With A Polycarboxylic Acid Or Derivative And A Polyamine Or The Corresponding Salt Thereof; Or With A Lactam; Or With An Aminocarboxylic Acid; Or With The Corresponding Polymers; And Wherein The Monomer Or Polymer Was Derived From At Least One Saturated Reactant Patents (Class 525/178)
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Patent number: 5998019Abstract: A multiple layer structure comprising a skin layer composed of a polypropylene copolymer with styrene ethylene-butene styrene block copolymer within a range of 0-20% by weight skin layer, and, a radio frequency ("RF") susceptible layer adhered to the skin layer. The RF layer has a first component of a propylene based polymer, a second component of a nonpropylene polyolefin, a third component of a radio frequency susceptible polymer, and a fourth component of a polymeric compatibilizing agent.Type: GrantFiled: November 16, 1993Date of Patent: December 7, 1999Assignee: Baxter International Inc.Inventors: Larry A. Rosenbaum, William Anderson, Lecon Woo, Dean Laurin, Angeles Lillian Buan, Michael T.K. Ling, Yuan Pang Samuel Ding, Denise S. Hayward, Joseph P. Hoppesch, Gregg Nebgen, Stanley Westphal
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Patent number: 5998545Abstract: The present invention relates to a mixture of polymers (A) having polyamide blocks and copolymers (B) comprising vinylaromatic units and unsaturated carboxylic anhydride units, the quantity of (B) being sufficient for the melt index (or melt flow index, MFI) of the mixture of (A) and (B) to be less than the melt index of (A) alone.It also relates to masterbatches of (A) and (B).Type: GrantFiled: January 22, 1998Date of Patent: December 7, 1999Assignee: Elf Atochem S.A.Inventors: Denis Melot, Alain Bouilloux, Benoit Ernst
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Patent number: 5994468Abstract: The instant invention teaches a method for enabling the formation of a high damping, soft polymer gel. The method includes: reacting a poly(maleimide-co-alkenyl benzene) polymer with a nylon and an alkyl diamine under substantially dry conditions sufficient to form a nylon grafted poly(maleimide-co-alkenyl benzene) polymer product; and, dispersing the nylon grafted poly(maleimide-co-alkenyl benzene) polymer product with an extender oil sufficient to form the gel. The instant invention also contemplates a polymer gel composition, a polymer composition and an article manufactured from the polymer gel composition.Type: GrantFiled: May 6, 1998Date of Patent: November 30, 1999Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz, James E. Hall, Naruhiko Mashita, Hideo Takeichi
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Patent number: 5986005Abstract: The present invention relates to a modifier composition, a stock mixture and a final composition comprising a fluoro elastomer and a thermoplastic polyamide, as well as to the film obtained from the final composition.Type: GrantFiled: November 17, 1997Date of Patent: November 16, 1999Assignee: Elf Atochem S.A.Inventors: Regis Jacquemet, Jean-Jacques Labaig, Joachim Merziger
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Patent number: 5986006Abstract: Homo- or copolymers A composed ofA.sub.1) 40-100% by weight of monomers of the general formula I ##STR1## A.sub.2) 0-60% by weight of monomers of the general formula II ##STR2## and A.sub.3) 0-10% by weight of further monomers capable of free radical polymerization,the percentages by weight of the monomers A.sub.1) to A.sub.3) summing to 100% andR.sup.1 and R.sup.4 being identical or different radicals and each being hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.2, R.sup.3, R.sup.5, R.sup.6 being identical or different radicals and each being hydrogen or C.sub.1 -C.sub.4 -alkyl,with the proviso that at least two radicals from the group consisting of R.sup.1, R.sup.2 and R.sup.3 and from the group consisting of R.sup.4, R.sup.5 and R.sup.6 are hydrogen, andR.sup.7 is alkyl, cycloalkyl, aryl or aralkyl,are used as branching agents for amino-containing thermoplastic polymers.Type: GrantFiled: January 29, 1998Date of Patent: November 16, 1999Assignee: BASF AktiengsellschaftInventors: Alexander Gluck, Walter Gotz, Gregor Ley
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Patent number: 5973076Abstract: Disclosed are a polybutene-1 resin composition comprising a polybutene-1 resin and a Form-II to Form-I crystal transformation accelerator, and a method of accelerating the Form-II to Form-I crystal transformation comprising molding the polybutene-1 resin composition and allowing the molded product to stand at about 0 to 50.degree. C., the crystal transformation accelerator being an amide compound.Type: GrantFiled: November 29, 1995Date of Patent: October 26, 1999Assignee: New Japan Chemical Co., Ltd.Inventors: Masafumi Yoshimura, Naoki Ikeda, Kazuaki Mizoguchi, Hiroshi Kitagawa
