With A Polycarboxylic Acid Or Derivative And A Polyamine Or The Corresponding Salt Thereof; Or With A Lactam; Or With An Aminocarboxylic Acid; Or With The Corresponding Polymers; And Wherein The Monomer Or Polymer Was Derived From At Least One Saturated Reactant Patents (Class 525/178)
  • Patent number: 5574080
    Abstract: A building material including reclaimed leather, neoprene, and nylon. The reclaimed materials are shredded and blended together with a matrix material. The matrix material is a polymeric adhesive. The chips with the matrix material are heated to form a uniform mixture. The uniform mixture is then molded into the building material sheets.
    Type: Grant
    Filed: December 26, 1995
    Date of Patent: November 12, 1996
    Inventor: Darwin J. Longhart
  • Patent number: 5567770
    Abstract: This invention relates to liquid crystalline polymers, having a glass transition temperature of greater than 140.degree. C., blended with tetrafluoroethylene polymers, said blends having improved wear properties.
    Type: Grant
    Filed: May 17, 1994
    Date of Patent: October 22, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Robert R. Luise
  • Patent number: 5561192
    Abstract: An unsaturated polyester resin and low profile additive containing diketo groups.
    Type: Grant
    Filed: October 14, 1994
    Date of Patent: October 1, 1996
    Assignee: The Ohio State University
    Inventors: L. James Lee, Reiko Saito, Debbie Yuen-Yuen Chiu
  • Patent number: 5559185
    Abstract: A thermoplastic resin composition superior in impact resistance, heat resistance, flexural rigidity, processability and solvent resistance which comprises: (A) 100 parts by weight of a resin composition comprising 5-95% by weight of a polyphenylene ether, or a polyphenylene ether and polystyrene, and 95-5% by weight of a polyamide resin; (B) 5-50 parts by weight of a modified saturated rubber obtained by grafting 5-100 parts by weight of an aromatic vinyl compound on 100 parts by weight of a saturated type rubber and allowing 0.05-10 parts by weight of a compatibilizing agent to react with said rubber; and (c) 0.05-20 parts by weight of a compatibilizing agent.
    Type: Grant
    Filed: January 13, 1995
    Date of Patent: September 24, 1996
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroomi Abe, Taichi Nishio, Yasurou Suzuki, Mitsuji Tsuji, Takashi Sanada
  • Patent number: 5548037
    Abstract: A process for preparing melt spun polymeric fiber made from polymerized amide monomers includes the steps of pigmenting the polymer, incorporating within the polymer sufficient SO.sub.3 H groups or salts thereof to give the polymer a sulphur content of between about 10 and about 160 equivalents per 10.sup.6 grams polymer and thereafter chemically blocking with a chemical blocking agent a portion of amino end groups present in the sulphonated polymer.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: August 20, 1996
    Assignee: BASF Corporation
    Inventors: Matthew B. Hoyt, Andrew M. Coons, III, David N. Dickson
  • Patent number: 5532053
    Abstract: The present invention relates to a laminate film useful as a material from which to manufacture surgical and other protective garments. The laminate film comprises at least one layer formed from a first polyetherester copolymer produced from the condensation reaction of dimethyl-1,4-cyclo hexane dicarboxylate and 1,4-cyclo hexane dimethanol and poly(tetramethylene ether glycol) and a second layer comprising a material selected from the group consisting of an ethylene-vinyl acetate copolymer, an ethylene methacrylate copolymer, a second polyetherester copolymer, an anhydride modified polyolefin copolymer, and a polyether block amide copolymer. The total amount of the first polyetherester copolymer present in the laminate is greater than or equal to 35 wt. % of the total weight of the laminate film to provide strength to the laminate film. The laminate film may be bonded to one or more layers of polyesters, polyolefins, polyamides, and non-woven fabrics.
    Type: Grant
    Filed: March 1, 1994
    Date of Patent: July 2, 1996
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Walter B. Mueller
  • Patent number: 5516837
    Abstract: A molding resin composition comprising 99.9 to 50% by weight of polyimide represented by the formula: ##STR1## and 0.1 to 50% by weight of polyether ketone resin and/or polyester resin, and more particularly comprising the polyester resin capable of forming an anisotropical molten phase at a temperature of 420.degree. C. or less, and a polyimide-based molding resin composition which comprises the said resins and other additives such as phenolic resin, fluororesin, graphite, carbon fibers, aromatic polyamide fibers, potassium titanate fibers and a crystallization accelerator, and is excellent in thermal resistance, chemical resistance, mechanical strength and processability.
