and possessing a molecular weight of less than 500 g/mol, the copolymerization E) taking place in the presence or absence of at least one polymeric additive having number-average molecular weights of from 200 g/mol to 109 g/mol.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: July 25, 2006
    Assignee: Clariant GmbH
    Inventors: Roman Morschhäuser, Jan Glauder, Sonja Klein, Matthias Löffler
  • Patent number: 7078455
    Abstract: The present invention relates to aqueous plastic material dispersions based on vinyl ester copolymers, having a solids content of up to 80% by weight and a minimum film formation temperature below 20° C., which is substantially stabilized by ionic components, the vinyl ester copolymers containing at least one homo- or copolymer A and at least one homo- or copolymer B, methods for producing the same and the use thereof.
    Type: Grant
    Filed: March 14, 2002
    Date of Patent: July 18, 2006
    Assignee: Celanese Emulsions GmbH
    Inventors: Carsten Heldmann, Harald Petri, Thomas Wirth
  • Patent number: 7067578
    Abstract: Process for the preparation of latices by batchwise radical polymerization of one or more monomers, comprising the participation, in the polymerization, of: (a) one or more fine dispersions of one or more finely dispersed monomers and (b) one or more seed latices of one or more seeding polymers.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: June 27, 2006
    Assignee: Solvay (Societe Anonyme)
    Inventor: Henri Massillon
  • Patent number: 7053146
    Abstract: The invention relates to compositions comprising copolymers based on acryloyldimethyltaurine and also synergistic additives selected from anionic, cationic, nonionic, and betaine surfactants. The compositions exhibit a pronounced thermoassociative behavior and are outstandingly suitable as thickeners. The copolymers of the present invention are useful in formulating cosmetics, pharmaceuticals, and oil field chemicals.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: May 30, 2006
    Assignee: Clariant GmbH
    Inventors: Roman Morschhäuser, Christoph Kayser, Matthias Löffler, Karl Heinz Heier, Aranka Tardi, Manfred Schade, Gernold Botthof
  • Patent number: 7037956
    Abstract: A water-soluble resin composition comprising a water-soluble resin and a colorant, which copolymer has a weight average molecular weight of at least 8,000 and is prepared by polymerizing an ethylenically unsaturated carboxylic acid monomer and a monomer copolymerizable therewith in the presence of an alcoholic hydroxyl group-containing water-soluble high polymer or a copolymerizable surface active agent to give a copolymer having an acid value in the range of 5 to 120 and then neutralizing the thus-obtained copolymer with a basic, exhibits a reduced viscosity change when it is stored for a long period, and is useful as an aqueous ink capable of giving an image having good dot reproducibility and good abrasion resistance.
    Type: Grant
    Filed: October 19, 2001
    Date of Patent: May 2, 2006
    Assignee: Zeon Corporation
    Inventors: Xiang Liu, Tomomi Onitake, Toshihiro Inoue
  • Patent number: 7037978
    Abstract: The invention relates to a quasi-interpenetrating network of polymer chains, the chains comprising linear polyacrylamide (LPA) chains in the form of a main frame having a weight average molecular weight of approximately 0.05 million to approximately 25 million g/mole, and a radius of gyration of approximately 10 nm to 350 nm; and polydimethylacrylamide (PDMA) chains prepared by polymerizing PDMA in the presence of the LPA main frame, wherein the LPA and PDMA chains are entangled within one another and interpenetrate one another, and wherein the quasi-interpenetrating network has substantially no chemical cross-linking.
    Type: Grant
    Filed: September 25, 2003
    Date of Patent: May 2, 2006
    Assignee: The Research Foundation of SUNY at Stony Brook
    Inventors: Benjamin Chu, Liguo Song, Dufei Fang, Dehai Liang, Tianbo Liu, Yanmei Wang, Qicong Ying
  • Patent number: 7026369
    Abstract: To provide an aqueous emulsion composition which has high adhesion strength for a wide variety of materials including molded products and affords sufficient wettability even for the object to be adhesive bonded of low surface polarity so that it can develop sufficient adhesiveness and whose emulsion is stable so satisfactorily as to provide good mechanical stability and storage stability, and to provide an adherent composition comprising the aqueous emulsion composition, at least ethylene-vinyl acetate copolymer or modified resin thereof, photo polymerization initiator, and unsaturated ethylenic monomer are mixed and dissolved or dispersed, to prepare oil drop component, followed by emulsifying the oil drop component in water by using a surface-active agent, whereby an aqueous emulsion composition, in which micelles each encapsulating at least the ethylene-vinyl acetate copolymer or modified resin thereof, the photo polymerization initiator and unsaturated ethylenic monomer are dispersed in water, is prepared
    Type: Grant
    Filed: July 22, 2002
    Date of Patent: April 11, 2006
    Assignee: Mitsui Takeda Chemicals, Inc.
    Inventors: Kenji Kuroda, Susumu Okatani, Hiroyuki Shiraki
  • Patent number: 7012114
    Abstract: The present invention relates to a latex with modified surface chemistry, which may be obtained by carrying out a free-radical emulsion polymerization in the presence of at least one ethylenically unsaturated monomer or at least one polymer containing residual ethylenically unsaturated bonds, of at least one free-radical polymerization initiator, of at least one water-soluble and/or water-dispersible monoblock, diblock or triblock polymer comprising at its end an active group capable of forming a radical, chosen from dithioesters, xanthates, thioether-thiones and diothiocarbamates. The invention similarly relates to redispersible powders that may be obtained by drying the said latices.
    Type: Grant
    Filed: December 8, 2000
    Date of Patent: March 14, 2006
    Inventors: William Bett, Jean-Christophe Castaing, Jean-Francois D'Allest