Interpolymers Patents (Class 525/60)
  • Patent number: 6221952
    Abstract: An aqueous emulsion composition is provided that includes, as the dispersoid, a (co)polymer that contains at least one monomer unit selected from ethylenic unsaturated monomers and dienic monomers, and, as the dispersant, (A) a polyvinyl alcohol (co)polymer, and (B) a condensate of an alkali metal salt of an aromatic sulfonic acid with formaldehyde in a ratio, (A)/(B), of from 100/0.05 to 100/100 in terms of the solid content of the two. The composition is characterized by its fluidity such that the apparent viscosity of the composition is prevented from being lowered relative to the increase in the shear rate of the composition, and that the apparent viscosity of the composition is increased relative to the increase in the shear rate thereof. In addition, the composition has excellent high initial adhesiveness and viscosity-increasing ability.
    Type: Grant
    Filed: June 9, 1998
    Date of Patent: April 24, 2001
    Assignee: Kuraray Co., Ltd.
    Inventor: Masato Nakamae
  • Patent number: 6214933
    Abstract: A composition comprises a polyolefin, such as polyethylene, as a major constituent and poly(ethylene oxide) as a minor constituent. The composition exhibits an inverse phase morphology so that the poly(ethylene oxide) forms a continuous phase and the polyolefin forms a dispersed or discontinuous phase in the film. Desirably, the polyolefin and the poly(ethylene oxide) are grafted with a polar, vinyl monomer. The composition can be used in disposable personal hygiene articles.
    Type: Grant
    Filed: June 7, 1999
    Date of Patent: April 10, 2001
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: James H. Wang, David M. Schertz
  • Patent number: 6211289
    Abstract: Modified polyvinyl acetals are prepared by saponification of 1-alkylvinyl acetate-vinyl acetate copolymers, which contain 1-alkylvinyl acetate/vinyl acetate in a weight ratio of 1/99-40/60 and subsequent acetalization the saponification products containing at least 80% units of vinyl alcohol and 1-alkyl vinyl alcohol with one or more aliphatic aldehydes with 1-6 C atoms under acid catalysis in an aqueous and/or organic medium; as well as to a method for the manufacture and the use thereof, especially in printing inks.
    Type: Grant
    Filed: November 25, 1998
    Date of Patent: April 3, 2001
    Assignee: Wacker Chemie GmbH
    Inventors: Peter Tschirner, Peter Heiling, Otto-Sebastian Huber, Guenter Braunsperger, Klaus Haefner, Georg Friedl
  • Patent number: 6180689
    Abstract: The present invention concerns a fluid loss control agent for a petroleum industry (or analogous) cement slurry, comprising a surfactant and a micro-gel obtained by chemical cross-linking of a polyvinyl alcohol. The micro-gel and the surfactant are advantageously compatible with a wide range of petroleum industry cement additives and can also produce compositions which are gas tight.
    Type: Grant
    Filed: October 26, 1999
    Date of Patent: January 30, 2001
    Assignee: Schlumberger Technology Corporation
    Inventor: Eric Moulin
  • Patent number: 6162864
    Abstract: A polyvinyl alcohol is provided containing structural units of the following formula (I) at a molar fraction of 0.05-0.50 and the structural units of the following formula (II) at a molar fraction of 0.0001 to 0.50; ##STR1## wherein R.sup.1, R.sup.2, R.sub.3 and X are as desribed herein, and its use in preparation of gels, particularly hydrogels, effective for use in wound dressing materials.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: December 19, 2000
    Assignee: Kuraray Co., Ltd.
    Inventors: Masao Tanihara, Yoshiharu Fukunishi
  • Patent number: 6103823
    Abstract: A three stages process for the preparation of solid thermoplastic compositions based on polyvinyl alcohol comprising the mixing in a mixer of a first charge, comprising the polyvinyl alcohol and solid plasticizers, with a second charge constituted by one or more hydroxylated organic compounds selected from glycols, glycol ethers and alkanolamines and at least a salt of an alkaline and/or alkaline earth metal, and a third charge containing at least one or more solid polyhydroxylated alcohols, glycols and glycolic ethers, liquid alkanolamines, organic or inorganic mineral acids, hydrated inorganic salts, polymers having a low molecular weight, stabilizers and possible mineral charges, is described.
    Type: Grant
    Filed: February 18, 1998
    Date of Patent: August 15, 2000
    Assignee: Panteco S.R.L.
    Inventors: Adriano Centofanti, Gianfranco Centofanti
  • Patent number: 6068922
    Abstract: A process for making a substantially uniform composition of short aramid fibers and polymer wherein the fibers are provided with a significant moisture content to improve handling characteristics and are partially dried and opened by shear forces in an extruder before contact with the polymer in the extruder.
