With Saturated 1,2-epoxy Reactant Containing More Than One 1,2-epoxy Group Per Mole Or Polymer Derived Therefrom; Or With Solid Copolymer Derived From At Least One Unsaturated 1,2-epoxy Reactant Wherein The Epoxy Reactant Contains More Than One 1,2-epoxy Group Per Mole And At Least One Saturated Reactant Patents (Class 525/65)
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Patent number: 4939201Abstract: Thermoplastic molding compositions based on thermoplastic polyesters (a.sub.1), graft polymers incorporating acrylate rubbers as grafting bases (a.sub.2), copolymers of aromatic vinyl monomers and acrylonitrile or methacrylonitrile (a.sub.3) which contain a polymeric component (B) having carboxyl, carboxyl derivative, hydroxyl or epoxy groups or, alternatively, where graft polymers (a.sub.2) or copolymers (a.sub.3) carry such groups have a balanced range of properties.Type: GrantFiled: October 7, 1988Date of Patent: July 3, 1990Assignee: BASF AktiengesellschaftInventors: Erhard Seiler, Karl Ruppmich, Manfred Knoll, Walter Heckmann, Dietrich Lausberg, Rainer Bueschl
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Patent number: 4933380Abstract: An air-drying aqueous coating composition for eletrodeposition comprising[A] water-solubilized product or a water-dispersed product obtained by reacting (A-1) an epoxy resin and (A-2) a maleinized product of a (semi)drying oil fatty acid-modified vinyl polymer having an acid value of 10 to 200 in such proportions that the solids weight ratio of the component (A-1) to the component (A-2) is from 90/10 to 5/95, and[B] an amphoteric organic solvent having affinity for component [A].Type: GrantFiled: September 1, 1989Date of Patent: June 12, 1990Assignee: Kansai Paint Co.Inventors: Tetsuo Aihara, Yasuharu Nakayama, Shigeki Matsubara
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Patent number: 4929665Abstract: A resin composition comprising (a) 100 parts by weight of a block copolymer composed of polyphenylene sulfide segments and polyphenylene sulfide sulfone segments and (b) 0.01 to 20 parts by weight of at least one compound selected from the group consisting of epoxy resins, maleimide compounds, N,N'-diarylcarbodiimide compounds and organosilane compounds and as required, (c) an organic filler.Type: GrantFiled: January 19, 1988Date of Patent: May 29, 1990Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Toshio Inoue, Takayuki Mine, Hitoshi Izutsu, Toshihide Yamaguchi, Fumihiro Kobata, Juheiji Kawabata
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Patent number: 4916174Abstract: A rubber-modified phenolic resin composition contains a novolak-type phenolic resin in which at least one modifying agent selected from the group consisting of an ABS resin and an MBS resin is homogeneously dispersed. The composition has good impact resistance and thermal shock resistance. The composition is prepared by adding at least one modifying agent described above to a novolak-type phenolic resin which is heated and melted at its softening point or more, so that the modifying agent is homogeneous dispersed in the resin. The resin composition is suitably used as a curing agent for an epoxy resin encapsulant for sealing electronic devices.Type: GrantFiled: September 13, 1988Date of Patent: April 10, 1990Assignees: Kabushiki Kaisha Toshiba, Toshiba Chemical CorporationInventors: Akira Yoshizumi, Shinetsu Fujieda, Ken Uchida, Naoko Kihara, Kazuhiro Sawai, Tsutomu Nagata, Shinji Murakami, Shigeyuki Kouchiyama
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Patent number: 4914153Abstract: A polyphenylene ether resin composition having improved solvent resistance comprising (A) a modified polyphenylene ether obtained by modifying a polyphenylene ether with a modifier such as maleic anhydride and (B) a modified polyolefin obtained by modifying a polyolefin with both a modifier such as maleic anhydride and a vinyl or vinylidene compound such as styrene, and optionally (C) a binder such as phenylenediamine.Type: GrantFiled: November 17, 1987Date of Patent: April 3, 1990Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Shizuo Togo, Akikazu Amagai, Yoshinori Kondo, Toshiaki Yamada
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Patent number: 4894413Abstract: Improvement in the method for preparing resin compositions for use as a laminate material in printed wiring boards wherein the resin composition is formed by mixing an epoxy-anhydride prepolymer with maleated polybutadiene and a suitable solvent. The improvement involves preparing the epoxy-anhydride prepolymer using a two step procedure instead of a single step. The two step procedure prevents uncontrolled exothermic reactions from occurring during preparation of commercial quantities of the epoxy-anhydride prepolymer and increases the versatility of the process since different anhydrides can be used in each of the two steps.Type: GrantFiled: October 9, 1987Date of Patent: January 16, 1990Assignee: Hughes Aircraft CompanyInventors: Ephraim H. Catsiff, William E. Elias
