Abstract: An aqueous alkaline dispersion of a rubbery graft or over polymerized copolymer of a diene and a vinyl pyridine on a polyacrylate seed (core or substrate), said acrylate polymer having a Tg of not above about -20.degree. C., desirably also containing a polybutadiene, and a water soluble, heat reactable phenolic resin, in certain amounts is useful in forming an adhesive for bonding glass fiber reinforcing elements or cords to rubber compounds or stocks. After dipping the glass fiber cord in the one-step adhesive dip, the coated cord is heated to dry it and heat cure or heat set the adhesive on the cord. Thereafter, the adhesive containing glass fiber cord is combined or laminated (calendered) with a curable rubber compound and the resulting assembly is cured to form a composite in which the glass fiber cord is bonded to the rubber by means of said adhesive.
Abstract: An improved aqueous composition for impregnating multifilament glass strand comprises emulsified polybutadiene homopolymer, butadiene-styrene-vinylpyridine terpolymer, resorcinol-formaldehyde resin, emulsified wax, a thickening agent and a defoaming agent with the homopolymer and the terpolymer emulsified with a synthetic anionic surfactant having sulfate, sulfonate or sulfosuccinate groups.
Abstract: Cationic solution addition copolymers of monoethylenically unsaturated copolymerizable monomers are described having Mannich base side chains with the structure: ##STR1## where R and R' are selected from C.sub.1 -C.sub.8 alkyl and C.sub.1 -C.sub.8 alkanol, or are together constituted by a C.sub.2 -C.sub.8 alkylene group. This copolymer is preferably reacted with a diepoxide in a stoichiometric deficiency with respect to the amine groups in the side chains. At least a portion of the tertiary amine groups are then reacted with a solubilizing acid to form a salt which enables the copolymer to be dissolved in water.
Type:
Grant
Filed:
May 18, 1981
Date of Patent:
July 27, 1982
Assignee:
De Soto, Inc.
Inventors:
Kazys Sekmakas, Raj Shah, Aurelio J. Parenti
Abstract: A composition containing a methylene donor, hydrophobic component containing an organic hydrophobic diluent and an isocyanate; and an aqueous component containing a water compatible aldehyde condensate and use thereof as an impregnant or bonding agent for cellulosic materials including paper, wood and cotton, and/or fibrous materials including synthetic fibers, such as rayon and nylon.
Type:
Grant
Filed:
September 16, 1980
Date of Patent:
July 27, 1982
Assignee:
Ashland Oil, Inc.
Inventors:
Jeffrey E. Martin, Albert F. Vozella, Golden F. Watts, Edwin R. Luckman
Abstract: Acrylic latex sealants are rendered water-resistant and have improved wet adhesion to a variety of substrates by incorporating hydrophobic resins and an aminosilane hydrolyzate therein.
Abstract: An aqueous binder dispersion for use in the production of composite bodies by vulcanizing a vulcanizable rubber composition on a substrate which is stable under vulcanization conditions comprising water and at least one emulsifier and a solids content of from 20% to 50% by weight of a solids composition of,(a) per 1000 parts by weight of a polymer selected from the group consisting of polyvinylidene chloride, vinylidene chloride/alkyl acrylate copolymers, butadiene/acrylonitrile copolymers and mixtures thereof,(b) from 100 to 500 parts by weight of at least one aromatic poly-C-nitroso compound,(c) from 50 to 300 parts by weight of masked polyfunctional isocyanates,(d) from 20 to 100 parts by weight of a water-soluble polymer selected from the group consisting of polyvinyl pyrrolidone and water-soluble copolymers of vinyl pyrrolidone, and(e) from 5 to 500 parts by weight of customary fillers and pigments, adhesion-improving resins based on formaldehyde condensation products, adhesion-improving condensation pro
Type:
Grant
Filed:
June 3, 1980
Date of Patent:
June 22, 1982
Assignee:
Henkel Kommanditgesellschaft auf Aktien (Henkel GaA)
Inventors:
Hans-Peter Kohlstadt, Riza N. zelli, Gerhard Gierenz
Abstract: Room temperature curable latices can be produced by copolymerizing ketimine derivative ethylenically unsaturated monomers with conventional ethylenically unsaturated monomers in an emulsion process at a controlled pH greater than about 7.2 to produce a coagulum-free latex containing blocked amine (--NH.sub.2) groups. In use, the pH of the latex can be adjusted to acidic below 7 to generate unblocked reactive amino groups which can be cured or cross-linked at about room temperature with water-dispersed polymers such as epoxy, double bond or isothiocyanate containing polymers.