Contains An Exterior Ethylenic Substituent Bonded Directly Or Indirectly To A Single Carbon Atom Of The Fused Ring System Patents (Class 526/284)
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Patent number: 8415424Abstract: An aromatic ring-containing polymer for an underlayer of a resist, including a unit structure represented by Chemical Formula 1:Type: GrantFiled: July 2, 2012Date of Patent: April 9, 2013Assignee: Cheil Industries, Inc.Inventors: Min-Soo Kim, Hwan-Sung Cheon, Sung-Wook Cho, Seung-Bae Oh, Jee-Yun Song
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Patent number: 8404797Abstract: An end-modified soluble polyfunctional vinyl aromatic copolymer, which is improved in heat resistance, thermal stability, solvent solubility, and compatibility with acrylate compounds, and a curable resin composition using the same are disclosed. The end-modified soluble polyfunctional vinyl aromatic copolymer is obtained by allowing a divinyl aromatic compound (a), a monovinyl aromatic compound (b), and an aromatic ether compound (c) to react with each other, and has, at an end, an end group derived from the aromatic ether compound and having an acrylate bond. The copolymer has a number average molecular weight Mn of 500 to 100,000, an introduction amount (c1) of the end group derived from the aromatic ether compound satisfies (c1)?1.0 (group/molecule), a molar fraction a? of a structural unit derived from the divinyl aromatic compound and a molar fraction b? of a structural unit derived from the monovinyl aromatic compound in the copolymer satisfy 0.05?a?/(a?+b?)?0.95.Type: GrantFiled: March 3, 2009Date of Patent: March 26, 2013Assignee: Nippon Steel Chemical Co., Ltd.Inventors: Masanao Kawabe, Hiroko Terao, Natsuko Okazaki
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Patent number: 8362170Abstract: Provided is a polymerizable compound represented by the following general formula (ca-1) or (cb-1): wherein the variables in the formulae are defined in the specification.Type: GrantFiled: June 18, 2012Date of Patent: January 29, 2013Assignee: FUJIFILM CorporationInventors: Shuji Hirano, Kaoru Iwato, Hiroshi Saegusa, Yusuke Iizuka
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Publication number: 20130023637Abstract: The present invention is to provide a novel polymerizable chiral compound (chiral agent) having high left-handed helical twisting power, a polymerizable liquid crystal composition comprising the polymerizable chiral compound and a polymerizable liquid crystal compound, a liquid crystal polymer, and an optically anisotropic body.Type: ApplicationFiled: March 10, 2011Publication date: January 24, 2013Applicant: ZEON CORPORATIONInventors: Kei Sakamoto, Kentaro Tamura, Kumi Okuyama
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Publication number: 20130012648Abstract: The invention provides a colored composition including a dye multimer having an alkali-soluble group as a dye, the dye multimer having a weight-average molecular weight (Mw) of from 5,000 to 20,000 and a dispersity (weight-average molecular weight (Mw)/number-average molecular weight (Mn)) of from 1.00 to 2.50.Type: ApplicationFiled: March 30, 2011Publication date: January 10, 2013Applicant: FUJIFILM CORPORATIONInventors: Yoshihiko Fujie, Masaru Yoshikawa, Shinichi Kanna, Kenta Ushijima
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Patent number: 8329841Abstract: The present invention relates to a photoreactive polymer that comprises a multi-cyclic compound in a main chain, and a polymerization method thereof. Since the photoreactive polymer according to the present invention comprises a multi-cyclic compound having a high glass transition temperature as a main chain, the thermal stability is excellent, and since the mobility of the main chain is relatively high as compared to that of an additional polymer, a photoreactive group can be freely moved in the main chain of the polymer. Accordingly, it is possible to overcome a slow photoreactive rate that is considered a disadvantage of a polymer material used to prepare an alignment film for known liquid crystal display devices.Type: GrantFiled: December 15, 2011Date of Patent: December 11, 2012Assignee: LG Chem, Ltd.Inventors: Dai-Seung Choi, Hye-Young Jung, Sung-Ho Chun, Heon Kim, Sung-Don Hong, Dong-Woo Yoo
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Publication number: 20120308927Abstract: Provided are polymers and photoresist compositions useful in forming photolithographic patterns. Also provided are substrates coated with the photoresist compositions and methods of forming photolithographic patterns. The compositions, methods and coated substrates find particular applicability in the manufacture of semiconductor devices.Type: ApplicationFiled: December 2, 2011Publication date: December 6, 2012Applicants: Dow Global Technologies LLC, Rohm and Haas Electronic Materials LLCInventors: Young Cheol Bae, David Richard Wilson, Jibin Sun