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Patent number: 4880866Abstract: Novel thermoplastic polyester compositions having improved impact behavior are produced. These compositions comprise a blend of poly (C.sub.2 -C.sub.4 alkylene terephthalate) with certain low molecular weight diepoxide resins, a triphenyl phosphonium halide catalyst, and a multiphase composite polymer. The multiphase polymer has a first elastomeric phase polymerized from a monomer system including butadiene or butadiene/styrene and a final rigid thermoplastic phase polymerized in the presence of the elastomeric phase.Type: GrantFiled: June 17, 1987Date of Patent: November 14, 1989Assignee: Hoechst CelaneseInventors: Donal McNally, H. Leslie LaNieve, Jerome L. Costanzo
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Patent number: 4879337Abstract: A higher solid coating composition comprises a solid resin mixture of polyol resin and alkyletherified melamine resin, 0.2.about.10 parts by weight of an aliphatic sulfonic acid compound and 1.about.100 parts by weight of a non-aqueous polymer dispersion based on 100 parts by weight of the resin mixture. The non-aqueous polymer dispersion consists of (a) organic solvent component, (b) particle component insoluble in the component (a), and (c) particular dispersion stabilizer component soluble in the component (a) and capable of stably dispersing the component (b) into the component (a).Type: GrantFiled: November 2, 1987Date of Patent: November 7, 1989Assignee: Nippon Oil and Fats Co., Ltd.Inventors: Kishio Shibato, Masataka Kawamura
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Patent number: 4876295Abstract: Flexible thermoplastic epoxy resins are prepared by reacting (1) an advanced epoxy resin prepared by reacting a mixture of an aromatic based epoxy resin and an aliphatic based epoxy resin with a polyhydric phenol in the presence of an advancement catalyst with (2) a monocarboxylic acid or anhydride thereof; reacting the resultant product with a mixture of an armotic based epoxy resin and a monofunctional material reactive with vicinal epoxy groups; and reacting the resultant product with a carboxyl terminated elastomer. These resins are particularly useful in formulating pavement marking paints.Type: GrantFiled: April 18, 1988Date of Patent: October 24, 1989Assignee: The Dow Chemical CompanyInventors: Michael B. Cavitt, David J. Duncan
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Patent number: 4863988Abstract: A composition for curable paints, comprising(A) 100 parts by weight of a resin for curable paints, and(B) 0.5 to 10 parts by weight of chlorinated and graft-modified polypropylene which is produced by chlorinating polypropylene graft-modified with a grafting component selected from the group consisting of alpha,beta-unsaturated dicarboxylic acids, anhydrides thereof and esters thereof, and which has a chlorine content of 5 to 50% by weight, said graft-modified polypropylene having a degree of saponification of 5 to 150 mg/g and an intrinsic viscosity [.eta.] of 0.1 to 5 dl/g. A curable paint comprising the composition and a diluent.Type: GrantFiled: October 13, 1988Date of Patent: September 5, 1989Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Hajime Inagaki, Tadao Saitoh
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Patent number: 4855355Abstract: A molding resin composition comprising (A) a saturated polyester resin, (B) a graft copolymer and (C) a rubber-reinforced resin, wherein a weight ratio of the saturated polyester resin (A) to a total weight of the graft copolymer (B) and the rubber-reinforced resin (C) is from 95:5 to 5:95, a weight ratio of the graft copolymer (B) to the rubber-reinforced resin is from 100:0 to 5:95, and the graft copolymer (B) is one prepared by copolymerizing an unsaturated epoxide monomer and at least one monomer selected from the group consisting of aromatic vinyl monomers, cyanated vinyl monomers and alkyl unsaturated carboxylates in the presence of an ethylene-.alpha.-olefin base rubber, which can provide a molded article having improved impact strength, weld strength, stiffness and mold shrinkage factor.Type: GrantFiled: March 28, 1988Date of Patent: August 8, 1989Assignee: Sumitomo Naugatuck Co., Ltd.Inventors: Mikio Hirai, Tokuo Tatsuda, Tomio Yoshida
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Patent number: 4853433Abstract: Epoxy resin materials essentially contain(A) an epoxy resin having a mean molecular weight of from 300 to 6,000 and on average from 1.5 to 3.0 epoxy groups in the molecule and(B) a polyacrylate resin obtainable by polymerization of essentially(b.sub.1) from 30 to 95% by weight of esters of acrylic acid and/or methacrylic acid and/or ethylacrylic acid with C.sub.1 -C.sub.20 -alcohols in the presence of(b.sub.2) from 5 to 70% by weight of carboxyl-containing copolymers having a mean molecular weight of from 500 to 20,000, obtainable by bulk or solution polymerizationand are used for heat-curable finishes, adhesive bonds and coatings.Type: GrantFiled: April 1, 1988Date of Patent: August 1, 1989Assignee: BASF AktiengesellschaftInventors: Rainer Blum, Gerd Rehmer, Rolf Osterloh, Hans Sander
