Interpolymers Patents (Class 525/60)
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Patent number: 6756442Abstract: The invention relates to silane-modified polyvinyl acetals obtained by acetalizing partially hydrolyzed or fully hydrolyzed vinyl ester polymers having at least 50 mol % of vinyl alcohol units with one or more aldehydes, optionally in the form of their hemiacetals or their acetals, where at least one aldehyde contains hydrolyzable silane groups.Type: GrantFiled: August 13, 2002Date of Patent: June 29, 2004Assignee: Wacker Polymer Systems GmbH & Co. KGInventors: Kurt Stark, Thomas Kornek, Bernhard Glaser, Karl-Heinz Eichel
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Patent number: 6753370Abstract: A resin composition comprises a copolymer (A) comprising ethylene as a major component produced with a single-site catalyst, and an ethylene-vinyl alcohol copolymer (B) having an ethylene content of 20-60 mol. % and a degree of hydrolysis of 95% or above, the resin composition satisfying the equation (1): 1/99≦{weight of (A)}/{weight of (B)}≦<99/1 (1) A preferred resin composition comprises a copolymer (A) which has a density of 0.90-0.94 g/cm3 and the resin composition further comprises a carboxylic acid-modified polyolefin (C) and satisfies the equations (2) and (3): 60/40≦{weight of (A)}/{(weight of (B)}≦: 99/1 (2) 0.1/99.9≦X≦: 20/80 (3) wherein X={weight of (C)}/{total weight of (A) and (B)}. Another preferred resin composition comprises a copolymer (A) which has a density of 0.85-0.Type: GrantFiled: March 7, 2002Date of Patent: June 22, 2004Assignee: Kuraray Co., Ltd.Inventors: Shigeki Nakatsukasa, Hiroyuki Ohgi, Kazuyori Yoshimi
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Patent number: 6737013Abstract: A ceramic-molding binder includes a vinyl alcohol polymer having an ethylene unit content of 2 to 19 mole %, a polymerization degree of 200 to 2,000, a degree of saponification of 80 to 99.99 mole %, and a carboxylic acid and lactone ring content of 0.02 to 0.4 mole %. The use of the ceramic-molding binder provides green moldings with better formability and handling properties during the formation of smaller green moldings of more complex shape, and also provides ceramic products of good quality, higher yields, and fewer ceramic cracks when obtained by sintering such green moldings.Type: GrantFiled: November 2, 2000Date of Patent: May 18, 2004Assignee: Kuraray Co., LtdInventors: Takeshi Kusudou, Toshiyuki Akasawa
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Patent number: 6716930Abstract: A method for processing a solution of ethylene-vinyl alcohol copolymer in a solvent other than water, which involves continuously substituting a part of the solvent in the solution with water to produce a high-concentration ethylene vinyl alcohol copolymer solution without gelling, whereby an ethylene-vinyl alcohol copolymer solution is fed into a column vessel selected from a plate column and a packed column, and a part of the solvent in the solution is substituted with water in the column vessel.Type: GrantFiled: August 7, 2001Date of Patent: April 6, 2004Assignee: Kuraray Co., Ltd.Inventors: Noboru Yanagida, Masafumi Mikami
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Patent number: 6710125Abstract: The invention provides a method for preparing a 1-benzotriazolylcarbonate ester of a water-soluble and non-peptidic polymer by reacting a terminal hydroxyl group of a water-soluble and non-peptidic polymer with di(1-benzotriazolyl)carbonate in the presence of an amine base and an organic solvent. The polymer backbone can be poly(ethylene glycol). The 1-benzotriazolylcarbonate ester can then be reacted directly with a biologically active agent to form a biologically active polymer conjugate or reacted with an amino acid, such as lysine, to form an amino acid derivative.Type: GrantFiled: February 6, 2002Date of Patent: March 23, 2004Assignee: Nektar Therapeutics AL, CorporationInventor: Antoni Kozlowski
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Patent number: 6709735Abstract: A film with excellent oxygen barrier properties is disclosed. A barrier coating used thereon is also disclosed, including polyvinyl alcohol and a copolymer of maleic acid and acrylic acid, and wherein the copolymer of maleic acid and acrylic acid has a weight average molecular weight of about 3500 to about 5000. The barrier coating is typically less than about 1 micrometer in thickness and provides an oxygen barrier of less than about 0.3 cc.mil/100 in2/day/atm when tested at 23 degrees Celsius and 0 percent relative humidity according to ASTM D3985. A method of stripping low molecular eight fractions from the copolymer is also disclosed. Metallized coated film according to the present invention shows surprising barrier properties.Type: GrantFiled: November 12, 2002Date of Patent: March 23, 2004Assignee: Mitsubishi Polyester Film, LLCInventors: Robert Posey, Edwin C. Culbertson
