With A Polycarboxylic Acid Or Derivative And A Polyamine Or The Corresponding Salt Thereof; Or With A Lactam; Or With An Aminocarboxylic Acid; Or With The Corresponding Polymers; And Wherein The Monomer Or Polymer Was Derived From At Least One Saturated Reactant Patents (Class 525/178)
  • Patent number: 5244974
    Abstract: The invention relates to polymers containing units of the structure ##STR1## or mixtures of A with more than one of B, B-1 and B-2; wherein R and R.sup.1 are each independently C.sub.1 to C.sub.18 alkyl;R.sup.2 is oxygen, sulfur or --NR.sup.5 --;R.sup.5 is hydrogen or lower alkyl;R.sup.3 is alkylene having from 3 to 6 carbon atoms, optionally mono- or di- substituted with lower alkyl;W is hydrogen --NH.sub.4, an alkali metal or an alkaline earth metal;Y is alkylene;Z is hydrogen, --NH.sub.4, an alkali metal or an alkaline earth metal or mixtures thereof;X is lower alkyl, a hydroxy phenyl radical or mixtures thereof;t has a value of from 2 to 8 andm, m', m" and n independently have a value of from 30 to 3,500 and n represents at least 5 mole percent of the polymeric product. The invention is also related to the synthesis of the above polymers and to their use as superior adhesives which have significantly improved bond strength.
    Type: Grant
    Filed: September 20, 1991
    Date of Patent: September 14, 1993
    Assignee: ISP Investments Inc.
    Inventors: Ratan K. Chaudhuri, Jenn S. Shih
  • Patent number: 5241007
    Abstract: Fluorinated styrenes of the formula I; ##STR1## where R.sub.1 is a C.sub.1 -C.sub.6 alkyl and R.sub.2 is the repeating unit ##STR2## where x is zero or any positive integer, which are useful as compatibilizing and toughening agents for various polymers such as styrene, dienes (butadiene, isoprene, etc.) acrylates, polymethacrylates, polycarbonates, polyesters, polyamides, etc. Particularly preferred are p-(1,1,1,3,3,3-hexafluoro-2-hydroxy isopropyl)-.alpha.-methylstyrene, polymers thereof, block and random copolymers thereof and polymer blends incorporating the same.
    Type: Grant
    Filed: January 21, 1992
    Date of Patent: August 31, 1993
    Assignee: The United Statets of America as represented by the Secretary of Commerce
    Inventors: Charles C. Han, Manjun He, Yongming Liu, Yi Feng, Ming Jiang
  • Patent number: 5234997
    Abstract: A fiber-reinforced chlorinated polyethylene composition comprises 100 parts by weight of a continuous phase of a chlorinated polyethylene and 2-100 parts by weight of a polyamide dispersed in the continuous phase in a fine short fiber form. Further a process comprises kneading a chlorinated polyethylene and a fiber-formable polyamide at a temperature not lower than the melting point of the polyamide and then stretching the kneaded product to obtain the above fiber-reinforced chlorinated polyethylene composition. When in the above process, the kneading is effected by further adding a reactive binder, there can be obtained a fiber-reinforced chlorinated polyethylene composition wherein the compatibility and dispersion of the fiber-formable polyamide with and in the chlorinated polyethylene are improved.
    Type: Grant
    Filed: March 20, 1990
    Date of Patent: August 10, 1993
    Assignee: Ube Industries, Ltd.
    Inventors: Kunio Oda, Denichi Oda, Yuichi Fujii, Takeshi Takagi
  • Patent number: 5227430
    Abstract: The invention relates to compatible polymer mixtures of a polyamide and a special vinyl monomer containing copolymerized structural units of the bisphenol derivative type. The new mixtures are suitable for the production of thermoplastic molding compounds.
    Type: Grant
    Filed: April 29, 1991
    Date of Patent: July 13, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Holger Lutjens, Karl-Erwin Piejko, Rudiger Plaetschke
  • Patent number: 5225489
    Abstract: This invention relates to mixtures of short fibers of varying lengths, diameters and aspect ratios composed of an anisotropic polymer, to compositions containing said fibers and one or more thermoplastic or thermoset resins, and to a process for forming said mixtures.
    Type: Grant
    Filed: December 11, 1990
    Date of Patent: July 6, 1993
    Assignee: Allied-Signal Inc.
    Inventors: Dusan C. Prevorsek, Kwok W. Lem, Hong B. Chin
  • Patent number: 5223571
    Abstract: A refrigerant-transport hose having an inner tube, an outer tube located radially outwardly of the inner tube, and a reinforcing fiber layer interposed between the inner and outer tubes, the reinforcing fiber layer and the inner and outer tubes providing an integral tubular body, and inner tube including a gas-impermeable resinous layer formed of a composition containing a polyamide resin produced by reaction of hexamethylene diamine and an aliphatic dicarboxylic acid having eight to sixteen carbon atoms.
