From Hydrocarbon Monomer Containing At Least Two Ethylenic Groups, E.g., Butadiene, Etc. Patents (Class 526/335)
  • Publication number: 20090312496
    Abstract: Carboxylate terminated thiocarbonates are reacted with a polyfunctional alcohol to form a hydroxyl-terminated thiocarbonate compound.
    Type: Application
    Filed: June 4, 2009
    Publication date: December 17, 2009
    Inventors: John Ta-Yuan Lai, Ronald P. Shea
  • Patent number: 7632889
    Abstract: A cleaning blade, for use in an image-forming apparatus, formed by a molded resin composition containing a rubber component consisting of a thermosetting elastomer containing acrylonitrile as a constituent monomer thereof and having a bound acrylonitrile amount of 15 to 50%.
    Type: Grant
    Filed: September 13, 2006
    Date of Patent: December 15, 2009
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventor: Mutsuki Sugimoto
  • Patent number: 7625979
    Abstract: Lithium-terminated polymers of one or more conjugated dienes and of one or more mono alkenyl arenes are coupled by reaction with an alkoxy silane coupling agent having the formula Rx—Si—(OR?)y, where x is 0 or 1, x+y=4, R and R? are the same or different, R is selected from aryl hydrocarbon radicals, linear alkyl hydrocarbon radicals and branched alkyl hydrocarbon radicals, and R? is selected from linear and branched alkyl hydrocarbon radicals, such that the resulting polymer composition contains less than about ten weight percent of uncoupled polymer diblock. The polymer compositions are subsequently selectively hydrogenated, and are useful in a variety of compounds and end use applications.
    Type: Grant
    Filed: June 4, 2003
    Date of Patent: December 1, 2009
    Assignee: Kraton Polymers U.S. LLC
    Inventors: Harvey E. Atwood, Robert C. Bening, Mark Hageman, Dale L. Handlin, Jr., Adrie A van der Huizen, Kimberly A. Johnson, Carl L. Willis
  • Patent number: 7608658
    Abstract: This invention discloses a process for manufacturing an elastomeric article by liquid injection molding, said process comprising the steps of: (I) heating a curable composition comprised of (1) a liquid polymer comprised of repeat units that are derived from a conjugated diolefin monomer, wherein said liquid polymer has a weight average molecular weight which is within the range of 5,000 to 100,000, and wherein the liquid polymer is functionalized with an amine moiety, (2) a carbonyl inhibited platinum catalyst, and (3) a tetrakis(dialkyl siloxy) silane crosslinking agent, to a temperature which is within the range of 30° C. to 100° C.; (II) injecting the heated curable composition into a mold at a temperature which is within the range of 100° C. to 210° C. to produce the elastomeric article; and (III) removing the elastomeric article from the mold.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: October 27, 2009
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Michael Joseph Rachita, Vanessa Marika Guscoff, Lawson Gibson Wideman
  • Patent number: 7605217
    Abstract: The present invention provides a crosslinked propylene-based elastomer having an isotactic propylene triad tacticity of from 65 to 95%, a melting point by DSC equal to or less than 110° C., a heat of fusion of from 5 J/g to 50 J/g, an ultimate tensile strength of 1 MPa or greater, a Die C tear strength of 50 lb/in or greater, and a ratio of Shore A hardness to MFR@230° C. prior to crosslinking of 160 or less, and comprising at least 75 wt % propylene-derived units, at least 5 wt % ethylene-derived units, and from 0.3 to 10 wt % diene-derived units. The present invention also provides elastomeric compositions comprising a crosslinked propylene-based elastomer as described herein and from 0 to 5 parts by weight of carbon black per 100 parts of polymer. The present invention also provides articles such as films, fibers, nonwovens, molded objects, and extruded forms which include any of the inventive compositions described herein.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: October 20, 2009
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sudhin Datta, Abdelhadi Sahnoune
  • Patent number: 7585918
    Abstract: A block polymer compound containing block segments, characterized in that at least one hydrophilic segment among the block segments is a copolymer segment composed of an ionic or hydrophilic repeating unit structure and a hydrophobic repeating unit structure.
