Cyclic Anhydride Patents (Class 525/285)
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Patent number: 5851966Abstract: Compositions of matter for use in oils and fuels are disclosed. The compositions arise from reaction products (C) formed by reacting substituted carboxylic acylating agents (A) with carboxylic reactants (B). The reactant (A) is usually a polyolefin substituted succinic anhydride or acid which is reacted with (B). (B) is usually a glyoxylic compound. Carboxylic reaction products (C) may further be reacted to form succinimide dispersants, esters or other derivatives. Products (C) may also be reacted with an .alpha.-.beta. unsaturated compound to form second carboxylic reaction products.Type: GrantFiled: June 5, 1997Date of Patent: December 22, 1998Assignee: The Lubrizol CorporationInventors: Mark R. Baker, Paul E. Adams, Jeffry G. Dietz
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Patent number: 5847036Abstract: The present invention provides a (meth)acrylic molding material comprising (A) a (meth)acrylic polymer obtained by polymerization of monomer components essentially containing a monomer having (a) carboxyl group(s) and an alkyl (meth)acrylate monomer, and (B) one or more kinds of monomers containing a vinyl group, wherein 30-600 parts by weight of aluminum hydroxide and 0.01-10 parts by weight of a succinic acid derivative are added for 100 parts by weight of the total of said polymer (A) and monomer (B). The (meth)acrylic molding material is thickened by aluminum hydroxide and the thickening behavior is controlled by the succinic acid derivative to prevent the viscosity from increasing with time, accordingly, the (meth)acrylic molding material shows good workability.Type: GrantFiled: June 21, 1996Date of Patent: December 8, 1998Assignee: Nippon Shokubai Co., Ltd.Inventors: Kouji Takabatake, Yuichi Kawata, Shigeo Otome
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Patent number: 5821301Abstract: Disclosed is a modified chlorinated polyolefin resin composition, as well as a method for producing the same, which has adhesion to polyolefin substrates without the need of steam-washing or degreasing the polyolefin surface with chlorine-based organic solvents such as trichloroethane, and which is improved in such properties as interlayer adhesion to base-coats and/or top-coats and gasohol resistance. The modified polyolefin resin composition for polyolefin resin paints comprises: a chlorinated polyolefin having an acid value of 1 to 500 mg.multidot.KOH/g, which is obtained by chlorinating a polyolefin modified with one kind, or more than one kind, of compounds selected from a group consisting of .alpha., .beta.-unsaturated carboxylic acids and/or acid anhydrides thereof in a range of 1 to 50% by weight; and a compound and/or a resin thereof having one epoxy group per molecule represented by the structural formula as described in the specification.Type: GrantFiled: April 9, 1997Date of Patent: October 13, 1998Assignee: Toyo Kasei Kogyo Company LimitedInventors: Tatsuo Tsuneka, Takafumi Masuda, Kenichiro Isomoto, Teruaki Ashihara, Shozo Maekawa, Tetsuzo Nishioka, Ryozo Orita
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Patent number: 5798420Abstract: This invention relates to block polymers containing both crystalline and elastomeric blocks, the block copolymer having an A block and a B block. The A block is a polyethylene or an ethylene polymer optionally containing an alpha-olefin and optionally a non-conjugated diene, and is generally crystalline. The B block is an ethylene, .alpha.-olefin copolymer. Also disclosed is a process for manufacture of the block copolymers and methods for coupling the block copolymers. Coupled block copolymers are useful as thermoplastic elastomers exhibiting physical properties approaching those of crosslinked EP or EPDM elastomers, but showing thermal processability after coupling. The block copolymers of the present invention may also be used as a lubricant or fuel additive, as a plastics blend component, and as a component in hot melt adhesives.Type: GrantFiled: May 19, 1997Date of Patent: August 25, 1998Assignee: Exxon Chemical Patents, Inc.Inventors: Charles Cozewith, Gary William Ver Strate, Roger K. West, Gaetano A. Capone
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Patent number: 5792729Abstract: A terpolymer having an average M.sub.n of from 600 to 100,000 is obtained by the terpolymerization of a 1-olefin having from 10 to 30 carbon atoms, maleic anhydride, and a 1,1 -disubstituted polyisobutylene having an average M.sub.n of from 500 to 5,000.Type: GrantFiled: August 20, 1996Date of Patent: August 11, 1998Assignee: Chevron Chemical CorporationInventors: James J. Harrison, William R. Ruhe, Jr.