    Type: Grant
    Filed: January 17, 1992
    Date of Patent: June 29, 1993
    Assignee: Tokai Rubber Industries, Ltd.
    Inventors: Ichiro Igarashi, Hiroaki Ito
  • Patent number: 5200468
    Abstract: Polymer compositions are provided which are capable of being formed into shaped articles and comprise a poly(2-methylpentamethylene terephthalamide), also known as nylon M5T, and a minor amount of an ionomer, e.g., a partially neutralized copolymer of an alpha-olefin and an alpha, beta-ethylenically unsaturated carboxylic acid. In particular, the compositions may be melt spun and drawn into filaments having good mechanical properties.
    Type: Grant
    Filed: October 23, 1990
    Date of Patent: April 6, 1993
    Assignee: Hoechst Celanese Corp.
    Inventor: Joseph Pickton
  • Patent number: 5198500
    Abstract: Disclosed is an improved process of the post-emulsion method capable of forming crosslinked resin particles which do not have fusion bonds between particles and which have good storage stability and good redispersibility in an aqueous medium. The process comprises (a) dispersing in an aqueous medium a resinous component comprising (I) a base resin having a glass transition temperature (Tg) of 0.degree. C. or less and a polymerizable double bond, (II) a monomer which, when polymerized, provides a resin of which Tg is 20.degree. C. higher than that of said base resin, or a resin of which Tg is 20.degree. C. higher than that of the base resin, and (III) a polyvinyl compound; (b) crosslinking inside the dispersed resin particles and; (c) removing the aqueous medium therefrom.
    Type: Grant
    Filed: January 15, 1991
    Date of Patent: March 30, 1993
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Hisaichi Muramoto, Yusuke Ninomiya, Keizou Ishii, Shinichi Ishikura
  • Patent number: 5189107
    Abstract: Polymer particles prepared by polymerizing polymerizable monomers by seed polymerization, with far more excellent polymerization stability than conventional seed polymerization processes, in the presence of a polymer emulsion comprising low molecular weight polymer particles, radically polymerizable in an aqueous system. The polymer particles are present in an amount of 0.5-30 parts by weight (on solid basis) per 100 parts by weight of polymerizable monomers, have a weight average molecular weight of 500-10,000 and are prepared by emulsion polymerization or soap-free polymerization. The seed polymerization is carried out by initially charging less than 30% by weight of said polymerizable monomers to the polymerization mixture, and after the polymerization conditions are established, by continuously or intermittently adding the remaining portion of said polymerizable monomers to the reaction system.
    Type: Grant
    Filed: March 6, 1990
    Date of Patent: February 23, 1993
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Kiyoshi Kasai, Fujio Sakurai, Hiroshi Tadenuma
  • Patent number: 5179183
    Abstract: Curable compositions based on (N-substituted carbamoyloxy)alkanoyloxyalkyl acrylate polymers. When cured the compositions are, for example, high-quality industrial finishes, sealants or encapsulants.
    Type: Grant
    Filed: June 30, 1989
    Date of Patent: January 12, 1993
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Joseph V. Koleske, Donald F. Smith, Jr., Robert J. Weber, Jr.
  • Patent number: 5169582
    Abstract: In a method and apparatus for the production of thermoplastic, caprolactam containing molding compositions by hydrolytic polymerization of caprolactam in stirrer autoclaves in which a molten mass is polymerized at pressures of 5 to 20 bar and temperatures of 220.degree. to 280.degree. C., the molten mass is transferred into an intermediate vessel to which vacuum is applied for continued polymerization and removal of volatile portions. Subsequently, the mass is continuously fed into a multi-screw extruder, in order to attain at increased temperatures and vacuum the desired polymerization degree and the desired monomer and oligomer contents. In a subsequent zone of the extruder, when desired, additional agents are worked in, whereafter a further degasification occurs in the end zone of the extruder, whereafter the mass is extruded, quenched, subdivided and dried. The method and apparatus use relatively little energy as compared with the prior art.
    Type: Grant
    Filed: September 11, 1989
    Date of Patent: December 8, 1992
    Assignee: EMS-Inventa AG
    Inventor: Gerhard Illing
  • Patent number: 5137974
    Abstract: Hot melt adhesive composition of ethylene copolymer grafted with lactam oligomer, characterized by improved melt flow characteristics.
