Conjugated Diene Hydrocarbon Monomer Patents (Class 524/571)
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Publication number: 20100108239Abstract: A tire composition with a Shore A hardness, according to DIN 53 505 and ASTM D2240, of not less than 40 and not greater than 95 and a glass-transition temperature Tg (E?max), according to DIN 53 513 with a specified temperature sweep of ?80° C. to +80° C. and a specified compression of 10+0.2% at 10 Hz, not less than ?80° C. and not greater than 0° C., with improved abrasion performance, in particular for pneumatic tires, has the following composition: at least one vulcanizable diene rubber selected from natural rubbers, synthetic polyisoprene rubbers, polyisobutylene rubbers, polybutadiene rubbers (BR), and random styrene-butadiene rubbers; from 35 to 300 phr of at least one active filler selected from carbon blacks, silicas, silicon based fillers, and metal oxides, of which at least 10 phr must be carbon blacks, silicas, or some combination thereof; from 0 to 250 phr of other or further additives; from 0.Type: ApplicationFiled: October 30, 2008Publication date: May 6, 2010Inventors: Carla Recker, William Michael York, Thomas Kramer, Katharina Herzog, Boris Mergell, Richard W. Cruse
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Patent number: 7709561Abstract: There is provided a rubber composition for a tread obtained by compounding (a) 5-40 parts by mass of a softening agent including an oil in which an extraction quantity with dimethylsulfoxide (DMSO) by IP346 process is controlled to less than 3% by mass and (b) 5-40 parts by mass of a liquid polymer having a viscosity average molecular weight of 45,000-100,000 based on 100 parts by mass of a rubber component, and considerably improving the fracture properties and wear resistance and controlling the lowering of the modulus of elasticity as compared with the case of compounding the conventional high aromatic oil.Type: GrantFiled: October 30, 2003Date of Patent: May 4, 2010Assignee: Bridgestone CorporationInventors: Masayuki Ohashi, Tadashi Shibata
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Publication number: 20100095837Abstract: An article with an abradable dry powder coating thereon comprises an abradably coated article with a substrate surface and having at least one coating of a liquid primer on the substrate surface and then coating with at least one abradable dry powder coating on the surface of the liquid primer. The sequence of layers may also be reversed, or additional layers may be useful. The abradable dry powder coating is formed of a dry powder coating composition including a thermoset resin having a cure temperature combined with at least one filler material, wherein the filler is formed of a material which does not melt substantially at or below the cure temperature of the resin, whereby an abradable coating results employing a filler to make the coating.Type: ApplicationFiled: October 30, 2007Publication date: April 22, 2010Inventor: Andrew W. Suman
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Publication number: 20100093921Abstract: The present invention generally relates to the use of EPDM (ethylene-propylene diene monomer) polymer compounds used in place of NR (natural rubber), SBR (styrene butadiene rubber), polyisoprene and other polymers in energy absorption elastomeric systems. In one embodiment a method of continuously manufacturing an EPDM based compound cured via a peroxide based cure system and used in an energy absorption elastomeric system is disclosed. The method includes the steps of forming a continuous part from a compound based on ethylene-propylene diene terpolymer and then curing the part via a continuous process and optionally cutting the final part to the appropriate length. Various advantages are achieved via the use of peroxide cured EPDM as replacements for NR, SBR, polyisoprene and other polymers.Type: ApplicationFiled: October 13, 2009Publication date: April 15, 2010Applicant: PRODUCTION SYSTEMS, INC.Inventors: Frederick E. Pedersen, Eldon S. Eady
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Patent number: 7696282Abstract: The present invention relates to a method for the hydrogenation of unsaturated polymers containing double bonds, the unsaturated polymers present in latex form being hydrogenated in the presence of a metal-containing colloid.Type: GrantFiled: January 7, 2005Date of Patent: April 13, 2010Assignee: LANXESS Deutschland GmbHInventors: Thomas Weiβ, Karin Creutz
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Patent number: 7691957Abstract: This invention is concerned with a butadiene-based polymer having a high cis-1,4 bond content, a low vinyl bond content and a molecular weight distribution of a specified range, and more particularly a butadiene-based polymer having a 1,3-butadiene monomer unit, characterized in that a cis-1,4 bond content and a vinyl bond content in the 1,3-butadiene monomer unit as measured by a Fourier transform infrared spectroscopy (FT-IR) is not less than 98.0% and not more than 0.3%, respectively, and a ratio (Mw/Mn) of weight average molecular weight (Mw) to number average molecular weight (Mn) is 1.6-3.5.Type: GrantFiled: June 23, 2004Date of Patent: April 6, 2010Assignee: Bridgestone CorporationInventors: Eiju Suzuki, Yoichi Ozawa, Tetsuya Ohmura, Junko Kurazumi
