With Polycarboxylic Acid Or Derivative And A Polyol At Least One Of Which Is Saturated, A Condensate Or Solid Polymer Thereof; Or With Solid Polymer Derived From At Least One Polycarboxylic Acid Or Derivative And At Least One Polyol Wherein At Least One The Reactants Forming The Solid Polymer Is Saturated Patents (Class 525/165)
  • Patent number: 6099759
    Abstract: The present invention has for subjects, novel benzopyran derivatives, substituted in position 2 with an adamantyl group as well as the compositions and (co)polymer matrices containing such derivatives. Said derivatives possess interesting photochromic properties.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: August 8, 2000
    Assignee: Corning Incorporated
    Inventor: You-Ping Chan
  • Patent number: 6063474
    Abstract: A composition having repellency to low surface tension fluids comprising a material prepared by forming a mixture of a polymer selected from the group consisting of polyolefin, polyamide, polyester, polyacrylate, and blends and copolymers thereof, and a fluorochemical compound comprising a fluorocarbon/hydrocarbon ester of the formulae:R.sub.f --O--C(O)--R.sub.1 or R.sub.f --C(O)--O--R.sub.1whereinRf is selected from the group consisting of:1) F(CF.sub.2).sub.x --(CH.sub.2).sub.m wherein x is from about 4 to about 20 and m is from about 0 to about 6; and2) F(CF.sub.2).sub.x --SO.sub.2 N(R.sub.2)--R.sub.3 where x is a positive integer from about 4 to about 20, R.sub.2 is an alkyl radical of from about 1 to about 4 carbon atoms, R.sub.3 is an alkylene radical of from about 1 to about 12 carbon atoms; andR.sub.1 is an aliphatic hydrocarbon having from about 12 to about 76 carbon atoms; andprovided that said fluorochemical compound is other than perfluoroalkylethyl stearate; andmelt extruding the mixture.
    Type: Grant
    Filed: August 14, 1998
    Date of Patent: May 16, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Kimberly Gheysen Raiford, Theodor Arthur Liss, Edward James Greenwood
  • Patent number: 6054209
    Abstract: A tearable film comprising a resin blend which is: (1) a blend of a first polymer which is a styrenic polymer and a second polymer selected from the group consisting of a polyester and a polyamide; or (2) a first polymer which is a polyester and a second polymer selected from the group consisting of a polycarbonate, an acrylic polymer and a polyamide. The film has an continuous phase and a dispersed phase, thereby forming an islands-sea structure, wherein the continuous phase constitutes 35-98 wt % and the dispersed phase constitutes 2-65 wt % of the film.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: April 25, 2000
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Shinichiro Imanishi, Kenji Ueda, Katsuhiko Sumida
  • Patent number: 6048939
    Abstract: Processability of non-fluorinated melt-processible polymers is improved by introducing a process aid comprising a fluoroelastomer latex or aqueous fluoropolymer dispersion to the non-fluorinated polymer and extruding the blend.
    Type: Grant
    Filed: January 2, 1998
    Date of Patent: April 11, 2000
    Assignee: Dupont Dow Elastomers, L.L.C.
    Inventor: Donnan Edwin Priester
  • Patent number: 6027814
    Abstract: The invention relates to a composition including (i) at least one polyamide and at least one copolymer (A) of ethylene with at least one comonomer chosen from unsaturated carboxylic acids, esters of unsaturated carboxylic acids or vinyl esters of saturated carboxylic acids and (ii) being in powder form. These compositions are subsequently deposited on metal substrates and then a highly corrosion-resistant coating is obtained by melting.
    Type: Grant
    Filed: October 6, 1997
    Date of Patent: February 22, 2000
    Assignee: Elf Atochem S.A.
    Inventors: Olivier Julien, Michael Werth, Arnaud Tedoldi, Jean-Marc Sage
  • Patent number: 6020387
    Abstract: A low density polymer composition including a polymer component capable of being cured, a low density filler in an amount sufficient to reduce the density of the polymer and a thixotrope present in a sufficient amount to impart a sufficient viscosity and to inhibit separation of the filler from the polymer until after the polymer is cured. The resulting lightweight, filled polymer composition is a strong electrical insulator, has low shrinkage, a low coefficient of thermal expansion, low cured density and a soft filler that does not harden the polymer. Methods of preparing and using the low density polymer compositions are also disclosed.
    Type: Grant
    Filed: September 22, 1997
    Date of Patent: February 1, 2000
    Assignee: Caschem, Inc.
    Inventors: William J. Downey, Christopher Andreola, Paul R. Lydigsen, Wayne E. Wright
  • Patent number: 6013727
    Abstract: A thermoplastic composition which may be unvulcanized or vulcanized is provided which comprises a polymer blend of an elastomeric thermoplastic engineering resin and a halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene. A process for preparing a dynamically vulcanized composition is also provided.
