Mixed With -n=c=x Reactant Or Polymer Derived Therefrom (x Is Chalcogen); Or Wherein Solid Polymer Is Derived From A -n=c=x Reactant And Also A Polycarboxylic Acid Or Derivative And A Polyhydroxy Reactant Patents (Class 525/440.01)
  • Patent number: 8334347
    Abstract: A 2K basecoat clearcoat system includes a solvent borne basecoat having a low Tg branched polyester polyol, optionally, a high Tg, high molecular weight thermoplastic resin, and a hardener that includes an isocyanate functional material suitable for crosslinking the polyester polyol, and optional thermoplastic resin. The solvent borne clearcoat composition includes a low Tg linear or branched polyester polyol, at least one other multi-functional polyol, and an isocyanate functional material suitable for crosslinking the polyester and multi-functional polyols.
    Type: Grant
    Filed: February 10, 2010
    Date of Patent: December 18, 2012
    Assignee: The Sherwin-Williams Company
    Inventors: Hong Ding, Zhicheng Li, Weilin Tang, Ganesh S. Desai, Thomas J. Staunton, Brian J. Wayton, Heather N. Becker, Prabhjot K. Sahota
  • Patent number: 8318845
    Abstract: The invention provides a golf ball having a core and a cover of at least one layer that is formed over the core and is made of a resin composition. The ball has a weight change ratio, in a 72-hour accelerated moisture absorption test conducted at a temperature of 40° C. and a relative humidity of 90%, of less than 0.287%. By using in the golf ball a polyurethane having a good resistance to water vapor transmission, the weight change ratio and decrease in initial velocity with use over an extended period of time are held to a minimum, enabling the ball quality to be maintained.
    Type: Grant
    Filed: October 7, 2009
    Date of Patent: November 27, 2012
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Satoshi Matsuda, Hiroyuki Nagasawa
  • Publication number: 20120269974
    Abstract: The invention relates to an aqueously dispersible polyurethane having a specific amount of substance of hydroxyl groups, —OH, of at least 0.6 mol/kg, and additionally satisfying at least two of the following conditions: a) a degree of branching measured as specific amount of substance of tertiary and/or quaternary aliphatic carbon atoms of from 0.01 mol/kg to 0.5 mol/kg, b) a specific amount of urea groups >N—CO—N< of from 0.8 mol/kg to 2 mol/kg, and c) a specific amount of substance of hydroxyl groups, —OH, of from 1 mol/kg to 4 mol/kg, wherein in each case the specific amount of substance is based on the mass of the polyurethane, a process for the preparation thereof, and a method of use thereof.
    Type: Application
    Filed: October 27, 2010
    Publication date: October 25, 2012
    Applicant: CYTEC AUSTRIA GmbH
    Inventors: Anton Arzt, Markus Schafheutle, Gerlinde Petritsch, Julius Burkl, Robert Harrer, Ulrike Kuttler
  • Patent number: 8293836
    Abstract: A curable coating composition includes a uretdione compound having one uretdione group and having a plurality of functional groups selected from crosslinkable groups and groups that modify a coating property. The disclosed coating compositions include those having a binder component having a plurality of active hydrogen-containing groups. When the uretdione compound has a functional group that is a crosslinkable group, the coating composition further includes a crosslinker that has a plurality of crosslinking groups reactive under curing conditions with the crosslinkable group. Also disclosed is a method of making the curable coating composition, including preparing the uretdione compound having one uretdione group and having at least one further functional group.
    Type: Grant
    Filed: May 20, 2009
    Date of Patent: October 23, 2012
    Assignee: BASF Coatings GmbH
    Inventors: David C. Cranfill, Walter H Ohrbom, Patrick J Mormile
  • Publication number: 20120264609
    Abstract: The present invention provides a composition comprising an active ingredient with a maximum solubility in water at 20° C. of 10 g/l, and a hyperbranched polyester which is joined to a polar polymer which comprises a polycondensate or a polymer comprising ethylenically unsaturated monomers. The invention further relates to the hyperbranched polyester mentioned and to a process for preparation thereof. It further relates to the use of the hyperbranched polyester for solubilizing the active ingredient in aqueous compositions.
    Type: Application
    Filed: December 15, 2010
    Publication date: October 18, 2012
    Inventors: Holger Türk, Monika Haberecht, Hiroe Yamada, Bernd Bruchmann, Daniel Schönfelder, Michael Ishaque, Joachim Clauss
  • Patent number: 8288478
    Abstract: Golf balls containing at least one layer made from a thermoplastic polyurethane or polyurethane-urea that is the reaction product of a polyisocyanate with moisture-resistant polyol and a curing agent are provided. The moisture-resistant polyol may be prepared by dimerizing unsaturated aliphatic monocarboxylic acid or ester containing 10 to 60 carbon atoms followed by reacting it with a monomeric, oligomeric, or polymeric diol. In one preferred version, the moisture-resistant polyol is a branched polyester polyol containing 36 carbon atoms. The composition can be prepared using prepolymer or one-shot manufacturing techniques. The resulting golf ball has desirable playing performance properties including high resiliency, toughness, impact durability, moisture-resistance, and soft feel.
