With A Polycarboxylic Acid Or Derivative And A Polyamine Or The Corresponding Salt Thereof; Or With A Lactam; Or With An Aminocarboxylic Acid; Or With The Corresponding Polymers; And Wherein The Monomer Or Polymer Was Derived From At Least One Saturated Reactant Patents (Class 525/178)
  • Patent number: 4533524
    Abstract: What are disclosed are plastisols comprising a finely divided vinyl chloride polymer and the usual fillers, additives, and plasticizers, to which plastisols is added, as an adhesion promoter, the condensation product formed between (1) a polyaminoamide, comprising polymerized fatty acids and an excess of a polyalkylene polyamine and (2) a carboxylic acid or an ester thereof, and methods for coating or adhering a substrate with such plastisols by applying said plastisols to the substrate and baking at temperatures of 90.degree. C. and up.
    Type: Grant
    Filed: December 30, 1982
    Date of Patent: August 6, 1985
    Assignee: Schering AG.
    Inventors: Christian Burba, Ulrich Goeke, Norbert Esper
  • Patent number: 4530974
    Abstract: Articles having reduced thrombogenicity when in contact with blood products containing albumin and methods of their use are provided. The articles comprise at the surface of blood contact a water insoluble polymeric substrate material having covalently attached thereon aliphatic extensions of 14 to 20 carbon units. When exposed to blood the aliphatic chain extensions provide a hydrophobic binding site for albumin. The articles when implemented with whole blood or blood products selectively enhance albumin affinity binding to the exclusion of other blood components, and subsequently minimize thrombus formation.
    Type: Grant
    Filed: July 13, 1982
    Date of Patent: July 23, 1985
    Assignee: Board of Regents, The University of Texas System
    Inventors: Mark S. Munro, Alfred J. Quattrone, Steven R. Ellsworth, Robert C. Eberhart
  • Patent number: 4511684
    Abstract: The instant invention relates to thermoplastically processable polyamides which are rendered flame retardant by means of a new flame retarding agent; the conversion product of cyanuric acid and triazine compounds having free --NH.sub.2 in a molar ratio of at least 2 triazine nuclei per mole of cyanuric acid. The properties of polyamide thermoplasts are changed only slightly through the incorporation of the new flame retarding agent.
    Type: Grant
    Filed: December 15, 1982
    Date of Patent: April 16, 1985
    Assignee: Ems-Inventa AG
    Inventors: Eduard Schmid, Manfred Hoppe
  • Patent number: 4506042
    Abstract: Disclosed is a curable resin composition comprising (a) at least one maleimide compound selected from the group consisting of N-(alkenylphenyl)maleimide derivatives, and dimers and polymers thereof and (b) one or more kinds of epoxy resins, each having at least one epoxy group in the unit molecule thereof. The resin composition may contain, besides the above two components, an amino compound as a further component (c). The resin composition may comprise a prepolymer of any two components among the three components (a), (b) and (c) and the remaining component. The resin compositions are useful as molding materials, for the fabrication of laminates, and as varnishes, including insulation varnishes and impregnating varnishes.
    Type: Grant
    Filed: April 4, 1983
    Date of Patent: March 19, 1985
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Hikotada Tsuboi, Motoo Kawamata, Masayuki Oba, Nobuhito Koga
  • Patent number: 4469829
    Abstract: Amino-group bearing, low molecular weight 1,3-butadiene polymers used as stabilizers for molded or unshaped plastics in amounts of 0.01 to 2.0 weight percent referred to the plastic, where the amino-group bearing component is derived from a substituted piperidine having the general formula: ##STR1## where R represents similar or different alkyl groups having 1 to 3 carbon atoms.
    Type: Grant
    Filed: August 18, 1983
    Date of Patent: September 4, 1984
    Assignee: Chemische Werke Huls AG
    Inventors: Alfred Konietzny, Hans-Dieter Zagefka, Konrad Rombusch, Hanns-Jorg Bax
  • Patent number: 4451616
    Abstract: A process for preparation of filler-containing polytetrafluoroethylene fine powder by coagulating polytetrafluoroethylene together with at least one filler selected from the group consisting of polyimide resins, polyamide-imide resins, polyamide resins and carbon fiber powders from their aqueous dispersion, characterized in that a water-insoluble organic liquid having a boiling point of from 30.degree. to 150.degree. C. and a surface tension of not more than 35 dyne/cm at 20.degree. C. is added to the aqueous dispersion under agitation at any stage from the start to the end of the coagulation.
