Contains An Exterior Ethylenic Substituent Bonded Directly Or Indirectly To A Single Carbon Atom Of The Fused Ring System Patents (Class 526/284)
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Patent number: 5635575Abstract: A polymer having the function of water treatment and labeled with a fluorescent substance having a allyl group is disclosed. A process for producing the polymer for water treatment having the function of water treatment and labeled with a fluorescent substance having allyl group comprises copolymerizing a fluorescent substance having allyl group obtained by introducing allyl group into a fluorescent substance using a Grignard reagent with a monomer having a polymerizable double bond. The polymer having the function of water treatment and labeled with a fluorescent substance having an allyl group can be obtained under atmospheric pressure. Concentration of the polymer for water treatment can be measured conveniently, accurately and quickly. Therefore, concentration of the polymer in water can be easily adjusted to the optimum value. Degradation of the labeled polymer by chlorine can be prevented when an agent for water treatment containing the labeled polymer and a hydantoin compound is used.Type: GrantFiled: October 4, 1994Date of Patent: June 3, 1997Assignee: Kurita Water Industries Ltd.Inventors: Mayumi Kira, Norimasa Kobayashi
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Patent number: 5623040Abstract: Compounds of formulae I and II ##STR1## wherein R is phenyl and R.sub.1 to R.sub.4 are H or a substituent such as phenylthio, and one of the substituents R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is a group of formula III--X--C(O)--CR.sub.5 .dbd.C(R.sub.6).sub.2 (III)or R is substituted by a group of formula III, wherein X is a linking group or --X--C(O)-- is a direct bond, and R.sub.5 and R.sub.6 are each independently of the other H, halogen, C.sub.1 -C.sub.12 alkyl or C.sub.6 -C.sub.10 aryl, can be polymerised to homopolymers or copolymers. The monomers and polymers are reversible photochromic systems which can be used as colour indicators, as photochemically modifiable colour filters, or for the optical storage of information.Type: GrantFiled: August 2, 1995Date of Patent: April 22, 1997Assignee: Ciba-Geigy CorporationInventors: Evelyn Fischer, Walter Fischer
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Patent number: 5612434Abstract: Copolymers of olefinically unsaturated monomers, wherein at least one of the monomers is an isomer mixture of a cyclic or polycyclic olefinically unsaturated compound, which mixture contains a mass fraction from 8 to 50 per cent of at least one isomer of the main component in addition to this main component. The copolymers are useful, for example, in coating compositions.Type: GrantFiled: October 3, 1995Date of Patent: March 18, 1997Assignee: Hoechst AktiengesellschaftInventors: Ulrich Epple, Holger Schmidt, Gerhard Brindoepke, Karl-Friedrich Doessel
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Patent number: 5604292Abstract: Novel conjugated amino substituted phenylene polymers are disclosed having on-linear optical properties, and which can be converted to electrically conductive polymers. Such polymers are produced by reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). The polymers can also be made directly by treatment of the bis chlormethyl dimethyl aniline hydrochloride derivative with alkali metal alkoxide.Type: GrantFiled: May 31, 1994Date of Patent: February 18, 1997Assignee: The Untied States of America as represented by the Secretary of the NavyInventors: John D. Stenger-Smith, William P. Norris, Andrew P. Chafin, Scott T. Sackinger
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Patent number: 5596036Abstract: A hardenable composition suitable for flooring and for coating concrete surfaces comprising(a) an acrylic binder comprising a (meth)acrylic ester of the formula ##STR1## where R.sub.1 is C.sub.2-6 alkylene, n is 0-3 and R.sub.2 is a radical of an aromatic or alicyclic dicarboxylic acid ester or a dicyclopentenyl radical, n being 0 only when R.sub.2 is a dicyclopentenyl radical, and(b) a component which is one or both (preferably both) of carbon black and a polyfunctional aliphatic or aromatic polyester- or polyether- urethane oligomer. The composition also preferably comprises aggregate such as sand. The compositions have excellent impact resistance and flexural strength.Type: GrantFiled: June 6, 1995Date of Patent: January 21, 1997Assignee: Sandoz Ltd.Inventor: Karoly Disch o
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Patent number: 5585450Abstract: An oligomerized cyclobutarene containing 80 weight percent or more of oligomers of a degree of polymerization of three or more.Type: GrantFiled: June 5, 1995Date of Patent: December 17, 1996Assignee: The Dow Chemical CompanyInventors: Frank L. Oaks, Eric S. Moyer, Edward W. Rutter, Jr., Robert F. Harris
