Conjugated Diene Hydrocarbon Monomer Patents (Class 524/571)
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Publication number: 20110297751Abstract: A thermoset composite material that my used in the fabrication of structural components including railroad ties comprise a substantially homogeneous blend of an amount of vulcanized rubber particles including a predetermined ratio of different particles sizes, and a thermoset elastomeric binding agent added to the vulcanized rubber particles. The blend may comprise about 30% to about 97% by weight of the vulcanized rubber particles, and the blend is subjected to compression molding at a predetermined temperature and pressure for a resident time period forming the composite material.Type: ApplicationFiled: June 2, 2011Publication date: December 8, 2011Inventors: Anthony M. Cialone, Peter Waznys, Michael Grubb
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Patent number: 8071682Abstract: A method for producing a conjugated diene polymer is provided that includes a step of polymerizing a conjugated diene-containing monomer in a hydrocarbon solvent in the presence of an alkali metal catalyst, thus giving a polymer having a catalyst-derived alkali metal at one terminus of a polymer chain comprising a conjugated diene-based monomer unit, and a step of reacting the polymer obtained in the step of polymerizing and a trialkoxysilane compound represented by the formula below. (In the formula, M denotes an oxygen atom or a sulfur atom, R1, R2, and R3 independently denote an alkyl group having 1 to 4 carbon atoms, m denotes an integer of 1 to 5, and n denotes an integer of 0 to 5.Type: GrantFiled: June 17, 2008Date of Patent: December 6, 2011Assignee: Sumitomo Chemical Company, LimitedInventors: Naoaki Maeda, Mayumi Oshima, Katsunari Inagaki
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Publication number: 20110288193Abstract: The present invention relates to a novel process for the production of polybutadiene-containing mouldings.Type: ApplicationFiled: October 23, 2009Publication date: November 24, 2011Applicant: LANXESS DEUTSCHLAND GMBHInventors: Heike Kloppenburg, Alex Lucassen, David Hardy, Jochen Kroll, Alexander Lissy, Dino Tebling
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Publication number: 20110287205Abstract: Mercaptosilanes are disclosed of the formula I wherein R1 is an alkyl polyether group —O—(R5—O)m—R6. They are prepared by a procedure in which a silane of the formula II is subjected to a catatyzed reaction with an alkyl polyether R1—H, R7—OH being split off, the molar ratio of the alkyl polyethers R1—H to the silane of the formula II is at least 0.5 and R7—OH is separated off from the reaction mixture continuously or discontinuously. They can be used in shaped articles.Type: ApplicationFiled: August 2, 2011Publication date: November 24, 2011Inventors: Oliver Klockmann, Philipp Albert, Andre Hasse, Karsten Korth, Relmund Pieter
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Patent number: 8053501Abstract: A curable composition comprising: (A) a hydrocarbon compound having a plurality of carbon-carbon double bonds, and (B) a carbonaceous material. The hydrocarbon compound may preferably be 1,2-polybutadiene. The curable composition may be used for a fuel cell separator.Type: GrantFiled: September 9, 2010Date of Patent: November 8, 2011Assignee: Showa Denko K.K.Inventors: Etsuko Kadowaki, Tadashi Iino, Hiroshi Uchida, Terutoshi Kumaki, Kentaro Seki
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Patent number: 8053512Abstract: A backbone modified polymer comprising the reaction product of an elastomeric polymer and a sulfide modifier represented by Formula 1: AS—Y-Zm (Formula 1), and wherein Y is (C12-C100) aralkyl, (C12-C100) aryl, (C12-C100) alkyl, or (C12-C100) dialkylether (alkyl-O-alkyl), and wherein each may be optionally substituted with (C1-C4alkyl, (C1-C4alkoxy, (C7-C16aryl, (C7-C16 aralkyl, nitrile, amine, NO2, alkoxy, or thioalkyl; S is sulfur; A is hydrogen, —(S)p—R1 or -MR2R3R4; Z is —SH, —S-MR5R6R7, —S—(S)p—R8, —NR9R10, —NR11COR12, —O—CO—R13, —NCO, or —COOR14; M is silicon or tin; N is nitrogen; O is oxygen; m is the number one, two or three; p is the number one, two, three, four or five; R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13 and R14 are the same or different, and are each, independently, selected from hydrogen (H), (C1-C16) alkyl, (C6-C16) aryl, (C7-C16) aralkyl or (C3-C30) tri(hydrocarbyl)silyl, and wherein the hydrocarbyl groups are each independently selected from (C1-C16) alkyl, (C6-C16) aryl, orType: GrantFiled: December 14, 2007Date of Patent: November 8, 2011Assignee: Styron Europe GmbHInventors: Sven K. H. Thiele, Joachim Kiesekamp
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Patent number: 8053510Abstract: The present invention is directed to a pneumatic tire having a wire-reinforced component comprising (A) a metallic wire; and (B) a rubber composition contacting the wire, the rubber composition comprising (1) a diene based elastomer; and (2) from 2 to 20 phr of at least one carboxylic acid selected from the group consisting of salicylic acid and dithiodipropionic acid.Type: GrantFiled: September 3, 2009Date of Patent: November 8, 2011Assignee: The Goodyear Tire & Rubber CompanyInventors: Erik Paul Sandstrom, Paul Harry Sandstrom