    Type: Grant
    Filed: September 30, 2004
    Date of Patent: September 8, 2009
    Assignee: Canon Kabushiki Kaisha
    Inventors: Koichi Sato, Ikuo Nakazawa, Sakae Suda, Ryuji Higashi, Masayuki Ikegami, Keiichiro Tsubaki
  • Patent number: 7582715
    Abstract: The invention relates to new polymerization processes including diluents including hydrofluorocarbons and their use to produce novel polymers substantially free of long chain branching. In particular, the invention relates to copolymers of an isoolefin, preferably isobutylene, and a multiolefin, preferably a conjugated diene, more preferably isoprene, substantially free of long chain branching.
    Type: Grant
    Filed: December 19, 2003
    Date of Patent: September 1, 2009
    Assignee: Exxonmobil Chemical Patents Inc.
    Inventors: Scott Thomas Milner, Timothy Daniel Shaffer, David Yen-Lung Chung
  • Publication number: 20090210987
    Abstract: A hypoallergenic wetsuit and material is described that uses closed cell acrylonitrile butadiene rubber in place of neoprene to eliminate the problems associated with neoprene and rubber allergies. In sonic embodiments of the present invention, polyvinyl chloride (PVC) is blended with the acrylonitrile butadiene rubber. The density of the closed cell acrylonitrile butadiene rubber may vary depending on the hypoallergenic wetsuit application. Low densities such as less than 70 kg./m3, and preferably 50 to 61 Kg./m3, are desirable in many applications.
    Type: Application
    Filed: February 26, 2009
    Publication date: August 27, 2009
    Inventor: Carl Lee Demetropoulos
  • Patent number: 7579057
    Abstract: A resin molded article which is a molded article obtained by irradiating a resin molded article containing 100 to 60 parts by weight of (A) syndiotactic 1,2-polybutadiene having a crystallinity of 5% or more and 0 to 40 parts by weight of (B) another thermoplastic polymer with an electron beam, in which the 50% stress of the molded article after the electron beam irradiation (50% M:M2) is from 1.01 to 2.5 times the 50% stress before the electron beam irradiation (50% M:M1), and the molded article has steam sterilization resistance. The molded article is excellent in flexibility and hardness, excellent in steam sterilization resistance, and useful for medical applications such as an infusion tube, an infusion solution container, a catheter and the like.
    Type: Grant
    Filed: March 23, 2004
    Date of Patent: August 25, 2009
    Assignee: JSR Corporation
    Inventors: Teruo Aoyama, Minoru Furuichi
  • Patent number: 7566745
    Abstract: A subject for the invention is to provide a method of refractive index regulation by which the refractive index of an optical polymer molding can be efficiently changed without necessitating a complicated step, such as the step of oxidizing beforehand, and which when used for producing an optical device, imparts excellent transparency thereto. Another subject is to provide a photochemically refractive-index-changing polymer or photochemically refractive-index-changing polymer composition for use in the method.
    Type: Grant
    Filed: October 1, 2004
    Date of Patent: July 28, 2009
    Assignee: Nitto Denko Corporation
    Inventors: Yoshihide Kawaguchi, Yutaka Moroishi, Tetsuo Inoue, Kazunori Mune
  • Publication number: 20090171046
    Abstract: A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing employs a lanthanide-based catalyst system.
    Type: Application
    Filed: December 31, 2007
    Publication date: July 2, 2009
    Inventors: Steven Luo, Kevin M. McCauley, Jason T. Poulton
  • Publication number: 20090163685
    Abstract: A method for producing a photocurable liquid resin which comprises (A) a step of producing a conjugated diene-based polymer or a conjugated diene/aromatic vinyl-based copolymer, which has a weight-average molecular weight of 5,000 to 40,000 and a molecular weight distribution of 3.
    Type: Application
    Filed: November 21, 2006
    Publication date: June 25, 2009
    Applicant: Bridgestone Corporation
    Inventors: Toshiki Takizawa, Naoyuki Ohmori
  • Publication number: 20090124730
    Abstract: A primary modified polymer composed of (1) a hydrogenated polymer obtained by hydrogenating at least one non-hydrogenated polymer selected from the group consisting of polymers comprising conjugated diene monomer units and copolymers comprising conjugated diene monomer units and vinyl aromatic monomer units and (2) groups of a primary modifier having a functional group which are bonded to the polymer (1), which has a specific vinyl aromatic monomer unit content, a specific vinyl aromatic polymer block content, a specific weight-average molecular weight, and a specific degree of hydrogenation of the double bonds of conjugated diene monomer units; a secondary modified polymer obtained by reacting a primary modified polymer composed of (?) a base polymer and (?) groups of a primary modifier having a functional group which are bonded to the polymer (?) with a secondary modifier; and compositions comprising the primary or secondary modified polymer and at least one other component.