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Patent number: 4846905Abstract: Disclosed is a thermally-curable, one-part epoxy adhesive composition comprising: (1) a glycidyl ether epoxide having a048477475 n epoxy functionality grater than one and a molecular weight between about 150 and 10,000; (2) a catalyst comprising (i) an acid of the formula H.sup.+ SbF.sub.5 X.sup.- wherein X is halogen, hydroxy, or --OR where --OR is the residue of an aliphatic or aromatic alcohol having a molecular weight less than about 10,000 and (ii) N,N-diethyl-o-toluidine; (3) an aliphatic or non-aromatic cyclic polyol having about 2 to 18 carbon atoms, at least two hydroxy groups of which are primary or secondary, and being free of electron-withdrawing substituents, amine substituents, or large substituents that cause steric hindrance in the .alpha.-position in relation to the carbon attached to the methylol group of the polyol; and (4) a toughening agent that does not react with the epoxide during curing and has an epoxide compatible component and an epoxide incompatible component.Type: GrantFiled: April 6, 1988Date of Patent: July 11, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kent S. Tarbutton, Janis Robins
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Patent number: 4837273Abstract: The present invention relates to new binder combinations comprising(A) 99-30 parts by weight of OH-functional graft copolymer resins prepared by copolymerization of a polybutadiene having a molecular weight of from 500 to 10000 and containing more than 30% of 1,2-vinyl structure with selected olefinically unsaturated monomers and(B) 1 to 70 parts by weight of a multifunctional crosslinking resin, preferably a polyisocyanate resin. The new binder combinations are suitable for preparing coatings having a very high level of elasticity and an excellent surface hardness.Type: GrantFiled: February 8, 1988Date of Patent: June 6, 1989Assignee: Bayer AktiengesellschaftInventors: Christian Wamprecht, Manfred Schonfelder, Peter Hohlein, Lothar Kahl
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Patent number: 4837248Abstract: Flexible thermoplastic epoxy resins are prepared by reacting (1) an advanced epoxy resin prepared by reacting a mixture of an aromatic based epoxy resin and an aliphatic based epoxy resin with a polyhydric phenol in the presence of an advancement catalyst with (2) a monocarboxylic acid or anhydride thereof; reacting the resultant product with a mixture of an aromatic based epoxy resin and a monofunctional material reactive with vicinal epoxy groups; and reacting the resultant product with a carboxyl terminated elastomer. These resins are particularly useful in formulating pavement marking paints.Type: GrantFiled: April 18, 1988Date of Patent: June 6, 1989Assignee: The Dow Chemical CompanyInventors: Michael B. Cavitt, David J. Duncan
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Patent number: 4812513Abstract: An epoxy resin composition comprising:(A) 1 to 40 parts by weight of a modified low molecular weight polyolefin obtained by graft copolymerizing at least one graft monomer selected from the group consisting of:(i) at least one unsaturated carboxylic acid derivative selected from the group consisting of unsaturated carboxylic acids and anhydrides thereof and esters thereof,(ii) at least one aromatic vinyl compound, and(iii) at least one nitrile compound, onto a low molecular weight polyolefin having an inherent viscosity [.eta.] of 0.01 dl/g to 1.0 dl/g, as measured in decalin at a temperature of 135.degree. C.,(B) 99 to 60 parts by weight of an epoxy resin (the total amount of (A) and (B) is 100 parts by weight),(C) a hardener for epoxy resin, and optionally(D) 0.01 to 20 parts by weight of a monoamine compound.Type: GrantFiled: February 16, 1988Date of Patent: March 14, 1989Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Toshiyuki Hirose
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Patent number: 4801645Abstract: Thermoplastic resin composition is provided which comprises epoxy compound in a resin made from polyphenylene ether and modified-polyolefin with or without polypropylene. The composition is useful for preparing shaped articles, sheet or film and is superior in heat resistance, mechanical properties and processability.Type: GrantFiled: March 18, 1987Date of Patent: January 31, 1989Assignee: Sumitomo Chemical Company, Ltd.Inventors: Taichi Nishio, Takashi Sanada, Takayuki Okada
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Patent number: 4798761Abstract: Compositions comprising a mixture of (A) an epoxy resin composition consisting essentially of (1) at least one epoxy resin which has an average of not more than 2 vicinal epoxy groups per molecule; (2) at least one epoxy resin which has an average of more than 2 vicinal epoxy groups per molecule and (3) at least one rubber or elastomer; and (B) optionally, a low viscosity reactive diluent, are useful in preparing low temperature curable compositions. Also claimed is low temperature curable compositions containing the above components (A) and (B); (C) at least one cycloaliphatic amine hardener and (D) optionally, an accelerator for component (D).Type: GrantFiled: November 3, 1987Date of Patent: January 17, 1989Assignee: The Dow Chemical CompanyInventors: Paul L. Wykowski, Paul M. Puckett