    Type: Grant
    Filed: April 14, 1998
    Date of Patent: May 30, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Giorgio P. Vercesi, Jean Pierre Jakob, Nicolas Cudre-Mauroux
  • Patent number: 5994449
    Abstract: Disclosed are resin compositions that are the reaction product of epihalohydrin with a mixture of polyaminoamide and vinyl amine polymer containing a minimum of about 1 mole % vinyl amine monomer units, wherein said polyaminoamide comprises the reaction product of dicarboxylic acid, or a derivative thereof, with polyamine selected from the group consisting of methyl bis(3-aminopropyl)amine and polyalkylenepolyamine containing from two to four alkylene groups having two to four carbons, two primary amine groups, and one to three secondary amine groups. Also disclosed are a process for creping fibrous webs utilizing the resin compositions, and creped paper prepared by the process. Also disclosed is wet and dry strength paper containing the resin compositions and processes for creping fibrous webs utilizing the resin compositions as creping adhesives.
    Type: Grant
    Filed: January 23, 1997
    Date of Patent: November 30, 1999
    Assignee: Hercules Incorporated
    Inventor: William Walter Maslanka
  • Patent number: 5990238
    Abstract: A polymer includes an ethylene-containing backbone having substituents attached thereto, wherein the substituents include a urethane linked nitrogen-bonded hydrocarbon side chain having about 5 carbon atoms or more in length and a terminal methyl group; and an oxygen linked water solubilizing group. The polymer is particularly useful in a release coating composition and is suitable for forming films from aqueous dispersions thereof, organic solvent dispersions thereof, or mixtures thereof.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: November 23, 1999
    Assignee: 3M Innovative Properties Company
    Inventors: James P. DiZio, Roy Wong, Hildegard M. Schneider
  • Patent number: 5900461
    Abstract: A poly(ethylene glycol) derivative is disclosed that is activated with a sulfone moiety for selective attachment to thiol moieties on molecules and surfaces. The activated PEG is water soluble, hydrolytically stable for extended periods, and forms hydrolytically stable linkages with thiol moieties. The linkages generally are not reversible in reducing environments. The PEG derivative is useful for modifying the characteristics of substances including modifying biologically active molecules and surfaces for biocompatibility. Methods for synthesizing the active PEG and for preparing conjugates of the active PEG and other substances, including biologically active substances, are also disclosed.
    Type: Grant
    Filed: February 23, 1998
    Date of Patent: May 4, 1999
    Assignee: Shearwater Polymers, Inc.
    Inventor: J. Milton Harris
  • Patent number: 5895797
    Abstract: Disclosed is a polymer composition which comprises as the main components an ethylene-vinyl alcohol base copolymer (A) and a block copolymer (B) which has a polymer block containing an aromatic vinyl monomer unit and a polymer block containing an isobutylene unit, and in which a phase composed of said component (A) and a phase composed of said component (B) are separated each other. This polymer composition has good flexibility or rubber elasticity and also good barrier properties to gases or the like and it can be molded or formed into a product having such properties without a vulcanization step so that it is useful as a material for packaging material for food or drink, container packing, medical container for infusion fluid or the like.
    Type: Grant
    Filed: June 18, 1997
    Date of Patent: April 20, 1999
    Assignee: Kuraray Co., Ltd.
    Inventors: Hiroshi Hayashihara, Kenji Shachi, Kazushige Ishiura
  • Patent number: 5866655
    Abstract: A vinyl alcohol polymer with a side chain being a hydroxyalkyl group having 2 to 20 carbon atoms is disclosed. Conventional water-soluble vinyl alcohol polymers gives, where they have a high interfacial activity, an aqueous solution with much-foaming and hence a problem when used for commercial purposes. On the other hand, the vinyl alcohol polymer of the present invention gives, where it is water-soluble, an aqueous solution with less-foaming in spite of its high interfacial activity, and hence an excellent industrial applicability. The vinyl alcohol polymer of the present invention is useful as thermoplastic resin and dispersion stabilizer. In addition, the vinyl alcohol polymer of the present invention is usable for various purposes, e.g.
    Type: Grant
    Filed: May 28, 1997
    Date of Patent: February 2, 1999
    Assignee: Kuraray Co., Ltd.