    Type: Grant
    Filed: April 25, 1990
    Date of Patent: August 11, 1992
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: George W. Prejean
  • Patent number: 5132368
    Abstract: The subject invention provides a composition having excellent extrusion characteristics comprising a difficulty-melt-processible polymer and 0.002-0.5 wt. % of one or more fluoropolymer process aids wherein the fluoropolymer has a fluorine to carbon ratio of at least 1:2, is capable of forming a die-coating film under the prevailing conditions of extrusion temperature and pressure, and contains an effective amount of polar functional polymer chain end groups, --W, wherein --W is selected from --COF, --SO.sub.2 F, --SO.sub.3 M, --OSO.sub.3 M, --COOR, and --COOM, wherein R is C.sub.1-3 alkyl and M is hydrogen, a metal cation, preferably an alkali or alkaline earth metal cation, or a quaternary ammonium cation.
    Type: Grant
    Filed: September 3, 1991
    Date of Patent: July 21, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: George R. Chapman, Jr., Donnan E. Priester, Charles W. Stewart, Robert E. Tarney
  • Patent number: 5115025
    Abstract: This invention is directed to polymers (including oligomers) that contain (N-substituted carbamoyloxy)alkanoyloxyalkyl acrylates, to a process for their preparation by reacting the carbamoyloxy alkanoyloxyalkyl acrylates with themselves, with lactone acrylates, and/or with other ethylenically unsaturated monomers, and to coating, ink, adhesive, and sealant compositions (including the cured coatings, inks, adhesives, and sealants) that are obtained by curing the above compositions by various means. The cured compositions, which are, for example, high-quality industrial finishes, sealants or encapsulants, are preferably made by incorporation of various conventional crosslinking agents and other normally-used formulating ingredients with the polymeric compositons of the invention.
    Type: Grant
    Filed: June 30, 1989
    Date of Patent: May 19, 1992
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Joseph V. Koleske, Donald F. Smith, Jr., Robert J. Weber, Jr.
  • Patent number: 5106910
    Abstract: Improved polyamide-based compositions are provided which are particularly formulated for plasma-spray application to surfaces subjected to acidic conditions. The compositions include respective amounts of polyvinylidene fluoride, a polyamide (e.g., Nylon 11) and a compatable adhesive such as a nylon terpolymer adhesive.
    Type: Grant
    Filed: November 9, 1989
    Date of Patent: April 21, 1992
    Assignee: Applied Polymer Systems
    Inventors: Larry G. Weidman, Alma L. Coats
  • Patent number: 5094806
    Abstract: A process of blow molding, and compositions useful in the process. The articles are blow molded from compositions formed from thermoplastic polymeric material, a fluorinated olefinic polymer or copolymer and, optionally, an elastomeric impact modifier.
    Type: Grant
    Filed: November 6, 1989
    Date of Patent: March 10, 1992
    Assignee: The Dow Chemical Company
    Inventor: Michael K. Laughner
  • Patent number: 5077338
    Abstract: A method of preparing a fiber reinforced elastomer by forming fibers therein in-situ and an elastomer made thereby are provided. In the method, a fiber forming material, preferably a high performance polymer, is dissolved in a compatible solvent to form a solvent/polymer mixture, and the mixture is added to the elastomer during compounding or mixing. The polymer is quickly dispersed into the elastomer, and the solvent rapidly evaporates. The shear of the mixer causes elongation of the polymer into fibers. The fibers may also be oriented by the shear of the mixer.
    Type: Grant
    Filed: August 23, 1990
    Date of Patent: December 31, 1991
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: William C. T. Tung, Deborah A. Tung, Mellis M. Kelley, Douglas C. Callander, 1
  • Patent number: 5075380
    Abstract: This invention relates to soft, rubber-like, thermoplastically processible polymer alloys based on 10 to 50% by weight of (cyclo)aliphatic, thermoplastic polyamides and 90 to 50% by weight of special cross-linked, particulate alkyl acrylate copolymer rubbers suitable for the preparation of rubber-like, elastic moulding compounds.The invention also relates to a process for their preparation.
    Type: Grant
    Filed: August 10, 1990
    Date of Patent: December 24, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Lindner, Lothar Meier, Otto Billinger, Karl-Erwin Piejko
  • Patent number: 5049606
    Abstract: A thermosetting resin composition formed of a polyaminobismaleimide resin, which is composed of a bismaleimide compound and a diamine compound, and a solid lubricant. The composition has low coefficient of friction and excellent wear resistance, and can be utilized for self-lubricating parts.