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Patent number: 5952423Abstract: Plastic compositions, containers useful in the storage of red blood cells, and methods for providing such red blood cell storage containers and for storing red blood cells are disclosed. The plastic composition includes a polyolefin copolymer and a plasticizer. The flexibility of such plastic compositions and containers made thereof is substantially unchanged upon heating to a high temperature relative to its flexibility before such heating.Type: GrantFiled: July 18, 1997Date of Patent: September 14, 1999Assignee: Baxter International Inc.Inventors: Shaye-Wen Shang, Michael Tung-Kiung Ling, Lecon Woo
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Patent number: 5939512Abstract: A composition comprising a polyamide, a polyolefinic modifier, and an ethylene/acrylic acid copolymer.Type: GrantFiled: February 28, 1998Date of Patent: August 17, 1999Assignee: AllliedSignal Inc.Inventors: Jay A. Gervasi, Harold W. Tuller, Wesley F. Smith, Charles W. Alpaugh
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Patent number: 5936039Abstract: Processes for the preparation of a thermoplastic elastomer comprising a triblend of engineering resin, dynamically vulcanized alloy of thermoplastic olefin polymer and elastomeric copolymer, and a compatibilizer for the engineering resin and alloy. The compatibilizer can be formed in a separate step or in-situ in a one step process. The processes produce compositions which retain structural integrity at high temperature, and have good tensile properties, elongation and fluid resistance.Type: GrantFiled: November 10, 1997Date of Patent: August 10, 1999Inventors: Kang-Bo Wang, Kuo-Shein Shen, Krishna Venkataswamy, Craig A. Chmielewski
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Patent number: 5936040Abstract: Novel maleimide copolymers have at least two monomeric units, a maleimide unit and a vinyl unit having a pendant group, the pendant group having two to twenty-one carbon atoms, at least one nitrogen atom and at least one oxygen atom. The copolymer has an average molecular weight between about 1,000 and about 6,000,000. Preferred maleimide copolymers include acrylamide/maleimide copolymers, N-vinyl amide/maleimide copolymers, vinyl lactam/maleimide copolymers, alkenyl cyclic imino ether/maleimide copolymers, and acryloylamide/maleimide copolymers. The substantially water soluble maleimide copolymers are useful for inhibiting the formation of clathrate hydrates in a fluid having hydrate-forming constituents by reducing the rate of nucleation, growth, and/or agglomeration of gas hydrate crystals in a petroleum fluid stream, thereby inhibiting the formation of a hydrate blockage in the pipe conveying the petroleum fluid stream.Type: GrantFiled: November 21, 1997Date of Patent: August 10, 1999Assignee: Exxon Production Research CompanyInventors: Christine Ann Costello, Enock Berluche, Russell Harlan Oelfke, Larry Dalton Talley
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Patent number: 5919864Abstract: A thermoplastic elastomer composition containing a thermoplastic resin component including 10 to 95% by weight of a polypropylene having a syndiotactic structure and an elastomer component and having a value of .alpha., defined as follows, of 1 or less:.alpha.=(.phi.d/.phi.m).times.(.eta.m/.eta.d)wherein the volume fraction of the thermoplastic resin component is .phi.m, the melt viscosity thereof at the mixing conditions is .eta.m and the volume fraction of the elastomer component is .phi.d, the melt viscosity thereof is .eta.d.Type: GrantFiled: March 6, 1998Date of Patent: July 6, 1999Assignee: The Yokohama Rubber Co., Ltd.Inventors: Jiro Watanabe, Osamu Ozawa, Noriaki Kuroda, Gou Kawaguchi
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Patent number: 5916954Abstract: A coating composition and method are disclosed for reducing vibration and noise when applied to a structure such as in transportation and industrial equipment systems. The coating composition of the present invention includes a viscoelastic material with discrete stiff fibers suspended therewithin. The viscoelastic material is preferably selected from acrylics, silicones and polyurethanes, and the discrete fibers are preferably carbon fibers.Type: GrantFiled: July 3, 1997Date of Patent: June 29, 1999Assignee: TRW Inc.Inventors: Jack R. Bohn, Teh Hwei Lee, Allen J. Bronowicki
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Patent number: 5910544Abstract: A thermoplastic elastomer composition comprising:i) from 15 to 80 parts by weight of a polyamide thermoplastic resin as component A;ii) from 20 to 85 parts by weight of a rubber composition as component B, the rubber composition containing a copolymer rubber composed of a copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a p-alkylstyrene, where at least a part of the p-alkylstyrene unit portions thereof have a halogen atom; andiii) a cross-linking agent,wherein the thermoplastic resin component A forms a continuous phase and at least part of component B is dispersed in component A as a dispersed phase and at least part of the dispersed phase is cross-linked by the cross-linking agent.Type: GrantFiled: June 25, 1997Date of Patent: June 8, 1999Assignee: The Yokohama Rubber Co., Ltd.Inventors: Osamu Ozawa, Tetsuji Kawazura, Noriaki Kuroda, Yoshihiro Aoyagi, Jiro Watanabe, Gou Kawaguchi