    Type: Grant
    Filed: March 2, 1994
    Date of Patent: May 14, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Toshihiko Tsutsumi, Toshiyuki Nakakura, Toshiaki Takahashi, Atsushi Morita, Yoshihisa Gotoh, Hiroyasu Oochi
  • Patent number: 5506300
    Abstract: The present invention provides a composition that softens at a predetermined temperature, preferably between about 20.degree. C. and 90.degree. C., and more preferably between about 20.degree. C. and about 62.degree. C., comprising at least one block copolymer having at least two thermal transition temperatures. The composition is characterized by at least two thermal transition temperatures, one of which is a predetermined lower transition temperature, preferably between about 20.degree. C. to 90.degree. C., and more preferably between about 20.degree. C. to about 62.degree. C., and one of which is an upper transition temperature. The present invention also provides a method of making the composition, a method of making biomedical materials and articles, and toys and toy components, with shape-memory properties from the composition, and biomedical materials and articles, and toys and toy components, with shape-memory properties made from the composition.
    Type: Grant
    Filed: February 18, 1993
    Date of Patent: April 9, 1996
    Assignee: Thoratec Laboratories Corporation
    Inventors: Robert S. Ward, Judy S. Riffle
  • Patent number: 5498409
    Abstract: An insoluble material for adsorbing a pyrogen comprising a polymer of an aziridine compound. According to the present invention, a large amount of the pyrogen can be easily removed from a solution containing pyrogen, and a large amount of the material for adsorbing the pyrogen can be prepared in easy steps. Therefore, the adsorbing material can greatly contribute to the preparation of medicines.
    Type: Grant
    Filed: February 10, 1993
    Date of Patent: March 12, 1996
    Assignees: Chuichi Hirayama, Kohjin Co., Ltd.
    Inventors: Chuichi Hirayama, Keijun Hiraoka, Sunao Morimoto
  • Patent number: 5494964
    Abstract: Polyester resins suitable as binders for electrophotographic toners and for acceptor layers for the thermal diffusion printing process based on hydroxyl-containing prepolymers of olefinically unsaturated monomers obtained by(1) polymerization of a mixture of(a) from 60 to 90% by weight of styrene or of a styrene derivative,(b) from 0 to 40% by weight of one or more C.sub.1 -C.sub.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: February 27, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Georg Meichsner, Thomas Wuensch, Rainer Dyllick-Brenzinger
  • Patent number: 5484848
    Abstract: The invention describes a process for the production of a composite article of at least two component pieces, firmly bonded to one another, of a vulcanized rubber compound on the one hand and a polyamide composition on the other hand, the vulcanized rubber compound being prepared under customary vulcanization conditions in contact with the polyamide composition by vulcanization of a rubber compound which comprises the following components:I. 100 parts by weight of a rubber,II. 0 to 300 parts by weight of fillers,III. 0 to 150 parts by weight of plasticizer,IV. 1 to 10 parts by weight of peroxide vulcanization agent,V. 0 to 4 parts by weight of vulcanization activators andVI. 1 to 10 parts by weight of a silane containing double bonds.
    Type: Grant
    Filed: April 5, 1994
    Date of Patent: January 16, 1996
    Assignee: Huels Aktiengesellschaft
    Inventors: Hans Jadamus, Friedrich G. Schmidt, Horst Heuer
  • Patent number: 5480941
    Abstract: A process is disclosed for preparing a masterbatch composition of elastomer with a high concentration of aramid fibers, as the sole particulate component, distributed therethroughout.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: January 2, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Arnold Frances
  • Patent number: 5453465
    Abstract: A non-vulcanized thermoplastic composition comprising a polyamide and an elastomeric halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene is prepared by blending the polyamide and elastomeric copolymer in the presence of specified metal compounds in an amount insufficient for vulcanizing the composition. Optionally, the resulting composition may be subjected to vulcanization.
    Type: Grant
    Filed: May 14, 1993
    Date of Patent: September 26, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Thomas C. Yu, Hsien C. Wang, Kenneth W. Powers
  • Patent number: 5439737
    Abstract: A fusible interlining has a textile substrate employed with a single adhesive layer and is intended to be bonded to drapery. The adhesive layer includes a first phase in the form of thermoplastic powder of dense granules whose primary function is to ensure the adhesion of the fusible interlining to the drapery at the time of bonding. A second phase of the adhesive layer is a crosslinkable system including a crosslinkable resin and a hardener in the form of a homogeneous matrix whose main function is to coat the granules of the thermoplastic powder of the bonding system.