    Type: Grant
    Filed: February 25, 2010
    Date of Patent: October 16, 2012
    Assignee: Acushnet Company
    Inventors: Murali Rajagopalan, Derek A. Ladd, Michael J. Sullivan
  • Patent number: 8278397
    Abstract: Disclosed are a medical instrument and a medical material each comprising an aliphatic polyester resin composition, which are hardly reduced in strength and impact resistance upon the sterilization by ionizing radiation or have excellent shape-retaining properties after a heat treatment. Specifically, a medical instrument and a medical material both sterilized by ionizing radiation are provided, each of which contains a biodegradable resin and a polycarbodiimide compound in an amount of 0.1 to 10% by weight on the resin. The biodegradable resin is polybutylene succinate, a copolymer of polybutylene succinate, or a mixture of polybutylene succinate and a copolymer of polybutylene succinate with polylactic acid or poly(3-hydroxyalkanoate). A method of producing such medical instrument and medical material is also provided.
    Type: Grant
    Filed: March 23, 2009
    Date of Patent: October 2, 2012
    Assignee: Terumo Kabushiki Kaisha
    Inventor: Hiromasa Kohama
  • Patent number: 8252868
    Abstract: A thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property containing (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer of (B1) a hard segment block with at least one of a polyamide, polyester, polyolefin or polyurethane, and (B2) a soft segment block having an ether bond.
    Type: Grant
    Filed: November 4, 2011
    Date of Patent: August 28, 2012
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Masaaki Mawatari, Tatsuya Toneri
  • Publication number: 20120095168
    Abstract: A method for controlling the physical state of an ultra-high molecular weight polymer to make the ultra-high molecular weight polymer suitable for further processing, and related polymers compositions methods and systems, wherein the method comprises combining a catalyst, monomers, and an additive, for a time and under condition to allow synthesis of a nascent polymer and co-crystallization of the nascent polymer with the additive.
    Type: Application
    Filed: October 18, 2011
    Publication date: April 19, 2012
    Inventors: Julia A. KORNFIELD, Artemis AILIANOU, Sara RONCA, Sanjay RASTOGI, Giuseppe FORTE
  • Patent number: 8143341
    Abstract: An aqueous coating composition containing a colorant, a film-forming polymer and a curing agent. The composition further comprises an adjuvant resin having two or more functional groups reactive with the curing agent and positioned between the functional groups a moiety containing at least 10 contiguous carbon atoms.
    Type: Grant
    Filed: March 29, 2006
    Date of Patent: March 27, 2012
    Assignee: PPG Industries Ohio, Inc
    Inventors: Shanti Swarup, Calum H. Munro
  • Publication number: 20120035324
    Abstract: The invention relates to a process for preparing a reinforced and reactive thermoplastic composition having a continuous phase which is based on at least one thermoplastic polymer and dispersed in which is a discontinuous phase based on at least one reactive reinforcing agent that may be immiscible with said at least one thermoplastic polymer, and also to a composition obtained by this process.
    Type: Application
    Filed: August 2, 2011
    Publication date: February 9, 2012
    Applicant: HUTCHINSON
    Inventors: Nicolas Garois, Philippe Sonntag, Grégory Martin, Matthieu Vatan, Jacques Drouvroy
  • Patent number: 8106133
    Abstract: The invention provides a flexible tube for an endoscope, which is excellent in elasticity (impact resilience), has suitable flexibility and also has chemical resistance. Disclosed is a flexible tube for an endoscope including a flexible-tube material covered thereon with a jacket, wherein the jacket contains two or more thermoplastic polyester elastomers crosslinked therein.
    Type: Grant
    Filed: July 19, 2010
    Date of Patent: January 31, 2012
    Assignee: Olympus Medical Systems Corp.
    Inventors: Hitoshi Ogura, Yuuri Takeuchi
  • Patent number: 8084538
    Abstract: The present invention provides a thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property. The present invention relates to a thermoplastic polymer composition comprising (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer comprising (B1) a hard segment block comprising at least one polymer selected from the group consisting of a polyamide, a polyester, a polyolefin and a polyurethane, and (B2) a soft segment block having an ether bond, with the proviso that a total amount of the components (A) and (B) is 100% by mass.
    Type: Grant
    Filed: January 26, 2009
    Date of Patent: December 27, 2011
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Masaaki Mawatari, Tatsuya Toneri
  • Publication number: 20110306734
    Abstract: The present invention relates to a thermoplastically processable polyurethane elastomer having a hardness of 50 Shore A to 70 Shore D (ISO 868), which are obtained from reacting components comprising a) one or more linear polyester diols having a functionality from 1.8 to 2.2, wherein the one or more linear polyester diols comprise succinic acid 1,3-propionate and have an average molecular weight from 1,950 to 4,000 g/mol. b) one or more organic diisocyanates, and c) one or more diols having a molecular weight from 60 to 350 g/mol, wherein the components have a molar NCO:OH ratio of from 0.9:1 to 1.1:1.