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Publication number: 20100081761Abstract: The invention relates to a polymer composition comprising a matrix polymer, silica particles dispersed therein, and a coupling agent and a screening agent for the silica particles, and is characterized in that the screening agent is an alkylamine compound. The polymer composition is particularly suitable for the manufacture of rubber tyres with improved rolling resistance.Type: ApplicationFiled: November 23, 2007Publication date: April 1, 2010Inventors: Louis-Philippe Antoine Eugène Maria Reuvekamp, Gerard Nijman, Ewout Feenstra
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Publication number: 20100076151Abstract: The invention pertains to a particle comprising a composition containing a matrix and a peroxide or azo radical initiator, wherein the particle is a fiber or fibrid selected from aramid, polyester, polyimide, cellulose, and glass. The invention further relates to particle-elastomers comprising said composition, and skim products, tires, tire treads, and belts comprising these particle-elastomers.Type: ApplicationFiled: July 16, 2009Publication date: March 25, 2010Applicant: TEIJIN ARAMID B.V.Inventors: Rabindra Nath DATTA, Sebastianus Christoffel Josephus PIERIK, Johan P. BAAIJ, Sumana Datta
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Publication number: 20100076142Abstract: A defoaming agent which can effectively eliminate foams generated in the occasions of preparation, coating, drying and baking of water-based paint, by addition thereof by itself, without combined use of other kind(s) of defoaming agent(s), and furthermore without impairing appearance of baked coated film of the paint or recoatability of the paint is provided. Such a defoaming agent for water-based paint has the composition comprising (1) polyoxyethylene hydrogenated castor oil triisostearates and (2) polyalkyl vinyl ether, polybutadiene, polybutene or polyisoprene, which are dissolved in (3) liquid normal paraffin, liquid isoparaffin or liquid cycloparaffin, at such a ratio that the blended amount of (1) occupies 2-90% by weight of the total composition.Type: ApplicationFiled: March 20, 2009Publication date: March 25, 2010Inventors: Tomoko Arima, Takashi Horiguchi, Shigehiro Kawahito
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Publication number: 20100069568Abstract: A backbone modified polymer comprising the reaction product of an elastomeric polymer and a sulfide modifier represented by Formula 1: AS—Y-Zm (Formula 1), and wherein Y is (C12-C100) aralkyl, (C12-C100) aryl, (C12-C100) alkyl, or (C12-C100) dialkylether (alkyl-O-alkyl), and wherein each may be optionally substituted with (C1-C4alkyl, (C1-C4alkoxy, (C7-C16aryl, (C7-C16 aralkyl, nitrile, amine, NO2, alkoxy, or thioalkyl; S is sulfur; A is hydrogen, —(S)p—R1 or -MR2R3R4; Z is —SH, —S-MR5R6R7, —S—(S)p—R8, —NR9R10, —NR11COR12, —O—CO—R13, —NCO, or —COOR14; M is silicon or tin; N is nitrogen; O is oxygen; m is the number one, two or three; p is the number one, two, three, four or five; R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13 and R14 are the same or different, and are each, independently, selected from hydrogen (H), (C1-C16) alkyl, (C6-C16) aryl, (C7-C16) aralkyl or (C3-C30) tri(hydrocarbyl)silyl, and wherein the hydrocarbyl groups are each independently selected from (C1-C16) alkyl, (C6-C16) aryl, orType: ApplicationFiled: December 14, 2007Publication date: March 18, 2010Applicant: Dow Global Technologies Inc.Inventors: Sven H.K. Thiele, Joachim Kiesekamp
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Patent number: 7678861Abstract: New compositions for use as protective coatings and/or adhesives are provided. The compositions comprise a hydrocarbon resin (e.g., terpene rosin) and a rubber (e.g., EPDM) dispersed or dissolved in a solvent system. The solvent system is preferably a single-solvent system, and the compositions are preferably free of surfactants, dyes, and chromophores. The compositions can be cured or dried to form layers or films that are chemically and thermally resistant, but that can be readily dissolved and removed at the appropriate stage in the fabrication process.Type: GrantFiled: August 20, 2008Date of Patent: March 16, 2010Assignee: Brewer Science Inc.Inventors: John C. Moore, Michelle R. Fowler
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Publication number: 20100056711Abstract: There is provided a continuous method for producing a conjugated diene polymer, comprising: polymerizing a conjugated diene, a compound of formula (I) below, and optionally other monomer in the presence of an alkali metal catalyst in a hydrocarbon solvent, wherein X1, X2, and X3 independently denote a group as defined in the specification.Type: ApplicationFiled: August 24, 2009Publication date: March 4, 2010Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Toru FUJII, Seiichi MABE, Mayumi OSHIMA
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Publication number: 20100056709Abstract: A conjugated diene polymer is provided that comprises a conjugated diene-based constituent unit and a constituent unit of formula (I) below, at least one terminus of the polymer being modified by a compound having a linkage of formula (II) below. wherein X1, X2, and X3 independently denote a group as defined in the specification.Type: ApplicationFiled: August 24, 2009Publication date: March 4, 2010Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventor: Mayumi OSHIMA