    Type: Grant
    Filed: March 19, 1993
    Date of Patent: August 8, 1995
    Assignee: Lainiere de Picardie
    Inventor: Mohamed F. Trabelsi
  • Patent number: 5422398
    Abstract: A compatibilizer for polymer blends is presented. The compatibilizer comprises a sulfonated polystyrene and may be used to prepare miscible blends of the sulfonated polystyrene with two or more polymers having polar groups, e.g., polyamides, polyethers, polyesters, polysulfones and polyamines. The sulfonated polystyrene compatibilizer may be used in conjunction with a counterion.
    Type: Grant
    Filed: August 17, 1994
    Date of Patent: June 6, 1995
    Assignee: The University of Connecticut
    Inventor: Robert A. Weiss
  • Patent number: 5416164
    Abstract: A poly(p-phenylene terephthalamide) composition is disclosed comprising 50 to 95 weight percent PPD-T and 5 to 50 weight percent PVP along with a process for making the composition and articles made from the composition.
    Type: Grant
    Filed: April 12, 1993
    Date of Patent: May 16, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Kiu-Seung Lee
  • Patent number: 5414046
    Abstract: Novel thermally stable resins comprising halogens and not epoxide termination groups are described. The thermally stable resins may be employed in polymer systems to yield flame retardant polymer compositions.
    Type: Grant
    Filed: June 17, 1994
    Date of Patent: May 9, 1995
    Assignee: General Electric Company
    Inventor: Gary C. Davis
  • Patent number: 5410000
    Abstract: Copolyester compositions are provided which comprise the reaction product of at least one straight chain, branched, or cycloaliphatic C.sub.2 -C.sub.10 alkane diol or a chemical equivalent thereof, a mixture of at least two cycloaliphatic diacids or chemical equivalents thereof, the mixture comprising predominantly a trans-enantiomer, and at least one aromatic diacid or a chemical equivalent thereof. These copolyesters have superior ductility to the homopolymers of the diol component and either of the diacid components.
    Type: Grant
    Filed: August 18, 1994
    Date of Patent: April 25, 1995
    Assignee: General Electric Company
    Inventor: Willem F. H. Borman
  • Patent number: 5405657
    Abstract: A process for the production of flexible impregnated protective, auxiliary and insulating materials on a fibre basis for electrical purposes by the application of an impregnating agent to the material to be impregnated, followed by curing, characterised in that a solvent-free impregnating mass containing one or more olefinically unsaturated, radically polymerisable polyesters, which contain one or more radically polymerisable monomers as reactive diluents, one or more plasticizing agents and optionally one or more peroxide-free radical initiators is applied to the material to be impregnated and curing is then carried out with high energy radiation and optionally by further heating.
    Type: Grant
    Filed: November 2, 1993
    Date of Patent: April 11, 1995
    Assignee: Herberts G.m.b.H.
    Inventors: Udo Bastian, Rainer Krause, Gerhard Kiessling
  • Patent number: 5389725
    Abstract: The thermoplastic resin composition containing a fluorine-containing elastomer, which is produced by incorporating a base-treated fluorine-containing elastomer into a thermoplastic resin and has a base-treated fluorine-containing elastomer content of 0.1 to 50% by weight, the composition being excellent in impact resistance and heat resistance and useful for producing various products in the fields of aviation, machinery, office machines, electricity and electronics.
    Type: Grant
    Filed: November 8, 1993
    Date of Patent: February 14, 1995
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Toru Bando
  • Patent number: 5371143
    Abstract: Fluorine-containing thermoplastic elastomeric compositions comprising: (A) a continuous phase comprising: (1) about 0 to 90 weight percent of thermoplastic polymer having a melt temperature or glass transition temperature greater than about 150.degree. C., and (2) about 10 to 100 weight percent of block thermoplastic elastomer having a melt temperature greater than about 150.degree. C.; and (B) a disperse phase comprising particles or domains of cured, fluoroelastomer composition. Such compositions are preferably prepared by dynamically vulcanizing the ingredients of the fluorine-containing thermoplastic elastomeric composition.