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Patent number: 4790948Abstract: Lubricating oils of improved properties contain a terpolymer of glycidyl methacrylate, lauryl methacrylate, and stearyl methacrylate which has been functionalized or coupled with phenothiazine and with N-methyl piperazine.Type: GrantFiled: October 14, 1986Date of Patent: December 13, 1988Assignee: Texaco Inc.Inventors: Christopher S. Liu, William P. Hart, Maria M. Kapuscinski
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Patent number: 4787703Abstract: Epoxy-grafted, low molecular weight amorphous polymer compositions are employed in pourable, liquid telecommunication cable encapsulation compositions. Also disclosed is a method for encapsulating telecommunication cables as well as cables encapsulated with such an epoxy-grafted liquid encapsulant.Type: GrantFiled: June 4, 1987Date of Patent: November 29, 1988Assignee: Uniroyal Chemical Company, Inc.Inventors: Richard F. Tomko, Revati Ranganathan, William D. Sigworth, Dong-Hak Bae
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Patent number: 4780507Abstract: There is disclosed a thermosetting resin composition comprising a thermosetting cyanate ester resin composition (A) and a butadiene based copolymer (B)(i) or an epoxy resin-modified butadiene based copolymer (B)(ii), in which said component (B)(i) or (B)(ii) are used for modifying said component (A), component (A) and (B) being as follows;(A) a cyanate ester thermosetting resin composition comprising a cyanate ester compound selected from the group consisting of,(i) a polyfunctional cyanate ester having at least two cyanate group in its molecule,(ii) prepolymer of the cyanate ester of (i),(iii) coprepolymer of the cyanate ester of (i) and an amine, and(iv) mixtures thereof, and optionally adding another thermosetting resin,(B)(i) a butadiene based copolymer comprising a butadienaromatic vinytl monomer copolymer having 0.Type: GrantFiled: November 14, 1986Date of Patent: October 25, 1988Assignees: Mitsubishi Gas Chemical Co. Inc., Nippon Soda Co. LtdInventors: Morio Gaku, Hidenori Kimbara, Hiroo Muramoto, Shiro Higashida, Fumio Sato
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Patent number: 4778851Abstract: Epoxy resins contain a discontinuous phase dispersed therein, of grafted rubber particles having an insoluble rubber core and having a grafted shell containing a functionalized compound such as that provided by polymerized glycidyl methacrylate, which is reactive under curing conditions with a functionality of the epoxy resin phase. The dispersions are stable and are useful as curable coatings, and for providing toughened resins for structural applications.Type: GrantFiled: January 12, 1987Date of Patent: October 18, 1988Assignee: The Dow Chemical CompanyInventors: David E. Henton, Dale M. Pickelman, Charles B. Arends, Victor E. Meyer
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Patent number: 4771106Abstract: An adhesive resin composition is described, comprising: (A) a thermoplastic copolyester resin prepared from (1) a dicarboxylic acid component comprising from 40 to 100 mol % of terephthalic acid and from 0 to 60 mol % of other aromatic dicarboxylic acid and (2) a low molecular weight glycol component comprising from 40 to 100 mol % of 1,4-butanediol and from 0 to 60 mol % of diethylene glycol or 1,6-hexanediol and further from 0 to 10 mol %, based on the total carboxylic acid, of polytetramethylene glycol having a molecular weight of from 600 to 6,000, which has a melting point of from 90.degree. to 160.degree. C. and a reduced viscosity of at least 0.5; and (B) an ethylene copolymer having at least one functional group selected from an epoxy group, a carboxylic acid group, and a dicarboxylic anhydride group; and if desired, (C) a thermoplastic resin other than the resin (A), and if further desired, (D) a polyfunctional epoxy compound.Type: GrantFiled: September 21, 1987Date of Patent: September 13, 1988Assignees: Sumitomo Chemical Co., Ltd., Toyobo Co., Ltd.Inventors: Tadayuki Ohmae, Mitsuyuki Okada, Hiroshi Nagai, Yutaka Mizumura
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Patent number: 4735992Abstract: Polymers resulting from the association of two reactive components having a low melt viscosity, characterized in that one of the components is a polypropylene modified by grafting an unsaturated monomer bearing an acid anhydride group and the other is a compound R posessing at least two groups which are reactive towards this anhydride group.Uses in the manufacture of moulded articles by the reaction-injection-moulding technique, or in the manufacture of composite materials.Uses as coatings for metallic articles.Type: GrantFiled: December 3, 1986Date of Patent: April 5, 1988Assignee: Societe AtochemInventor: Pierre Nogues