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Publication number: 20110269899Abstract: Provided by using a catalyst containing an yttrium compound is conjugated diene polymer with very low solution viscosity, improved workability, high degree of branching, and high content of cis-1,4 structures. Also provided is a rubber composition utilizing the polymer and allowing excellent dispersion of reinforcing agent. According to a method of manufacturing a conjugated diene polymer characterized by polymerizing a conjugated diene at 50 to 120° C. in the presence of a catalyst obtained from (A) an yttrium compound, (B) an ionic compound consisting of a non-coordinating anion and a cation, and (C) an organoaluminum compound, the conjugated diene polymer has the following characteristics that: (1) a ratio (Tcp/ML1+4) between a 5 wt % toluene solution viscosity (Tcp) measured at 25° C. and a Mooney viscosity (ML1+4) at 100° C. is 0.1 to 1.2; and (2) a content of cis-1,4 structures is 80% or higher, and a content of 1,2 structures is lower than 5%.Type: ApplicationFiled: December 4, 2009Publication date: November 3, 2011Applicant: UBE INDUSTRIES, LTD.Inventors: Masato Murakami, Koji Shiba, Takeshi Shoda, Mitsuharu Anbe
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Patent number: 8048951Abstract: A rubber latex composition is disclosed having reduced allergenicity. Methods for producing a rubber latex composition having reduced allergenicity are also disclosed.Type: GrantFiled: January 20, 2009Date of Patent: November 1, 2011Assignee: Vystar CorporationInventors: William Doyle, Matthew Clark, Travis Honeycutt
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Publication number: 20110259498Abstract: Radial tire for motor vehicle, comprising: a crown comprising a tread provided with at least one radially outer part intended to come into contact with the road; two beads, two sidewalls connecting the beads to the tread, a carcass reinforcement passing into the two sidewalls and anchored in the beads; the crown being reinforced by a crown reinforcement or belt placed circumferentially between the carcass reinforcement and the tread; a radially inner elastomer layer known as a “sublayer”, having a formulation different from the formulation of the radially outer elastomer layer, this sublayer being placed between the radially outer layer of the tread and the belt, wherein said sublayer comprises at least one diene elastomer and, as a high-density filler, more than 50 phr of particles having a density of greater than 4 g/cm3. This sublayer of specific formulation has the ability to reduce the rolling noise emitted by the tire without compromising its usage properties.Type: ApplicationFiled: December 10, 2009Publication date: October 27, 2011Applicants: Michelin Recherche et Technique S.A., Societe De Technologie MichelinInventors: Salvatore Pagano, Mitsue Tanaka
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Patent number: 8044147Abstract: A nitrile group-containing copolymer rubber comprising 10 to 40 wt % of ?,?-ethylenically unsaturated nitrile unit (a), 10 to 60 wt % of ?,?-ethylenically unsaturated carboxylic acid ester unit (b), and 20 to 70 wt % in total of conjugated diene unit (c) and saturated conjugated diene unit (d), wherein a content ratio “x” of a conjugated diene unit (c) based on the total content of said conjugated diene unit (c) and said saturated conjugated diene unit (d) is 0.08 or smaller, and “x·A” defined as a product of said ratio “x” and a content ratio “A” (%) of said ?,?-ethylenically unsaturated nitrile unit (a) is 1.5 or smaller. According to the present invention, a nitrile group-containing copolymer rubber capable to provide a rubber vulcanizate highly balanced in mechanical strength, heat aging resistance, oil resistance, cold resistance and ozone resistance, and a vulcanizable rubber composition using the rubber can be provided.Type: GrantFiled: February 22, 2006Date of Patent: October 25, 2011Assignee: Zeon CorporationInventors: Hiroyasu Nagamori, Akira Tsukada, Takafumi Kawanaka
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Patent number: 8044138Abstract: A carboxylic acid-modified nitrile copolymer latex is provided. The copolymer latex comprises a carboxylic acid-modified nitrile copolymer of an unsaturated monomer having at least one crosslinkable functional group selected from vinyl and epoxy groups. The use of the copolymer latex enables the production of a molded article that does not undergo long stirring and maturation, causes no allergic reactions due to the absence of sulfur and a vulcanization accelerator, has good oil resistance and high mechanical strength, and produces a soft feeling. Further provided is a latex composition for dip forming comprising the copolymer latex, and an article produced from the latex composition by dip forming.Type: GrantFiled: December 9, 2009Date of Patent: October 25, 2011Assignee: LG Chem, Ltd.Inventors: Jung Su Han, Byoung Yun Kim, Ho Yeul Choi, Chang Sun Han, Seung Hun Yang, Jung Eun Kim
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Patent number: 8044131Abstract: There is provided a rubber composition for a tread having excellent hardness and improving the processability and grip performance of a tire, and a tire comprising thereof. A rubber composition for a tread comprising 30 to 80 parts by weight of silica having a BET specific surface area of less than 150 m2/g and 10 parts by weight or less of carbon black based on 100 parts by weight of a rubber component comprising an epoxidized natural rubber, and a tire comprising thereof.Type: GrantFiled: January 5, 2006Date of Patent: October 25, 2011Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Tomoaki Hirayama, Takao Wada, Mamoru Uchida
