Mixed With Additional Polycarboxylic Acid And A Polyamine; Amino Carboxylic Acid Or Derivative; Polyamine Salt Of A Polycarboxylic Acid; Lactam; Or Polymer Derived Therefrom Patents (Class 525/432)
  • Patent number: 5760143
    Abstract: An ester-amide block copolymer of the formula (1): ##STR1## wherein R is an aromatic hydrocarbon group with 6-20 carbon atoms and G is a residue of an aliphatic polyester, an aliphatic polycarbonate, an aliphatic polyethercarbonate or a polyorganosiloxane, and having a weight average molecular weight of 30,000-1,000,000. This copolymer is advantageously prepared by polycondensing an activated acyl lactam-terminated aromatic amide of the formula (2) with a diol of the formula (3) by bulk polymerization in a molten state: ##STR2## wherein R and G are the same as defined above.
    Type: Grant
    Filed: November 15, 1995
    Date of Patent: June 2, 1998
    Assignee: Tosoh Corporation
    Inventors: Yuji Kubo, Hiroshi Yamakawa, Isamu Kirikihira, Shinji Shimosato
  • Patent number: 5756597
    Abstract: Thermomechanical and thermo-oxidative stabilities in resin composites across the range of aerospace "engineering thermoplastic" resins are improved by forming four crosslinks at each addition polymerization site in the backbone of the resin using crosslinking functionalities of the general formula: ##STR1## in the oligomers, wherein ##STR2## .beta.=the residue an organic radical selected from the group consisting of: ##STR3## R.sub.8 =a divalent organic radical; X=halogen;Me=methylT=allyl or methallyl,G=--CH.sub.2 --, --S--, --CO--, --SO--, --O--, --CHR.sub.3 --, or --C(R.sub.3).sub.2 --;i=1 or 2;R.sub.3 =hydrogen, lower alkyl, lower alkoxy, aryl, or aryloxy; and.THETA.=--C.tbd.N, --O--C.tbd.N, --S--C.tbd.N, or --CR.sub.3 .dbd.C(R.sub.3).sub.2.
    Type: Grant
    Filed: February 12, 1997
    Date of Patent: May 26, 1998
    Assignee: The Boeing Company
    Inventors: Hyman R. Lubowtiz, Clyde H. Sheppard
  • Patent number: 5756571
    Abstract: An intumescent fire retardant graft polyamide polymer aving resistance to dripping on exposure to fire, and the method of making such graft polyamide polymers, comprising from about 10-40 percent by weight of a melamine compound, 40-95 percent of a thermoplastic polyamide polymer, and 1-10 percent of an oligomer containing 1-4 monomer units of, or reactive with, the polyamide polymer. The graft polymer is formed at about the melting temperature of the polyamide. Caprolactam, and adipic acid-hexamethylene diamine oligomers perform well in forming the graft polyamides with melamine compounds. Effective melamine compounds are melamine, melamine cyanurate, melamine phosphate, melamine borate, methylol melamine, and trimelamine isocyanurate. Extraneous materials such as fiber, glass, and antioxidants may be added to affect the physical properties of the product.
    Type: Grant
    Filed: February 13, 1997
    Date of Patent: May 26, 1998
    Assignee: Agrinutrients Company, Inc.
    Inventor: William Percy Moore
  • Patent number: 5750633
    Abstract: A dope for cast formation comprising a fluorine including polyimide resin and an organic solvent (P) as main components. The fluorine including polyimide resin has at least one --CF.sub.3 group in the repeating molecular unit. The organic solvent (P) is present during the resin polymerization of the fluorine including polyimide resin. The organic solvent (P) is diethylene glycol dimethyl ether.
    Type: Grant
    Filed: October 24, 1995
    Date of Patent: May 12, 1998
    Assignee: Nitto Denko Corporation
    Inventors: Tomomi Ohara, Hisao Hachisuka
  • Patent number: 5750232
    Abstract: This invention relates to a plastic composite material which comprises:a thermoplastic plastic sheet and, bonded to one side thereof,a thermoplastic spun felt comprising a hot-melt adhesive, to a method of producing it and to its use.
    Type: Grant
    Filed: June 27, 1995
    Date of Patent: May 12, 1998
    Assignee: Elf Atochem Deutschland GmbH
    Inventors: Roland Eugen Steenblock, Joachim Buhrmann
  • Patent number: 5747615
    Abstract: Heat-curable resin systems containing at least one liquid monomer and one solid component, and which have superior tack and drape, may be prepared by slurry mixing a slurry compatible solid into at least one liquid monomer such that the finished resin system contains the solid as a discontinuous phase having a particle size of less than about 20 .mu.m.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: May 5, 1998
    Assignee: Cytec Technology Corp.
