With Polycarboxylic Acid Or Derivative And A Polyol At Least One Of Which Is Saturated, A Condensate Or Solid Polymer Thereof; Or With Solid Polymer Derived From At Least One Polycarboxylic Acid Or Derivative And At Least One Polyol Wherein At Least One The Reactants Forming The Solid Polymer Is Saturated Patents (Class 525/165)
  • Publication number: 20040116645
    Abstract: Coating compositions comprising:
    Type: Application
    Filed: September 25, 2003
    Publication date: June 17, 2004
    Inventors: Jos Huybrechts, Ann Vaes, Lieve Bastin, Leen Tanghe
  • Publication number: 20040110899
    Abstract: A resin composition has 60 to 85% by weight of a polystyrene resin, and 15 to 40% by weight of a polyether ester amide. The polystyrene resin is a copolymer comprising a styrene monomer and a (meth)acrylate monomer.
    Type: Application
    Filed: October 3, 2003
    Publication date: June 10, 2004
    Inventors: Naoya Miara, Nobuyasu Suzuki, Masahiko Kawano
  • Publication number: 20040110890
    Abstract: Polyester compositions which contain a copolymer of ethylene, an acrylate ester, and a fibrous filler having a relatively small diameter are particularly suitable for parts whose surface appearance is important, such as appliance panels and automobile body panels. The compositions have good toughness and an otherwise excellent balance of other physical properties.
    Type: Application
    Filed: August 26, 2003
    Publication date: June 10, 2004
    Inventor: Claire Brissot
  • Publication number: 20040106734
    Abstract: Polymer compositions comprising poly-glycolic acid (PGA) or a functional derivative thereof with a tensile strength of at least 1200 MPa are disclosed. Processes suitable for manufacturing said compositions are also described, comprising rendering PGA into an amorphous state then drawing to form a highly orientated polymer structure. The polymer compositions can be used to make artefacts, for example sutures, or used in combination with other polymers or non-polymeric substances to produce other artefacts, for example medical devices suitable for implantation into the human body. Processes for the production of said artefacts are also described.
    Type: Application
    Filed: September 25, 2003
    Publication date: June 3, 2004
    Inventor: John Rose
  • Publication number: 20040054084
    Abstract: A thermoplastic resin composition material 1 includes a resin portion (a) 2 made of a thermoplastic resin (A); elastomer portions (b) 3 made of a thermoplastic elastomer (B) having substantially no compatibility with the thermoplastic resin (A) and having a glass transition temperature of lower than or equal to −40° C.; and polymer portions (c) 4 made of a high polymer (C) having substantially no compatibility with the thermoplastic resin (A) and the thermoplastic elastomer (B), having a glass transition temperature or crystallization temperature of lower than or equal to −50° C., and having a viscosity at 40° C. of 0.1 to 200000 cP. The material has a structure in which the elastomer portions (b) 3 are dispersed in the resin portion (a) 2, and the polymer portions (c) 4 are dispersed in the elastomer portions (b) 3.
    Type: Application
    Filed: July 3, 2003
    Publication date: March 18, 2004
    Inventors: Naoki Wakita, Hiroaki Arita
  • Patent number: 6706824
    Abstract: By heating at above the melting point and/or glass transition point of the polycondensate and adding an aromatic dicyanate; or adding a mixture comprising an aromatic dicyanate and a polyfunctional compound selected from the class of sterically hindered hydroxyphenyl-alkyl-phosphonic esters and monoesters, diphosphonites and secondary aromatic amines; or adding a mixture comprising (i) an aromatic dicyanate, (ii) at least one polyfunctional compound selected from the class of sterically hindered hydroxyphenyl-alkyl-phosphonic esters and monoesters, diphosphonites and secondary amines, and (iii) a difunctional epoxide, it is possible to bring about an increase in the molecular weight and/or viscosity of virgin polycondensate and polycondensate recyclates.