    Type: Grant
    Filed: June 18, 1992
    Date of Patent: December 6, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Charles T. Novak, Paul N. Nelson, Sehyun Nam, William DeMoully, Kenneth D. Goebel
  • Patent number: 5371153
    Abstract: The present process for producing aromatic polyamide fibers for reinforcement of rubbers lies in that, in the first step, the fibers are dipped in an epoxy treating solution containing aromatic glycidylamines having 2 or more epoxy groups in one molecule and aromatic amines at a specific ratio and dried and cured, and thereafter, in the second step, the fibers are dipped in a treating solution for the second step containing resorcin formaldehyde resins and rubber latices and dried and cured. More preferably, specific chlorophenol compounds are added to the treating solution for the second step.The aromatic polyamide fibers obtained by the process of the present invention provide rubber products excellent in water resistance when they are used for reinforcement of rubbers, and the products have high adhesive strength in initial adhesion and besides, small decrease in adhesive strength even if they are dipped in water for a long time.
    Type: Grant
    Filed: April 11, 1994
    Date of Patent: December 6, 1994
    Assignee: Sumitomo Chemical Company Limited
    Inventors: Hideyuki Kuribayashi, Tatsuya Koizumi
  • Patent number: 5369171
    Abstract: A polymer mixture reinforced by an in situ, melt-polymerized microphase whereby the rigidity of the base material is increased, a process for manufacturing same, and use thereof for providing reinforced compositions and articles in which the polymer mixture is prepared by polymerizing a component B in a melt of a component A composed of at least one thermoplastic polymer. Component B is composed of at least one compound having the structure ##STR1## The reaction of component B in a melt of component A results in linear, branched or cross-linked, high or low molecular weight polymers constituting a microphase. Preferably, the microphases have the form of microfibers. In the structure of component B, X is NH.sub.2, NHR.sup.3, OH or an N-substituted, Y-activated lactam of the ##STR2## type which is activated with an electrophilic substituent Y, where Y is CO, SO.sub.2, or R.sup.5 P.dbd.O; R.sup.1, R.sup.2 and R.sup.
    Type: Grant
    Filed: June 10, 1992
    Date of Patent: November 29, 1994
    Assignee: Rehau AG + Co.
    Inventors: Rolf Mulhaupt, Joachim Rosch, Siegfried Hopperdietzel, Ekkehard Weinberg, Herbert Klein
  • Patent number: 5364905
    Abstract: A continuous method for the in-situ polymerization of plastic in an elastomeric material in a form suitable for reinforcing the elastomeric material is provided. The method comprises feeding elastomer and a monomer or monomer precursor of a reinforcing material into a mixing device, mixing the elastomer and the monomer or monomer precursor vigorously, initiating polymerization, and causing the monomers to continue to polymerize until the polymer solidifies when the melting point of the polymer produced exceeds the mixing temperature of the elastomer, terminating polymerization.
    Type: Grant
    Filed: April 26, 1991
    Date of Patent: November 15, 1994
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Richard G. Bauer, Donald J. Burlett, Joseph W. Miller, Jr., Gordon R. Schorr, Pradeep M. Bapat
  • Patent number: 5352741
    Abstract: An adhesive composition particularly useful for bonding a heat-recoverable polymeric sleeve around a cable splice to form a cable splice case comprises a polyamide and a copolymer of ethylene and an ester of an ethylenically unsaturated carboxylic acid, said copolymer having a melt flow index of at least 40 as measured according to ASTM D12380-70; the amount of copolymer being at least 38% based on the weight of the polyamide.
    Type: Grant
    Filed: June 5, 1992
    Date of Patent: October 4, 1994
    Assignee: N.V. Raychem S.A.
    Inventors: Etienne L. Dierickx, Noel M. M. Overbergh
  • Patent number: 5350796
    Abstract: A composition for improving the wet strength of cellulosic fibrous webs is comprised of an aminopolyamide-epichlorohydrin acid salt resin having an E/N ratio of from about 0.6 to about 2.0 and from about 1% to about 35% of a water soluble cationic polymer based on the weight of the resin. The composition has a total organic chlorine content of from about 0.5% to 1.0% by weight based on the weight of the aminopolyamide-epichlorohydrin acid salt resin.