    Inventor: Linas Norman Repecka
  • Patent number: 5747591
    Abstract: A combination of polymeric components provides desired characteristics in forming medical instruments such as catheters and balloons for dilatation catheters. For example, a balloon material is formed from a blend of polymeric components, including a first crystalline polymeric component and a second softening polymeric component. Where the first two components are generally incompatible, the balloon material can also include a third compatibilizing agent to facilitate blending the first two polymeric components together. The first polymeric component can be a branched or straight chain polyamide having a molecular weight of at least about 5000, or a polyester prepared from aromatic dicarboxylic acids having 8 to 14 carbon atoms or aliphatic dicarboxylic acids having from 2 to 12 carbon atoms, and at least one glycol having the formula HO(CH.sub.2).sub.n OH, where n is an integer from 2 to 10, neopentyl glycol and cyclohexane dimethanol.
    Type: Grant
    Filed: October 31, 1996
    Date of Patent: May 5, 1998
    Assignee: Advanced Cardiovascular Systems, Inc.
    Inventors: Ziyun Chen, Tai Cheng, Ketan Muni, Udayan Patel, Robert Saltman
  • Patent number: 5739262
    Abstract: This invention relates to a novel ternary polyamide for the production of monofilaments, films and injection moulded articles.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: April 14, 1998
    Assignee: Bayer AG
    Inventors: Heinrich Morhenn, Dieter Brokmeier, Werner Nielinger
  • Patent number: 5728765
    Abstract: The invention is based on the surprising and unexpected finding that the impact performance of a thermoplastic composition containing aromatic polycarbonate resin and glass fibers is improved upon incorporation therewith of a particular silicone rubber powder. The silicone rubber powder, added at a level of about 0.5 to 4 percent, relative to the weight of the composition, is characterized in that it contains a mixture of (a) a polydiorganosiloxane and (b) silica, said glass fibers being of the type which do not, per se, adhere to the polycarbonate matrix in which they are incorporated.
    Type: Grant
    Filed: August 10, 1995
    Date of Patent: March 17, 1998
    Assignee: Bayer Corporation
    Inventors: James Y. J. Chung, Nelson R. Lazear
  • Patent number: 5726278
    Abstract: A process for manufacturing polyamide molded articles having improved resistance to discoloration while also having good heat stability involving preparing masterbatch pellets of at least a polyamide and a heat stabilizer, diluting the polyamide masterbatch pellets with a dilution polyamide resin to form a polyamide mixture, and molding the polyamide mixture into a molded article.
    Type: Grant
    Filed: April 24, 1996
    Date of Patent: March 10, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Tsunao Kenmochi
  • Patent number: 5714566
    Abstract: Thermomechanical and thermo-oxidative stabilities in resin composites across the range of aerospace "engineering thermoplastic" resins are improved by forming four crosslinks at each addition polymerization site in the backbone of the resin using crosslinking functionalities of the general formula: ##STR1## in the oligomers, wherein Z= ##STR2## .beta.=the residue an organic radical selected from the group consisting of: ##STR3## --O--.O slashed.--COOH, --O--.O slashed.--COX, --X, --O.paren open-st.(R.sub.8 .paren close-st.OH, ##STR4## --O--.O slashed.--NH.sub.2 ; E= ##STR5## R.sub.8 =a divalent organic radical; X=halogen;Me=methylT=allyl or methallyl.G=--CH.sub.2 --, --S--, --CO--, --SO--, --O--, --CHR.sub.3 --, or --C(R.sub.3).sub.2 --;i=1 or 2;R.sub.3 =hydrogen, lower alkyl, lower alkoxy, aryl, or aryloxy; and.THETA.=--C.tbd.N; --O--C.tbd.N, --S--C.tbd.N, or --CR.sub.3 .dbd.C(R.sub.3).sub.2.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: February 3, 1998
    Assignee: The Boeing Company
    Inventors: Hyman R. Lubowtiz, Clyde H. Sheppard
  • Patent number: 5708125
    Abstract: A process for producing precondensates of partially crystalline or amorphous, thermoplastically processable, partially aromatic polyamides or copolyamides, and the use of the higher molecular weight of polyamides, accessible from the precondensates, for producing molding compositions, which are further processable by means of suitable processing techniques, involves the control of temperature and water vapor partial pressure, in a batch process.
