Water Dnrm Containing Patents (Class 524/510)
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Patent number: 4980410Abstract: An improved adhesive composition comprising a nonacidic aqueous latex copolymer of a lower acrylate, an acrylic nitrile and a glycidyl acrylate having a crosslinking agent dissolved in the aqueous phase.Type: GrantFiled: May 30, 1989Date of Patent: December 25, 1990Assignee: E. I. du Pont de Nemours and CompanyInventors: Michael Fryd, Walter E. Pye, Richard D. Redfearn
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Patent number: 4980409Abstract: Disclosed are an aqueous matte coating composition containing an aqueous dispersion (I) formed by dispersing into water (A) a water-dispersible vinyl copolymer having an acid value of 15 to 150 and a hydroxyl value of 30 to 200 and hving alkoxysilane group on its side chain and (B) a melamine resin not having complete compatibility with said vinyl copolymer (A); and an aqueous matte coating composition containing an aqueous dispersion (II) of the vinyl copolymer (A), and an aqueous dispersion (III) formed by dispersing into water (B) a melamine resin not having complete compatibility with the vinyl copolymer (A) and (C) a water-dispersible vinyl copolymer having neither alkoxysilane group nor complete compatibility with the melamine resin (B), and having an acid value of 15 to 150 and a hydroxyl value of 30 to 200.Type: GrantFiled: October 10, 1989Date of Patent: December 25, 1990Assignee: Kansai Paint Co., Ltd.Inventors: Hiromi Harakawa, Hiroshi Inoue, Hiroyuki Negishi
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Patent number: 4942198Abstract: The invention relates to aqueous two-component lacquers containing pigments and other customary additives for single-layered coating of finish film and continuous edges. The two-component lacquers according to the invention are such lacquers in which the first component (component (A)) contains 0.1 to 15% by weight, preferably 2 to 10% by weight, based on the total weight of component (A), of a blocked acid as a potential hardening catalyst and 10 to 90% by weight, preferably 20 to 65% by weight, based on the total weight of component (A), of an aqueous dispersion of a self-crosslinking polyacrylate, in which the polyacrylate contains, as the groups which facilitate self-crosslinking, acid amide derivative groups which correspond to the general structural formula --CO--N(R.sup.1)--CH(R.sup.2)--OR.sup.3, in which R.sup.1 =an H atom or a --CH(R.sup.2)--OR.sup.3 grouping, R.sup.2 =an H atom or a --COOR.sup.4 group, R.sup.Type: GrantFiled: September 27, 1988Date of Patent: July 17, 1990Assignee: Basf Lacke & Farben AktiengesellschaftInventors: Karl-heinz Dickerhof, Gunther Schwarz
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Patent number: 4940841Abstract: The invention relates to aqueous two-component paints containing customary additives and, if appropriate, pigments, for one-coat coating of finishing sheeting and continuous edging, characterized in that the paints containing as paint component (I)(A) 40 to 85% by weight, preferably 60 to 85% by weight, of an aqueous dispersion of a self-crosslinking polyacrylate resin, which contains as the groups capable of bringing about the self-crosslinking acid amide derivative groups corresponding to the general structural formula--CO--N(R.sup.1)--CH(R.sup.2)--OR.sup.3,whereinR.sup.1 =a hydrogen atom or a --CH(R.sup.2)--OR.sup.3 group,R.sup.2 =a hydrogen atom or a --COOR.sup.4 group,R.sup.3 =a hydrogen atom or a hydrocarbon radical of 1 to 10 carbon atoms, preferably the methyl, ethyl, (iso)propyl or (iso)butyl radical,R.sup.Type: GrantFiled: August 16, 1989Date of Patent: July 10, 1990Assignee: BASF Lacke & Farben AktiengesellschaftInventor: Karl-Heinz Dickerhof
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Patent number: 4889887Abstract: Gelable acid compositions containing novel crosslinkable copolymers and the novel copolymers. The copolymers contain an N-(alkoxymethylene)acrylyl moiety. In addition there are provided gelable acid compositions containing a group of polyfunctional reactants that contain a plurality of --CH.sub.2 OH and/or --CH.sub.2 CH.sub.2 OH groups in the molecule.Type: GrantFiled: February 22, 1988Date of Patent: December 26, 1989Assignee: Union Carbide Chemicals and Plastics Company Inc.Inventors: You-Ling Fan, James P. Stanley, George L. Brode
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Patent number: 4866119Abstract: Woven pile fabrics, particularly upholstery fabrics and corduroy, characterized by a superior balance of strength and softness are back-coated utilizing an aqueous emulsion prepared by the emulsion polymerization of a vinyl ester of an alkanoic acid interpolymerized with 10 to 30% by weight ethylene; 15 to 40% by weight of a C4-C10 dialkyl maleate; to 5% by weight of copolymerizable N-methylol containing monomer; 0 to 4% by weight of an olefinically unsaturated carboxylic acid and 0 to 1% by weight of a polyethylenically unsaturated comonomer.Type: GrantFiled: September 8, 1987Date of Patent: September 12, 1989Assignee: National Starch and Chemical CorporationInventor: Paul R. Mudge