    Type: Grant
    Filed: November 1, 2000
    Date of Patent: March 16, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rudolf Pfaendner, Kurt Hoffmann, Heinz Herbst
  • Patent number: 6703446
    Abstract: Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x  (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylam
    Type: Grant
    Filed: June 21, 2002
    Date of Patent: March 9, 2004
    Assignee: FMC Corporation, Lithium Division
    Inventors: James A. Schwindeman, Robert J. Letchford, Conrad W. Kamienski, Roderic P. Quirk
  • Patent number: 6699939
    Abstract: Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x  (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylam
    Type: Grant
    Filed: June 21, 2002
    Date of Patent: March 2, 2004
    Assignee: FMC Corporation, Lithium Division
    Inventors: James A. Schwindeman, Robert J. Letchford, Conrad W. Kamienski, Roderic P. Quirk
  • Publication number: 20040028909
    Abstract: A synthetic composition is described including (i) a clear thermosetting resin selected from the group consisting of unsaturated polyester resins and vinyl functional monomers and oligomers; (ii) at least one metal complex promotor; (iii) at least one UV stabiliser, and (iv) an aliphatic and/or aromatic polyallyl ether pendant monomer or polymer; or (v) a soluble clear thermoplastic resin and/or a wax; or a combination of (iv) and (v). The synthetic composition can be applied to a substrate. A suitable organic peroxide is suitably added prior to or after application to the substrate to facilitate the curing reactions. A primer or build coat may also be present under the synthetic composition.
    Type: Application
    Filed: July 22, 2003
    Publication date: February 12, 2004
    Inventors: Peter Clifford Hodgson, Keith Cyrus Stanistreet
  • Publication number: 20040024119
    Abstract: The invention generally relates to thermoplastic blends having improved properties. Optionally, these blends may be dynamically vulcanized. More specifically, this invention is directed to a composition comprising a blend of chloromethylated(styrene-isobutylene) polymer and a thermoplastic resin selected from the group consisting of polyamides, polyesters, polycarbonates, polysulfones, polyacetals, polyacetones, acrylonitrile-butadiene styrene resins, polyphenylene oxide, polyphenylene sulfide, styrene-acrylonitrile resins, styrene-maleic anhydride resins, polyamides, aromatic polyketones, ethylene vinyl alcohol polymer and mixtures thereof. Tires and tire components such as air permeation prevention films comprising these compositions are also provided.
    Type: Application
    Filed: July 3, 2003
    Publication date: February 5, 2004
    Inventor: Hsien-Chang Wang
  • Patent number: 6673454
    Abstract: To provide the thermosetting powder coating composition which comprises a fluorine-containing copolymer having crosslinkable functional group and a curing agent, in which the fluorine-containing copolymer has a fluoroolefin unit, has a fluorine content of not less than 10% by weight and is not dissolved in tetrahydrofuran substantially. A coating line can be shared with other powder coating composition because even when the composition mixes to other powder coating composition, it causes no coating defects, and yet a coated article having a coating film excellent in physical properties can be provided.
    Type: Grant
    Filed: May 10, 2001
    Date of Patent: January 6, 2004
    Assignee: Daikin Industries, Ltd.
    Inventors: Nobuhiko Tsuda, Takahiro Kitahara, Ryuji Iwakiri, Masaru Nagato, Ryoichi Fukagawa, Go Nagai
  • Patent number: 6664366
    Abstract: Thermally stable polymers comprising chain members derived from at least one 1,3-dihydroxybenzene moiety and at least one aromatic dicarboxylic acid moiety, said polymer being substantially free of anhydride linkages linking at least two mers of the polymer chain, are prepared using an interfacial method comprising the steps of: (a) combining at least one 1,3-dihydroxybenzene moiety and at least one catalyst in a mixture of water and at least one organic solvent substantially immiscible with water; (b) adding to the mixture from (a) a controlled stoichiometric ratio of at least one acid chloride and at least one base while maintaining the pH between about 4 and about 8.5, and (c) adjusting the pH of the reaction mixture to a value in the range of about 7 and about 9 following complete addition of acid chloride, and stirring the reaction mixture for a time sufficient to destroy any anhydride linkages in the polymer chain.
