With Polycarboxylic Acid Or Derivative And A Polyol At Least One Of Which Is Saturated, A Condensate Or Solid Polymer Thereof; Or With Solid Polymer Derived From At Least One Polycarboxylic Acid Or Derivative And At Least One Polyol Wherein At Least One The Reactants Forming The Solid Polymer Is Saturated Patents (Class 525/165)
  • Patent number: 4356281
    Abstract: The flame retardancy of a polyethylene terephthalate ester molding composition is improved by mixing therewith both a salt of oxalic acid and polytetrafluoroethylene having a number average molecular weight Mn of more than 10.sup.5. The oxalic acid salt has the formula K.sub.3 [Al(C.sub.2 O.sub.4).sub.3 ], K.sub.2 [Mg(C.sub.2 O.sub.4).sub.2 ] or Rb.sub.3 [Al(C.sub.2 O.sub.4).sub.3 ]. The preferred composition contains from 5-15% by weight of the oxalic acid salt and 0.1-0.5% by weight of polytetrafluoroethylene. The composition having improved flame retardancy may be used to advantage for making shaped articles by injection molding.
    Type: Grant
    Filed: October 7, 1980
    Date of Patent: October 26, 1982
    Assignee: Akzo NV
    Inventors: Ted Brink, Stephanus A. G. de Graaf
  • Patent number: 4349503
    Abstract: A composition and a method to crystallize the composition. The composition comprises a linear saturated polyester, preferably poly(ethylene terephthalate) and from 0.05 percent to 0.6 percent of sodium nitrite. The composition can contain a plasticizer, impact modifier and a filler.
    Type: Grant
    Filed: May 15, 1981
    Date of Patent: September 14, 1982
    Assignee: Allied Corporation
    Inventor: Shaul M. Aharoni
  • Patent number: 4338243
    Abstract: Use of a selected antimonate has been found to increase flame-retardancy without lowering thermal resistivity of a polyurethane terephthalate molding blend which contains an ionic hydrocarbon copolymer or ionic salt of a hydrocarbon acid and a low molecular weight compound.
    Type: Grant
    Filed: May 7, 1980
    Date of Patent: July 6, 1982
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: James L. Hecht, Paul C. Yates
  • Patent number: 4337187
    Abstract: A cationic electrocoating composition containing a polyhydroxyamine and polyesters or alkyds and optionally a crosslinker resin.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: June 29, 1982
    Assignee: E. I. DuPont de Nemours and Company
    Inventor: Isidor Hazan
  • Patent number: 4325859
    Abstract: A stable organic polymer-polyol-alkali metal silicate emulsion is produced by mixing an aqueous solution of an alkali metal silicate or alkali metal metasilicate pentahydrate, a liquid polyol, an organic polymer in a fluid state, and a small amount of an acid while heating the mixture to 40.degree. C. to 100.degree. C. and agitating until the mixture emulsifies. The emulsion may be used to produce organic polymer-polyurethane silicate foams and resinous product.
    Type: Grant
    Filed: July 20, 1981
    Date of Patent: April 20, 1982
    Inventor: David H. Blount
  • Patent number: 4322334
    Abstract: Unsaturated polyester resin compositions that have a low shrinking property, and at the same time, an enough strength are provided. The compositions comprises (1) 30-70 parts by weight of an unsaturated polyester obtained by reacting terephthalic acid and/or isophthalic acid and one or more of unsaturated acids selected from the group consisting of maleic anhydride, maleic acid and fumaric acid, with a glycol, and having the unsaturation degree of 1.5-5.0 and the acid value of 18-40, (2) 70-30 parts by weight of .alpha.,.beta.-ethylenically unsaturated monomer, and (3) 5-30 parts by weight of a thermoplastic resin having the number average molecular weight of 5,000-500,000.
    Type: Grant
    Filed: December 4, 1979
    Date of Patent: March 30, 1982
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Kouji Arakawa, Kanemasa Nomaguchi, Etsuji Iwami
  • Patent number: 4303767
    Abstract: Flame-retardant antistatic polymer additives are provided which inhibit the buildup of electrostatic charges upon the addition of such compositions to synthetic polymeric fibers, i.e., polyamide fibers, and at the same time do not contribute to the flammability characteristics of such polymeric fibers. The flame-retardant antistatic polymer compositions are useful in combinations with fibers such as polyamide, polyester, polyurea, polyurethane, polysulfonamide, polyolefin and polyacrylic fibers. The antistatic effect is obtained by the process of coating the fibers or dispersing in or on the fibers up to about 12 percent by weight of a polymer composition which is the reaction product of:(a) a polyoxyalkylene compound or polyester thereof and(b) at least one reactant selected from the group consisting of (1) a diol, (2) a polyester and (3) an aliphatic or aromatic diacid or derivative of (3), wherein at least one said reactant is halogenated.