    Type: Application
    Filed: May 26, 2011
    Publication date: December 15, 2011
    Applicant: Bayer MaterialScience AG
    Inventors: Wolfgang Bräuer, Yi Shen, Wolfgang Kaufhold, Hartmut Nefzger, Henricus Peerlings
  • Publication number: 20110306719
    Abstract: Blends made of thermoplastic polyurethanes (TPUs) and of polylactides (PLAs) are produced via A) reaction of at least one thermoplastic polyurethane with at least one diisocyanate or one diisocyanate prepolymer which has at least two isocyanate groups, or a mixture thereof, in the melt, with reduction of the molar mass of the thermoplastic polyurethane and with formation of a thermoplastic polyurethane having an excess of isocyanate end groups, B) introduction of at least one polylactide into the melt of the stage A) product, and reaction of the stage A) product with the polylactide at a temperature below 190° C., C) cooling of the resultant blend, where no polyols are used in stages A) to C).
    Type: Application
    Filed: June 15, 2011
    Publication date: December 15, 2011
    Applicant: BASF SE
    Inventors: Klaus HILMER, Kai Brüning, Hans-Gerhard FRITZ, Alina Corina ZGAVERDEA
  • Patent number: 8048958
    Abstract: An object of the present invention is to provide a golf ball comprising a core and a cover, wherein the cover is made from a cover composition containing, as a resin component, a thermoplastic polyurethane (A) and a polyisocyanate mixture (B) in which a polyisocyanate (b-1) having at least three isocyanate groups is dispersed in a thermoplastic resin (b-2) which does not substantially react with an isocyanate group; and wherein the cover composition has a slab hardness of more than 60 and not more than 75 in Shore D hardness, and the cover has the thickness of 2.5 mm or less.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: November 1, 2011
    Assignee: SRI Sports Limited
    Inventors: Tsutomu Hirau, Toshiyuki Tarao
  • Patent number: 8048970
    Abstract: Novel low viscosity oligomeric polyols and the use thereof in coating compositions are disclosed. The novel low viscosity oligomeric polyols may be prepared by reacting at least one melamine aldehyde resin and at least one of ?,?-diol, ?,?-diol, or mixture thereof. The reaction may occur in the presence of an acid catalyst. Coating compositions with a low VOC able to cure under ambient and forced dry conditions while providing good application and performance characteristics, such as an improved scratch resistance, are also disclosed.
    Type: Grant
    Filed: September 5, 2006
    Date of Patent: November 1, 2011
    Assignee: Akzo Nobel Coatings International B.V.
    Inventors: Alexander Leo Yahkind, Xueting Qiu, Dhruv Vrajlal Parekh
  • Publication number: 20110257273
    Abstract: A low-molecular-weight polyester resin which can elasticize a resin suitably and can be used for various purposes, various resins obtained by using the resin, and the purposes thereof. The polyester resin is obtained by polymerizing a monomer composition containing 10 to 90 weight % of a linear dicarboxylic acid and/or diol having at least 8 carbon atoms (I), 5 to 80 weight % of a branched dicarboxylic acid and/or diol having at least 4 carbon atoms (II-1) and/or 2 to 40 weight % of at least one polyfunctional monomer (II-2) selected from the group consisting of polyols, polycarboxylic acids and hydroxycarboxylic acids having 3 or more functional groups respectively and which has the number average molecular weight of 500 to 5000 and is amorphous.
    Type: Application
    Filed: April 11, 2011
    Publication date: October 20, 2011
    Applicant: NIPPON BEE CHEMICAL CO., LTD.
    Inventors: Naoya YABUUCHI, Hirofumi YAMASHITA, Koji MORITA, Yasunori MIWA
  • Patent number: 8034873
    Abstract: In-situ plasticized thermoplastic polyurethane (TPU) compositions are made by a process which involves reacting a polyol, glycol chain extender and a polyisocyanate where the reaction is conducted in the presence of a plasticizer. The reactants together with the plasticizer are added to a reaction extruder and reacted to form the in-situ plasticized TPU.
    Type: Grant
    Filed: December 5, 2006
    Date of Patent: October 11, 2011
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventor: Sridhar K. Siddhamalli
  • Publication number: 20110245366
    Abstract: The invention relates to a process for preparing polyester alcohols by catalytically reacting at least one at least difunctional carboxylic acid or a derivative thereof with at least one at least difunctional alcohol, which comprises performing at least part of the reaction in the presence of microwave radiation.