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Patent number: 5910545Abstract: Disclosed is a thermoplastic composition comprising an unreacted mixture of a poly(lactic acid) polymer; a polybutylene succinate polymer or a polybutylene succinate adipate polymer, or a mixture of such polymers; and a wetting agent. The thermoplastic composition exhibits substantial biodegradable properties yet is easily processed. The thermoplastic composition is useful in making multicomponent fibers or nonwoven structures that may be used in a disposable absorbent product intended for the absorption of fluids such as body fluids.Type: GrantFiled: October 31, 1997Date of Patent: June 8, 1999Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Fu-Jya Tsai, Brian T. Etzel
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Patent number: 5900464Abstract: Polar polymers having the following formula:FG--(Q).sub.d --R.sub.n --Z--J--?A(R.sup.1 R.sup.2 R.sup.3)!.sub.x(I)wherein FG is H or a protected or non-protected functional group; Q is a polar hydrocarbyl group derived by incorporation of a polar compound selected from group consisting of esters, amides, and nitriles of acrylic and methacrylic acid, and mixtures thereof; d is an integer from 10 to 2000; R is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; n is an integer from 0 to 5; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; ?A(R.sup.1 R.sup.2 R.sup.3)!.sub.x is a protecting group, in which A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.Type: GrantFiled: July 10, 1996Date of Patent: May 4, 1999Assignee: FMC CorporationInventors: Robert J. Letchford, James A. Schwindeman, Conrad W. Kamienski, Roderic P. Quirk
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Patent number: 5898046Abstract: A composition having repellency to low surface tension fluids comprising a material prepared by forming a mixture of a polymer selected from the group consisting of polyolefin, polyamide, polyester, polyacrylate, and blends and copolymers thereof, and a fluorochemical compound comprising a fluorocarbon/hydrocarbon ester of the formulae:R.sub.f --O--C(O)--R.sub.1 or R.sub.f --C(O)--O--R.sub.1whereinR.sub.f is selected from the group consisting of:1) F(CF.sub.2).sub.x --(CH.sub.2).sub.m wherein x is from about 4 to about 20 and m is from about 0 to about 6; and2) F(CF.sub.2).sub.x --SO.sub.2 N(R.sub.2)--R.sub.3 where x is a positive integer from about 4 to about 20, R.sub.2 is an alkyl radical of from about 1 to about 4 carbon atoms, R.sub.3 is an alkylene radical of from about 1 to about 12 carbon atoms; andR.sub.1 is an aliphatic hydrocarbon having from about 12 to about 76 carbon atoms; andprovided that said fluorochemical compound is other than perfluoroalkylethyl stearate; andmelt extruding the mixture.Type: GrantFiled: October 7, 1997Date of Patent: April 27, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Kimberly Gheysen Raiford, Theodor Arthur Liss, Edward James Greenwood
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Patent number: 5885718Abstract: A treating agent comprises a nitrile group-containing highly saturated polymer rubber latex (A) having an iodine value of 120 or less, a rubber latex (B) other than the highly saturated polymer rubber latex, and a water-soluble resorcinol/formaldehyde condensate in amounts of 15 to 80%, 5 to 70% and 2 to 15%, all by weight in terms of solids, respectively. A rubber-reinforcing fiber product is coated with the treating agent. A rubber article such as a toothed belt, a tire and the like is made using this rubber-reinforcing fiber product. The glass fiber product coated with the treating agent may be further coated with a halogen-containing polymer-based adhesive as a secondary treating agent. Thus, the treating agent exhibits a large bonding force between the reinforcing fiber product and a matrix. Even if the rubber article is repeatedly subjected to a flexing stress, the strength thereof cannot be reduced. A peel-off cannot occurs between the reinforcing fiber product and the rubber matrix.Type: GrantFiled: January 31, 1996Date of Patent: March 23, 1999Assignee: Nippon Glass Fiber Co., Ltd.Inventors: Akira Okamura, Masato Sekiguchi
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Patent number: 5883186Abstract: Thermoplastic molding materials containA) from 4 to 95% by weight of a semicrystalline, partly aromatic copolyamide composed ofa.sub.1) from 30 to 44 mol % of units which are derived from terephthalic acid,a.sub.2) from 6 to 20 mol % of units which are derived from isophthalic acid,a.sub.3) from 43 to 49.5 mol % of units which are derived from hexamethylenediamine anda.sub.4) from 0.5 to 7 mol % of units which are derived from aliphatic cyclic diamines of 6 to 30 carbon atoms,the molar percentages of components a.sub.1) to a.sub.4) together giving 100%, andB) from 4 to 95% by weight of a polyolefin homo- or copolymer or a mixture thereof,C) from 1 to 20% by weight of a compatibilizer,D) from 0 to 20% by weight of an elastomeric polymer,E) from 0 to 50% by weight of a fibrous or particulate filler andF) from 0 to 30% by weight of conventional additives and processing assistants,the percentages by weight of components A to F together giving 100%.Type: GrantFiled: June 23, 1997Date of Patent: March 16, 1999Assignee: BASF AktiengesellschaftInventors: Axel Gottschalk, Herbert Fisch, Gunter Pipper, Martin Weber