    Type: Grant
    Filed: November 13, 1979
    Date of Patent: December 1, 1981
    Assignee: BASF Wyandotte Corporation
    Inventors: David D. Newkirk, Robert B. Login, Basil Thir
  • Patent number: 4290927
    Abstract: An intimate polyblend of about 5-90% by weight of a thermoplastic copolyester or block copolyester elastomer and about 95-10% by weight of a vulcanizable synthetic or natural rubber. The preferred copolyester is a copolyester of polybutylene terephthalate and the prefered block copolyetherester is polybutylene terophthalate-poly (tetramethylene oxide) glycol block copolyester. These polyblends can be vulcanized to elastomeric molded articles which exhibit an excellent oil and oxygen/ozone resistance even at elevated temperatures, a high impact strength, an increased scuff resistance and an improved flexibility at low and high temperatures. The vulcanized molded articles also have an improved adhesive property with polyester fibers or fabrics.
    Type: Grant
    Filed: April 16, 1980
    Date of Patent: September 22, 1981
    Assignee: Toray Industries, Inc.
    Inventors: Chiaki Tanaka, Masanobu Morikawa, Yoshio Kohno
  • Patent number: 4288570
    Abstract: Thermoplastic compositions are described comprising blends of epichlorohydrin rubber and poly(alkyl methacrylate) resin. Compositions in which the rubber is cross-linked are also described.
    Type: Grant
    Filed: May 12, 1980
    Date of Patent: September 8, 1981
    Assignee: Monsanto Company
    Inventors: Aubert Y. Coran, Raman Patel
  • Patent number: 4259458
    Abstract: Described herein are molding compositions comprising a blend of a polyarylate, a polyester, and at least one thermoplastic polymer selected from the group consisting of an aromatic polycarbonate, a styrene resin, an alkyl acrylate resin, a polyurethane, a vinyl chloride polymer, a poly(aryl ether), a copolyetherester block polymer or a polyhydroxyether. These blends have excellent compatability and can be molded into a variety of articles.
    Type: Grant
    Filed: August 9, 1979
    Date of Patent: March 31, 1981
    Assignee: Union Carbide Corporation
    Inventor: Lloyd M. Robeson
  • Patent number: 4247427
    Abstract: Thermoplastic segmented copolyester elastomer consisting essentially of a multiplicity of recurring short chain ester units and long chain ester units joined through ester linkages, said short chain ester units amounting to 15 to 75 percent by weight of said copolyester and being derived from dicarboxylic acid such as an aromatic acid, e.g., terephthalic acid or a mixture of terephthalic acid and isophthalic acid, and an organic diol such as butanediol, and said long chain ester units amounting to 25 to 85 percent by weight of said copolyester and being derived from dicarboxylic acid such as an aromatic acid, e.g., terephthalic acid, or a mixture of terephthalic and isophthalic acids, and a long chain glycol such as polytetramethylene ether glycol, said copolyester having a melt index of less than 150 and a melting point of at least 90.degree. C., modified with 0.
    Type: Grant
    Filed: May 14, 1979
    Date of Patent: January 27, 1981
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: John M. Edinger
  • Patent number: 4238193
    Abstract: Durable excellent water absorption property and antistatic property can be given to synthetic fiber by a simple method. In the method, a polymerization initiator is absorbed in the fiber and then the fiber is applied with a water-soluble polymerizable monomer and heat treated to form a polymer thereon.
    Type: Grant
    Filed: September 19, 1978
    Date of Patent: December 9, 1980
    Assignee: Kanebo, Ltd.