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Publication number: 20120270155Abstract: There are provided a novel compound, a polymeric compound, a resist composition, an acid generator and a method of forming a resist pattern the compound represented by general formula (1-1): wherein each of R1 and R3 independently represents a single bond or a divalent linking group; A represents a divalent linking group; each of R2 and R4 independently represents a hydroxyl group, a hydrocarbon group which may have a substituent, or a group represented by general formula (1-an1), (1-an2) or (1-an3), provided that at least one of R2 and R4 represents a group represented by general formula (1-an1), (1-an2) or (1-an3); and n0 is preferably 0 or 1, and wherein Y1 represents a single bond or —SO2—; R5 represents a linear or branched monovalent hydrocarbon group of 1 to 10 carbon atoms, cyclic monovalent hydrocarbon group of 3 to 20 carbon atoms or monovalent hydrocarbon group of 3 to 20 carbon atoms having a cyclic partial structure which may be substituted with a fluorine atom; and M+ represents an organic caType: ApplicationFiled: April 18, 2012Publication date: October 25, 2012Applicant: TOKYO OHKA KOGYO CO., LTD.Inventors: Yoshitaka Komuro, Yoshiyuki Utsumi, Akiya Kawaue, Masatoshi Arai
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Patent number: 8283423Abstract: The present invention generally relates to methods for the synthesis of species including monomers and polymers. Methods of the invention comprise the use of chemical techniques including metathesis chemistry to synthesize, for example, monomers and/or polymers with desired functional groups.Type: GrantFiled: September 28, 2007Date of Patent: October 9, 2012Assignee: Massachusetts Institute of TechnologyInventors: Timothy M. Swager, John P. Amara
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Publication number: 20120252217Abstract: A resist underlayer film-forming composition includes (A) a polymer that includes a repeating unit shown by a formula (1), and has a polystyrene-reduced weight average molecular weight of 3000 to 10,000, and (B) a solvent, wherein R3 to R8 individually represent a group shown by the following formula (2) or the like, —O—R1?R2 ??(2) wherein R1 represents a single bond or the like, and R2 represents a hydrogen atom or the like.Type: ApplicationFiled: August 30, 2011Publication date: October 4, 2012Applicant: JSR CorporationInventors: Shin-ya MINEGISHI, Yushi MATSUMURA, Shinya NAKAFUJI, Kazuhiko KOMURA, Takanori NAKANO, Satoru MURAKAMI, Kyoyu YASUDA, Makoto SUGIURA
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Patent number: 8278025Abstract: The formation of high-resolution resist patterns by liquid immersion lithography with various fluids is enabled by protecting a resist film from deterioration (such as bridging) during the immersion exposure in a fluid (such as water) and the fluid from deterioration and improving the stability of a resist film in the storage after exposure without increase in the number of treatment steps. A material for forming resist protection films which comprises an alkali-soluble polymer for forming a protective overcoat for a resist film, characterized in that the contact angle of the polymer to water is 90° or above. The polymer is preferably an acrylic polymer which comprises as the essential components constituent units derived from (meth) acrylic acid and constituent units derived from a specific acrylic ester.Type: GrantFiled: December 22, 2005Date of Patent: October 2, 2012Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Keita Ishiduka, Kotaro Endo
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Patent number: 8252877Abstract: Provided is a polymerizable compound represented by the following general formula (ca-1) or (cb-1): wherein the variables in the formulae are defined in the specification.Type: GrantFiled: December 11, 2009Date of Patent: August 28, 2012Assignee: FUJIFILM CorporationInventors: Shuji Hirano, Kaoru Iwato, Hiroshi Saegusa, Yusuke Iizuka
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Publication number: 20120206810Abstract: The present invention provides a resin composition for a composite optical element including: a first (meth)acrylate having a fluorene skeleton; and a second (meth)acrylate having a biphenyl ring but having no hydroxyl group. In the resin composition, the content of the first (meth)acrylate is 4 to 42 wt %.Type: ApplicationFiled: February 7, 2012Publication date: August 16, 2012Applicant: PANASONIC CORPORATIONInventor: Nobuyuki KOBAYASHI