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Patent number: 4732937Abstract: Epoxide-functionalized polyphenylene ethers, which may be prepared by the reaction of various acid-functionalized polyphenylene ethers with functionalized epoxides, are useful in the preparation of polyphenylene ether copolymers. These copolymers are, in turn, useful for the compatibilization of blends of polyphenylene ethers with such other polymers as polyesters and polyamides.Type: GrantFiled: July 14, 1986Date of Patent: March 22, 1988Assignee: General Electric CompanyInventor: Paul D. Sybert
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Patent number: 4720516Abstract: A polyolefin resin composition comprising a polyolefin modified with an unsaturated carboxylic acid, at least one member selected from the group consisting of polyepoxides, polyisocyanates, and polyamines, and a reinforcement.Type: GrantFiled: December 16, 1982Date of Patent: January 19, 1988Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Kazuo Kishida, Isao Sasaki, Hiroshi Mori, Yasuaki Ii
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Patent number: 4719263Abstract: Thermoplastic and thermoset materials containing an effective amount of an antistatic agent for improving antistatic properties thereof, the antistatic agent is selected from homopolymers and copolymers of an epihalohydrin.Type: GrantFiled: May 10, 1985Date of Patent: January 12, 1988Assignee: The B. F. Goodrich CompanyInventors: James P. Barnhouse, Simon H. Yu
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Patent number: 4688054Abstract: A liquid jet recording head has a liquid passage communicated to the discharging outlet of the liquid provided on a substrate surface, said passage being formed by subjecting a layer of a resin composition curable with an active energy ray to a predetermined pattern exposure with the use of said active energy ray to thereby form a cured region of said resin composition and removing the uncured region from said layer, said resin composition comprising the component (i) shown below and at least one of the components (ii) and (iii) shown below:(i) a graft copolymerized polymer comprising a trunk chain composed mainly of structural units derived from at least one monomer selected from the group consisting of alkyl methacrylate, acrylonitrile and styrene, having graft chains composed mainly of structural units derived from at least one monomer selected from the group consisting of (A) hydroxyl containing acrylic monomers, (B) amino or alkylamino containing acrylic monomers, (C) carboxylic containing acrylic or vinType: GrantFiled: June 30, 1986Date of Patent: August 18, 1987Assignee: Canon Kabushiki KaishaInventors: Tadayoshi Inamoto, Hiromichi Noguchi, Megumi Munakata
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Patent number: 4683264Abstract: (1) A hardenable coating composition for polypropylene resins, having a chlorinated polyolefin as a principal constitutional element provided partially a crosslinking reaction beforehand between carboxyl group or acid anhydride group of a chlorinated polyolefin (I) obtained by chlorinating, to a degree within a range from 10 wt % to 50 wt %, a polyolefin which is modified with one or two or more types of compounds selected from a group consisting of unsaturated polycarboxylic acids or their acid anhydrides and has a saponification value ranging from 6 to 60, and epoxy group of a compound or a resin (II) which has at least two epoxy groups per molecule.(2) A hardenable coating composition for polypropylene resins described in claim 1, wherein the weight ratio of chlorinated polyolefin (I) to the compound or the resin (II) which has epoxy groups is 100:0.5-50.Type: GrantFiled: April 8, 1986Date of Patent: July 28, 1987Assignee: Sanyo-Kokusaku Pulp Co., Ltd.Inventors: Keiji Urata, Yoshio Kurome
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Patent number: 4668736Abstract: An epoxy resin composition is provided. This composition contains (a) a curable glycidyl ether epoxide group-containing material, (b) an amino- terminated aliphatic polyether curing agent, (c) a polymeric toughening agent having both a rubbery phase and a thermoplastic phase or being capable of forming, with the epoxide group-containing material, both a rubbery phase and a thermoset phase on curing, and (d) a metal salt catalyst capable of providing an exotherm of at least 20.degree. C.Type: GrantFiled: March 21, 1986Date of Patent: May 26, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventors: Janis Robins, Charles D. Wright
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Patent number: 4661559Abstract: Described herein is a composition which contains a specific group of hardeners, an epoxy resin and a thermoplastic polymer. When combined with a structural fiber the composition produces composites which have improved impact resistance, improved tensile properties and high compressive properties.Type: GrantFiled: January 10, 1985Date of Patent: April 28, 1987Assignee: Union Carbide CorporationInventors: Hugh C. Gardner, Michael J. Michno, Jr., George L. Brode, Robert J. Cotter