    Inventors: Naoki Fujiwara, Takeshi Kusudou, Takaharu Kawahara, Toshiaki Sato
  • Patent number: 5849842
    Abstract: Binders useful in photosensitive compositions contain units A, B, C and D, wherein A is present in an amount of 0.5 to 15 wt. % and is of the formula ##STR1## B is present in an amount of 10 to 35 wt. % and is of the formula ##STR2## C is present in an amount of 10 to 50 wt. % and is of the formula ##STR3## wherein R.sup.1 is methyl, ethyl, propyl, and D is present in an amount of 25 to 70 wt. % and is of the formula ##STR4## wherein n is an integer of from 1 to 3 and R.sup.2, R.sup.3 are hydrogen or methyl and R.sup.4 is alkyl, aralkyl or aryl.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: December 15, 1998
    Assignee: Kodak Polychrome Graphics, LLC
    Inventors: Hans-Joachim Timpe, Udo Dwars, Harald Baumann, Celin Savariar-Hauck
  • Patent number: 5849810
    Abstract: The invention relates to a novel process for the manufacture of mouldings, especially contact lenses, in which a soluble prepolymer comprising crosslinkable groups is crosslinked in solution, and also to mouldings, especially contact lenses, obtainable in accordance with that process. The present invention relates also to novel prepolymers that can be used in the process according to the invention, especially derivatives of a polyvinyl alcohol having a molecular weight of at least about 2000 that, based on the number of hydroxy groups of the polyvinyl alcohol, comprise from approximately 0.5 to approximately 80% of units of formula I ##STR1## wherein R is lower alkylene having up to 8 carbon atoms,R.sup.1 is hydrogen or lower alkyl andR.sup.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: December 15, 1998
    Assignee: CIBA Vision Corporation
    Inventor: Beat Muller
  • Patent number: 5849840
    Abstract: A dispersing stabilizer including (A) a polyvinyl alcohol resin containing oxyalkylene groups and having a surface tension of 35 to 55 dyne/cm at 20.degree. C. as a 1% by weight aqueous solution, or said resin and (B) a water-soluble polymer or a polyvinyl alcohol resin having a low degree of hydrolysis and a low degree of polymerization. When using the dispersing stabilizer of the present invention, both of a porosity and a bulk density of a polyvinyl resin particle can be improved at the same time, and, in addition, a distribution of particle size and a uniformity of porosity can be further improved.
    Type: Grant
    Filed: April 23, 1997
    Date of Patent: December 15, 1998
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Motokazu Maruhashi, Kizo Ohnishi
  • Patent number: 5849843
    Abstract: Multiple component polymer compositions for fabrication into articles. In particular, polymeric compositions comprising a heat resistant polymer; a radio frequency ("RF") susceptible polymer; a compatibilizing polymer; the composition having physical properties within the range a<40,000 psi; b>=70%; c<30%; d>1.0; e<0.1%; f<0.1%; g>=0.05; h<=60%; i=0; wherein: a is the mechanical modulus of the composition measured according to ASTM D-882; b is the percent recovery in length of the composition after an initial 20% deformation; c is the optical haze of the composition being 9 mils in thickness according to ASTM D-1003; d is the loss tangent of the composition at 1 Hz measured at melt processing temperatures; e is the elemental halogen content by weight of the composition; f is the low molecular weight water soluble fraction of the composition; g is the dielectric loss between 1 and 60 MHz and over temperatures of 25.degree. to 250.degree. C.
    Type: Grant
    Filed: November 16, 1993
    Date of Patent: December 15, 1998
    Assignee: Baxter International Inc.
    Inventors: Dean Laurin, Angeles Lillian Buan, Lecon Woo, Michael T. K. Ling, Yuan Pang Samuel Ding, William Anderson, Larry A. Rosenbaum, Denise S. Hayward, Joseph P. Hoppesch, Gregg Nebgen, Stanley Westphal
  • Patent number: 5837768
    Abstract: A creping adhesive containing about 1% to about 25% by weight solids comprising a multipolymer blend of polyoxazoline, polyethyleneimine, and modified polyethyleneimine, which imparts softness and resistance to bleaching, to a cellulosic web, and methods of using same are provided.
    Type: Grant
    Filed: February 5, 1997
    Date of Patent: November 17, 1998
    Assignee: Hercules Incorporated
    Inventors: Joseph F. Warchol, Cynthia D. Walton
  • Patent number: 5834556
    Abstract: In accordance with the present invention, there are provided methods to render cells non-adhesive and/or non-immunogenic with respect to macromolecules typically encountered in culture media or in physiological media.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: November 10, 1998
    Assignee: Vivorx, Inc.
    Inventors: Neil P. Desai, Patrick Soon-Shiong, Paul A. Sandford, Roswitha E. Heintz
  • Patent number: 5830956
    Abstract: The present invention relates to biodegradable polymers built-up ofa) monoethylenically unsaturated dicarboxylic acids and/or the salts thereof,b) monoethylenically unsaturated monocarboxylic acids and/or the salts thereof,c) monounsaturated monomers which, after hydrolysis, can be converted to monomers with a hydroxyl group covalently bonded to the C-C-chain, and, optionally,d) further radically copolymerizable monomers,with the sum of the monomers according to a) to d) amounting to 100%.The present invention further relates to a process of producing said polymers by radical polymerization and hydrolysis in aqueous medium, and to the use of said polymers as additive or cobuilder in detergents and cleaning agents, in the pretreatment of cotton, as bleaching stabilizers, as auxiliary agent in textile printing and in the manufacture of leather, as well as in the inhibition of water hardness and as dispersing agent.