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Publication number: 20100056710Abstract: A conjugated diene polymer is provided that comprises a conjugated diene-based constituent unit and a constituent unit of formula (I) below, at least one terminus of the polymer being modified by a silicon compound having a linkage of formula (II) below and/or a linkage of formula (III) below, wherein X1, X2, and X3 independently denote a group as defined in the specification.Type: ApplicationFiled: August 24, 2009Publication date: March 4, 2010Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventor: Mayumi OSHIMA
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Publication number: 20100048806Abstract: A process for producing a modified polymer rubber comprising the steps of: (1) polymerizing a conjugated diene monomer or a combination thereof with an aromatic vinyl monomer in a hydrocarbon solvent, in the presence of an alkali metal catalyst or a specified alkali metal compound, to form an alkali metal end-carrying active polymer, and (2) reacting the alkali metal end-carrying active polymer with a specified isocyanurate compound or a combination thereof with a specified coupling agent in a hydrocarbon solvent.Type: ApplicationFiled: October 29, 2009Publication date: February 25, 2010Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Katsunari INAGAKI, Seiichi MABE, Mayumi OSHIMA
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Patent number: 7661164Abstract: A tear and fatigue resistant gel article comprising two or more communicating internal volumes like cavities when depressed by external pressure or force is capable of collapsing unto itself in a controllable and directionally preselected manner by venting static air within said internal through openings in said gel article, said gel article is made from gel compositions having rigidity of from about 20 gram Bloom to about 1,800 gram Bloom suitable for cushioning and other uses.Type: GrantFiled: April 12, 2007Date of Patent: February 16, 2010Assignee: Applied Elastomerics, Inc.Inventor: John Y. Chen
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Publication number: 20100036035Abstract: A nanocomposite material suitable for electrical insulation includes a polymer compounded with a substantially homogeneously distributed functionalized nanoparticle filler. The nanocomposite material is produced by compounding the polymer with the functionalized nanoparticle filler by imparting a shear force to a mixture of the polymer and filler capable of preventing agglomeration of the filler whereby the filler is substantially homogeneously distributed in the nanocomposite material. The electrical insulation may be adapted for AC or DC high voltage, and may also be adapted for low or medium voltage to prevent formation of water tree structures.Type: ApplicationFiled: July 17, 2009Publication date: February 11, 2010Applicant: Rensselaer Polytechnic InstituteInventors: John Keith Nelson, Walter Zenger, Robert John Keefe, Linda Sue Schadler Feist
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Patent number: 7652096Abstract: A rubber composition for a tire tread including 100 parts by weight of a diene-based rubber and 5 to 150 parts by weight of carbon black having a nitrogen adsorption specific area N2SA (m2/g) of 80 to 150 and satisfying a relationship between a TINT (%) and dibutyl phthalate absorption DBPA (ml/100 g) of TINT (%)>1.4 DBPA (ml/100 g) and capable of increasing the frictional force without impairing the hysteresis loss.Type: GrantFiled: December 3, 2003Date of Patent: January 26, 2010Assignee: The Yokohama Rubber Co., Ltd.Inventors: Naoya Amino, Yoshihisa Inoue
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Publication number: 20100012241Abstract: A cushion gum for bonding a tire tread to a tire carcass, the cushion gum comprising an essentially unsaturated diene elastomer, between (0.5) and (25) phr of a metal salt of a carboxylic acid and a peroxide curing system. The essentially unsaturated diene elastomer may be, in some embodiments, a highly unsaturated diene elastomer such as, for example, natural rubber.Type: ApplicationFiled: December 14, 2007Publication date: January 21, 2010Inventors: Xiaofeng Shaw Yang, Brian R. Bergman
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Patent number: 7640957Abstract: This invention relates to high performance tires designed for high vehicular speeds having thin treads with a maximum thickness of about three centimeters with a running surface which is comprised of a rubber composition which is highly loaded with a combination of reinforcing filler and rubber processing oil. The combination of reinforcing filler is comprised of conductive carbon black and optionally at least one of classical rubber reinforcing carbon black and precipitated silica and their mixtures. This high level of a combination of selective reinforcing filler together with rubber processing oil in the tread rubber is provided to promote a reduction in internal heat generation within the thin tread during high vehicular speeds, particularly for vehicles intended to be used as race cars.Type: GrantFiled: September 23, 2005Date of Patent: January 5, 2010Assignee: The Goodyear Tire & Rubber CompanyInventor: Paul Harry Sandstrom