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Publication number: 20120123074Abstract: The present invention provides an optical anisotropic material having a good light stability, and provides a di(meth)acrylate compound represented by the following formula (1) and a polymerizable liquid crystalline composition that are suitable for the production of the optical anisotropic material. Further, the present invention provides an optical element having a good light stability and an optical information writing/reading device using the same.Type: ApplicationFiled: January 5, 2012Publication date: May 17, 2012Applicant: Asahi Glass Company, LimitedInventors: Satoshi OKADA, Makoto Hasegawa, Hiroshi Kumai, Hiromichi Nagayama
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Patent number: 8158748Abstract: The invention provides hetero-functional compound compounds useful in a variety of adhesive applications. More particularly, the invention provides compounds bearing at least one electron rich olefinic bond and at least one electron poor olefinic bond, wherein the two olefinic bonds are separated by a C3 to about C500 aliphatic, cycloaliphatic, or aromatic spacer.Type: GrantFiled: August 13, 2009Date of Patent: April 17, 2012Assignee: Designer Molecules, Inc.Inventors: Stephen M. Dershem, Farhad G Mizori
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Patent number: 8129466Abstract: A pigment dispersant is disclosed comprising a tri-block copolymer having a first block comprising a glycidyl(meth)acrylate reacted with a napthoic acid, a second block comprising (meth)acrylic acid alkyl esters, and a third block comprising (meth)acrylic acid alkyl esters, wherein said third block is different from said second block. The dispersant is suited for use in a nanoparticulate dispersion comprising pigment particles having an average primary particle size of less than 100 nm.Type: GrantFiled: March 25, 2008Date of Patent: March 6, 2012Assignee: PPG Industries Ohio, IncInventors: W. David Polk, Eldon L. Decker, Noel R. Vanier, Brian E. Woodworth
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Publication number: 20120035337Abstract: The present invention relates to novel materials particularly useful for ophthalmic applications and methods for making and using the same. More particularly, the present invention relates to relatively soft, optically transparent, foldable, high refractive index Materials particularly suited for use in the production of intraocular lenses, contact lenses, and other ocular implants and to methods for manufacturing and using the same.Type: ApplicationFiled: October 13, 2011Publication date: February 9, 2012Applicant: KEY MEDICAL TECHNOLOGIES, INC.Inventors: Khalid Mentak, Anthony Keslinke, Kevin Phan
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Publication number: 20120008079Abstract: The present invention provides a liquid crystal display device capable of reducing the probability of image sticking. The liquid crystal display device includes a pair of substrates and a liquid crystal layer between the substrates. At least one of the substrates includes an alignment film and a polymer layer on the alignment film. The polymer layer includes monomer units derived from at least two species of polymerizable monomers. The at least two species of polymerizable monomers include at least two species of monomers selected from the group consisting of: specific polyfunctional monomers and specific monofunctional monomers.Type: ApplicationFiled: October 8, 2009Publication date: January 12, 2012Inventors: Masanobu Mizusaki, Takashi Katayama, Yuichi Kawahira, Takeshi Noma, Yohei Nakanishi
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Publication number: 20110315964Abstract: A polymerizable monomer represented by the following formula (1) wherein at least one of Ar1 to Ar3 is substituted by a group represented by the following formula (2) and which is substituted by one or more groups comprising a polymerizable functional group. Ar1 to Ar3 are a substituted or unsubstituted aryl group having 6 to 40 ring carbon atoms, Ar6 is a substituted or unsubstituted aryl group having 6 to 40 ring carbon atoms and Ar4 and Ar5 are a substituted or unsubstituted arylene group having 6 to 40 ring carbon atoms.Type: ApplicationFiled: March 5, 2010Publication date: December 29, 2011Inventors: Mitsuru Eida, Nobuhiro Yabunouchi, Yumiko Mizuki, Masami Watanabe, Akinori Yomogita
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Publication number: 20110294070Abstract: A polymer is obtained from a hydroxyphenyl methacrylate monomer having an acid labile group substituted thereon. A positive resist composition comprising the polymer as a base resin has a very high contrast of alkaline dissolution rate before and after exposure, a high resolution, a good profile and minimal line edge roughness of a pattern after exposure, a retarded acid diffusion rate, and good etching resistance.Type: ApplicationFiled: June 1, 2011Publication date: December 1, 2011Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Jun Hatakeyama, Seiichiro Tachibana, Koji Hasegawa
