Wherein One Of Said Silicon Materials Contains Si-h Bond Patents (Class 525/478)
-
Patent number: 8937136Abstract: A curable composition and use thereof are provided. The exemplary curable composition can show excellent processability and workability. Also, the curable composition can have a high refractive index before or after curing. The composition has low moisture permeability before or after curing and shows excellent crack resistance, thermal shock resistance, adhesive property and hardness. In addition, the composition does not cause color change such as whitening under a high-temperature or high-humidity condition, and does not exhibit stickiness on a surface thereof. The curable composition may be used as an adhesive material or as an encapsulation material for semiconductor devices such as an LED, a CCD, a photo coupler, or a photovoltaic cell.Type: GrantFiled: July 5, 2013Date of Patent: January 20, 2015Assignee: LG Chem, Ltd.Inventors: Bum Gyu Choi, Min Jin Ko, Myung Sun Moon, Jae Ho Jung, Dae Ho Kang, Min Kyoun Kim, Byung Kyu Cho
-
Patent number: 8937131Abstract: Provided are a curable composition and its use. The curable composition can exhibit excellent processability and workability. The curable composition exhibits excellent light extraction efficiency, hardness, thermal and shock resistance, moisture resistance, gas permeability and adhesiveness, after curing. In addition, the curable composition can provide a cured product that exhibits long-lasting durability and reliability even under harsh conditions, and that does not cause whitening and surface stickiness.Type: GrantFiled: July 29, 2013Date of Patent: January 20, 2015Assignee: LG Chem, Ltd.Inventors: Min Jin Ko, Jae Ho Jung, Bum Gyu Choi, Min A Yu
-
Patent number: 8933177Abstract: To provide a release modifier which provides a heavy release force to a cured release layer of silicone coating composition. The release modifier comprises an organopolysiloxane resin-organopolysiloxane condensation reaction product that is obtained by the condensation reaction of (a1) 100 weight parts of MQ-type organopolysiloxane resin in which the molar ratio of the M unit to the Q unit is 0.6 to 1.0 and the content of the hydroxyl group or alkoxy group is 0.3 to 2.0 weight % with (a2) 20 to 150 weight parts of chain-form diorganopolysiloxane that has an average degree of polymerization of 100 to 1000 and at least one hydroxyl group or alkoxy group; this organopolysiloxane resin-organopolysiloxane condensation reaction product preferably has a prescribed hydroxyl group content.Type: GrantFiled: July 9, 2009Date of Patent: January 13, 2015Assignee: Dow Corning Toray Company, Ltd.Inventors: Seiji Hori, Takateru Yamada, Chung Mien Kuo
-
Patent number: 8921496Abstract: A curable composition and use thereof are provided. The exemplary curable composition can show excellent processability and workability. Also, the curable composition can have a high refractive index before or after curing. The composition has low moisture permeability before or after curing and shows excellent crack resistance, thermal shock resistance, adhesive property and hardness. In addition, the composition does not cause color change such as whitening, under a high-temperature or high-humidity condition, and does not exhibit stickiness on a surface thereof. The curable composition may be used as an adhesive material or as an encapsulation material for semiconductor devices such as an LED, a CCD, a photo coupler, or a photovoltaic cell.Type: GrantFiled: July 5, 2013Date of Patent: December 30, 2014Assignee: LG Chem, Ltd.Inventors: Bum Gyu Choi, Min Jin Ko, Myung Sun Moon, Jae Ho Jung, Dae Ho Kang, Min Kyoun Kim, Byung Kyu Cho
-
Patent number: 8916654Abstract: A curable composition and the use thereof are provided. The exemplary curable composition can show excellent processability and workability. Also, the curable composition can have a high refractive index before or after curing. The composition has low moisture permeability before or after curing and shows excellent crack resistance, thermal shock resistance, adhesive property and hardness. In addition, the composition does not cause color change such as whitening under a high-temperature or high-humidity condition, and does not exhibit stickiness on a surface thereof. The curable composition may be used as an adhesive material or as an encapsulation material for semiconductor devices such as an LED, a CCD, a photo coupler, or a photovoltaic cell.Type: GrantFiled: July 5, 2013Date of Patent: December 23, 2014Assignee: LG Chem, Ltd.Inventors: Bum Gyu Choi, Min Jin Ko, Myung Sun Moon, Jae Ho Jung, Dae Ho Kang, Min Kyoun Kim, Byung Kyu Cho
-
Patent number: 8916653Abstract: A curable composition and use thereof are provided. The exemplary curable composition can show excellent processability and workability. Also, the curable composition can have a high refractive index before or after curing. The composition has low moisture permeability before or after curing and shows excellent crack resistance, thermal shock resistance, adhesive property and hardness. In addition, the composition does not cause color change such as whitening under a high-temperature or high-humidity condition, and does not exhibit stickiness on a surface thereof. The curable composition may be used as an adhesive material or as an encapsulation material for semiconductor devices such as an LED, a CCD, a photo coupler, or a photovoltaic cell.Type: GrantFiled: July 5, 2013Date of Patent: December 23, 2014Assignee: LG Chem, Ltd.Inventors: Bum Gyu Choi, Min Jin Ko, Myung Sun Moon, Jae Ho Jung, Dae Ho Kang, Min Kyoun Kim, Byung Kyu Cho