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Patent number: 5521269Abstract: The present invention relates to a spiropyran compound represented by the formula (1); an optically active spiropyran compound wherein an asymmetric center is introduced on a spirocarbon; and optical functional materials using these compounds, ##STR1## wherein R.sup.1 is alkyl group having 1 to 20 carbon atoms, aralkyl group, hydroxyethyl group, methacryloxymethyl group or methacryloxyethyl group; R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are the same or different and are each hydrogen atom, alkyl group having 1 to 6 carbon atoms, aryl group, aralkyl group, alkoxy group having 1 to 5 carbon atoms, hydroxymethyl group, carboxyl group, halogen atom, amino group, cyano group, trichloromethyl group, trifluoromethyl group or nitro group; R.sup.6 and R.sup.7 are the same or different and are each hydrogen atom, alkyl group having 1 to 6 carbon atoms, aryl group, aralkyl group, halogen atom, cyano group or nitro group; R.sup.Type: GrantFiled: November 14, 1994Date of Patent: May 28, 1996Assignee: Otsuka Kagaku Kabushiki KaishaInventor: Akira Miyashita
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Patent number: 5502139Abstract: A cross-linkable polymeric casting composition includinga fluorene diacrylate or dimethacrylate monomer; anda comonomer including a polymerisable double bond.Type: GrantFiled: April 20, 1995Date of Patent: March 26, 1996Assignee: Sola International Holdings Ltd.Inventors: Huan K. Toh, Chong M. Kok
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Patent number: 5455318Abstract: Method of metathetical polymerization and copolymerization of cycloalkenes of norbornene type in the presence of catalytic system which is comprised ofa) a catalytic precursor prepared by reaction of a tungsten compound containing at least one atom of chlorine, bromine and/or iodine with sterically hindered amines, whereby concentration of the tungsten is 0.01 to 50 milimols per mol of monomer and molar ratio of tungsten/amine is 0.01 to 1:5,b) cocatalyst selected from the group of organic compounds of aluminium, tin, lead, silicon, lithium, magnesium, boron, zinc or germanium, whereby molar ratio tungsten/cocatalyst is 1:1 to 1:20 and possibly,c) moderator of the polymerization reaction selected from the group of ethers, esters, ketons or nitriles in mole ratio cocatalyst/moderator 1:1 to 1:10.Type: GrantFiled: October 15, 1993Date of Patent: October 3, 1995Assignee: Chemopetrol, s.p. Litvinov, Vyzkumny ustav makromolekularni chemieInventors: Jiri Stohandl, Pavel Vozka, Irena Varekova, Miroslav Karafiat, Jiri Ondr j, Jiri Mejzlik, Hynek Balcar, Kamil Stepanek, Gerhardt Heller, Jaromir Lederer
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Patent number: 5430116Abstract: Polymeric and oligomeric bile acids are described which can be prepared by polymerization of monomeric bile acids of the formula IG--X--A (I)in which G, X and A have the given meanings or by copolymerization with a monomer of the formula IV ##STR1## in which R.sup.9 and R.sup.10 have the given meanings, or by copolymerization with N-vinylpyrrolidone or its derivatives,and/or by copolymerization with ethylenically unsaturated dicarboxylic anhydrides and ethylenically unsaturated dicarboxylic acids each having 2 to 6 carbon atoms; their esters or half esters, alkyl esters having 1-6 carbon atoms, cycloalkyl esters having 5 to 8 carbon atoms, benzyl esters or phenyl esters being understood as esters. They can be used as pharmaceuticals, foodstuff additives, formulation auxiliaries and detergents.Type: GrantFiled: December 17, 1992Date of Patent: July 4, 1995Assignee: Hoechst AktiengesellschaftInventors: Werner Kramer, Stefan Mullner, Matthias Gutweiler, Matthias Kroggel
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Patent number: 5422410Abstract: The invention is a process for making high molecular weight polymers of monoalkenyl arene monomers comprising:1) copolymerizing vinylbenzocyclobutene with the monoalkenyl arene monomer through the vinyl moiety;2) submitting the thus formed copolymer to conditions sufficient to open the side rings of the benzocyclobutene moieties;wherein the amount of vinylbenzocyclobutene in the copolymer is such that the polymer formed by step 2) does not reach a gel point. Such copolymers allow the building of molecular weight after the initial polymerization.Type: GrantFiled: February 28, 1994Date of Patent: June 6, 1995Assignee: The Dow Chemical CompanyInventors: Wen-Hong Tong, Janet M. Goss, Jeffrey R. Montanye