    Type: Grant
    Filed: March 25, 2002
    Date of Patent: December 16, 2003
    Assignee: General Electric Company
    Inventors: James Manio Silva, David Michel Dardaris, Gregory Allen O'Neil, Joseph Anthony Suriano
  • Patent number: 6663962
    Abstract: For the preparation of powders formed of copolyesteramides by anionic polymerization, at least one lactam and at least one lactone are copolymerized in solution in a solvent in the presence of a catalyst and of an activator, the solvent being a solvent of the lactam and the powders being insoluble in the solvent. Preferably at least two lactams and at least one lactone are copolymerized, and the copolymerization is preferably carried out in the presence of a finely divided organic or inorganic filler. The copolymerization is preferably carried out in the presence of an N,N′-alkylenebisamide, such as ethylenebisstearamide (EBS) disclosed in EP 192 515, or generally amides of formula R1-NH—CO—R2, in which R1 can be replaced by an R3-CO—NH— or R3-O— radical and in which R1, R2 and R3 denote an aryl, alkyl or cycloalkyl radical.
    Type: Grant
    Filed: July 11, 2001
    Date of Patent: December 16, 2003
    Assignee: Atofina
    Inventors: Christophe Le Crom, Roland Guerin
  • Publication number: 20030229191
    Abstract: A polymeric sorbent that can be employed in the extraction and purification of polar and nonpolar molecules from a complex media (e.g. pharmaceuticals from biological matrices) by solid phase extraction (SPE). The sorbent exhibits a strong capacity for the retention of polar molecules and can facilitate the recovery of compounds possessing a range of polarities while furnishing clean extracts showing low ion suppression. The polymer is wettable and remains wetted over long periods of time.
    Type: Application
    Filed: September 23, 2002
    Publication date: December 11, 2003
    Inventors: Krishna M.R. Kallury, David C. Jones, Vipul J. Shah
  • Patent number: 6660398
    Abstract: The invention concerns powder thermosetting coating compositions comprising (a) an amorphous polyester containing carboxyl groups, rich in isophthalic acid and neopentylglycol, optionally branched with a polycarboxylic acid or a polyol containing at least three functional groups; (b) a semicrystalline polyester containing carboxyl groups prepared from one or several saturated aliphatic dicarboxylic acids with linear chain, and from a saturated aliphatic diol with linear or cyclic chain optionally branched with a polycarboxylic acid or with a polyol containing at least three functional groups, and having a melting point (Tm) of at least 40° C. and an acid value of 5 to 50 mg of KOH/g, and (c) a cross-linking agent. Said compositions are useful for preparing powder paints and varnishes providing excellent quality coatings whereof the brilliance, measured at an angle of 60°, according to the ASTM D 523 standard is always less than 50%, that is half-gloss or matt coatings.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: December 9, 2003
    Assignee: UCB, S.A.
    Inventors: Luc Moens, Kris Buysens, Daniel Maetens
  • Publication number: 20030225216
    Abstract: The present invention provides a water dispersed resin composition for flocking that is capable of flocking piles on polyolefin substrates without performing a primer treatment. The water dispersed resin composition has been improved in at least one property selected from the coatability of the resin composition, the adhesion between a coating formed therefrom and a substrate, the abrasion resistance of a flocked film formed therewith and the pile retention of the coating. The water dispersed resin composition for flocking comprises a resin composition comprising a copolymer obtained by polymerizing a monomer mixture comprising: component (A): CH2═C(R1)—COO—R2, wherein R1 is a hydrogen atom or a methyl group, R2 is a monocyclic alkyl group; and other unsaturated monomers; and component (B): a resin composition of chlorinated polyolefin.
    Type: Application
    Filed: April 2, 2003
    Publication date: December 4, 2003
    Inventor: Mitsuo Satoh
  • Publication number: 20030225217
    Abstract: Disclosed is a thermosetting powder coating composition comprising (A) a glycidyl group-containing acrylic resin obtained by (co)polymerizing monomers containing an ethylenically unsaturated monomer having a glycidyl group and/or a &bgr;-methylglycidyl group, (B) a polycarboxyl curative, and (C) an alcohol adduct of a styrene/maleic anhydride copolymer. Also disclosed are a cross-linked cured film of the composition and a process for preparing the composition. According to the invention, blending efficiency and dispersibility of the components of a powder coating, particularly those between the resin component and the curative component, are improved without changing a conventional production process of a powder coating, i.e., a process consisting of melt blending, cooling solidification, pulverization and sieving, and thereby a thermosetting powder coating composition, which is capable of forming a cross-linked cured film improved in appearance properties (high gloss, etc.