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Patent number: 5777036Abstract: Particulate graft copolymers A) are composed ofa.sub.1) from 5 to 70% by weight, based on A), of a grafting base having a glass transition temperature of less than 10.degree. C. and based ona.sub.11) from 50 to 99.94% by weight, based on a.sub.1), of at least one alkyl acrylate where the alkyl radical is of 1 to 30 carbon atoms,a.sub.12) from 0 to 49.9% by weight, based on a.sub.1), of a further monounsaturated monomer copolymerizable with b.sub.11) anda.sub.13) from 0.01 to 5% by weight, based on a.sub.1), of polyfunctional crosslinking monomers,a.sub.2) from 20 to 85% by weight, based on A), of a stage polymerized in the presence of component a.sub.1) and comprisinga.sub.21) from 95 to 100% by weight, based on a.sub.2), of at least one monomer having a refractive index n.sub.D.sup.20 of more than 1.51 anda.sub.22) from 0 to 5% by weight, based on a.sub.2), of a polyfunctional, crosslinking monomer anda.sub.Type: GrantFiled: April 15, 1997Date of Patent: July 7, 1998Assignee: BASF AktiengesellschaftInventors: Wolfgang Fischer, Jurgen Koch, Graham Edmund McKee
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Patent number: 5763531Abstract: Preparation of storage stable, polybutadiene containing, unsaturated polyester resins by heating a mixture containing an unsaturated hydroxyl terminated polybutadiene resin, a saturated anhydride or dibasic acid, an unsaturated anhydride or dibasic acid, a polymerization inhibitor and, optionally, a saturated glycol, while removing water as it is formed, the molar ratio of the saturated anhydride or acid to the unsaturated anhydride or acid being at least equal to 2.Type: GrantFiled: April 22, 1997Date of Patent: June 9, 1998Assignee: Elf Atochem North America, Inc.Inventor: Robert H. Boutier
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Patent number: 5728776Abstract: When producing a graft modified polyolefin by melting and kneading a polyolefin, a radical-polymerizable monomer and a radical-polymerization initiator, the producing efficiency is improved. The grafting reaction is effected by feeding the melted polyolefin containing either one of said radical-polymerizable monomer and the radical-polymerization initiator to the other. When said radical-polymerizable monomer is an unsaturated carboxylic anhydride, said unsaturated carboxylic anhydride as a starting material is preliminarily heated at 50.degree. to 250.degree. C., and then fed to the grafting reaction mentioned above. When the monomer is an unsaturated carboxylic acid or an acid anhydride of such an unsaturated carboxylic acid, an organic peroxide of a formula (I) is used as the radical-polymerization initiator. ##STR1## In this formula (I), two substituting groups connected directly to the benzene ring have an ortho-positional relationship or a meta-positional relationship, R.sub.1, R.sub.2, R.sub.3, R.sub.Type: GrantFiled: January 25, 1996Date of Patent: March 17, 1998Assignee: Kawasaki Steel CorporationInventors: Kazuya Takemura, Kazumichi Sashi, Taichi Ogawa, Tadahiro Wakui, Shigeru Takano
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Patent number: 5716708Abstract: A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein.Type: GrantFiled: January 19, 1995Date of Patent: February 10, 1998Inventor: Richard J. Lagow
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Patent number: 5714096Abstract: The present invention is directed to a positive temperature coefficient composition comprising by weight based on total composition, 10-30% carbon black possessing a DBP absorption of about 125 cc/100 g carbon black or less; 10-40% chlorinated, maleic anhydride grafted, polypropylene resin; and organic medium capable of solubilizing the resin.Type: GrantFiled: September 3, 1996Date of Patent: February 3, 1998Assignee: E. I. Du Pont de Nemours and CompanyInventor: Jay Robert Dorfman
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Patent number: 5708128Abstract: Novel thermoset polyimide and composite materials comprising the thermoset polyimides and a fibrous reinforcement are prepared according to this invention. The thermoset polyimides are obtained by heat-treating a linear polyamic acid or a linear polyimide prepared by using 4,4'-bis(3-aminophenoxy)biphenyl and pyromellitic dianhydride as essential monomers or by adding 4,4'-diaminodiphenyl ether or 3,3',4,4'-biphenyltetracarboxylic dianhydride to the essential monomers and by end-capping the molecular chain end with an aromatic dicarboxylic anhydride having a carbon-carbon triple bond. The thermoset polyimides have essential excellent properties of thermoplastic polyimide and additionally has enhanced heat resistance and improved mechanical properties. The thermoset polyimide can be used to provide various kinds of composite materials for aircraft matrices, electric and electronic appliances and others.Type: GrantFiled: June 24, 1996Date of Patent: January 13, 1998Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Hideaki Oikawa, Shoji Tamai, Masahiro Ohta, Akihiro Yamaguchi
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Patent number: 5698617Abstract: Disclosed are functionalized polyolefins prepared by mixing a polyolefin with a concentrate and extruding the resulting blend, where the concentrate is in the form of olefin polymer particles coated with a mixture of additives including:A) from 0.05 to 30% by weight, based on the total weight of the concentrate, of one or more nonpolymerizable polar vinyl monomers;B) from 0.05 to 30% in moles, with respect to (A), of a free radical generating initiator which is not active at temperatures lower than or equal to 70.degree. C., and optionally,C) from 0.1 to 5% by weight, based on the total weight of the concentrate, of a coating substance.Type: GrantFiled: May 27, 1993Date of Patent: December 16, 1997Assignee: Montell North America Inc.Inventors: Roberto Marzola, Gian Luigi Rigosi