    Type: Application
    Filed: December 22, 2008
    Publication date: May 14, 2009
    Inventors: Takaaki Matsuda, Shigeki Takayama, Toshinori Shiraki, Shigeo Nakajima, Yasuhiro Kusanose
  • Patent number: 7528204
    Abstract: The present invention discloses a process for synthesizing a hydrogenated polymer that comprises: (1) preparing a aqueous polymerization medium which is comprised of (a) at least one monomer, (b) a polymerization control agent, and an emulsifier, wherein the emulsifier is prepared in-situ within the aqueous polymerization medium; (2) initiating polymerization of said monomer within the aqueous polymerization medium to produce a latex of an unsaturated polymer; (3) treating the latex of the unsaturated polymer with (a) an oxidant selected from the group consisting of oxygen, air and hydroperoxides; (b) a reducing agent selected from the group consisting of hydrazine and hydrates of hydrazine; and (c) a metal ion activator to produce the hydrogenated polymer.
    Type: Grant
    Filed: May 2, 2005
    Date of Patent: May 5, 2009
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Dane Kenton Parker, Frank James Feher, Viswanath Mahadevan
  • Patent number: 7524908
    Abstract: A copolymerized high polymer film includes plural organic polymers, as skeleton, and is manufactured by blowing more than two kinds of organic monomers of respectively specific structures, in a vapor phase condition, onto the surface of a heated substrate, through plasma being generated in a reaction chamber. As a result, manufacture of an organic high polymer film capable of further reducing the effective relative permittivity of organic polymer films as a whole can be achieved, and, at the same time, further improvement in mechanical strength of film as well as film forming speed can be achieved.
    Type: Grant
    Filed: May 27, 2005
    Date of Patent: April 28, 2009
    Assignee: NEC Corporation
    Inventors: Jun Kawahara, Keizo Kinoshita, Nobutaka Kunimi, Akinori Nakano
  • Publication number: 20090099325
    Abstract: A method for preparing a functionalized polymer, the method comprising the steps of preparing a reactive polymer and reacting the reactive polymer with a heterocyclic nitrile compound.
    Type: Application
    Filed: June 23, 2008
    Publication date: April 16, 2009
    Inventors: Steven Luo, Ryouji Tanaka, Kouichirou Tani
  • Patent number: 7504457
    Abstract: A method of forming a functionalized polymer, the method comprising reacting a living polymer with a compound defined by the formula where R5 includes a monovalent organic group, R6 independently includes a monovalent organic group, each R7 independently includes hydrogen or a monovalent organic group, each R8 independently includes hydrogen or monovalent organic group, R9 includes a monovalent organic group, M is silicon or tin, and x includes an integer from about 2 to about 10, where R5 and R6 may optionally each independently be alkoxy groups, and where R7, R8, and R9 are non-Zerewitinoff organic groups.
    Type: Grant
    Filed: January 13, 2006
    Date of Patent: March 17, 2009
    Assignee: Bridgestone Corporation
    Inventors: Terrence E. Hogan, Christine Rademacher, David F. Lawson, H. James Harwood
  • Publication number: 20090069520
    Abstract: Provided is a method for polymerizing a polymer precursor, comprising: contacting a polymer precursor with a lithium carborane catalyst and an initiator under polymerizing conditions. A reaction solvent may be used, but is not necessary. Also provided is a method of preparing lithium carborane polymers, comprising: contacting a lithium carborane polymer precursor having a terminal alkenyl or alkynyl group with an initiator and an optional reaction solvent under polymerizing conditions. Functionalized carborane anions are also provided.
    Type: Application
    Filed: August 4, 2006
    Publication date: March 12, 2009
    Inventors: Josef Michel, Kamesh Vyakaranam, Stefanie Korbe
  • Publication number: 20090062495
    Abstract: A process for the solution polymerization of olefins with improved on-stream time is provided. The solution polymerization process of the current invention comprises a method for the on-line removal of foulant material from one or more heat exchangers downstream of a polymerization reactor. Removal of foulant material is accomplished by deliberately applying a positive pressure differential across a heat exchanger. In the process of the current invention, reactor shut down is not required for the purpose of cleaning foulant material from a heat exchanger.