    Type: Application
    Filed: May 28, 2003
    Publication date: December 4, 2003
    Applicant: Mitsui Chemical, Inc.
    Inventors: Mitsuyuki Mizoguchi, Yoshiharu Hirose
  • Patent number: 6656981
    Abstract: The present invention provides a method for reducing dust deposits on polyolefin films. Further subjects of the invention are the use of a polyetheresteramide for reducing dust deposits on polyolefin films and coextruded multilayer polyolefin films containing a polyetheresteramide at least in one outer layer.
    Type: Grant
    Filed: August 27, 2001
    Date of Patent: December 2, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Nicola Lelli, Nadi Ergenc
  • Publication number: 20030207995
    Abstract: A toner additive comprising a polymer of at least one monomer selected from the group consisting of vinyltoluene, a-methyl styrene and isopropenyl toluene, which has a ring and ball softening point of 130-170° C., or a copolymer of styrene and at least one kind of monomer selected from the above group which has a ring and ball softening point of 110-170° C. By adding such toner additive to a toner, an electrostatic image developing toner which has excellent pulverizability in the pulverizing process and does not fuse to equipment can be obtained. In addition, such toner additive does not affect the fundamental performances of a toner such as electrostatic performance, fixing performance, color, etc. Therefore, an electrostatic image developing toner and electrostatic image developer capable of producing a high quality image can be obtained at a low cost.
    Type: Application
    Filed: May 30, 2003
    Publication date: November 6, 2003
    Applicant: Mitsui Chemicals, Inc.
    Inventor: Taiji Kameoka
  • Patent number: 6642310
    Abstract: Extrusion processability of non-fluorinated melt-processable polymers is improved by introducing a fluoropolymer process aid by means whereby the weight average particle size of the fluoropolymer is greater than 2 microns as it reaches the extruder die entrance.
    Type: Grant
    Filed: September 17, 2001
    Date of Patent: November 4, 2003
    Assignee: DuPont Dow Elastomers L.L.C.
    Inventors: George Richard Chapman, Jr., Steven Richard Oriani
  • Patent number: 6641924
    Abstract: The present invention relates to a white, biaxially oriented polyester film having at least a base layer, the characterizing features of which are that at least this base layer comprises a cycloolefin copolymer (COC) at a concentration of from 4 to 60% by weight, based on the base layer, where the glass transition temperature of cycloolefin copolymer (COC) is within the range from 70 to 270° C.
    Type: Grant
    Filed: October 19, 1999
    Date of Patent: November 4, 2003
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Gottfried Hilkert
  • Publication number: 20030181590
    Abstract: A nonaqueous coating material curable thermally or thermally and with actinic radiation, comprising
    Type: Application
    Filed: February 28, 2003
    Publication date: September 25, 2003
    Inventors: Bernhard Lettmann, Harald Borgholte, Marion Fischer
  • Publication number: 20030166778
    Abstract: The invention concerns a micro-composite polymer/polymer material comprising 25 to 35 wt. % of a semicrystalline polymer (I), forming a dispersed phase localised inside a thermoplastic or elastomeric polymer (II) forming a matrix, the temperature of crystallisation of the polymer forming a dispersed phase being higher by at least 20° C. than the melting or softening point of polymer (II) forming the matrix, and the dispersed phase of said material having specifically a morphology such that it induces crosslinking of the continuous phase.
    Type: Application
    Filed: March 12, 2003
    Publication date: September 4, 2003
    Inventors: Philippe Cassagnau, Alain Michel
  • Patent number: 6596843
    Abstract: Thermally stable polymers comprising resorcinol arylate chain members are prepared using an interfacial method comprising the steps of: interfacial method for preparing polymers comprising resorcinol arylate polyester chain members substantially free of anhydride linkages linking at least two mers of the polymer chain, comprising the steps of: (a) preparing an aqueous solution comprising at least one resorcinol moiety, said solution having a pH less than or equal to about 5; (b) after step (a), preparing a mixture comprising the resorcinol moiety, at least one catalyst and at least one organic solvent substantially immiscible with water; and (c) adding to the mixture from (b) at least one dicarboxylic acid dichloride while maintaining the pH between 3 and 8.5 through the presence of an acid acceptor, wherein the total molar amount of acid chloride groups is stoichiometrically deficient relative to the total molar amount of phenolic groups.