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Patent number: 5869573Abstract: A resin composition comprising 2 to 30 wt. parts of polyaminoamide and 98 to 70 wt. parts of a saponified ethylene-vinyl ester copolymer which comprises 20 to 60% of ethylene units based on the whole monomeric units and has a saponification degree for the vinyl ester units of at least 90%, and a shaped article comprising this resin composition.Type: GrantFiled: December 23, 1997Date of Patent: February 9, 1999Assignee: Sumitomo Chemical Company, LimitedInventors: Ryuma Kuroda, Taiichi Sakaya, Tadatoshi Ogawa
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Patent number: 5869574Abstract: A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150.degree. C. The present invention can provide a composition comprising various heat resisting thermoplastic resins and a fluorine-containing polymer having a functional group which is capable of developing an affinity with said resins and forming a uniform dispersion.Type: GrantFiled: April 17, 1997Date of Patent: February 9, 1999Assignee: Daikin Industries, Ltd.Inventors: Tetsuo Shimizu, Yoshihisa Yamamoto, Seitaro Yamaguchi, Nobuhiko Tsuda, Noriyasu Yamane, Takafumi Yamato, Masahiro Kumegawa, Takayuki Araki
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Patent number: 5866648Abstract: A long fiber-reinforced polymer alloy resin composition (C) is provided which is obtained by blending a master batch (A) containing a long fiber reinforcement (a2) having a length of 3 to 30 mm in a resin matrix of a polyamide resin (a1), with a substantially polymer-alloyed resin diluent (B) obtained by melt kneading 45 to 20% by weight of a crystalline polyolefin resin (b1) and 55 to 80% by weight of a polyamide resin (b2), the crystalline polyolefin resin (b1) containing a modified olefin crystalline polymer (b11) having been substantially modified with unsaturated carboxylic acids. In this resin composition (C), the amount of the long fiber reinforcement (a2) is in the range of 10 to 60% by weight, and the amount of the crystalline polyolefin resin (b1) in resin components ((a1)+(b1)+(2)) other than the long finer reinforcement (a2) is in the range of 20 to 45% by weight. This resin composition (C) is excellent in tensile strength and particularly excellent in repeated impact resistance properties.Type: GrantFiled: February 12, 1996Date of Patent: February 2, 1999Assignee: Chisso CorporationInventors: Koichi Saito, Takashi Shimpuku, Rikio Yonaiyama
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Patent number: 5866673Abstract: The invention relates to polymerisable double-bond derived polyamides obtainable by reacting the polyamide in an aqueous solution with a compound which contains both a polymerisable double bond and an oxirane ring. These derived polyamides may be processed to provide graft polymers with improved properties.Type: GrantFiled: July 21, 1997Date of Patent: February 2, 1999Assignee: Merck Patent Gesellschaft mit Beschrankter HaftungInventors: Egbert Muller, Anja Seiler, Roland Gensert
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Patent number: 5859137Abstract: New ethylene/acid copolymer ionomers which contain both (meth)acrylic acid and certain dicarboxylic acid monomers are described. The polymers may be melt processed as readily as ethylene/(meth)acrylic acid dipolymer ionomers, in contrast to ethylene/acid copolymer ionomers containing only dicarboxylic acid monomer derived in-chain acid units. Polymers with typical levels of (meth)acrylic acid and low levels of diacid provide ionomers comparable to existing ionomers, but which have adhesive and polymer blend compatibilizing characteristics, while polymers with higher levels of diacid will exhibit properties which depend on in-chain diacid derived units.Type: GrantFiled: March 25, 1998Date of Patent: January 12, 1999Assignee: E. I. du Pont de Nemours and CompanyInventor: Richard Tien-Hua Chou
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Patent number: 5847042Abstract: A polyolefin resin composition of the present invention comprising 0.01 to 2.0 parts by weight of an anti-blocking agent per 100 parts by weight of a polyolefin resin, wherein said anti-blocking agent has substantially two or more maximum values in a weight-based particle size distribution and a difference between a particle diameter giving the largest maximum value and a particle diameter giving the smallest maximum value is not less than 3.0 .mu.m.Type: GrantFiled: September 18, 1995Date of Patent: December 8, 1998Assignee: Sumitomo Chemical Company, LimitedInventors: Satoru Hosoda, Satoru Koyama, Kenzo Chikanari