    Type: Grant
    Filed: February 27, 1990
    Date of Patent: September 17, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Norimasa Yamaya, Masahiro Ohta, Akihiro Yamaguchi
  • Patent number: 5039784
    Abstract: A process for the continuous and discontinuous production of polycaprolactam is disclosed which includes the step of polymerizing, by anionic polymerization, .epsilon.-caprolactam to which suitable initiators and activators are added. The process may optionally include the addition of comonomers, pigments, electroconductive fillers, modifying polymers, inorganic fillers, reinforcing fibers, inorganic fillers and/or other additives to a dispersing media in which the polymerization takes place with polycaprolctam, copolymers or composites thereof being obtained in the form of particles. The foregoing additives may, for example, be added to the dispersing media dropwise with mechanical or convective stirring under controlled temperature conditions.
    Type: Grant
    Filed: November 22, 1989
    Date of Patent: August 13, 1991
    Inventor: Giovanni Canalini
  • Patent number: 5026742
    Abstract: Radiation-crosslinkable contact adhesive mixtures are prepared from polymers having a glass transition temperature of less than 0.degree. C. and a K value of from 20 to 80, derivatives of dihydroxypropyl (meth)acrylates as reactive diluents and small amounts of polymerizable tertiary amino compounds by a process in which the mixture is heated at from 80.degree. to 120.degree. C. for not more than 2 hours and solvents are then separated off under atmospheric or reduced pressure.
    Type: Grant
    Filed: August 15, 1989
    Date of Patent: June 25, 1991
    Assignee: BASF Aktiengesellschaft
    Inventor: Gerd Rehmer
  • Patent number: 5008339
    Abstract: A mixed polymer material is formed of a polyelectrolyte ternary copolymer having a hydrophobic backbone and containing 10 to 90 percent unsubstituted portions and the remainder being substituted with hydrophilic groups such as a styrene ternary copolymer of the formula: ##STR1## where R.sup.1 is alkyl, preferably ethyl, and R.sup.5 is hydroxyalkyl, preferably hydroxethyl. The ternary copolymer self-segregates into discrete hydrophilic and hydrophobic domains and is believed to act as a template to segregate the polyelectrolyte into the domains. The mixed polymer has large ion-exchange capacity, very high effective diffusion constants of incorporated counter-ions and prolonged retention of multiply-charged counter-ions. The mixed polymer forms a stable and effective coating for electrodes for electrocatalytic applications.
    Type: Grant
    Filed: July 8, 1988
    Date of Patent: April 16, 1991
    Assignee: California Institute of Technology
    Inventors: Fred C. Anson, Donald D. Montgomery
  • Patent number: 5003009
    Abstract: Impact-resistant nylon molding materials containA a linear, thermoplastic nylon composed of radicals derived from terephthalic acid and isophthalic acid and alkanediamines of 4 to 10 carbon atoms, andB from 5 to 60% by weight, based on A, of one or more copolymers of1. from 50 to 80% by weight of ethylene,from 20 to 50% by weight of a primary or secondary C.sub.2 -C.sub.8 -alkyl ester of (meth)acrylic acid andfrom 0.5 to 10% by weight of a monomer possessing an acidic functional group or a latent acidic functional group, or2. from 70 to 98% by weight of a primary or secondary C.sub.2 -C.sub.8 -alkyl ester of (meth)acrylic acid,from 1 to 30% by weight of a monomer possessing an acidic functional group or a latent acidic functional group, andfrom 1 to 5% by weight of a monomer containing 2 or more olefinic double bonds in the molecule,the percentages stated in 1. and 2. summing to 100% in each case, andC. if required, effective amounts of additives.
    Type: Grant
    Filed: July 20, 1988
    Date of Patent: March 26, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans G. Matthies, Horst Reimann
  • Patent number: 4996263
    Abstract: It is desirable to increase the modulus of rubbers utilized in a wide variety of applications. This invention discloses a technique for modifying rubbers to improve their modulus without sacrificing other properties. The subject invention more specifically relates to a process for preparing a rubber composition having a high modulus which comprises reacting maleic anhydride with at least one polydiene rubber and at least one nylon.
    Type: Grant
    Filed: October 6, 1988
    Date of Patent: February 26, 1991
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: James B. Pyke, Richard G. Bauer, Martin P. Cohen, Pawan K. Handa
  • Patent number: 4994524
    Abstract: Dispersions of core-shell polymers in caprolactam wherein the core-shell polymer comprises a crosslinked elastomer core and a hard thermoplastic shell prepared by adding an aqueous dispersion of core-shell polymer to an aqueous solution of caprolactam, stirring the mixture to provide a uniform dispersion and evaporating water from the mixture. Such dispersions can be combined with caprolactam polymerization initiator and caprolactam polymerization catalyst to provide rubber-modified nylon-6 polymers.