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Patent number: 5698637Abstract: A method for modifying polyolefins by grafting with a carboxylic acid, carboxylic acid anhydride or other functionalized monomer in the presence of two additional comonomers, one being an aliphatic diolefin and the other an aromatic vinyl or (meth)acrylate monomer.Type: GrantFiled: June 30, 1995Date of Patent: December 16, 1997Assignee: Borealis Holding A/SInventor: Jari Aarila
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Patent number: 5695838Abstract: Disclosed are (1) an adhesive polypropylene resin composition comprising (a) 50 to 90 parts by weight of a modified polypropylene or a composition containing said modified polypropylene, said modified polypropylene being graft-modified with at least one monomer selected from the group consisting of an unsaturated carboxylic acid from the group consisting of an unsaturated carboxylic acid and a derivative thereof and (b) 10 to 50 parts by weight of a modified polyolefin other than the modified polypropylene or the composition (a), said modified polyolefin being grafted with at least one monomer selected from the group consisting of an unsaturated carboxylic acid and a derivative thereof, and (2) a multi layer laminate body comprising (i) a layer of a polyolefin (ii) a layer of the above-said adhesive polypropylene resin composition and (iii) a layer of a polyamide resin and/or an ethylene/vinyl alcohol copolymer, said layers being laminated in the order of (i), (ii) and (iii).Type: GrantFiled: August 15, 1996Date of Patent: December 9, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Haruhiko Tanaka, Hideshi Kawachi
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Patent number: 5684090Abstract: A bimodal, crosslinked toner resin can be prepared in non-aqueous solvent, e.g., toluene, using standard solution polymerization techniques. The resin-forming process prepares a precursor resin from ethylenically unsaturated monomer(s), and then grafts maleic anhydride onto the precursor resin to form a modified precursor resin. The modified precursor resin is reacted with a polyfunctional molecule, e.g. a diol, to provide a crosslinked resin. The process is preferably conducted in the presence of a low molecular weight polymeric additive, e.g., polystyrene, to provide a bimodal as well as crosslinked toner resin composition. With the addition of a colorant, a toner powder may be formed.Type: GrantFiled: May 15, 1995Date of Patent: November 4, 1997Assignee: Image Polymers CompanyInventor: Francis L. Chupka, Jr.
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Patent number: 5679742Abstract: An anhydride-functional polymer is obtained by at least partially hydrogenating an unsaturated polymer which was obtained by reacting under ene reaction conditions:(i) an unsaturated anhydride having the structure: ##STR1## wherein R.sub.1 and R.sub.2 are each independently hydrogen, alkyl of 1 to about 6 carbons, or alkoxy of 1 to about 6 carbons, or a halogen; and(ii) at least one polyolefin having at least two carbon--carbon double bonds in the polyolefin backbone and having an average of at least three carbon atoms in the polyolefin backbone between the carbon--carbon double bonds.Type: GrantFiled: August 26, 1996Date of Patent: October 21, 1997Assignee: The Sherwin-Williams CompanyInventors: Richard S. Valpey, III, Mohamad D. Shalati, Rodney M. Harris, Thomas W. Yokoyama
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Patent number: 5668215Abstract: The present invention provides a functional group-containing alkyl acrylate-butadiene-aromatic vinyl compound copolymer which is obtained from the following layers by emulsion graftlinking polymerization: an inner layer comprising polybutadiene or an aromatic vinyl compound-butadiene copolymer; a middle layer comprising an aromatic vinyl compound-an alkyl acrylate copolymer; and an outer layer comprising an alkyl acrylate-a functional group-containing vinyl compound copolymer. The functional group-containing alkyl acrylate-butadiene-aromatic vinyl compound copolymer can be incorporated into a PC/PBT alloy as an impact modifier, thus the impact strength of the modified alloy composition at room temperature and low temperatures can be increased effectively.Type: GrantFiled: September 20, 1996Date of Patent: September 16, 1997Assignee: Industrial Technology Research InstituteInventors: Cheng-Lung Chao, Juh-Shyong Lee, Feng-Chih Chang
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Patent number: 5668219Abstract: A process for the percolation leaching of minerals from a mineral-beating ore comprises agglomerating the mineral-bearing ore with an agglomerating agent of a cationic block copolymer having a polymeric segment and a block containing an ammonium cation optionally with a block derived from an acrylamide monomer, forming the ore/agglomerating agent mixture into a heap, and leaching the heap by percolation with a leaching solution for subsequent recovery of the minerals at an acidic pH.Type: GrantFiled: March 22, 1996Date of Patent: September 16, 1997Assignee: BetzDearborn Inc.Inventors: David M. Polizzotti, Wen P. Liao, Donald C. Roe
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Patent number: 5665828Abstract: The invention relates to a polybutylene polymer or oligomer which contains in its molecule at least one acryl group, said polybutylene being prepared by reacting(A) an anhydride-functional polybutylene, or derivative thereof, with(B) an acryl-functional compound having at least one hydroxyl-containing group, chlorine, isocyanate group, epoxy group or amine group in its molecule.Type: GrantFiled: October 31, 1996Date of Patent: September 9, 1997Assignee: Dow Corning CorporationInventor: Kenneth Michael Lee