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Publication number: 20110269867Abstract: A novel alkali-soluble polymer compound including a dehydrogenated pimaric acid and/or its isomer as a repeating unit, and a photosensitive resin composition including the alkali-soluble polymer compound as an effective binder matrix are provided. A photosensitive resin composition using the alkali-soluble polymer compound including a dehydrogenated resin acid has excellent photosensitivity and developing characteristics cause a less deformation in a firing process, has excellent elasticity. Thus, the photosensitive resin composition is advantageous for curing various transparent photosensitive materials, in particular, materials of column spacers, an overcoat, a passivation layer, or the like, used for fabricating color filters of an LCD.Type: ApplicationFiled: April 28, 2011Publication date: November 3, 2011Applicant: LG CHEM. LTD.Inventors: Keon Woo LEE, Sang Kyu KWAK, Chang Soon LEE, Hye Hyeon KIM
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Patent number: 8048972Abstract: The present invention relates to novel materials particularly useful for ophthalmic applications and methods for making and using the same. More particularly, the present invention relates to relatively soft, optically transparent, foldable, high refractive index materials particularly suited for use in the production of intraocular lenses, contact lenses, and other ocular implants and to methods for manufacturing and using the same.Type: GrantFiled: June 25, 2010Date of Patent: November 1, 2011Assignee: Key Medical Technologies, Inc.Inventors: Khalid Mentak, Anthony Keslinke, Kevin Phan
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Publication number: 20110251365Abstract: Optical compensation films (positive C-plate) with disk anisotropic subunits (OASUs) that have high positive birefringence throughout the wavelength range 400 nm<?<800 nm are provided. The optical compensation films may be processed by solution casting to yield a polymer film with high birefringence without the need for stretching, photopolymerization, or other processes. Such optical compensation films are suitable for use as a positive C-plate in LCDs, particularly IPS-LCDs.Type: ApplicationFiled: April 6, 2011Publication date: October 13, 2011Inventors: Frank W. Harris, Dong Zhang, Xiaoling Joe Zheng, Ted Calvin Germroth, Thauming Kuo, Jiaokai Alexander Jing, Brian Michael King
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Patent number: 7998657Abstract: Novel ester compounds having formulae (1) to (4) wherein A1 is a polymerizable functional group having a carbon-carbon double bond, A2 is oxygen, methylene or ethylene, R1 is a monovalent hydrocarbon group, R2 is H or a monovalent hydrocarbon group, any pair of R1 and/or R2 may form an aliphatic hydrocarbon ring, R3 is a monovalent hydrocarbon group, and n is 0 to 6 are polymerizable into polymers. Resist compositions comprising the polymers as a base resin are thermally stable and sensitive to high-energy radiation, have excellent sensitivity and resolution, and lend themselves to micropatterning with electron beam or deep-UV.Type: GrantFiled: October 26, 2010Date of Patent: August 16, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masaki Ohashi, Takeshi Kinsho, Takeru Watanabe
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Publication number: 20110189550Abstract: An overcharge inhibitor is provided which increases an internal resistance of a battery, being electropolymerized by reaction with a positive electrode at a high potential in overcharging. The overcharge inhibitor is produced by using a polymer containing a polymerizable monomer as a repeating unit. The polymerizable monomer has a functional group that is electropolymerized at a potential of 4.3 to 5.5 V based on a lithium metal reference.Type: ApplicationFiled: August 18, 2010Publication date: August 4, 2011Inventors: Jinbao ZHAO, Norio Iwayasu, Yuki Okuda, Hidetoshi Honbo
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Patent number: 7977441Abstract: An acetylene-based polymer, comprising n recurring units represented by the following Formula (1): CH?CAn??(1) wherein, n is an integer of 10 to 10,000; each A represents a group selected from a naphthyl group, a phenanthryl group, a pyrenyl group and an anthryl group, which is mono- or di-substituted with a group selected from alkyl groups, alkyl groups substituted with aromatic hydrocarbon groups, R1—O— groups, —S—R2 groups, —NR3R4 groups, a cyano group, a carboxyl group, R5SO2— groups, —COOR6 groups, —CON(R7)(R8) groups and —COR9 groups (each of R1, R5, R6 and R9 is an alkyl group, each of R2, R3, R4, R7 and R8 is a hydrogen atom or an alkyl group); and the recurring units may be the same as or different from each other.Type: GrantFiled: November 24, 2006Date of Patent: July 12, 2011Assignee: National Institute of Advanced Industrial Science and TechnologyInventor: Kenji Tsuchihara