    Type: Grant
    Filed: January 31, 1991
    Date of Patent: January 11, 2000
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Narayanaswami Raja Dharmarajan, Robert Chester Puydak, Hsien Chang Wang, Kenneth William Powers, Thomas Chen-Chi Yu, Donald Ross Hazelton
  • Patent number: 5989723
    Abstract: A conductive polyester-based alloy sheet having three layers laminated together by co-extrusion, which comprises one substrate layer and two surface layers, wherein the surface layers are conductive and comprise polyester, acrylonitrile-butadiene-styrene (abbreviated as ABS) and/or polystyrene (abbreviated as PS), a compatibilizer, and a toughening agent, wherein the surface layers have a surface conductivity of not more than 10.sup.8 ohms. The melt flow index of the material for the conductive layers during the extrusion step is not less than 5.0 g/min (loading, 10 Kg; temperature, 250.degree. C.). The substrate layer is made from acrylonitrile-butadiene-styrene and/or polystyrene.
    Type: Grant
    Filed: May 16, 1997
    Date of Patent: November 23, 1999
    Assignee: Far Eastern Textile Ltd.
    Inventors: Tsan Hung Tsai, Rong Shiun Pan, Cheng Chung Wu, Yuan Hwey Hsu, Jen Hao Wei, Shung Mine Hong
  • Patent number: 5985117
    Abstract: Ion-selective membranes are disclosed which are suitable for use in ion-selective sensors. The membranes include a mercuracarborand ionophore. Exemplary ion-selective membranes include Mercuracarborand-3 as the ionophore which is incorporated within a polymer matrix. The ion-selective membranes may be used in a wide variety of ion sensors including ion-selective membrane electrodes.
    Type: Grant
    Filed: December 29, 1997
    Date of Patent: November 16, 1999
    Assignee: The Regents of the University of California
    Inventors: Leonidas G. Bachas, M. Frederick Hawthorne, Ibrahim H. A. Badr
  • Patent number: 5981661
    Abstract: A flame retarded resin molding compositions with enhanced weatherable properties, which comprise a polyester and polycarbonate blend modified with an organopolysiloxane-polycarbonate and a glycidyl ester impact modifier for enhancing weatherablity and a flame retarding amount of a halogenated flame retardant.
    Type: Grant
    Filed: August 29, 1997
    Date of Patent: November 9, 1999
    Assignee: General Electric Company
    Inventors: Jun Liao, Luca Pietro Fontana, Kevin Mitchell Snow
  • Patent number: 5962131
    Abstract: Process for the production of preoriented filaments from polyester-based polymer mixtures by spinning the polymer mixtures with a draw-off speed v of at least 2500 m/min, a second amorphous, thermoplastically processable copolymer having a glass transition temperature of more than 100.degree. C. being added to the polyester, wherein the ratio of the melt viscosity of the copolymer to the melt viscosity of the polyester is 1:1 to 10:1, in that the amount of copolymer added to the polyester is at least 0.05 wt.
    Type: Grant
    Filed: August 5, 1998
    Date of Patent: October 5, 1999
    Assignee: Degussa Aktiengesellschaft
    Inventors: Helmut Schwind, Wolfgang Janas, Klaus Dorn, Peter Kempf, Dietmar Wandel, Joachim Cziollek, Ulrich Thiele, Alexander Klein, Heinz-Dieter Schumann
  • Patent number: 5955096
    Abstract: Methods and compositions are provided for enhancing the bioadhesive properties of polymers used in drug delivery systems. The bioadhesive properties of a polymer are enhanced by incorporating an anhydride oligomer into the polymer to enhance the ability of the polymer to adhere to a tissue surface such as a mucosal membrane. Anhydride oligomers which enhance the bioadhesive properties of a polymer include oligomers synthesized from dicarboxylic acid monomers, preferably those found in Krebs glycolysis cycle, especially fumaric acid. The oligomers can be incorporated within a wide range of polymers including proteins, polysaccharides and synthetic biocompatible polymers. In one embodiment, anhydride oligomers can be incorporated within polymers used to form or coat drug delivery systems, such as microspheres, which contain a drug or diagnostic agent. The oligomers can either be solubilized and blended with the polymer before manufacture or else used as a coating with polymers over existing systems.