    Type: Grant
    Filed: August 23, 1995
    Date of Patent: November 3, 1998
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Dolf Stockhausen, Frank Krause, Helmut Klimmek
  • Patent number: 5807927
    Abstract: A process for the production of mouldings, in particular contact lenses, in which a water-soluble, crosslinkable polymer is crosslinked in solution, and mouldings, in particular contact lenses, obtainable by this process; and novel water-soluble, crosslinkable polymers which can be employed in the crosslinking process, in particular those based on polyvinyl alcohol having a molecular weight of at least about 2000 which comprises units of the formulae: XI and XII, XI and XIII or XI, XII and XIII. In said Formulae, U is (a) or --Y--NH--CO--O--Z--O--CH.dbd.CH.sub.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: September 15, 1998
    Assignee: CIBA Vision Corporation
    Inventors: Friedrich Stockinger, Beat Muller
  • Patent number: 5792809
    Abstract: Disclosed herein is a polyvinyl alcohol shaped article which comprises a polyvinyl alcohol (A) and rubber particles (B), said rubber particles (B) comprising a rubber component having a glass transition temperature of 5.degree. C. or less and an average particle diameter of 5 .mu.m or less and a polyvinyl alcohol (C) being bonded to the surface of said rubber component, with the weight ratio of said rubber component on the basis of the total weight of said polyvinyl alcohols being in the range of 0.03 to 2. The polyvinyl alcohol shaped article of the present invention has a high impact strength at low temperatures and in low humidity, and also has a high strength and Young's modulus in high humidity, and has an excellent appearance.
    Type: Grant
    Filed: April 10, 1997
    Date of Patent: August 11, 1998
    Assignee: Kuraray Co., Ltd.
    Inventors: Masahiro Nagao, Masato Nakamae, Takeshi Kusudou, Hirotoshi Miyazaki
  • Patent number: 5783628
    Abstract: A modified polyvinyl alcohol is disclosed, which comprises the following structural units (I) and (II) and has a weight average molecular weight of from 3,000 to 400,000: ##STR1## wherein R.sup.1 represents H or CH.sub.3 ; and M.sup.1 represents H, an alkali metal, ammonium, alkylammonium, or alkanolammonium. The modified polyvinyl alcohol may be sulfonated. The modified polyvinyl alcohol is used as a dispersant such as a drilling fluid additive.
    Type: Grant
    Filed: March 7, 1996
    Date of Patent: July 21, 1998
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Akira Yada, Yoshihiro Kawamori, Hiroshi Nishiguchi, Akira Kitada, Yoshiyuki Mori
  • Patent number: 5753753
    Abstract: This invention relates to an improved process for producing a vinyl alcohol containing polymer having a narrow particle size without substantial reactor fouling. The process for producing the vinyl alcohol containing polymer involves hydrolyzing a vinyl ester containing polymer, e.g., a polymer containing polymerized vinyl alkanoate units in the presence of an alcoholic medium and a hydrolysis catalyst in the presence of an alcoholic medium having finely divided, inert material such as an alkali metal carbonate dispersed therein. The finely divided inert material acts as nucleating sites for the polyvinyl alcohol as it precipitates from the solution during hydrolysis.
    Type: Grant
    Filed: February 19, 1997
    Date of Patent: May 19, 1998
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Kien Van Phung, Dennis Sagl
  • Patent number: 5744546
    Abstract: Polymers containing a high percentage of vinyl alcohol units are difficult to process into sheet, film, injection-molded objects, or fibers. Such melt-processing is greatly enhanced by admixing certain hydrogenated block copolymers formed by sequential anionic polymerization of butadiene and styrene, followed by hydrogenation, then followed by grafting of maleic anhydride.
    Type: Grant
    Filed: February 7, 1997
    Date of Patent: April 28, 1998
    Assignee: Rohm and Haas Company
    Inventors: Thierry Christian Claude Diaz, Jean-Philippe Gaetan Meyer, Carlos Alfonso Cruz
  • Patent number: 5739208
    Abstract: A poly(ethylene glycol) derivative is disclosed that is activated with a sulfone moiety for selective attachment to thiol moieties on molecules and surfaces. The activated PEG is water soluble, hydrolytically stable for extended periods, and forms hydrolytically stable linkages with thiol moieties. The linkages generally are not reversible in reducing environments. The PEG derivative is useful for modifying the characteristics of substances including modifying biologically active molecules and surfaces for biocompatibility. Methods for synthesizing the active PEG and for preparing conjugates of the active PEG and other substances, including biologically active substances, are also disclosed.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 14, 1998
    Assignee: Shearwater Polymers, Inc.
    Inventor: J. Milton Harris
  • Patent number: 5712334
    Abstract: Disclosed are a lactone-modified polyvinyl alcohol and a process for the preparation thereof, a polymer composition, a permanently anti-electrostatic resin composition, a lactone-modified resin having hydroxyl groups, and a process for the preparation thereof. The lactone-modified polyvinyl alcohol can be used in wide fields owing to the capability of freely adjusting the water solubility, such as water-soluble, gradually water-soluble, low water-soluble, and water-insoluble by a degree modified by lactone compounds, and owing to possessing properties both of PVA and lactones. Furthermore, the lactone-modified polyvinyl alcohol has properties such as being plasticizers or softening agents, and as a result, there can be provided a polymer composition having excellent properties by mixing with a hydrophilic polymer or polar polymer.