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Publication number: 20110098412Abstract: The present invention discloses a method for partially hydrogenating polymer. The method comprises providing a polymer having at least one vinyl aromatic block; and hydrogenating the polymer in presence of a heterogeneous catalyst on a support selected from the group consisting of BaSO4, Al2O3, TiO2, ZrO2, active carbon and any combination thereof to obtain a hydrogenated polymer. The hydrogenated polymer comprises at least one hydrogenated vinyl aromatic block having a carbon ring linking with a backbone of the hydrogenated polymer, wherein the average weight percent of the hydrogenated vinyl aromatic block(s) having only one and two double bonds on the carbon ring is between 1-30 wt % based on the total weight of the hydrogenated polymer.Type: ApplicationFiled: August 27, 2010Publication date: April 28, 2011Applicant: TSRC CORPORATIONInventor: Hung Chieh Hou
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Patent number: 7931825Abstract: A polymerizable composition comprising a bifunctional (meth)acrylate compound represented by general formula (1) and a monofunctional (meth)acrylate compound having a nitrile group at the terminal thereof represented by general formula (2). The mass ratio of them (the former/the latter) is from 90/10 to 40/60.Type: GrantFiled: January 7, 2008Date of Patent: April 26, 2011Assignee: Adeka CorporationInventors: Masatomi Irisawa, Ken Matsumoto
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Patent number: 7911722Abstract: A composition for forming a prism layer and a prism film manufactured using the same. The composition for forming a prism layer includes a UV-curable monomer A, including a fluorene derivative diacrylate monomer represented by Formula 1 or 2; a UV-curable monomer B, including at least one acrylate monomer; a photoinitiator; and an additive, and thus is excellent in surface strength, adhesion to a substrate film and anti-yellowing properties, with a viscosity suitable for formation of the prism layer.Type: GrantFiled: January 26, 2006Date of Patent: March 22, 2011Assignee: Kolon Industries, Inc.Inventors: Woo Chul Jung, Chang Kun Kim, Jong Min Park
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Publication number: 20110065879Abstract: The invention relates to a copolymer that can be obtained by the polymerization of the monomers (A), (B) and (C), (A) being a monomer of formula (I) wherein A is C2-C4 alkylene and B is a C2-C4-alkylene different from A, k corresponds to the number 0 or 1, m is a number between 0 and 500, n is a number between 0 and 500, the sum of m+n being equal to between 1 and 1000; (B) contains an ethylenically unsaturated monomer containing an aromatic group; and (C) is an ethylenically unsaturated monomer containing an alkyl radical. The copolymers according to the invention are suitable as dispersants for pigments.Type: ApplicationFiled: July 23, 2008Publication date: March 17, 2011Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Bjoern Fechner, Carsten Schaefer, Alexander Woerndle
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Publication number: 20110060108Abstract: A polyester resin having excellent dimensional stability against environmental changes and excellent dimensional stability in the processing step while having excellent moldability and a biaxially oriented polyester film comprising the same. The polyester resin comprises a recurring unit represented by the following formula (A) and a recurring unit represented by the following formula (B) as the main constituents: —O—C(O)—R1—C(O)—O—R2—O—??(A) —O—C(O)—R3—C(O)—O—R2—O—??(B) (R1 is a phenylene group or naphthalenediyl group, R2 is an alkylene group having 2 to 4 carbon atoms or cyclohexylene group, and R3 is 6,6?-(alkylenedioxy)di-2-naphthoic acid), wherein the content of the recurring unit (B) is not less than 5 mol % and less than 50 mol %, and the ratio of adjacent recurring units (A) and (B) is less than 0.9 based on a value obtained by doubling the product of the content of the recurring unit (A) and the content of the recurring unit (B).Type: ApplicationFiled: January 15, 2009Publication date: March 10, 2011Applicant: TEIJIN LIMITEDInventors: Eiji Kinoshita, Mitsuo Tojo