    Type: Application
    Filed: March 30, 2011
    Publication date: October 6, 2011
    Applicant: BASF SE
    Inventors: Lionel GEHRINGER, Faissal-Ali El-Toufaili, Ulrike Mahn, Christian Pilger
  • Publication number: 20110237758
    Abstract: The present invention provides a urethane-forming reaction catalyst which is useful for catalyzing a reaction between an isocyanate compound, in particular, an aliphatic isocyanate and a hydroxyl group-containing compound to form a urethane material, which does not affect the performance of the urethane material, and which can be easily removed from the resulting urethane material, and a method for producing a metal compound-free urethane material using the urethane-forming reaction catalyst. The catalyst of the present invention is a urethane-forming reaction catalyst for producing a urethane material by allowing a hydroxyl group-containing compound to react with an isocyanate compound, the catalyst being at least one solid acid catalyst selected from the group consisting of a (A) composite metal oxide in which a metal oxide (A-2) or a non-metal compound (A-3) is carried on a surface of a metal oxide carrier (A-1), (B) zeolite, and a (C) heteropoly acid.
    Type: Application
    Filed: September 16, 2009
    Publication date: September 29, 2011
    Applicant: DIC Corporation
    Inventors: Hironobu Oki, Yasuyuki Watanabe, Youichi Abe
  • Patent number: 8017232
    Abstract: Provided is a pressure-sensitive adhesive composition for a plasma display in which a moire phenomenon can be prevented without disposing an anti-glare film and the like in order to decrease a thickness of an optical filter in a plasma display, improve a productivity of the optical filter and reduce a cost thereof and an adhesive sheet prepared by forming the same. The pressure-sensitive adhesive composition used for an optical filter of a plasma display comprises (A) a (meth)acrylic ester base copolymer having a cross-linkable functional group in a molecule, (B) a cross-linking agent and (C) an organic fine particle in which a difference in a refractive index from that of the above (meth)acrylic ester base copolymer is 0.03 or more and which has an average particle diameter of 1 to 15 ?m and an adhesive sheet prepared by forming the same.
    Type: Grant
    Filed: March 25, 2009
    Date of Patent: September 13, 2011
    Assignee: Lintec Corporation
    Inventors: Kenichi Murayama, Satoru Shoshi
  • Patent number: 8017690
    Abstract: An object of the present invention is to provide a golf ball comprising a core consisting of a center and at least one intermediate layer covering the center, and a cover covering the core, wherein the cover is made from a cover composition containing, as a resin component, a thermoplastic polyurethane (A) and a polyisocyanate mixture (B) in which a urethane prepolymer (b-1) having at least two isocyanate groups is dispersed in a thermoplastic resin (b-2) which does not substantially react with an isocyanate group; and wherein the cover composition has a slab hardness of more than 60 and not more than 75 in Shore D hardness, and at least one piece or one layer of the intermediate layer is formed from a low hardness intermediate layer composition which has a slab hardness of 40 or less in Shore D hardness.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: September 13, 2011
    Assignee: SRI Sports Limited
    Inventors: Tsutomu Hirau, Toshiyuki Tarao
  • Patent number: 8008394
    Abstract: The invention is directed to coating compositions for direct coating of plastic substrates, comprising the following components: A) a hydroxy-functional binder component, comprising at least one branched hydroxy-functional polyester having a hydroxyl value of 50-300 mg KOH/g solid, a polydispersity of <2 and a number average molecular weight (Mn) of 300 to 4000, having at least three branches, and having at least one hydroxyl group on each of the at least three branches, B) a crosslinking component for the hydroxyfunctional binder component A), C) at least one adhesion promoting component and optionally, D) organic solvents, additives conventionally found in paints as well as pigments and/or fillers.
    Type: Grant
    Filed: July 13, 2005
    Date of Patent: August 30, 2011
    Assignee: E.I. du Pont de Nemours & Company
    Inventors: Wolfgang Stricker, Udo Hellmann, Yvonne Seulen, Rolf Lackmann
  • Publication number: 20110207895
    Abstract: A polyurethane adhesive which is useful in bonding porous and non-porous surfaces is provided. The adhesive is especially useful in bonding windshield glass into automotive frames under a variety of environmental conditions, particularly in after market windshield replacement applications. The polyurethane includes at least one urethane prepolymer which is based on at least one thermoplastic polyol. In one embodiment, the urethane prepolymer may be formed from one or more polyisocyanates, one or more polyetherpolyols and one or more thermoplastic polyesterpolyols, wherein the prepolymer has a free isocyanate content of from about 0.6 to about 3.5% by weight, based on the weight of the polyurethane. In another embodiment, a one-part adhesive composition is provided which includes an isocyanate-functional and thermoplastic polyurethane prepolymer having a free isocyanate content of from about 0.6 to about 3.