    Type: Grant
    Filed: June 25, 1996
    Date of Patent: September 21, 1999
    Assignee: Brown University Research Foundation
    Inventors: Camila A. Santos, Jules S. Jacob, Benjamin A. Hertzog, Gerardo P. Carino, Edith Mathiowitz
  • Patent number: 5919864
    Abstract: A thermoplastic elastomer composition containing a thermoplastic resin component including 10 to 95% by weight of a polypropylene having a syndiotactic structure and an elastomer component and having a value of .alpha., defined as follows, of 1 or less:.alpha.=(.phi.d/.phi.m).times.(.eta.m/.eta.d)wherein the volume fraction of the thermoplastic resin component is .phi.m, the melt viscosity thereof at the mixing conditions is .eta.m and the volume fraction of the elastomer component is .phi.d, the melt viscosity thereof is .eta.d.
    Type: Grant
    Filed: March 6, 1998
    Date of Patent: July 6, 1999
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Jiro Watanabe, Osamu Ozawa, Noriaki Kuroda, Gou Kawaguchi
  • Patent number: 5898046
    Abstract: A composition having repellency to low surface tension fluids comprising a material prepared by forming a mixture of a polymer selected from the group consisting of polyolefin, polyamide, polyester, polyacrylate, and blends and copolymers thereof, and a fluorochemical compound comprising a fluorocarbon/hydrocarbon ester of the formulae:R.sub.f --O--C(O)--R.sub.1 or R.sub.f --C(O)--O--R.sub.1whereinR.sub.f is selected from the group consisting of:1) F(CF.sub.2).sub.x --(CH.sub.2).sub.m wherein x is from about 4 to about 20 and m is from about 0 to about 6; and2) F(CF.sub.2).sub.x --SO.sub.2 N(R.sub.2)--R.sub.3 where x is a positive integer from about 4 to about 20, R.sub.2 is an alkyl radical of from about 1 to about 4 carbon atoms, R.sub.3 is an alkylene radical of from about 1 to about 12 carbon atoms; andR.sub.1 is an aliphatic hydrocarbon having from about 12 to about 76 carbon atoms; andprovided that said fluorochemical compound is other than perfluoroalkylethyl stearate; andmelt extruding the mixture.
    Type: Grant
    Filed: October 7, 1997
    Date of Patent: April 27, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Kimberly Gheysen Raiford, Theodor Arthur Liss, Edward James Greenwood
  • Patent number: 5885718
    Abstract: A treating agent comprises a nitrile group-containing highly saturated polymer rubber latex (A) having an iodine value of 120 or less, a rubber latex (B) other than the highly saturated polymer rubber latex, and a water-soluble resorcinol/formaldehyde condensate in amounts of 15 to 80%, 5 to 70% and 2 to 15%, all by weight in terms of solids, respectively. A rubber-reinforcing fiber product is coated with the treating agent. A rubber article such as a toothed belt, a tire and the like is made using this rubber-reinforcing fiber product. The glass fiber product coated with the treating agent may be further coated with a halogen-containing polymer-based adhesive as a secondary treating agent. Thus, the treating agent exhibits a large bonding force between the reinforcing fiber product and a matrix. Even if the rubber article is repeatedly subjected to a flexing stress, the strength thereof cannot be reduced. A peel-off cannot occurs between the reinforcing fiber product and the rubber matrix.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: March 23, 1999
    Assignee: Nippon Glass Fiber Co., Ltd.
    Inventors: Akira Okamura, Masato Sekiguchi
  • Patent number: 5872192
    Abstract: Thermosetting powder coatings based on epoxide-containing acrylate copolymer resins are disclosed comprising:(A) an acrylate copolymer that contains glycidyl ether residues;(B) an aliphatic and/or cycloaliphatic polybasic acid and/or a polyol-modified anhydride of a polybasic acid and/or an amorphous or semi-crystalline carboxy-functional copolyester resin and/or a carboxy-functional acrylic resin;(C) and, optionally, fillers and/or pigments and/or additives wherein the acrylate copolymer (A) has a molecular weight (Mw) of 1,000 to 30,000 and a glass transition temperature of 20 to 120.degree. C. and is obtainable by, in a first step, preparing a hydroxyl-functional acrylate copolymer (D), which copolymer is then transformed into the acrylate copolymer (A), by reaction with epihaloalkanes. The aforementioned compositions can be processed further to give thermosetting powder coatings which can be applied to substrates such as metal to form protective coatings or films.
    Type: Grant
    Filed: August 11, 1997
    Date of Patent: February 16, 1999
    Assignee: EMS--Inventa AG
    Inventors: Andreas Kaplan, Rene Gisler, Albert Reich
  • Patent number: 5869574
    Abstract: A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150.degree. C. The present invention can provide a composition comprising various heat resisting thermoplastic resins and a fluorine-containing polymer having a functional group which is capable of developing an affinity with said resins and forming a uniform dispersion.
    Type: Grant
    Filed: April 17, 1997
    Date of Patent: February 9, 1999
    Assignee: Daikin Industries, Ltd.