    Type: Grant
    Filed: July 6, 1995
    Date of Patent: January 13, 1998
    Assignee: EMS-Inventa AG
    Inventors: Hanns-Jorg Liedloff, Manfred Schmid
  • Patent number: 5705600
    Abstract: The present invention relates to blends of a polyester, polyamide or polyester/amide containing a copolymerizable fluorescence quenching compound and a second polymer. The blends of the present invention display reduced fluorescence. Specifically the blends comprise(a) a polyester/amide comprising:(1) a dicarboxylic acid component which comprises at least 0.1 mol % of a dicarboxylic acid selected from the group consisting of terephthalic acid and/or terephthalate ester;(2) a diol and/or diamine component;(3) 0.1 to 99.9 mol %, based on 100 mol % dicarboxylic acid and 100 mol % diol, of a copolymerizable fluorescence quenching compound;(b) a second polymer selected from the group poly(alkylene terephthalate) homo and copolyesters, poly(alkylene naphthalate) homo and copolyesters, poly(cycloalkylene terephthalate) homo and copolyesters, poly(alkylene 1,4-cyclohexanedicarboxylate) homo and copolyesters, and polycarbonate homo and copolymers.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: January 6, 1998
    Assignee: Eastman Chemical Company
    Inventors: Allan Scott Jones, Jean Carroll Fleischer, Max Allen Weaver
  • Patent number: 5705574
    Abstract: Polyimide oligomers include (1) linear, mono-functional crosslinking oligomers prepared by condensing a monoanhydride end cap with a diamine that includes alternating ether and "sulfone" (--SO.sub.2 --, --S--, --CO--, --(CF.sub.3).sub.2 C--, or --(CH.sub.3).sub.2 C--) linkages connecting alternating aromatic radicals and with a dianhydride (or dianhydride mixture), particularly the unsaturated, aliphatic dianhydride commonly known as MCTC; (2) linear, mono- or difunctional crosslinking oligomers prepared by condensing an amine end cap with a diamine and a dianhydride; and (3) multidimensional, crosslinking oligomers having an aromatic hub and at least three radiating arms connected to the hub, each arm including a crosslinking end cap at its distal end and at least one imide linkage.Blends, prepregs, and composites can be prepared from the oligomers.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: January 6, 1998
    Assignee: The Boeing Company
    Inventors: Hyman R. Lubowitz, Clyde H. Sheppard
  • Patent number: 5700900
    Abstract: A copolyamide composition and article molded therefrom, the molded article being transparent, being especially rigid, tough and cold impact resistant, having good resistance to solvents, and exhibiting negligible changes in mechanical properties in the conditioned state due to very low water absorption. The copolyamide composition including long-chain monomer building blocks and being comprised of from about 30 to about 96 parts by weight of at least one long-chain monomer which is suitable as a long-chain building block for a polyamide and which has from 9 to 12 carbon atoms; and from about 4 to about 70 parts by weight of precursor monomers for semiaromatic polyamides, which precursor monomers comprise at least one diamine, H.sub.2 N--R--NH.sub.
    Type: Grant
    Filed: September 15, 1995
    Date of Patent: December 23, 1997
    Assignee: EMS-Inventa AG
    Inventors: Manfred Hewel, Hans Dalla Torre
  • Patent number: 5696202
    Abstract: Colorless, amorphous polyamides, their blends or alloys, and the molded articles with high alternate bending strengths that can be produced from them, are made available; they are preferably made up of aliphatic diamines and aliphatic dicarboxylic acids, and at the same time have high strength, high rigidity, high heat distortion, and good solvent resistance.
    Type: Grant
    Filed: November 9, 1995
    Date of Patent: December 9, 1997
    Assignee: Ems-Inventa AG
    Inventor: Phil. Hans Dalla Torre
  • Patent number: 5691412
    Abstract: A polyamide/aliphatic polyester block copolymer (A) comprising a polyamide block and an aliphatic polyester block, (B) satisfying the expression, T.sub.1 -T<100-C (in which T is the melting point (.degree.C.) of the above block copolymer, T.sub.1 is the melting point (.degree.C.) of a polyamide composed of the polyamide block and C is the content (wt. %) of the polyamide block), (C) exhibiting the extraction amount which satisfies the expression, when extracted in tetrahydrofuran, E<(100-C).times.0.4 (in which E is the extraction amount (wt. %) when the block copolymer is refluxed in tetrahydrofuran, and C is the content (wt. %) of the polyamide block) and (D) having an intrinsic viscosity, measured at 35.degree. C., in the range of from 0.5 to 5; a process for the production thereof; a fiber formed therefrom; and an intimate blend comprising a thermoplastic resin having no or poor compatibility with polyamide and the block copolymer.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: November 25, 1997
    Assignee: Teijin Limited
    Inventors: Shunichi Matsumura, Takashi Ito, Takanori Miyoshi
  • Patent number: 5688901
    Abstract: Partly aromatic semicrystalline thermoplastic polyamide molding compositions containA) from 40 to 100% by weight of a copolyamide composed ofa.sub.1) from 30 to 44 mol % of units which are derived from terephthalic acid,a.sub.2) from 6 to 20 mol % of units which are derived from isophthalic acid,a.sub.3) from 43 to 49.5 mol % of units which are derived from hexamethylenediamine anda.sub.4) from 0.5 to 7 mol % of units which are derived from aliphatic cyclic diamines of 6 to 30 carbon atoms,the molar percentages of components a.sub.1) to a.sub.4) together giving 100%, andB) from 0 to 50% by weight of a fibrous or particulate filler,C) from 0 to 30% by weight of an elastomeric polymer andD) from 0 to 30% by weight of conventional additives and processing assistants,the percentages by weight of components A) to D) together giving 100%.