-
Publication number: 20140350194Abstract: Provided are a curable composition and its use. The curable composition may provide a cured product having excellent processability, workability and adhesive property, and having no whitening and surface stickiness. The curable composition has excellent thermal resistance and crack resistance at high temperature, and excellent gas barrier ability, and thus allows a semiconductor device to stably maintain performance at high temperature for a long time when applied to the device.Type: ApplicationFiled: August 11, 2014Publication date: November 27, 2014Inventors: Min Jin KO, Jae Ho JUNG, Bum Gyu CHOI, Dae Ho KANG, Min A. YU, Min Kyoun KIM, Byung Kyu CHO
-
Publication number: 20140346556Abstract: Provided are a curable composition and its use. The curable composition may provide a cured product having excellent processability, workability, and adhesive property, and having no whitening and surface stickiness. The curable composition has excellent thermal resistance and crack resistance, and low gas permeability, and thus provides a device having excellent initial performance when being applied to a semiconductor device and maintaining stable performance when being used at a high temperature for a long time.Type: ApplicationFiled: August 12, 2014Publication date: November 27, 2014Inventors: Min Jin Ko, Kyung Mi Kim, Young Ju Park
-
Publication number: 20140350195Abstract: Provided are a curable composition and its use. The curable composition may provide a cured product having excellent processability and workability, no whitening and surface stickiness, and an excellent adhesive property. Since the curable composition has excellent thermal resistance, gas barrier-ability, and crack resistance, even when a semiconductor device to which the composition is applied is used at a high temperature for a long time, performance of the device may be stably maintained.Type: ApplicationFiled: August 13, 2014Publication date: November 27, 2014Inventors: Min Jin KO, Kyung Mi KIM, Young Ju PARK, Bum Gyu CHOI, Dae Ho KANG, Byung Kyu CHO, You Na YANG
-
Publication number: 20140346550Abstract: Provided are a curable composition and its use. The curable composition may provide a cured product having excellent processability, workability, and adhesive property, and having no whitening and surface stickiness. The curable composition has excellent thermal resistance at a high temperature, gas barrierability, and crack resistance, and thus, when applied to a semiconductor device, may stably maintain performance of the device at a high temperature for a long time.Type: ApplicationFiled: August 11, 2014Publication date: November 27, 2014Inventors: Min Jin KO, Kyung Mi KIM, Young Ju PARK, Jae Ho JUNG, Min A YU, Min Kyoun KIM
-
Patent number: 8895678Abstract: A cross-linkable silicone composition comprising at least the following components: (A) an organopolysiloxane represented by an average unit formula and containing phenyl and alkenyl groups; (B) an organopolysiloxane represented by a general formula and containing phenyl and alkenyl groups; (C) an organopolysiloxane having in one molecule at least one phenyl group and two silicon-bonded hydrogen atoms; and (D) a hydrosilylation catalyst, can be cross-linked by a hydrosilylation reaction and forms a solid body which has high hardness at room temperature and becomes significantly soft or a liquefied at high temperature.Type: GrantFiled: June 7, 2012Date of Patent: November 25, 2014Assignee: Dow Corning Toray Co., Ltd.Inventor: Makoto Yoshitake
-
Patent number: 8895662Abstract: A curable composition comprises the following: (A) a branched polymer having an average unit formula (I?): [(R?)2SiO2/2]a?[(CH2?CH)(R?)2SiO1/2]b?[R?SiO3/2]c?[O1/2Si(R?)2(CH2CH2)(R?)2SiO1/2]e?; (B) a branched organopolysiloxane having at least one silicon-bonded alkenyl group and having a siloxane unit of formula R4SiO3/2; (C) an organopolysiloxane having an average unit formula (II) being capped with H: (R52SiO2/2)f(R63SiO1/2)g(R7SiO3/2)h(SiO4/2)i(CH2CH2)j; and (D) a catalyst, wherein R?, R4 to R7, a? to c?, e? and f to j are as defined in the specification.Type: GrantFiled: April 30, 2014Date of Patent: November 25, 2014Assignee: Eternal Chemical Co., Ltd.Inventors: Chih Chiang Yang, Hsin Hung Chen, Wan Hsi Yang, Kwei Wen Liang
-
Publication number: 20140332987Abstract: Provided is a curable resin composition capable of forming a cured product which has excellent heat resistance, transparency, and flexibility and particularly excels in reflow resistance and barrier properties to a corrosive gas. The curable resin composition includes a ladder-type polyorganosilsesquioxane and an isocyanurate compound such as a triglycidyl isocyanurate compound, a monoallyl diglycidyl isocyanurate compound, a diallyl monoglycidyl isocyanurate compound, or a triallyl isocyanurate compound.Type: ApplicationFiled: December 19, 2012Publication date: November 13, 2014Inventors: Shigeaki Kamuro, Yasunobu Nakagawa