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Patent number: 5663237Abstract: A supercritical graft copolymerization process is described which includes the steps of: adding a polymer into a high pressure reactor; adding a free radically polymerizable monomer into the reactor; adding a free radical polymerization initiator; adding a sufficient amount of a supercritical solvent to dissolve at least a portion of the polymer and the monomer when supercritical conditions are achieved inside the reactor; and heating and pressurizing the reactor to achieve supercritical conditions therein for a time sufficient to effect a graft copolymerization on the polymer by the polymerizing monomer which forms at least one side chain on the polymer. In general, the reaction pressure will range from 70 atm. to 200 atm. and the reaction temperature will range from 50.degree. C. to 90.degree. C. In the examples provided above, the supercritical solvent was carbon dioxide.Type: GrantFiled: June 15, 1995Date of Patent: September 2, 1997Assignee: The University of AkronInventors: Sunggyu Lee, Soonjong Kwak, Fouad Azzam
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Patent number: 5663238Abstract: The present invention relates to a random copolyester containing naphthalene ring structure, in particular to a random copolyester containing a first repeating unit which is the same as that of polyalkylene naphthalate, such as polyethylene naphthalate (PEN) and polybutylene naphthalate (PBN), and a second repeating unit which is similar to the first repeating unit except that an aryl ether linkage is incorporated thereto. The present copolyester can be prepared from a dihydroxyethoxy compound and bis(hydroxyalkyl)naphthalate via a direct melt polycondensation in the presence of a metallic catalyst.Type: GrantFiled: July 11, 1995Date of Patent: September 2, 1997Assignee: National Science CouncilInventors: Chun-Shan Wang, Yih-Min Sun
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Patent number: 5658993Abstract: A water-soluble or water-dispersible graft copolymer obtainable by free-radical graft copolymerization of(I) at least one monoethylenically unsaturated monomer onto(II) polymers with a molecular weight of 200-5000 of monoethylenically unsaturated dicarboxylic acids or anhydrides thereofusing from 5 to 2,000 parts by weight of the monomers (I) per 100 parts by weight of grafting base, a process for preparing the graft copolymers and the use of the graft copolymers as additive to phosphate-free or reduced phosphate textile detergents, as dispersants and preventers of deposits in cleaners for hard surfaces and as water-treatment agents for reducing the deposition of scale and the separation out of water hardness in water-conveying systems.Type: GrantFiled: January 30, 1996Date of Patent: August 19, 1997Assignee: BASF AktiengesellschaftInventors: Walter Denzinger, Axel Kistenmacher, Johannes Perner, Angelika Funhoff, Birgit Potthoff-Karl, Hans-Jurgen Raubenheimer
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Patent number: 5658967Abstract: The invention relates to a method for providing a surface with carboxyl groups. A compound is applied to the surface with at least one functional group which can be converted into a carboxyl group. Thereafter, this surface is treated with a plasma to immobilize the compound, and then the functional group is converted into a carboxyl group. Also provided is a surface having carboxyl groups which is obtained with this method and a product with such a surface for exposure to blood, typically in vivo blood flows.Type: GrantFiled: May 18, 1995Date of Patent: August 19, 1997Assignee: Cordis CorporationInventors: Jan Feijen, Johannes G. A. Terlingen, Jan Pleun Lens
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Patent number: 5651927Abstract: Multiple sequential chemical reactions on a polymeric feedstock are carried out in an extruder with multiple reaction zones. Each reaction zone has means for introduction of reagents, for mixing of reagents with polymer and for removal of by/co-products or unreacted reagents.Type: GrantFiled: June 5, 1996Date of Patent: July 29, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Richard Stephen Auda, William Myers Davis, David Yen-Lung Chung, Lawrence William Flatley, Jr., Brenton George Jones, Donald Andrew White, Hans Gerlach Woudboer
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Patent number: 5650468Abstract: Continuous process for grafting a polyolefin within a melt including a polyolefin of linear olefin containing from 2 to 8 carbon atoms, a graftable functional monomer and a radical-generator, in an extruder including at its exit a compression zone followed by a discharge zone, in which at least one antioxidant additive is introduced into the melt not later than before the latter enters the compression zone of the extruder.Stabilized grafted polyolefin obtained by means of this process.Type: GrantFiled: December 22, 1994Date of Patent: July 22, 1997Assignee: Solvay (Societe Anonyme)Inventors: Eric Vandevijver, Pascal Lefevre, Eric Fassiau, Claude Vogels
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Patent number: 5646215Abstract: The invention relates to a functionalized polybutylene polymer which contains at least one unsaturated group in its molecule, said functionalized polybutylene being prepared by reacting (A) an anhydride-functional polybutylene with (B) an allyl-functional compound having at least one hydroxyl-containing group in its molecule.Type: GrantFiled: October 31, 1996Date of Patent: July 8, 1997Assignee: Dow Corning CorporationInventor: Kenneth Michael Lee