    Type: Grant
    Filed: September 28, 2001
    Date of Patent: July 22, 2003
    Assignee: General Electric Company
    Inventors: Daniel Joseph Brunelle, Paul Dean Sybert, Gregory Allen O'Neil, Joseph Anthony Suriano, Tiberiu Mircea Siclovan, Zhaohui Su
  • Publication number: 20030134978
    Abstract: A powder coating composition includes an acid-functional polyester resin and a matting agent selected from styrene-maleic anhydride copolymers and acid-functional acrylic resins. The compositions provide low gloss finishes at low curing temperatures, as well as consistent gloss over a wide range of curing temperatures.
    Type: Application
    Filed: October 9, 2002
    Publication date: July 17, 2003
    Inventors: Tina L. Tullos, Brian T. Myers, Charles P. Tarnoski
  • Patent number: 6586527
    Abstract: Polyester molding compositions, which have improved crystallization and processing, a cycloaliphatic polyester component, and a nucleating agent comprising a fluoropolymer containing a thermoplastic resin.
    Type: Grant
    Filed: March 20, 2001
    Date of Patent: July 1, 2003
    Assignee: General Electric Company
    Inventors: Peter Hendrikus Theodurus Vollenberg, Gerardus Bernardus Wilhelmus Hieltjes, Franciscus Petrus Maria Mercx, Aagje Petronella den Breejen
  • Publication number: 20030119959
    Abstract: An object of the present invention is to provide a softening agent for a thermoplastic resin that gives flexibility, impact-resistance, etc. to a thermoplastic resin.
    Type: Application
    Filed: November 1, 2002
    Publication date: June 26, 2003
    Applicant: Kyowa Yuka Co., Ltd.
    Inventors: Toshihiro Inayama, Shigeru Murata, Tatsuo Niimi
  • Publication number: 20030088026
    Abstract: The present invention relates to a thermoplastic resin composition which has an improved impact resistance while maintaining mechanical properties such as strength and rigidity. In the present invention, a thermoplastic resin (A) is mixed with a polytetrafluoroethylene-containing mixed powder (B) consisting of a polytetrafluoroethylene (b1) having a particle diameter of 10 &mgr;m or less and an organic polymer (b2). In this case, the polytetrafluoroethylene-containing mixed powder (B) is mixed so that the amount of a polytetrafluoroethylene component is from 0.0001 to 20 parts by weight based on 100 parts by weight of the thermoplastic resin (A), and a polymer having an epoxy group was used as the organic polymer (b2). The thermoplastic resin composition of the present invention can be widely used in the fields of automotive parts, electric and electronic parts, and precision instrument parts.
    Type: Application
    Filed: September 20, 2002
    Publication date: May 8, 2003
    Inventors: Hideyuki Fujimoto, Atsunori Koshirai
  • Publication number: 20030088027
    Abstract: Polymer blends, in particular polyphenylene ether-polyamide blends, are effectively compatibilized by incorporating under blending conditions certain oligomers, cooligomers, polymers and copolymers of narrow molecular weight distribution that are prepared under free radical polymerization conditions with glycidyl-functionalized nitroxyl initiators. The oligomers, cooligomers, polymers and copolymers contain at least one oxyamine group and at least one glycidyl-containing initiator group. The polymer blends have excellent mechanical properties.
    Type: Application
    Filed: July 10, 2002
    Publication date: May 8, 2003
    Inventors: Hui Chin, James Botkin, Francesco Fuso, Wiebke Wunderlich
  • Patent number: 6552127
    Abstract: A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150° C.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: April 22, 2003
    Assignee: Daikin Industries, Ltd.
    Inventors: Tetsuo Shimizu, Yoshihisa Yamamoto, Seitaro Yamaguchi, Nobuhiko Tsuda, Noriyasu Yamane, Takafumi Yamato, Masahiro Kumegawa, Takayuki Araki
  • Patent number: 6551393
    Abstract: A modified particle is disclosed wherein a particle has an attached group having the formula: wherein Ar represents an aromatic group; R1 represents a bond, an arylene group, an alkylene group, wherein R4 is an alkyl or alkylene group or an aryl or arylene group; R2 and R3, which can be the same or different, represent hydrogen, an alkyl group, an aryl group, —OR5, —NHR5, —NR5R5, or —SR5, wherein R5, which is the same or different, represents an alkyl group or an aryl group; and SFR represents a stable free radical.