-
Patent number: 8877860Abstract: A two-part curable liquid silicone rubber composition comprises a first liquid composition and a second liquid composition. The first and second liquid compositions are stored separately and yield, upon mixing, a silicone rubber forming composition. The silicone rubber composition comprises: (A) an alkenyl group-containing organopolysiloxane comprising (A-1) an organopolysiloxane having only a silicon-bonded alkenyl group at each molecular terminal and (A-2) an organopolysiloxane having from 1 to 4 silicon-bonded alkenyl groups in side molecular chains and containing not greater than 2.0 wt. % of alkenyl groups; (B) a calcium carbonate powder; (C) a hydrosilylation reaction catalyst; and (D) an organohydrogenpolysiloxane having silicon-bonded hydrogen atoms.Type: GrantFiled: March 28, 2012Date of Patent: November 4, 2014Assignee: Dow Corning Toray Co., Ltd.Inventors: Tomoko Tasaki, Yuichi Tsuji
-
Patent number: 8877877Abstract: A polyorganosiloxane composition, an encapsulation material, and an electronic device, the polyorganosiloxane composition including a linear first polyorganosiloxane resin including a moiety represented by the following Chemical Formula 1 and a moiety represented by the following Chemical Formula 2, the first polyorganosiloxane resin including double bonds at both terminal ends thereof, and a second polyorganosiloxane resin having a three dimensional network structure,Type: GrantFiled: August 11, 2011Date of Patent: November 4, 2014Assignee: Cheil Industries, Inc.Inventors: Sang-Ran Koh, June-Ho Shin, Woo-Han Kim, Sung-Hwan Cha, Hyun-Jung Ahn
-
Patent number: 8859693Abstract: A curable silicone composition comprises (A) (A-1) a dialkylpolysiloxane that has at least two alkenyl groups in each molecule and a viscosity of at least 1,000 mPa·s to not more than 50,000 mPa·s and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO4/2 unit, R12R2SiO1/2 unit, and R13SiO1/2 unit wherein R1 is alkyl and R2 is alkenyl and that contains the alkenyl group in the range from at least 0.5 mass % to less than 3.5 mass %; (B) an organopolysiloxane that has at least three silicon-bonded hydrogen atoms; and (C) a hydrosilylation reaction catalyst. The curable composition provides a highly transparent cured silicone material that has a hardness in the range from at least 30 to not more than 80, a parallel light transmittance at 25° C. of at least 90%, and a parallel light transmittance at 200° C. that is at least 99% of the parallel light transmittance at 25° C.Type: GrantFiled: January 29, 2010Date of Patent: October 14, 2014Assignee: Dow Corning Toray Co., Ltd.Inventors: Chiichiro Hasegawa, Makoto Yoshitake, Hiroshi Akitomo
-
Patent number: 8859635Abstract: Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it.Type: GrantFiled: June 27, 2011Date of Patent: October 14, 2014Assignee: Bluestar Silicones France SASInventors: John White, Michel Feder, Alain Pouchelon, Yassine Maadadi, Lucile Gambut-Garel
-
Patent number: 8853332Abstract: A curable silicone composition comprises (A) (A-1) an alkenyl-containing dialkylpolysiloxane and a viscosity of at least 1,000 mPa·s to not more than 20,000 mPa·s and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO4/2 unit, R12R2SiO1/2 unit, and R13SiO1/2 unit wherein R1 is alkyl and R2 is alkenyl, that contains from 2.5 to 5.0 mass % alkenyl group, and that has a ratio for the total number of moles of R12R2SiO1/2 and R13SiO1/2 units to 1 mole of the SiO4/2 unit in the range from 0.70 to 1.10; (B) an organopolysiloxane that contains at least 0.9 mass % silicon-bonded hydrogen; and (C) a hydrosilylation reaction catalyst. The curable composition provides a bending-tolerant and highly transparent cured silicone material that has a hardness in the range from 80 to 95, and a parallel light transmittance at 200° C. of a value that is at least 99% of the parallel light transmittance at 25° C.Type: GrantFiled: January 29, 2010Date of Patent: October 7, 2014Assignee: Dow Corning Toray Co., Ltd.Inventors: Chiichiro Hasegawa, Makoto Yoshitake, Hiroshi Akitomo
-
Patent number: 8847414Abstract: A resin for an encapsulation material includes a first polysiloxane including hydrogen bound to silicon (Si—H) at its terminal end, and a second polysiloxane including an alkenyl group bound to silicon (Si—Vi) at its terminal end, wherein a ratio (Si—H/Si—Vi) of hydrogen bound to silicon (Si—H) in the first polysiloxane to the alkenyl group bound to silicon (Si—Vi) in the second polysiloxane is about 1 to about 1.Type: GrantFiled: December 29, 2011Date of Patent: September 30, 2014Assignee: Cheil Industries, Inc.Inventors: Sung-Hwan Cha, Sang-Ran Koh, Yong Kook Kim, Woo-Han Kim, Ha Neul Kim, Chi Won An
-
Patent number: 8846828Abstract: A curable organopolysiloxane composition comprising: (A) a branched-chain organopolysiloxane that contains in one molecule at least three alkenyl groups and at least 30 mole % of all silicon-bonded organic groups in the form of aryl groups; (B) a linear-chain organopolysiloxane that contains aryl groups and has both molecular terminals capped with diorganohydrogensiloxy groups; (C) a branched-chain organopolysiloxane that contains in one molecule at least three diorganohydrogensiloxy groups and at least 15 mole % of all silicon-bonded organic groups in the form of aryl groups; and (D) a hydrosilylation catalyst. The composition is capable of forming a cured body that has a high index of refraction and strong adhesion to substrates.Type: GrantFiled: June 11, 2009Date of Patent: September 30, 2014Assignee: Dow Corning Toray Co. Ltd.Inventors: Takashi Sagawa, Makoto Yoshitake