    Type: Application
    Filed: November 22, 2010
    Publication date: August 25, 2011
    Applicant: Sika Technology AG
    Inventors: Steven A. Rosenburg, Hong Yao, Thomas Bove, Adrian Van Maurik, Hans Peter Tschan, Norman Blank
  • Publication number: 20110200836
    Abstract: A gas-barrier material having a gas-barrier layer which comprises a polycarboxylic acid polymer, the gas-barrier layer having a chemical bond stemming from an isocyanate group formed in the surface thereof, and the content of nitrogen being at least not less than 1 atom % per the total amount of carbon, oxygen and nitrogen in the surface layer. The gas-barrier material comprising a polycarboxylic acid polymer which is a high hydrogen-bonding polymer exhibits excellent anti-blocking property without dependent upon the degree of crosslinking.
    Type: Application
    Filed: September 25, 2008
    Publication date: August 18, 2011
    Applicant: TOYO SEIKAN KAISHA, LTD.
    Inventors: Yusuke Obu, Kashiko Kawai
  • Publication number: 20110190413
    Abstract: A process for preparing polyesters by catalytically reacting at least one polyfunctional carboxylic acid or derivative of a polyfunctional carboxylic acid with at least one polyfunctional alcohol.
    Type: Application
    Filed: February 2, 2011
    Publication date: August 4, 2011
    Applicant: BASF SE
    Inventors: Lionel Gehringer, Elke Gütlich-Hauk, Horst Binder
  • Patent number: 7989556
    Abstract: An object of the present invention is to provide a modifier which improves moldability in melt molding, particularly, injection molding, extrusion molding, profile molding, direct blow molding, or calendar processing molding using a polyester resin and, furthermore, which can improve mechanical physical property while maintaining transparency, and a polyester molded article using the modifier. The present invention relates to a modifier for a polyester resin, comprising an amorphous polyester resin (I), and a reactive compound (II) containing two or more glycidyl groups and/or isocyanate groups per one molecule and having a weight average molecular weight of not less than 200 and not more than 500 thousands.
    Type: Grant
    Filed: December 1, 2004
    Date of Patent: August 2, 2011
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Kenji Shiga, Mitsuo Nishida
  • Patent number: 7968647
    Abstract: A method of synthesizing polyester toner resins comprises: polycondensing polycarboxylic acids, polyols and free fatty acids to form low molecular weight polyester resins with alkenyl group or hydroxyl group or a combination of both; wherein at least one of said polycarboxylic acids, said polyols or said free fatty acids derive from natural oils; crosslinking the polyester via alkenyl group with radical initiator and vinyl monomer or via hydroxyl group with diisocyanate to generate polyester of higher molecular weight and melting point; obtaining a first fraction with a molecular weight ranged between 3000 and 15000 and a second fraction with a molecular weight larger than 15000; and combining said first fraction with said second fraction to form said polyester toner resins.
    Type: Grant
    Filed: June 13, 2008
    Date of Patent: June 28, 2011
    Assignees: Universiti Malaya, Jadi Imaging Technologies SDN BHD
    Inventor: Seng Neon Gan
  • Patent number: 7968641
    Abstract: A polyurethane dispersion is prepared by reacting a hydroxy-functional sulfonated unsaturated alkyd with an isocyanate in the presence of one or more vinyl monomers to form a blend containing the vinyl monomers and a sulfonated polyurethane polymer containing ethylenic groups. The blend is dispersed in water and the vinyl monomers are reacted by free radical polymerization.
    Type: Grant
    Filed: February 24, 2009
    Date of Patent: June 28, 2011
    Assignee: Valspar Sourcing, Inc.
    Inventor: T. Howard Killilea
  • Patent number: 7968668
    Abstract: A novel macromer or mixture thereof is described herein, comprising benzoyl isocyanate terminal moieties and at least two residues of a water-soluble polymer having a molecular weight ranging from 80 to 10,000 adjacent to the carbonyl group of the benzoyl isocyanate moieties, thereby forming at least two ester linkages in the macromer or mixture thereof. A method for making a polyisocyanate macromer is also described herein.
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: June 28, 2011
    Assignee: Ethicon Inc.
    Inventors: Benjamin D. Fitz, Christopher M. Westergom
  • Patent number: 7902302
    Abstract: Hydroxy-functional polyester-polyurethane dispersions comprising a reaction product of: (a) at least one, at least difunctional polyol component; (b) at least one ionizable compound having at least one acid group and at least one functional group capable of reacting with isocyanate groups, the at least one functional group selected from the group consisting of mono-, di-, and trihydroxycarboxylic acids, hydroxysulfonic acids, aminosulfonic acids, and aminocarboxylic acids; (c) at least one acid anhydride; and (d) at least one, at least difunctional polyisocyanate component; methods for preparing such dispersions; compositions containing such dispersions; and uses thereof.