    Type: Grant
    Filed: July 24, 1980
    Date of Patent: May 29, 1984
    Assignee: Daikin Kogyo Co., Ltd.
    Inventors: Shoji Kawachi, Toshinori Kadowaki, Katsutoshi Yamamoto
  • Patent number: 4448956
    Abstract: Polyamides such as nylon-6 type polyamides are prepared by the reaction or copolymerization of a major amount by weight of a lactam and a minor amount by weight of a graft copolymer of maleic anhydride on a low molecular weight liquid conjugated diene polymer or copolymer or of a copolymer of a conjugated diene and a monovinyl aryl monomer or a nitrile. For example, a graft of maleic anhydride on liquid butadiene/acrylonitrile copolymer is copolymerized with epsilon-caprolactam using an anionic lactam polymerization catalyst (a lactamate salt) like the reaction product of ethyl magnesium bromide and epsilon-caprolactam. The present invention may be useful in a RIM (Reaction Injection Molding) process. The resulting polyamides have improved impact strength and water resistance. They can be used to make automobile and truck bodies and parts.
    Type: Grant
    Filed: May 10, 1983
    Date of Patent: May 15, 1984
    Assignee: The General Tire & Rubber Company
    Inventors: Gerd M. Lenke, Earl G. Melby, Hubert J. Fabris
  • Patent number: 4447580
    Abstract: A resin composition comprising (A) a polymer having, in the molecule, at least two groups represented by the following structural formula (I): ##STR1## wherein R.sub.1 is isopropyl, sec-butyl, tert-butyl, a C.sub.5-20 alkyl group, a C.sub.3-20 cycloalkyl group, a C.sub.5-20 alkenyl group, a C.sub.3-20 hydroxyalkyl group, a C.sub.5-20 alkoxyalkyl group, a C.sub.3-20 aminoalkyl group, a C.sub.6-20 aryl group or a C.sub.6-20 arylalkyl group, and n is 0, 1 or 2, and (B) a polymer having an electron attractive group and an .alpha.,.beta.-ethylenic double bond adjacent thereto. Though said composition is stable at room temperature, it is crosslinked and cured at high temperatures because the amino group of the polymer (A) adds to the double bond of the polymer (B). Accordingly, said resin composition is suitable for use as a cathodic electrocoating material.
    Type: Grant
    Filed: November 12, 1981
    Date of Patent: May 8, 1984
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Hideo Ai, Naohiro Tsuruta
  • Patent number: 4440916
    Abstract: Particles of two different normally solid materials are caused to react by generating free radicals on the surfaces of at least one of the solids by mechanical working, suitably by comminution, at cryogenic temperatures. At least one of the solids is preferably a polymeric material while the other may be a different polymer, a catalyst, a lubricity enhancing material, a filler, a pigment or the like.
    Type: Grant
    Filed: May 6, 1982
    Date of Patent: April 3, 1984
    Assignee: General Technology Applications, Inc.
    Inventors: Paul F. Waters, Thomas T. Scambos
  • Patent number: 4438230
    Abstract: Vulcanizable polymer compositions, comprising a polymer blend and a curative system, and a process for preparing the compositions are provided. The polymer blend comprises a flux blend of a PVC, a carboxylated nitrile rubber and a nylon having a melting point of less than about 210.degree. C., and stabilizers. Vulcanizates of the polymer compositions have improved properties and may be used, for example, in spinning cots.
    Type: Grant
    Filed: November 29, 1982
    Date of Patent: March 20, 1984
    Assignee: Polysar Limited
    Inventor: Herbert F. Schwarz
  • Patent number: 4429078
    Abstract: Compositions containing a polymer of PTFE and a polymer capable of exhibiting an anisotropic melt characterized in that the compositions contain between 0.05 and 99.5% of PTFE and 0.5 to 99.95% by weight of the polymer capable of forming an anisotropic melt. The presence of a minor amount of the anisotropic melt-forming polymer, that is, from 0.5 to 50% by weight of the composition enables the processability of PTFE to be improved, even to the extent of providing an injection mouldable PTFE composition. Compositions containing 20 to 50% by weight of PTFE confer benefits on anisotropic melt-forming polymers, such as lubricity and greater versatility in fabrication operations. Concentration of 0.05 to 5.0% by weight of PTFE are particularly suitable for modifying the viscosity characteristics of the low melt viscosity anisotropic melt-forming polymers so that such anisotropic melt polymers are less subject to problems such as flashing and jetting during moulding.