    Type: Grant
    Filed: February 1, 2002
    Date of Patent: April 22, 2003
    Assignee: Cabot Corporation
    Inventors: Wayne Devonport, Robert S. Whitehouse, Russell L. Warley, Thimma R. Rawalpally, Hairuo Tu
  • Publication number: 20030069358
    Abstract: The invention relates to thermoplastic pavement marking compositions comprising synthetic polymeric fibers.
    Type: Application
    Filed: September 26, 2002
    Publication date: April 10, 2003
    Applicant: 3M Innovative Properties Company
    Inventors: Randall H. Helland, Chin Yee Ng
  • Publication number: 20030045638
    Abstract: The present invention provides a fully vulcanized thermoplastic elastomer comprising a rubber phase with a controllable particle size and a spheroidic shape, the preparation and use thereof. Fully vulcanized powdery rubber is blended with plastic by conventional method for blending rubbers, and thus obtaining a fully vulcanized thermoplastic elastomer, which comprises a rubber phase with a controllable particle size and a spheroidic shape, and which shows high tensile strength and high elongation at break, good appearance and good processibility.
    Type: Application
    Filed: July 25, 2002
    Publication date: March 6, 2003
    Inventors: Jinliang Qiao, Yiqun Liu, Xiaohong Zhang, Jianming Gao, Genshuan Wei, Shijun Zhang, Zhihai Song, Jiuqiang Li, Dechuan Zhuang
  • Publication number: 20030045637
    Abstract: This invention provides both a pigment dispersing resin which is a copolymer of:
    Type: Application
    Filed: April 5, 2002
    Publication date: March 6, 2003
    Inventors: Yuko Hoshida, Yoshiyuki Yukawa, Isao Kamimori, Akihiko Yamanouchi
  • Publication number: 20030040591
    Abstract: The present invention provides new fluoromonomers having the generic structure: CF2═CF(OCH2CH2)nOR where n is an integer and R is a functional group and methods for producing same. A new method of synthesizing the fluoromonomers is provided. The present invention also relates to new fluoropolymers prepared from any one or combination of the new fluoromonomers and having the generic structure: —[—CF2CF{(OCH2CH2)nOR}—]m— where n is an integer, m is an integer and R represents an unsubstituted or inertly substituted hydrocarbyl group.The method also relates to new copolymers or terpolymers prepared from the new fluoromonomers alone, the new fluoromonomers and existing fluoromonomers or the new fluoromonomers and existing hydrocarbon or functionalized hydrocarbon monomers.
    Type: Application
    Filed: March 23, 1999
    Publication date: February 27, 2003
    Inventors: MOLLY S. SHOICHET, ROBERT D. LOUSENBERG
  • Publication number: 20020197559
    Abstract: A polymer comprising recurring units of formula (1-1) or (1-2) wherein R1, R2, R3 and R4 are H or alkyl, or R1 and R2, and R3 and R4 taken together may form a ring with each pair being alkylene, and k is 0 or 1 and having a Mw of 1,000-500,000 is novel. A resist composition comprising the polymer as a base resin is sensitive to high-energy radiation, has excellent sensitivity, resolution, etching resistance, and minimized swell and lends itself to micropatterning with electron beams or deep-UV.
    Type: Application
    Filed: April 22, 2002
    Publication date: December 26, 2002
    Applicant: Shin-Etsu Chemical Co., Ltd.
    Inventors: Tsunehiro Nishi, Takeshi Kinsho, Seiichiro Tachibana, Takeru Watanabe, Koji Hasegawa, Tomohiro Kobayashi
  • Publication number: 20020193521
    Abstract: Plastics and plastics additives including PNPs having a mean diameter in the range of from 1 to 50 nanometers, the PNPs including as polymerized units at least one multi-ethylenically-unsaturated monomer are provided. Also provided is a method for providing an improved plastic.