-
Publication number: 20140288235Abstract: A curable silicone composition comprising: (A) an organopolysiloxane that has at least a straight-chain polysiloxane block represented by the general formula: —R1R2SiO)m—, wherein R1 is a C1-6 alkyl group or the phenyl group, R2 is a C2-10 alkenyl group, and m is a positive number from 5 to 50; (B) an organopolysiloxane that has at least a straight-chain polysiloxane block represented by the general formula: —(R3HSiO)n—, wherein R3 is a C1-6 alkyl group or the phenyl group and n is a positive number from 10 to 100; and (C) a hydrosilylation reaction catalyst, cures to form a cured product that has a small thermal expansion coefficient.Type: ApplicationFiled: September 27, 2012Publication date: September 25, 2014Inventors: Kazuo Hirai, Makoto Yoshitake
-
Patent number: 8828551Abstract: The general field of the invention is that of airbags. The invention relates to a process for improving the tear strength and the combing strength of coated fabrics intended for uses in the field of inflatable bags, using a silicone composition comprising an additive consisting of a polyorganosiloxane resin (V) and a calcium carbonate. After coating the composition onto the fabric supports and curing, the coated supports not only have optimum adhesion and crease resistance properties, but also have good properties in terms of combing strength and tear strength.Type: GrantFiled: July 25, 2012Date of Patent: September 9, 2014Assignee: Bluestar Silicones France SASInventors: Laurent Dumont, Alain Pouchelon
-
Patent number: 8816022Abstract: The present invention provides rubber sealing members having an exterior surface adapted to sealingly engage an inner surface of a chamber of a medical device, the exterior surface of the sealing member having a coating thereon prepared from a curable composition including: (a) a first organopolysiloxane having at least two alkenyl groups; and (b) a second organopolysiloxane having at least two pendant hydrogen groups, the second organopolysiloxane being different from the first organopolysiloxane, wherein at least one of the first organopolysiloxane, the second organopolysiloxane or an optional third organopolysiloxane of the curable composition comprises a fluoro group.Type: GrantFiled: October 25, 2013Date of Patent: August 26, 2014Assignee: Becton, Dickinson and CompanyInventors: Xia Zhao, Yongming Liu
-
Patent number: 8815400Abstract: An epoxy resin composition including (A) an epoxy resin that is solid at room temperature and has a softening point of 40° C. to 110° C., (B) a curing agent that is solid at room temperature and has a softening point of not less than 40° C. to 110° C., (C) a curing accelerator, (D) an inorganic filler having a mass-average particle size of 0.05 to 5 ?m, (E) a diluent, and (F) a specific dimethyl silicone, in which at least one of the component (A) and the component (B) is silicone-modified is provided. The composition can be used in a silicon chip die attach method or to produce a semiconductor device containing a silicon chip, a substrate and a cured product of the composition, in which the silicon chip is bonded to the substrate via the cured product.Type: GrantFiled: January 17, 2012Date of Patent: August 26, 2014Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Tatsuya Kanamaru, Shinsuke Yamaguchi
-
Publication number: 20140231861Abstract: A curable composition comprises the following: (A) a branched polymer having an average unit formula (I?): [(R?)2SiO2/2]a?[(CH2?CH)(R?)2SiO1/2]b?[R?SiO3/2]c?[O1/2Si(R?)2(CH2CH2)(R?)2SiO1/2]e?; (B) a branched organopolysiloxane having at least one silicon-bonded alkenyl group and having a siloxane unit of formula R4SiO3/2; (C) an organopolysiloxane having an average unit formula (II) being capped with H: (R52SiO2/2)f(R63SiO1/2)g(R7SiO3/2)h(SiO4/2)i(CH2CH2)j; and (D) a catalyst, wherein R?, R4 to R7, a? to c?, e? and f to j are as defined in the specification.Type: ApplicationFiled: April 30, 2014Publication date: August 21, 2014Applicant: ETERNAL CHEMICAL CO., LTD.Inventors: Chih Chiang Yang, Hsin Hung Chen, Wan Hsi Yang, Kwei Wen Liang
-
Publication number: 20140231862Abstract: A curable composition comprises the following: (A) a polymer having at least two silicon-bonded alkenyl groups and having an average unit formula (I?): (R12SiO2/2)a1(R23SiO1/2)b1(CH2CH2)e1; (B) a branched organopolysiloxane having at least one silicon-bonded alkenyl group and having a siloxane unit of formula R4SiO3/2; (C) an organopolysiloxane having an average unit formula (II) being capped with H: (R52SiO2/2)f(R63SiO1/2)g(R7SiO3/2)h(SiO4/2)i(CH2CH2)j; and (D) a catalyst, wherein R1, R2 and R4 to R7 and a1, b1, e1 and f to j are as defined in the specification.Type: ApplicationFiled: April 30, 2014Publication date: August 21, 2014Applicant: ETERNAL CHEMICAL CO., LTD.Inventors: Chih Chiang Yang, Kwei Wen Liang, Hsin Hung Chen, Wan Hsi YANG