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Patent number: 5644001Abstract: This invention relates to novel pure hydrocarbyl succinylating agents, substantially pure derivatives thereof, to a method of preparation of pure substituted succinylating agents and their derivatives, and to the use of thereof as additives for fuels and lubricants. The hydrocarbyl substituted succinylating agents are pure because the real and apparent mole ratios of the succinyl groups to the hydrocarbyl groups in such agents are substantially the same. These are produced by reacting an olefin polymer such as poly(iso)butylene with maleic anhydride to form a hydrocarbyl substitued succinylating agent which is then cleaned by solvent extraction to remove any impurities therein before use in further reactions.Type: GrantFiled: March 11, 1996Date of Patent: July 1, 1997Assignee: BP Chemicals LimitedInventors: John Richard Blackborow, Michael John Clarke
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Patent number: 5643989Abstract: A composite material consisting of continuous random glass mats with a new non-peroxide sizing chemistry, polypropylene and a functionalized polypropylene. This composite gives unexpectedly higher performance in bumper beam applications. The functionalized polypropylene contains anhydride functionalities, which are preferably maleic anhydride.Type: GrantFiled: February 28, 1995Date of Patent: July 1, 1997Assignee: Azdel, Inc.Inventors: Hendrik T. Van De Grampel, Yongsheng Hou, Dennis O. Spencer, Robert G. Swisher, Thomas V. Thimons
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Patent number: 5643998Abstract: A recyclable polymer is formed of a plurality of oligomer units obtained by polymerizing a fixed number of monomers, and linkage units for linking the oligomer units through a chemical bond which is different from a bond between monomers constituting the oligomer units, thereby allowing repetitive scission and re-bonding of the linkage units by a predetermined treatment not cleaving the bond between monomers. The recyclable polymer is decomposable into oligomers and the oligomers can be linked again into the original polymer without degrading the quality of the polymer. A process for producing the recyclable polymer, a method for recovering the recyclable polymer, and a method for regenerating the recyclable polymer are also provided.Type: GrantFiled: March 8, 1995Date of Patent: July 1, 1997Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Mitsuru Nakano, Arimitsu Usuki, Akane Okada, Osami Kamigaito
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Patent number: 5635565Abstract: A rubber-modified thermoplastic resin is obtained by polymerizing (b) an aromatic vinyl compound and (c) a vinyl cyanide compound in the presence of (a) a rubbery polymer, and in which the content of the component (a) is 50 to 85% by weight, the content of the component (b) is 5 to 48% by weight and the content of the component (c) is 2 to 45% by weight, and which resin has a Q value of 30.times.10.sup.-4 to 50.times.10.sup.-3 and a grafting degree of 5% by weight or more. A thermoplastic resin composition comprising the above rubber-modified thermoplastic resin and at least one other thermoplastic resin is prepared.Type: GrantFiled: December 18, 1995Date of Patent: June 3, 1997Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Hajime Miyajima, Tsugio Asakawa, Noriaki Ijuin, Hiroo Nakamura, Toshihiro Ogawa, Shinichi Kimura
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Patent number: 5633091Abstract: An anhydride-functional polymer obtained by reacting under graft copolymerization reaction conditions,(A) an unsaturated polymer which was obtained by reacting under ene reaction conditions a mixture of reactants comprising:(i) an unsaturated anhydride having the structure: ##STR1## wherein R.sub.1 and R.sub.2 are each independently hydrogen, alkyl of 1 to about 6 carbons, or alkoxy of 1 to about 6 carbons, or a halogen; and(ii) at least one polyolefin having at least two carbon-carbon double bonds in the polyolefin backbone and having an average of at least three carbon atoms in the polyolefin backbone between the carbon-carbon double bonds; and(B) at least one ethylenically unsaturated monomer which is copolymerizable with the unsaturated polymer.Type: GrantFiled: August 26, 1996Date of Patent: May 27, 1997Assignee: The Sherwin-Williams CompanyInventors: Rodney M. Harris, Mohamad D. Shalati, Joyce A. Bibeau
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Patent number: 5629383Abstract: A stable partially polymerized syrup comprising dispersed rubber-like composite particles in a resin phase may be converted to a metastable syrup in which the rubber-like composite and resin phases are co-continuous by subjecting the stable syrup to high shear under pressure.Type: GrantFiled: May 10, 1996Date of Patent: May 13, 1997Assignee: Novacor Chemicals (Internatioanal) SAInventor: Thomas R. Doyle
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Patent number: 5625004Abstract: A process for the preparation of an alkenyl-substituted succinic anhydride wherein the alkenyl substituent has a number average molecular weight of from about 500 to 5000 and the average number of succinic groups per alkenyl group is greater than 1.2 which comprises:(a) reacting a polyolefin having an alkylvinylidene isomer content of less than about 10 percent and a number average molecular weight of about 500 to 5000 with maleic anhydride at a temperature in the range of about 200.degree. C. to 250.degree. C. to provide a mixture of alkenyl succinic anhydride having an average of about 1.0 succinic group per alkenyl group and unreacted polyolefin, and(b) reacting the mixture of alkenyl succinic anhydride and unreacted polyolefin from step (a) with maleic anhydride in the presence of a free radical initiator at a temperature in the range of about 100.degree. C. to 220.degree. C. to thereby provide an alkenyl succinic anhydride having an average of greater than 1.2 succinic groups per alkenyl group.Type: GrantFiled: July 23, 1992Date of Patent: April 29, 1997Assignee: Chevron Research and Technology CompanyInventors: James J. Harrison, William R. Ruhe, Jr.