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Patent number: 5840807Abstract: The invention relates to a packaging comprising a thermoplastic film based on a polymer containing polyamide blocks and polyether blocks, said polymer being permeable to water vapor, to ethylene, to CO.sub.2 and to oxygen, such that the permeability to CO.sub.2 is very much greater than the permeability to oxygen. The invention is particularly useful for making sachets in order to conserve fresh fruit, vegetables or meat.Type: GrantFiled: December 13, 1996Date of Patent: November 24, 1998Assignee: Elf Atochem S.A.Inventors: Alain Frey, Roland Leroux, Laurent Fischer
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Patent number: 5824745Abstract: Post consumer recyclable plastics are combined with a ethylene-octene copolymer and a polyamide to prepare a resin composition that can be used in conventional molding processes to fabricate new and useful plastic articles of manufacture.Type: GrantFiled: February 28, 1997Date of Patent: October 20, 1998Inventor: William F. Brown
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Patent number: 5804649Abstract: The present invention discloses a water-soluble self-acid-doped polyaniline, and its sodium salt, which can be cast into free-standing films from their aqueous solutions. A process for preparing a water-soluble self-acid-doped polyaniline is also disclosed, which comprises reacting a polyaniline with a strong base to convert the amino nitrogen thereof to anionic nitrogen; reacting sultone with the anionic nitrogen to form a side chain alkanesulfonic acid group; doping with protonic acid to form precipitate; dissolving (undoping) the precipitate in an alkaline aqueous solution; removing excess alkali from the alkaline aqueous solution; and contacting the resulting aqueous solution with a H.sup.+ -type ion exchange resin. Moreover, an aqueous solution of the present water-soluble self-acid-doped PAn can be easily mixed with an additional water soluble polymer or polymer emulsion, which can then be cased into a polymer blend film having improved mechanical properties and coupling strength to a substrate.Type: GrantFiled: July 21, 1997Date of Patent: September 8, 1998Assignee: National Science CouncilInventors: Show-An Chen, Gue-Wuu Hwang
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Patent number: 5804659Abstract: Monofilaments useful in papermaking fabrics which contain blended polyphthalamide and fluoropolymer and a process for making these monofilaments. These monofilaments have improved dry heat stability, knot strength, loop strength and abrasion resistance. The process reduces polymer shear in the extruder and eliminates polymer build up on the spinneret face.Type: GrantFiled: December 18, 1996Date of Patent: September 8, 1998Assignee: Asten, Inc.Inventor: John R. Reither
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Patent number: 5804681Abstract: The present invention relates to thermoplastic polyamides and to thermoplastic elastomers based on polyamide with improved thermomechanical performance. They are obtained by grafting along the polymer chain with alkoxysilanes having at least one unsaturation, and especially vinyltrialkoxysilanes of formula CH.sub.2 .dbd.CH--Si--(OR).sub.3 where R represents an alkyl or an alkoxy-substituted alkyl group. The weight ratio of the silane to polyamide in the grafted polymer is generally between 0.1 and 5%. These grafted polyamides may be crosslinked by hydrolysis in steam at 100.degree. C. or by contact with water. The grafted and optionally crosslinked polyamides may be used for producing molded or extruded articles, such as tubes, jackets, single-layer and multilayer films and complex parts, and powder for coating substrates.Type: GrantFiled: June 7, 1995Date of Patent: September 8, 1998Assignee: Elf Atochem S. A.Inventor: Patrice Breant
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Patent number: 5783634Abstract: Thermoplastic molding materials containA) from 1 to 99% by weight of a partly aromatic copolyamide composed ofa.sub.1) from 30 to 44 mol % of units which are derived from terephthalic acid,a.sub.2) from 6 to 25 mol % of units which are derived from isophthalic acid,a.sub.3) from 43 to 49.5 mol % of units which are derived from hexamethylenediamine anda.sub.4) from 0.5 to 7 mol % of units which are derived from aliphatic cyclic diamines of 6 to 30 carbon atoms,the molar percentages of components a.sub.1) to a.sub.4) together giving 100%,B) from 1 to 99% by weight of an aromatic polycarbonate,C) from 0 to 30% by weight of a polymeric component having OH groups,D) from 0 to 60% by weight of fibrous or particulate fillers or of a mixture thereof,E) from 0 to 40% by weight of rubber impact modifiers andF) from 0 to 40% by weight of conventional additives and processing assistants.Type: GrantFiled: March 13, 1997Date of Patent: July 21, 1998Assignee: BASF AktiengesellschaftInventors: Martin Weber, Herbert Fisch, Gunter Pipper, Axel Gottschalk