    Type: Grant
    Filed: October 25, 1993
    Date of Patent: September 27, 1994
    Assignee: Henkel Corporation
    Inventors: David I. Devore, Nancy Clungeon, Stephen A. Fischer
  • Patent number: 5342894
    Abstract: Graft copolymers of .epsilon.-caprolactam are made by a process in which .epsilon.-caprolactam is polymerized in the presence of a copolymer of an aliphatic acrylate and an ethylenically unsaturated carboxylic acid, such as n-butylacrylate and acrylic acid. Such grafted polymers which have nylon-6 side chains grafted onto the acrylate polymer backbone are useful as hot melt adhesives. In the process for preparing these polymers, the backbone polymer is formed initially by solution polymerization at a moderate temperature and the .epsilon.-caprolactam is then added and the temperature increased in the presence of an acidic catalyst. .epsilon.-Caprolactam can be used as the solvent in the polymerization of the backbone polymer.
    Type: Grant
    Filed: March 13, 1992
    Date of Patent: August 30, 1994
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Lloyd M. Robeson, Robert K. Pinschmidt, Jr., Dilip R. Abayasekara
  • Patent number: 5321079
    Abstract: A thermoplastic polyamide comprising a copolyamide and a modified copolyolefin. The copolyamide is the reaction product of a hexamethylene diamine, which may be substituted with one or more alkyl groups, and a his (4-aminocyclohexyl) alkane which is substituted adjacent to the amino groups, and a dicarboxylic acid.Molded bodies made therefrom have high rigidity, excellent impact resistance over a broad temperature range, low water uptake, high dimensional stability, low permeability to oxygen, and high shape retention on heating. They are particularly suitable for injection molding and extrusion, especially for the preparation of thin walled or large surface area shapes.
    Type: Grant
    Filed: August 5, 1992
    Date of Patent: June 14, 1994
    Assignee: Ems - Inventa AG
    Inventors: Hans D. Torre, Manfred Hoppe
  • Patent number: 5302429
    Abstract: Vinyl aromatic polymers having a minimum molecular weight of about 500,000, and preferably of about 1,500,000, are blended at levels of from about 1 to about 25% with thermoplastic resins to improve the melt rheology of the thermoplastic resins and facilitate blow molding, thermoforming, extrusion and similar processes.
    Type: Grant
    Filed: November 21, 1991
    Date of Patent: April 12, 1994
    Assignee: Rohm and Haas Company
    Inventor: Nazir A. Memon
  • Patent number: 5294384
    Abstract: The present invention is directed to a process for forming a thermoplastic composition from carpet wherein a carpet sample are melt blended without separating the carpet into its component parts. The process of the present invention produces a thermoplastic composition useful as a substitute for virgin thermoplastics in a variety of applications.
    Type: Grant
    Filed: March 25, 1993
    Date of Patent: March 15, 1994
    Assignee: Monsanto Company
    Inventors: Donald J. David, Jerauld L. Dickerson, Thomas F. Sincock
  • Patent number: 5290865
    Abstract: A process for producing a graft copolymer comprising melt-blending:(A) 1 to 90 parts by weight of an ethylene copolymer, based on the weight of the graft copolymer, comprising (a) 40 to 99.9% by weight of ethylene units, (b) 0 to 60% by weight of .alpha.,.beta.-unsaturated carboxylic acid alkyl ester units, and (c) 0.1 to 10% by weight of maleic anhydride units;(B) 0.1 to 10 moles of a lactam metal salt compound per mole of the maleic anhydride units (c) of the ethylene copolymer (A); and(C) 10 to 99 parts by weight of a lactam compound, based on the weight of the graft copolymer,which results in a graft copolymer having high impact strength, high flexibility, satisfactory dyeability, and well-balanced physical properties over a wide temperature range.
    Type: Grant
    Filed: December 1, 1992
    Date of Patent: March 1, 1994
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Tadayuki Ohmae, Yoshiki Toyoshima, Toshio Kawakita
  • Patent number: 5288532
    Abstract: An extruded film article such as a bag comprises a blend of a thermoplastic polymer such as ethylene vinyl acetate and an olefinic oxide polymer such as poly (ethylene oxide), with a modifier such as liquid smoke absorbed in the blend. The modifier is transferable from the film to a receiving surface such as a food body in fluid transfer relationship with the film.
    Type: Grant
    Filed: October 27, 1992
    Date of Patent: February 22, 1994
    Assignee: Viskase Corporation
    Inventors: Roger L. Juhl, Stanley Lustig, Donatas Tijunelis
  • Patent number: 5283284
    Abstract: Polypropylene resins are improved in mechanical properties and in rigidity without loss in thermal processability when blended with polyphthalamide resins together with a minor amount of a carboxylated polyolefin compatibilizing aid. Filled compositions, including glass-filled polypropylenes are similarly benefited when blended with a polyphthalamide and a carboxylated polyolefin compatibilizing aid.