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Patent number: 4861820Abstract: An adhesive composition comprising(A) 100 parts by weight of a copolymer latex mixture consisting of(a1) 50 to 95% by weight (expressed as a solid content) of a butadiene-styrene-vinylpyridine copolymer latex and(a2) 5 to 50% by weight (expressed as a solid content) of a carboxylated butadiene-styrene base copolymer latexand(B) 10 to 30 parts by weight of a resorcinformalin resin, which adheres fiber to rubber with good initial adhesion strength and/or without deterioration of adhesion strength after thermal history, and has good mechanical stability.Type: GrantFiled: August 27, 1987Date of Patent: August 29, 1989Assignee: Sumitomo Naugatuck Co., Ltd.Inventors: Yasushi Toyoda, Saburo Mishiba, Toshiyasu Nishioka
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Patent number: 4840990Abstract: The present invention relates to aqueous binder dispersions for the preparation of, inter alia, paints and finishes, substantially containing(A) from 0.5 to 50% by weight of a phenolic resin precondensate,(B) from 20 to 70% by weight of a copolymer of predominant proportions of alkyl acrylates and/or methacrylates, minor proportions of comonomers with groups capable of crosslinking and other comonomers, the copolymer being in the form of a dispersion and being crosslinkable by a condensation reaction, and(C) from 10 to 70% by weight of a graft elastomer comprising a diene polymer as the base polymer and a copolymer of, substantially, styrene, acrylonitrile and C.sub.1 -C.sub.6 -alkyl acrylates and/or methacrylates, as the graft polymer, the graft elastomer being in the form of a dispersion, the percentages being based on the solids content of the total amount of (A), (B) and (C).Type: GrantFiled: September 26, 1988Date of Patent: June 20, 1989Assignee: BASF AktiengesellschaftInventors: Erich Gullbins, Graham E. McKee, Gregor Ley
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Patent number: 4812215Abstract: An aqueous, cationically electrodepositable coating composition contains a ternary sulfonium or quaternary phosphonium group containing resin, an aminoplast or phenoplast crosslinking agent and a catalytic amount of a non-ionic ester of a sulfonic acid as latent acid catalyst to catalyze the reaction between the sulfonium or phosphonium group containing resin and the aminoplast crosslinking agent.Type: GrantFiled: August 12, 1988Date of Patent: March 14, 1989Assignee: PPG Industries, Inc.Inventors: Richard F. Karabin, Ken W. Niederst, Michael G. Sandala, Edward R. Coleridge
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Patent number: 4808655Abstract: The present invention relates to aqueous binder dispersions for the preparation of, inter alia, paints and finishes, substantially containing(A) from 0.5 to 50% by weight of a phenolic resin precondensate,(B) from 20 to 70% by weight of a copolymer of predominant proportions of alkyl acrylates and/or methacrylates, minor proportions of comonomers with groups capable of crosslinking and other comonomers, the copolymer being in the form of a dispersion and being crosslinkable by a condensation reaction, and(C) from 10 to 70% by weight of a graft elastomer comprising a diene polymer as the base polymer and a copolymer of, substantially, styrene, acrylonitrile and C.sub.1 -C.sub.6 -alkyl acrylates and/or methacrylates, as the graft polymer, the graft elastomer being in the form of a dispersion, the percentages being based on the solids content of the total amount of (A), (B) and (C).Type: GrantFiled: August 28, 1987Date of Patent: February 28, 1989Assignee: BASF AktiengesellschaftInventors: Erich Gulbins, Graham E. McKee, Gregor Ley
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Patent number: 4788246Abstract: Disclosed is a micro gel particle having a cationic charge, which is electrodepositable. The micro gel particle is obatined in the form of aqueous dispersion. The micro gel particle dispersion is prepared by a process comprisingemulsifying in an aqueous medium a resin composition comprising(A) 100 parts by weight of a cationic film-forming aqueous resin, and(B) 10 to 250 parts by weight of a thermosetting crosslinking agent which is self-crosslinked or crosslinked with said aqueous resin (A) in terms of condensation or addition reaction;parts by weight being based on the solid content of the resin composition, andheating the resultant emulsion to above a crosslinkable temperature of said crosslinking agent (B).Type: GrantFiled: November 30, 1987Date of Patent: November 29, 1988Assignee: Nippon Paint Co., Ltd.Inventors: Yasuyuki Tsuchiya, Kenshiro Tobinaga
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Patent number: 4731409Abstract: An aqueous coating composition comprising (A) an aqueous medium, (B) at least one water soluble or dilutable resin which has a water tolerance of 4 or more and whose 1% by weight aqueous solution shows a surface tension of 51 dyne/cm or less, and (C) fine particles of resinous solution of water insoluble resin in a hydrophobic solvent, the particles being uniformly dispersed in the combination of said aqueous medium (A) and the water soluble or dilutable resin (B) and having a mean diameter of 1.mu. or less, which is characterized in that the absolute value of difference in solubility parameter (.vertline..DELTA.Sp.vertline.) between said resinous solution and said water soluble or dilutable resin is within a range of .vertline..DELTA.Sp.vertline.<2.The present coating composition is excellent in storage stability and application characteristics, resulting a coating with excellent gloss and surface smoothness.Type: GrantFiled: February 3, 1987Date of Patent: March 15, 1988Assignee: Nippon Paint Co., Ltd.Inventors: Hiroshi Miwa, Hideyoshi Noda, Sakuichi Konishi