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Patent number: 5770654Abstract: A composition which is a uniform blend of 50-90 weight % of a polyamide melt-processable within the temperature range of 180.degree.-210.degree. C. and 50-10 weight % of recovered plasticized polyvinylbutyral, optionally also containing a small amount of an elastomeric ethylene copolymer carrying pendant succinic anhydride groups, has high impact strength and good flexural modulus. The polyamide in these compositions forms the matrix, and the plasticized polyvinylbutyral and any elastomer present form the dispersed phase. Such compositions have good barrier properties and are useful, among others, in applications where good toughness is required, for example, in packaging subjected to rough handling.Type: GrantFiled: March 20, 1997Date of Patent: June 23, 1998Assignee: E. I. du Pont de Nemours and CompanyInventor: Philip Strubing Blatz
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Patent number: 5766273Abstract: Polymer blends containa) from 10 to 90% by weight of an imide of a copolymer based on an .alpha.-olefin and on an ethylenically unsaturated dicarboxylic acid and a polyamine andb) from 10 to 90% by weight of a copolymer which differs from a) and contains at least two monomers selected from the group consisting of ethylene, acrylates, vinyl esters, vinyl ethers and ethylenically unsaturated dicarboxylic acids or dicarboxylic acid derivatives,and are used as additives for mineral oil middle distillates.Type: GrantFiled: February 25, 1997Date of Patent: June 16, 1998Assignee: BASF AktiengesellschaftInventors: Gabriele Dralle-Voss, Knut Oppenlander, Bernd Wenderoth, Dieter Faul, Wolfgang Kasel
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Patent number: 5762850Abstract: Hoses are often reinforced with fabric to improve their performance characteristics, such as burst strength. For instance, radiator hose used in automotive applications is generally reinforced with continuous yarn. However, it is a labor-intensive process to manufacture such hoses which include fiber reinforcements. A substantial amount of material waste also generally occurs in the manufacture of such fiber-reinforced hose. By utilizing the technique of this invention, hose which has a high level of burst strength can be manufactured without including continuous yarn reinforcement.Type: GrantFiled: December 16, 1996Date of Patent: June 9, 1998Assignee: The Goodyear Tire & Rubber CompanyInventors: Kevin James Pyle, Mark Samuel Sinsky, Paul Harry Sandstrom
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Patent number: 5760131Abstract: Rigid-rod and segmented rigid-rod polymers, methods for preparing the polymers and useful articles incorporating the polymers are provided. The polymers incorporate rigid-rod backbones with pendant solubilizing groups attached thereto for rendering the polymers soluble.Type: GrantFiled: June 2, 1995Date of Patent: June 2, 1998Assignee: Maxdem IncorporatedInventors: Matthew Louis Marrocco, III, Robert R. Gagne, Mark Steven Trimmer
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Patent number: 5750626Abstract: A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150.degree. C. The present invention can provide a composition comprising various heat resisting thermoplastic resins and a fluorine-containing polymer having a functional group which is capable of developing an affinity with said resins and forming a uniform dispersion.Type: GrantFiled: August 9, 1994Date of Patent: May 12, 1998Assignee: Daikin Industries, Ltd.Inventors: Tetsuo Shimizu, Yoshihisa Yamamoto, Seitaro Yamaguchi, Nobuhiko Tsuda, Noriyasu Yamane, Takafumi Yamato, Masahiro Kumegawa, Takayuki Araki
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Patent number: 5741854Abstract: A thermoplastic resin composition is provided exhibiting enhanced levels of dart impact strength. The composition contains a vinyl aromatic resin, an increased tetrafluoroethylene polymer and a reduced level of metal salt of a fatty acid. The tetrafluoroethylene polymer is introduced into the composition in the form of a preblend of tetrafluoroethylene polymeric powder and a carrier material. The compositions are useful for making molded articles such as business machine housings. A method for making the composition is also provided.Type: GrantFiled: July 31, 1996Date of Patent: April 21, 1998Assignee: General Electric CompanyInventor: Jianing Huang
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Patent number: 5726278Abstract: A process for manufacturing polyamide molded articles having improved resistance to discoloration while also having good heat stability involving preparing masterbatch pellets of at least a polyamide and a heat stabilizer, diluting the polyamide masterbatch pellets with a dilution polyamide resin to form a polyamide mixture, and molding the polyamide mixture into a molded article.Type: GrantFiled: April 24, 1996Date of Patent: March 10, 1998Assignee: E. I. du Pont de Nemours and CompanyInventor: Tsunao Kenmochi
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Patent number: 5719238Abstract: A method of improving the tribological properties of a polyketone polymer are presented in which polyketone polymer starting materials are blended with an aramide. Blends produced according to this process are also presented. The blend is particularly useful in the manufacture of articles used in applications where surfaces are in contact during motion.Type: GrantFiled: July 7, 1995Date of Patent: February 17, 1998Assignee: Shell Oil CompanyInventors: John Edmond Flood, John Wilbur Kelley