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Publication number: 20040010082Abstract: A highly water-absorptive ophthalmic lens which is formed of a macromolecular material including vinyl alcohol unit as a major component, wherein the improvement comprises: the macromolecular material being formed by saponifying a copolymer obtained by copolymerization of a polymerizable monomer composition which consists of vinyl acetate and diethylene glycol divinyl ether; the ophthalmic lens having a water content in a range from 73% to 84%; and the ophthalmic lens having a ratio of a dimensional change of less than ±2% and is free from whitening after (A) the ophthalmic lens has been subjected to three cycles of a freezing-thawing operation wherein the ophthalmic lens formed of the macromolecular material is left at a temperature of not higher than −10° C. for not less than twelve hours, and is subsequently left at a temperature in a range from 15° C. to 30° C. for not less than six hours, and/or (B) the ophthalmic lens has been kept at a temperature in a range from 1° C.Type: ApplicationFiled: July 7, 2003Publication date: January 15, 2004Applicant: Menicon Co. Ltd.Inventor: Masuji Ichihara
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Patent number: 6657004Abstract: The present invention provides a film for packaging chemical agents, which contains an oxyalkylene unit-containing polyvinyl alcohol resin (A) and a carboxyl-containing polyvinyl alcohol resin (B), and preferably further containing a sulfo-containing polyvinyl alcohol resin (C). This film shows fine solubility in water even after a long-term packaging of an acidic chemical agent or alkaline chemical agent, and is superior in mechanical strength. Thus, the film for packaging chemical agents of the present invention is suitably used for packaging a chemical agent, such as powdered soap, synthetic detergent, agricultural chemical, antibacterial, deodorant, insecticide and the like, which is cast into water when in use.Type: GrantFiled: May 15, 2001Date of Patent: December 2, 2003Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.Inventor: Tomoyoshi Mizutani
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Patent number: 6652942Abstract: The present invention provides a multiple layered non-PVC containing tubing structure. The tubing structure has a first and a second layer.Type: GrantFiled: January 8, 2001Date of Patent: November 25, 2003Assignee: Baxter International Inc.Inventors: Michael T. K. Ling, Ketan Shah, Bill Hurst, Samuel Ding
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Patent number: 6653400Abstract: This invention provides a method for producing a saponified ethylene-vinyl acetate copolymer in which visible imperfections (particularly fish eyes) of the saponified copolymer is inhibited. In this invention, a mixture solution is prepared by adding water to a methanol solution after saponifying an ethylene-vinyl acetate copolymer, and insoluble materials are removed from this mixture solution. Various types of filter or centrifugal separator are used to remove insoluble materials. It is preferable that the weight ratio of methanol to water is from 5:5 to 9:1, the concentration of the saponified copolymer is from 30 to 60 wt %, and the temperature is from 55 to 80° C. This method is particularly suitable for producing a saponified ethylene-vinyl acetate copolymer having an ethylene content of 20 to 70 mol % and a saponification degree of at least 95 mol %.Type: GrantFiled: June 28, 2001Date of Patent: November 25, 2003Assignee: Kuraray Co., Ltd.Inventors: Takaharu Kawahara, Toshio Tuboi
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Patent number: 6646050Abstract: An adhesive composition comprising (A) a copolymer of a (meth)acrylic ester having a Mw of 500,000 to 200,000 and (B) a crosslinking agent comprising an adduct of a polyisocyante comprising (a) isocyanate difunctional adducts of a diisocyanate with a diol (b) adducts of a diisocyanate with a polyhydric alcohol, having an isocyanate functionality of three or greater, in a weight ratio of the amounts of (a) to (b) of 95:5 to 10:90. An adhesive sheet and an adhesive optical component comprising a layer of the adhesive composition. The adhesive composition exhibits excellent adhesion with adherents, and stress relaxation and follows changes in the dimensions of substrates.Type: GrantFiled: March 13, 2001Date of Patent: November 11, 2003Assignee: Lintec CorporationInventors: Tomoo Ohrui, Toshio Sugizaki
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Patent number: 6635709Abstract: A dispersion stabilizer for suspension polymerization of a vinyl compound containing a vinyl alcohol polymer (A) having a content of an ethylene unit of 0.5 to 10 mol %, a degree of saponification of 60 mol % or more and a degree of polymerization of 600 or more and a vinyl alcohol polymer (B) selected from the group consisting of a vinyl alcohol polymer (B1) having a content of an ethylene unit of 0.5 to 10 mol %, a degree of saponification of 20 to 80 mol % and a degree of polymerization of 100 to 600, a vinyl alcohol polymer (B2) having a degree of saponification of 20 to 60 mol % and a degree of polymerization of 100 to 600 and a vinyl alcohol polymer (B3) having a content of an ethylene unit of 0.5 to 10 mol %, a degree of saponification of 90 mol % or more and a degree of polymerization of 1,000 or more.Type: GrantFiled: July 19, 2001Date of Patent: October 21, 2003Assignee: Kuraray Co., Ltd.Inventors: Masaki Kato, Naokiyo Inomata, Seiji Tanimoto