    Inventors: Akio Kisaichi, Masao Oguchi, Toshihide Takeda, Akira Aikawa, Toshio Saito
  • Patent number: 4222926
    Abstract: A flame-retarding thermoplastic polyester resin composition comprising (1) a polyester obtained from a terephthalic acid or an alkyl ester thereof and a glycol having 2 to 4 carbon atoms, (2) an organohalogen compound, (3) an inorganic flame-retarding supplementary agent, and (4) at least one polymer selected from a saponified polyvinyl acetate having a saponification degree of greater than 50%, an ethylene/vinyl acetate copolymer and a saponified ethylene/vinyl acetate copolymer, and optionally (5) a reinforcing agent; and a process for production thereof.
    Type: Grant
    Filed: April 4, 1978
    Date of Patent: September 16, 1980
    Assignee: Dainippon Ink & Chemicals, Inc.
    Inventors: Shioji Mizuno, Norio Enokimoto
  • Patent number: 4221700
    Abstract: A stabilized synthetic polymer composition comprising(1) 100 parts by weight of a synthetic polymer,(2) 0.001 to 5 parts by weight of a poly(alkylated alkenylphenol) composed substantially of monomeric units represented by the following formula (I) ##STR1## wherein R represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; R.sub.1 represents an alkyl group having 1 to 18 carbon atoms; and R.sub.2 represents a hydrogen atom or an alkyl group having 1 to 18 carbon atoms; and(3) 0.001 to 5 parts by weight of an auxiliary stabilizer selected from the group consisting of polyhydric alcohol esters of alkylthioalkanoic acids, polyesters of thiodipropionic acid and organic phosphite compounds.
    Type: Grant
    Filed: July 5, 1978
    Date of Patent: September 9, 1980
    Assignee: Maruzen Oil Co., Ltd.
    Inventors: Motomobu Minagawa, Mitsuo Akutsu, Hiroshi Fujiwara, Masayuki Kashiki
  • Patent number: 4218362
    Abstract: A powder marking agent comprising a fine powder which comprises, on a total volume basis,(a) about 48% to about 92% of a thermoplastic linear polyester,(b) about 5 to about 30% of a heat-resistant pigment, and(c) about 2 to about 40% of a fluorine-containing polymer,with the total by volume percent of the heat-resistant pigment (b) and the fluorine-containing polymer (c) being about 45% or less and a marking method which comprises applying the powder marking agent described above onto a metal member in a marking pattern.
    Type: Grant
    Filed: November 17, 1977
    Date of Patent: August 19, 1980
    Assignees: Fuji Photo Film Co., Ltd., Chugoku Marine Paints, Ltd.
    Inventors: Satoru Honjo, Kenichi Sawada, Masaki Fukagawa
  • Patent number: 4173595
    Abstract: A thermosetting composition is disclosed characterized in that it comprises (by weight) from 60 to 90% of a bis-maleimide of the formula: ##STR1## in which A represents a divalent radical chosen from the group consisting of phenylene radicals and radicals of the formula: ##STR2## where T represents --CH.sub.2 --, --C(CH.sub.3).sub.2 --, --O-- or --SO.sub.2 --; and from 10 to 40% of N-vinylpyrrolid-2-one. The preferred bis-maleimide is N,N'-(4,4'-diphenylmethane)-bis-maleimide. The composition may be modified by the addition of an unsaturated polyester. The composition is useful for the manufacture of molded articles or of articles having a cellular structure, or for the impregnation of electrical coils.
    Type: Grant
    Filed: January 5, 1978
    Date of Patent: November 6, 1979
    Assignee: Rhone-Poulenc Industries
    Inventors: Max Gruffaz, Jean-Louis Locatelli
  • Patent number: 4172103
    Abstract: Thermoplastic moulding compounds of1. 10-95% by weight of an aromatic polycarbonate in which at least 50% of the linear chains comprise recurrent structural units of the formula ##STR1## in which R represents C.sub.1 -C.sub.3 alkyl and X represents a single bond, --O--, --CO--, --SO.sub.2 --, C.sub.1 -C.sub.10 alkylene, C.sub.1 -C.sub.10 alkylidene, C.sub.5 -C.sub.15 cycloalkylene, C.sub.5 -C.sub.15 cycloalkylidene or ##STR2## 2. 5-90% by weight of a thermoplastic resin and/or 3. 5-90% BY WEIGHT OF RUBBER WHICH MAY BE MODIFIED.
    Type: Grant
    Filed: August 23, 1977
    Date of Patent: October 23, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Volker Serini, Wolfgang Cohen, Hugo Vernaleken, Gunter Perlstocker