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Patent number: 4724244Abstract: Cathodic coating agents which are rendered water-dilutable by the addition of an acid, contain binder systems possessing basic nitrogen groups and may or may not contain pigments, dyes, fillers, solvents, antioxidants, other surface coating assistants and/or additional crosslinking components, the binder system containing sulfonate and/or phosphonate groups or the esters of these groups in an amount of from 0.05 to 3% by weight, and the preparation of such products.The novel coating agents are useful for the cathodic electrocoating of electrically conductive substrates.Type: GrantFiled: April 27, 1987Date of Patent: February 9, 1988Assignee: BASF AktiengesellschaftInventors: Fritz E. Kempter, Wolfram Weiss, Rolf Osterloh, Albrecht Zosel
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Patent number: 4699945Abstract: Disclosed is a self-adhesive coating for polypropylene foams. The coating is the chemical crosslinking product of 2-chlorobutadiene/methacrylic acid copolymer and a prepolymer of an aminoplastic or phenolic plastic containing methylol groups.Type: GrantFiled: March 21, 1986Date of Patent: October 13, 1987Assignee: Firma Carl FreudenbergInventors: Jorg Hausdorf, Joachim Kandler, Volker Siekermann, Wilfried Getrost
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Patent number: 4687809Abstract: A room temperature setting adhesive composition capable of giving high initial bond strength as well as cured bonds having good resistance to water and boiling contains, as main components thereof, (A) an emulsion containing an acetoacetylated polyvinyl alcohol and a vinyl acetate copolymer produced by copolymerizing an acetoacetylated, ethylenically unsaturated monomer and another ethylenically unsaturated monomer and (B) a resorcinol resin precondensate and, as a curing agent, (C) hexamethylenetetramine.Type: GrantFiled: June 24, 1986Date of Patent: August 18, 1987Assignee: National Starch and Chemical CorporationInventors: Takeshi Kamikaseda, Makoto Yamamoto
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Patent number: 4632946Abstract: A halogen-free flameproofed thermoplastic molding material consists of a halogen-free thermoplastic resin (A) and one or more further halogen-free components.The thermoplastic resin (A) is present in an amount of from 30 to 90% by weight, based on the molding material. The latter contains, as further components, from 1 to 50% by weight of a phenol/aldehyde resin (B), from 1 to 50% by weight of a nitrogen-containing organic compound (C) and from 3 to 50% by weight of a phosphorus-containing organic compound (D), the percentages in each case being based on the molding material.The molding material is used for the production of flameproofed moldings.Type: GrantFiled: January 18, 1985Date of Patent: December 30, 1986Assignee: BASF AktiengesellschaftInventors: Volker Muench, Juergen Hambrecht, Adolf Echte, Karl H. Illers, Johann Swoboda
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Patent number: 4623679Abstract: A binder which is suitable for coating agents and is based on a combination which is essentially free of protective colloids and consists of an aqueous primary dispersion of a synthetic polymer and a water-insoluble polycondensate of phenols and aldehydes, some of which may be replaced by ketones, is prepared by a process in which the phenolic components for the polycondensate are first mixed with an aqueous primary dispersion of a synthetic polymer which contains glycidyl, carbonyl, N-methylol, N-alkoxymethyl, ether, amino and/or hydrazo groups and may furthermore contain carboxyl or hydroxyl groups, and the polycondensation with the aldehydes (and ketones) is then carried out in this mixture, under conventional conditions.The binders prepared according to the invention are useful as binders for dispersion paints and coatings, in particular as heat-curable binders for metal finishes.Type: GrantFiled: June 13, 1985Date of Patent: November 18, 1986Assignee: BASF AktiengesellschaftInventors: Juergen Gimpel, Erich Gulbins, Gregor Ley
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Patent number: 4618657Abstract: A heat curable coating composition which deposits a release coating containing a smaller proportion of silicone release material is disclosed. This composition comprises (1) an hydroxy-functional resin which is preferably a polyester resin; (2) a cross-linking agent for the polyester, such as an aminoplast resin; and (3) at least one and preferably a mixture of at least two reactive silicones which are preferably polysiloxanes. These two polysiloxanes comprise: (A) a hydrogen- or alkoxy-functional polysiloxane; and (B) an elastomeric polysiloxane reactive with the hydrogen- or alkoxy-functional polysiloxane to provide release properties. Either or both of the polysiloxanes are reactive with the hydroxy-functional resin or the cross-linking agent. Components (1), (2) and (3) are compatible in a liquid admixture which may contain a volatile inert organic solvent or which may be solvent-free.Type: GrantFiled: March 11, 1985Date of Patent: October 21, 1986Assignee: DeSoto, Inc.Inventors: John Katchko, Thomas H. Plaisance, Karel Kriz