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Patent number: 6624246Abstract: The invention provides a method for preparing a 1-benzotriazolylcarbonate ester of a water-soluble and non-peptidic polymer by reacting a terminal hydroxyl group of a water-soluble and non-peptidic polymer with di(1-benzotriazolyl)carbonate in the presence of an amine base and an organic solvent. The polymer backbone can be poly(ethylene glycol). The 1-benzotriazolylcarbonate ester can then be reacted directly with a biologically active agent to form a biologically active polymer conjugate or reacted with an amino acid, such as lysine, to form an amino acid derivative.Type: GrantFiled: February 6, 2002Date of Patent: September 23, 2003Assignee: Shearwater CorporationInventor: Antoni Kozlowski
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Hyperbranched amphiphilic polymeric additives and polymer compositions with increased surface energy
Patent number: 6617397Abstract: The surface energy of polymeric substrates is increased by the application or incorporation of novel amphiphilic block copolymers. The block copolymer additives comprise a linear hydrophilic polymer or oligomer and a random hyperbranched polymer or oligomer and is completely or partially terminated with lipophilic end groups. The polymeric articles or constructions which benefit from the application or incorporation of the amphiphilic block copolymers in the areas of anti-fog, dissipation of static electricity, paintability, dyeability, printability, wicking of moisture, adhesion and polymer compatibility include carpet fibers, composite fibers, agricultural films, nonwoven coverstock, exterior automotive bumper fascia, packaging, hygienic products, incompatible polymer blends, laminated articles and eyewear.Type: GrantFiled: March 4, 2002Date of Patent: September 9, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: John James McNamara, Anunay Gupta, David Devore -
Patent number: 6613833Abstract: A method for producing an aqueous ethylene-vinyl alcohol copolymer (EVOH) composition that ensures efficient removal of alcohol not worsening the environment in and around working areas, and which provides EVOH pellets of the aqueous composition, which can be produced stably and can be washed rapidly, the method involving introducing an EVOH solution that contains at least 50 parts by weight, relative to 100 parts by weight of EVOH therein, of an alcohol having a boiling point of not higher than 100° C., into a vessel, and contacting it with water vapor in the vessel, thereby letting the alcohol out along with water vapor and taking the resulting aqueous EVOH composition that contains from 0 to 10 parts by weight of the alcohol and from 10 to 500 parts by weight of water, relative to 100 parts by weight of EVOH therein, out of the vessel; and the EVOH pellets obtained by cutting the aqueous EVOH composition obtained in the method.Type: GrantFiled: August 7, 2001Date of Patent: September 2, 2003Assignee: Kuraray Co., Ltd.Inventors: Takaharu Kawahara, Toshio Tuboi, Yukihiro Ohara
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Patent number: 6608166Abstract: A three dimensional copolymer network of polyphenylene ether segments and styrenic resins such as styrene/acrylonitrile copolymers provide articles of high heat reesistance and dielectric properties suitable for use in electronic components. Methods for preparing the copolymers employ polyphenylene ether polymers with end caps having at least one pair of unsaturated aliphatic carbon atoms, i.e. carbon-carbon double bond, and polymerize styrene monomers and acrylonitrile monomers or styrene/acrylonitrile copolymers or both in the presence of these polyphenylene ether polymers.Type: GrantFiled: August 30, 2001Date of Patent: August 19, 2003Assignee: General Electric CompanyInventors: Hua Guo, Manuel Cavazos, John B. Yates, III
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Patent number: 6565938Abstract: A resin composition comprising a saponified ethylene-vinyl acetate copolymer (A), a polyamide resin having a melting point not exceeding 160° C. (B), and a small proportion of a boron compound (C) and a laminate comprising a multi-lamellar shaped article comprised of the above resin composition layer (X) and a thermoplastic resin layer (Y).Type: GrantFiled: November 9, 2001Date of Patent: May 20, 2003Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki KaishaInventors: Masahiko Toyosumi, Kenji Ninomiya
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Publication number: 20030092850Abstract: Disclosed is a process for producing a powdered water-soluble polymer comprising hydrolyzing a copolymer comprising an N-vinylamide unit and a vinyl acetate unit while dispersed in water under a basic condition and then washing the resulting powdered water-soluble polymer with at least one washing liquid selected from an alcohol, water at 20° C. or lower, and salt water.Type: ApplicationFiled: December 27, 2002Publication date: May 15, 2003Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Yasuharu Mori, Kohichi Satoh, Nobuhiko Ueno
