With Saturated 1,2-epoxy Reactant Containing More Than One 1,2-epoxy Group Per Mole Or Polymer Derived Therefrom; Or With Solid Copolymer Derived From At Least One Unsaturated 1,2-epoxy Reactant Wherein The Epoxy Reactant Contains More Than One 1,2-epoxy Group Per Mole And At Least One Saturated Reactant Patents (Class 525/65)
  • Patent number: 4456732
    Abstract: A thermoplastic resin composition having improved weld strength, said composition consisting essentially of(A) 45 to 94.9% by weight of polycarbonate resin,(B) 5 to 40% by weight of a rubber-modified styrene-maleic anhydride copolymer resin, and(C) 0.1 to 15% by weight of an epoxy resin and/or a phenoxy resin.
    Type: Grant
    Filed: June 10, 1983
    Date of Patent: June 26, 1984
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Junji Nambu, Kenji Yoshino, Nagao Ariga, Kyotaro Shimazu, Hiroyuki Sato
  • Patent number: 4446258
    Abstract: Aqueous compositions suitable for sanitary can coatings comprising the neutralized water dispersible ionic polymer product of the reaction of an epoxy resin with acid polymer, and a different resin which is not necessarily self-dispersible in water, as well as several methods of preparing such compositions, are disclosed. The second resin which is not necessarily self-dispersible in water is introduced either preformed at any stage or is prepared, in situ, in the presence of the epoxy resin esterified with acid polymer either before the ionic epoxy resin-acid polymer product is dispersed in water. The epoxy resin-acid polymer product acts as a polymeric surfactant capable of keeping even a normally non self-dispersible second polymer in stable dispersion in water.
    Type: Grant
    Filed: December 30, 1982
    Date of Patent: May 1, 1984
    Assignee: Mobil Oil Corporation
    Inventors: Shaw C. Chu, Arthur T. Spencer
  • Patent number: 4444923
    Abstract: An improved process for preparing epoxy acrylate dispersions from the reaction product of an epoxy resin and carboxyl containing polymer in the presence of tertiary amine in which the carboxyl containing polymer is formed, in situ, in the presence of a solvent solution of the epoxy resin and then subjected to the esterification reaction which can be conducted in a single pot.
    Type: Grant
    Filed: December 30, 1982
    Date of Patent: April 24, 1984
    Assignee: Mobil Oil Corporation
    Inventor: William H. McCarty
  • Patent number: 4433088
    Abstract: Novel compositions are provided which comprise a polyphenylene ether, optionally a high impact polystyrene, optionally, an effective amount of an aromatic phosphate flame retardant, and a low molecular weight polymer selected from a polyolefin glycol or a polyamide, said composition being free from or excluding a substantial content of polyolefin, such as polyethylene. Such compositions when molded are readily paintable, and exhibit good adhesion between the paint and the molded compositions as distinguished from compositions containing polyolefins, such as polyethylene, which has been found to adversely affect paint adhesion. In addition, the novel compositions possess good or improved Izod and Gardner impact strengths, and in the case of polyolefin glycol, such as polyethylene glycol, the mutual solubility of all the components of the compositions is increased. Included within the disclosure of the invention are methods of preparing and molding such compositions and the molded products obtained therefrom.
    Type: Grant
    Filed: May 26, 1982
    Date of Patent: February 21, 1984
    Assignee: General Electric Company
    Inventors: William R. Haaf, James A. Huebner, Arthur Katchman
  • Patent number: 4413092
    Abstract: A polymer blend capable of being molded to an impact resistant, article which comprises a vinyl halide homopolymer or copolymer, a conventional impact resistant enhancing polymer agent for polyvinyl halide wherein the monomer units consist essentially of acrylonitrile, 1,3-butadiene and styrene residues and a thermoplastic block elastomer wherein the essential and predominant monomer units are the residue of a mono-alkenyl aromatic hydrocarbon and the residue of an alkadiene hydrocarbon. The thermoplastic elastomer is normally incompatible with the vinyl halide polymer or copolymer. The vinyl halide polymer or copolymer constitutes the major proportion of said blend and the block and methacrylate polymers together constitute a minor proportion of the composition. The weight ratio of block polymer to acrylonitrile-butadiene-styrene polymer is preferably about 1:5 to about 5:1.