    Type: Grant
    Filed: October 30, 1981
    Date of Patent: January 31, 1984
    Assignee: Imperial Chemical Industries PLC
    Inventors: Frederic N. Cogswell, Martin S. Swerdlow
  • Patent number: 4426496
    Abstract: Thermosettable resin compositions are disclosed which comprise a mixture of (1) an unsaturated polymerizable monomer, (2) an unsaturated polymerizable resin selected from (a) unsaturated polyester or polyesteramide resins, (b) vinyl ester resins and (c) dicyclopentadiene modified unsaturated polyester of polyesteramide resins and (3) a poly(allyl)poly(alkenylphenol).
    Type: Grant
    Filed: October 28, 1982
    Date of Patent: January 17, 1984
    Assignee: The Dow Chemical Company
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 4424239
    Abstract: The invention provides for a coating composition for metal surfaces wherein the binder is made up of (A) 10-80% by weight of a solid, powdered polyamide having a softening point of 110.degree.-230.degree. C. and an average particle size of 0.5-200 .mu. m, (B) 20-90% by weight of a hydroxyl groups-containing polymer having a number average molecular weight of 800-20,000 and a hydroxyl functionality of 1.5-6, and the composition also contains a cross-linking agent for component B in an amount such that the molar ratio of the reactive groups of the cross-linking agent to that of component B is 0.6-1.5, and 40-60% by weight of an organic solvent for component B, the boiling point thereof being 140.degree.-310.degree. C. The invention also relates to a process for coating a metal surface using said coating composition.
    Type: Grant
    Filed: December 23, 1982
    Date of Patent: January 3, 1984
    Assignees: Astral Societe de Peintures et Vernis, ATO Chimie
    Inventors: Gabriel H. A. Nota, Anton Toth
  • Patent number: 4417020
    Abstract: Compositions containing a polymer of PTFE and a polymer capable of exhibiting an anisotropic melt characterized in that the compositions contain between 0.05 and 99.5% of PTFE and 0.5 to 99.95% by weight of the polymer capable of forming an anisotropic melt. The presence of a minor amount of the anisotropic melt-forming polymer, that is, from 0.5 to 50% by weight of the composition enables the processability of PTFE to be improved, even to the extent of providing an injection mouldable PTFE composition. Compositions containing 20 to 50% by weight of PTFE confer benefits on anisotropic melt-forming polymers, such as lubricity and greater versatility in fabrication operations. Concentration of 0.05 to 5.0% by weight of PTFE are particularly suitable for modifying the viscosity characteristics of the low melt viscosity anisotropic melt-forming polymers so that such anisotropic melt polymers are less subject to problems such as flashing and jetting during moulding.
    Type: Grant
    Filed: November 3, 1981
    Date of Patent: November 22, 1983
    Assignee: Imperial Chemical Industries PLC
    Inventors: Derrick S. Bailey, Brian P. Griffin
  • Patent number: 4414362
    Abstract: Polyamides from lactams are prepared by the reaction of an initiator compound, a liquid hydroxy containing nitrile copolymer and a lactam using as a catalyst a minor amount of a lactam anionic polymerization catalyst. The resulting polyamides exhibit high impact strength and improved dimensional stability or reduced sensitivity to dimensional change upon exposure to a high humidity environment.
    Type: Grant
    Filed: March 4, 1982
    Date of Patent: November 8, 1983
    Assignee: The General Tire & Rubber Company
    Inventors: Gerd M. Lenke, Hubert J. Fabris
  • Patent number: 4399258
    Abstract: By the incorporation of small amounts of specific polyamides into polyalkenes, such as polypropylene and polyethylene, it is possible to significantly improve the dyeing properties, including color intensity, color homogeneity and color fastness, of the polyalkene. Polyamides useful for this purpose are derived from mixed dicarboxylic acids, diamine and triamine containing two primary and one tertiary amine groups.
    Type: Grant
    Filed: January 21, 1982
    Date of Patent: August 16, 1983
    Assignee: Emery Industries, Inc.
    Inventors: Adrien G. Hinze, Robert P. Roggeveen, Abraham J. Meulenberg
  • Patent number: 4373046
    Abstract: A flame-retardant and radiation-resistant polymer composition comprising a polymer and a halogenated acenaphthylene condensate having a structural unit of the formula (I) or (II): ##STR1## (wherein X is chlorine or bromine, n and n' are each an integer of 2 to 6, R is a substituent other than halogen, m and m' are each an integer of 0 to 4, n (or N')+m(or m').ltoreq.6, and when m or m' is 2 or more, each R may be the same or different) and a flame-retardant and radiation-resistant resin molded product prepared therefrom are herein disclosed.