    Type: Grant
    Filed: February 6, 1995
    Date of Patent: November 18, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Fisch, Gunter Pipper, Klaus Muhlbach, Heiner Gorrissen
  • Patent number: 5684120
    Abstract: Colorless, transparent copolyamides, made up of monomers based on cycloaliphatic diamines and aromatic dicarboxylic acids and a maximum of 20 mol % of further polyamide-forming aliphatic monomers, which have glass transition temperatures of at least 175.degree. C., their blends and alloys, along with the molded articles that can be produced from them and a process for their preparation are proposed.
    Type: Grant
    Filed: November 9, 1995
    Date of Patent: November 4, 1997
    Assignee: EMS-Inventa AG
    Inventor: Phil Hans Dallas Torre
  • Patent number: 5677394
    Abstract: A melt-processable block copolyesterimide comprising the repeating units (I), (II) and (III) and, optionally, a repeating unit (IV), wherein (I) is a repeating unit of the formula ##STR1## wherein R is an aliphatic polyether chain and/or a polysiloxane chain; (II) and (III) are repeating units of the formulas ##STR2## wherein Z is hydrogen, alkyl, alkoxy, aryl, halogen and w is zero or one; and (IV) is a repeating unit of the formula ##STR3## wherein Z' is hydrogen, alkyl, alkoxy, aryl or halogen and the phenylene ring is substituted in by Z' in the m- or p-positions. The repeating unit of formula (I) is present in an amount of 5 to 50 mole-%, the repeating unit of formula (II) is present in an amount of 10 to 80 mole-%, the repeating unit of formula (III) is present in an mount of 5 to 50 mole-% and the repeating unit of formula (IV) is present in an amount of 0 to 45 mole-% of the block copolyesterimide.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: October 14, 1997
    Assignee: Neste OY
    Inventors: Frank Bohme, Doris Pospiech, Manfred Ratzsch, Christer Bergstrom, Mika Harkonen, Heli Alanko, Pentti Passiniemi
  • Patent number: 5674952
    Abstract: The resin composition of the present invention allows the molding of a hollow molded product, able to stably form a long parison and having a three-dimensionally curved shape, by the formation of a copolyamide having a melting point of 225.degree. C. or more and a crystallization temperature of 230.degree. C. or less obtained by a polymerization of 66, 6T and 6I components at a specific compounding ratio.
    Type: Grant
    Filed: April 13, 1994
    Date of Patent: October 7, 1997
    Assignee: Toray Industries, Inc.
    Inventors: Koji Onishi, Shiro Kataoka, Masatoshi Iwamoto
  • Patent number: 5670608
    Abstract: A polyamide (9-T polyamide) comprising (a) 60 to 100 mole of terephthalic acid and (b) a diamine component comprising 60 to 100 mole % of 1,9-nonanediamine, said polyamide having an intrinsic viscosity ?.eta.! as determined by measurement in concentrated sulfuric acid at 30.degree. C. of 0.6 to 2.0 dl/g and having at least 10% of terminal groups thereof blocked. Another polyamide (9M-T polyamide) comprises a dicarboxylic acid component (a) comprising 60 to 100 mole % of terephthalic acid and a diamine component (b) comprising 60 to 100 mole % of 1,9-nonanediamine and 2-methyl-1,8octanediamine, the molar ratio between said 1,9 nonanediamine and said 2-methyl-1,8-octanediamine being in a range of 60:40 to 99:1, said polyamide having an intrinsic viscosity ?.eta.! as determined by measurement in concentrated sulfuric acid at 30.degree. C. of 0.4 to 3.0 dl/g.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: September 23, 1997
    Assignee: Kuraray Co., Ltd.
    Inventors: Hideaki Oka, Tsugunori Kashimura, Shinichi Yokota, Hiroshi Hayashihara
  • Patent number: 5665815
    Abstract: Compositions including at least one polyamide obtained by polycondensation of meta-xylylenediamine and of a dicarboxylic acid, as well as at least one copolymer based on methyl methacrylate and on acrylic and/or methacrylic acid, the said copolymer being advantageously at least partially neutralized with an alkali metal. These compositions exhibit a high melt viscosity at low shear rate, which facilitates their processing.
    Type: Grant
    Filed: August 14, 1995
    Date of Patent: September 9, 1997
    Assignee: Solvay (Societe Anonyme)
    Inventors: Robert Vankan, Philippe Degee, Robert Jerome, Philippe Teyssie
  • Patent number: 5658995
    Abstract: Random block copolymers having the formula: ##STR1## wherein R.sub.1 is --CH.dbd.CH-- or (--CH.sub.2 --).sub.j, in which j is zero or an integer from one to eight; R.sub.2 is selected from hydrogen, straight and branched alkyl and alkylaryl groups containing up to 18 carbon atoms and derivatives or biologically and pharmaceutically active compounds covalently bonded to said copolymer; each R.sub.3 is independently an alkylene group containing up to 4 carbon atoms; y is an integer between about 5 and about 3000; and f is the percent molar fraction of alkylene oxide in the copolymer and ranges between about 1 and about 99 mole percent. Implantable medical devices and drug delivery implants containing the random block copolymers are also disclosed, along with methods for drug delivery and for preventing the formation of adhesions between injured tissues employing the random block copolymers. Polyarylate random block copolymers are also described.