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Patent number: 5624999Abstract: A functionalised polymer, especially an ashless dispersant or a viscosity index improver dispersant, suitable for use as a lubricating or fuel oil additive, or as an intermediate for use in the manufacture of such an additive, is prepared from reactants in different phases by reacting the reactants in a reaction region defined by adjacent surfaces between which there is relative movement or in a thin film on a surface over which they move.Type: GrantFiled: May 12, 1995Date of Patent: April 29, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Alessandro Lombardi, Geraldo Barini, Carmine D'Antonio, Stefano Gusi
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Patent number: 5599879Abstract: A super-tough polymeric composition comprising an engineering thermoplastic and a modified radial polymer. The engineering thermoplastic is selected from the group consisting of polyamides, thermoplastic polyesters, polyphenylene ether resins, polyarylene sulfide resins, polysulfone and the like. The modified radial polymer is modified by grafting a compound containing a carboxylic acid or carboxylic acid derivative group. The modified, radial polymer has from about 3 to about 50 arms, as determined using light scattering techniques and the arms will be olefin polymers. The polymer compositions will yield shaped articles which fail ductilely when tested using ASTM procedure D-256 at room temperature and some at -20.degree. F.Type: GrantFiled: May 25, 1994Date of Patent: February 4, 1997Assignee: Shell Oil CompanyInventors: Richard Gelles, Carl L. Willis, John E. Gorman, Andres M. Arismendi, Jr.
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Patent number: 5591805Abstract: An anhydride-functional polymer is obtained by reacting under ene reaction conditions:(i) an unsaturated anhydride having the structure: ##STR1## wherein R.sub.1 and R.sub.2 are each independently hydrogen, alkyl of 1 to about 6 carbons, or alkoxy of 1 to about 6 carbons, or a halogen; and(ii) at least one polyolefin having at least two carbon-carbon double bonds in the polyolefin backbone and having an average of at least three carbon atoms in the polyolefin backbone between the carbon-carbon double bonds.Type: GrantFiled: February 15, 1996Date of Patent: January 7, 1997Assignee: The Sherwin-Williams CompanyInventors: Mohamad D. Shalati, Rodney M. Harris, Joyce A. Bibeau, Richard S. Valpey, III
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Patent number: 5589541Abstract: A process for producing a modified propylene polymer comprising the steps of premixing a propylene polymer with a vinyl monomer and polymerizing the vinyl monomer by kneading the premix at a temperature of a melting point thereof or higher is described, wherein the propylene polymer is a particulate propylene polymer having a specific surface area of 0.1 m.sup.2 /g or more. A modified propylene polymer composition is also described, obtained by mixing (a) a particulate propylene polymer having a specific surface area of 0.1 m.sup.2 /g or more, (b) 5% by weight or more of a vinyl monomer mainly comprising an aromatic vinyl monomer based on the total weight of the vinyl monomer and the propylene polymer, and (c) a radical polymerization initiator, substantially impregnating the vinyl monomer and the radical polymerization initiator into the propylene polymer, and then polymerizing the vinyl monomer by melt-kneading.Type: GrantFiled: March 28, 1995Date of Patent: December 31, 1996Assignee: Dainippon Ink and Chemicals Inc.Inventors: Masafumi Kinoshita, Toshio Niwa, O. Shibata
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Patent number: 5587433Abstract: A method for producing esters of hydroxy terminated polybutadiene, including the steps of: (a) providing an anhydride; (b) reacting a hydroxy terminated polybutadiene with the anhydride to form a carboxyl terminated polybutadiene derivative; (c) reacting the derivative with an epoxide. Also a curable composition, including: (a) an ester of hydroxy terminated polybutadiene; (b) a copolymerizable ethylenically unsaturated monomer; and (c) a drier.Type: GrantFiled: August 17, 1995Date of Patent: December 24, 1996Assignee: Sartomer Company, Inc.Inventor: Rudolph H. Boeckeler
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Patent number: 5587418Abstract: The present invention intends to provide a thermosetting coating composition provided with workability, excellent adhesion, weatherability, good appearance, etc. capable of use in a primerless colored base coat and top clear coat by a 2-coat, 1-bake method on a polyolefinic substrate. Moreover, the present invention intends to provide a coated body having excellent adhesion, weatherability, good appearance, etc. realized by a 2-coat, 1-bake method. This thermosetting coating composition is a composition comprising a graft copolymer obtained by copolymerizing acrylic monomer, unsaturated carboxylic acids, acrylic monomers containing hydroxyl group with chlorinated polyolefin containing anhydride in the presence of organic solvents. This coating composition is available for use as a primerless colored base coat 2-coat, 1-bake coating on the polyolefinic substrates.Type: GrantFiled: June 5, 1995Date of Patent: December 24, 1996Assignees: Nissan Motor Co., Ltd, TBL Co., Ltd.Inventors: Ryo Sasaki, Toshiro Ina