    Type: Grant
    Filed: May 29, 1992
    Date of Patent: February 1, 1994
    Assignee: Amoco Corporation
    Inventors: Gary T. Brooks, Brian L. Joss, Charles L. Myers
  • Patent number: 5281659
    Abstract: Provided are polyester compositions having thermally stable colorants copolymerized therein, said colorants comprised of at least one electron-rich aromatic moiety attached to a negatively substituted 2,5-dioxypyrrolin-3-yl moiety and containing at least one, and preferably, two polyester reactive groups. Also provided are polyester color concentrates and blends of the colored polyester compositions with other thermoplastic polymers and shaped or formed articles comprised of same.
    Type: Grant
    Filed: November 2, 1992
    Date of Patent: January 25, 1994
    Assignee: Eastman Kodak Company
    Inventors: Max A. Weaver, Clarence A. Coates, William W. Parham, Samuel D. Hilbert, James J. Krutak, Wayne P. Pruett
  • Patent number: 5278214
    Abstract: The present invention discloses a polyolefin resin composition comprising a specific cycloolefin-based polymer (a), a graft-modified elastomer (b) and a compound (c) having one amino group in the molecule, and containing, based on the total amount of the components (a), (b) and (c), 50 to 95% by weight of the component (a), 1 to 50% by weight of the component (b) and 0.01 to 45% by weight of the component (c). This polyolefin resin composition is improved particularly in mechanical properties such as impact strength, etc., while retaining excellent properties of the cycloolefin-based polymer (a).
    Type: Grant
    Filed: January 29, 1992
    Date of Patent: January 11, 1994
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Satoru Moriya, Akio Ishimoto, Mamoru Takahashi
  • Patent number: 5272221
    Abstract: The present invention provides a nylon composition having increased hydrolyzability which is obtained by physically mixing 100 parts by weight of a nylon with 1 to 50 parts by weight of at least one polymer selected from the group consisting of polylactic acid, polyglycolic acid and a copolymer containing 50 mol % or more of a lactic acid unit or a glycolic acid unit as a repeating unit in its chain; and a method for increasing the hydrolyzability of a nylon by preparing such a composition. High hydrolyzability can be imparted to the nylon inherently having extremely low hydrolyzability without impairing its original mechanical strength. Therefore, various molded articles made from the nylon can be hydrolyzed under natural circumstances, and thus the wastes are not stored.
    Type: Grant
    Filed: April 3, 1992
    Date of Patent: December 21, 1993
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Toshio Kitao, Yoshiharu Kimura, Hideki Yamane, Hiroki Nakata, Hosei Shinoda
  • Patent number: 5270401
    Abstract: Disclosed is a plastics composition comprising a thermoplastic blend comprising: (1) 5-95 wt % of a polyamide (PA) and 95-5 wt % of a polyester (PE) incorporating 1-50 wt % of an aliphatic dimer fatty acid, (2) 0.01-30 parts by weight of a compound having at least one ethylenically unsaturated group or propylene group and further having a carboxylic, acid anhydride, acid amide, imido, carboxylic ester, amino or hydroxyl group per 100 parts by weight based on the combined weight of PA and PE, (3) 0-90 parts by weight of a polyester not modified with dimer fatty acid per 100 parts by weight based on the combined weight of PA and PE. Preferably the polyester (PE) is a polyethylene terephthalate or polybutylene terephthalate modified with di-oleic acid. The blends have a greatly improved elongation at break and are readily spinnable.
    Type: Grant
    Filed: October 11, 1991
    Date of Patent: December 14, 1993
    Assignee: DSM N.V.
    Inventors: Chi K. Sham, Wilhelmus T. M. Jansen, Martin A. Doherty
  • Patent number: 5268445
    Abstract: The invention relates to segmented copolyesteramides built up from units derived from one or more flexible segments, 1,4-butanediol, 1,4-butanediamine and terephthalic.