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Patent number: 4657971Abstract: A modified block copolymer composition comprising a thermoplastic polymer and a modified block copolymer consisting essentially of a base block copolymer of a monovinyl substituted aromatic hydrocarbon polymer block and an olefin compound polymer block having an ethylenic unsaturation degree not exceeding 20%, the base block copolymer having a molecular unit containing a carboxylic acid group and/or a group derived therefrom grafted thereto. The modified block copolymer composition of the present invention is a resinous composition excellent in impact resistance, adhesion, paint adhesion, weatherability, resistance to thermal deterioration, transparency and gloss or a rubbery or leather-like composition excellent in heat resistance, abrasion resistance, compression set resistance, adhesion, transparency, oil resistance, weatherability and resistance to heat aging.Type: GrantFiled: August 26, 1985Date of Patent: April 14, 1987Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Toshinori Shiraki, Fusakazu Hayano, Hideo Morita
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Patent number: 4657970Abstract: A modified block copolymer composition comprising a thermoplastic polymer and a modified block copolymer consisting essentially of a base block copolymer of a monovinyl substituted aromatic hydrocarbon polymer block and an olefin compound polymer block having an ethylenic unsaturation degree not exceeding 20%, the base block copolymer having a molecular unit containing a carboxylic acid group and/or a group derived therefrom grafted thereto. The modified block copolymer composition of the present invention is a resinous composition excellent in impact resistance, adhesion, paint adhesion, weatherability, resistance to thermal deterioration, transparency and gloss or a rubbery or leather-like composition excellent in heat resistance, adrasion resistance, compression set resistance, adhesion, transparency, oil resistance, weatherability and resistance to heat aging.Type: GrantFiled: August 26, 1985Date of Patent: April 14, 1987Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Toshinori Shiraki, Fusakazu Hayano, Hideo Morita
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Patent number: 4645803Abstract: New and improved heat curable compositions are disclosed comprising epoxidic resin(s) and aromatic ether-sulfone polyamines, alone or in combination with other diamine curing agents and/or curing catalysts alone, or in further combination with reinforcements, e.g., graphite fibers and, optionally modified with second resins. The cured neat resins and fiber resin matrix compositions exhibit high toughness, compression strength and short beam shear strength under dry, wet and hot/wet conditions.Type: GrantFiled: February 29, 1984Date of Patent: February 24, 1987Assignee: American Cyanamid CompanyInventors: Dalip K. Kohli, Michael M. Fisher
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Patent number: 4642325Abstract: A cathode-depositing electrodeposition coating composition having excellent low-temperature curability comprising as essential ingredients(A) 100 parts by weight of a reaction product of (1) a high molecular compound having a molecular weight of 500 to 5,000 and containing carbon-carbon double bonds with an iodine number of 50 to 500 and 3 to 12% by weight of oxirane oxygen, and (2) 30 to 300 millimoles, per 100 g of the high molecular compound (1), of a specified amine compound,(B) 10 to 200 parts by weight of a reaction product of a specified diglycidyl compound with 1.9 to 2.1 moles, per molecule of the diglycidyl compound, of an alpha, beta-unsaturated carboxylic acid or an unsaturated fatty acid having a molecular weight of 100 to 350 and containing at least 10% by weight of a carbon-carbon double bond, or a mixture of both,(C) 0.Type: GrantFiled: April 5, 1985Date of Patent: February 10, 1987Assignee: Nippon Oil Company, Ltd.Inventors: Yutaka Otsuki, Hiroyoshi Omika, Akio Oshima, Yoshihiko Araki, Yasuyuki Tsuchiya
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Patent number: 4629760Abstract: A composition comprisinga. a major amount of an aromatic polycarbonate;b. a minor quantity of a polyester selected from polyalkylene terephthalate and polycycloalkylene terephthalate, isophthalate or a mixture of the two acids;c. a minor quantity of an elastomeric acrylate copolymer with a second order transition temperature, Tg, of less than -10.degree. C. and phenoxy resin effective to significantly maintain the impact strength and ductility at break after exposing a stressed part to brake fluid comprising alcohols and ethers.Type: GrantFiled: November 1, 1985Date of Patent: December 16, 1986Assignee: General Electric CompanyInventors: Ping Y. Liu, Harold F. Giles, Jr.