    Type: Grant
    Filed: February 24, 1982
    Date of Patent: November 1, 1983
    Assignee: Occidental Chemical Corporation
    Inventor: Gilbert Witschard
  • Patent number: 4377663
    Abstract: A composition comprising a homogeneous blend of 95 to 5 parts by weight of an oxidation-curable type water-soluble resin and 5 to 95 parts by weight of a vinyl polymer obtained by polymerizing a vinyl monomer or monomers in the presence of a neutralized, water-soluble product of an adduct between a substantially amorphous polymer obtained by ring-opening polymerization of dicyclopentadiene and maleic acid or maleic anhydride. The composition is useful as a coating material, and has advantageous properties of both emulsions and water-soluble resins, such as good drying, good water resistance, good solvent resistance, good luster and good corrosion resistance.
    Type: Grant
    Filed: September 24, 1981
    Date of Patent: March 22, 1983
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventor: Hiroshi Wakabayashi
  • Patent number: 4348500
    Abstract: Described herein are molding compositions comprising a blend of (a) a polyarylate derived from a dihydric phenol and an aromatic dicarboxylic acid, (b) a polyester derived from an aliphatic or cycloaliphatic diol and at least one aromatic dicarboxylic acid, (c) an epoxide and, optionally, at least one thermoplastic polymer. An article molded from these compositions has a good balance of mechanical properties and improved hydrolytic stability.
    Type: Grant
    Filed: December 24, 1980
    Date of Patent: September 7, 1982
    Assignee: Union Carbide Corporation
    Inventors: Lloyd M. Robeson, Ted T. Szabo
  • Patent number: 4340523
    Abstract: A cathodic electrocoating composition containing a polyhydroxyamine dispersant and an epoxy reacted with an entity such as a fatty amine and optionally a crosslinker polymer.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: July 20, 1982
    Assignee: E. I. DuPont de Nemours and Company
    Inventor: Isidor Hazan
  • Patent number: 4338413
    Abstract: Thermoplastic blends comprising mixtures of dissimilar plastics and dissimilar rubbers are described; they are improved by incorporation of functionalized olefin polymer.
    Type: Grant
    Filed: October 16, 1980
    Date of Patent: July 6, 1982
    Assignee: Monsanto Company
    Inventors: Aubert Y. Coran, Raman Patel
  • Patent number: 4338235
    Abstract: A cationic electrocoating composition containing a polyhydroxyamine and acrylic or methacrylic polymers and optionally a crosslinker resin.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: July 6, 1982
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Isidor Hazan
  • Patent number: 4338236
    Abstract: An acrylic polyamine copolymer with amine and hydroxy functionality. The copolymer can be formulated with auxiliary resins and optional crosslinkers to make a nearly-neutral pH cathodic dispersion and the formulations can be used in cathodic electrodeposition, giving good cure response at 150.degree.-175.degree. C.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: July 6, 1982
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Isidor Hazan
  • Patent number: 4337187
    Abstract: A cationic electrocoating composition containing a polyhydroxyamine and polyesters or alkyds and optionally a crosslinker resin.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: June 29, 1982
    Assignee: E. I. DuPont de Nemours and Company
    Inventor: Isidor Hazan
  • Patent number: 4335031
    Abstract: A cationic electrocoating composition containing a polyhydroxyamine and polybutadiene and optionally a crosslinker resin.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: June 15, 1982
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Isidor Hazan
  • Patent number: 4317894
    Abstract: Coating compositions consist essentially of (a) ethylenically unsaturated monomers, (b) polyol-containing curable resins, (c) resins having ethylenic unsaturation and (d) solvent. The compositions are especially useful for the coating of products made from sheet molding compounds.
    Type: Grant
    Filed: December 11, 1979
    Date of Patent: March 2, 1982
    Assignee: PPG Industries, Inc.
    Inventors: Ronald J. Lewarchik, Betty J. Carter
  • Patent number: 4304698
    Abstract: An epoxy-modified polyolefin wax, which consists of a low-molecular-weight polyolefin grafted, copolymerized and modified with an epoxy group-containing, ethylenically unsaturated compound and has a number average molecular weight of from 600 to 10,000 and an epoxy equivalent of from 200 to 100,000, is disclosed.This epoxy-modified polyolefin wax is very valuable as a modifier for improving brittleness or adhesion (adhesiveness) in various resins, especially thermosetting resins.