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Publication number: 20110257331Abstract: The invention relates to rubber compositions containing a treated silica, particularly sulfur cured rubber compositions, and articles of manufacture having a component thereof such as, for example tires. The invention particularly relates to synthetic amorphous silica, particularly a precipitated silica, treated with a combination of allylsilane and dialkylsilane.Type: ApplicationFiled: April 19, 2010Publication date: October 20, 2011Inventors: Bruce Raymond Hahn, Byoung Jo Lee
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Patent number: 8034868Abstract: A rubber composition obtained by compounding thereinto a rubber component containing 0.5 to 100% by weight of a modified conjugated diene-based polymer having a fullerene bonded thereto in the molecule and having a weight average molecular weight of 50,000 or more excellent processability, superior balance of modulus and heat buildup, excellent cold flowability and superior tan ? balance.Type: GrantFiled: March 18, 2009Date of Patent: October 11, 2011Assignee: The Yokohama Rubber Co., Ltd.Inventors: Makoto Ashiura, Tetsuji Kawazura, Fumito Yatsuyanagi
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Publication number: 20110244384Abstract: The invention relates to carbon black granulates having an APC value, measured at a conveying speed of 8 m/s and a solid load of 27 g/kg, less than or equal to 20 and a 25 [mu]m pressure filter value of less than 5 bar cm2/g. The carbon black granulate is produced by carbon black powder being pre-granulated in a first mixing granulator with addition of a granulation liquid with or without binders and being granulated to a finished state in a second mixing granulator without further addition of granulation liquid. The carbon black granulate can be used as a filler, reinforcing filler, UV stabilizer, conductive carbon black, pigment, or reducing agent.Type: ApplicationFiled: November 10, 2009Publication date: October 6, 2011Applicant: Evonik Carbon Black GmbHInventors: Manfred Bertzick, Werner Heister, Wilfried Ostendorf, Matthias Katzer
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Publication number: 20110245398Abstract: A method for producing a conjugated diene polymer composition is provided that comprises the step of kneading a conjugated diene polymer, silica and a silane coupling agent using a kneading machine in the presence of 1 to 50 parts by weight of water and/or carbon dioxide relative to 100 parts by weight of the conjugated diene polymer.Type: ApplicationFiled: March 22, 2011Publication date: October 6, 2011Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Hisakatsu HAMA, Mana ITO
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Patent number: 8030397Abstract: This invention discloses a process for manufacturing an elastomeric article by liquid injection molding, said process comprising the steps of: (I) heating a curable composition comprised of (1) a liquid polymer comprised of repeat units that are derived from a conjugated diolefin monomer, wherein said liquid polymer has a weight average molecular weight which is within the range of 5,000 to 100,000, and wherein the liquid polymer is functionalized with an amine moiety, (2) a carbonyl inhibited platinum catalyst, and (3) a tetrakis(dialkyl siloxy) silane crosslinking agent, to a temperature which is within the range of 30° C. to 100° C.; (II) injecting the heated curable composition into a mold at a temperature which is within the range of 100° C. to 210° C. to produce the elastomeric article; and (III) removing the elastomeric article from the mold.Type: GrantFiled: November 2, 2008Date of Patent: October 4, 2011Assignee: The Goodyear Tire & Rubber CompanyInventors: Michael Joseph Rachita, Vanessa Marika Guscoff, Lawson Gibson Wideman
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Patent number: 8030392Abstract: A rubber composition for sidewall contains 10 to 40 mass % syndiotactic-1,2-polybutadiene-containing polybutadiene rubber and 10 to 30 mass % tin-modified polybytadiene rubber in a polymer component, and contains 10 to 40 parts by mass silica with respect to 100 parts by mass polymer component. Thus, cut resistance and ozone resistance as well as fuel efficiency of a car can be improved.Type: GrantFiled: September 17, 2009Date of Patent: October 4, 2011Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Hirokazu Ishida
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Publication number: 20110236816Abstract: The invention relates to carbon black having a C-14 content greater than 0.05 Bq/g and a ratio ?D50/Dmode of the aggregate size distribution of less than 0.7. The carbon black is produced by thermal oxidative pyrolysis or thermal cleavage of the carbon black raw material in that the carbon black raw material contains renewable carbon black raw materials and an oxygen deficiency is present in the pyrolysis/cleavage reaction. The carbon blacks can be used in rubber and rubber mixtures, plastic, printing inks, inks, inkjet inks, toners, lacquers, paints, paper, adhesives, batteries, pastes, bitumens, concrete, and other building materials and as reducing agents in metallurgy.Type: ApplicationFiled: October 9, 2009Publication date: September 29, 2011Applicant: Evonik Carbon Black GmbHInventors: Michael Stanyschöfsky, Gernot Meinerzhagen, Paul Messer, Joachim Fröhlich