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Patent number: 4607079Abstract: A composition comprising a major amount of an aromatic polycarbonate and quantities of both an acrylate elastomeric copolymer with a second order transition temperature, Tg, of less than -10.degree. C. and a phenoxy resin effective to substantially maintain the impact strength and ductility at break after exposing a stressed part to brake fluid comprising alcohols and ethers.Type: GrantFiled: June 24, 1985Date of Patent: August 19, 1986Assignee: General Electric CompanyInventors: Harold F. Giles, Jr., Ping Y. Liu
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Patent number: 4600648Abstract: Disclosed is a hot-melt adhesive composed of a composition comprising an acid-modified olefin resin formed by graft modification of an ethylenically unsaturated carboxylic acid or its anhydride or a resin composition containing said modified olefin resin and an oxirane ring-containing compound, wherein said composition has a carbonyl group concentration of 1 to 600 millimoles per 100 g of the composition and an oxirane oxygen concentration of 0.01 to 50 millimoles per 100 g of the composition.Type: GrantFiled: April 23, 1985Date of Patent: July 15, 1986Assignee: Toyo Seikan Kaisha, Ltd.Inventors: Jinichi Yazaki, Kozaburo Sakano, Junichi Matsuo
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Patent number: 4595716Abstract: Provides new and improved water-reducible coating compositions and methods of making them. Three preferred processes are disclosed. These differ in the manner of incorporating and chemical nature of an extender polymer.Broadly, the process of the invention is one for forming an aqueous dispersion of a fluent resinous composition ofa. a mixture in an organic solvent of(i) an ionizable graft polymer of an epoxy resin and an addition polymerized resin, the addition polymerized resin being bonded to aliphatic backbone carbon atoms of the epoxy resin by carbon-to-carbon bonds, and(ii) an extender resin;b. an aqueous vehicle, andc. an ionizing agent;the ionization present from said combined components being sufficient to establish the components as a dispersion in the aqueous vehicle, and then addition polymerizing a quantity of addition polymerizable monomer, under addition polymerizing conditions, in said aqueous dispersion, the aqueous dispersion serving as a vehicle therefor.Type: GrantFiled: August 30, 1984Date of Patent: June 17, 1986Assignee: SCM CorporationInventors: James T. K. Woo, Vincent W. Ting, Richard M. Marcinko
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Patent number: 4588623Abstract: A metal plated poly(aryl ether) containing article, said poly(aryl ether) comprising a blend of a poly(aryl ether) polymer, a styrene and/or acrylic copolymer and a compatibilizing amount of a polyhydroxyether.Type: GrantFiled: May 16, 1985Date of Patent: May 13, 1986Assignee: Union Carbide CorporationInventors: Tyler F. Hartsing, Jr., Marvin E. Sauers, Lloyd M. Robeson
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Patent number: 4563501Abstract: A cathode-precipitating electrodeposition coating composition consisting essentially of (A) 100 parts of a high-molecular-weight compound having a molecular weight of 500 to 10,000 and containing an amino group and a carbon-carbon double bond, (B) 3 to 200 parts by weight of a reaction product obtained by reacting an unsaturated carboxylic acid having 3 or 4 carbon atoms with the terminal glycidyl group of a glycidyl compound obtained by reacting a bisphenol with epichlorohydrin, and (C) 0.2 to 20 parts by weight of an oil-soluble manganese salt of a monoester of a 1,2-dicarboxylic acid or a manganese salt of sulfonated or maleinized polybutadiene having a molecular weight of 300 to 3,000.Type: GrantFiled: May 10, 1983Date of Patent: January 7, 1986Assignee: Nippon Oil Company, Ltd.Inventors: Yutaka Otsuki, Yoshihiko Araki, Hiroyoshi Omika, Hajime Hara, Kazuho Aoyama
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Patent number: 4550130Abstract: A polyolefin resin composition comprising a polyolefin modified with an unsaturated carboxylic acid, at least one member selected from the group consisting of polyepoxides, polyisocyanates, and polyamines, and a reinforcement.Type: GrantFiled: February 28, 1984Date of Patent: October 29, 1985Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Kazuo Kishida, Isao Sasaki, Hiroshi Mori, Yasuaki Ii
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Patent number: 4548985Abstract: Disclosed is a hot-melt adhesive composed of a composition comprising an acid-modified olefin resin formed by graft modification of an ethylenically unsaturated carboxylic acid or its anhydride or a resin composition containing said modified olefin resin and an oxirane ring-containing compound, wherein said composition has a carbonyl group concentration of 1 to 600 millimoles per 100 g of the composition and an oxirane oxygen concentration of 0.01 to 50 millimoles per 100 g of the composition.Type: GrantFiled: June 27, 1983Date of Patent: October 22, 1985Assignee: Toyo Seikan Kaisha, Ltd.Inventors: Jinichi Yazaki, Kozaburo Sakano, Junichi Matsuo
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Patent number: 4547530Abstract: Miscible blends of poly-2-oxazolines and thermoplastic polymers are disclosed herein. These blends exhibit a single glass transition point indicative of a miscible blend. The blends of this invention are useful as membranes, particularly separation membranes for mixtures of organic compounds or organic compounds and water and a pervaporation process.Type: GrantFiled: November 15, 1983Date of Patent: October 15, 1985Assignee: The Dow Chemical CompanyInventors: Kathleen M. McCreedy, James C. Pawloski, Henno Keskkula, Edward H. Yonkers