    Type: Grant
    Filed: November 27, 1995
    Date of Patent: August 19, 1997
    Assignee: Rutgers, The State University
    Inventors: Joachim B. Kohn, Chun Yu
  • Patent number: 5654396
    Abstract: We achieve solvent resistance and extended use life for advanced polyimides by including at least some solvent-resistant linkages in the backbone in place of phenoxyphenyl sulfone linkages and using diPEPA or PEPA crosslinking end caps.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: August 5, 1997
    Assignee: The Boeing Company
    Inventors: Hyman R. Lubowitz, Clyde H. Sheppard
  • Patent number: 5652326
    Abstract: A polyetheresteramide having good heat resistance, permanent antistatic property and superior compatibility with thermoplastic resins and a resin composition containing of the polyetheresteramide are disclosed, wherein the polyetherester-amide consists essentially of a polyamide oligomer with carboxylic chain ends having a number average molecular weight between 200 and 5,000 and a bisphenol compound with oxyalkylene units having a number average molecular weight between 300 and 3,000. Antistatic resin compositions with good antistatic property and heat resistance are obtained from compositions comprising 3 to 40% by weight of the polyetheresteramide and 60 to 97% by weight of thermoplastic resins. The antistatic resin compositions can contain as compatibilizers vinyl polymers having functional groups such as carboxyl and epoxy groups or block polymers containing polyolefin blocks and aromatic vinyl polymer blocks.
    Type: Grant
    Filed: March 1, 1994
    Date of Patent: July 29, 1997
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Yasuhiro Ueda, Eiichi Senda, Yoshitsugu Takai, Tokiko Kokubu, Toshiaki Okamoto, Eiji Ichihara
  • Patent number: 5645850
    Abstract: The present invention describes an aliphatic polyoxaamide polymer and blends thereof that may be used to produce surgical devices such as sutures, sutures with attached needles, molded devices, and the like. The aliphatic polyoxaamide of the present invention have a first divalent repeating unit of formula I:[X--C(O)--C(R.sub.1) (R.sub.2)--O--(R.sub.3)--O--C(R.sub.1) (R.sub.2)--C(O)--] Iand a second repeating unit selected from the group of formulas consisting of:[--Y--R.sub.17 --].sub.T, I[--O--R.sub.5 --C(O)--].sub.B, and III([--O--R.sub.9 --C(O)].sub.P --O--) XIand combinations thereof, wherein X and Y are selected from the group consisting of --O-- and --N(R)--, provided both X and Y are not both --O-- and may be blended with a second polymer that is preferably biocompatable.
    Type: Grant
    Filed: August 7, 1996
    Date of Patent: July 8, 1997
    Assignee: Ethicon, Inc.
    Inventors: Rao S. Bezwada, Dennis D. Jamiolkowski
  • Patent number: 5639833
    Abstract: The invention is directed to molding materials containingA) from 1 to 99% by weight of polyarylene ethers having repeating units I ##STR1## where t and q may each be an integer 0, 1, 2 or 3,T, Q and Z may each be a chemical bond or --O--, --S--, --SO.sub.2 --, S.dbd.O, C.dbd.O, --N.dbd.N--, R.sup.a C.dbd.CR.sup.b -- or --CR.sup.c R.sup.d --, with the proviso that at least one of the groups T, Q and Z is --SO.sub.2 -- or C.dbd.O,R.sup.a and R.sup.b,R.sup.c and R.sup.d, andAr and Ar.sup.1 are as defined in the specification,B) from 1 to 99% by weight of copolyamides containingb.sub.1) from 30 to 44 mol % of units which are derived from terephthalic acid,b.sub.2) from 6 to 20 mol % of units which are derived from isophthalic acid,b.sub.3) from 43 to 49.5 mol % of units which are derived from hexamethylenediamine,b.sub.4) from 0.5 to 7 mol % of units which are derived from aliphatic cyclic diamines of 6 to 30 carbon atoms andb.sub.5) from 0 to 4 mol % of further polyamide-forming monomers which differ from b.sub.
    Type: Grant
    Filed: August 10, 1995
    Date of Patent: June 17, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Weber, Herbert Fisch, Gunter Pipper, Axel Gottschalk
  • Patent number: 5639832
    Abstract: Process for the preparation of products of the reaction of polyaspartimides and amino acids by reaction of amino acids with polyaspartimides in aqueous medium at pH values at which at least 5% of the amino groups in the amino acids are in non-protonated form in equilibrium with the protonated form, and use of the reaction products obtainable in this way and of products of the reaction of polyaspartimides with alkanolamines or aminated C.sub.1 -C.sub.30 -fatty alcohol alkoxylates which contain as copolymerized units up to 50 mol % of ethylene oxide and/or propylene oxide per mol of fatty alcohol, as additive to detergents and cleaners, as scale inhibitor and as dispersant.