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Patent number: 7893293Abstract: A chemically amplified positive resist composition comprising (A) a resin which comprises (i) a polymerization unit represented by the formula (I): wherein R7 represents a hydrogen atom etc., R8 represents a C1-C4 alkyl group, p represents an integer of 1 to 3, and q represents an integer of 0 to 2, (ii) at least one polymerization unit selected from a group consisting of a polymerization unit represented by the formula (II): wherein R1 represents a hydrogen atom etc., R2 represents a C1-C8 alkyl group and ring X represents an alicyclic hydrocarbon group, and a polymerization unit represented by the formula (IV): wherein R3 represents a hydrogen atom etc., R4 and R5 independently represents a hydrogen atom etc., R10 represents a C1-C6 alkyl group etc., and (iii) a polymerization unit represented by the formula (III): wherein R3, R4 and R5 are the same as defined above, E represents a divalent hydrocarbon group, G represents a single bond etc., Z represents a carbonyl group etc.Type: GrantFiled: June 20, 2008Date of Patent: February 22, 2011Assignee: Sumitomo Chemical Company, LimitedInventors: Makoto Akita, Isao Yoshida, Kazuhiko Hashimoto
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Patent number: 7847013Abstract: A thermosetting resin composition for producing a color filter for a CMOS image sensor is provided. The thermosetting resin composition comprises an organic solvent and a self-curing copolymer having structural units represented by Formulae 1, 2, 3 and 4, which are described in the specification.Type: GrantFiled: May 7, 2008Date of Patent: December 7, 2010Assignee: Cheil Industries Inc.Inventors: O Bum Kwon, Kil Sung Lee, Jae Hyun Kim, Jung Hyun Kim
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Publication number: 20100261858Abstract: The present invention relates to novel materials particularly useful for ophthalmic applications and methods for making and using the same. More particularly, the present invention relates to relatively soft, optically transparent, foldable, high refractive index materials particularly suited for use in the production of intraocular lenses, contact lenses, and other ocular implants and to methods for manufacturing and using the same.Type: ApplicationFiled: June 25, 2010Publication date: October 14, 2010Applicant: KEY MEDICAL TECHNOLOGIES, INC.Inventors: Khalid Mentak, Anthony Keslinke, Kevin Phan
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Publication number: 20100219405Abstract: A polymer containing a repeating unit expressed by General Formula (I): General Formula (I) where Ar1 represents a substituted or unsubstituted aromatic hydrocarbon group; Ar2 and Ar3 each independently represent a divalent group of a substituted or unsubstituted aromatic hydrocarbon group; and R1 and R2 each independently represent a hydrogen atom, substituted or unsubstituted alkyl group, or substituted or unsubstituted aromatic hydrocarbon group.Type: ApplicationFiled: September 11, 2008Publication date: September 2, 2010Inventors: Toshiya Sagisaka, Takashi Okada, Masaomi Sasaki, Masafumi Torii, Takuji Kato, Tamotsu Aruga, Satoshi Yamamoto, Daisuke Goto, Shinji Matsumoto
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Patent number: 7786230Abstract: Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising the steps of: a) preparing a catalyst mixture including i) a precatalyst; ii) a first cocatalyst; and iii) a second cocatalyst; and b) subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, wherein the product yield of the prepared polymer is 50% by weight or more based on the total weight of the monomer.Type: GrantFiled: July 20, 2006Date of Patent: August 31, 2010Assignee: LG Chem, Ltd.Inventors: Sung-Cheol Yoon, Sung-Ho Chun, Won-Kook Kim, Tae-Sun Lim, Heon Kim, Jung-Min Lee
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Patent number: 7786231Abstract: Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising: preparing a catalyst mixture including i) a precatalyst, containing a Group 10 transition metal having a ligand containing oxygen ions bonded to the metal; ii) a first cocatalyst which is an organic compound containing a Group 15 element; and iii) a second cocatalyst which is capable of providing an anion and weakly coordinating to the metal of the precatalyst; and subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, at a temperature of 80-200° C., the total amount of the organic solvent being 50-800% by weight based on the total weight of the monomer contained in the monomer solution, and the product yield of the polymer being 50% by weight or more based on the total weight of the monomer.Type: GrantFiled: November 20, 2008Date of Patent: August 31, 2010Assignee: LG Chem, Ltd.Inventors: Sung-Cheol Yoon, Sung-Ho Chun, Won-Kook Kim, Tae-Sun Lim, Heon Kim, Jung-Min Lee
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Publication number: 20100216958Abstract: Isobutene, isoprene, and butadiene are obtained from mixtures of C4 and/or C5 olefins by dehydrogenation. The C4 and/or C5 olefins can be obtained by dehydration of C4 and C5 alcohols, for example, renewable C4 and C5 alcohols prepared from biomass by thermochemical or fermentation processes. Isoprene or butadiene can be polymerized to form polymers such as polyisoprene, polybutadiene, synthetic rubbers such as butyl rubber, etc. in addition, butadiene can be converted to monomers such as methyl methacrylate, adipic acid, adiponitrile, 1,4-butadiene, etc. which can then be polymerized to form nylons, polyesters, polymethylmethacrylate etc.Type: ApplicationFiled: February 24, 2010Publication date: August 26, 2010Inventors: Matthew W. Peters, Joshua D. Taylor, Leo E. Manzer, David E. Henton