    Inventors: Tetsuo Shimizu, Yoshihisa Yamamoto, Seitaro Yamaguchi, Nobuhiko Tsuda, Noriyasu Yamane, Takafumi Yamato, Masahiro Kumegawa, Takayuki Araki
  • Patent number: 5863986
    Abstract: Polymer alloy comprising a) one or more cycloolefin copolymers and b) one or more types of core-shell particles and c) one or more block copolymers.
    Type: Grant
    Filed: January 23, 1997
    Date of Patent: January 26, 1999
    Assignees: Ticona GmbH, Mitsui Petrochemical Industries, Ltd
    Inventors: Otto Herrmann-Schonherr, Frank Osan
  • Patent number: 5857926
    Abstract: Disclosed herein is a golf ball cover composition comprising a combination of ionomer, ethylene-propylene rubber, and copolymer formed from (a) an .alpha.-olefin having two to eight carbon atoms, (b) an unsaturated monomer of the acrylate ester class having from 1-21 carbon atoms, and (c) an acid which includes at least one member selected from the group consisting of .alpha., .beta.-ethylenically unsaturated mono- and dicarboxylic acids, the weight ratio of the ethylene-propylene rubber to copolymer of .alpha.-olefin, acrylate ester and acid being in the range of 25:75 to 75:25. The novel cover composition enables the production of a golf ball having a high coefficient of restitution and a very soft cover with excellent cut resistance.
    Type: Grant
    Filed: June 13, 1997
    Date of Patent: January 12, 1999
    Assignee: Lisco, Inc.
    Inventors: Michael J. Sullivan, Edward J. Kaltenbacher
  • Patent number: 5849847
    Abstract: Polyalkenylaromatic-polyethylene copolymers are prepared using protected functional organolithium initiators. Polymerization of an alkenylsubstituted aromatic monomer followed by ethylene, results in a protected functional block polystyrene-co-polyethylenyllithium. Termination with a functionalizing agent followed by deprotection produces polymeric products with high functionalization at the initiating chain-end and at least partial functionalization at the terminal chain-end.
    Type: Grant
    Filed: July 29, 1996
    Date of Patent: December 15, 1998
    Assignee: FMC Corporation
    Inventor: Roderic P. Quirk
  • Patent number: 5847042
    Abstract: A polyolefin resin composition of the present invention comprising 0.01 to 2.0 parts by weight of an anti-blocking agent per 100 parts by weight of a polyolefin resin, wherein said anti-blocking agent has substantially two or more maximum values in a weight-based particle size distribution and a difference between a particle diameter giving the largest maximum value and a particle diameter giving the smallest maximum value is not less than 3.0 .mu.m.
    Type: Grant
    Filed: September 18, 1995
    Date of Patent: December 8, 1998
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Satoru Hosoda, Satoru Koyama, Kenzo Chikanari
  • Patent number: 5846642
    Abstract: A polyester film for thermal lamination, comprising:a polyester A of 140.degree. to 245.degree. C. in melting point mainly composed of ethylene terephthalate and/or ethylene isophthalate, a thermoplastic elastomer mixed at a ratio by weight of 81:19 to 98:2 with the elastomer comprising particles having a particle size ratio of 2 to 100 is excellent not only in formability but also in act resistance and taste property, and hence ideal for application on to the inner faces of packages, containers, etc.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 8, 1998
    Assignee: Toray Industries, Inc.
    Inventors: Masahiro Kimura, Shiro Imai
  • Patent number: 5820780
    Abstract: The present invention provides a liquid crystal polyester resin composition, which is manufactured at low cost and has favorable gas barrier properties and improved impact resistance, vibration-damping properties, thin-wall properties (mechanical properties of thin-wall molded articles), and film-forming properties, while maintaining excellent heat resistance and mechanical properties of a liquid crystal polyester. A liquid crystal polyester resin composition of the invention includes 55.0 through 99.9 percent by weight of a liquid crystal polyester as a component (A) and 0.1 through 45.0 percent by weight of an epoxy group-containing ethylene copolymer as a component (B), wherein the component (B) includes: (a) 50 through 96.5 percent by weight of an ethylene unit; (b) 0.5 through 30 percent by weight of an unsaturated glycidyl carboxylate unit or an unsaturated glycidyl ether unit; and (c) 3 through 40 percent by weight of an ethylenically unsaturated ester compound unit.
    Type: Grant
    Filed: January 23, 1997
    Date of Patent: October 13, 1998
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Motonubu Furuta, Takanari Yamaguchi
  • Patent number: 5760131
    Abstract: Rigid-rod and segmented rigid-rod polymers, methods for preparing the polymers and useful articles incorporating the polymers are provided. The polymers incorporate rigid-rod backbones with pendant solubilizing groups attached thereto for rendering the polymers soluble.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: June 2, 1998
    Assignee: Maxdem Incorporated
    Inventors: Matthew Louis Marrocco, III, Robert R. Gagne, Mark Steven Trimmer
  • Patent number: 5750626
    Abstract: A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150.degree. C. The present invention can provide a composition comprising various heat resisting thermoplastic resins and a fluorine-containing polymer having a functional group which is capable of developing an affinity with said resins and forming a uniform dispersion.