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Patent number: 5403908Abstract: The present invention provides an aryl styrene-based polymer of a degree of polymerization of at least 5 having recurring units represented by the general formula ##STR1## in the formula, R.sup.1 to R.sup.5 each denote a hydrogen atom, halogen atom or substituent group containing at least either one kind of a carbon atom, oxygen atom, nitrogen atom, sulfur atom, phosphorus atom, selenium atom, silicon atom and tin atom and at least one of the R.sup.1 to R.sup.5 denotes an aryl group having a hydrogen atom, aryl group having a halogen atom or aryl group having a substituent group containing at least either one kind of a carbon atom, oxygen atom, nitrogen atom, sulfur atom, phosphorus atom, selenium atom, silicon atom and tin atom, of which the stereospecificity is a mainly syndiotactic configuration and a method for the preparation thereof as well as a styrene-based copolymer and a method for the preparation thereof.Type: GrantFiled: April 30, 1993Date of Patent: April 4, 1995Assignee: Idemitsu Kosan Company, LimitedInventors: Masami Watanabe, Shuji Machida, Satoshi Asahi
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Patent number: 5391670Abstract: The alkylation resins of this invention comprise the alkylation reaction product of (a) at least one substituted or unsubstituted polycyclic aromatic compound and (b) at least one ethylenically unsaturated hydrocarbon monomer having at least two carbon-carbon double bonds that reacts with the polycyclic aromatic compound by alkylation in the presence of an acid catalyst, wherein the ratio of (a) to (b) in the resin is about 1:9 to about 3:1 by weight. The resins have a weight average molecular weight of less than 10,000 measured by size exclusion chromatography, and a Ring & Ball softening point of about 50.degree. to about 250.degree. C. Because of their high softening point and low molecular weight, the resins are useful in a variety of applications such as flow rate modifiers for engineering polymers, tackifiers for adhesives, and flushing agents for inks.Type: GrantFiled: August 9, 1993Date of Patent: February 21, 1995Assignee: Hercules IncorporatedInventors: Atanu Biswas, Daniel W. Klosiewicz
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Patent number: 5391634Abstract: Optically-active, amphiphilic, free-radical addition copolymers having an optically-active hydrophobic portion and an ionic hydrophilic portion are effective resolving agents. This utility is based on a unique combination of properties, viz., water solubility, chirality and amphiphilicity, i.e., having a dual hydrophobic and hydrophilic nature.Type: GrantFiled: January 21, 1994Date of Patent: February 21, 1995Assignee: The Dow Chemical CompanyInventors: Mladen Ladika, Thomas E. Fisk
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Patent number: 5387644Abstract: A hardenable monomer composition useful for flooring composition, grouts, mortars and the like comprises a mixture of crosslinkable acrylic monomer, carbon black and/or polyester- or polyether-methane oligomer having at least two polymerizable double bonds and a paraffin oil.The monomer is preferably of the formula I ##STR1## and there is preferably present other monomers, particularly hydroxypropyl methacrylate.Type: GrantFiled: December 14, 1993Date of Patent: February 7, 1995Assignee: Sandoz Ltd.Inventor: Karoly Discho
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Patent number: 5384378Abstract: Copolymers with non-linear optical properties, which contain or are composed of repeating units of the formula (I) ##STR1## where D is an electron donor,A is an electron acceptor,R.sup.1, R.sup.2, R.sup.3 and R.sup.4 can be the same as or different from one another, and are each H, alkyl, cycloalkyl, or R.sup.3 and R.sup.4 are each CN, NO.sub.2 or CHO, or R.sup.1 forms with R.sup.2, or R.sub.3 forms with R.sup.4, a fused-on ring,X is CH and/or N,m is an integer from 2 to 11, andR is hydrogen or methyl,and repeating units of at least one of the formulae (II), (III) and (IV) ##STR2## are suitable for the production of optical components.Type: GrantFiled: September 21, 1993Date of Patent: January 24, 1995Assignee: BASF AktiengesellschaftInventors: Karl-Heinz Etzbach, Stefan Beckmann, Oskar Nuyken, Peter Strohriegl, Harry Mueller
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Patent number: 5384381Abstract: Graft copolymers having improved phase binding between the graft base and the grafted-on polymer, are prepared from:a) a grafted-on polymer phase containing one or more monomers from the group consisting of (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinyl halides, styrene and styrene derivatives, andb) a peroxy group-containing copolymer phase containing from 0.01 to 20% by weight of an olefinically unsaturated peroxy compound of the general formula I or II ##STR1## where R.sup.1 is a chemical bond or a linear or branched alkyl chain having 1 to 10 carbon atoms or a cycloalkyl group having 3 to 10 carbon atoms, R.sup.2 and R.sup.3 are an alkyl group having 1 to 4 carbon atoms, R.sup.4 is an alkyl group or an alkyl-substituted phenyl group having 3 to 12 carbon atoms, and R.sup.5 is a cycloalkyl group having 3 to 12 carbon atoms, and from 80 to 99.Type: GrantFiled: November 15, 1993Date of Patent: January 24, 1995Assignee: Wacker Chemie GmbHInventors: Klaus Kohlhammer, Hermann Petersen, Walter Dobler