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Publication number: 20090312476Abstract: The invention relates to rubber mixtures, comprising: (A) at least one rubber, (B) at least one oxidic filler and (C) at least one (haloorganyl)alkylpolyethersilane of the general formula (X)(X?)(X?)Si—R1—Hal. The rubber mixtures can be used for production of mouldings.Type: ApplicationFiled: May 10, 2007Publication date: December 17, 2009Applicant: Evonik Degussa GmbHInventors: Karsten Korth, Andre Hasse, Dirk Laur, Ingo Kiefer, Oliver Klockmann, Philipp Albert, Manuel Friedel
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Publication number: 20090306267Abstract: A rubber mixture with improved abrasion with improved abrasion performance, in particular for pneumatic tires, has the following composition: from 30 to 100 phr of at least one diene rubber; from 0.1 to 10 phr of at least one vulcanization accelerator selected from the group consisting of: thiazole accelerators, mercapto accelerators, sulfenamide accelerators, guanidine accelerators, thiuram accelerators, dithiocarbamate accelerators, amine accelerators, thioureas, and/or other accelerators; and a vulcanization system of sulfur comprising elemental sulfur, sulfur donor and silane between 0.25 and 0.08 moles per 100 parts by weight of the rubber elastometer, whereby the free sulfur contributes in the range of 0 to 70%, the sulfur donor contributes in the range of 5 to 30%, and the silane contributes in the range of 20 to 95%.Type: ApplicationFiled: June 5, 2008Publication date: December 10, 2009Inventors: William Michael York, Carla Recker, Katharina Herzog, Hajo Weinreich, Boris Mergell, Viktoriya Tkachenko, Norbert Mueller, Juergen Wagemann
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Patent number: 7629397Abstract: Provided for herein is a process for separating a hydrocarbon-rubber from a hydrofluorocarbon diluent comprising contacting a polymer slurry comprising the hydrocarbon-rubber dispersed within the hydrofluorocarbon diluent with a hydrocarbon solvent capable of dissolving the hydrocarbon-rubber, to produce a first liquid phase and a second liquid phase, and separating the first liquid phase from the second liquid phase.Type: GrantFiled: June 23, 2006Date of Patent: December 8, 2009Assignee: ExxonMobil Chemical Patents Inc.Inventors: Michael F. McDonald, Scott T. Milner, D. Shaffer Timothy, N. Webb Robert, D. Hembree Richard
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Publication number: 20090298998Abstract: The invention is a method of producing an essentially electrically neutral polymer dispersion, comprising a polymerizing one or more monomers in the presence of a nonionic surfactant, wherein the polymerization preferably occurs in the absence of ionic surfactants. The invention also includes methods of producing positively or negatively charged polymer dispersions comprising producing the essentially nonionic polymer dispersion and further adding a cationically-charged or anionically-charged surfactant or electrolyte. The invention further includes dispersions produced by the methods of the invention and polymer films and powders produced from these dispersions.Type: ApplicationFiled: April 4, 2007Publication date: December 3, 2009Applicant: BASF SEInventors: Koichi Takamura, Armin Burghart
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Patent number: 7625975Abstract: The present invention relates to a composition acting as coupling agent between fillers and peroxidically crosslinking elastomers in rubber compounds, which comprises, as component comprising silicon compounds, a mixture a) of vinylalkoxysiloxanes with alkylalkoxy-siloxanes, or b) of vinylalkoxysiloxanes with phenylalkoxy-siloxanes, or c) of vinylalkoxysiloxanes with phenyl/alkyl-alkoxysiloxanes or d) of acrylic or methacrylic alkoxysiloxanes with alkylalkoxysiloxanes, or e) of acrylic or methacrylic alkoxysiloxanes with phenylalkoxysiloxanes, or f) of acrylic or methacrylic alkoxysiloxanes with phenyl/alkylalkoxysiloxanes, or g) of at least one co-oligomeric organosiloxane which, as organofunctional groups, bears at least one group from the series vinyl, acrylic and methacrylic, and at least one group from the series alkyl and phenyl, and at least one alkoxy or hydroxy group.Type: GrantFiled: June 20, 2003Date of Patent: December 1, 2009Assignee: Degussa AGInventors: Dieter Barfurth, Helmut Mack, Burkhard Standke
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Patent number: 7625971Abstract: Disclosed are silica-filled rubber granules comprised of a cocoagulation product of rubber and silica, which are extremely less powdery and excellent in handling and kneading, as well as an industrially advantageous process for producing same. The silica-filled rubber granules of the present invention are dried granules of a cocoagulation product of rubber and silica particles, which are characterized in that an average particle diameter (D50) in terms of the sieve analysis is 300˜3000 ?m and the weight ratio of the granules within the range of D50±(D50×0.5) is at least 50% by weight. The silica-filled rubber granules are produced by supplying a cake of a cocoagulation product of silica and rubber having a water content of 40˜80% by weight to a drier provided with an indirect-heating type container having stirring wing blades, and then drying the cake while stirring it with the stirring wing blade.Type: GrantFiled: August 19, 2004Date of Patent: December 1, 2009Assignees: Tokuyama Corporation, Zeon CorporationInventors: Shinji Tokunaga, Tsunetoshi Sugimura, Kazutaka Watanabe, Osamu Yatabe, Takeshi Karato, Takahiko Fukahori, Yoshihiro Chino