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Patent number: 6559228Abstract: There is a vinyl 4-hydroxybenzal-vinylalcohol-vinyl acetate copolymer, a 4-t-butoxycarbonyloxybenzal-vinyl alcohol-vinyl acetate copolymer and a vinyl 4-t-butoxycarbonyloxybenzal-vinyl 4-hydroxybenzal-vinyl alcohol-vinyl acetate copolymer suitable for photoresist and methods for preparing the same. The latter two polymers contain 4-hydroxybenzal groups all or parts of which are protected with t-butoxycarbonyl group. Superior in transparency, thermal stability, mechanical strength, and adhesiveness to silicon wafer, the photoresists prepared from the protected copolymers can enhance the resolution of fine circuit by virtue of low weight loss upon the thermal treatment after exposure.Type: GrantFiled: March 21, 2001Date of Patent: May 6, 2003Assignees: Hyundai Electronics Industries Co. Ltd., Korea Advanced Institute of Science and Technology (“KAIST”)Inventors: Jin Baek Kim, Hyun Woo Kim
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Patent number: 6559227Abstract: Disclosed is a process for producing a powdered water-soluble polymer comprising hydrolyzing a copolymer comprising an N-vinylamide unit and a vinyl acetate unit while dispersed in water under a basic condition and then washing the resulting powdered water-soluble polymer with at least one washing liquid selected from an alcohol, water at 20° C. or lower, and salt water.Type: GrantFiled: July 28, 2000Date of Patent: May 6, 2003Assignee: Mitsubishi Chemical CorporationInventors: Yasuharu Mori, Kohichi Satoh, Nobuhiko Ueno
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Patent number: 6559226Abstract: The present invention provides golf balls having a cover, a core, and optionally one or more intermediate layers between the cover and the core, wherein at least one of the cover, the core and, if present, the intermediate layer or layers, includes an anionic polymer. The anionic polymer has at least one of a neutralizable hydroxyl or dealkylable ether group, at least a portion of which are neutralized or dealkylated by a metal ion to provide anionic moieties. The anionic polymer compositions of the present invention can be used to provide improved characteristics to golf balls made therefrom.Type: GrantFiled: April 24, 2001Date of Patent: May 6, 2003Assignee: Achushnet CompanyInventor: Murali Rajagopalan
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Patent number: 6552123Abstract: Provided are melt-spun fibers comprising, as at least one component, a water-soluble polyvinyl alcohol, and a method for producing fibrous structures comprising the fibers. The thermoplastic polyvinyl alcohol fibers comprise, as at least one component, a water-soluble polyvinyl alcohol containing from 0.1 to 25 mol % of C1-4 &agr;-olefin units and/or vinyl ether units, having a molar fraction, based on vinyl alcohol units, of a hydroxyl group of vinyl alcohol unit located at the center of 3 successive vinyl alcohol unit chain in terms of triad expression of being from 70 to 99.9 mol %, having a carboxylic acid and lactone ring content of from 0.02 to 0.15 mol %, and having a melting point falling between 160° C. and 230° C., and contain from 0.0003 to 1 part by weight, relative to 100 parts by weight of the polyvinyl alcohol therein and in terms of sodium ion, of an alkali metal ion.Type: GrantFiled: December 16, 1999Date of Patent: April 22, 2003Assignee: Kuraray Co., Ltd.Inventors: Takashi Katayama, Kazuhiko Tanaka, Naoki Fujiwara, Tomoaki Kimura, Akihiro Hokimoto, Nobuhiro Koga, Hitoshi Nakatsuka, Yoshimi Umemura, Hiroshi Kanehira, Masao Kawamoto, Junyo Nakagawa
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Patent number: 6537468Abstract: The invention is directed at an ion-conductive solid polymer-forming composition, a binder resin and an ion-conductive solid polymer electrolyte comprising (A) a polymeric compound containing polyvinyl alcohol units and having an average degree of polymerization of at least 20, in which compound some or all of the hydroxyl groups on the polyvinyl alcohol units are substituted with oxyalkylene-containing groups to an average molar substitution of at least 0.3, (B) an ion-conductive salt, and (C) a compound having crosslinkable functional groups. The composition and the polymer electrolyte obtained therefrom have a high ionic conductivity and a high tackiness. Moreover, the polymer electrolyte has a semi-interpenetrating polymer network structure, giving it excellent shape retention.Type: GrantFiled: November 21, 2000Date of Patent: March 25, 2003Assignee: Nisshinbo Industries, Inc.Inventors: Kimiyo Hata, Takaya Sato
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Patent number: 6533964Abstract: The invention provides a novel polymeric compound comprising polyvinyl alcohol units and having an average degree of polymerization of at least 20, in which some or all of the hydroxyl groups on the polyvinyl alcohol units are substituted with oxyalkylene-containing groups to an average molar substitution of at least 0.3; a binder resin composed of this polymeric compound; an ion-conductive polymer electrolyte composition having a high ionic conductivity and high tackiness which lends itself well to use as a solid polymer electrolyte in film-type cells and related applications; and a secondary cell.Type: GrantFiled: November 22, 2000Date of Patent: March 18, 2003Assignee: Nisshinbo Industries, Inc.Inventors: Kimiyo Hata, Takaya Sato