    Type: Grant
    Filed: December 26, 1996
    Date of Patent: January 27, 1998
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Kazushi Watanabe, Takaaki Fujiwa, Tomohisa Isobe, Hiroshi Sagane
  • Patent number: 5658977
    Abstract: Cold water insoluble, hot water soluble and/or dispersible, disposable films, fabrics and other useful articles of manufacture are formed from a miscible polymeric resin blend comprised of cold water soluble partially hydrolyzed polyvinyl alcohol, cold water insoluble hot water disintegrable aliphatic polyester, and minor proportions of processing and performance aids. The aliphatic polyester has a melt temperature above the normal body temperature of a human (37 degrees C.; 98.6 degrees F.) and is present in the resin blend at a concentration sufficient to constitute the continuous phase of the blend, with the polyvinyl alcohol constituting a discontinuous phase of the blend. The aliphatic polyester thus renders the resin blend, and the partially hydrolyzed polyvinyl alcohol in the blend, cold water insoluble and determines the temperature at which articles formed from the blend will be subject to dissolution in an aqueous bath and subsequent disposal in an environmentally and ecologically sound fashion.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: August 19, 1997
    Assignee: Planet Polymer Technologies, Inc.
    Inventors: Xiaoming Yang, Robert J. Petcavich
  • Patent number: 5639525
    Abstract: The invention relates to a polymer compound for the production of sealing elements for vessel or container closures, which sealing elements when closed have a barrier effect preventing the penetration of gaseous or vaporous substances such as oxygen or aromatic compounds, in particular benzenes, phenyl ethers and suchlike into the vessel and/or show an excess pressure valve effect at interior vessel pressures of between approx. 3 and 10 bar and may be produced by mechanical forming of the unshaped thermally plastified polymer compound and its subsequent hardening directly on or in the vessel closure ("in shell" moulding), comprising a mixture of butyl and/or acrylate rubber and a polymer of an .alpha.-oleflnic unsaturated monomer as well as, if appropriate, one or several further polymer components and common additives such as glide enhancers, pigment, talcum and stabilizers. The invention further relates to a sealing element of this kind and a corresponding vessel or container closure.
    Type: Grant
    Filed: March 11, 1992
    Date of Patent: June 17, 1997
    Assignee: DS-Chemie GmbH
    Inventors: Tino Kuhn, Georg Schlenk
  • Patent number: 5635553
    Abstract: A resin composition including (A) a mixture of one or more polyamide resins and one or more ethylene/vinyl alcohol copolymers; (B) 2,2'-methylenebis(4-methyl-6-tert-butylphenol); and (C) at least one polyalkyleneglycol is provided. The resin composition exhibits improved flowability during processing and remarkably decreased possibility of fish eye gel formation, thereby allowing for the production of formed products having a good external appearance.
    Type: Grant
    Filed: April 17, 1996
    Date of Patent: June 3, 1997
    Assignees: Sumitomo Chemical Co., Ltd., Ube Industries, Ltd.
    Inventors: Kanako Fukuda, Tetsuo Yamaguchi, Michiaki Yoshidomi, Yutaka Yamaguchi
  • Patent number: 5612412
    Abstract: Disclosed are a lactone-modified polyvinyl alcohol and a process for the preparation thereof, a polymer composition, a permanently anti-electrostatic resin composition, a lactone-modified resin having hydroxyl groups, and a process for the preparation thereof.The lactone-modified polyvinyl alcohol can be used in wide fields owing to capability of freely adjusting a water solubility such as water-soluble, gradually water-soluble, low water-soluble, and water-insoluble by a degree modified by lactone compounds, and owing to possessing both properties in PVA and lactones.Furthermore, the lactone-modified polyvinyl alcohol has a property as plasticizers or softening agents, as a result, there can be provided a polymer composition having an excellent property by mixing with hydrophilic polymer or polar polymer.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 18, 1997
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Kazushi Watanabe, Takaaki Fujiwa, Tomohisa Isobe, Hiroshi Sagane
  • Patent number: 5594069
    Abstract: A process for producing mixed poly(vinyl acetals) containing butyral acetal groups and long chain acetal groups derived from one or more aldehydes containing at least six C atoms, by conducting an acetalization reaction forming long chain acetal groups in the substantial of absence butyraldehyde until gel break occurs, adding butyraldehyde after gel break and continuing acetalization until the desired reaction endpoint is reached. Reaction temperature is from about 40.degree. C. up to the boiling point of water at the pressure of the acetalization reaction and preferably between about 75.degree. C. and about 98.degree..