    Type: Grant
    Filed: August 9, 1994
    Date of Patent: May 12, 1998
    Assignee: Daikin Industries, Ltd.
    Inventors: Tetsuo Shimizu, Yoshihisa Yamamoto, Seitaro Yamaguchi, Nobuhiko Tsuda, Noriyasu Yamane, Takafumi Yamato, Masahiro Kumegawa, Takayuki Araki
  • Patent number: 5744522
    Abstract: A low gloss coating composition having a 60.degree. gloss of less than about 60 which contains:a) a glycidyl group-containing acrylic copolymer;b) an aromatic polyester; andc) an isocyanurate curing agent having the formula: ##STR1## wherein R.sub.1 -R.sub.3 are independently selected from the group consisting of divalent alkylene groups of 1 to 18 carbon atoms and divalent groups of 3 to 21 carbon atoms and containing an ester linkage, and R.sub.4 -R.sub.6 are independently selected from the group consisting of H, organic salt groups, alkyl groups of 1 to 20 carbon atoms and C(O)R.sub.7 wherein R.sub.7 is an alkyl group of 1 to 22 carbon atoms.
    Type: Grant
    Filed: September 13, 1996
    Date of Patent: April 28, 1998
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Paul J. Prucnal, Szu-Ping Lu
  • Patent number: 5723537
    Abstract: Pigment pastes are produced by pasting or blending one or several pigments and/or fillers in a paste resin based on a polyester oligomer polyacrylate which is obtainable by radical polymerisation ofA) 80-50 wt % ofa) one or several hydroxyfunctional acrylic acid esters and/or methacrylic acid esters andb) one or several monofunctional ethylenically unsaturated acids, as well as, optionally,c) one or several alpha,beta-ethylenically unsaturated monomers without functional groups inB) 20-50 wt % of one or several hydroxyfunctional polyester oligomers with a calculated molecular weight of 200-1000, a hydroxy number of 280-600 and an acid number of 0-1.5, obtainable by polycondensation of one or several diols, polyols and dicarboxylic acids and derivatives thereof,whereby the monomers a), b) and c) are used in such quantities as to ensure that the polyester oligomer polyacrylate obtained has a hydroxyl number of 150-390 and an acid number of 16-40.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: March 3, 1998
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Gerda Bajorat, Claudia Hamel, Hartmut Kern
  • Patent number: 5717035
    Abstract: There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of a polymerized conjugated diene of at least 5 carbon atoms, such as isoprene, and B is a block of a polymer of a conjugated diene, different from that of formula (1), of at least 4 carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from an aryl-substituted olefin, such as styrene, and the conjugated diene used to polymerize the block I, the second middle polymer block of the diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block.
    Type: Grant
    Filed: October 22, 1996
    Date of Patent: February 10, 1998
    Assignee: Mobil Oil Corporation
    Inventors: Thomas S. Coolbaugh, Frederick C. Loveless, Demetreos N. Matthews
  • Patent number: 5717032
    Abstract: A filming composition comprises an acryl emulsion having a molecular weight of 1.5.about.2.5 million and a decomposition starting temperature of 200.degree..about.250.degree. C., as a main component. The composition has a tendency to decompose at low temperature and can be completely decomposed and removed during frit sealing, without the need for separate baking or complex equipment. A screen having good characteristics can be obtained through an advantageous method.
    Type: Grant
    Filed: March 10, 1995
    Date of Patent: February 10, 1998
    Assignee: Samsung Display Devices Co., Ltd.
    Inventors: Hyeon-sang Kim, Jong-ho Oh
  • Patent number: 5710213
    Abstract: Novel functionalized peroxides which may be used as crosslinking, grafting and curing agents, initiators for polymerization reactions and as monomers for condensation polymerizations to form peroxy-containing polymers, which in turn can be used to prepare block and graft copolymers, have the following Formula I: ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, X, Y.sup.1, Y.sup.2, Y.sup.3, Z.sup.1, Z.sup.2, x, y and z are as defined in the Summary of the Invention. The compounds of Formula I may be prepared by reacting hydroxy-containing tertiary hydroperoxides with diacid halides, phosgene, dichloroformates, diisocyanates, anhydrides and lactones to form the functionalized peroxides. These reaction products may be further reacted, if desired, with dialcohols, diamines, aminoalcohols, epoxides, epoxy alcohols, epoxy amines, diacid halides, dichloroformates and diisocyanates to form additional functionalized peroxides.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: January 20, 1998
    Assignee: Elf Atochem North America, Inc.