    Type: Grant
    Filed: February 10, 1981
    Date of Patent: February 8, 1983
    Assignee: Japan Atomic Energy Research Institute
    Inventors: Miyuki Hagiwara, Yousuke Morita
  • Patent number: 4350794
    Abstract: Polyamide molding and extrusion compositions prepared by melt-blending a polyamide resin and a polyamide reactive halogen functional elastomer. The invention includes a process for preparing the resin and the molded or extruded product.
    Type: Grant
    Filed: June 18, 1980
    Date of Patent: September 21, 1982
    Assignee: Monsanto Company
    Inventor: Marlowe V. Moncur
  • Patent number: 4278776
    Abstract: Vulcanizable mixes based on elastomeric copolymers of vinylidene fluoride with fluorinated or chlorofluorinated olefins, or with fluorinated vinyl ethers, and which comprise, as processing aid, at least one fluorinated polyamide, are disclosed.
    Type: Grant
    Filed: June 12, 1980
    Date of Patent: July 14, 1981
    Assignee: Montedison S.p.A.
    Inventors: Gastone Mauro, Carlo Lagana, Sergio Geri, Ezio Strepparola
  • Patent number: 4265970
    Abstract: An acrylic fiber having improved basic dyeability and hot/wet properties, the fiber being made up of a blend of (a) at least 60 weight percent of a polymer of at least 35 weight percent of acrylonitrile copolymerized with up to 65 weight percent of at least one other mono-olefinic monomer and a minor amount of a sulfonated vinyl monomer with (b) 0.5 to 40 weight percent of the polyterephthalamide of a mixture of 2,2,4 and 2,4,4 trimethyl hexamethylene diamine, the fiber being made up of a two-phase heterogeneous suspension of the polyterephthalamide in a continuous phase of the acrylic polymer. Without the sulfonated vinyl monomer the fiber will have superior hot/wet properties but will show no improvement in dyeability, the dyeability of the fiber being enhanced only when the sulfonated vinyl monomer is present as a part of the acrylic polymer chain.
    Type: Grant
    Filed: June 6, 1980
    Date of Patent: May 5, 1981
    Assignee: Monsanto Company
    Inventor: Hartwig C. Bach
  • Patent number: 4263185
    Abstract: This invention relates to medical technique and more particularly it relates to biodestructive materials used to manufacture elements for fixation of bone fragments.Said material contains a matrix of non-toxic polymer resolvable in the body consisting of hydrophilic and hydrophobic repeat units, and a reinforcing component of non-toxic fibres or threads resolvable in the body. The matrix polymer is preferably a copolymer of methyl methacrylate and N-vinyl pyrrolidone, and the reinforcing component is preferably fibre or threads of polyamide and oxycellulose.Said material can be used in medicine for fixation of bone fragments in fractures or injuries of bones.
    Type: Grant
    Filed: October 1, 1979
    Date of Patent: April 21, 1981
    Inventors: Sergei I. Belykh, Anatoly B. Davydov, Gennady L. Khromov, Anatoly D. Moschensky, Ilya A. Movshovich, Gennady I. Roitberg, Gennady L. Voskresensky, Gely G. Pershin, Valery A. Moskvitin
  • Patent number: 4255530
    Abstract: A binder composition which comprises (A) from 99 to 50% by weight of copolymer consisting of copolymerized units of (a) from 5 to 90% by weight of at least one aliphatic (meth)acrylate containing from 1 to 8 carbon atoms in the alcohol moiety; (b) from 0 to 60% by weight of at least one aromatic vinyl or isopropylene compound containing from 8 to 14 carbon atoms; (c) from 1 to 40% by weight of at least one comonomer selected from (I) at least one mono (meth)acrylate of an alcohol containing from 2 to 8 carbon atoms and having from 2 to 4 hydroxyl groups; and/or (II) at least one maleic acid semi-ester corresponding to the following general formula ##STR1## wherein R.sub.1 represents hydrogen or methyl; and R.sub.2 represents hydrogen, methyl, ethyl, propyl, i-propyl or phenyl; and (d) from 0 to 60% by weight of at least one other olefinically unsaturated comonomer; and (B) from 1 to 50% by weight of a saturated lactam.
    Type: Grant
    Filed: November 20, 1979
    Date of Patent: March 10, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Hohlein, Jochen Schoeps
  • Patent number: 4243769
    Abstract: Compatibilized blends and composites of materials containing nitrile functionality with materials normally incompatible therewith are formed by mixing the components in the presence of an acid compatibilizing agent.