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Publication number: 20090292046Abstract: The invention provides methods of producing composite polymers by combining fillers with polymers in the presence of pre-formed high molecular weight polymer. Monomer polymerization can be initiated through the addition of initiators or by reactive chemical groups on the surface of the fibers. The composite materials formed possess superior mechanical properties compared to similar polymer composites made by either purely mechanical mixing or solely polymerization of monomers in the presence of the fillers.Type: ApplicationFiled: June 8, 2009Publication date: November 26, 2009Applicant: COLORADO SCHOOL OF MINESInventors: John R. Dorgan, Birgit Braun
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Publication number: 20090281223Abstract: A method of forming a sulfur-vulcanized elastomeric by combining at least one diene elastomer and at least one reinforcing filler, with an effective amount of a coupling agent consisting of a combination of: 10 to 90%, of a product (I) consisting of a blend of poly(alkylphenol) polysulfides of formula: in which: R is an alkyl radical containing 1 to 20 carbon atoms; n and n? are two integers, which may be identical or different, from 1 to 8; p is an integer from 0 to 50; and 10 to 90% of a product (II) consisting of bis(triethoxysilylpropyl)tetrasulfide, to form a mixture; thereafter working said mixture; and thereafter heating said mixture to vulcanize said mixture. 90% of bis(triethoxysilylpropyl)tetrasulfide.Type: ApplicationFiled: July 27, 2009Publication date: November 12, 2009Applicant: Arkema FranceInventor: Thierry Aubert
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Patent number: 7615591Abstract: A rubber composition comprises a diene rubber component, a filler and a softening agent, in which a given amount of a filler is compounded based on 100 parts by mass of a diene rubber component, and a softening agent is included in a given amount per the filler, and not less than 60% by mass of the diene rubber component is a solution-polymerized styrene-butadiene copolymer rubber having a mass average molecular weight of not less than 1,000,000, and the filler is selected from the group consisting of carbon black, silica and an inorganic agent of a formula (I): mM.xSiOy.zH2O (wherein M is at least one metal selected from the group consisting of aluminum, magnesium, titanium and calcium, or an oxide of such a metal or a hydroxide of such a metal, m is a number of 1-5, x is a number of 0-10, y is a number of 2-5 and z is a number of 0-10), wherein each of the filler and the softening agent is charged in at least two fractions.Type: GrantFiled: February 2, 2005Date of Patent: November 10, 2009Assignee: Bridgestone CorporationInventor: Hideki Matsui
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Patent number: 7612144Abstract: An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.Type: GrantFiled: September 13, 2007Date of Patent: November 3, 2009Assignee: Bridgestone CorporationInventors: Terrence E. Hogan, William Hergenrother, Yuan-Yong Yan, David Lawson
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Publication number: 20090250151Abstract: A tire including at least one structural element includes a crosslinked elastomeric material obtained by crosslinking a crosslinkable elastomeric composition including: (a) 100 phr of at least one elastomeric polymer; (b) 0.1 phr to 15 phr, preferably 0.3 phr to 10 phr, of at least one methylene donor compound: c) 0.4 phr to 20 phr, preferably 0.8 phr to 15 phr of at least one methylene acceptor compound; (d) 1 phr to 50 phr, preferably 2 phr to 40 phr, more preferably 4 phr to 30 phr, of at least one layered material, the at least one layered material having an individual layer thickness of 0.2 nm to 30 nm, preferably 0.3 nm to 15 nm, more preferably 0.Type: ApplicationFiled: July 20, 2006Publication date: October 8, 2009Inventors: Maurizio Galimberti, Gaetano Guerra, Angela Lostritto, Luca Giannini
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Publication number: 20090247695Abstract: A process for simply and inexpensively producing a conjugated diene polymer with a narrow molecular weight distribution and a high cis-bond content at a low cost is provided. The process comprises a polymerization step, wherein a conjugated diene polymer having a cis-1,4-bond content of 98.5 mass % or more and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) measured by gel permeation chromatography of 2.5 or less is obtained by carrying out a polymerization reaction in conjugated diene compounds using a catalyst composition containing a rare earth element-containing compound or a reaction product of the rare earth element-containing compound with a Lewis base, an aluminoxane and/or organoaluminum compound, and an iodine-containing compound.Type: ApplicationFiled: December 5, 2006Publication date: October 1, 2009Applicants: JSR Corporation, Bridgestone CorporationInventors: Takahiro Nakamura, Kouichirou Tani, Ryouji Tanaka, Takuo Sone, Toshihiro Tadaki, Junko Kurazumi, Koji Masaki, Yoichi Ozawa