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Patent number: 8022136Abstract: By using a vulcanized rubber composition containing a rubber component composed of at least any one of a natural rubber, a modified natural rubber and a synthetic rubber, and chemically modified microfibril cellulose, it is possible to provide a vulcanized rubber composition that is environmentally conscious and that exhibits excellent rupture characteristics and a low energy loss, and a pneumatic tire that is excellent in rolling resistance property, steering stability and durability.Type: GrantFiled: September 4, 2008Date of Patent: September 20, 2011Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Hiroyuki Yano, Yukio Isobe, Naoya Ichikawa, Takayuki Hattori
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Publication number: 20110224364Abstract: The present invention relates to a rubber composition containing carbon black for blending with rubber which is obtained in a reaction equipment comprising a combustion gas-generating zone, a reaction zone and a reaction-stopping zone by producing a high temperature combustion gas in the combustion gas-generating zone, subsequently spraying and introducing a raw material into the reaction zone to form a reaction gas stream containing carbon black and then quenching the above reaction gas stream by a multistage quenching medium-introducing means to terminate the reaction, wherein (1) the above carbon black for blending with rubber satisfies the following relational equations (1) and (2): 10<X<40 ??(1) 90<Z<100 ??(2) (wherein X represents a toluene extract light transmittance (%) of the carbon black after introducing a first quenching medium from a raw material-introducing position, and Z represents a toluene extract light transmittance (%) of the carbon black after introducing a final quenchiType: ApplicationFiled: September 30, 2009Publication date: September 15, 2011Applicant: BRIDGESTONE CORPORATIONInventor: Yasushi Yamagishi
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Patent number: 8017533Abstract: A steel plate reinforcing sheet includes a restricting layer and a reinforcing layer, the reinforcing layer being formed of foam composition including styrene synthetic rubber, aromatic epoxy resin, and a foaming agent. A total thickness of the restricting layer and reinforcing layer is not more than 3.5 mm, and the steel plate reinforcing sheet is formed to have adhesion at 5° C. to an oiled, cold-rolled steel plate of not less than 2.0N/25 mm and also has bending strength of not less than 18N after being heated at 160° C. for twenty minutes. This ensures both sufficient adhesion to the steel plate and sufficient reinforcement of the same steel plate. Thus, this steel plate reinforcing plate, when adhesively bonded to a steel plate used in a variety of industrial machines properly and then foamed, can provide an effective reinforcement of the steel plate by forming the steel reinforcing plate bonded to the steel plate.Type: GrantFiled: July 1, 2004Date of Patent: September 13, 2011Assignee: Nitto Denko CorporationInventors: Atsushi Kuriu, Takio Itou, Hiroichi Ukei, Manabu Matsunaga
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Publication number: 20110213074Abstract: Described are diol-derived organofunctional silanes in which the silanes contain cyclic and bridged alkoxy groups derived from hydrocarbon-based diols and methods for the preparation of the silanes. Also described are rubber compositions containing the diol-derived organofunctional silanes, methods for the preparation of the rubber compositions and articles of manufacture containing the rubber compositions, in particular, automotive tires and components thereof.Type: ApplicationFiled: May 11, 2011Publication date: September 1, 2011Applicant: Momentive Performance Materials Inc.Inventors: Antonio Chaves, Richard W. Cruse, Eric R. Pohl
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Publication number: 20110203596Abstract: The invention disclosed herein relates to an improved process for making elastomeric polyisoprene articles. In particular, the process of the invention is a system which produces synthetic polyisoprene articles exhibiting tensile strength properties similar to that of solvent-based processes using natural rubber latex. The process comprises an accelerator composition at the pre-cure stage comprising a dithiocarbamate, a thiazole and a guanidine compound. In a preferred embodiment, the accelerator composition comprises zinc diethyldithiocarbamate (ZDEC), zinc 2-mercaptobenzothiazole (ZMBT) and diphenyl guanidine (DPG), in conjunction with a stabilizer, such as sodium caseinate. The invention also includes an elastomeric polyisoprene product made by the process, such as a surgeon's glove.Type: ApplicationFiled: September 22, 2010Publication date: August 25, 2011Applicant: ALLEGIANCE CORPORATIONInventors: Shiping Wang, Yun-Siung Tony Yeh, Randell Wenig, Wong Weicheong