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Publication number: 20030050410Abstract: A method for producing a saponified ethylene-vinyl acetate copolymer (EVOH) comprises: supplying into a second reactor a solution containing the copolymer that is saponified partially with an alkali catalyst under a predetermined pressure in a first reactor; and saponifying further the partially-saponified copolymer in the second reactor under a pressure higher than the predetermined pressure in the first reactor. According to the method, an EVOH having a high saponification degree can be produced efficiently with a small amount of alkali catalyst.Type: ApplicationFiled: September 16, 2002Publication date: March 13, 2003Inventors: Takaharu Kawahara, Yukihiro Ohara, Toshio Tuboi, Tetsuya Hikasa
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Patent number: 6524498Abstract: An electrolyte composition and a solid polymer electrolyte for electric double-layer capacitors are endowed with high ionic conductivity, high tackiness and shape retention. The invention is also directed at a polarizable electrode-forming composition and a polarizable electrode having a high adhesion, high dielectric properties, and excellent shape retention. A high-performance electric double-layer capacitor arrived at using the above compositions and components is additionally disclosed.Type: GrantFiled: November 22, 2000Date of Patent: February 25, 2003Assignee: Nisshinbo Industries, Inc.Inventors: Kimiyo Hata, Takaya Sato
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Publication number: 20030013806Abstract: A method of improving ink stability. A block co-polymer is added to either an under-/overprinting vehicle or an ink vehicle. The polymer increases chemical interactions between the ink the print media. The under-/overprinting vehicle and the ink vehicle interact through electrostatic interactions while the polymer increases smearfastness by interacting with the print media through non-covalent interactions.Type: ApplicationFiled: May 25, 2001Publication date: January 16, 2003Inventor: David M. Schut
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Patent number: 6500897Abstract: The present invention is a hydrolytically modified, biodegradable polymer and a method of making a hydrolytically modifiable a biodegradable polymer. In a preferred embodiment, the invention is a method of grafting polar groups onto biodegradable polymers and modified biodegradable polymer compositions produced by the method. The polymer compositions are useful as components in flushable and degradable articles. Water-sensitive polymer blends and method of making those polymer blends are also disclosed.Type: GrantFiled: December 29, 2000Date of Patent: December 31, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventors: James H. Wang, David M. Schertz
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Patent number: 6472470Abstract: Vinyl alcohol polymers having an ethylene unit content of 2 to 19 mole %, a polymerization degree of 200 to 2,000, a degree of saponification of 80 to 99.99 mole % and a total content of carboxyl group and lactone rings of 0.02 to 0.4 mole % are excellent in thermal stability, water resistance, gas-barrier properties, water vapor-barrier property, stability of aqueous solution kept at low temperatures and biodegradability.Type: GrantFiled: December 2, 1999Date of Patent: October 29, 2002Assignee: Kuraray Co., Ltd.Inventors: Naoki Fujiwara, Kazuyuki Somemiya, Takeshi Kusudou
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Patent number: 6465142Abstract: Poly(vinyl butyral) compounds of Formula 1 where R1 is alkyl, dialkyl ether, alkyl carbonyl, cycloalkyl, cycloalkyl alkyl, aryl, aryl carbonyl, alkaryl carbonyl, aralkyl, or alkyl aralkyl; Z is —OH or —NHR2, where R2 is independently alkyl, dialkyl ether, alkyl carbonyl, cycloalkyl, cycloalkyl alkyl, aryl, aryl carbonyl, alkaryl carbonyl, aralkyl, alkyl, aralkyl or R2 is H. x is 60 to 95 mol %, y is 3 to 40 mol %, z is 0 to 20 mol %; and x+y+z is 100 mol %, a process for preparing compounds of Formula I, an intermediate in the synthesis of compounds of Formula I, and a photoconductor for electrophotography containing a compound of Formula I as a binder in the charge generation layer are described.Type: GrantFiled: November 20, 1997Date of Patent: October 15, 2002Assignee: Hewlett-Packard CompanyInventors: Khe C. Nguyen, Sivapackia Ganapathiappan
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Patent number: 6455226Abstract: The present invention provides photoresist polymers and photoresist compositions comprising the same. In one aspect, the photoresist polymer is of the Formula: where Y, R1, a, b and c are as described herein. Photoresist compositions of the present invention have good transmittance at wavelengths of 193 nm and 157 nm, etching resistance, heat resistance, and adhesiveness. In addition, photoresist compositions of the present invention can be developed easily in aqueous TMAH solution, and are therefore suitable for lithography processes using VUV (157 nm) and EUV (13 nm) wavelength-light sources for fabricating a minute circuit of a high integration semiconductor device.Type: GrantFiled: November 1, 2000Date of Patent: September 24, 2002Assignee: Hyundai Electronics Industries Co., Ltd.Inventors: Geun Su Lee, Jae Chang Jung, Hyeong Soo Kim, Ki Ho Baik