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Publication number: 20090234064Abstract: An aqueous elastomer dispersion includes a dispersed phase and an aqueous phase. The dispersed phase includes an elastomer including curable aliphatic conjugated-diene elastomers, such as polyisoprene, and a minor amount of at least one additive. The aqueous phase includes water and other optional components in either a soluble state or a dispersion state. The aqueous elastomer dispersion may be prepared by dissolving an elastomer, such as rubber, and additives in a solvent mixture and then converting the resulting solution into an aqueous emulsion. The aqueous emulsion is concentrated and the solvent is stripped from it to yield a dilute latex. The dilute latex that is obtained is concentrated again. Articles made from the aqueous elastomer dispersion include medical gloves, condoms, probe covers, dental dams, finger cots, catheters and the like.Type: ApplicationFiled: March 13, 2009Publication date: September 17, 2009Applicant: Allegiance CorporationInventors: Shiping WANG, Seong Fong Chen, Ida Berger, Yun-Siung Tony Yeh, Wei Cheong Wong
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Publication number: 20090234066Abstract: Tyre and rubber composition for tyre, based on at least one isoprene elastomer (for example natural rubber), an inorganic filler as reinforcing filler (for example silica) and a coupling system which provides the bonding between the said reinforcing inorganic filler and the isoprene elastomer, the said coupling system comprising, in combination: as first coupling agent, a silane sulphide compound; as second coupling agent, an at least bifunctional organosilicon compound (for example an organosilane or an organosiloxane) which can be grafted to the elastomer by means of an azodicarbonyl functional group (—CO—N?N—CO—).Type: ApplicationFiled: May 11, 2006Publication date: September 17, 2009Inventors: Jose Carlos Araujo Da Silva, Nathalie Binde, Pierre Robert, Sebastien Sterin, Anne Veyland
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Publication number: 20090234057Abstract: The use of a rubber compound wherein the mechanical properties thereof are improved. In particular, the rubber compound has an increased elongation at rupture and/or increased tensile strength and/or increased tear strength and also a reduced compression set (DVR). The rubber compound includes a rubber having at least two functional groups which can be cross-linked by hydrosilylation, a cross-linking agent including hydrosiloxane or a hydrosiloxane derivative or a mixture of several hydrosiloxanes or derivatives, which include at least two SiH-groups per molecule in the centre, a hydrosilylation catalyst system, at least one filling material and a coagent which can be cross-linked by hydrosilylation, for use as a material in the insertion area of the fuel cells.Type: ApplicationFiled: September 16, 2006Publication date: September 17, 2009Applicant: Carl Freudenberg KGInventors: Matthias Adler, Ruth Bieringer, Michael Viol
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Patent number: 7588065Abstract: The subject of the present invention is the use of cohesive, low-hysteresis compositions comprising small amounts of reinforcing fillers to produce profiled filing members arranged in the bottom zone of tires in order to improve the life thereof.Type: GrantFiled: February 10, 2000Date of Patent: September 15, 2009Assignee: Michelin Recherche et Technique, S.A.Inventor: Frédéric Serre
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Patent number: 7585915Abstract: A description is given of an aqueous dispersion adhesive based on an aqueous polymer dispersion comprising at least one emulsion polymer with small amounts of crosslinkable N-methylol groups, at least one protective colloid, and at least one crosslinking agent containing N-methylol groups, of which at least one is etherified with an alkanol, said crosslinking agent being selected from the group consisting of hydroxymethylated cyclic ethyleneureas, hydroxymethylated cyclic propyleneureas, hydroxymethylated bicyclic glyoxal diureas, hydroxymethylated bicyclic malonaldehyde diureas or combinations thereof. The aqueous dispersion adhesive can be employed in particular for adhesively bonding porous and semiporous substrates.Type: GrantFiled: July 26, 2004Date of Patent: September 8, 2009Assignee: Celanese Emulsions GmbHInventors: Martin Jakob, Werner Prass
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Publication number: 20090215952Abstract: Elastomer isoprene rubber compositions contain an effective amount of a polyfunctional coupling system (A) as an inorganic-elastomer filler coupling agent, and (B) at least one elastomer of natural or synthetic rubber; (C) an inorganic filler as reinforcing filler; (D) other conventional constituents or additives comprising one or more vulcanizing agent(s), the polyfunctional coupling system being of the constituents (A1) and (A2): (A1) is at least one coupling agent selected from among the functionalized organosilicon compounds of formula (I): [(G0)3SiO1/2]m [(G0)2SiO2/2]n [G0SiO3/2]o [SiO4/2]p [(G2)a(G1)a?(Z-CO—N?N—CO-A)SiO(3-a-a?)/2]q and (A2) is at least one coupling agent selected among polysulfurated “symmetric” silanes, or sulfurated “asymmetric” silanes.Type: ApplicationFiled: May 18, 2006Publication date: August 27, 2009Inventors: Laurent Guy, Michel Fernandez, Sebastien Sterin