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Publication number: 20110201750Abstract: This invention relates to a polymer composition comprising: 70 wt % to 99.5 wt % of a nitrile-group containing elastomer, wherein the elastomer has: a Mooney Viscosity of 15 to 115 MU; and a nitrile monomer content of 0.5 wt % to 50 wt %; and 0.5 wt % to 30 wt % of a non-functionalized plasticizer (NFP), wherein the NFP has: a kinematic viscosity at 100° C. of 4 to 1000 cSt, a flash point of ?200° C., a viscosity index of ?120, and a specific gravity of ?0.865; and wherein the composition has: a 25% compression set at 70 hours and ?30° C. that is at least 110% of the 25% compression set of same composition without the NFP tested at the same conditions, and a retained tensile strength, in MPa, after 168 hours at 175° C., that is at least about 88% of the retained tensile strength of the same composition that has not been aged.Type: ApplicationFiled: February 15, 2010Publication date: August 18, 2011Inventors: Bruce A. Harrington, David B. Dunaway, Chon-Yie Lin
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Patent number: 7994236Abstract: A method for preparing a polymer product, the method comprising polymerizing conjugated diene monomer, optionally together with vinyl aromatic monomer, within a hydrocarbon solvent by employing a lithium-containing initiator, thereby forming a living polymer cement, where about 0.04 to about 0.Type: GrantFiled: December 15, 2005Date of Patent: August 9, 2011Assignee: Firestone Polymers, LLCInventors: James H. Pawlow, William L. Hergenrother
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Publication number: 20110186328Abstract: Semi-conductive or insulating compositions including an ethylene/octane or butene copolymer and at least one additional polymer, such LDPE, are described. The compositions may also include carbon black and other additives.Type: ApplicationFiled: February 1, 2010Publication date: August 4, 2011Applicant: GENERAL CABLE TECHNOLOGIES CORP.Inventor: Mark R. EASTER
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Patent number: 7987880Abstract: The rubber composition for a tire base tread includes a rubber component containing not less than 15% by weight of a terminal-modified diene rubber having a number average molecular weight prior to modification of 150000 to 400000, a filler, and a compound (vulcanizing agent) represented by the following general formula (1) in an amount of 0.5 to 5 parts by weight based on 100 parts by weight of the rubber component: (wherein R represents a benzyl group, and n represents an integer of 3 to 12.Type: GrantFiled: November 19, 2008Date of Patent: August 2, 2011Assignee: Toyo Tire & Rubber Co., Ltd.Inventor: Norihiko Nakamura
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Patent number: 7989546Abstract: The Invention relates to a method for the preservation of natural rubber latex comprising the step of adding to natural latex at least one hydrophobically modified saccharide. The hydrophobically modified saccharide is preferably a hydrophobically modified fructan, a hydrophobically modified starch hydrolysate, or a mixture thereof. The invention further relates to a natural rubber latex containing a hydrophobically modified saccharide, and to vulcanized natural rubber products containing a hydrophobically modified saccharide.Type: GrantFiled: March 4, 2008Date of Patent: August 2, 2011Assignee: Beneo-Orafti S.A.Inventors: Karl Booten, Amir Hashim Bin Yatim, Manroshan Singh
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Publication number: 20110180195Abstract: Alkoxy-modified silsesquioxane compounds are described. The alkoxy-modified silsesquioxane compounds contain an alkoxysilane group that participates in an alkoxysilane-silica reaction as a silica dispersing agent in rubber, with the release of zero to about 0.1% by weight of the rubber of volatile organic compounds (VOC), especially alcohol, during compounding and further processing. Further described are methods for making alkoxy-modified silsesquioxanes, methods for making vulcanizable rubber compounds containing alkoxy-modified silsesquioxanes, vulcanizable rubber compounds containing alkoxy-modified silsesquioxanes, and pneumatic tires comprising a component that contains alkoxy-modified silsesquioxanes.Type: ApplicationFiled: September 16, 2010Publication date: July 28, 2011Applicant: Bridgestone CorporationInventors: William L. Hergenrother, Chenchy J. Lin, Terrence E. Hogan, Ashley S. Hilton
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Publication number: 20110184093Abstract: According to at least one aspect of the present invention, a rubber composition is provided. In at least one embodiment, the rubber composition comprises a rubber, an oil blend of a petroleum oil and a bio-based oil, the bio-based oil being non-hydroxyl-functionalized, hydroxyl-functionalized, or combinations thereof; and a filler. In certain instances, the bio-based oil includes a soy oil. In certain other instances, the soy oil is hydroxyl-functionalized having a hydroxyl number of from 10 to 350 KOH/g, 40 to 150 KOH/g, or 25 to 200 KOH/g. According to at least another aspect of the present invention, there is provided a method comprising providing a rubber composition as described herein and molding the rubber composition to form the rubber article.Type: ApplicationFiled: January 22, 2010Publication date: July 28, 2011Applicant: FORD GLOBAL TECHNOLOGIES, LLCInventors: Christine Perry, Cynthia Mowery Flanigan