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: December 7, 1993
    Assignee: General Electric Company
    Inventors: Reinoud J. Gaymans, Jeannette L. Haan
  • Patent number: 5268134
    Abstract: Hoses are often reinforced with fabric to improve their performance characteristics, such as burst strength. By utilizing the technique of this invention, hose which has a high level of burst strength can be manufactured without including continuous yarn reinforcement. This invention specifically reveals a process for manufacturing a hose which involves the steps of (1) extruding a rubber composition into the form of a tube, wherein the rubber composition contains (a) an EPDM alloy comprised of (i) standard EPDM rubber, (ii) an EPDM rubber having thermoplastic side chains grafted thereto, and (iii) dispersed thermoplastic wherein the thermoplastic is selected from the group consisting of nylons, polyesters, and polyphenylene oxides, (b) an EPDM rubber, (c) carbon black, (d) at least one curative, (e) zinc oxide, (f) a processing oil, and (g) stearic acid; (2) shaping the tube into the geometric form desired for the hose; and (3) curing the rubber composition at a temperature within the range of 130.degree. C.
    Type: Grant
    Filed: June 15, 1992
    Date of Patent: December 7, 1993
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Donald J. Burlett, Kevin J. Pyle, Mark S. Sinsky, Ricahrd G. Bauer, Deborah A. Tung, Vetkav R. Parameswaran
  • Patent number: 5268029
    Abstract: This invention provides cationic emulsions of bituminous binders of the bitumen/polymer type, formed by a dispersion of an organic phase of the binder in an aqueous phase containing a cationic nitrogenous emulsifier and a mineral or organic acid, the acid being in appropriate quantity so that the pH of the aqueous phase is comprised between 3 and 9. The aqueous phase also contains an agent consisting of at least one water-soluble sequestering salt of polyfunctional nitrogenized carboxylic acid, particularly a salt of alkaline metal or of amine of mono- and di (hydroxy-2 ethyl) glycine and optionally a water-soluble thickening agent. To obtain the emulsions, which are usable for road applications, the emulsifying agent, the sequestering agent and optionally the thickening agent may be used in the form of a premixture containing the agents and called cationic emulsifying system.
    Type: Grant
    Filed: September 17, 1991
    Date of Patent: December 7, 1993
    Assignee: ELF France
    Inventors: Francis Demangeon, Emile Lopez
  • Patent number: 5264523
    Abstract: A uniform mixture of a polytetrafluoroethylene molding powder and an organic filler, which can provide moldings having improved properties without lowering the appearance and mechanical property, is obtained without sticking the filler to the wall of a mixer by mixing the molding powder and the filler in the presence of a silane coupling agent and a polar solvent, or by previously treating the organic filler with the silane coupling agent and mixing the treated filler with the molding powder.
    Type: Grant
    Filed: August 1, 1990
    Date of Patent: November 23, 1993
    Assignee: Daikin Industries, Ltd.
    Inventors: Norimasa Honda, Tomohiko Hirata, Hirokazu Yukawa
  • Patent number: 5262496
    Abstract: A process for making polymers of conjugated dienes which contain hydroxyl groups, including highly reactive primary hydroxyl groups, in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from at least 0.1 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol having one unprotected hydroxyl group in a solvent in the presence of a Lewis acid selected from the group consisting of MX.sub.n where M is selected from the group consisting of boron, aluminum, iron and tin, and X is a halogen, and organic complexes of such acids.A diene polymer containing 0.
    Type: Grant
    Filed: April 16, 1993
    Date of Patent: November 16, 1993
    Assignee: Shell Oil Company
    Inventors: Robert C. Bening, James R. Erickson, Charles J. Stark, David J. St. Clair
  • Patent number: 5260374
    Abstract: The present invention relates to improved polyphenylene ether-polyamide composition wherein the polyamide component comprises a mixture of amorphous and crystalline polyamide.
    Type: Grant
    Filed: December 28, 1990
    Date of Patent: November 9, 1993
    Assignee: General Electric Company
    Inventor: Robert R. Gallucci
  • Patent number: 5258461
    Abstract: Polymer films are formed by electrocodeposition of solutions containing a dispersion of charged particles of a first polymer and charged particles of a second polymer. Microheterogeneous films are obtained having micro-domains of a minor component polymer dispersed in the major component polymer. Processes for preparing dispersions for electrocodeposition are also provided In a first process, two polymers are dissolved in a common solvent and then dispersed as small charged particles in another solvent which is a precipitant for both polymers. In another process, a dispersion of a first polymer is prepared by adding a solution of the first polymer to a dispersant solvent, and then a solution of a second polymer is dispersed in the dispersion of the first polymer. In another process, a solution of the second polymer is added to a dispersion of the first polymer which contains only a single non-solvent for the second polymer.