    Type: Grant
    Filed: September 6, 1995
    Date of Patent: June 17, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Gunnar Schornick, Dieter Boeckh, Richard Baur, Birgit Potthoff-Karl, Volker Schwendemann, Christian Schade, Alexander Kud
  • Patent number: 5639723
    Abstract: Reaction products of polybasic acids and amino-containing compounds, which are obtainable by heating a mixture of (a) a polybasic carboxylic acid selected from the group consisting of citric acid, isocitric acid, aconitic acid, itaconic acid and/or tartaric acid and (b) an amino-containing compound in a molar ratio of (a) to (b) of from 1:0.1 to 1:10 to at least 80.degree. C. are used as additives in low-phosphate and phosphate-free detergents and cleaning agents.
    Type: Grant
    Filed: January 23, 1995
    Date of Patent: June 17, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Dieter Boeckh, Richard Baur, Alexander Kud, Volker Schwendemann
  • Patent number: 5637653
    Abstract: Polymer blend materials composed of an aromatic polyamide and flexible polyamide wherein the aromatic polyamide molecules are uniformly dispersed in a matrix of the flexible polyamide which are produced by first blending the flexible polyamide and monomer(s) for the aromatic polyamide in a solvent, then next polymerizing the monomer(s) in the presence of a phosphite compound, resulting in a transparent gel product capable of being fabricated into useful shaped articles without causing marked phase separation observed in polymer blend materials obtained by conventional coagulation method. The in situ formed aromatic polyamide is uniformly dispersed in the flexible polyamide matrix even in fabricated forms, giving improved transparency over the starting flexible polyamide and improved resistance toward chemicals such as acids, especially after heat treatment.
    Type: Grant
    Filed: May 2, 1995
    Date of Patent: June 10, 1997
    Assignees: Dainippon Ink and Chemicals, Incorporated, Research Triangle Institute
    Inventors: Jack Preston, Satoshi Idemura
  • Patent number: 5635586
    Abstract: Polymers of maleic acid may be prepared by thermally polymerizing malic acid, maleic acid or fumaric acid with less than one equivalent of ammonia. The polymers are modified by the incorporation of amines, carboxylic acids or combinations thereof. The polymers formed are excellent inhibitors of alkaline earth salt deposition, dispersants, tartar control additives, detergent additives, and water treatment agents.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: June 3, 1997
    Assignee: Calwood Chemical Industries, Inc.
    Inventors: Louis L. Wood, Gary J. Calton
  • Patent number: 5608014
    Abstract: The present invention provides a three-component blend of (i) certain aromatic polyethersulfones, (ii) certain aromatic polyimides, and (iii) certain aromatic polyimides, polyamides or polyamide-imides or mixtures thereof. The blends provide gas separation membranes with superior gas transport properties.
    Type: Grant
    Filed: April 17, 1995
    Date of Patent: March 4, 1997
    Assignee: L'Air Liquide, S.A.
    Inventor: Okan M. Ekiner
  • Patent number: 5599658
    Abstract: A highly useful photographic film base comprises a miscible blend of poly(ethylene naphthalate) and a poly(ether imide) in specified proportions. Photographic elements prepared with this film base have a lesser tendency to take core-set and post process curl than do elements prepared with poly(ethylene naphthalate) film base.
    Type: Grant
    Filed: December 19, 1995
    Date of Patent: February 4, 1997
    Assignee: Eastman Kodak Company
    Inventors: Jehuda Greener, Wen-Li A. Chen
  • Patent number: 5591809
    Abstract: The present invention provides novel one-step processes for preparing highly branched macromolecule polymers that have highly controlled molecular architectures. The process comprises the reaction of a branching monomer such as a substituted phenyl compound having the formula: ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 are defined herein, with a core monomer and an end-capping monomer, such as a phenolic ester, for a sufficient period of time and at a sufficient temperature to directly produce the highly branched polymer, in a single processing step.
    Type: Grant
    Filed: August 18, 1995
    Date of Patent: January 7, 1997
    Assignee: Hoechst Celanese Corporation
    Inventors: Richard Vicari, Kathleen N. Juneau, Carl D. Murphy
  • Patent number: 5576389
    Abstract: A powder coating comprising a thermosetting resinous composition comprising a base resin having 2 or more oxirane groups in its molecule and a hardener for epoxy resin, which is characterized by further containing 0.5 to 10% by weight based on the base resin weight of a vinyl resin containing 1 to 10% by weight of at least one aliphatic dicarboxylic acid selected from thiomalic acid, maleic acid, fumaric acid and itaconic acid and having a number average molecular weight of 1000 to 8000 and a glass transition temperature of -40.degree. to 100.degree. C. The coating obtained is excellent in smoothness, gloss and image clarity.
    Type: Grant
    Filed: August 14, 1995
    Date of Patent: November 19, 1996
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Tasaburo Ueno, Akimitsu Uenaka, Harunori Gohji, Yuji Toyoda, Kouichi Tsutsui
  • Patent number: 5571874
    Abstract: A molecular composite material having excellent properties such as mechanical strength, heat resistance, solvent resistance, etc. is produced by dissolving a prepolymer of a rigid aromatic polymer in a monomer of a matrix polymer to form a homogeneous solution and then heating the homogeneous solution to cause a thiazole ring closure reaction of the prepolymer and a polymerization reaction of the monomer.