    Type: Grant
    Filed: February 17, 1995
    Date of Patent: January 14, 1997
    Assignee: Monsanto Company
    Inventors: Donald J. David, Nestor A. Rotstein
  • Patent number: 5587429
    Abstract: A processing aid system composition containing fluoropolymer processing aid, polar-side-group-containing extrusion adjuvant, and poly(oxyalkylene) polymer enhances extrusion of polyolefins.
    Type: Grant
    Filed: April 4, 1995
    Date of Patent: December 24, 1996
    Assignee: E. I. DuPont de Nemours and Company
    Inventor: Donnan E. Priester
  • Patent number: 5583163
    Abstract: The invention relates to a novel process for the manufacture of mouldings, especially contact lenses, in which a soluble prepolymer comprising crosslinkable groups is cross-linked in solution, and also to mouldings, especially contact lenses, obtainable in accordance with that process. The present invention relates also to novel prepolymers that can be used in the process according to the invention, especially derivatives of a polyvinyl alcohol having a molecular weight of at least about 2000 that, based on the number of hydroxy groups of the polyvinyl alcohol, comprise from approximately 0.5 to approximately 80% of units of formula I ##STR1## wherein R is lower alkylene having up to 8 carbon atoms,R.sup.1 is hydrogen or lower alkyl andR.sup.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: December 10, 1996
    Assignee: Ciba Geigy Corporation
    Inventor: Beat Muller
  • Patent number: 5561206
    Abstract: Disclosed is a copolymer represented by the following general formula (1): ##STR1## wherein R.sub.1 represents a group based on a polymer or a copolymer possessing electroconductivity and inducing coloration or discoloration on being oxidized or reduced, R.sub.2 and R.sub.3 represent independently a hydrogen atom or an alkyl group having 1 to 1,000 carbon atoms, A represents a group possessing polarity and exhibiting affinity for ions, and L and M are independently an integer of at least 1, providing that the total degree of polymerization is an integer in the range of 10 to 12,000. The copolymer may be a block copolymer or a random copolymer. This copolymer exhibits electrochromism and, therefore, is useful as a coloring-discoloring material which induces coloration or discoloration on being oxidized or reduced, particularly as an electrochromic substance used in an electrochromic display device.
    Type: Grant
    Filed: April 3, 1995
    Date of Patent: October 1, 1996
    Assignees: Yoshida Kogyo K.K., Takakazu Yamamoto
    Inventors: Takakazu Yamamoto, Masaki Wakabayashi
  • Patent number: 5559175
    Abstract: Preparation of polyvinyl acetals which can form emulsifier- and surfactant-free aqueous dispersions and redispersible dry powders and contain copolymeric polyvinyl acetals with, in amounts sufficient to form a dispersion, comonomer units carrying sulfo salt groups which are derived from copolymeric polyvinyl alcohol (PVALs) which contained comonomer units carrying sulfonate groups in the salt form. The preparation is carried out by acetalization of the starting polyvinyl alcohols to be used with aldehydes or aldehyde acetals under acid-catalyzed acetalization conditions in an aqueous medium, emulsifier-free stable aqueous polyvinyl acetal dispersions being obtained, from which dry redispersible polyvinyl acetal powders can be obtained by spray drying or freeze drying. The polyvinyl acetals according to the invention can be plasticized by mixing in plasticizers both in their aqueous dispersion form and in the dry powder form.
    Type: Grant
    Filed: February 24, 1995
    Date of Patent: September 24, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Matthias Kroggel, Hermann Schindler
  • Patent number: 5525665
    Abstract: A composition suitable for use as a binder of ceramic materials is disclosed. The improved binder contains substantially hydrolyzed copolymer made from monomers having ester or amide functional groups, poly(vinyl formamide) or a copolymer of vinyl alcohol and vinyl amine.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: June 11, 1996
    Assignee: Nalco Chemical Company
    Inventors: Kevin J. Moeggenborg, Peter E. Reed
  • Patent number: 5514736
    Abstract: Compositions of stabilized stereoregular polymers of branched higher alpha-olefins, grafting compounds, free radical generators, glass and epoxy resins and/or epoxy-functional silanes and/or hydroxy functional compounds are provided as well as methods for making these compounds and articles thereof.
    Type: Grant
    Filed: March 8, 1995
    Date of Patent: May 7, 1996
    Assignee: Phillips Petroleum Company
    Inventors: Edwin Boudreaux, Jr., Howard F. Efner, Mary J. Hagenson
  • Patent number: 5492953
    Abstract: Provided are resin compositions comprising the following (A), (B), (C), which is at least one member selected from (C.sub.1) through (C.sub.3) and (D):(A): a polyolefin,(B): a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 20 to 65 mol % and a saponification degree of vinyl acetate component of at least 96%,(C): (C.sub.1): at least one inorganic substance selected from titanium oxide, talc, calcium carbonate, mica and absorptive inorganic materials,(C.sub.2): at least one compound selected from the group consisting of metal salts of higher fatty acid having 8 to 22 carbon atoms, metal salts of ethylenediaminetetraacetic acid and hydrotalcite, and(C.sub.3): a polyolefin modified with an unsaturated carboxylic acid or derivatives thereof;and,(D): a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 68 to 98 mol % and a saponification degree of vinyl acetate component of at least 20%.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: February 20, 1996
    Assignee: Kuraray Co., Ltd.