    Type: Grant
    Filed: May 16, 2008
    Date of Patent: March 8, 2011
    Assignee: Bayer MaterialScience AG
    Inventors: Harald Blum, Heino Müller
  • Publication number: 20110040004
    Abstract: Formulations comprising an isosorbide-modified unsaturated polyester comprising maleic acid, fumaric acid, itaconic acid or maleic anhydride and isosorbide and one or more low profile additives. The formulations exhibit better shrink control in molding compound formulations with standard low profile additives than their non-isosorbide-modified analogues. These isosorbide-modified unsaturated polyester resins may be applied in molding compounds like sheet molding compounds or bulk molding compounds and may be components of fiber reinforced composites or other composite materials.
    Type: Application
    Filed: August 12, 2009
    Publication date: February 17, 2011
    Inventors: Dejan D. Andjelkovic, Darcy A. Culkin, Roman Loza, Micheal J. Sumner, Timothy A. Tuffs, Dennis H. Fisher
  • Publication number: 20110021721
    Abstract: The present invention provides a polyurethane elastomer composition for electrophotographic printing, including: a polyester polyol (A) obtained by polycondensing a polyvalent carboxylic acid (A-1) containing sebacic acid as a main component and a polyhydric alcohol (A-2) selected from (I) a linear glycol having 2 to 4 carbon atoms, (II) a linear glycol having 2 to 4 carbon atoms and a glycol having 2 to 4 carbon atoms with an alkyl side chain and (III) a linear glycol having 2 to 4 carbon atoms and 1,6-hexaneglycol; a polyisocyanate compound (B); and a mixture (C) of a short-chain diol and a short-chain triol. The polyurethane elastomer composition for electrophotographic printing has reduced temperature dependency, improved long-term durability and satisfactory mechanical strength. An electrophotographic printing member is also provided.
    Type: Application
    Filed: February 18, 2009
    Publication date: January 27, 2011
    Inventor: Masaya Masumoto
  • Publication number: 20110021720
    Abstract: A method of synthesizing polyester toner resins comprises: polycondensing polycarboxylic acids, polyols and free fatty acids to form low molecular weight polyester resins with alkenyl group or hydroxyl group or a combination of both; wherein at least one of said polycarboxylic acids, said polyols or said free fatty acids derive from natural oils; crosslinking the polyester via alkenyl group with radical initiator and vinyl monomer or via hydroxyl group with diisocyanate to generate polyester of higher molecular weight and melting point; obtaining a first fraction with a molecular weight ranged between 3000 and 15000 and a second fraction with a molecular weight larger than 15000; and combining said first fraction with said second fraction to form said polyester toner resins.
    Type: Application
    Filed: June 13, 2008
    Publication date: January 27, 2011
    Applicants: UNIVERSITI MALAYA, JADI IMAGING TECHNOLOGIES SDN BHD
    Inventor: Seng Neon Gan
  • Patent number: 7872078
    Abstract: The present invention is directed to curable film-forming compositions comprising: (a) a polymeric binder comprising a polyester having hydroxyl functional groups; and (b) a curing agent comprising a polyisocyanate having at least three isocyanate functional groups. In certain embodiments, after application to a substrate as a coating and after curing, the compositions demonstrate a Fisher microhardness of at least 120 at ambient temperatures of 15 to 25° C. and a softening point greater than or equal to 35° C. Additionally, in certain embodiments, after application to a substrate as a coating and after curing, the compositions demonstrate a 20° gloss recovery of at least 75% when subjected to the DRY ABRASION TEST METHOD.
    Type: Grant
    Filed: August 28, 2007
    Date of Patent: January 18, 2011
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Lyle L. Foringer, Constantine A. Kondos, Richard J. Sadvary, Kurt G. Olson, Dennis A. Simpson
  • Patent number: 7842756
    Abstract: A copolymer and a process of making the copolymer are disclosed. The copolymer is produced from reacting a glycidyl ester and/or ether with a polyol comprising a functionality of at least 2 wherein at least 50% by weight of the copolymer comprises a minimum of 3n+X repeating units, wherein n is a monomer unit and X is a monomer unit and/or other reactant. The copolymer may also include less than 50% of the polymeric units having the same molecular weight. The present invention is further directed to processes for preparing the copolymer and to coating compositions employing the copolymer.
    Type: Grant
    Filed: March 17, 2008
    Date of Patent: November 30, 2010
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Jonathan T. Martz, Erick B. Iezzi
  • Patent number: 7834102
    Abstract: The invention is an composition comprising a) one or more isocyanate functional polyether based prepolymers; b) one or more isocyanate functional polyester prepolymers wherein the one or more polyesters used to prepare the prepolymers having melting points of from about 45 to about 59° C.; c) one or more polyisocyanates having a nominal functionality of about 3 or greater; d) one or more nonconductive carbon blacks; e) one or more catalysts for the reaction of isocyanates moieties with hydroxyl groups. In a preferred embodiment the composition of the invention further comprises one or more isocyanate functional polyester prepolymers wherein the one or more polyesters used to prepare the prepolymers having melting points of about 60 to about 90° C.