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Patent number: 4612254Abstract: Novel metal-modified phenolic resins useful in the color developer part of a carbonless copy paper system are disclosed, as well as methods for preparing such resins. The metal-modified phenolic resins are reaction products of an aromatic carboxylic acid and a partial condensation reaction product (an oligomer) of a phenol and an aldehyde. The metal-containing compound is added either to the mixture of phenol and aldehyde in forming the oligomer or to the mixture of aromatic carboxylic acid and the oligomer. The color developer materials of the invention are coated on a paper substrate which forms a part of a pressure sensitive recording paper system. The color developer materials exhibit improved performance over prior art colored developer materials.Type: GrantFiled: March 7, 1985Date of Patent: September 16, 1986Assignee: Occidental Chemical CorporationInventors: James W. Ginter, Donald H. Thorpe, Victor F. G. Cooke
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Patent number: 4599375Abstract: Polymeric compositions endowed with high flame self-extinguishing properties, comprising a polymer selected from amongst olefinic polymers, polystyrene, polybutylene terephthalate, SAN and ABS copolymers, and also, for 100 parts of composition:(a) 20-50 parts of piperazine acid pyrophosphate;(b) 0-3 parts of at least a compound selected from TiO.sub.2, SiO.sub.2, silicic acid, in powder having particle size .ltoreq.0.1 micron;(c) 0-35 parts of at least a compound selected from ammonium polyphosphate, melamine, melamine phosphate and pyrophosphate, polycarboxypiperazine, ethylene urea/formaldehyde condensates, as a substitute for an equal weight of compound (a), and in such amount that the composition still contains at least 5 parts of such compound (a).Type: GrantFiled: May 16, 1984Date of Patent: July 8, 1986Assignee: Montedison S.p.A.Inventors: Ferruccio Berte', Franco Marciandi, Marco Binaghi
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Patent number: 4594383Abstract: A water soluble copolymer of polymerizable esters of unsaturated carboxylic acids having the hydrazide group as a substituent comprises a major proportion of monomer units which are methyl acrylate and/or methyl methacrylate and a minor proportion of co-monomer units which are one or more alkyl esters of acrylic acid or methacrylic acid wherein the alkyl group comprises at least four carbon atoms. The copolymer has film forming properties which make it useful for use in protective coatings. The invention includes a film forming composition comprising the copolymer and a cross-linking agent which cross-linking agent is an aldehyde or an organic thermosetting resin containing methylol or methoxy groups, the copolymer and cross-linking agent being dissolved in an aqueous medium in amounts such that they will form a film when applied to a surface. The composition is applied to a surface and heated at 120.degree. to 180.degree. C.Type: GrantFiled: December 26, 1984Date of Patent: June 10, 1986Assignee: The British Petroleum Company p.l.c.Inventors: Sidney G. Fogg, Frank C. Robertson
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Patent number: 4569963Abstract: An adhesive composition for bonding fibers to a rubber is made of an aqueous dispersion composed mainly of a resorcinol/formaldehyde resin and a rubbery vinylpyridine copolymer latex. Particles of the rubbery vinylpyridine copolymer latex having a weight-average particle size of at least 0.15 micron, provided when the weight-average particle size is less than 0.16 micron, the particles having a particle size of at least 0.18 micron amount to at least 5% by weight.Type: GrantFiled: July 3, 1984Date of Patent: February 11, 1986Assignee: Nippon Zeon Co., Ltd.Inventors: Hiroshi Hisaki, Yasuhiro Nakano, Naohiko Takahashi, Yuichi Inoue
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Patent number: 4560717Abstract: Formaldehyde-containing cationic electrodepositable compositions to which are added a formaldehyde scavenger are disclosed. Also disclosed are the use of these compositions in a method of cationic electrodeposition. Free formaldehyde in cationic compositions can lower the pH of the compositions making them more corrosive to the metal parts such as ferrous metal tanks and attending piping and pumps in contact with such compositions. The presence of the formaldehyde scavenger in such compositions stabilizes the pH.Type: GrantFiled: July 3, 1984Date of Patent: December 24, 1985Assignee: PPG Industries, Inc.Inventors: Roger M. Christenson, Joseph T. Valko, Joseph E. Plasynski, Roger L. Scriven
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Patent number: 4560714Abstract: Disclosed are carboxylic acid containing polymeric microgel particles which are prepared by polymerizing in aqueous emulsion a monomer mixture containing about 10-50% by weight of polymerizable carboxylic acid monomers, up to 5% of a difunctional crosslinking monomer and one or more carboxyl-free relatively water insoluble polymerizable vinyl monomers. The resulting microgel particles are water-swellable and may be employed as stabilizers for use in the preparation of aqueous dispersions of film-forming resins containing smaller amounts of organic solvents than conventional aqueous dispersions of this type. Such dispersions are useful as coating compositions, yielding coatings having less water sensitivity and improved adhesion as compared with coatings obtained from conventional aqueous dispersions of film-forming resins.Type: GrantFiled: January 18, 1985Date of Patent: December 24, 1985Assignee: Celanese CorporationInventors: Chandrasen Gajria, Yehuda Ozari