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Publication number: 20110178233Abstract: The present invention relates to an elastomer mixture resulting from the modification of a diene elastomer by a coupling agent that introduces, into the elastomer chain, an alkoxysilane group bearing a tertiary or secondary amine functional group. This mixture predominantly comprises the diene elastomer coupled by the alkoxysilane group bearing a tertiary or secondary amine functional group which is bonded to the diene elastomer through the silicon atom. The invention also relates to a reinforced rubber composition, in particular that can be used for the manufacture of tyres, which comprises a reinforcing filler and an elastomer matrix comprising at least this elastomer mixture, and to its preparation process. This composition has improved hysteresis and mechanical properties in the vulcanized state, and also improved processing in the uncured state.Type: ApplicationFiled: April 27, 2009Publication date: July 21, 2011Applicants: Societe De Technologie Michelin, Michelin Recherche et Technique S.A.Inventors: Philippe Chaboche, Jean-Michel Favrot, Nicolas Seeboth, Fanny Barbotin, Stéphanie De Landtsheer
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Publication number: 20110178234Abstract: An aqueous elastomer dispersion includes a dispersed phase and an aqueous phase. The dispersed phase includes an elastomer including curable aliphatic conjugated-diene elastomers, such as polyisoprene, and a minor amount of at least one additive. The aqueous phase includes water and other optional components in either a soluble state or a dispersion state. The aqueous elastomer dispersion may be prepared by dissolving an elastomer, such as rubber, and additives in a solvent mixture and then converting the resulting solution into an aqueous emulsion. The aqueous emulsion is concentrated and the solvent is stripped from it to yield a dilute latex. The dilute latex that is obtained is concentrated again. Articles made from the aqueous elastomer dispersion include medical gloves, condoms, probe covers, dental dams, finger cots, catheters and the like.Type: ApplicationFiled: March 31, 2011Publication date: July 21, 2011Applicant: ALLEGIANCE CORPORATIONInventors: Shiping WANG, Seong F. Chen, Ida Berger, Yun-Siung T. Yeh, Wei C. Wong
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Patent number: 7976955Abstract: The rubber compositions described herein have been found to have an exceptionally long life as a spring-biased actuator diaphragm material that maintains its position compressed, e.g., bolted, between opposed flanges, while maintaining excellent compressibility, low temperature flexibility, hydrocarbon resistance, abrasion resistance and mechanical strength. The compositions include a copolymer rubber component; a plasticizer for the copolymer rubber; a vulcanizing agent for the copolymer rubber; a silica filler; and a coupling agent, such as a silane coupling agent, capable of coupling the silica filler to the copolymer rubber.Type: GrantFiled: October 29, 2007Date of Patent: July 12, 2011Assignee: Fisher Controls International LLCInventor: Ted Dennis Grabau
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Publication number: 20110160359Abstract: Compositions suitable for use as encapsulants are described. The inventive compositions include a high molecular weight polymeric material, a curing agent, an inorganic compound, and a coupling agent. Optional elements include adhesion promoting agents, colorants, antioxidants, and UV absorbers. The compositions have desirable diffusivity properties, making them suitable for use in devices in which a substantial blocking of moisture ingress is desired, such as photovoltaic (PV) modules.Type: ApplicationFiled: March 7, 2011Publication date: June 30, 2011Inventors: MICHAEL D. KEMPE, PREM THAPA
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Patent number: 7968630Abstract: The present invention is directed to a pneumatic tire having at least one component including a sulfur vulcanizable rubber composition, the rubber composition including at least one diene based rubber and at least one zinc porphyrin compound.Type: GrantFiled: September 8, 2005Date of Patent: June 28, 2011Assignee: The Goodyear Tire & Rubber CompanyInventors: Carlo Kanz, Uwe Ernst Frank
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Patent number: 7968631Abstract: The present invention is directed to a pneumatic tire having at least one component including a sulfur vulcanizable rubber composition, the rubber composition including at least one diene based rubber and at least one zinc naphthalocyanine compound.Type: GrantFiled: September 8, 2005Date of Patent: June 28, 2011Assignee: The Goodyear Tire & Rubber CompanyInventors: Carlo Kanz, Uwe Ernst Frank