    Inventor: Daryl L. Stein
  • Patent number: 5710210
    Abstract: Novel functionalized peroxides which may be used as crosslinking, grafting and curing agents, initiators for polymerization reactions and as monomers for condensation polymerizations to form peroxy-containing polymers, which in turn can be used to prepare block and graft copolymers, have the following Formula I: ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, X, Y.sup.1, Y.sup.2, Y.sup.3, Z.sup.1, Z.sup.2, x, y and z are as defined in the Summary of the Invention. The compounds of Formula I may be prepared by reacting hydroxy-containing tertiary hydroperoxides with diacid halides, phosgene, dichloroformates, diisocyanates, anhydrides and lactones to form the functionalized peroxides. These reaction products may be further reacted, if desired, with dialcohols, diamines, aminoalcohols, epoxides, epoxy alcohols, epoxy amines, diacid halides, dichloroformates and diisocyanates to form additional functionalized peroxides.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: January 20, 1998
    Assignee: Elf Atochem North America, Inc.
    Inventor: Daryl L. Stein
  • Patent number: 5700885
    Abstract: An extruder screw having a plurality of plasticating sections sufficient for plasticating polymeric materials of different bulk density.
    Type: Grant
    Filed: October 27, 1995
    Date of Patent: December 23, 1997
    Assignee: The Dow Chemical Company
    Inventors: Hoang T. Pham, Chad A. Strait, Richard O. Kirk
  • Patent number: 5698657
    Abstract: Flexible epoxy resins are made by curing the epoxy with an amine curing agent in the presence of a low molecular weight acrylate copolymer made from a major amount of a lower aliphatic ester or amide of acrylic or methacrylic acid and a minor amount of an ethylenically unsaturated monomer having functionality reactive with functional groups present in the epoxy resin or its curing agent. The acrylate copolymer has a number average molecular weight in the range of 1000 to 6000, preferably 2000 to 3000, and a ratio of weight average to number average molecular weight in the range of 1 to 3.5. Copolymers of butylacrylate and acrylic acid or maleic anhydride are favored. Further advantages are realized by including in the cure formulation a monofunctional diluent reactive with the curative.
    Type: Grant
    Filed: August 3, 1995
    Date of Patent: December 16, 1997
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Mark David Conner, Richard Henry Bott, William Edward Starner, Lloyd Mahlon Robeson
  • Patent number: 5684089
    Abstract: A pregellable adhesive containing several polymers, of which at least one is olefinically unsaturated and the other capable of curing by esterification, prepared in such a way that it cures by two different chemical reaction mechanisms which can be activated successively and catalyzed at least substantially independently of one another.
    Type: Grant
    Filed: December 13, 1996
    Date of Patent: November 4, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Thierry Lanoye, Anne-Marie Garnault
  • Patent number: 5683819
    Abstract: A composite comprised of a nitrile group-containing highly saturated copolymer rubber and a fibrous material, which copolymer rubber is a product obtained by hydrogenating the conjugated diene portion of an unsaturated nitrile-conjugated diene copolymer. The highly saturated copolymer rubber has an alkylthio group having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and having a sulfur atom which is directly bound to at least one of the tertiary carbon atoms; and the copolymer rubber further has a Mooney viscosity of 15 to 200 and an iodine value not larger than 80. This composite is useful for a belt.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: November 4, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Osamu Mori, Mitsugu Ishihara, Motofumi Oyama
  • Patent number: 5681889
    Abstract: The present invention provides hydrophilic crosslinked polymer fine particles made of a copolymer composed of:2-50% by weight of (a) a monoethylenic monomer having a polyoxyalkylene or polyvinylpyrrolidone chain,20-97% by weight of (b) a (meth)acrylamide type monoethylenic monomer,1-30% by weight of (c) a crosslinkable unsaturated monomer selected from the group consisting of compounds having, in the molecule, at least two polymerizable double bonds, and compounds having, in the molecule, at least one functional group selected from hydrolyzable silyl groups and 1,2-epoxy groups and one polymerizable double bond, and0-50% by weight of (d) other monoethylenic monomer. Said polymer fine particles are superior in polymerization stability as well as in dispersion stability during storage, undergoes no adverse effect by dispersion stabilizer owing to no use of said stabilizer, and are suitably used for formation of a hydrophilic film.