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Patent number: 4546014Abstract: Disclosed are carboxylic acid containing polymeric microgel particles which are prepared by polymerizing in aqueous emulsion a monomer mixture containing about 10-50% by weight of polymerizable carboxylic acid monomers, up to 5% of a difunctional crosslinking monomer and one or more carboxyl-free relatively water insoluble polymerizable vinyl monomers. The resulting microgel particles are water-swellable and may be employed as stabilizers for use in the preparation of aqueous dispersions of film-forming resins containing smaller amounts of organic solvents than conventional aqueous dispersions of this type. Such dispersions are useful as coating compositions, yielding coatings having less water sensitivity and improved adhesion as compared with coatings obtained from conventional aqueous dispersions of film-forming resins.Type: GrantFiled: January 18, 1985Date of Patent: October 8, 1985Assignee: Celanese CorporationInventors: Chandrasen Gajria, Yehuda Ozari
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Patent number: 4544699Abstract: An adhesive composition, particularly useful for laminating carboxylate-containing films, comprises an aqueous dispersion of a film-forming vinylidene chloride copolymer wherein the vinylidene chloride copolymer includes on a comonomer weight basis:(a) from about 45 to about 90 percent vinylidene chloride,(b) from about 5 to about 25 percent of a polar comonomer having one or more hydroxyl groups, and(c) from about 0 to about 30 percent of a plasticizing monomer for vinylidene chloridein combination with:(d) a cross-linking agent dissolved in the continuous aqueous phase of the vinylidene chloride copolymer.Type: GrantFiled: October 11, 1983Date of Patent: October 1, 1985Assignee: Union Oil Company of CaliforniaInventor: John Biale
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Patent number: 4539348Abstract: Disclosed are carboxylic acid containing polymeric microgel particles which are prepared by polymerizing in aqueous emulsion a monomer mixture containing about 10-50% by weight of polymerizable carboxylic acid monomers, up to 5% of a difunctional crosslinking monomer and one or more carboxyl-free relatively water insoluble polymerizable vinyl monomers. The resulting microgel particles are water-swellable and may be employed as stabilizers for use in the preparation of aqueous dispersions of film-forming resins containing smaller amounts of organic solvents than conventional aqueous dispersions of this type. Such dispersions are useful as coating compositions, yielding coatings having less water sensitivity and improved adhesion as compared with coatings obtained from conventional aqueous dispersions of film-forming resins.Type: GrantFiled: January 14, 1985Date of Patent: September 3, 1985Assignee: Celanese CorporationInventors: Chandrasen Gajria, Yehuda Ozari
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Patent number: 4537931Abstract: This invention provides flow-regulated adhesive latex formulations which exhibit unique shear-thinning properties for coating of substrates such as tire cord. The essential components of an invention aqueous adhesive composition for textile-rubber bonding consist of (1) an associative thickener, (2) a phenol-aldehyde resin; and (3) a latex of curable elastomer.Type: GrantFiled: November 14, 1983Date of Patent: August 27, 1985Assignee: Celanese CorporationInventors: Gunilla E. Gillberg-La Force, Helen A. Kravas
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Patent number: 4529767Abstract: A thermosetting latex paint is disclosed which cures to provide better gloss and gloss retention of ultraviolet exposure. This latex paint comprises water having suspended therein copolymer particles of aqueous emulsion copolymerized monomers consisting essentially of monoethylenically unsaturated monomers including at least about 30% up to about 80% of vinyl acetate, the balance of the monomers in the copolymer including from 2% up to about 15% of monomers providing reactive hydrogen atoms, like hydroxyethyl methacrylate, to enable the copolymer to thermoset in the presence of a curing agent which reacts with the reactive hydrogen atoms of the copolymer, like hexamethoxymethyl melamine. The copolymer particles are suspended in the water by surfactant comprising at least 2% up to about 8%, based on total monomers, of an ethylene oxide adduct of an alkyl-substituted phenol having from 10-18 carbon atoms in the alkyl group with 5-14 moles of adducted ethylene oxide per mole of said substituted phenol.Type: GrantFiled: April 2, 1984Date of Patent: July 16, 1985Assignee: DeSoto, Inc.Inventors: Christine P. Bashleben, Gregory D. Shay, Alfred E. Smith
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Patent number: 4525520Abstract: In a microencapsulation process which causes hydrophobic core material containing an oil-soluble melamine-formaldehyde precondensate to emulsified in water or in a hydrophilic medium, and to form capsule wall film under conditions for promoting polycondensation, the process which is characterized in that said oil-soluble melamine-formaldehyde precondensate is 40 to 100% in a degree of formaldehyde substitution, 80 to 100% in alkylation degree, and 4 to 11 in hydrophobic degree.Type: GrantFiled: March 23, 1984Date of Patent: June 25, 1985Assignee: Kanzaki Paper Manufacturing Company, Ltd.Inventors: Shunsuke Shioi, Gensuke Matoba, Makoto Miyake