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Patent number: 7964664Abstract: A gelatinous elastomer comprising an A-B-A triblock copolymer and a plasticizer useful, for example, in casting fine-detail molds at a low processing temperature. The gelatinous elastomer comprises copolymer molecules having a molecular weights generally evenly distributed across a range of molecular weights rather than having a relatively narrow molecular weight distribution centered about a single molecular weight. The A-B-A triblock copolymer may include SEBS, SEEPS, or other triblock copolymers. The plasticizer may include mineral oil or other plasticizing fluids.Type: GrantFiled: February 1, 2006Date of Patent: June 21, 2011Assignee: Edizone, LLCInventor: Tony M. Pearce
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Publication number: 20110124774Abstract: An organic polymer is transferred from one solvent to another. In a first step, a solution of the polymer in a first solvent is divided into droplets, dispersed into a liquid phase such as water bath, and the first solvent is re-moved from the droplets to produce a slurry in the liquid phase. Then, the second solvent is contacted with the slurry to dissolve the organic polymer and produce a second solution. The second solution is removed from the liquid phase. The process is especially suitable for transferring a butadiene polymer from a hydrocarbon solvent into a halogenated solvent for bromination.Type: ApplicationFiled: August 3, 2009Publication date: May 26, 2011Inventor: Douglas C. Greminger
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Patent number: 7943696Abstract: A vulcanized rubber composition comprising the vulcanization product of a functional polymer, where the functional polymer is defined by the formula where R is selected from C1 to C6 trialkyl-silyl groups, C1 to C20 alkyl groups, C4 to C20 cycloalkyl groups, C6 to C20 aryl groups, thienyl, furyl, and pyridyl groups; and R may optionally have attached thereto any of the following functional groups: C1 to C10 alkyl groups, C6 to C20 aryl groups, C2 to C10 alkenyl groups, C3 to C10 non-terminal alkynyl groups, ethers, tert-amines, oxazolines, thiazolines, phosphines, sulfides, silyls, and mixtures thereof; where R1 is selected from C2 to C8 alkylene groups, where X is NR, and where ? is a polymer chain.Type: GrantFiled: September 15, 2009Date of Patent: May 17, 2011Assignee: Bridgestone CorporationInventors: Terrence E. Hogan, William Hergenrother, Yuan-Yong Yan, David Lawson
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Rubber mixture comprising environmentally friendly softeners cross reference to related applications
Publication number: 20110112213Abstract: The invention relates to a rubber mixture, in particular for vehicle air-inflated tires, seat belts, belts and hoses. The rubber mixture is characterized by the following composition: at least one polar or non-polar rubber and at least one bright and/or dark filler and at least one softener, wherein the softener is free of polycyclic aromatics according to Directive 76/769/EEC, and wherein the carbon source for the softener comes from non-fossil sources, and other additives.Type: ApplicationFiled: January 13, 2011Publication date: May 12, 2011Inventors: Carla Recker, Thorsten Reese, Jens Schöning -
Patent number: 7935417Abstract: A melt-kneading method for filling material and elastomer or resin, characterized in that a filling material constituted by a filler, and an elastomer or resin (thermoplastic resin or thermosetting resin), are introduced from a material introduction part at the end of a melt-kneading part having a cylinder with a screw and a heater, and the molten elastomer or resin and filling material constituted by a filler are kneaded under the conditions of 1000 to 3000 rpm in the rotation speed of the screw and 1500 to 4500 sec?1 in shear speed to feed the mixture from the rear edge to tip of the screw to be trapped in a space provided at the tip of the screw, after which the mixture is moved from the space to the rear edge of the screw through a hole provided at the center of the screw, with the cycle process performed for a specified period based on recirculation using the screw.Type: GrantFiled: February 8, 2008Date of Patent: May 3, 2011Assignee: National Institute of Advanced Industrial Science and TechnologyInventors: Hiroshi Shimizu, Yongjin Li
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Publication number: 20110095238Abstract: The present invention relates to novel composites that incorporate carbon nanospheres into a polymeric material. The polymeric material can be any polymer or polymerizable material compatible with graphitic materials. The carbon nanospheres are hollow, graphitic nanoparticles. The carbon nanospheres can be manufactured from a carbon precursor using templating catalytic nanoparticles. The unique size, shape, and electrical properties of the carbon nanospheres impart beneficial properties to the composites incorporating these nanomaterials.Type: ApplicationFiled: January 6, 2011Publication date: April 28, 2011Applicant: HEADWATERS TECHNOLOGY INNOVATION, LLC.Inventors: Bing Zhou, Cheng Zhang, Martin Fransson, Raymond B. Balée
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Patent number: 7930782Abstract: A tear and fatigue resistant gels, gel composites, and gel articles including collapsible articles having two or more communicating internal volumes like cavities when depressed by external pressure or force is capable of collapsing unto itself in a controllable and directionally preselected manner by venting static air within said internal through openings in said gel article, said gel of said article having rigidity of from about 20 gram Bloom to about 1,800 gram Bloom suitable for cushioning, cushioning composites, cushioning gel liners, cushioning composite gel liners, and other uses of selected shape gels, gel composites, and articles.Type: GrantFiled: June 5, 2007Date of Patent: April 26, 2011Assignee: Applied Elastomerics, Inc.Inventor: John Y. Chen