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Publication number: 20090215948Abstract: Elastomeric isoprene rubber compositions contain an effective amount of a coupling agent (A) comprising an organosilicon compound with coupling agent functions for inorganic/elastomeric fillers and include (B) at least one natural or synthetic rubber elastomer, (C) an inorganic filler as reinforcement filler, (D) other conventional constituents or additives comprising vulcanization agents; the coupling agent (A) being a functionalized organosilicon compound, including the following two compounds (i) and (2i), (i) being at least one functionalized siloxane corresponding to the formula (I): [(G0)3SiO1/2]m[(G0)2SiO2/2]n[G0SiO3/2]o[SiO4/2]p[(G2)a(G1)a?(Z-CO N?N—CO-A)SiO(3-a-a?)/2]q and (2i) being a mixture of at least one functionalized siloxane (i) with (3i) at least one functionalized organosilane also corresponding to formula (I) where m=n=o=p=0 (zero), q=1, a=0, 1, 2 or 3 and the sum a+a?=3.Type: ApplicationFiled: May 19, 2006Publication date: August 27, 2009Inventors: Laurent Guy, Michel Fernandez, Sèbastien Sterin
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Patent number: 7579403Abstract: Stain resistant composition comprises a hyperbranched polymer having pendent olefinic groups and comprising polymer units derived from one or more terminally-unsaturated, acyclic aliphatic diene and polymer units derived from maleic anhydride. Optionally, the hyperbranched polymer may further comprise polymer units derived from one or more 1-alkenes and/or a chain transfer agent. A method to provide stain resistance to a substrate comprises applying the stain resistant composition to said substrate. Suitable substrates include textiles and hard surfaces.Type: GrantFiled: April 4, 2006Date of Patent: August 25, 2009Assignee: E. I. du Pont de Nemours and CompanyInventors: Stephen Ernest Jacobson, Patricia Metzger Cotts
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Publication number: 20090209698Abstract: A process for the preparation of an aqueous rubber emulsion (artificial latex), comprising the steps: (a) size reduction of the rubber, whereby granules are produces with shorter dissolving time; (b) cement formation, wherein the granules of step (a) are dissolved in a suitable hydrocarbon solvent; (c) preparation of an aqueous soap solution; (d) emulsification of the cement formed in step (b), using the aqueous soap solution prepared in step (c), thus forming an oil in water emulsion; (e) hydrocarbon solvent removal, resulting in an aqueous emulsion of the rubber, and optionally (f) emulsion concentration, forming an artificial latex with a higher solids content, wherein in step (a) the size reduction is carried out using a chopper and/or granulator characterized in that a soap is used as processing aid, preferably identical to the soap used in steps (c) and (d).Type: ApplicationFiled: March 26, 2007Publication date: August 20, 2009Applicant: KRATON POLYMERS U.S. LLCInventors: Adrie A. Van Der Huizen, Jean Furton, Arwin W. Van Der Waal
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Patent number: 7576153Abstract: An elastomeric composition usable for the manufacture of tires, based on at least (i) a diene elastomer, (ii) an inorganic filler as reinforcing filler and (iii), as (inorganic filler/diene elastomer) coupling agent, a organosilicon compound which is at least bifunctional and can be grafted on to the elastomer by means of a sulfur group having a polythiosulfenamide function, of formula: ?Si—A—Sx—NR1R2,??(I) in which: A is a divalent bond group, whether straight-chain or branched, which makes it possible to join the polythiosulfenamide group to a silicon atom of the organosilicon compound; x is an integer or fractional number of from 2 to 4; R1 represents hydrogen or a monovalent hydrocarbon group; R2 represents a monovalent hydrocarbon group selected from among C3-C8 alkyls, whether straight-chain or branched, C5-C10 cycloalkyls, C6-C18 aryls and (C6-C18)aryl-(C1-C8)alkyls; R1 and R2 possibly forming together and with the nitrogen atom to which they are bonded a single hydrocarbon ring.Type: GrantFiled: June 21, 2004Date of Patent: August 18, 2009Assignee: Michelin Recherche et Technique S.A.Inventors: Carlos José Araujo Da Silva, Christiane Blanchard, Gérard Mignani, Salvatore Pagano, Jean-Claude Tardivat
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Publication number: 20090203836Abstract: A composition of matter is disclosed that comprises at least one silane coupling agent for coupling an elastomer and a filler wherein said silane comprises at least one hydrolysable group that, upon compounding said silane with said elastomer and filler, is released to yield a compound that improves downstream processability of the compounded composition or the properties of the final rubber product or both.Type: ApplicationFiled: April 9, 2009Publication date: August 13, 2009Applicant: MOMENTIVE PERFORMANCE MATERIALS INC.Inventors: Richard W. Cruse, Robert J. Pickwell
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Publication number: 20090199945Abstract: Tire, including at least one structural element including a crosslinked elastomeric material obtained by crosslinking a crosslinkable elastomeric composition, includes: (a) at least one diene elastomeric polymer; (b) at least one activator obtained by dry comilling a mixture including: at least one salt, or one oxide, or one hydroxide of a metal belonging to groups 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, or 16 of the Periodic Table of the Elements; and at least one layered material, said layered material having an individual layer thickness of 0.01 nm to 30 nm, preferably 0.05 nm to 15 nm, and more preferably 0.1 nm to 2 nm; (c) at least one vulcanization accelerator; and (d) sulfur or derivatives thereof.Type: ApplicationFiled: March 3, 2006Publication date: August 13, 2009Inventors: Maurizio Galimberti, Clementina Spera, Attilio Citterio