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Patent number: 5367039Abstract: Disclosed is a process for preparing a colored polymer without color change between a reactant color dye and an obtained polymer. The process of the present invention comprises polymerizing a vinyl polymerizable monomer (A), and a polymerizable dye (B) prepared by reacting a (meth)acryloyl compound having a group reactive with an active hydrogen, with a dye represented by the formula: ##STR1## wherein R.sub.1 and R.sub.2, which are the same or different, show a hydrogen atom or a group having the formula; ##STR2## (R.sub.3 represents --(CH.sub.2)m-NH.sub.2, or --(CH.sub.2)m-OH, R.sub.4 represents a hydrogen atom, an alkyl group, a cycloalkyl group or an allyl group, n is an integer of 1 to 5 and m is 0 or an integer of 1 to 5), provided that both R.sub.1 and R.sub.2 do not represents a hydrogen atom, X and Y, which are different, --OH or --NHR.sub.1,in the presence of a polymerization initiator, and a color difference between the polymerizable dye and the obtained colored vinyl polymer is within .+-.Type: GrantFiled: January 12, 1993Date of Patent: November 22, 1994Assignee: Nippon Paint Company, Ltd.Inventors: Naoya Yabuuchi, Chikayuki Otsuka, Akio Kashihara
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Patent number: 5349035Abstract: A process for preparing a copolymer suitable for use in an optical element which comprises the step of radically-polymerizing a composition which comprises at least one first monomer represented by formula (I), at least one second monomer represented by any one of formulas (II, III, and IV), and 0,005 to 1.0 weight percent of said polymerizable composition of an organic chain transfer agent having a chain transfer coefficient at 50.degree.-60.degree. C. of greater than 0.6 with acrylic monomer or styrenic monomer; in the presence of a radical polymerization initiator, is disclosed. Also disclosed is a copolymer suitable for use as an optical element obtained by the foregoing process and an optical element comprising this copolymer. The process of the disclosure provides essentially striation-free polymers which can be used to fabricate optical elements including thick lenses for glasses.Type: GrantFiled: April 16, 1993Date of Patent: September 20, 1994Assignee: Akzo Nobel N.V.Inventors: Johannes Brand, Wilfridus M. Brouwer
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Patent number: 5286439Abstract: Semiconductor chips are packaged by injection molding while continuously feeding a lead frame, characterized by using for the injection molding a hydrogenated polymer (A) obtained by the hydrogenation of a polymer obtained by ring-opening polymerization of a specific norbornene derivative or a monomer mixture comprising said norbornene derivative and other monomer copolymerizable therewith, wherein said injection molding for the packaging is carried out under the conditions of a resin temperature in the range of 280.degree. C. to 360.degree. C.; the molding temperature in the range of Tg -80.degree. C. to Tg +10.degree. C., wherein Tg is the glass transition temperature of the hydrogenated polymer (A) is Tg; and the injection pressure in the range of 10 to 200 kgf/cm.sup.2.Type: GrantFiled: December 15, 1992Date of Patent: February 15, 1994Assignee: Japan Synthetic Rubber Co., Ltd.Inventor: Hironobu Shinohara
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Patent number: 5274060Abstract: Copolymers having a molecular weight (Mw) of from 10.sup.3 to 10.sup.6, measured by gel-permeation chromatography, that are crosslinkable by acid catalysis and that consist ofa) 100-80 mol. % of structural repeating units of formulae I and II ##STR1## in a ratio of from 1:1 to 1:9 and b) 0-20 mol. % of structural repeating units of formula III ##STR2## wherein X and X' each independently of the other are ##STR3## R is hydrogen or a protecting group that can be removed by the action of acids, the radicals R.sub.1 each independently of the other are C.sub.1 -C.sub.5 alkyl, phenyl or naphthyl or together are 1,2-phenylene or --[C(R.sub.3)(R.sub.4)].sub.x -- wherein R.sub.3 and/or R.sub.4 =hydrogen or methyl and x is from 2 to 5, the radicals R.sub.2 each independently of the other are hydrogen, C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy, R.sub.5 and R.sub.7 are each hydrogen, R.sub.6 is hydrogen, halogen or methyl and R.sub.8 is hydrogen, halogen, methyl, --CH.sub.2 halogen, --CH.sub.Type: GrantFiled: February 27, 1992Date of Patent: December 28, 1993Assignee: Ciba-Geigy CorporationInventor: Ulrich Schadeli
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Patent number: 5272218Abstract: Disclosed are polymers which contain NLO dye moieties based upon a barbituric acid group, a thiobarbituric acid group or a 1,3-bis(dicyanomethylene)indan-2-ylidene group. These polymers, after poling, are useful in NLO elements in devices employing nonlinear optics. Also disclosed are various intermediates used in making such polymers.Type: GrantFiled: August 21, 1992Date of Patent: December 21, 1993Assignee: E. I. Du Pont de Nemours and CompanyInventors: Lap-Tak A. Cheng, Wilson Tam