    Type: Grant
    Filed: November 26, 1990
    Date of Patent: November 2, 1993
    Assignee: Xerox Corporation
    Inventors: John S. Facci, Ronald E. Jansen, David H. Pan, William G. Herbert, Donald S. Sypula, Joseph Mammino
  • Patent number: 5252672
    Abstract: The invention relates to improved polymer blends of polyamides and vinyl polymers containing sulfonamide structural units. Polyamide molding compounds having reduced water absorption and improved dimensional stability coupled with good mechanical properties, such as impact strength and rigidity, minimal discoloration, high heat resistance and migration resistance, are thus obtained.
    Type: Grant
    Filed: December 3, 1991
    Date of Patent: October 12, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Georg Heger, Holger Lutjens, Gerd Fengler, Christian Lindner
  • Patent number: 5252673
    Abstract: A macromolecular mitomycin derivative excellent in antitumor ability is produced by causing a specific divinyl ether-maleic anhydride copolymer to react with a specific aminocarboxylic acid and causing mitomycin C to react on the resultant reaction product. The derivative is optionally converted into a pharmacologically acceptable salt.
    Type: Grant
    Filed: March 12, 1992
    Date of Patent: October 12, 1993
    Assignees: Agency of Industrial Science & Technology, Ministry of International Trade & Industry
    Inventors: Takashi Hirano, Takeshi Todoroki, Shinichi Ohashi
  • Patent number: 5252661
    Abstract: Thermoplastic molding compositions contain as essential componentsA) 40-95% by weight of a partly aromatic copolyamide composed essentially ofA.sub.1) 20-90% by weight of units derived from terephthalic acid and hexamethylenediamine,A.sub.2) 0-50% by weight of units derived from .epsilon.-caprolactam andA.sub.3) 0-80% by weight of units derived from adipic acid and hexamethylenediamine,B) 5-60% by weight of an impact modifying rubber, and in additionC) 0-50% by weight of fibrous or particulate fillers or mixtures thereof.
    Type: Grant
    Filed: April 6, 1992
    Date of Patent: October 12, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Horst Reimann, Gunter Pipper, Hans-Peter Weiss, Christoph Plachetta, Eckhard M. Koch, Gerd Blinne, Walter Goetz, Peter Steiert
  • Patent number: 5250625
    Abstract: The cross-linking of halogenated polymers such as chlorinated polyethylene with bis-(2,5-dimercapto-1,3,4-thiadiazole) in the presence of a basic substance may easily be carried out and leads to improved properties of the vulcanisate, in particular when amidamines such as, for example, tetraethylene pentamine distearate are used as basic substances.
    Type: Grant
    Filed: April 16, 1991
    Date of Patent: October 5, 1993
    Assignee: Rhein Chemie Rheinau GmbH
    Inventor: Helfried Ehrend
  • Patent number: 5250624
    Abstract: A miscible blend composition comprising (a) a polyamide having a melting point greater than about 175.degree. C. or is amorphous and (b) a vinylphenol containing polymer. The blend is particularly useful for packaging applications due to its chemical resistance and clarity.
    Type: Grant
    Filed: May 7, 1992
    Date of Patent: October 5, 1993
    Assignee: Eastman Kodak Company
    Inventors: David M. Teegarden, Christine J. T. Landry, Michael R. Landry, Timothy E. Long, Dennis J. Massa, Ralph H. Colby
  • Patent number: RE34984
    Abstract: The present invention provides a nylon composition having increased hydrolyzability which is obtained by physically mixing 100 parts by weight of a nylon with 1 to 50 parts by weight of at least one polymer selected from the group consisting of polylactic acid, polyglycolic acid and a copolymer containing 50 mol % or more of a lactic acid unit or a glycolic acid unit as a repeating unit in its chain; and a method for increasing the hydrolyzability of a nylon by preparing such a composition. High hydrolyzability can be imparted to the nylon inherently having extremely low hydrolyzability without impairing its original mechanical strength. Therefore, various molded articles made from the nylon can be hydrolyzed under natural circumstances, and thus the wastes are not stored.
    Type: Grant
    Filed: April 7, 1994
    Date of Patent: June 27, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Toshio Kitao, Yoshiharu Kimura, Hideki Yamane, Hiroki Nakata, Hosei Shinoda