    Type: Grant
    Filed: July 27, 1988
    Date of Patent: February 19, 1991
    Assignee: Monsanto Company
    Inventor: Kishore Udipi
  • Patent number: 4992311
    Abstract: Disclosed herein are a resin composition comprising 5 to 95% by weight of a vinylidene chloride resin and 5 to 95% by weight of a polyamide resin having a low crystalline melting point of not higher than 210.degree. C. and a molded product of said resin composition.The molded product of the present invention shows a molded product excellent in gas-barrier property and impact strength at low temperature, particularly a film, sheet or container.Among the resin compositions of the present invention, since the composition having 60 to 95% by weight of vinylidene chloride resin is particularly rich in gas-barrier property, it is suitable for packaging foods, and since the composition having more than 40% by weight and not more than 95% by weight of polyamide resin is excellent particularly in impact strength at low temperature, it is suitable as the packaging material for use at an extremely low temperature.
    Type: Grant
    Filed: April 4, 1989
    Date of Patent: February 12, 1991
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Nobuyuki Hisazumi, Tsutomu Uehara, Hiroyuki Ohba, Kazuhiko Hirose
  • Patent number: 4987017
    Abstract: A thermoplastic elastomer composition which comprises 25-95% by weight of a polyamide and 75-5% by weight of a halogenated butyl rubber, a chlorosulfonated polyethylene or both thereof. Said composition is excellent in resistance to Freon gas permeation and has good oil resistance and low-temperature resistance. A hose wherein the layer to be contacted with a gas is made of the above thermoplastic elastomer composition is suitable as a Freon gas R-22 hose.
    Type: Grant
    Filed: February 28, 1990
    Date of Patent: January 22, 1991
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Hozumi Sato, Humito Shimada, Akio Sakaguchi, Yasuhiko Takemura, Tadaaki Nishi, Hisao Ono, Masanobu Nagano, Takumi Miyachi
  • Patent number: 4980419
    Abstract: The invention relates to polymers containing a lactam functionality and having in its molecule repeating units of the general formula: ##STR1## wherein R.sup.1 is C.sub.1 to C.sub.18 alkyl;R.sup.2 is oxygen, sulfur or amino;R.sup.3 is alkylene having 3 to 6 carbon atoms optionally substituted with lower alkyl;Z is hydrogen, an alkali metal, an alkaline earth metal or ammonia;n has a value of from 30 to 3,500 andt has a value of from 2 to 8;and to the use and synthesis of said polymer.
    Type: Grant
    Filed: July 3, 1989
    Date of Patent: December 25, 1990
    Assignee: GAF Chemicals Corporation
    Inventor: Ratan K. Chaudhuri
  • Patent number: 4952630
    Abstract: Dispersion-process-produced, non-melt-processible, particulate, core-shell, tetrafluoroethylene copolymer comprising recurring units of tetrafluoroethylene and modifying recurring units of at least one ethylenically unsaturated comonomer that is copolymerizable with the tetrafluoroethylene, the number of recurring units of comonomer in the shell being sufficient to enable the copolymer to compound uniformly with an elastomer or plastic without forming visible agglomerates, and blends thereof with elastomeric and plastic resins.
    Type: Grant
    Filed: November 6, 1989
    Date of Patent: August 28, 1990
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Richard A. Morgan, Charles W. Stewart
  • Patent number: 4937290
    Abstract: It is desirable to increase the modulus of rubbers utilized in a wide variety of applications. This invention discloses a technique for modifying rubbers to improve their modulus without sacrificing other properties. The subject invention more specifically relates to a process for preparing a rubber composition having a high modulus which comprises reacting at least one thio acid with at least one polydiene rubber and at least one nylon.
    Type: Grant
    Filed: September 26, 1988
    Date of Patent: June 26, 1990
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Richard G. Bauer, James B. Pyke
  • Patent number: 4923925
    Abstract: Resin compositions of (A) 50-95 percent by weight of a polyamide and (B) 5-50 percent by weight of a modified polyolefin containing in side chains 0.005-5 molar percent of functional groups expressed by formulas (I) and/or (II) below and 0.005-5 molar percent of functional groups expressed by formulas (III) and/or (IV) below provide molds having a high impact resistance and are applicable to automobile parts. ##STR1## Where R.sub.1 represents hydrogen or methl and wherein R.sub.2, R.sub.3 and R.sub.4 represent hydrogen, aliphatic, alicyclic or aromatic residual groups having 1-30 carbon atoms.
    Type: Grant
    Filed: September 1, 1987
    Date of Patent: May 8, 1990
    Assignee: Toray Industries, Inc.