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Patent number: 5270116Abstract: A method for monitoring the coating weight, uniformity, defects or markings present in a coating of a composition applied to a substrate comprises the steps:a) providing a substrate with a functional coating of a composition comprising an effective amount of uvescer that absorbs radiant energy, i.e., has an excitation energy, of wavelength .lambda..sub.1 and emits radiant energy of wavelength .lambda..sub.2 ;b) scanning the coating with radiant energy having a wavelength within wavelength .lambda..sub.1 ;c) detecting the radiant energy of wavelength .lambda..sub.2 emitted by the coating; andd) optionally, correlating the emitted radiant energy to independently measured standard coating weights or thicknesses, of the coating so as to measure coating weight, thickness, uniformity, defects, or markings.Type: GrantFiled: June 5, 1991Date of Patent: December 14, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kurt C. Melancon, George V. D. Tiers
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Patent number: 5256723Abstract: A two-chamber cartridge for fastening anchor elements in holes of a support structure is prepared. The chambers contain cycloaliphatic compounds and the reaction initiators. The separator separating the two chambers is destroyed inside the bore hole so that the mixing of the cycloaliphatic compounds and the reaction initiators can take place.Type: GrantFiled: September 10, 1992Date of Patent: October 26, 1993Assignee: Hilti AktiengesellschaftInventors: Ulrich Hense, Rudolf Hinterwaldner, Peter Mauthe
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Patent number: 5208306Abstract: Compounds containing at least one alkenyl group, at least one maleimide group and at least one rodlike mesogenic moiety are prepared by reacting one or more aminophenols containing one or more rodlike mesogenic moieties with a stoichiometric quantity of a maleic anhydride per amine group of said aminophenol and then alkenylating the resulting phenolic functional maleimide.Type: GrantFiled: August 7, 1992Date of Patent: May 4, 1993Assignee: The Dow Chemical CompanyInventor: Robert E. Hefner, Jr.
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Patent number: 5196296Abstract: Epoxy acrylate resins of this invention having a structure of the general formula (I) ##STR1## in which R is hydrogen or a lower alkyl group, R' is hydrogen or methyl group, and n is an integer from 0 to 20 are heat-resistant, solvent-soluble, and photosensitive and photosensitive resin compositions containing said epoxy acrylate resins as main component exhibit high photosensitivity in addition to strong adhesion to substrates, good resistance to heat and chemicals, and good mechanical and electrical properties and are useful as materials for forming insulation films for multilayer devices and protective films for image sensors and as protective films for solder resists, plating resists, and color filters.Type: GrantFiled: July 26, 1990Date of Patent: March 23, 1993Assignees: Nippon Steel Corporation, Nippon Steel Chemical Co., Ltd.Inventors: Kazuhiro Watanabe, Takero Teramoto
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Patent number: 5187248Abstract: Novel laser-optical recording elements which can be repeatedly erased and recorded on contain recording layers (a) which exhibit enantiotropic, ferroelectric smectic liquid crystalline (S.sub.c*) behavior, so that they can be switched back and forth between two thermodynamically stable, optically distinguishable ferroelectric smectic liquid crystalline S.sub.C* order states on exposure to a laser beam of sufficient luminous power, by applying an external electric field. The recording layers (a) themselves consist mainly or exclusively of novel polymers P having chiral mesogenic side groups.Type: GrantFiled: December 30, 1991Date of Patent: February 16, 1993Assignee: BASF AktiengesellschaftInventors: Karl-Heinz Etzbach, Gerhard Wagenblast, Wolfgang Brox, Axel Paul, Volker Bach
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Patent number: 5185143Abstract: What is described herein is solution polymerization in acetone solvent of a monomer mixture of maleic anhydride, vinyl acetate and isobornyl acrylate or methacrylate.Type: GrantFiled: January 13, 1992Date of Patent: February 9, 1993Assignee: ISP Investments Inc.Inventor: Jeffrey M. Cohen
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Patent number: 5182316Abstract: A curable composition, the cure of which can be monitored optically, comprises at least one of a hydride curable silicone, an ethylenically unsaturated compound, and a cationically polymerizable monomer, and as cure monitor dibenzofulvene or derivative thereof. The cure monitor is a latent fluorophore which reacts under the cure conditions to form a UV-detectable fluorophore.The invention also provides a method for measuring degree of cure of a polymeric material which can be a coating or an article.Type: GrantFiled: November 26, 1991Date of Patent: January 26, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Robert J. DeVoe, Katherine A. Brown-Wensley, George V. D. Tiers