-
Patent number: 8810046Abstract: A silicone resin composition contains a cage octasilsesquioxane having a group represented by the following formula (1), an alkenyl group-containing polysiloxane containing an alkenyl group having a number of moles larger than that of a hydrosilyl group in the cage octasilsesquioxane, a hydrosilylation catalyst, and an organohydrogenpolysiloxane. (where, in formula, R1 represents a monovalent hydrocarbon group selected from a saturated hydrocarbon group and an aromatic hydrocarbon group. R2 represents hydrogen or a monovalent hydrocarbon group selected from a saturated hydrocarbon group and an aromatic hydrocarbon group. The molar ratio of the monovalent hydrocarbon group:hydrogen in R2 in the cage octasilsesquioxane as a whole is, as an average value, in the range of 6.5:1.5 to 5.5:2.5).Type: GrantFiled: October 17, 2012Date of Patent: August 19, 2014Assignee: Nitto Denko CorporationInventors: Haruka Ona, Hiroyuki Katayama
-
Patent number: 8809469Abstract: The present invention is a curable organopolysiloxane composition containing (A) a compound shown by the following average composition formula (1), wherein R1 represents an aliphatic unsaturated group, R2 represents a monovalent hydrocarbon group, R3 represents an aliphatic hydrocarbon group, Ar represents an aryl group, and “n” and “m” represent positive numbers which satisfy n?1, m?1, and n+m?10, (B) a hydrogen atom-containing organic silicon compound having at least two silicon atom-bonded hydrogen atoms per one molecule while not having an aliphatic unsaturated group, and (C) a hydrosilylation catalyst which contains a platinum group metal. Thereby, there can be provided a curable organopolysiloxane composition which can give a cured product having high transparency, high refractive index, and excellent thermal shock resistance; an optical device sealing material; and an optical device.Type: GrantFiled: January 18, 2013Date of Patent: August 19, 2014Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Ataru Kobayashi, Toshiyuki Ozai
-
Patent number: 8809127Abstract: Provided is a curable composition and its use. The curable composition may exhibit excellent processability and workability. The curable composition has excellent light extraction efficiency, crack resistance, hardness, thermal and shock resistance and an adhesive property after curing. The curable composition may provide a cured product exhibiting stable durability and reliability under severe conditions for a long time and having no whitening and surface stickiness.Type: GrantFiled: December 23, 2013Date of Patent: August 19, 2014Assignee: LG Chem, Ltd.Inventors: Min Jin Ko, Jae Ho Jung, Myung Sun Moon, Bum Gyu Choi, Dae Ho Kang, Min Kyoun Kim, Byung Kyu Cho
-
Patent number: 8796398Abstract: There are provided a composition for forming a superfine pattern and a method employing the same for forming a superfine pattern. The composition enables to simply produce a superfine pattern with high mass productivity. The composition comprises perhydropolysilazane (I), silicon-containing polymer (II) having a hydrocarbon group, and a solvent. The mixture of those polymers contains silicon-hydrogen bonds and silicon-hydrocarbon group bonds in such amounts that the number of the silicon-hydrocarbon group bonds is in a ratio of 1 to 44% based on the total number of the silicon-hydrogen bonds and the silicon-hydrocarbon group bonds. The composition is applied on a resist pattern to form a spacer formed of the composition on the side wall of the ridges in the pattern, and then the spacer or a resin layer disposed around the spacer is used as a mask to form a superfine pattern.Type: GrantFiled: December 27, 2010Date of Patent: August 5, 2014Assignee: AZ Electronic Materials USA Corp.Inventors: Munirathna Padmanaban, Jin Li, Toru Koike, Yusuke Takano, Kazunori Kurosawa
-
Patent number: 8791213Abstract: The invention provides a curable silicone resin composition comprising: (A) an organopolysiloxane containing an aromatic group having two or more alkenyl groups, and having a viscosity at 25° C. of 10 to 1,000,000 mPa·s, (B) an organopolysiloxane having a resin structure, comprising 10 to 80 mol % of a SiO4/2 unit, 1 to 80 mol % of a (R1)2SiO2/2 unit, and 1 to 60 mol % of a (R2)3SiO1/2 unit, and containing a SiOH group in a range of 0.1 to 5.0 mol %, (C) an organohydrogenpolysiloxane having two or more SiH group, and among whole substituents bonded to the silicon atom, 20 to 80 mol % is a phenyl group, and a SiO4/2 unit is less than 5 mol %, and (D) a platinum group metal catalyst, and the component (B) is contained in an amount of 20 to 80% by mass based on a sum of the component (A) and the component (B).Type: GrantFiled: July 1, 2013Date of Patent: July 29, 2014Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Tomoyuki Mizunashi, Tsutomu Kashiwagi, Kinya Kodama
-