    Type: Grant
    Filed: August 22, 1994
    Date of Patent: November 5, 1996
    Assignee: Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Tatsuya Hattori, Kazuhiro Kagawa, Hiroshi Akita, Hiroto Kobayashi
  • Patent number: 5569724
    Abstract: N-Methylol derivatives of polycondensation products containing quaternary N atoms obtained fromA) basic ureas of the formulaHN(R.sup.1)--C--N(R.sup.2)--X.sup.1 --N(R.sup.3, R.sup.4) (I),B) polyamines of the formula(R.sup.6, R.sup.7)N--X.sup.2 --N(R.sup.8, R.sup.9) (II)andC) bifunctional alkylating agents,in whichX.sup.1, X.sup.2 and R.sup.1 -R.sup.9 have the meanings given in the description, are new. They are used as agents for improving the wet fastness properties of dyeings on cellulose and cellulose blend fabrics.
    Type: Grant
    Filed: January 27, 1995
    Date of Patent: October 29, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Udo-Winfried Hendricks, Ralf Heinen
  • Patent number: 5565523
    Abstract: A combination of polymeric components provides desired characteristics in forming medical instruments such as catheters and balloons for dilatation catheters. For example, a balloon material is formed from a blend of polymeric components, including a first crystalline polymeric component and a second softening polymeric component. Where the first two components are generally incompatible, the balloon material can also include a third compatibilizing agent to facilitate blending the first two polymeric components together. The first polymeric component can be a branched or straight chain polyamide having a molecular weight of at least about 5000, or a polyester prepared from aromatic dicarboxylic acids having 8 to 14 carbon atoms or aliphatic dicarboxylic acids having from 2 to 12 carbon atoms, and at least one glycol having the formula HO(CH.sub.2).sub.n OH, where n is an integer from 2 to 10, neopentyl glycol and cyclohexane dimethanol.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: October 15, 1996
    Assignee: Advanced Cardiovascular Systems, Inc.
    Inventors: Ziyun Chen, Tai Cheng, Ketan Muni, Udayan Patel, Robert Saltman
  • Patent number: 5561201
    Abstract: The molecular composite material having excellent properties such as mechanical strength, heat resistance, solvent resistance, etc. is produced by (a) polymerizing an aromatic diaminodithiol compound, of which hydrogen atoms of thiol groups of aromatic diaminodithiol compound are substituted with substituted or unsubstituted alkyl groups, with a dicarboxylic acid derivative to form an aromatic polythiazole prepolymer, (b) dissolving the aromatic polythiazole prepolymer in an organic solvent to prepare a solution thereof; (c) adding a monomer of the matrix polymer to the solution to polymerize the monomer to the matrix polymer in the solution; (d) removing the organic solvent from a mixture of the aromatic polythiazole prepolymer and the matrix polymer; and (e) heating a mixture of the aromatic polythiazole prepolymer and the matrix polymer to cause a thiazole ring closure reaction of the aromatic polythiazole prepolymer.
    Type: Grant
    Filed: March 15, 1994
    Date of Patent: October 1, 1996
    Assignee: Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Tatsuya Hattori, Kazuhiro Kagawa
  • Patent number: 5552518
    Abstract: Polymers of maleic acid may be prepared by thermally polymerizing malic acid, maleic acid or fumaric acid with less than one equivalent of ammonia. The polymers are modified by the incorporation of amines, carboxylic acids or combinations thereof. The polymers formed are excellent inhibitors of alkaline earth salt deposition, dispersants, tartar control additives, detergent additives, and water treatment agents.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: September 3, 1996
    Assignee: Calwood Chemical Industries, Inc.
    Inventors: Louis L. Wood, Gary J. Calton
  • Patent number: 5541267
    Abstract: A polyamide composition comprising an aliphatic polyamide such as nylon 6 and an oligomeric aromatic polyamide, such as oligomers of poly(tolylene diisophthalamide), which exhibit improved retention flexural modulus and flexural strength at ambient humidity, i.e. about 50% to about 65%.
    Type: Grant
    Filed: November 28, 1994
    Date of Patent: July 30, 1996
    Assignee: AlliedSignal Inc.
    Inventors: Murali K. Akkapeddi, Jeffrey H. Glans, Gerald J. Dege, Sengshiu J. Chung
  • Patent number: 5536792
    Abstract: A process is disclosed for making circuit elements by photolithography comprising depositing an antireflective polyimide or polyimide precursor layer on a substrate and heating the substrate at 200.degree. C. to 500.degree. to provide a functional integrated circuit element that includes an antireflective polyimide layer. The antireflective polyimide layer contains a sufficient concentration of at least one chromophore to give rise to an absorbance sufficient to attenuate actinic radiation at 405 or 436 nm. Preferred chromophores include those arising from perylenes, naphthalenes and anthraquinones. The chromophore may reside in a dye which is a component of the polyimide coating mixture or it may reside in a residue which is incorporated into the polyimide itself.