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Patent number: 7569632Abstract: A rubber composition which is effective in improving the reaction efficiency of a silane coupling agent in kneading, suppressing generation of air bubbles, improving processability and abrasion resistance and lowering rolling resistance, and a process for preparing the same, wherein the rubber composition includes silica, 3 to 15 parts by weight of a silane coupling agent based on 100 parts by weight of the silica and 0.3 to 1.45 parts by weight of a potassium salt based on 100 parts by weight of silica.Type: GrantFiled: June 21, 2006Date of Patent: August 4, 2009Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Yasuhisa Minagawa, Noriko Yagi, Noboru Wakabayashi
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Publication number: 20090186965Abstract: Provided are elastomeric compositions comprising at least one elastomer and a hydrocarbon polymer additive. Preferably the hydrocarbon polymer additive comprises from 60 to 90% piperylene, from 5 to 15% cyclic components, from 5 to 20% styrenic components, up to 5% isoprene, up to 5% indenic components, and up to 10% amylene. Also provided are elastomeric compositions comprising at least one elastomer and a hydrocarbon polymer additive, wherein the hydrocarbon polymer additive has a molecular weight of from 520 to 650 g/mole and a glass transition temperature (Tg) of from 48 to 53° C. The elastomeric compositions are particularly useful in making tires and other cured rubber articles.Type: ApplicationFiled: December 29, 2008Publication date: July 23, 2009Inventors: Michael B. Rodgers, Anthony J. Dias, Rick Dowell Davis, Thomas R. Barbee, Shawn W. Mowry
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Patent number: 7560501Abstract: An encapsulant composition. The encapsulant composition includes a resin material consisting of epoxy or cyanate ester resins, from about 1.0% by weight to about 5% by weight of the composition of a flexibilizing agent including a flexibilizer containing functional groups capable of reaction with the epoxy or cyanate ester resin during thermally induced curing, a filler material including substantially spherical or spheroidal particles such that each particle has a diameter less than about 41 microns, and a thermoplastic other than the flexibilizer. The thermoplastic is separated from the cured epoxy or cyanate ester resin. The thermoplastic includes a poly(arylene)ether. The flexibilizer includes bis(2,3-epoxy-2-methylpropyl)ether.Type: GrantFiled: May 29, 2008Date of Patent: July 14, 2009Assignee: International Business Machines CorporationInventor: Konstantinos I. Papathomas
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Publication number: 20090162718Abstract: Embodiments of the present invention include cured elastomeric materials of high purity, compositions for making them, and articles comprising the cured elastomeric materials. Embodiments of the invention include cured elastomers that have less than 200 ng/cm2 of calcium. In some embodiments, the cured elastomer is made from cross linked ethylene-propylene-diene terpolymers and can be free from cross linked fluorpelastomers or silicone elastomers. The cured elastomers in embodiments of the present invention may be used for seals including o-rings and gaskets.Type: ApplicationFiled: November 30, 2006Publication date: June 25, 2009Inventor: Charles W. Extrand
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Publication number: 20090155472Abstract: The invention relates to a building material composition which is suitable in particular for use as a bitumen-free sealant for sealing structures and contains a polymer dispersion or a corresponding redispersion powder, in particular based preferably on emulsion polymers which are redispersible in an aqueous medium, together with polystyrene particles, hollow ceramic and synthetic microspheres and, if appropriate, at least one binder and, if appropriate, further additives. The sealant according to the invention can in principle be formulated as a 1C or 2C application system. In addition to excellent sealing properties, as can conventionally be achieved only with bitumen-containing sealants, the bitumen-free building material composition according to the invention shows in particular excellent shrinkage behavior after application.Type: ApplicationFiled: September 1, 2006Publication date: June 18, 2009Applicant: Henkel AG & Co. KGaAInventors: Manfred Grasse, Udo Windhovel, Katharina Lehmkuehler, Caroline Pfefferle
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Publication number: 20090156736Abstract: The present invention relates to new coating materials for atmospheric corrosion control.Type: ApplicationFiled: January 26, 2006Publication date: June 18, 2009Applicant: BASF AktiengesellschaftInventors: Gerhard Fischer, Monica Fernandez Gonzalez, Marc Schroder, Konrad Roschmann, Alexander Gothlich, Hermann Bergmann, Guido Vandermeulen