    Inventors: Kazumasa Chiba, Kazuhiko Kobayashi, Osamu Ueno
  • Patent number: 4921889
    Abstract: Thermoplastic molding materials contain, as essential components,(A) from 2 to 97.9% by weight of a nylon,(B) from 2 to 97.9% by weight of a polyaryl ether ketone and(C) from 0.1 to 30% by weight of a polymeric component containing hydroxyl groupsand in addition(D) from 0 to 50% by weight of an impact-modifying rubber and(E) from 0 to 60% by weight of fibrous and/or particulate fillers.
    Type: Grant
    Filed: December 1, 1987
    Date of Patent: May 1, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Dietrich Lausberg, Erhard Seiler
  • Patent number: 4914162
    Abstract: Thermoplastic polyamide mixtures of polyamides based on dimerized fatty acids in which at least one polyamide contains as an incorporated unit (a) a C.sub.2 -C.sub.10 aliphatic diamine capable of diamide formation, which is N-substituted with C.sub.10 -C.sub.25 -alkyl, and (b) a C.sub.2 -C.sub.40 -diamine capable of diamide formation comprising a diprimary amine, a heterocyclic amine, or a diomine containing one or two secondary amino groups and which is N-C.sub.1 -C.sub.8 -alkyl-substituted on at least one side.
    Type: Grant
    Filed: October 31, 1988
    Date of Patent: April 3, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Roberto Leoni, Werner Gruber, Juergen Wichelhaus
  • Patent number: 4849474
    Abstract: Novel moisture resistant polyamide compositions are prepared comprising at least one polyamide and at least one di- or poly- hydric compound, oligomer or polymer free of sterically hindered hydroxy groups.
    Type: Grant
    Filed: November 10, 1988
    Date of Patent: July 18, 1989
    Assignee: General Electric Company
    Inventor: Robert R. Gallucci
  • Patent number: 4849476
    Abstract: A flexible thermoplastic resin composition is disclosed comprising (A) from 5 to 59 parts by weight of a polyamide resin and (B) from 95 to 41 parts by weight of an ethylene copolymer containing (a) from 50 to 90% by weight of ethylene, (b) from 5 to 49% by weight of an .alpha.,.beta.-unsaturated carboxylic acid alkyl ester, and (c) from 0.5 to 10% by weight of maleic anhydride. The resin composition of the invention has excellent cold resistance, particularly impact strength at low temperatures, and an excellent balance between rubbery elasticity and rigidity in addition to excellent thermal resistance, abrasion resistance, and chemical resistance.
    Type: Grant
    Filed: February 17, 1987
    Date of Patent: July 18, 1989
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Kentaro Mashita, Jinsho Nambu, Shoji Ishii
  • Patent number: 4847329
    Abstract: This invention is directed to polymers (including oligomers) that contain (N-substituted carbamoyloxy)alkanoyloxyalkyl acrylates, to a process for their preparation by reacting the carbamoyloxy alkanoyloxyalkyl acrylates with other ethylenically unsaturated monomers, and to coating, ink, adhesive, and sealant compositions (including the cured coatings, inks, adhesives, and sealants) that are obtained by crosslinking the above compositions by various means. The cured compositions, which are, for example, high-quality industrial finishes, sealants or encapsulants, are made by incorporation of various conventional crosslinking agents and other normally-used formulating ingredients with the polymeric compositions of the invention.
    Type: Grant
    Filed: June 30, 1987
    Date of Patent: July 11, 1989
    Assignee: Union Carbide Corporation
    Inventors: Joseph V. Koleske, Donald F. Smith, Jr., Robert J. Weber, Jr.
  • Patent number: 4833191
    Abstract: A process for preparing a predispersed fiber composition useful for dispersing discontinuous fibers into a rubber or plastic polymer compound is disclosed which comprises mixing at least about 15 percent by weight of a pourable binder composition with up to about 85 percent by weight of discontinuous fibers at a temperature of from about 40.degree. C. to about 150.degree. C. until a homogeneous predispersed fiber composition is obtained. The binder composition comprises from about 50 to 100 percent by weight of a rubber or plastic polymer, from 0 to about 50 perecnt by weight of a plasticizer or peptizer for the polymer, and from 0 to about 45 percent by weight of critical chemical additives, and is pourable at ambient tmeperature or becomes pourable upon being heated to a temperature of up to about 135.degree. C. and has a Brookfield viscosity of less than about 1,300,000 centipoises at the temperature at which it is pourable.