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Patent number: 6451751Abstract: There is provided a process for producing particles of amine reaction product by means of a carrier having a melting point between 30 degrees Celsius and 135 degrees Celsius, optionally followed by a coating step. Processed amine reaction products and finished compositions incorporating such processed product are also herein provided.Type: GrantFiled: December 20, 2000Date of Patent: September 17, 2002Assignee: The Procter & Gamble CompanyInventors: Alfred Busch, Marcel Homblé, Christophe Laudamiel, Johan Smets, Rafael Trujillo, Jean Wevers
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Hyperbranched amphiphilic polymeric additives and polymer compositions with increased surface energy
Patent number: 6444758Abstract: The surface energy of polymeric substrates is increased by the application or incorporation of novel amphiphilic block copolymers. The block copolymer additives comprise a linear hydrophilic polymer or oligomer and a random hyperbranched polymer or oligomer and is completely or partially terminated with lipophilic end groups. The polymeric articles or constructions which benefit from the application or incorporation of the amphiphilic block copolymers in the areas of anti-fog, dissipation of static electricity, paintability, dyeability, printability, wicking of moisture, adhesion and polymer compatibility include carpet fibers, composite fibers, agricultural films, nonwoven coverstock, exterior automotive bumper fascia, packaging, hygienic products, incompatible polymer blends, laminated articles and eyewear.Type: GrantFiled: February 7, 2001Date of Patent: September 3, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: John James McNamara, Anunay Gupta, David Devore -
Patent number: 6420004Abstract: The invention concerns composite polyester films with good barrier properties relative to gases. More precisely, it concerns a biaxially drawn film, based on polyester and having improved barrier properties relative to gases, characterised in that it comprises a base polyester film of 5 to 50 &mgr;m, coated on one of its two surfaces with a deposit containing polyvinyl alcohol and a water dispersible copolyester with sulphonyloxy units, said composite film having permeability to oxygen measured at 23° C. under 50% relative humidity, not more than 5 cm3/m2/24 h. Said composite films have, besides being transparent and having barrier properties, excellent resistance to mechanical stresses, such as in particular crumpling.Type: GrantFiled: March 20, 2000Date of Patent: July 16, 2002Assignee: Toray Plastics Europe S.A.Inventors: Didier Veyrat, Eric Maitre
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Patent number: 6410155Abstract: The present invention is directed to a novel process of making N-isopropyl acrylamide (NiPAm) polymers based upon the reaction of poly(acrylic acid) and N-isopropylamine. The disclosed method of the present invention uses polyacrylic acid as a starting material to synthesize NiPAm polymers. In one embodiment, the present invention discloses a condensation reaction of an intermediate salt to form homopolymers, copolymers and terpolymers of N-isopropyl acrylamide (NiPAm) with acrylic acid and/or alkyl acrylates in a molten state, which is adaptable to a continuous reactive extrusion process. Binder compositions, water-dispersible products and thermoformable articles containing the NiPAm polymers are also disclosed.Type: GrantFiled: May 18, 2001Date of Patent: June 25, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Pavneet Singh Mumick, Yihua Chang, James Hongxue Wang
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Patent number: 6410644Abstract: The present invention is directed to a novel process of making N-isopropyl acrylamide (NiPAm) polymers based upon the reaction of poly(acrylic acid) and N-isopropylamine. The disclosed method of the present invention uses polyacrylic acid as a starting material to synthesize NiPAm polymers. In one embodiment, the present invention discloses a condensation reaction of an intermediate salt to form homopolymers, copolymers and terpolymers of N-isopropyl acrylamide (NiPAm) with acrylic acid and/or alkyl acrylates in a molten state, which is adaptable to a continuous reactive extrusion process. Binder compositions, water-dispersible products and thermoformable articles containing the NiPAm polymers are also disclosed.Type: GrantFiled: May 18, 2001Date of Patent: June 25, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Pavneet Singh Mumick, Yihua Chang, James Hongxue Wang