Patent number: 8791221Abstract: Provided is a metallosiloxane compound (A) prepared by reacting a bifunctional silane compound (S1), a monofunctional silane compound (S2), a boron compound (M), and optionally H2O in a molar ratio of [the silane compound (S1)]:[the silane compound (S2)]:[the boron compound (M)]:[H2O] of n:m:k:a, where n, m, k, and a satisfy all conditions (i), (ii), and (iii), in which the metallosiloxane compound has at least one Si—H bond or C2-10 alkenyl group per molecule, and the conditions (i), (ii), and (iii) are expressed as follows: (i) n>0, m>0, k>0, a?0; (ii) m/n?0.5; and (iii) (n+m)/k?1.8.Type: GrantFiled: November 29, 2011Date of Patent: July 29, 2014Assignee: Daicel CorporationInventor: Tomoya Egawa
-
Patent number: 8779043Abstract: A silicone resin composition contains a first organopolysiloxane having, in one molecule, both at least two ethylenically unsaturated hydrocarbon groups and at least two silanol groups; a second organopolysiloxane having, in one molecule, at least two hydrosilyl groups without having an ethylenically unsaturated hydrocarbon group; a hydrosilylation catalyst; and a hydrosilylation retarder.Type: GrantFiled: October 11, 2012Date of Patent: July 15, 2014Assignee: Nitto Denko CorporationInventors: Hirokazu Matsuda, Ryuichi Kimura, Hiroyuki Katayama
-
Patent number: 8779074Abstract: A silicone emulsion composition is provided comprising organopolysiloxane, organohydrogenpolysiloxane, surfactant, and water. Two organopolysiloxanes of different type are blended, whereby a cured silicone coating is improved to be fully adherent to plastic film and lightly peelable from pressure-sensitive adhesive. By limiting the SiH content of organohydrogenpolysiloxane, the composition is improved in shelf stability. A specific surfactant is used to control the size of emulsion particles so as to improve wettability to plastic film.Type: GrantFiled: June 6, 2013Date of Patent: July 15, 2014Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Shinji Irifune, Tsutomu Nakajima
-
Publication number: 20140179879Abstract: A silicone resin composition includes a cage octasilsesquioxane; a polysiloxane containing alkenyl groups at both ends containing an alkenyl group having the number of moles smaller than the number of moles of the hydrosilyl group of the cage octasilsesquioxane; a hydrosilylation catalyst; a hydroxyl group-containing polysiloxane, organohydrogenpolysiloxane, or a polysiloxane containing alkenyl groups at side chain.Type: ApplicationFiled: February 28, 2014Publication date: June 26, 2014Applicant: NITTO DENKO CORPORATIONInventors: Haruka FUJII, Hiroyuki KATAYAMA
-
Publication number: 20140179863Abstract: An addition curable self-adhesive silicone rubber composition is provided. This silicone rubber composition comprises (A) 100 parts by weight of an organopolysiloxane containing at least 2 alkenyl groups bonded to silicon atoms per molecule, (B) 0.05 to 10 parts by weight of an organosilicon compound containing 1 to 100 silicon atoms which has at least 1 phenylene skeleton per molecule, and which has at least 1 hydrogen atom bonded to a silicon atom, (C) 0 to 30 parts by weight of an organohydrogenpolysiloxane containing at least 2 hydrogen atoms bonded to silicon atoms per molecule, and containing no phenylene skeleton in the molecule, (D) 0.001 to 0.1 part by weight of a triazole compound, and (E) a catalytic amount of a platinum catalyst. This silicone rubber composition is capable of forming a cured article having good adhesion to various organic resins.Type: ApplicationFiled: December 6, 2013Publication date: June 26, 2014Applicant: Shin-Etsu Chemical Co., Ltd.Inventor: Nobu KATO
-
Publication number: 20140175505Abstract: The present invention provides an encapsulant for optical semiconductor devices, which is capable of suppressing surface tackiness of a cured product and is also capable of enhancing the heat resistance and thermal cycle characteristics of the cured product. An encapsulant for optical semiconductor devices according to the present invention which includes: a first organopolysiloxane which is represented by formula (1A) or formula (1B) and has an alkenyl group and a methyl group bonded to a silicon atom; a second organopolysiloxane which is represented by formula (51A) or formula (51B) and has a hydrogen atom bonded to a silicon atom and a methyl group bonded to a silicon atom; and a catalyst for hydrosilylation reaction, and the content ratios of methyl groups bonded to silicon atoms in the first and second organopolysiloxanes each are 80 mol % or more.Type: ApplicationFiled: July 11, 2012Publication date: June 26, 2014Inventors: Ryosuke Yamazaki, Mitsuru Tanikawa, Takashi Watanabe, Osamu Inui, Yoshitaka Kunihiro, Chizuru Kimu, Yusuke Kobayashi, Hidefumi Yasui, Minoru Suezaki, Yasunari Kusaka, Tasuku Yamada
-
Patent number: 8759456Abstract: Disclosed is an addition reaction-curable organopolysilmethylenesiloxane copolymer composition including: (A) an organopolysilmethylenesiloxane copolymer represented by formula (a) shown below: which has in one molecule at least two alkenyl groups bonding to silicon atoms; (B) an organopolysiloxane represented by formula (b) shown below: R2aSiO(4-a)/2??(b) which has in one molecule at least two alkenyl groups bonding to silicon atoms; (C) an organohydrogenpolysilmethylenesiloxane and/or organohydrogenpolysiloxane; and (D) a platinum group metal-based catalyst. The copolymer composition excels in heat resistance, electrical insulation, mechanical strength, and optical properties, and exhibits good water resistance, hydrolysis resistance and gas barrier properties under severe use conditions without suffering gas permeability and poor chemical resistance inherent in silicone rubber.Type: GrantFiled: February 27, 2012Date of Patent: June 24, 2014Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Toshio Shiobara, Tsutomu Kashiwagi, Takeshi Fukuda