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Patent number: 5164464Abstract: Thermosettable vinyl ester resin compositions are prepared from polyepoxide compounds, optionally, monoepoxide compounds, at least one of which contains a mesogenic or rigid rodlike moiety and a monounsaturated monocarboxylic acid. These vinyl ester resins can be mixed with polymerizable ethylenically unsaturated monomers which can, if desired, contain a mesogenic or rigid rodlike moiety.Type: GrantFiled: June 7, 1991Date of Patent: November 17, 1992Assignee: The Dow Chemical CompanyInventors: Robert E. Hefner, Jr., Jimmy D. Earls, Paul M. Puckett
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Patent number: 5159030Abstract: Compounds containing at least one alkenyl group, at least one maleimide group and at least one rodlike mesogenic moiety are prepared by reacting one or more aminophenols containing one or more rodlike mesogenic moieties with a stoichiometric quantity of a maleic anhydride per amine group of said aminophenol and then alkenylating the resulting phenolic functional maleimide.Type: GrantFiled: March 25, 1991Date of Patent: October 27, 1992Assignee: The Dow Chemical CompanyInventor: Robert E. Hefner, Jr.
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Patent number: 5157072Abstract: Cycloaliphatic compounds, which have one or more ethylenically unsaturated substituents, are disclosed as components of borehole-filling masses, optionally together with other curable components.Type: GrantFiled: December 4, 1990Date of Patent: October 20, 1992Assignee: Hilti AktiengesellschaftInventors: Ulrich Hense, Rudolf Hinterwaldner, Peter Mauthe
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Patent number: 5151475Abstract: This is an improvement upon a process which comprises anionically polymerizing monomers with an anionic polymerization initiator in a suitable solvent thereby creating a living polymer. The improvement comprises terminating the polymerization by the addition of a terminating agent selected from the group consisting of boranes, ammonia, halogens, hydrocarbons containing a C-H group where the carbon is connected directly to a triply-bound carbon or to two doubly-bound carbons and silanes.Type: GrantFiled: April 15, 1991Date of Patent: September 29, 1992Assignee: Shell Oil CompanyInventors: Craig A. Stevens, Carma J. Gibler, Linda R. Chamberlain, Thomas F. Brownscombe
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Patent number: 5145926Abstract: This invention relates to poly(aryl indane) polymers.Type: GrantFiled: March 26, 1990Date of Patent: September 8, 1992Assignee: Allied-Signal Inc.Inventors: Kundan M. Patel, Frank Mares
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Patent number: 5132390Abstract: The present invention is directed to liquid cyrstalline polyesters which are soluble and have low melting points. Preferably the solubility in halogenated solvent is greater than 10 wt. % and the crystalline melting point is less than 125.degree. C. The polyesters are thermotropic and nematic, and preferably have a number average molecular weight from 1,000 to 25,000. The polyesters include a cyclohexane ring in the backbone and are more particularly main-chain thermotropic polyester which contain trans-1,4 cyclohexane dicarboxylate mesogens and flexible spacer groups. These compositions are useful in coating applications including floor coverings.Type: GrantFiled: May 13, 1991Date of Patent: July 21, 1992Assignee: Armstrong World Industries, Inc.Inventors: Roman C. Domszy, Paul J. Shannon
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Patent number: 5124240Abstract: An optical recording medium consists essentially of a base material and a light-absorbing layer which contains a thermoplastic binder and at least one dye, wherein the thermoplastic binder is a polycyclic hydrocarbon which has a glass transition temperature Tg of greater than 150.degree. C. and is soluble to more than 3% by weight in an aliphatic or aromatic hydrocarbon.Type: GrantFiled: March 16, 1990Date of Patent: June 23, 1992Inventors: Sibylle Brosius, Bernhard Albert, Michael Schmitt, Klaus D. Schomann, Harald Kuppelmaier, Ulrich Harten