    Inventors: Sumio Itamura, Tohei Moritani, Toshiaki Sato, Taichi Negi
  • Patent number: 5422395
    Abstract: A vinyl acetylsalicylate-vinyl alcohol based copolymer which comprises a structural unit having the following formula (1): ##STR1## and a structural unit having the following formula (2): ##STR2## optionally with at least one member selected from the group consisting of a structural unit having the following formula (3): ##STR3## and a structural unit having the following formula (4): ##STR4## In the copolymer, the amounts of vinyl acetylsalicylate units and vinyl alcohol units, degree of polymerization and the like can be controlled, whereby the efficacy of acetylsalicylic acid can be easily controlled as desired. Therefore, the copolymer is expected to be widely applicable as medicament.
    Type: Grant
    Filed: June 24, 1994
    Date of Patent: June 6, 1995
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Makoto Ooura, Yoshiro Onda, Kiyokazu Imai
  • Patent number: 5418285
    Abstract: Proposed is a novel vinyl chloride-based copolymeric resin suitable as an electron beam-curable binder resin for forming a magnetic recording layer of a magnetic recording medium. The binder resin is a vinyl chloride-based copolymeric resin containing monomeric units having a hydroxy group which is reacted with an ethylenically unsaturated monomeric compound having an isocyanato group in a molecule and then subjected to a modification reaction with an amine compound. The magnetic recording medium, e.g., magnetic recording tape, prepared by using the binder resin is excellent in the surface properties such as gloss and traveling resistance as well as in the magnetic properties such as residual magnetic flux density and squareness ratio of the magnetic hysteresis loop.
    Type: Grant
    Filed: July 8, 1993
    Date of Patent: May 23, 1995
    Assignee: Nissin Chemical Industry Co., Inc.
    Inventors: Masahiko Ikka, Tomoki Horiguchi, Yoshiyuki Yasuhara
  • Patent number: 5389709
    Abstract: Provided are resin compositions comprising the following (A), (B), (C), which is at least one member selected from (C.sub.1) through (C.sub.3), and (D):(A): a polyolefin,(B): a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 20 to 65 mol % and a saponification degree of vinyl acetate component of at least 96%,(C):(C.sub.1): at least one inorganic substance selected from titanium oxide, talc, calcium carbonate, mica and absorptive inorganic materials,(C.sub.2): at least one compound selected from the group consisting of metal salts of higher fatty acid having 8 to 22 carbon atoms, metal salts of ethylenediaminetetraacetic acid and hydrotalcite, and(C.sub.3): a polyolefin modified with an unsaturated carboxylic acid or derivatives thereof;and,(D): a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 68 to 98 mol % and a saponification degree of vinyl acetate-component of at least 20%.
    Type: Grant
    Filed: November 6, 1992
    Date of Patent: February 14, 1995
    Assignee: Kuraray Co., Ltd.
    Inventors: Sumio Itamura, Tohei Moritani, Toshiaki Sato, Taichi Negi
  • Patent number: 5380588
    Abstract: Provided are polyvinyl alcohol-based synthetic fiber having excellent performances as a fiber for FRC that is prepared by autoclave curing and its very effective production processes. One of the processes comprises having a monoaldehyde or a dialdehyde or its acetalization product penetrate into the central region of a polyvinyl alcohol-based synthetic fiber at a first stage and then, at a second stage, effecting crosslinking reaction with a mixed solution containing a monoaldehyde and an acid. The other process comprises conducting acetalization with a bath containing 100 to 250 g/l of formaldehyde and 30 to 80 g/l of sulfuric acid at a temperature of 70.degree. to 100.degree. C. The processes can give a polyvinyl alcohol-based synthetic fiber having a strength of at least 11 g/d, a gel elasticity of at least 6.0.times.10.sup.-3 g/cm.multidot.d and a dissolution ratio of not more than 40% and being able to withstand an autoclave curing at 140.degree. C.
    Type: Grant
    Filed: June 23, 1992
    Date of Patent: January 10, 1995
    Assignee: Kuraray Company Limited
    Inventors: Masakazu Nishiyama, Yasuhiro Harada, Akio Mizobe
  • Patent number: 5378759
    Abstract: Polymers containing a high percentage of vinyl alcohol units may be blended with copolymers of alkyl methacrylates and unsaturated organic acids and processed into sheet, film, fiber and other objects which exhibit an useful balance of barrier and strength properties.