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Patent number: 6407145Abstract: The invention relates to a novel process for the manufacture of mouldings, especially contact lenses, in which a soluble prepolymer comprising crosslinkable groups is crosslinked in solution, and also to mouldings, especially contact lenses, obtainable in accordance with that process. The present invention relates also to novel prepolymers that can be used in the process according to the invention, especially derivatives of a polyvinyl alcohol having a molecular weight of at least about 2000 that, based on the number of hydroxy groups of the polyvinyl alcohol, comprise from approximately 0.Type: GrantFiled: September 17, 1998Date of Patent: June 18, 2002Assignee: Novartis AGInventor: Beat Müller
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Publication number: 20020045704Abstract: Disclosed are adhesive formulations as creping process aids for producing an absorbent creped cellulosic sheet having a high level of surface-perceived softness that comprises continuously forming a web of cellulosic papermaking fibers, adhering said web to a thermal drying means by means of adhesive compositions comprising polymers having at least one primary or secondary amine group in the backbone such as chitosan, polyvinylamine, polyvinyl alcohol-vinyl amine and polyaminoamide in combination with crosslinking agents such as dialdehydes or zirconium compounds having a valence of plus four including ammonium zirconium carbonate, zirconium acetylacetonate, zirconium acetate, zirconium carbonate, zirconium sulfate, zirconium phosphate, potassium zirconium carbonate, zirconium sodium phosphate and sodium zirconium tartrate and creping said treated web from said thermal drying means.Type: ApplicationFiled: July 13, 2001Publication date: April 18, 2002Applicant: James River CorporationInventors: Phuong Van Luu, Cristian M. Neculescu, Dawn M. Mews
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Patent number: 6346570Abstract: Provided are a water resistant composition comprising a uniform mixture of (A) at least one of modified polyvinyl alcohol containing either from 1 to 20 mol % of &agr;-olefin units with not more than 4 carbon atoms, from 0.01 to 1 mol % of silyl groups, or from 1 to 20 mol % of &agr;-olefin units with not more than 4 carbon atoms and from 0.01 to 1 mol % of silyl groups and (B) an organotitanium compound having a chelating ligand, in a blend ratio of component (A) to the component (B) between 99.99/0.01 and 60/40 by weight; a coating agent comprising the composition; a thermal recording material having a coat layer of the composition; and an ink-jet recording material having an ink-absorbing layer of the composition.Type: GrantFiled: August 22, 2000Date of Patent: February 12, 2002Assignee: Kuraray Co., Ltd.Inventors: Somemiya Kazuyuki, Sadahiko Shiraga, Naoki Fujuwara, Atsushi Jikihara, Toshiyuki Akasawa
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Publication number: 20020010263Abstract: Herein are disclosed a curable resin composition for overcoat of flexible circuit which comprises a hydrogenated polybutadiene polyol with a number-average molecular weight of 1,000-8000 and having 2-10 hydroxyl groups per molecule (Polyol A), and a polybutadiene polyblock isocyanate (Isocyanate X), and other similar curable resin compositions, which can be an overcaoting agent which can give a coat film involving no such trouble that the coat film gets overhardened and the curling is increased.Type: ApplicationFiled: October 15, 1999Publication date: January 24, 2002Inventor: HIROSHI ORIKABE
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Publication number: 20010053826Abstract: A superabsorbent resin composition comprising the following componentsType: ApplicationFiled: July 3, 2001Publication date: December 20, 2001Applicant: Kao CorporationInventors: Yasunori Hosokawa, Tadashi Igarashi, Isao Tsuru, Yoko Hanada
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Publication number: 20010025072Abstract: A purging agent which contains an ethylene-vinyl alcohol copolymer and which satisfies the conditions specified by the equations (1) and (2) below:Type: ApplicationFiled: June 18, 1997Publication date: September 27, 2001Inventors: TAICHI NEGI, SYUKITI KAWAMURA, HIROMICHI NAKANO, SATOSHI HIROFUJI
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Patent number: 6294609Abstract: Particularly useful as a barrier layer in packaging, e.g. multilayer structures, is a composition based on an ethylene-vinyl alcohol copolymer comprising: 50 to 98% by weight of an EVOH copolymer 1 to 50% by weight of a polyethylene (A) 1 to 15% by weight of a polyethylene (B) being a blend of a polyethylene (B1) and a polyethylene (B2) chosen from elastomers, very-low-density polyethylenes and metallocene polyethylenes, the blend of (B1) and (B2) being cografted by an unsaturated carboxylic acid or a functional acid derivative thereof.Type: GrantFiled: January 19, 2000Date of Patent: September 25, 2001Assignee: AtofinaInventors: Denis Bertin, Denis Germain
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Patent number: 6288165Abstract: A process for producing vinyl acetate polymers comprises, after polymerization of at least one monomer comprising vinyl acetate, adding a conjugated polyene having a boiling point of at least 20° C. Saponified products of the vinyl acetate polymers obtained by this process can give molded articles causing little coloring and generation of gel-like agglomerates.Type: GrantFiled: December 5, 1997Date of Patent: September 11, 2001Assignee: Kuraray Co., Ltd.Inventors: Takeshi Moritani, Kaoru Ikeda, Akimasa Aoyama, Takaharu Kawahara, Yukihiro Ohara, Naoshi Nakagawa, Toshinori Tsugaru