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Patent number: 4521460Abstract: A stable aqueous dispersion of a room temperature curing polymer effective for forming films resistant to water and organic solvents, said polymer being a water-dispersible vinyl addition polymer containing a sufficient proportion of pendant N-methylolhydrazide groups to cause the polymer to cure in situ on a substrate when said dispersion is applied to the substrate and dried at ambient temperature. The polymer preferably sufficient pendant carboxylic salt groups to render the polymer water-dispersible or water soluble.Type: GrantFiled: June 10, 1983Date of Patent: June 4, 1985Inventors: Shmuel Dabi, Peter Loewrigkeit, Kenneth A. Van Dyk
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Patent number: 4510275Abstract: An aqueous coating composition comprising, as film-forming components, at least one water soluble resin and at least one water-insoluble finely pulverized resin, one of said water soluble resins having certain specified tolerance and surface tension properties. This coating composition is very stable, shows excellent working properties, such durability and exhibits other desirable properties, and is useful as a coating, especially in the automobile industry.Type: GrantFiled: July 9, 1982Date of Patent: April 9, 1985Assignee: Nippon Paint Co., Ltd.Inventors: Shinichi Ihikura, Kazunori Kanda, Toshiharu Nakaya
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Patent number: 4508128Abstract: The present invention relates to improved drag reduction agents which are polymer complexes of a cationic polymer and an anionic polymer.Type: GrantFiled: November 2, 1983Date of Patent: April 2, 1985Assignee: Exxon Research & Engineering Co.Inventors: Ralph M. Kowalik, Ilan Duvdevani, Dennis G. Peiffer, Robert D. Lundberg
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Patent number: 4495325Abstract: Coating compositions containing large amounts of polymer-bound ultraviolet radiation absorbing stabilizers and cross linkers give highly ultraviolet absorbent properties.Type: GrantFiled: February 25, 1983Date of Patent: January 22, 1985Assignee: E. I. Du Pont de Nemours and CompanyInventors: Michael DeBergalis, Robert P. O'Fee
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Patent number: 4476191Abstract: A method of preparing a thermoplastic, water-soluble, phenolic aldehyde resin and the composition are provided to enhance the flexibility and resistance to compression fatigue breakage of glass fibers to which the resin has been applied. The method involves two steps. In the first step, the phenolic compound and the aldehyde are reacted to less than 100 percent completion in an amount so that the aldehyde to phenolic compound ratio is in the range of about 0.6 to about 1.5 and at an acidic pH and for a period of time equivalent to about 3 hours to about 10 hours when the temperature is in the range of about 55.degree. F. (13.degree. C.) to about 90.degree. F. (32.degree. C.) to produce a resinous mixture. In the second stage the pH of the reaction is adjusted within the range above about 7.0 to about 7.Type: GrantFiled: September 29, 1982Date of Patent: October 9, 1984Assignee: PPG Industries, Inc.Inventor: Mikhail M. Girgis
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Patent number: 4463117Abstract: A heat-stable, polymer-forming composition of a polymerizable material, a transition metal compound, a polymer chain terminator, and, optionally, a preventive antioxidant is disclosed as well as particular uses of such composition.Type: GrantFiled: April 19, 1982Date of Patent: July 31, 1984Assignee: Technicon Instruments CorporationInventor: Michael J. Malin
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Patent number: 4461859Abstract: A method of preparing a thermoplastic, water-soluble, phenolic aldehyde resin and the composition are provided to enhance the flexibility and resistance to compression fatigue breakage of glass fibers to which the resin has been applied. The method involves two steps. In the first step, the phenolic compound and the aldehyde are reacted to less than 100 percent completion in an amount so that the aldehyde to phenolic compound ratio is in the range of about 0.6 to about 1.5 and at an acidic pH and for a period of time equivalent to about 3 hours to about 10 hours when the temperature is in the range of about 55.degree. F. (13.degree. C.) to about 90.degree. F. (32.degree. C.) to produce a resinous mixture. In the second stage the pH of the reaction is adjusted within the range above about 7.0 to about 7.Type: GrantFiled: September 29, 1982Date of Patent: July 24, 1984Assignee: PPG Industries, Inc.Inventor: Mikhail M. Girgis
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Patent number: 4450251Abstract: Aqueous thermosetting varnish compositions that are particularly water resistant after curing are disclosed. These compositions contain by weight (A) about 20-40 percent of a solution copolymer polymerized from monomers consisting essentially of (a) about 50-75 percent vinyl ester of a C.sub.1 -C.sub.3 carboxylic acid, (b) about 10-45 percent of C.sub.1 -C.sub.8 alkyl acrylate or methacrylate ester and (c) about 5-15 percent of a mixture of (i) at least about 0.5 percent monoethylenically unsaturated C.sub.3 -C.sub.5 carboxylic acid and (ii) at least about 2 percent C.sub.2 -C.sub.4 hydroxyalkyl acrylate or methacrylate. The copolymer is polymerized at a temperature of at least 110.degree. C. and at a non-volatile solids content of 60-80 percent.Type: GrantFiled: March 9, 1983Date of Patent: May 22, 1984Assignee: DeSoto, Inc.Inventors: Edwin A. Zychowski, Ronald L. Richards