    Type: Grant
    Filed: December 15, 1995
    Date of Patent: October 28, 1997
    Assignee: Kansai Paint Co., Ltd
    Inventors: Masahiro Kondo, Hiroshi Inoue
  • Patent number: 5670263
    Abstract: Rubber articles e.g. rubber latex gloves have an adherent anti-tack coating comprising a mixture of a) a carboxylated synthetic rubber latex having a minimum film forming temperature (MFFT) of 10.degree. C. or above, with b) a latex polymer having an MFFT below 10.degree. C. and/or c) a water-soluble organic polymeric hydroxy material. Component b) tends to confer non-slip properties while component c) tends to confer lubricating properties.
    Type: Grant
    Filed: March 21, 1995
    Date of Patent: September 23, 1997
    Assignee: Tun Abdul Razak Research Centre
    Inventor: Keith Frederick Gazeley
  • Patent number: 5663240
    Abstract: A powder coating composition comprises (a) from 60-90 percent by weight of an epoxy functional copolymer having a Tg of from 25.degree.-70.degree. C. formed by polymerizing from 50-75 percent by weight of a glycidyl functional monomer and from 35-50 percent by weight of a monomer free of glycidyl functionality, and (b) from 10-40 percent by weight of a polycarboxylic acid crosslinking agent, wherein the ratio of epoxy:acid functionality is about 1:0.8 to 1.
    Type: Grant
    Filed: March 14, 1996
    Date of Patent: September 2, 1997
    Assignee: PPG Industries, Inc.
    Inventors: Robert L. Simeone, Robert D. Lippert, James B. O'Dwyer, Charles M. Kania
  • Patent number: 5660931
    Abstract: A biaxilly oriented polymer film having improved surface properties, anti-static property and printability is prepared from a mixture of 70 to 99 parts by weight of a polyester resin containing not less than 60% by weight of repeating units of ethylene terephthalate and having an intrinsic viscosity ranging from 0.4 to 0.9 dl/g, and 1 to 30 parts by weight of polyolefin resin having a melting flow index ranging from 1.5 to 25 g/10 min, wherein said polyester film further comprises 0.1 to 25 parts by weight of an inorganic particle.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: August 26, 1997
    Assignee: SKC Limited
    Inventors: Moon-Sun Kim, Sang-Il Kim, Young-Jin Lee, Bum-Sang Kim, Ju-Ik Son
  • Patent number: 5652326
    Abstract: A polyetheresteramide having good heat resistance, permanent antistatic property and superior compatibility with thermoplastic resins and a resin composition containing of the polyetheresteramide are disclosed, wherein the polyetherester-amide consists essentially of a polyamide oligomer with carboxylic chain ends having a number average molecular weight between 200 and 5,000 and a bisphenol compound with oxyalkylene units having a number average molecular weight between 300 and 3,000. Antistatic resin compositions with good antistatic property and heat resistance are obtained from compositions comprising 3 to 40% by weight of the polyetheresteramide and 60 to 97% by weight of thermoplastic resins. The antistatic resin compositions can contain as compatibilizers vinyl polymers having functional groups such as carboxyl and epoxy groups or block polymers containing polyolefin blocks and aromatic vinyl polymer blocks.
    Type: Grant
    Filed: March 1, 1994
    Date of Patent: July 29, 1997
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Yasuhiro Ueda, Eiichi Senda, Yoshitsugu Takai, Tokiko Kokubu, Toshiaki Okamoto, Eiji Ichihara
  • Patent number: 5643991
    Abstract: This invention relates to a blend comprising:(a) one or more substantially amorphous copolyester resins having a degree of crystallinity of less than 20 percent;(b) from about 5 to about 25 weight percent carbon black; and(c) from about 7 to about 30 weight percent of an impact modifier,wherein the total of the weight percentages of (a), (b), and (c) equal 100 percent.This invention is advantageous in that it provides the advantages of good electroconductivity, lack of brittleness, ability to thermoform into desired shapes, good impact strength, good sealing characteristics and acceptable environmental image.
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: July 1, 1997
    Assignee: Eastman Chemical Company
    Inventors: Candace Michele Stipe, Scott Arnold Hanson, Richard Leon McConnell
  • Patent number: 5641549
    Abstract: This invention is a composition, a kit to prepare the composition, cellular sheet made from the composition and thermoformed articles made from the sheet, in which the composition comprises polyethylene terephthalate, sufficient inert gas to give a sheet density of 0.4 to 1.25 gm/cc, a polytetrafluoroethylene nucleating agent and optionally a polyolefin additive and a heat stabilizer.
    Type: Grant
    Filed: December 14, 1995
    Date of Patent: June 24, 1997
    Assignee: Shell Oil Company
    Inventors: Walter Francis Johnston, Donald Edward Richeson, William George Perkins
  • Patent number: 5639827
    Abstract: Allyl ester copolymers with allylic alcohols and propoxylated allylic alcohols are disclosed. The high primary hydroxyl group content and favorable solubility characteristics make the allyl ester copolymers easy to formulate into many polymer products, including polyurethanes, polyesters, melamines, alkyds, uralkyds, and crosslinked polymeric resins.