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Patent number: 5583181Abstract: (I) The (co)polymerisation of ethylene is carried out in at least one reaction zone (R) under high pressure, at 150.degree.-320.degree. C.; (II) the reaction product is routed into a zone (S), under an intermediate pressure P, for separation of the (co)polymer, in the molten state, from the unreacted (co)monomer(s), or the reaction product is routed into a first separation zone (S1), under an intermediate pressure (P1); the (co)polymer issuing from (S1) is then routed into a second separation zone (S2), under a pressure P2<P1; (III) the (co)polymer is routed into a zone (SF), under low pressure, for final separation of the (co)polymer from the residual gases. Let-down zones (D), (D1) and (D2) are provided along the path of the (co)polymer between the zones (S) and (SF), (S1) and (S2), and (S2) and (SF) respectively, the grafting monomer or monomers being introduced on-line, in the path of the (co)polymer, at at least one point located at the level of the zone (D) or at at least one zone (D1, D2).Type: GrantFiled: January 12, 1995Date of Patent: December 10, 1996Assignee: ECP-Enichem Polymeres France S.A.Inventors: Jo el Audureau, Hacene Mehalla, Thierry Pellerin
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Patent number: 5576394Abstract: The present invention provides a functional group-containing alkyl acrylate-butadiene-aromatic vinyl compound copolymer which is obtained from the following layers by emulsion graftlinking polymerization: an inner layer comprising polybutadiene or an aromatic vinyl compound-butadiene copolymer; a middle layer comprising an aromatic vinyl compound--an alkyl acrylate copolymer; and an outer layer comprising an alkyl acrylate--a functional group-containing vinyl compound copolymer. The functional group-containing alkyl acrylate-butadiene-aromatic vinyl compound copolymer can be incorporated into a PC/PBT alloy as an impact modifier, thus the impact strength of the modified alloy composition at room temperature and low temperatures can be increased effectively.Type: GrantFiled: June 27, 1995Date of Patent: November 19, 1996Assignee: Industrial Technology Research InstituteInventors: Cheng-Lung Chao, Juh-Shyong Lee, Feng-Chih Chang
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Patent number: 5576393Abstract: Polymer particles which are substantially spherical and have protrusions on the surface thereof, with such a particle size distribution that the volume mean diameter dv thereof is 1.ltoreq.dv.ltoreq.15 (.mu.m), and the ratio of the volume mean diameter dv to the number mean diameter dn thereof, that is, dv/dn, is 1.ltoreq.dv/dn.ltoreq.1.2, are prepared, and used as a component for a toner for use in electrophotography.Type: GrantFiled: May 26, 1995Date of Patent: November 19, 1996Assignee: Ricoh Company, Ltd.Inventors: Hiroshi Yamashita, Hiromitsu Kawase, Keiko Shiraishi
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Patent number: 5576390Abstract: The present invention provides telechelic polyisobutylenes having aspartic acid ester terminal groups, the production thereof and the use thereof as modifiers preferably for thermoplastic aromatic polycarbonates, and the mixing thereof with reaction-less polyisobutylenes.Type: GrantFiled: June 8, 1995Date of Patent: November 19, 1996Assignee: Bayer AGInventors: Burkhard Kohler, Wolfgang Ebert, Klaus Horn, Richard Weider, Thomas Scholl
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Patent number: 5571869Abstract: Grafted polymer particles are prepared by a free-radical addition polymerization mechanism using a flame produced by igniting a mixture of a combustible gas and an oxidant to heat at least a portion of the surface of a solid polymer particle to produce free-radicals thereon. At least one polymerizable ethylenically unsaturated monomer is contacted and reacted with the free-radicals formed on the surface of the polymer to form a graft thereon.Type: GrantFiled: April 25, 1995Date of Patent: November 5, 1996Assignee: The University of AkronInventors: Sunggyu Lee, Ramesh Rengarajan
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Patent number: 5567775Abstract: This invention provides for curable and graft-cured polymer compositions prepared from a mixture comprising:a) an elastomeric copolymer containing from about 0.01 up to about 10 mole % of Y ester groups randomly distributed along and pendant to the elastomeric polymer chain, said Y ester groups having the structure: ##STR1## wherein R.sub.2 and R.sub.3 are independently selected from the group consisting of hydrogen and an alkyl group containing 1 to about 6 carbon atoms and R.sub.4 is selected from the group consisting of hydrogen, an alkyl group containing from 1 to about 28 carbon atoms, an aryl group and an alkenyl group containing from 2 to about 28 carbon atoms; andb) at least one free radically polymerizable monomer. The invention also provides for a process for preparing graft-cured polymer compositions comprising forming the above recited mixture of (a) and (b) and subjecting said mixture to free radical polymerization conditions. The Y ester groups pendant to the elastomeric polymer chain, e.g.Type: GrantFiled: June 6, 1995Date of Patent: October 22, 1996Assignee: Exxon Chemical Patents Inc.Inventors: Hsien C. Wang, Irwin J. Gardner, James V. Fusco