-
Publication number: 20140171599Abstract: An addition-curable silicone composition that provides a cured product having a particularly high transparency, an excellent light extraction efficiency and a favorable strength characteristic by subjecting the cured product to a lower refractive index by using a specific composition. The present invention was accomplished by an addition-curable silicone composition, including at least: (A) a linear organopolysiloxane having 2 or more aliphatic unsaturated groups bonded to a silicon atom and 1 or more CF3—(CF2)y—(CH2)z— groups bonded to a silicon atom in one molecule; (B) an organopolysiloxane having 2 or more aliphatic unsaturated groups bonded to a silicon atom and 1 or more CF3—(CF2)y—(CH2)z— groups bonded to a silicon atom in one molecule and having a branch structure of a siloxane unit represented by an SiO4/2 and/or an RSiO3/2; (C) an organosilicon compound represented by the following general formula (1); and (D) a platinum group metal-based catalyst.Type: ApplicationFiled: December 3, 2013Publication date: June 19, 2014Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Mitsuhiro IWATA, Toshiyuki OZAI, Yukito KOBAYASHI
-
Patent number: 8754174Abstract: A solventless addition-curable pressure sensitive silicone adhesive composition is provided. The composition comprises (A) an alkenyl group-containing polydiorganosiloxane; (B) a condensation product of (a) a polydiorganosiloxane having hydroxyl group or an alkoxy group on opposite ends of the molecular chain and (b) a polyorganosiloxane containing R13SiO1/2 unit and SiO2 unit as critical components and also a HOSiO3/2 unit in the molecule; (C1) a polyorganohydrosiloxane having at least three SiH groups per molecule; (C2) a polydiorganohydrosiloxane having SiH group on opposite ends; and (D) a platinum group metal catalyst. Use of the present composition enables production of a pressure sensitive adhesive agent having flexibility, pressure sensitive adhesiveness, and heat resistance, and the present composition is particularly effective for use as a buffer member having pressure sensitive adhesiveness.Type: GrantFiled: August 4, 2011Date of Patent: June 17, 2014Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Shunji Aoki
-
Patent number: 8748553Abstract: Composite materials contain a silicone addition crosslinkable silicone elastomer composition comprising an organopolysiloxane having aliphatic unsaturation, an Si—H functional cyclic organopolysiloxane, a hydrosilylation catalyst, together with specific adhesion promoters, applied to a substrate material.Type: GrantFiled: August 8, 2011Date of Patent: June 10, 2014Assignee: Wacker Chemie AGInventors: Martin Bortenschlager, Thomas Frese, Silvia Jung-Rossetti, Maria Leute
-
Patent number: 8748533Abstract: A curable organopolysiloxane composition comprises the following: (A) an organopolysiloxane having at least two silicon-bonded alkenyl groups and having an average unit formula (I): (R12SiO2/2)a(R23SiO1/2)b(R3SiO3/2)c(SiO4/2)d(CH2CH2)e; (B) a branched organopolysiloxane having at least one silicon-bonded alkenyl group and having a siloxane unit of formula R4SiO3/2; (C) an organopolysiloxane having an average unit formula (II) being capped with H: (R52SiO2/2)f(R63SiO1/2)g(R7SiO3/2)h(SiO4/2)i(CH2CH2)j; and (D) a catalyst, wherein R1 to R7 and a to j are as defined in the specification.Type: GrantFiled: November 22, 2011Date of Patent: June 10, 2014Assignee: Eternal Chemical Co., Ltd.Inventors: Kwei-Wen Liang, Chih-Chiang Yang
-
Patent number: 8742008Abstract: A process for forming a new group of siloxane-based compositions by a one-step co-hydrolysis and the compositions formed thereof. The siloxane-based compositions being functionalized with a carbon-carbon double (C?C) bond and a silicon-hydrogen (Si—H) bond. The C?C bond and hydrogen (H) each being attached directly to a silicon (Si) atom of the silicon-oxygen (Si—O) backbone of the siloxane-based composition. The C?C bond may be from a vinyl or an aromatic radical like a phenyl substituent. The C?C bond substituent provides the functionality needed for forming crosslinkages through standard dehydrocoupling catalysts without the need for siloxane fluids or organic compounds containing alkyl or aryl functional groups. The process provides for varying proportions of silanes as starting monomers to tailor the desired silicon, carbon, hydrogen and oxygen ratios in the siloxane-based compositions or resins.Type: GrantFiled: September 18, 2007Date of Patent: June 3, 2014Assignee: Starfire Systems, Inc.Inventors: Qionghua Shen, Walter J. Sherwood, Jr., Christopher K. Whitmarsh
-