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Patent number: 5698657Abstract: Flexible epoxy resins are made by curing the epoxy with an amine curing agent in the presence of a low molecular weight acrylate copolymer made from a major amount of a lower aliphatic ester or amide of acrylic or methacrylic acid and a minor amount of an ethylenically unsaturated monomer having functionality reactive with functional groups present in the epoxy resin or its curing agent. The acrylate copolymer has a number average molecular weight in the range of 1000 to 6000, preferably 2000 to 3000, and a ratio of weight average to number average molecular weight in the range of 1 to 3.5. Copolymers of butylacrylate and acrylic acid or maleic anhydride are favored. Further advantages are realized by including in the cure formulation a monofunctional diluent reactive with the curative.Type: GrantFiled: August 3, 1995Date of Patent: December 16, 1997Assignee: Air Products and Chemicals, Inc.Inventors: Mark David Conner, Richard Henry Bott, William Edward Starner, Lloyd Mahlon Robeson
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Patent number: 5686521Abstract: A milled carbon fiber reinforced polymer having increased abrasion resistive characteristics. The reinforced polymer comprises a base resin selected from the group consisting of polyolefins and polyamides. The base resin is combined with an amount of milled carbon fibers and further may be combined with polytetrafluoroethylene. The resulting composite materials have excellent friction and wear characteristics and are useful in the production of injection molded parts. The molded parts have a high impact strength, exhibit dimensional stability, are abrasion resistive, and are static dissipative, with the composite materials having particular utility as support fixtures for semiconductors during certain processing operations.Type: GrantFiled: April 23, 1996Date of Patent: November 11, 1997Assignee: Empak, Inc.Inventors: Brian Massengale, Paul Schauer, Charles Dahle, Barry Gregerson, Bonnie Bachman, Thomas Oesterle
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Patent number: 5683819Abstract: A composite comprised of a nitrile group-containing highly saturated copolymer rubber and a fibrous material, which copolymer rubber is a product obtained by hydrogenating the conjugated diene portion of an unsaturated nitrile-conjugated diene copolymer. The highly saturated copolymer rubber has an alkylthio group having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and having a sulfur atom which is directly bound to at least one of the tertiary carbon atoms; and the copolymer rubber further has a Mooney viscosity of 15 to 200 and an iodine value not larger than 80. This composite is useful for a belt.Type: GrantFiled: June 6, 1995Date of Patent: November 4, 1997Assignee: Nippon Zeon Co., Ltd.Inventors: Osamu Mori, Mitsugu Ishihara, Motofumi Oyama
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Patent number: 5684089Abstract: A pregellable adhesive containing several polymers, of which at least one is olefinically unsaturated and the other capable of curing by esterification, prepared in such a way that it cures by two different chemical reaction mechanisms which can be activated successively and catalyzed at least substantially independently of one another.Type: GrantFiled: December 13, 1996Date of Patent: November 4, 1997Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Thierry Lanoye, Anne-Marie Garnault
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Patent number: 5681899Abstract: The invention relates to impact modifiers for polyamide compositions which improve the impact strength of the polyamides without adversely affecting the flexural modules of the composition. The impact modifiers comprise blends of general purpose rubbers and a halogenated copolymer of a C.sub.4 to C.sub.7 isomonoolefin and an alkylstyrene. In addition, the invention is drawn to a polyamide composition containing such impact modifiers.Type: GrantFiled: July 17, 1995Date of Patent: October 28, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Hsien-Chang Wang, Dongming Li, Thomas Chen-Chi Yu
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Patent number: 5674819Abstract: This invention relates to compositions which are useful as additives in lubricants and fuels, and more particularly, to additives which are chlorine-free or contain only minor amounts of chlorine. More particularly, carboxylic compositions are described which are prepared by reacting a terpolymer derived from a mixture of monomers comprising ethylene, an alpha-olefin containing 3 to about 20 carbon atoms, and a non-conjugated polyene with an alpha,beta-monounsaturated dicarboxylic acid or reactive derivative thereof. These carboxylic compositions may be used in lubricating oil or fuel compositions or may be used to form carboxylic derivative compositions which are useful in lubricating oil and fuel compositions.Type: GrantFiled: November 9, 1995Date of Patent: October 7, 1997Assignee: The Lubrizol CorporationInventors: Matthew R. Sivik, David E. Ripple