    Type: Grant
    Filed: December 10, 1992
    Date of Patent: January 3, 1995
    Assignee: Rohm and Haas Company
    Inventors: Robert M. Amici, Edward E. LaFleur, William J. Work
  • Patent number: 5362802
    Abstract: Polymers containing a high percentage of vinyl alcohol units, especially when treated to remove impurities, when blended with copolymers of alkyl (meth)acrylates, N-vinyllactams or N-vinylamides, and unsaturated acids, preferably further with a small amount of plasticizer, may be applied as hot melt adhesives to paper, wood, and other cellulosic articles.
    Type: Grant
    Filed: March 18, 1994
    Date of Patent: November 8, 1994
    Assignee: Rohm and Haas Company
    Inventors: Robert M. Amici, Newman M. Bortnick, Roger K. Graham, Edward E. LaFleur, William J. Work
  • Patent number: 5362801
    Abstract: Polymers containing a high percentage of vinyl alcohol units, especially when treated to remove impurities, when blended with copolymers of alkyl (meth)acrylates, N-vinyllactams or N-vinylamides, and unsaturated acids, preferably further with a small amount of plasticizer, may be applied as hot melt adhesives to paper, wood, and other cellulosic articles.
    Type: Grant
    Filed: December 2, 1993
    Date of Patent: November 8, 1994
    Assignee: Rohm and Haas Company
    Inventors: Robert M. Amici, Newman M. Bortnick, Roger K. Graham, Edward E. LaFleur, William J. Work
  • Patent number: 5362803
    Abstract: Polymers containing a high percentage of vinyl alcohol units, when treated with acid to remove impurities, may be blended with low levels of copolymers of alkyl methacrylates and N-vinyllactams or N-vinylamides, optionally containing copolymerized acid, and processed into sheet, film, fiber and other objects which exhibit a useful balance of barrier and strength properties.
    Type: Grant
    Filed: July 16, 1993
    Date of Patent: November 8, 1994
    Assignee: Rohm and Haas Company
    Inventors: Edward E. LaFleur, Robert M. Amici, William J. Work
  • Patent number: 5356709
    Abstract: The present invention provides an improved coextruded medical grade port tubing. The medical grade port tubing provides characteristics that are desirable in the medical industry and therefore can be used as a medical port tubing in, for example, renal therapy or blood donor tubes. To this end, the present invention provides a non-PVC coextruded medical grade port tubing including: an outer layer comprising a blend of polypropylene copolymer and styrene-ethylene-butylene-styrene copolymer; a tie layer; and a core layer including a blend of polyamide and ethylene vinyl acetate.
    Type: Grant
    Filed: May 14, 1992
    Date of Patent: October 18, 1994
    Assignee: Baxter International, Inc.
    Inventors: Lecon Woo, Y. Wilson Cheung, Jerry D. Bartos, Michael T. K. Ling, Indrajit T. Patel, Ying-Cheng Lo
  • Patent number: 5354587
    Abstract: A fluid filtration material made of a porous substrate, e,g. a membrane or a fabric that is coated with a fluorinated copolymer that contains recurring vinyl alcohol units to impart hydrophilicity. The material is crosslinked with multifunctional epoxides to maintain hydrophilicity on exposure to heat or solvent.
    Type: Grant
    Filed: November 15, 1993
    Date of Patent: October 11, 1994
    Assignee: W. L. Gore & Associates, Inc.
    Inventor: Dilip R. Abayasekara
  • Patent number: 5352736
    Abstract: A liquid-absorbent composition comprising (a) a polymeric matrix component comprising crosslinked silanol moieties, and (b) a liquid-absorbent component comprising a water-absorbent polymer, preferably a water-soluble polymer. This composition is capable of forming liquid-absorbent, semi-interpenetrating polymeric networks, which are capable of absorbing significant quantities of those liquids that are solvents for the uncrosslinked portion of the network without loss of physical integrity and without leaching or other forms of phase separation. The compositions of this invention provides polymeric matrices which result in transparent coatings capable of providing improved combinations of ink absorption and durability, while at the same time retaining transparency and being amenable to the types of processing commonly used in producing transparent graphical materials.
    Type: Grant
    Filed: April 16, 1993
    Date of Patent: October 4, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: John J. Stofko, Jr., Mohammad Iqbal
  • Patent number: RE34988
    Abstract: A PVA film modified with anionic comonomers is provided for use as a water-soluble seal or pouch for alkaline or borate-containing cleaning compositions. The films comprise copolymers of 90-100% hydrolyzed vinyl alcohol with a nonhydrolyzable anionic comonomer, and have molecular weights characterized by a viscosity range of 4-35 cPs. The films are resistant to insolubilization caused by alkaline or borate-containing additives, are storage stable over a wide range of temperature and humidity storage conditions, rapidly and fully solubilize in a wash solution, and do not significantly impair cleaning performance of an additive enclosed within.
    Type: Grant
    Filed: December 4, 1991
    Date of Patent: July 4, 1995
    Assignee: The Clorox Company
    Inventors: Chihae Yang, Edward J. Kaufmann