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Patent number: 5118773Abstract: Herein is disclosed a vulcanizable rubber composition comprising a copolymer rubber constituted of ethylene, propylene and nonconjugated polyene, wherein ethylene/propylene molar ratio is 78/22 to 97/3 and the total content of propylene and nonconjugated polyene is 6 to 30% by mole in said copolymer rubber. By the use of the rubber composition of the present invention, a vulcanized product excellent in tensile strength, heat resistance, oil resistance, compression set resistance and flex behavior can be obtained. The vulcanized product can be used as automobile parts and other innumerable articles such as socket cover, heat resistant hose, electric wire, condenser cap, heat resistant belt, vibration-proof rubber, hoses weather strip, seal sponge, black side wall of tire, etc.Type: GrantFiled: October 30, 1991Date of Patent: June 2, 1992Assignee: Sumitomo Chemical Company, LimitedInventors: Hiroyoshi Takao, Hiroyuki Harada, Kiyoyuki Sugimori, Nobuyuki Yoshida, Masahiro Fukuyama, Hideaki Yamada, Junichi Koshiba
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Patent number: 5098973Abstract: The invention relates to a hardening resin composition including a monomer represented by the formulas (1) or (2), a monomer represented by the formula (3), and epoxyacrylate or epoxymethacrylate. This composition is easily hardened at low temperature, weak in odor, small in shrinkage in hardening, excellent during durability against water and hot water, and thus suitable as the flooring material for a food processing factory, refrigerated warehouse, and cold storage. ##STR1## where R.sup.1 to R.sup.6, p and r are as defined.Type: GrantFiled: May 23, 1990Date of Patent: March 24, 1992Assignees: Sumitomo Rubber Industries Ltd., Nippon Kayaku Kabushiki KaishaInventors: Soichiro Kozuka, Tetsuya Kojimoto, Minoru Yokoshima
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Patent number: 5091492Abstract: A resin composition for use as a paint contains a copolymer prepared by copolymerizing a monomer (I) represented by the following formula (I): ##STR1## wherein either one of X.sub.1 and X.sub.2 stands for an acryloyloxy or methacryloyloxy group, the other being a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; R.sub.1 to R.sub.10 each stand for a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; and n is an integer of 1 to 4; with an .alpha.,.beta.-ethylenically unsaturated monomer having a reactive functional group and an .alpha.,.beta.-ethylenically unsaturated monomer having no reactive functional group. A monomer mixture for preparing the copolymer contains 5 to 95 wt % of the monomer (I).Type: GrantFiled: August 7, 1990Date of Patent: February 25, 1992Assignees: Nippon Oil and Fats Co., Ltd., Mitsui Petrochemical Industries, Ltd.Inventors: Masahiro Ishidoya, Kishio Shibato, Osamu Ohe, Masaaki Kawasaki
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Patent number: 5077367Abstract: Syndiotactic homopolymers of an arylcyclobutene functional monomer and syndiotactic copolymers of an arylcyclobutene functional monomer and a vinylaromatic monomer are prepared by conducting the polymerization in the presence of a catalytic amount of a suitable coordination catalyst such as the reaction product of polymethylaluminoxane and a transition metal compound.Type: GrantFiled: June 22, 1990Date of Patent: December 31, 1991Assignee: The Dow Chemical CompanyInventors: Richard E. Campbell, Jr., Robert A. DeVries
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Patent number: 5047444Abstract: A curable composition, the cure of which can be monitored optically, comprises at least one of a hydride curable silicone, an ethylenically unsaturated compound, and a cationically polymerizable monomer, and as cure monitor dibenzofulvene or derivatives thereof. The cure monitor is a latent fluorophore which reacts under the cure conditions to form a UV-detectable fluorophore.The invention also provides a method for measuring degree of cure of a polymeric material which can be a coating or an article.Type: GrantFiled: May 31, 1989Date of Patent: September 10, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventors: Robert J. DeVoe, Katherine A. Brown-Wensley, George V. D. Tiers
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Patent number: 5002853Abstract: The present invention relates to a positive working photosensitive composition having an improved sensitivity due to the use of a sensitizer and having an excellent incandescent light safety. This composition comprises at least 1 molar % of a structural unit derived from at least one of monomers having the following general formulae: ##STR1## wherein: R.sub.1 represents a hydrogen atom, an alkyl group or a substituted alkyl group,R.sub.2 represents a divalent alkylene group or a substituted divalent alkylene group,R.sub.3, R.sub.4 and R.sub.5 may be the same as or different from each other and each represents an alkyl group, a substituted alkyl group, an aryl group or a substituted aryl group,R.sub.6 and R.sub.7 may be the same as or different from each other and each represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group or a substituted aryl group,Ar.sub.1 represents a single bond or Ar.sub.2, andAr.sub.Type: GrantFiled: October 5, 1989Date of Patent: March 26, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiaki Aoai, Teruo Nagano