    Type: Grant
    Filed: June 17, 1980
    Date of Patent: December 8, 1981
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Akihiro Tachi, Toru Tomoshige, Harumi Furuta, Norio Matsuzawa
  • Patent number: 4285847
    Abstract: Increasing the solids content of an aqueous dispersoid of:(a) a resin having aliphatic backbone carbons;(b) addition polymer, and(c) graft polymer consisting of addition polymer grafted to the aliphatic carbon atoms of said resin;which comprises bringing together ethylenically unsaturated monomer, initiator, and such dispersoid, and polymerizing the such monomer in situ.Preferred products produced are water-reducible epoxy resin-based. These are produced by a process which comprises initiating addition polymerization of ethylenically unsaturated monomer in the presence of such dispersoid.
    Type: Grant
    Filed: April 11, 1979
    Date of Patent: August 25, 1981
    Assignee: SCM Corporation
    Inventor: Vincent W. Ting
  • Patent number: 4283326
    Abstract: Poly (C.sub.2 -C.sub.4 alkylene terephthalate) molding composition containing mica and a multiphase composite polymer. The multiphase polymer has a first elastomeric phase polymerized from a monomer system including C.sub.1 -C.sub.6 alkyl acrylate as well as crosslinking and graftlinking monomers and has a final rigid thermoplastic phase polymerized in the presence of the elastomeric phase. Preferred compositions also include thermally stable reinforcing fibers such as glass fibers.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: August 11, 1981
    Assignee: GAF Corporation
    Inventors: John J. Charles, Robert C. Gasman
  • Patent number: 4277391
    Abstract: Poly (C.sub.2 -C.sub.4 alkylene terephthalate) molding composition containing three different types of antioxidants are disclosed.
    Type: Grant
    Filed: December 27, 1979
    Date of Patent: July 7, 1981
    Assignee: GAF Corporation
    Inventor: John J. Charles
  • Patent number: 4246089
    Abstract: A polyamine/epoxy ether graft copolymer having an acrylic polamine backbone with secondary amine and hydroxy functionality, part of which is terminal primary hydroxy groups, onto which is grafted an epoxy ether. The ether is an epoxy resin preferably reacted with nonylphenol resulting in a monoepoxide ether with one or less epoxy group per epoxy ether molecule. The ether is reacted with part of the secondary amine on the acrylic backbone. This system can be formulated to a nearly-neutral pH cathodic dispersion with good cure response at 150.degree.-175.degree. C. using conventional aminoplast crosslinkers.
    Type: Grant
    Filed: November 30, 1979
    Date of Patent: January 20, 1981
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Isidor Hazan
  • Patent number: 4245061
    Abstract: An epoxy-modified polyolefin wax, which consists of a low-molecular-weight polyolefin grafted, copolymerized and modified with an epoxy group-containing, ethylenically unsaturated compound and has a number average molecular weight of from 600 to 10,000 and an epoxy equivalent of from 200 to 100,000, is disclosed.This epoxy-modified polyolefin wax is very valuable as a modifier for improving brittleness or adhesion (adhesiveness) in various resins, especially thermosetting resins.
    Type: Grant
    Filed: December 11, 1978
    Date of Patent: January 13, 1981
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Akihiro Tachi, Toru Tomoshige, Harumi Furuta, Norio Matsuzawa
  • Patent number: 4204046
    Abstract: A pressure-sensitive adhesive composition based on liquid rubber, a cross-linking agent therefor and a tackifier, in which the liquid rubber component is a modified low molecular weight polyisoprene which is obtainable by adding 0.03 to 7 mol % of maleic anhydride or a derivative thereof, based on each isoprene monomer unit, to a low molecular weight polyisoprene having a molecular weight in the range of 10,000 to 90,000 is useful in producing a pressure-sensitive adhesive composition having very desirable tackiness, cohesive force and bonding characteristics without use of an organic solvent or with use of only a small amount of the solvent.
    Type: Grant
    Filed: January 10, 1979
    Date of Patent: May 20, 1980
    Assignee: Kuraray Company, Limited
    Inventors: Shobu Minatono, Hideo Takamatsu, Junnosuke Yamauchi, Katsuyoshi Terao
  • Patent number: 4195134
    Abstract: Polyester compositions comprising a blend of poly (C.sub.2 -C.sub.4 alkylene terephthalate) with a diepoxy compound and a multiphase composite polymer are disclosed. The multiphase polymer has a first elastomeric phase polymerized from a monomer system including C.sub.1 -C.sub.6 alkyl acrylate as well as crosslinking and graft-linking monomers and a final rigid thermoplastic phase polymerized in the presence of the elastomeric phase.
    Type: Grant
    Filed: December 21, 1978
    Date of Patent: March 25, 1980
    Assignee: GAF Corporation
    Inventor: Ernest A. Coleman