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Patent number: 4537805Abstract: This invention relates to a thermosetting plastisol dispersion composition comprising(1) at least one copolymer of acrylonitrile-butadiene-styrene (ABS) in powder form, which is insoluble in the reactive plasticizer at room temperature and plasticizable at a temperature at or above the fluxing temperature;(2) a liquid reactive plasticizer member of the group consisting of (a) at least one epoxide resin having an average of more than one epoxide group in the molecule, (b) at least one liquid monomer, oligomer or prepolymer characterized by (1) containing at least one ethylenically unsaturated group and (2) capable of solvating the ABS at the fluxing temperature, and (c) a mixture of (a) and (b); and(3) an effective amount of either a thermal initiator or photoinitiator for plasticizers present in the composition.The plastisol dispersion after fluxing can form a thermoset sealant, coating or adhesive after the crosslinking reaction.Type: GrantFiled: March 26, 1984Date of Patent: August 27, 1985Assignee: W. R. Grace & Co.Inventor: Shiow C. Lin
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Patent number: 4521490Abstract: A solventless, fluid epoxy resin composition is storage-stable against separation of phases for at least one year, and when cured provides adhesive bonds of improved peel strength at room and low temperatures without loss of lap shear strength at room and elevated temperatures. The composition comprises an epoxide group-containing compound having in situ polymerized, elastomeric particles colloidally dispersed therein, and as curing agent a poly(oxyhydrocarbolene)diamine compound and optionally, and preferably, a cure accelerator.Type: GrantFiled: August 11, 1983Date of Patent: June 4, 1985Assignee: Minnesota Mining and Manufacturing Co.Inventors: Alphonsus V. Pocius, William J. Schultz
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Patent number: 4521565Abstract: A cellulose derivative-containing aqueous dispersion which is obtained by polymerizing a mixture of a cellulose derivative, at least one radical-polymerizable unsaturated monomer capable of dissolving the cellulose derivative therein and water under radical polymerization conditions, said aqueous dispersion containing as a dispersion stabilizer a water-soluble or water-dispersible polymer in which polymeric chain group compatible with the polymer obtained said radical-polymerizable unsaturated monomer is chemically bonded onto a hydrophilic polymeric chain group.Type: GrantFiled: August 10, 1983Date of Patent: June 4, 1985Assignee: Daicel Chemical Industries, Ltd.Inventors: Hirotaka Toaba, Masatoshi Mikumo, Masahiro Asami
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Patent number: 4507411Abstract: A composition suitable for forming surface coatings, laminates or composite materials formed by bringing together:(a) a first polymer containing carboxylic acid, anhydride or acid chloride groups,(b) an amine or alcohol or a derivative thereof which is a tertiary amine, a ketimine, an acetal or an oxazolidine and(c) a second polymer capable of cross-linking with the first polymer in the presence of the amine or alcohol.The components may be initially in two packs and either mixed prior to application or sprayed onto the surface simultaneously from separate nozzles.The surface coatings are particularly suitable for coating surfaces which are otherwise difficult to coat and protect and may be applied to wet or rusted surfaces without surface preparation.Type: GrantFiled: September 24, 1981Date of Patent: March 26, 1985Assignee: The British Petroleum Company LimitedInventors: Kevin R. Gordon, Jeffrey R. Kelsey, Ivan C. Stannard
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Patent number: 4482671Abstract: Provides new and improved water-reducible coating compositions and methods of making them. Three preferred processes are disclosed. These differ in the manner of incorporating and chemical nature of an extender polymer.Broadly, the process of the invention is one for forming an aqueous dispersion of a fluent resinous composition ofa. a mixture in an organic solvent of(i) an ionizable graft polymer of an epoxy resin and an addition polymerized resin, the addition polymerized resin being bonded to aliphatic backbone carbon atoms of the epoxy resin by carbon-to-carbon bonds, and(ii) an extender resin;b. an aqueous vehicle, andc. an ionizing agent;the ionization present from said combined components being sufficient to establish the components as a dispersion in the aqueous vehicle, and then addition polymerizing a quantity of addition polymerizable monomer, under addition polymerizing conditions, in said aqueous dispersion, the aqueous dispersion serving as a vehicle therefor.Type: GrantFiled: November 1, 1982Date of Patent: November 13, 1984Assignee: SCM CorporationInventors: James T. K. Woo, Vincent W. Ting, Richard M. Marcinko
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Patent number: 4463129Abstract: Rubbery polymer compositions, e.g. based on chlorobutyl rubber, having improved adhesion to mineral substrates such as glass or metal, are produced by a stepwise reaction sequence. In a first stage the rubbery polymer is reacted with a reactive silane such as an amino trialkoxy silane, in a second stage the product is mixed with an epoxy resin, and in a third stage a further amount of reactive silane is reacted with the epoxy containing compound.Type: GrantFiled: November 23, 1981Date of Patent: July 31, 1984Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Yasukavu Shinada, Daniel E. Nerinckx