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Patent number: 7745555Abstract: The present invention relates to novel materials particularly useful for ophthalmic applications and methods for making and using the same. More particularly, the present invention relates to relatively soft, optically transparent, foldable, high refractive index materials particularly suited for use in the production of intraocular lenses, contact lenses, and other ocular implants and to methods for manufacturing and using the same.Type: GrantFiled: November 19, 2007Date of Patent: June 29, 2010Assignee: Key Medical Technologies, Inc.Inventors: Khalid Mentak, Anthony Keslinke, Kevin Phan
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Publication number: 20100144995Abstract: The invention relates to a method for producing a thermoplastic resin, comprising using a composition at least comprising a fluorene-containing dihydroxy compound represented by the following formula (1) and a fluorene-containing hydroxy compound represented by the following formula (2) in an amount of from 0.5 parts by weight to 1.5 parts by weight relative to 100 parts by weight of the fluorene-containing dihydroxy compound of formula (1).Type: ApplicationFiled: October 26, 2009Publication date: June 10, 2010Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Noriyuki KATO, Toshiaki Yamada, Shu Yoshida, Jun Hagiwara, Hiroki Furuhashi, Kazuaki Kaneko, Keiichi Kameyama
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Patent number: 7723007Abstract: The present invention provides a polymer compound which can constitute a photoresist composition which is capable of having an excellent resolution, forming a fine pattern with a good rectangularity, obtaining favorable resist characteristics even when acid strength of a acid generated from an acid generator is weak, and having favorable sensitivity; a photoresist composition including the polymer compound; and a resist pattern formation method using the photoresist composition.Type: GrantFiled: January 28, 2005Date of Patent: May 25, 2010Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Toshiyuki Ogata, Syogo Matsumaru, Yohei Kinoshita, Hideo Hada, Daiju Shiono, Hiroaki Shimizu, Naotaka Kubota
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Patent number: 7718744Abstract: Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising: preparing a catalyst mixture including i) a precatalyst, containing a Group 10 transition metal having a ligand containing oxygen ions bonded to the metal; ii) a first cocatalyst which is an organic compound containing a Group 15 element; and iii) a second cocatalyst which is capable of providing an anion and weakly coordinating to the metal of the precatalyst; and subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, at a temperature of 80-200° C., the total amount of the organic solvent being 50-800% by weight based on the total weight of the monomer contained in the monomer solution, and the product yield of the polymer being 50% by weight or more based on the total weight of the monomer.Type: GrantFiled: December 3, 2003Date of Patent: May 18, 2010Assignee: LG Chem, Ltd.Inventors: Sung-Cheol Yoon, Sung-Ho Chun, Won-Kook Kim, Tae-Sun Lim, Heon Kim, Jung-Min Lee
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Patent number: 7718342Abstract: A polymer is provided comprising recurring units having formulas (1), (2), (3), (4), (5), and (6) in amounts of 1-60 mol % (1), 1-60 mol % (2), 1-50 mol % (3), 0-60 mol % (4), 0-30 mol % (5), and 0-30 mol % (6), and having a Mw of 3,000-30,000 and a Mw/Mn of 1.5-2.5. R1, R3, R4, R7, R9, and R11 are H or CH3, Y is methylene or O, R2 is CO2R10 when Y is methylene and R2 is H or CO2R10 when Y is O, R10 is C1-C15 alkyl which may be separated by O, R5 and R6 are H or OH, R8 is a tertiary ester type acid-labile protective group, and R12 is OH-containing fluoroalkyl. A resist composition comprising the polymer has a high resolution and is improved in line edge roughness and I/G bias.Type: GrantFiled: December 27, 2006Date of Patent: May 18, 2010Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kenji Funatsu, Tomohiro Kobayashi, Koji Hasegawa, Tsunehiro Nishi