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Patent number: 7928157Abstract: This invention relates to a tire with a tread of a rubber composition which contains zinc rosinate within and on the surface of said rubber composition. Said zinc rosinate promotes enhanced wet traction for said tire tread by actually replacing a more conventional zinc stearate for a tire tread rubber composition. Said zinc rosinate is a product of a combination of rosin acid and zinc oxide formed in situ within said rubber composition. Said more conventional zinc stearate is a product of a combination of stearic acid and zinc oxide formed in situ within a tread rubber composition.Type: GrantFiled: September 10, 2007Date of Patent: April 19, 2011Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul Harry Sandstrom, Joseph Kevin Hubbell, Thomas Charles Lippello, III
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Patent number: 7923505Abstract: High-viscosity elastomeric adhesive compositions including a high softening point tackifier resin in combination with a base polymer can be used to create elastomeric composite laminates having effective adhesion and elastic properties. The elastomeric adhesive compositions suitably have a viscosity between about 100,000 and about 500,000 cps at between about 300 degrees Fahrenheit (149 degrees Celsius) and about 350 degrees Fahrenheit (177 degrees Celsius). Facing layers, such as nonwoven webs, films, elastic strands, fastening material, absorbent material, and the like, can be laminated to one or both surfaces of the elastomeric compositions to form elastomeric composite laminates. A method of making such compositions and laminates involves forming the compositions into elastomeric adhesive films and/or strands.Type: GrantFiled: November 13, 2007Date of Patent: April 12, 2011Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Peiguang Zhou, Gregory K. Hall
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Patent number: 7919558Abstract: A rubber composition containing (i) a conjugated diene-based rubber gel having a toluene swelling index of 16 to 70, (ii) a diene-based rubber such as natural rubber, polyisoprene rubber, aromatic vinyl-conjugated diene copolymer rubber and/or polybutadiene rubber, and (iii) an optional carbon black and/or silica and (a) a pneumatic tire using this composition as a high hardness reinforcing layer extending from a bead along a tire sidewalls, in which the fluidity and dimensional stability at the time of extrusion are improved, while maintaining a sufficient hardness of a high hardness reinforced rubber, (b) a pneumatic tire using this composition as two ends of a tire tread extrudate, maintaining a flex fatigue of the two ends of the tread, in which the extrudability and extrusion dimensional stability are improved and (c) a pneumatic tire using the composition as a 1.Type: GrantFiled: February 22, 2005Date of Patent: April 5, 2011Assignees: The Yokohama Rubber Co., Ltd., Zeon CorporationInventors: Naoya Amino, Misao Hiza, Takashi Shirokawa, Masao Nakamura, Koichi Endo
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Patent number: 7915335Abstract: A rubber composition is provided that attains both low heat generating property and high reinforcement property simultaneously at high levels, is capable of attaining low fuel consumption through the tire, is excellent in durability, and is good in workability and surface property. The rubber composition contains 100 parts by weight of a diene rubber component, from 0.5 to 50 parts by weight of bagasse charcoal having a BET specific surface area of from 10 to 300 m2/g, and at least one of carbon black and silica. The total amount of the bagasse charcoal, the carbon black and the silica is preferably from 30 to 100 parts by weight per 100 parts by weight of the diene rubber component.Type: GrantFiled: September 2, 2008Date of Patent: March 29, 2011Assignee: Toyo Tire & Rubber Co., Ltd.Inventor: Shinya Yamamoto
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Publication number: 20110071253Abstract: The present invention provides: a rubber composition for a tire having favorable productivity, excellent heat aging resistance and abrasion resistance, and excellent fuel economy; and a pneumatic tire using the rubber composition. The rubber composition contains neither soluble sulfur nor insoluble sulfur, and contains diene rubber, 1-15 parts by mass of compound 1 represented by formula (1) and 0.1-5 parts by mass of compound 2 represented by formula (2), per 100 parts by mass of the diene rubber, and the amount ratio of compound 1 to compound 2 (compound 1/compound 2) is 1-8. wherein R1-R4 are the same or different, and represent C1-20 alkyl, C6-20 aryl, or C7-20 aralkyl, and n represents an integer of 1-12; wherein R5-R7 are the same or different, and represent C5-12 alkyl, x and y are the same or different, and represent an integer of 2-4, and m represents an integer of 0-10.Type: ApplicationFiled: September 23, 2010Publication date: March 24, 2011Inventor: Kazuo HOCHI