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Patent number: 5567800Abstract: Controlled molecular weight phenylethynyl terminated imide oligomers (PETIs) have been prepared by the cyclodehydration of precursor phenylethynyl terminated amic acid oligomers. Amino terminated amic acid oligomers are prepared from the reaction of dianhydride(s) with an excess of diamine(s) and subsequently endcapped with phenylethynyl phthalic anhydride(s) (PEPA). The polymerizations are carried out in polar aprotic solvents such as N-methyl-2-pyrrolidinone or N,N-dimethylacetamide under nitrogen at room temperature. The amic acid oligomers are subsequently cyclodehydrated either thermally or chemically to the corresponding imide oligomers. Direct preparation of PETIs from the reaction of dianhydride(s) with an excess of diamine(s) and endcapped with phenylethynyl phthalic anhydride(s) has been performed in m-cresol. Phenylethynyl phthalic anhydrides are synthesized by the palladium catalyzed reaction of phenylacetylene with bromo substituted phthalic anhydrides in triethylamine.Type: GrantFiled: October 28, 1994Date of Patent: October 22, 1996Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Paul M. Hergenrother, Joseph G. Smith, Jr.
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Patent number: 5563118Abstract: An additive composition comprising a graft and derivatized copolymer prepared from ethylene and at least one (C.sub.3 -C.sub.10) alpha- monoolefin and, optionally, a polyene selected from non-conjugated dienes and trienes comprising from about 15 to 80 mole percent of ethylene, from about 20 to 85 mole percent of said (C.sub.3 -C.sub.10) alpha- monoolefin and from about 0 to 15 mole percent of said polyene having an average molecular weight ranging from about 5,000 to 500,000, which has been reacted with at least one olefinic carboxylic acid acylating agent to form one or more acylating reaction intermediates characterized by having a carboxylic acid acylating function within their structure and reacting said reaction intermediate with an amino-aromatic compound to form said graft derivatized copolymer, and a lubricating oil composition containing same are provided.Type: GrantFiled: June 6, 1995Date of Patent: October 8, 1996Assignee: DSM Copolymer, Inc.Inventors: Munmaya K. Mishra, Isaac D. Rubin
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Patent number: 5556923Abstract: The present invention provides a continuous process for producing an adducted derivatized EPM or EPDM oil solution, in which a grafted ethylene polymer is adducted with an antioxidant diamine for formation of an adduct during holding.Type: GrantFiled: August 22, 1995Date of Patent: September 17, 1996Assignee: DSM Copolymer, Inc.Inventors: Tony L. Caines, Michael L. Junker
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Patent number: 5556924Abstract: A photoreactive binder that may be used to enhance photospeed in either conventional plates or on-press developable lithographic printing plates. Briefly, a polymer of m-isopropenyl-.alpha.,.alpha.-dimethylbenzyl isocyanate is derivatized for vinyl group reactivity by reacting the isocyanate groups thereof with hydroxyalkyl acrylate. The resulting photopolymeric binder provides significantly higher photospeed than the non-reactive binder currently utilized in the production of conventional printing plates. The resulting lithographic printing plate also shows better durability (as manifested by longer run-length) and is more easily developed by the microencapsulated developers utilized in the present invention. As to the preparation of the photoreactive binders, the application discloses a method of copolymerizing m-isopropenyl-.alpha.,.alpha.Type: GrantFiled: February 15, 1996Date of Patent: September 17, 1996Assignee: Polaroid CorporationInventors: Maurice J. Fitzgerald, Frederick R. Kearney, Rong-Chang Liang, William C. Schwarzel
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Patent number: 5554695Abstract: There are disclosed a styrenic copolymer which comprises at least one structural unit represented by the general formula (I) ##STR1## and a structural unit represented by the general formula (II) ##STR2## or a structural unit represented by the general formula (IX) ##STR3## wherein the symbols are each as previously defined in the specification, the structural unit (II) or (IX) being contained in an amount of 0.01 to 99.9 mol %; and a process for the production of the above copolymer.The above styrenic copolymer has a high degree of syndiotactic configuration in the stereoregularity of the main chain of the structural unit (I) as well as adhesivity and compatibility with a resin of a different type.Type: GrantFiled: May 4, 1995Date of Patent: September 10, 1996Assignee: Idemitsu Kosan Co. Ltd.Inventors: Shuji Machida, Toshinori Tazaki