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Patent number: 7704669Abstract: To provide a resist which is excellent in the solubility in a resist solvent and little dependent on baking temperature and can form developed patterns reduced in line edge roughness. An acrylic polymer characterized by comprising units of the general formula (1), units of general formula (2), and units of general formula (3) and/or units of general formula (4), wherein R, R?, R? and R?? are each hydrogen, methyl, or trifluoromethyl; R1 is hydrogen, C1-4 linear or branched alkyl, alkoxy, or C1-4 linear or branched fluoroalkyl; X is a C7-20 polycyclic aliphatic hydrocarbon group consisting of carbon atoms and hydrogen atoms; R2 and R3 are each independently C1-4 linear or branched alkyl; R4 is a C4-20 alicyclic hydrocarbon group; R5 is C1-4 linear or branched alkyl; and R6 and R7 are each hydrogen or C1-4 linear or branched alkyl.Type: GrantFiled: August 4, 2004Date of Patent: April 27, 2010Assignee: JSR CorporationInventors: Kouichi Fujiwara, Hiroshi Yamaguchi, Atsushi Nakamura
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Publication number: 20100090163Abstract: A polymerizable composition comprising a bifunctional (meth)acrylate compound represented by general formula (1) and a monofunctional (meth)acrylate compound having a nitrile group at the terminal thereof represented by general formula (2). The mass ratio of them (the former/the latter) is from 90/10 to 40/60.Type: ApplicationFiled: January 7, 2008Publication date: April 15, 2010Applicant: Adeka CorporationInventors: Masatomi Irisawa, Ken Matsumoto
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Publication number: 20100032621Abstract: A polymerizable compound represented by general formula (1) of the invention has good solvent solubility and excellent alignment control properties and optical characteristics. In formula (1), M1 and M2 are each hydrogen or methyl; X1 and are each a single bond, or an optionally branched C1-10 alkylene, alkyleneoxy or alkyleneoxycarbonyloxy; X3 is optionally branched C1-10 alkylene; Y1 and Y2 are each an ester linkage, etc.; and rings A, B, C, and D are each a cyclic structure, such as 2,6-naphthlene.Type: ApplicationFiled: December 18, 2007Publication date: February 11, 2010Applicant: Adeka CorporationInventors: Kazuyuki Itano, Hiroya Fukunaga, Masatomi Irisawa, Tatsunori Kobayashi, Mineki Hasegawa
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Publication number: 20100021830Abstract: An aromatic ring-containing polymer, a polymer mixture, an antireflective hardmask composition, and a method for patterning a material on a substrate, the aromatic ring-containing polymer including at least one aromatic ring-containing polymer represented by Formulae 1, 2, or 3.Type: ApplicationFiled: October 1, 2009Publication date: January 28, 2010Inventors: Min Soo Kim, Dong Seon Uh, Chang Il Oh, Kyong Ho Yoon, Kyung Hee Hyung, Jin Kuk Lee, Jong-Seob Kim, Hwan Sung Cheon, Irina Nam, Nataliya Tokareva
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Patent number: 7629107Abstract: A positive photosensitive composition comprises: a polymer compound having an acid-decomposable structure on a terminal of the polymer compound; and a compound capable of generating an acid upon irradiation with actinic ray or radiation.Type: GrantFiled: September 18, 2007Date of Patent: December 8, 2009Assignee: FUJIFILM CorporationInventors: Akinori Shibuya, Takayuki Kato
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Publication number: 20090297979Abstract: The present invention provides; a polymer suitable as a base resin for a positive resist composition, in particular a chemically amplified positive resist composition, having a higher resolution, a larger exposure allowance, a smaller sparse-dense size difference, a better process applicability, a better pattern configuration after exposure, and in addition, a further excellent etching resistance, than a conventional positive resist; a positive resist composition using the same; a patterning process; and a novel polymerizable compound to obtain a polymer like this. The present invention was accomplished by a polymer whose hydrogen atom of at least a carboxyl group is substituted by an acid labile group represented by the following general formula (2), a positive resist composition using the same, a patterning process, and a novel polymerizable compound to obtain a polymer like this.Type: ApplicationFiled: May 18, 2009Publication date: December 3, 2009Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Jun Hatakeyama, Takeru Watanabe, Seiichiro Tachibana
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Patent number: RE41580Abstract: A novel lactone-containing compound is provided as well as a polymer comprising units of the compound. The polymer is used as a base resin to formulate a resist composition having a high sensitivity, resolution and etching resistance.Type: GrantFiled: September 23, 2005Date of Patent: August 24, 2010Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Koji Hasegawa, Tsunehiro Nishi, Takeshi Kinsho, Jun Hatakeyama, Osamu Watanabe