    Type: Grant
    Filed: August 25, 2006
    Date of Patent: November 16, 2010
    Assignee: Dow Global Technologies Inc.
    Inventors: Lirong Zhou, Daniel P. Heberer
  • Patent number: 7829637
    Abstract: A molding composition is provided that includes a thermoset cross-linkable polymeric resin, a fibrous filler and a thickener system. The thickener system includes an amine and an isocyanate that are reactive to form a polyurea. The polyurea is operative to thicken the molding composition formulation prior to polymeric resin thermoset with superior properties relative to conventional thickener systems. A molded article produced from a cross-linked thermoset polymeric resin containing fibrous filler and a polyurea present from 1 to 5 total weight percent of the article either forms an interpenetrating network between the resin and the polyurea or the resin and polyurea crosslink upon resin thermoset to further strengthen the resulting article. An alkali earth oxide or hydroxide simultaneously thickens through interaction with carboxylate functionality of the cross-linkable resin to provide a superior viscosity build and humidity tolerance.
    Type: Grant
    Filed: September 16, 2009
    Date of Patent: November 9, 2010
    Assignee: Continental Structural Plastics
    Inventors: Probir K. Guha, Michael J. Siwajek, Brian A. Beach
  • Patent number: 7772333
    Abstract: Film-forming materials include resins and/or crosslinkers having a —Si(OR)3 group. Film-forming resins can include epoxy, acrylic, polyurethane, polycarbonate, polysiloxane, polyvinyl, polyether, aminoplast, and polyester resins. A process to produce a film-forming resin includes reacting various polymers to incorporate a pendent group comprising a —Si(OR)3 group. Film-forming resins can be used in methods of producing coating compositions. Coating compositions can be used to coat a substrate, such as a metal substrate, by electrodeposition. Applied coatings containing the film-forming resins can be cured to form crosslinked films on substrates.
    Type: Grant
    Filed: March 13, 2007
    Date of Patent: August 10, 2010
    Assignee: BASF Coatings GmbH
    Inventors: Sergio Gonzalez, Timothy S. December
  • Patent number: 7763683
    Abstract: The present invention relates to polyester polyols with low functionality and a process for their production, to prepolymers prepared from these polyester polyols and a process for their production, and to polyurethanes prepared from these polyester polyols and/or from these prepolymers, and to processes for their production. These polyester polyols are produced in a two-step process. In the second step of this two-step process, one or more cyclic ester monomers is reacted with one or more polyester polyols at low temperatures.
    Type: Grant
    Filed: October 2, 2007
    Date of Patent: July 27, 2010
    Assignee: Bayer MaterialScience AG
    Inventors: Hartmut Nefzger, Gerhard Klein, Manfred Schmidt, Jens Krause, James-Michael Barnes, Erika Bauer
  • Patent number: 7728075
    Abstract: The invention relates to a high gloss car wash-resistant coating composition comprising a hydroxyl-functional binder and a cross-linker reactive with the hydroxyl groups of the binder and a method to prepare such a car wash-resistant coating. The invention further relates to the use of said coating composition, as a pigment-free top coat or a clear coat, in the finishing and refinishing of articles, for example motorcycles, cars, trains, buses, trucks, and aeroplanes. The coating composition after curing forms a coating having an initial gloss of at least 81 GU and a loss of gloss (LoG) of less than 0.18, the loss of gloss being determined by the formula (I): LoG=A+B·E?·(X)?1·10(C·?Tg)+D·(E?)?0.5; wherein A=0.0132, B=1.0197, C=0.0113, and D=0.0566, E? reflects the tensile storage modulus at 40° C. in GPa, ?Tg the width of the glass transition temperature in ° C., and X the cross-link density parameter in kPA/K all three parameters determined in a DMTA test at 11 Hz and a heating rate of 5° C./min.
    Type: Grant
    Filed: April 23, 2004
    Date of Patent: June 1, 2010
    Assignee: Nuplex Resins B.V.
    Inventors: Johannes Wilhemus Maria Schellekens, Martin Bosma, Freddy Gerhard Hendrikus Van Wijk, Paul Marie Vandevoorde
  • Publication number: 20100087273
    Abstract: A dual sensory golf ball having two identification layers comprising a first exterior surface identification layer having at least one first identifier and a second clear coat identification layer comprising a polymer and a second identifier wherein the second identifier is an additive comprising an odorant and wherein the second clear coat identification layer is substantially transparent to allow recognition of the first identifier.
    Type: Application
    Filed: March 10, 2008
    Publication date: April 8, 2010
    Inventor: Kyle Matthews
  • Patent number: 7682439
    Abstract: The invention relates to a dispersing agent comprising: the reaction product of A one or more polyisocyanates having an average functionality of from 2.0 to 5, with B a mixture from B1 monohydroxyl compounds, and B2 monohydroxy-, monocarboxylic acid compounds to form an intermediate, followed by reacting the intermediate with C an unsaturated monohydroxy functional anchoring group.