    Type: Grant
    Filed: September 13, 1996
    Date of Patent: June 17, 1997
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Shao-Hua Guo
  • Patent number: 5633079
    Abstract: A hard coat film having an easily slipping property which comprises a plastic film and a hard coating layer of 1 to 15 .mu.m thickness made from an ultraviolet curable resin on the plastic film, wherein the hard coating layer contains particles of a high molecular weight polyester resin dispersed therein and the surface of the hard coating layer is provided with 3 to 200 protrusions of a diameter of 0.05 to 3 .mu.m and a height of 0.01 to 2 .mu.m per 100 .mu.m.sup.2 of the surface, and a process for producing the hard coat film. The hard coat film has a low haze value, a good transparency, an excellent resistance to scratch, a low kinematic friction coefficient, and an excellent slipping property both between coated surfaces and between a coated surface and a surface having no treatment.
    Type: Grant
    Filed: March 6, 1995
    Date of Patent: May 27, 1997
    Assignee: Lintec Corporation
    Inventors: Satoru Shoshi, Shunpei Watanabe, Takanori Saito
  • Patent number: 5597651
    Abstract: Multi-component composites containing a linear polyester of an alkyl glycol and an aromatic diacid as one component, rubber as a second component, and a third component which is a compatibilizing polyester (polystyrene copolymer).
    Type: Grant
    Filed: October 26, 1995
    Date of Patent: January 28, 1997
    Assignee: Hoechst Celanese Corp.
    Inventors: Eui W. Choe, Charles E. Forbes, Jennifer A. Filbey, Stephan F. Sherriff
  • Patent number: 5587428
    Abstract: This invention relates to a polymeric vehicle which reduces or eliminates VOCs in coating compositions by providing a formulated coating composition which does not require an organic solvent for application to a substrate. The polymeric vehicle of the invention comprises at least one linear oligoester diol effective for crosslinking with a crosslinker, and having a number average molecular weight within controlled limits of a polydispersity index effective for controlling the viscosity of the polymeric vehicle.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 24, 1996
    Assignee: Eastern Michigan University
    Inventors: Frank N. Jones, Shou-Kuan Fu, Jun Hua, Xiaoying Yuan
  • Patent number: 5569714
    Abstract: Allyl ester copolymers with allylic alcohols and propoxylated allylic alcohols are disclosed. The high primary hydroxyl group content and favorable solubility characteristics make the allyl ester copolymers easy to formulate into many polymer products, including polyurethanes, polyesters, melamines, alkyds, uralkyds, and crosslinked polymeric resins.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: October 29, 1996
    Assignee: Arco Chemical Technology, L.P.
    Inventor: Shao-Hua Guo
  • Patent number: 5567770
    Abstract: This invention relates to liquid crystalline polymers, having a glass transition temperature of greater than 140.degree. C., blended with tetrafluoroethylene polymers, said blends having improved wear properties.
    Type: Grant
    Filed: May 17, 1994
    Date of Patent: October 22, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Robert R. Luise
  • Patent number: 5552488
    Abstract: In a process for crosslinking a polymer, a .beta.-dicarbonyl functionality is present as a reactive diluent and/or as a reactive solvent and/or on a crosslinking entity. The .beta.-difunctional compound reacts with formaldehyde which is either released during the crosslinking reaction (or otherwise present) whereby less formaldehyde is released, than would otherwise be released. The formaldehyde which reacts with the .beta.-dicarbonyl compound is either incorporated into the crosslinked polymer network or released in the form of a reaction product which is not as harmful to the environment as the unreacted formaldehyde. The process enables the reduction of formaldehyde release during crosslinking to levels otherwise unobtainable. Furthermore, the process enables a reduction in the amount of organic solvent utilized.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: September 3, 1996
    Assignee: BASF Corporation
    Inventors: Christopher J. Bradford, Adriana Ticu
  • Patent number: 5545475
    Abstract: A porous composite sheet is prepared from a mixture of polytetrafluoroethylene particulates and liquid crystal polymer particulates. The liquid crystal polymer in the porous composite sheet can be in the form of particulates contained within a polytetrafluoroethylene microstructure, or formed into a network of liquid crystal polymer fibers contained within and attached to the polytetrafluoroethylene microstructure. The porous composite sheet can be used as a self-reinforced porous sheet, for example, as a filter media. The pores of the composite sheet can be at least partially filled with polymeric resins and the composite sheet laminated to form useful electronic assemblies such as printed circuit boards and the like.
    Type: Grant
    Filed: July 5, 1995
    Date of Patent: August 13, 1996
    Assignee: W. L. Gore & Associates
    Inventor: Joseph E. Korleski