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Patent number: 4443569Abstract: The invention relates to thermosetting, cathodically depositable, aqueous electrocoating compositions which are produced by reacting a nitrogen base-containing binder, which contains tertiary amino groups and primary and/or secondary OH groups, with metal compounds, which are sparingly soluble or insoluble in water, of cobalt, copper, lead, nickel and/or manganese at temperatures between 100.degree. C. and 150.degree. C. under an inert gas. The resultant products are subsequently protonated with an acid and diluted with water in a manner known per se to yield electrocoating paints having a solids content of from 5 to 25% and pH values of 5 to 8. Octoates, naphthenates, borates, and also acetyl acetonates are preferred to be used as the metal compounds which are sparingly soluble or insoluble in water.Type: GrantFiled: April 8, 1982Date of Patent: April 17, 1984Assignee: Lackwerke Wulfing GmbH & Co.Inventors: Manfred Schroder, Arty R. T. Subramanyam
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Patent number: 4442248Abstract: An aqueous coating composition comprising from 45 to 98 parts by weight (solids) of aqueous resin(s) and from 2 to 55 parts by weight (solids) of finely divided water-insoluble resin(s), in which at least a part of said aqueous resin is selected from amphoteric resins having both carboxyl and amino groups. The resins may have mutually reactive functional groups.Type: GrantFiled: September 3, 1982Date of Patent: April 10, 1984Assignee: Nippon Paint Co., Ltd.Inventors: Kazunori Kanda, Shinichi Ishikura
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Patent number: 4442247Abstract: An aqueous coating composition comprising from 45 to 98 parts by weight (solids) of aqueous resin(s) and from 2 to 55 parts by weight (solids) of finely divided water-insoluble resin(s), in which at least a part of said aqueous resin is selected from special type of cationic resins. The resins may have mutually reactive functional groups.Type: GrantFiled: August 25, 1982Date of Patent: April 10, 1984Assignee: Nippon Paint Company, Ltd.Inventors: Shinichi Ishikura, Kazunori Kanda, Shohachiro Yamaguchi
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Patent number: 4439556Abstract: An aqueous coating composition for filamentary materials that are to be used in reinforcing elastomeric matrix materials is provided that renders reinforced elastomeric materials having improved properties of flexibility and fatigue resistance. The aqueous adhesive coating composition has a vinyl-pyridine-containing copolymer or terpolymer latex, a phenolic aldehyde condensate polymer, and a non-self-crosslinkable elastomeric latex with a low gel content of less than around 40 weight percent and a low average particle size of less than around 2000 angstroms. The vinyl pyridine-containing elastomeric latex is produced from a vinyl pyridine-containing monomer, 1,3-diene hydrocarbon monomer or the terpolymer is produced in the same way with the addition of a vinyl containing monomer. In addition the aqueous adhesive coating composition may contain a wax emulsion, antioxidant, and carboxylated styrene butadiene copolymer latex.Type: GrantFiled: September 29, 1982Date of Patent: March 27, 1984Assignee: PPG Industries, Inc.Inventor: Mikhail M. Girgis
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Patent number: 4436866Abstract: An aqueous coating composition is provided for filamentary materials that yields coated filamentary material with improved weavability and that yields reinforced elastomeric materials having improved properties of flexibility and fatigue resistance. The aqueous adhesive coating composition has a vinyl-pyridine-containing copolymer or terpolymer latex, a non-selfcrosslinkable elastomeric latex, a carboxylated butadiene polymer, and a phenolic aldehyde condensate polymer. The vinyl pyridine-containing elastomeric latex is produced from a vinyl pyridine-containing monomer, 1,3-diene hydrocarbon monomer or the terpolymer is produced in the same way with the addition of a vinyl containing monomer. The non-selfcrosslinkable elastomeric latex has a low gel content of less than around 40 weight percent and a low average particle size of less than around 2000 angstroms.Type: GrantFiled: November 25, 1981Date of Patent: March 13, 1984Assignee: PPG Industries, Inc.Inventor: Mikhail M. Girgis
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Patent number: 4409055Abstract: An aramid reinforcing element or cord is dipped in an aqueous adhesive composition of a phenolic-aldehyde resin and a vinyl pyridine latex and dried. The treatment is repeated again and preferably for three times. The repeatedly treated cord is then cured with a rubber compound to give improved H-adhesion values. If desired, a primer treatment with an epoxide may proceed the aqueous adhesive composition treatments.Type: GrantFiled: January 12, 1983Date of Patent: October 11, 1983Assignee: The General Tire & Rubber CompanyInventor: Otto C. Elmer