    Type: Application
    Filed: March 15, 2002
    Publication date: December 19, 2002
    Inventors: Carlos Alfonso Cruz, Robert Howard Gore, Timothy Roger Lynn, Warren Harvey MacHleder, Jane Elizabeth Weier, Newman Mayer Bortnick
  • Publication number: 20020188071
    Abstract: The invention relates to a mixture of biodegradable polyesters which includes an aromatic-aliphatic polyester (A), an aliphatic polyester (B) and a polyactic acid polymer (C) in which the concentration of A varies, with respect to (A+B) in the range between 40 and 70% by weight, and the concentration of C with respect to (A+B+C) is of between 6 and 30% by weight.
    Type: Application
    Filed: January 25, 2002
    Publication date: December 12, 2002
    Inventors: Catia Bastioli, Gianfranco Del Tredici, Italo Guanella, Roberto Ponti
  • Publication number: 20020188079
    Abstract: The present invention provides plastics with high toughness and the preparation thereof. The plastics with high toughness, which have the balance of stiffness and toughness, stable properties and good processability, are obtained by blending the rubber particles having an average particle size of 20 to 200 nm with the pseudoductile plastics, wherein the weight ratio of the rubber particles to the plastics is from 0.5:99.5 to 70:30. The present invention also provides plastics with both high stiffness and high toughness and the preparation thereof. The plastics with both high stiffness and high toughness, which have also an improved heat resistance and good processability, are prepared by blending the rubber particles having an average particle size of 20 to 500 nm and the crystalline plastics, wherein the amount of the rubber particles added in the plastics matrix is from 0.3 to 5 weight parts.
    Type: Application
    Filed: April 18, 2002
    Publication date: December 12, 2002
    Applicant: CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Jinliang Qiao, Shijun Zhang, Xiaohong Zhang, Yiqun Liu, Jianming Gao, Wei Zhang, Genshuan Wei, Jingbo Shao, Hua Yin, Renli Zhai, Zhihai Song, Fan Huang, Jiuqiang Li
  • Publication number: 20020188072
    Abstract: The present invention is to provide a curable coating composition having much less of a volatile organic component, and being excellent in coating film performance such as durability and scratch resistance, and a coating film forming method using the above curable coating composition capable of suppressing generation of sagging and so on.
    Type: Application
    Filed: March 26, 2002
    Publication date: December 12, 2002
    Applicant: NIPPON PAINT CO., LTD.
    Inventors: Akihiro Kanakura, Takashi Irie, Hiroto Yoneda, Hisaki Tanabe
  • Patent number: 6492443
    Abstract: A norbornene resin composition comprising 100 parts by weight of a thermoplastic norbornene polymer and 1 to 150 parts by weight of a thermosetting resin.
    Type: Grant
    Filed: April 7, 1999
    Date of Patent: December 10, 2002
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Junji Kodemura, Yasuo Tsunogae, Yasuhiro Wakizaka
  • Publication number: 20020183416
    Abstract: A melt extrudable low temperature curable powder coating composition for application onto heat sensitive substrates. The final cured coating produces a low gloss finish on the target substrate. The composition consists of an unsaturated polyester resin combined with a glycidyl functional acrylic resin, a crystalline or semi-crystalline polycarboxylic acid or anhydride and a free radical initiator. Optionally, if a harder, more wear-resistant surface is desired, the cure may be catalyzed by either a photoinitiator or a redox compound.
    Type: Application
    Filed: January 9, 2002
    Publication date: December 5, 2002
    Inventors: Andrew Thomas Daly, Richard Paul Haley, James R. Knaub, Carryll A. Seelig, Navin B. Shah, Gordon L. Tullos
  • Patent number: 6486257
    Abstract: This invention relates to high molecular weight block copolymers of &egr;-caprolactone and &ohgr;-lauryl lactam prepared by sequential bulk polymerization using a mixture of at least one anionic polymerization initiator and optionally at least one co-initiator. A preferred continuous sequential bulk reactive extrusion process comprises feeding a mixture of &ohgr;-lauryl lactam, at least one anionic polymerization initiator, and at least one co-initiator into the first (i.e., upstream) hopper of an extruder, and thereafter feeding &egr;-caprolactone into a second (i.e., downstream) hopper of the extruder. The preferred continuous sequential bulk reactive extrusion is solvent free, rapid (typical mean and maximum residence times in the extruder being no more than about 20 minutes and 30 minutes respectively), and produces a high conversion of monomers to block copolymer.