    Type: Grant
    Filed: October 4, 1977
    Date of Patent: January 6, 1981
    Assignee: National Distillers and Chemical Corp.
    Inventor: Ervin G. Pritchett
  • Patent number: 4243574
    Abstract: Poly(meta-phenylene isophthalamide) comprising encapsulated filler, a process for the preparation of these compositions by addition of the filler to the polymer solution before precipitation, and molded articles prepared from these materials characterized by increased strength at equal filler loadings.
    Type: Grant
    Filed: March 30, 1979
    Date of Patent: January 6, 1981
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Carl H. Manwiller
  • Patent number: 4238193
    Abstract: Durable excellent water absorption property and antistatic property can be given to synthetic fiber by a simple method. In the method, a polymerization initiator is absorbed in the fiber and then the fiber is applied with a water-soluble polymerizable monomer and heat treated to form a polymer thereon.
    Type: Grant
    Filed: September 19, 1978
    Date of Patent: December 9, 1980
    Assignee: Kanebo, Ltd.
    Inventors: Akio Kisaichi, Masao Oguchi, Toshihide Takeda, Akira Aikawa, Toshio Saito
  • Patent number: 4222882
    Abstract: Novel lubricating oil polymer additives are obtained by the following:(1) by preparing, by anionic polymerization, a living diene polymer of Mn of between about 20,000 and 300,000;(2) by functionalizing the said polymer by means of an N-substituted lactam of the type of N-alkylcaprolactam, N-binylcaprolactam, and particularly of the type of N-alkylpyrrolidione and N-vinylpyrrolidone; and(3) by hydrogenating the said functionalized polymer.A variant method of preparing the said polymers comprises subjecting the living polymer to a metalation operation before functionalization; the hydrogenation operation is carried out before metalation or after functionalization.The said polymers may be used as additives which improve the viscosity index and the dispersing power of lubricating oils. The amount of additive added is between about 0.1 and 10 percent by weight.
    Type: Grant
    Filed: January 26, 1979
    Date of Patent: September 16, 1980
    Assignees: Rhone-Poulenc Industries, l'Institut Francais du Petrole
    Inventors: Daniel Brulet, Robert Pocheville, Bernard Chauvel
  • Patent number: 4221700
    Abstract: A stabilized synthetic polymer composition comprising(1) 100 parts by weight of a synthetic polymer,(2) 0.001 to 5 parts by weight of a poly(alkylated alkenylphenol) composed substantially of monomeric units represented by the following formula (I) ##STR1## wherein R represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; R.sub.1 represents an alkyl group having 1 to 18 carbon atoms; and R.sub.2 represents a hydrogen atom or an alkyl group having 1 to 18 carbon atoms; and(3) 0.001 to 5 parts by weight of an auxiliary stabilizer selected from the group consisting of polyhydric alcohol esters of alkylthioalkanoic acids, polyesters of thiodipropionic acid and organic phosphite compounds.
    Type: Grant
    Filed: July 5, 1978
    Date of Patent: September 9, 1980
    Assignee: Maruzen Oil Co., Ltd.
    Inventors: Motomobu Minagawa, Mitsuo Akutsu, Hiroshi Fujiwara, Masayuki Kashiki
  • Patent number: 4198494
    Abstract: This invention relates to fiber blends, yarns and fabrics for use in lightweight garments offering protection against brief exposure to extreme thermal fluxes, the fiber blend comprising a component that fuses within 10 seconds upon exposure to a heat flux of 2 cal./cm..sup.2 /sec. and a component that in fabric form exhibits a flame strength of at least 20 mg. per denier for at least 10 seconds during exposure to a heat flux of 2 cal./cm..sup.2 /sec.
    Type: Grant
    Filed: September 30, 1974
    Date of Patent: April 15, 1980
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: William G. Burckel, deceased
  • Patent number: RE30322
    Abstract: 6-Nylons and 12-nylons having primary amino end-groups and an average degree of polymerization of about 5-60 are grafted onto elastomeric trunk polymers having anhydride groups, vicinal carboxylic groups, or carboxylic groups adjacent to alkoxycarbonyl groups by heating a mixture of the nylon and the trunk polymer, preferably under high shear conditions for about 1 minute or less to 30 minutes or more above the melting temperature of the nylon. The resulting elastomeric graft polymers are suitable for fabricating into a variety of articles, such as, for example, wire jacketing, hose, belts, seals, gaskets, and low pressure tires.
    Type: Grant
    Filed: December 15, 1978
    Date of Patent: July 1, 1980
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Clarence F. Hammer, Harold K. Sinclair