    Type: Grant
    Filed: October 6, 1987
    Date of Patent: May 23, 1989
    Assignee: Wyrough & Loser
    Inventors: Kenneth C. Bushway, Thomas N. Loser
  • Patent number: 4824898
    Abstract: A shaped article comprised of a tetrafluoroethylene polymer with a number average molecular weight of at least about 10.sup.6 which exhibits specific heat shrinking properties represented by an average maximum expansion ratio of from 2 to 10, a least maximum shrinkage ratio of 0.71 or less, an orientation release stress at 200.degree. C. of less than 5 Kg/cm.sup.2 and a shrinking starting temperature of at least 80.degree. C. The shaped article has excellent compression creep resistance, compression resistance, impact strength, dimensional stability, gas barrier property and tensile strength. Accordingly, it can be advantageously utilized as a sealant, a lining material, a bearing pad, a sliding pad, etc.
    Type: Grant
    Filed: March 24, 1988
    Date of Patent: April 25, 1989
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Masayuki Sukigara, Yasushi Kaneko, Hiroshi Kataoka
  • Patent number: 4822856
    Abstract: A process for preparing a polymeric blend stock comprising fluidizing a first particulated polymer, contacting the particulated polymer with droplets of a latex of a second polymer or polymer mixture, retaining the resulting product in a fluid state under conditions sufficient to dry the latex, and recovering the resulting dried polymeric blend stock.
    Type: Grant
    Filed: February 18, 1987
    Date of Patent: April 18, 1989
    Assignee: The Dow Chemical Company
    Inventors: Eugene R. Moore, Wen H. Tong
  • Patent number: 4785021
    Abstract: A method of adsorbing a substance such as an optically active substance, comprising contacting a solution of the substance in a solvent with an adsorbent consisting of a cross-linked polymer comprisingan optically active, synthetic poly(amino acid) represented by the general formula (I): ##STR1## wherein R stands for an organic group, R' stands for hydrogen or an alkyl group and n is an integer of at least 5, which may be protected at a terminal amino group anda carrier polymer supporting said synthetic poly(amino acid) thereon, said carrier polymer having affinity for said solvent. A method for producing the cross-linked polymer is also described.The adsorbent is especially useful for optical resolution of racemic mixtures.
    Type: Grant
    Filed: February 5, 1988
    Date of Patent: November 15, 1988
    Assignees: Research Development Corp. of Japan, Mitsubishi Kasei Corporation
    Inventor: Hideaki Kiniwa
  • Patent number: 4783511
    Abstract: A process for the preparation of moulded bodies of thermoplastic polyamides, which comprises intensively mixing a polyamide and a masterbatch, converting the mixture by conventional thermoplast processing to moulded bodies and, before use, conditioning the bodies by contact with ambient moisture or, briefly, with water, in which the masterbatch contains at least 5% by weight of a silane substituted by one, 2 or 3 hydrolysable radicals and a functional group which can undergo a chemical reaction, to form a bond, with amino groups and/or carboxyl groups and/or amide groups in the polyamide chain.
    Type: Grant
    Filed: June 11, 1987
    Date of Patent: November 8, 1988
    Assignee: Ems-Inventa AG
    Inventor: Eduard Schmid
  • Patent number: 4755562
    Abstract: Surface treating water-absorbent resins with a polyquaternary amine substantially increases both the rate of water absorption and the quantity of water absorbed and retained by the resin. In addition to improved water absorbing properties, the surface-treated resins maintain the necessary "dry feel" required for most applications.
    Type: Grant
    Filed: June 10, 1986
    Date of Patent: July 5, 1988
    Assignee: American Colloid Company
    Inventors: William Alexander, Mark Anderson, Barbara R. Regan
  • Patent number: 4714740
    Abstract: A thermoplastic polybend of nylon 66 and polymethylmethacrylate having superior friction and wear properties. Alternatively, the polybend composition may contain a third component of polytetrafluoroethylene to further improve its friction and wear properties.
    Type: Grant
    Filed: July 14, 1986
    Date of Patent: December 22, 1987
    Assignee: General Motors Corporation
    Inventors: Michael C. Lee, Mark A. Golden
  • Patent number: 4695488
    Abstract: A soil release composition comprising:(A) a polymer comprising 10 to 100% by weight of constituting units of the formula: ##STR1## wherein R.sub.f is a C.sub.3 --C.sub.21 fluoroalkyl group; R.sup.1 is a hydrogen atom or a C.sub.2 --C.sub.4 acyl group; R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are, the same or different, each a hydrogen atom, a methyl group or an ethyl group; A is a group of the formula: --CH.sub.2 CH(OR.sup.1)CH.sub.2 --OCO-- which R.sup.1 is the same as defined in the above, --CO--, --(CH.sub.2).sub.k N(R.sup.2)CO-- in which R.sup.2 is the same as defined in the above and k is an integer of 1 to 10, or --(CH.sub.2).sub.
    Type: Grant
    Filed: March 3, 1986
    Date of Patent: September 22, 1987
    Assignee: Daikin Industries, Ltd.