    Type: Grant
    Filed: April 19, 1995
    Date of Patent: July 16, 1996
    Assignee: International Business Machines Corporation
    Inventors: Dennis P. Hogan, Harold G. Linde, Ronald A. Warren
  • Patent number: 5534602
    Abstract: Polyetherimide compositions are provided having condensed bis (4-aminophenyl) sulfone units, diaminophenylindane units or a mixture thereof. These polyetherimides compositions have been found useful for making high temperature chip adhesives, laminating adhesives and film adhesives for high density interconnects in electronic circuitry.
    Type: Grant
    Filed: April 19, 1993
    Date of Patent: July 9, 1996
    Assignee: General Electric Company
    Inventors: John H. Lupinski, Herbert S. Cole, Jr.
  • Patent number: 5530091
    Abstract: Molten maleic anhydride is introduced in the form of fine droplets at 53.degree. C. to 250.degree. C. and preferably at 60.degree. C. to 120.degree. C. into a gas atmosphere which consists either of pure gaseous ammonia or of a gas mixture of ammonia and at least one other gas and of which the temperature is between 20.degree. C. and 500.degree. C. The process is carried out at a temperature of 120.degree. C. to 180.degree. C. for the production of polysuccinimide and at a temperature of 10.degree. C. to 120.degree. C. for the production of maleic amide acid.
    Type: Grant
    Filed: February 21, 1995
    Date of Patent: June 25, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Paul Wagner, Dietrich Gehrmann, Thomas Bamberger, Manfred Giltjes, Winfried Joentgen, Torsten Groth
  • Patent number: 5527863
    Abstract: Copolymers of polyaspartic acid which are suitable for the inhibition of scale deposition were obtained by reacting maleic acid, an additional polycarboxylic acid and ammonia in a stoichiometric excess, at 120.degree.-350.degree. C., preferably 180.degree.-300.degree. C., to provide copolymers of polysuccinimide. In a second embodiment, a polyamine was added to the reaction mix. These intermediate polysuccinimide copolymers could then be converted to the salts of copolymers of polyaspartic acid by hydrolysis with a hydroxide.Such copolymers are useful in preventing deposition of scale from water and find applications in treating water. Other applications include scale prevention additives for detergents. In addition, such copolymers inhibit dental tartar and plaque formation.
    Type: Grant
    Filed: January 27, 1995
    Date of Patent: June 18, 1996
    Assignee: Bayer AG
    Inventors: Louis L. Wood, Gary J. Calton
  • Patent number: 5527610
    Abstract: The invention provides a bioelastomer comprising tetrapeptide and/or pentapeptide monomeric units of the formula:R.sub.1 PGR.sub.2 G.sub.nwherein R.sub.2 is a peptide-producing residue of alanine or glycine; P is a peptide-producing residue of proline; G is a peptide-producing residue of glycine; R.sub.2 is a peptide-producing residue of glycine or alanine; and n is 0 or 1. In a further aspect of the invention, a method is provided for preventing adhesion of biological materials, such as protein, cells, and tissues, by forming a protective layer between a first surface and a second surface using the bioelastomer.
    Type: Grant
    Filed: May 20, 1994
    Date of Patent: June 18, 1996
    Assignees: The UAB Research Foundation, Bioelastics Research, Ltd.
    Inventor: Dan W. Urry
  • Patent number: 5521279
    Abstract: Polymers of maleic acid may be prepared by thermally polymerizing malic acid, maleic acid or fumaric acid with less than one equivalent of ammonia. The polymers are modified by the incorporation of amines, carboxylic acids or combinations thereof. The polymers formed are excellent inhibitors of alkaline earth salt deposition, dispersants, tartar control additives, detergent additives, and water treatment agents.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: May 28, 1996
    Assignee: Calwood Chemical Industries, Inc.
    Inventors: Louis L. Wood, Gary J. Calton
  • Patent number: 5519109
    Abstract: Moisture-curing polyamides containing reactive alkoxysilane groups and a process for their preparation are provided. The reactive alkoxysilane groups contain organic groups which are not reactive during the production process, the intended application or the curing process. These moisture-curing polyamides have low melt viscosities and are useful as sealing compounds, hotmelt adhesives and encapsulating materials.
    Type: Grant
    Filed: January 17, 1995
    Date of Patent: May 21, 1996
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hans-Georg Kinzelmann, Reimar Heucher, Juergen Wichelhaus
  • Patent number: 5519110
    Abstract: Polymers of maleic acid may be prepared by thermally polymerizing malic acid, maleic acid or fumaric acid with less than one equivalent of ammonia. The polymers are modified by the incorporation of amines, carboxylic acids or combinations thereof. The polymers formed are excellent inhibitors of alkaline earth salt deposition, dispersants, tartar control additives, detergent additives, and water treatment agents.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: May 21, 1996
    Assignee: Calwood Chemical Industries, Inc.
    Inventors: Louis L. Wood, Gary J. Calton