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Patent number: 5672677Abstract: A polyamide hot melt adhesive is provided. It comprises the polyamide condensation product of substantially equivalent quantities of (a) an acid component consisting essentially of one or more polymeric fatty acids and one or more dicarboxylic acids and (b) an amine component consisting essentially of (i) two or more non-cyclic aliphatic diamines and (ii) one or more amine-terminated polyglycol diamines. The amine component is substantially free of piperazine-containing polyamines. The adhesive has an open time of at least 120 seconds. Preferred non-cyclic aliphatic diamines are ethylenediamine and 1,6-diaminohexane, preferably present in about equimolar amounts. The composition may further comprise an aromatic sulfonamide plasticizer. The adhesive is particularly useful for spraying applications.Type: GrantFiled: January 12, 1996Date of Patent: September 30, 1997Assignee: The Dexter CorporationInventors: Paul L. Morganelli, Douglas E. Frost
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Patent number: 5654367Abstract: An alternating copolymer comprising a repeating unit of the formula:--Z--(X--Y).sub.n -- (I)wherein n is at least 2, X is O, S, Se or Te, and Y and Z are independently an aromatic or substituted aromatic group, and at least one other repeating unit, which is useful as a photosensitive material used in a spatial light modulator.Type: GrantFiled: May 26, 1995Date of Patent: August 5, 1997Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Akio Takimoto, Hirofumi Wakemoto, Eiichiro Tanaka, Masanori Watanabe, Junko Asayama, Hisahito Ogawa, Shigehiro Sato, Fumiko Yokotani
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Patent number: 5624994Abstract: The invention relates to a process for the preparation of composite material formed from a vulcanized elastomer, containing carboxylic acid or dicarboxylic acid anhydride groups, in combination with a thermoplastic elastomer containing polyamide blocks, which comprises vulcanizing an elastomer composition comprising said vulcanizable elastomer, a crosslinking system and, optionally, diverse adjuvants in a mold, one part of which is occupied by said thermoplastic elastomer containing polyamide blocks, the vulcanization temperature being between -15.degree. C. and +5.degree. C. with respect to the Vicat point of said thermoplastic elastomer containing polyamide blocks, the elastomer composition and the vulcanization kinetics being such that the material shows cohesive failure when subjected to stress for separation of the two elastomers.This process leads to composite materials which have excellent properties, in particular in respect of tensile strength (cohesive failure).Type: GrantFiled: October 13, 1995Date of Patent: April 29, 1997Assignee: Elf Atochem S. A.Inventors: Marius Hert, Patrick Alex
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Patent number: 5585439Abstract: An unsaturated polyester resin and low profile additive containing diketo groups.Type: GrantFiled: March 29, 1996Date of Patent: December 17, 1996Assignee: Ohio State UniversityInventors: L. James Lee, Reiko Saito, Debbie Y. Chiu
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Patent number: 5583187Abstract: Hot melt adhesive compositions, particularly biodegradable hot melt adhesives are prepared from 10 to 90% by weight of a thermoplastic methylol polyester prepared from the reaction of at least one dicarboxylic acid with a diglycidyl ether, a diglycidyl ester or a combination thereof; 0 to 90% by weight of a compatible tackifier; 0 to 80% by weight of a compatible plasticizer; 0 to 50% by weight of a compatible wax diluent and 0 to 3% by weight of a stabilizer.Type: GrantFiled: May 3, 1995Date of Patent: December 10, 1996Assignee: National Starch and Chemical Investment Holding CorporationInventors: Matthew L. Sharak, Charles W. Paul, Dilip Ray-Chaudhuri
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Patent number: 5576392Abstract: The resin composition of the present invention comprises (A) a cycloolefin resin selected from the group consisting of a random copolymer of a cycloolefin prepared from a specified cycloolefin such as norbornene or tetracyclododecene, a (co)polymer obtained by a ring-opening polymerization of such a cycloolefin and a product of hydrogenation of the above ring-opening (co)polymer; and(B) an oligomer having an allcyclic structure and/or an aromatic ring structure, e.g., a terpene resin oligomer. Therefore, the resin composition of the present invention is especially excellent in coating and bonding suitabilities.Type: GrantFiled: September 22, 1995Date of Patent: November 19, 1996Assignees: Mitsui Petrochemical Industries, Ltd., Hoechst AktiengesellschaftInventors: Yohzoh Yamamoto, Masashi Yatoumaru