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Publication number: 20010020065Abstract: There is a vinyl 4-hydroxybenzal-vinylalcohol-vinyl acetate copolymer, a 4-t-butoxycarbonyloxybenzal-vinyl alcohol-vinyl acetate copolymer and a vinyl 4-t-butoxycarbonyloxybenzal-vinyl 4-hydroxybenzal-vinyl alcohol-vinyl acetate copolymer suitable for photoresist and methods for preparing the same. The latter two polymers contain 4-hydroxybenzal groups all or parts of which are protected with t-butoxycarbonyl group. Superior in transparency, thermal stability, mechanical strength, and adhesiveness to silicon wafer, the photoresists prepared from the protected copolymers can enhance the resolution of fine circuit by virtue of low weight loss upon the thermal treatment after exposure.Type: ApplicationFiled: March 21, 2001Publication date: September 6, 2001Applicant: Hyundai Electronics Industries Co., Ltd.Inventors: Jin Baek Kim, Hyun Woo Kim
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Publication number: 20010014717Abstract: Coatings for implantable devices or endoluminal prosthesis, such as stents, are provided, including a method of forming the coatings. The coatings can be used for the delivery of an active ingredient or a combination of active ingredients.Type: ApplicationFiled: December 28, 2000Publication date: August 16, 2001Inventors: Syed F.A. Hossainy, Stephen D. Pacetti, Keith E. Fong, Vinayak Bhat, Deborra Sanders Millare, Judy A. Guruwaiya, Daryush Mirzaee, Evgenia Mandrusov
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Patent number: 6255033Abstract: A positive acting, heat-sensitive composition is presented, either coated on a lithographic base, or on a printing circuit board base, and comprises a water insoluble heat-sensitive resin, a novel adhesion promoter and a radiation absorbing agent—a dye or a pigment. An excellent film forming polymer that comprises acetal units directly pendant from the polymer polyvinyl alcohol backbone may be the only binder resin, when other resins being optional. The solubility of the coated material in the areas exposed to near-IR laser radiation in mild alkaline developers becomes considerably higher, allowing to obtain high resolved patterns of the etch-resistant material on printing circuit boards or lithographic printing plates. The composition can be applied on the substrate from a liquid or laminated as a dry film.Type: GrantFiled: July 30, 1999Date of Patent: July 3, 2001Assignee: Creo, Ltd.Inventors: Moshe Levanon, Emmanuel Lurie, Sergei Malikov, Oleg Naigertsik, Larisa Postel
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Patent number: 6245854Abstract: A hydrophilic coating composition for hydrophilically coating a metallic surface. The coating composition comprises a fluorocarbon-containing hydrophilic polymer comprising units of hydrophilic monomer and fluorocarbon-containing hydrophobic comonomer. The coating composition produces hydrophilic coatings on the metallic surface having a contact angle below about 50°.Type: GrantFiled: December 11, 1998Date of Patent: June 12, 2001Assignee: Visteon Global Technologies, Inc.Inventors: Chimere N. Obioha, Riad A. Farah, Dennis Schuetzle, Yun-xiang Zhang
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Vinyl 4-t-butoxycarbonyloxbenzal-vinyl alcohol-vinylacetate copolymer and preparation method thereof
Patent number: 6235836Abstract: There is a vinyl 4-hydroxybenzal-vinylalcohol-vinyl acetate copolymer, a 4-t-butoxycarbonyloxybenzal-vinyl alcohol-vinyl acetate copolymer and a vinyl 4-t-butoxycarbonyloxybenzal-vinyl 4-hydroxybenzal-vinyl alcohol-vinyl acetate copolymer suitable for photoresist and methods for preparing the same. The latter two polymers contain 4-hydroxybenzal groups all or parts of which are protected with t-butoxycarbonyl group. Superior in transparency, thermal stability, mechanical strength, and adhesiveness to silicon wafer, the photoresists prepared from the protected copolymers can enhance the resolution of fine circuit by virtue of low weight loss upon the thermal treatment after exposure.Type: GrantFiled: November 27, 1996Date of Patent: May 22, 2001Assignees: Hyundai Electronics Industries Co., Ltd., Korea Advanced Institute of Science and Technology (“KAIST”)Inventors: Jin Baek Kim, Hyun Woo Kim -
Patent number: 6221960Abstract: The present invention provides golf balls having a cover, a core, and optionally one or more intermediate layers between the cover and the core, wherein at least one of the cover, the core and, if present, the intermediate layer or layers, includes an anionic polymer. The anionic polymer has at least one of a neutralizable hydroxyl or dealkylable ether group, at least a portion of which are neutralized or dealkylated by a metal ion to provide anionic moieties. The anionic polymer compositions of the present invention can be used to provide improved characteristics to golf balls made therefrom.Type: GrantFiled: December 23, 1998Date of Patent: April 24, 2001Assignee: Asushnet CompanyInventor: Murali Rajagopalan