    Inventors: Iwao Hisamoto, Masaru Hirai, Sueyoshi Ishikawa
  • Patent number: 4694044
    Abstract: A method of adsorbing a substance such as an optically active substance, comprising contacting a solution of the substance in a solvent with an adsorbent consisting of a cross-linked polymer comprising an optically active, synthetic poly(amino acid) represent by the general formula (I): ##STR1## wherein R stands for an organic group, R' stands for hydrogen or an alkyl group and n is an integer of at least 5, which may be protected at a terminal amino group and a carrier polymer supporting said synthetic poly(amino acid) thereon, said carrier polymer having affinity for said solvent. A method for producing the cross-linked polymer is also described.The adsorbent is especially useful for optical resolution of racemic mixtures.
    Type: Grant
    Filed: March 6, 1985
    Date of Patent: September 15, 1987
    Assignee: Research Development Corp. of Japan
    Inventor: Hideaki Kiniwa
  • Patent number: 4632959
    Abstract: A modified polyolefin composition comprising(A) 50 to 99 parts by weight of a modified polyolefin having an intrinsic viscosity [.eta.] of 0.5 to 10 dl/g and a degree of crystallization of at least 20% selected from the group consisting of polyolefins modified with styrene-type hydrocarbons, polyolefins modified with unsaturated epoxy compounds, polyolefins modified with unsaturated silane compounds, halogenated polyolefins and hydroxyl group-containing polyolefins, and(B) 1 to 50 parts by weight of a thermoplastic polymer selected from the group consisting of(B-1) thermoplastic polymers having a flexural modulus of less than 1000 kg/cm.sup.2, a glass transition temperature (Tg) of not higher than 0.degree. C. and a weight average molecular weight (Mw) of at least 400,000, and(B-2) polar non-olefinic thermoplastic polymers or ethylenic polymers having a flexural modulus of at least 1000 kg/cm.sup.2 and an adhesion strength, with respect to the modified polyolefin (A), of not more than 200 g/cm.
    Type: Grant
    Filed: September 19, 1984
    Date of Patent: December 30, 1986
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventor: Riichiro Nagano
  • Patent number: 4607095
    Abstract: In one embodiment this invention provides a nonlinear optical substrate which comprises a transparent film of an external field-induced noncentrosymmetric macroscopic orientation of poly[[benzo(1,2-d:5,4-d')bisthiazole-2,6-diyl]-1,4-phenylene] molecules: ##STR1##
    Type: Grant
    Filed: March 5, 1985
    Date of Patent: August 19, 1986
    Assignee: Celanese Corporation
    Inventor: James E. Kuder
  • Patent number: 4595730
    Abstract: Unsaturated polyamide polymers are provided which are comprised of a polyamide chain terminated at one end by a group containing at least one double bond. The polymers are particularly useful in the preparation of molded object coatings, water tight joints, grafting onto thermoplastic polymers or copolymers, and the like.
    Type: Grant
    Filed: October 31, 1984
    Date of Patent: June 17, 1986
    Assignee: Atochem
    Inventors: Philippe Blondel, Camille Jungblut
  • Patent number: 4579905
    Abstract: A composition comprising an intimate thermoplastic admixture of at least two structurally dissimilar organic polymers, a delamination inhibiting effective amount of the first organic polymer covalent bond graft linked to the second organic polymer through a multifunctional graft linking agent of the insertion, electron deficient type the new admixtures are useful for the usual applications associated with the admixture properties.
    Type: Grant
    Filed: August 15, 1983
    Date of Patent: April 1, 1986
    Assignee: General Electric Company
    Inventor: Herman O. Krabbenhoft
  • Patent number: 4542192
    Abstract: A reactive hardenable polymer mixture which comprises(A) at least one epoxy compound and(B) at least one polycarboxylic acid compound in the form of a component selected from the group consisting of(a) at least one compound of formula ##STR1## wherein R.sup.1 is a radical derived from at least one polymeric product containing hydroxy groups selected from the group consisting of a polymerization and a condensation product and a combination thereof in the form of polyesters, polymers each having a hydroxy number between 20 and 300, phenol resins having a hydroxy number between 100 and 800 and combinations thereof,R.sup.2 is a radical of an at least tetrabasic cyclic carboxylic acid having at least one COOH-group in an o- or peri-position to the ester bond,R.sup.5 is a radical of an at least dibasic cyclic carboxylic acid having at least one COOH-group in o- or peri-position to the ester bond and R.sup.5 may also be as defined for R.sup.
    Type: Grant
    Filed: May 26, 1982
    Date of Patent: September 17, 1985
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Kurt Kraft, Gerd Walz, Thaddaus Wirth