    Type: Grant
    Filed: February 15, 2007
    Date of Patent: March 23, 2010
    Assignee: Ciba Corporation Tarrytown
    Inventors: Arend Noordam, Lothar Alexander Engelbrecht, Marcelles Van Der Sluis, Wendy Gezina Hof
  • Publication number: 20100056702
    Abstract: Powder mixtures for powder coatings comprising: (A) a non-blocked, micronized, cycloaliphatic diisocyanate-derived polyisocyanate which is solid below 40° C. and liquid above 120° C. and has an average particle size d50 of below 10 ?m; (B) a pulverulent binder component having an average particle size d50 of below 100 ?m, comprising 25 to 75 wt. % of at least one amorphous polyol (B1) and 75 to 25 wt. % of at least one crystalline or semicrystalline polyol (B2); and, (C) optionally, one or more powder coating auxiliary substances and additives; processes for preparing such mixtures; powder coating obtained therefrom and substrates coated therewith.
    Type: Application
    Filed: August 25, 2009
    Publication date: March 4, 2010
    Applicant: Bayer MaterialScience AG
    Inventors: Michael Grahl, Hans-Josef Laas, Jörg Büchner
  • Patent number: 7666945
    Abstract: The present invention is directed to a non-gelled, curable composition including at least one compound having a plurality of imide functional groups. The compound in particular contains a reaction product of at least one secondary monoamine and at least one maleimide, and is suitable for use in coatings and castings.
    Type: Grant
    Filed: September 27, 2007
    Date of Patent: February 23, 2010
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Kevin C. Olson, Gregory J. McCollum, Linda K. Anderson
  • Patent number: 7652121
    Abstract: The present invention is directed to a rheology control agent for coating compositions. The rheology control agent includes a compound having the Formula (II) including isomers or mixtures of isomers thereof: wherein R, R9, R10, m and n are described in the specification. The coating compositions containing the rheology control agent have improved rheology control on application and are useful for OEM, refinishing or repainting the exterior of automobile and truck bodies and parts thereof.
    Type: Grant
    Filed: January 12, 2006
    Date of Patent: January 26, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Christian Peter Lenges, Yanhui Niu, Yu-Ling Hsiao, Jiang Ding, Robert John Barsotti, Renee J. Kelly, Robert James Butera, Young H. Kim
  • Patent number: 7649050
    Abstract: A two package type clear coating composition which can form cured coating film excelling in all aspects of scratch resistance, acid resistance, stain resistance and finished appearance such as coated surface smoothness, comprising a hydroxyl-containing acrylic resin (A) having a hydroxyl value of 100-200 mgKOH/g and a number-average molecular weight of 5,000-10,000, which is obtained by copolymerization of a monomeric mixture comprising an aromatic vinyl monomer and a monomer having cyclohexyl ring; a trifunctional HMDI isocyanurate compound (B); and a polyester polyol (C) having a hydroxyl value of 250-350 mgKOH/g and a number-average molecular weight of 350-550, which is obtained by esterification reaction of C3-6 diol with dicarboxylic acid having cyclohexyl ring.
    Type: Grant
    Filed: September 26, 2007
    Date of Patent: January 19, 2010
    Assignees: Nissan Motor Co., Ltd., Kansai Paint Co., Ltd.
    Inventors: Tatsuya Ishihara, Hiroshi Yokoyama, Tomoyoshi Saitoh, Tatsuya Suzuki, Goro Saito, Toshiyuki Hanaoka, Yoshiyuki Yukawa
  • Patent number: 7638580
    Abstract: The object of the present invention is to provide a golf ball having a paint film which is obtained from an environment-friendly aqueous paint and is excellent in the impact-resistance and the wear-resistance. The present invention provides a golf ball having a paint film on a surface of a golf ball body, wherein the paint film is obtained by curing a paint composition comprising an aqueous polyol having a carboxyl group, an aqueous polycarbodiimide, and an aqueous polyisocyanate.
    Type: Grant
    Filed: January 31, 2006
    Date of Patent: December 29, 2009
    Assignee: SRI Sports Limited
    Inventors: Takashi Sasaki, Kazuhiko Isogawa
  • Patent number: 7632570
    Abstract: Aqueous resinous binders comprising graft copolymers, water-dilutable urethane polyols, epoxy-phosphorus acid reaction products, and an aqueous dispersion comprising the reaction product of trimellitic anhydride and a polyol, wherein the molar ratio of trimellitic anhydride to the polyol in the reaction product ranges from 1:2 to 1:4, and wherein the reaction product is further reacted with an anhydride to form another reaction product are disclosed. The binders are useful in primer formulations for automotive applications.
    Type: Grant
    Filed: July 5, 2007
    Date of Patent: December 15, 2009
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Paul H. Lamers, Christopher A. Verardi, Michele L. Meli, Carolyn A. K. Novak