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Patent number: 4997897Abstract: Dye monomers of the general chemical formula ##STR1## where X denotes an unsaturated polymerizable organic radical; andR is an organic diradical with 2 to 12 carbon atoms.Type: GrantFiled: August 3, 1990Date of Patent: March 5, 1991Assignee: Bausch & Lomb IncorporatedInventor: John B. Melpolder
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Patent number: 4965329Abstract: The invention is a compound which comprises an unsaturated cyclic imide moiety and an aryl cyclobutene moiety, wherein the cyclobutene moiety is fused to the aryl radical, and wherein the imide nitrogen is connected to the aryl radical by a direct bond or a bridging member. Another aspect of this invention is a polyimide polymeric composition which results from the polymerization of the above-described compounds.Type: GrantFiled: January 13, 1989Date of Patent: October 23, 1990Assignee: The Dow Chemical CompanyInventor: Robert A. Kirchhoff
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Patent number: 4962163Abstract: Thermosettable vinyl ester compositions are prepared from an advanced epoxy resin containing a mesogenic or rodlike moiety and a monounsaturated monocarboxylic acid and, optionally, a monoepoxide compound. These vinyl ester compounds can be mixed with polymerizable ethylenically unsaturated monomers which can, if desired, contain a mesogenic or rigid rodlike moiety.Type: GrantFiled: January 17, 1989Date of Patent: October 9, 1990Assignee: The Dow Chemical CompanyInventors: Robert E. Hefner, Jr., Jimmy D. Earls, Paul M. Puckett
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Patent number: 4943617Abstract: A liquid crystalline copolymer contains a comonomer to which a radical ##STR1## is bonded, where X is a chemical bond, O or NR.sup.1, Y is a chemical bond or --CO--, R.sup.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl and A is a linear or branched C.sub.2 -C.sub.20 -alkylene group which may be interrupted by --O-- or ##STR2## The liquid crystalline copolymers have very good lightfastness, high dichroism and a high absorption.Type: GrantFiled: September 1, 1987Date of Patent: July 24, 1990Assignee: BASF AktiengesellschaftInventors: Karl-Heinz Etzbach, Bernd Hisgen
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Patent number: 4937292Abstract: Photochemical conversion of tachysterols to previtamins is conducted in the presence of a polymeric photosensitizer which has the appropriate chromophore groups, e.g. anthracene groups, attached to a medium or high molecular weight, substantially uncrosslinked polymer backbone. The polymeric photosensitizer is soluble in solvents normally used for conducting the photochemical reaction (diethyl ether, dioxane, THF, t.butyl methyl ether) but insoluble in lower alcohols and hydrocarbons, so that it may be readily and simply recovered from the product mixture by use of such non-solvents.Type: GrantFiled: July 9, 1987Date of Patent: June 26, 1990Assignee: Solavchem Enterprises Inc.Inventor: Clarke E. Slemon
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Patent number: 4910119Abstract: New polymers comprising repeat units represented by the formula ##STR1## where R is a hydrogen or a halogen atom, a cyanide group or an alkyl group,R1, R2 and R3 are identical or different, and each denotes a hydrogen or a halogen atom, an alkyl group, an alkoxy group or an alkoxycarbonyl group,R4 is a hydrogen atom or a divalent radical,A denotes the atoms required for completing a mononuclear or dinuclear aromatic ring system andm is 2 or 3,are used as binders in positive-working, radiation-sensitive recording materials.Type: GrantFiled: September 15, 1988Date of Patent: March 20, 1990Assignee: Hoechst AktiengesellschaftInventors: Arnold Schneller, Juergen Sander
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Patent number: 4812542Abstract: Copolymers containing from 5 to 50 mol % of monomers having o-nitrocarbinol ester groups, from 95 to 50 mol % of O-substituted p-hydroxystyrene and from 0 to 30 mol % of other copolymerizable monomers are useful for producing positive-working photoresists and light-sensitive coating materials.Type: GrantFiled: December 8, 1987Date of Patent: March 14, 1989Assignee: BASF AktiengesellschaftInventors: Reinhold Schwalm, Horst Binder
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Patent number: 4795794Abstract: Disclosed is a dispersion polymerization process for affecting the preparation of particles which comprises dissolving in a suitable solvent a mixture of at least two first monomer components including at least one second monomer having covalently attached thereto a dye moiety, subsequently adding to the reaction mixture a polymerization initiator, thereafter affecting polymerization of the reaction mixture by heating, and separating the product particles therefrom.Type: GrantFiled: October 3, 1985Date of Patent: January 3, 1989Assignee: Xerox CorporationInventors: Francoise M. Winnik, Christopher K. Ober, Melvin D. Croucher