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Patent number: 4405744Abstract: A filler for paper, card or board which has a good retention and consists of an inert core material and a hydrophilic coating, which consists of polyacrylamide having a molecular weight of 10.sup.5 to 10.sup.7 or of a mixture of this polyacrylamide with a urea-formaldehyde condensation resin. The filler is prepared by suspending the inert core material in an aqueous solution of a polyacrylamide having a molecular weight of 10.sup.5 to 10.sup.7 or in an aqueous solution of such a polyacrylamide and a urea-formaldehyde condensation resin, and drying this suspension by spray drying or in a stream of hot air. This crosslinks the initially water-soluble polymer and forms a coating, adhering to the core, which is insoluble in water but is hydrophilic and swells, and becomes tacky, in the presence of water.Type: GrantFiled: May 20, 1981Date of Patent: September 20, 1983Assignee: Chemie Linz AktiengesellschaftInventors: Herbert Greinecker, Gerhard Stern
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Patent number: 4405746Abstract: An aqueous coating composition for filamentary materials that are to be used in reinforcing elastomeric matrix materials is provided that renders reinforced elastomeric materials having improved properties of flexibility and fatigue resistance. The aqueous adhesive coating composition has a vinyl-pyridine-containing copolymer or terpolymer latex, a phenolic aldehyde condensate polymer, and a non-self-crosslinkable elastomeric latex with a low gel content of less than around 40 weight percent and a low average particle size of less than around 2000 angstroms. The vinyl pyridine-containing elastomeric latex is produced from a vinyl pyridine-containing monomer, 1,3 diene hydrocarbon monomer or the terpolymer is produced in the same way with the addition of a vinyl containing monomer. In addition the aqueous adhesive coating composition may contain a wax emulsion, antioxidant, and carboxylated styrene butadiene copolymer latex.Type: GrantFiled: February 27, 1981Date of Patent: September 20, 1983Assignee: PPG Industries, Inc.Inventor: Mikhail M. Girgis
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Patent number: 4400229Abstract: Aqueous dispersions of a phenolic resole and a thermoplastics polymeric material or a rubber, suitable for use as adhesives, are prepared by(a) dissolving a solid thermoplastics polymeric material, such as a polyvinyl acetal or a nylon polyamide, or rubber in a phenol,(b) adding a nonionic or anionic surface active agent and/or protective colloid,(c) adjusting the mixture to a pH above 7 by addition of a base,(d) adding aqueous formaldehyde solution, or a formaldehyde donor, to a molar ratio of phenol to formaldehyde within the range 1:1 to 1:3,(e) if necessary, adding water, and(f) heating the mixture to form a phenolic resole.Type: GrantFiled: December 2, 1981Date of Patent: August 23, 1983Assignee: Ciba-Geigy CorporationInventors: Christopher G. Demmer, Roger Francombe, Edward W. Garnish, Derek J. R. Massy
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Patent number: 4390658Abstract: A crosslinkable coating composition is described which is miscible in all proportions with water and consists of crosslinked water-insoluble polymer microparticles sterically stabilised in dispersion in a liquid blend of a water-soluble crosslinking agent and a water-soluble, non-volatile substance of molecular weight less than 1000 which can take part in the crosslinking reaction but does not dissolve or swell the polymer, the amounts of the crosslinking agent and of the water-soluble non-volatile substance being up to 30% and 40% respectively of the total weight of film-forming material.Type: GrantFiled: October 22, 1980Date of Patent: June 28, 1983Assignees: Imperial Chemical Industries Limited, Dulux Australia LimitedInventors: Clive W. Graetz, Morice W. Thompson, Charles Bromley
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Patent number: 4376175Abstract: A composition capable of cleaning and protecting the surface of a substrate and of rendering it shiny, without subsequent polishing, comprising an aqueous system containing, in specified concentrations, a solid film forming high molecular weight acrylic polymer, a non-film forming resinous material, a plasticizing agent, a fluorocarbon surfactant and a blend of ether alcohol component and isopropanol in a pre-determined concentration range, the latter blend and the concentration of alcohol therein being primarily responsible for providing the substantially improved cleaning ability of the instant compositions.Type: GrantFiled: June 4, 1980Date of Patent: March 8, 1983Assignee: Airwick Industries, Inc.Inventor: Robert J. Posten
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Patent number: 4374216Abstract: This invention provides a non-gelling water-in-oil high solids slurry dispersion of water-soluble polymer.The slurry dispersion composition contains between about 40-80 weight percent of water-soluble polymer, and is prepared by dehydrating a water-in-oil dispersion of synthetic water-soluble polymer, and then slurrying a quantity of finely divided water-soluble polymer into the dehydrated dispersion.Type: GrantFiled: December 9, 1981Date of Patent: February 15, 1983Assignee: Celanese CorporationInventor: Laurence G. Dammann