Patent number: 8735525Abstract: The present invention relates to a curable composition. A curable composition may be provided; which shows excellent processability and workability; which shows excellent light extraction efficiency, crack resistance, hardness, thermal shock resistance and adhesive strength after curing; and which has excellent reliability and long-term reliability under high-temperature and/or high-moisture conditions. Also, turbidity and surface stickiness may be prevented in the cured product.Type: GrantFiled: July 20, 2012Date of Patent: May 27, 2014Assignee: LG Chem, LtdInventors: Min Jin Ko, Myung Sun Moon, Jae Ho Jung, Bum Gyu Choi, Dae Ho Kang, Min Kyoung Kim
-
Patent number: 8729208Abstract: A curable composition is provided. A cured product showing excellent light extraction efficiency, crack resistance, hardness, thermal shock resistance and adhesive strength after a curing, as well as showing excellent processability and workability is provided. Also, surface stickiness may be prevented in the cured product without causing turbidity etc.Type: GrantFiled: July 25, 2012Date of Patent: May 20, 2014Assignee: LG Chem, Ltd.Inventors: Min Jin Ko, Myung Sun Moon, Jae Ho Jung, Bum Gyu Choi, Dae Ho Kang, Min Kyoun Kim
-
Patent number: 8729195Abstract: An objective of the present invention is to provide a curable silicone composition of the present invention exhibiting superior adhesive properties with respect to a poor-adhesive resin such as PPS, even if the composition is cured at a relatively low temperature for a short period. The aforementioned objective of the present invention is achieved by a curable silicone composition comprising: (A) an organopolysiloxane having at least two alkenyl groups in a molecule, (B) an organopolysiloxane having at least two silicon-bonded hydrogen atoms in a molecule, (C) a hydrosilylation-reaction catalyst, and (D) an acid anhydride having an alkoxy group bonding to a silicon atom or an alkoxyalkoxy group bonding to a silicon atom.Type: GrantFiled: December 20, 2010Date of Patent: May 20, 2014Assignee: Dow Corning Toray Co., Ltd.Inventors: Yoshinori Taniguchi, Toyohiko Fujisawa, Yasushi Sugiura
-
Patent number: 8716412Abstract: A silicone resin composition includes a cage octasilsesquioxane; a polysiloxane containing alkenyl groups at both ends containing an alkenyl group having the number of moles smaller than the number of moles of the hydrosilyl group of the cage octasilsesquioxane; a hydrosilylation catalyst; a hydroxyl group-containing polysiloxane, organohydrogenpolysiloxane, or a polysiloxane containing alkenyl groups at side chain.Type: GrantFiled: June 15, 2012Date of Patent: May 6, 2014Assignee: Nitto Denko CorporationInventors: Haruka Fujii, Hiroyuki Katayama
-
Publication number: 20140110750Abstract: A curable composition is provided. A cured product showing excellent light extraction efficiency, crack resistance, hardness, thermal shock resistance and adhesive strength after a curing, as well as showing excellent processability and workability is provided. Also, surface stickiness may be prevented in the cured product without causing turbidity etc.Type: ApplicationFiled: December 30, 2013Publication date: April 24, 2014Applicant: LG CHEM, LTD.Inventors: Min Jin KO, Myung Sun MOON, Jae Ho JUNG, Bum Gyu CHOI, Dae Ho KANG, Min Kyoun KIM
-
Patent number: 8691910Abstract: A curable silicone composition comprising: an alkenyl-containing organopolysiloxane (A) that contains: a dialkylpolysiloxane (A-1) having on average at least 2 alkenyl groups in one molecule having a 25° C. viscosity in the range of 5,000 to 35,000 mPa·s, and a alkenyl-containing organopolysiloxane resin (A-2) consisting of SiO4/2 units, R12R2SiO1/2 units, and R13SiO1/2 units (where R1 designates alkyl groups with 1 to 10 carbon atoms, and R2 designates alkenyl groups) with the content of alkenyl groups ranging from 3.5 to 5.0 mass %, and with the ratio of the sum of the mole numbers of the R12R2SiO1/2 units and R13SiO1/2 units to 1 mole of the SiO4/2 units in the range from 0.5 to 1.4; an organopolysiloxane (B), wherein silicon-bonded hydrogen atoms are in an amount of at least 0.7 mass %; and a hydrosilylation catalyst (C). The composition is capable of forming a flex-resistant highly transparent cured silicone product with non-tacky surface.Type: GrantFiled: July 30, 2008Date of Patent: April 8, 2014Assignee: Dow Corning Toray Company, Ltd.Inventors: Chiichiro Hasegawa, Makoto Yoshitake, Hiroshi Akitomo
-
Patent number: 8674037Abstract: A silicon-containing polymer represented by the following average unit formula: (O2/2SiR1-R2-C6H4-R2-SiR1O2/2)x [R3 SiO(4-a)/2]y(R4O1/2)z (wherein R1 designates identical or different, substituted or unsubstituted monovalent hydrocarbon groups; R2 designates identical or different, substituted or unsubstituted alkylene groups; R3 designates substituted or unsubstituted monovalent hydrocarbon groups; R4 designates alkyl groups or hydrogen atoms; ‘a’ is a positive number that satisfies the following condition: 0=a=3; and ‘x’, ‘y’, and ‘z’ are positive numbers that satisfy the following conditions: 0<x<0.1; 0<y<1; 0=z<0.1; and (x+y+z)=1); and a curable polymer composition comprising: (A) the aforementioned silicon-containing polymer; (B) an organosilicon compound that contains in one molecule at least two silicon-bonded hydrogen atoms; and (C) a hydrosilylation catalyst.Type: GrantFiled: April 6, 2009Date of Patent: March 18, 2014Assignee: Dow Corning Toray Company, Ltd.Inventors: Yoshitsugu Morita, Yoshinori Taniguchi, Hiroshi Ueki