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: November 26, 2002
    Assignee: University of Akron
    Inventors: James L. White, Byong-Jun Kim
  • Patent number: 6479607
    Abstract: A PVC composition for use in cables, particularly computer cables, exhibits improved flame resistant qualities. In addition, the cable includes an outer insulating jacket of a transparent or translucent PVC material, which exhibits a slightly tinted appearance. The PVC material additionally includes reflective particles which provide an aesthetically appealing appearance of the cable.
    Type: Grant
    Filed: November 10, 2000
    Date of Patent: November 12, 2002
    Inventors: Henry Milan, Chris Tsai
  • Publication number: 20020165320
    Abstract: The present invention is related with a dielectric composition for the manufacture of an insulating structure of the type that comprises at least a dielectric resin. The composition comprises granules of a thermoset polymer and a dielectric resin in a ratio thermoset polymer/dielectric resin in the scale of 2:1 to 20:1, which allows it to support voltages of at least 45 kV and to have resistances of at least 25 M&OHgr;. The invention further comprises dielectric structures obtained from the composition, which can be increased in their dielectric strength by means of a layer of dielectric resin.
    Type: Application
    Filed: April 2, 2002
    Publication date: November 7, 2002
    Inventors: Gerardo Pagaza Melero, Saturnino Enrique Martinez Herrera, Victor Pagaza Melero
  • Patent number: 6476159
    Abstract: A gelcoat composition composed of a base resin having double bonds in a molecule and a modified silicone oil having double bonds in a molecule. The gelcoat composition is inexpensive and yet highly stainproof. It is suitable for application to bathroom waterproof panels, etc.
    Type: Grant
    Filed: August 16, 2000
    Date of Patent: November 5, 2002
    Assignee: Bridgestone Corporation
    Inventor: Yuichi Ishino
  • Publication number: 20020161120
    Abstract: Extrusion processability of non-fluorinated melt-processable polymers is improved by introducing a fluoropolymer process aid by means whereby the weight average particle size of the fluoropolymer is greater than 2 microns as it reaches the extruder die entrance.
    Type: Application
    Filed: September 17, 2001
    Publication date: October 31, 2002
    Inventors: George R. Chapman, Steven R. Oriani
  • Patent number: 6472472
    Abstract: Powder coating compositions for metal substrates, a method of powder coating a metal substrate, and a metal article are disclosed. The powder coating composition is a thermoplastic material and comprises: (a) a first polyester having a weight average molecular weight of about 10,000 to about 80,000 and a Tg of greater than 45° C. to about 100° C., (b) a second polyester having a weight average molecular weight of about 10,000 to about 70,000 and a Tg of about −10° C. to about 45° C., and optionally, (c) a modifying resin, such as an epoxy resin having an epoxy equivalent weight of about 500 to about 15,000, wherein the Tg of the first and second polyesters differ by about 5° C. to about 60° C. The powder coating composition is applied to a metal substrate to provide a composition film having a thickness of about 1 to about 200 microns.
    Type: Grant
    Filed: June 13, 2001
    Date of Patent: October 29, 2002
    Assignee: The Valspar Corporation
    Inventors: Rolf Jung, Christian Schmid
  • Patent number: 6472471
    Abstract: Various modified carbon products are disclosed which can form a part of a polymeric product containing the modified carbon product and a polymer. One type of modified carbon product disclosed is a carbon product having attached at least one organic group, monomeric group, or polymeric group. Another type of modified carbon product disclosed is a carbon product having attached a group having the formula: —Ar—CO2—R or —CnH2nCO2—R where R is an organic group, monomeric group, or a polymeric group.
    Type: Grant
    Filed: December 14, 1998
    Date of Patent: October 29, 2002
    Assignee: Cabot Corporation
    Inventors: Joel M. Cooke, Collin P. Galloway, Mark A. Bissell, Curtis E. Adams, Michael C. Yu, James A. Belmont, Robert M. Amici
  • Publication number: 20020156191
    Abstract: The invention relates to a process for the preparation of an impact-resistant polymer composition comprising 0.
    Type: Application
    Filed: December 14, 2001
    Publication date: October 24, 2002
    Inventors: Wilhelmus G.M. Bruls, Johannes F. Repin, Jan De Kroon