    Type: Application
    Filed: August 22, 2008
    Publication date: March 5, 2009
    Inventors: Eric Cheluget, Arun Sood, Rob VanAsseldonk, Ryan McCabe
  • Publication number: 20090030168
    Abstract: Redispersible polymer powders which are cationically stabilized by spray drying a polymer dispersion with a cationic polymer can be used in higher concentrations in chemical building construction materials without introducing adverse properties.
    Type: Application
    Filed: February 8, 2007
    Publication date: January 29, 2009
    Applicant: WACKER POLYMER SYSTEMS GMBH & CO. KG
    Inventors: Andrea Schorm, Hans-Peter Weitzel, Stefan Killat, Hermann Lutz
  • Publication number: 20090018297
    Abstract: A halogenated butyl polymer having improved properties, the butyl polymer derived from a monomer mixture comprising a C4 to C8 monoolefin monomer, a C4 to C14 multiolefin monomer and a styrenic monomer with a catalyst system to produce the butyl polymer. The improved properties include faster cure, higher maximum torque, higher delta torque, relatively stable modulus over time, improved hot air aging properties and improved aged flexure properties. These improved properties are believed to result from direct interaction between the styrenic moieties in the polymer backbone with a crosslinking agent added to vulcanize the halogenated butyl rubber.
    Type: Application
    Filed: June 3, 2008
    Publication date: January 15, 2009
    Inventor: Gabor Kaszas
  • Publication number: 20090013446
    Abstract: A test for determining whether an elastomeric article has a desired ratio of strength to comfort, i.e., a strength-comfort index, is disclosed. Methods for preparing strong, soft, and thin articles from synthetic latexes, to optimize the strength and comfort of the articles, are also disclosed. Using this index, and, optionally, comparing the results with those one obtained using natural rubber, one can determine whether an article of manufacture can be prepared from synthetic elastomers and still have optimal properties (i.e., strength and comfort), particularly as compared to a similar article prepared from natural rubber. The strength of an article is directly related to the force required to break a tensile specimen of the sample and thus the tensile strength of the article.
    Type: Application
    Filed: July 10, 2008
    Publication date: January 15, 2009
    Applicant: Dow Reichhold Specialty Latex, LLC
    Inventors: Kevin Grant Suddaby, Neil Douglas Redpath, Alicia Lee Sellers
  • Publication number: 20090005496
    Abstract: A method for producing a conjugated diene polymer is provided that includes a step of polymerizing a conjugated diene-containing monomer in a hydrocarbon solvent in the presence of an alkali metal catalyst, thus giving a polymer having a catalyst-derived alkali metal at one terminus of a polymer chain comprising a conjugated diene-based monomer unit, and a step of reacting the polymer obtained in the step of polymerizing and a trialkoxysilane compound represented by the formula below. (In the formula, M denotes an oxygen atom or a sulfur atom, R1, R2, and R3 independently denote an alkyl group having 1 to 4 carbon atoms, m denotes an integer of 1 to 5, and n denotes an integer of 0 to 5.
    Type: Application
    Filed: June 17, 2008
    Publication date: January 1, 2009
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Naoaki MAEDA, Mayumi Oshima, Katsunari Inagaki
  • Publication number: 20090005519
    Abstract: The invention concerns novel cytosine based modules and in particular their application in linear multiple hydrogen bonded arrays to form supramolecular polymers of the formula (II): and the use of these in supramolecular materials.
    Type: Application
    Filed: December 20, 2006
    Publication date: January 1, 2009
    Inventors: Kason Bala, Helen Claire Hailes, Valerie Gisele Helene Lafitte, Abil Aliev, Peter Golding
  • Patent number: 7470760
    Abstract: The present invention relates to a linear or branched diene elastomer having cyclic vinyl units. A linear diene elastomer according to the invention results from at least one conjugated diene and it comprises cyclic vinyl units in a mass content of greater than or equal to 15% while having a number-average molecular weight falling within a range of from 10,000 to 300,000 g/mol.
    Type: Grant
    Filed: January 14, 2004
    Date of Patent: December 30, 2008
    Assignee: Michelin Recherche Et Technique, S.A.
    Inventors: Jean-Luc Cabioch, Laurent Coissieux, Nicole Dajoux
  • Patent number: 7470744
    Abstract: A copolymer useful as a demulsifier or water clarifier may be prepared by polymerizing at least one aromatic monomer having one or more polymerizable double bonds; at least one oleophilic monomer having one or more polymerizable double bonds; at least one ionizable monomer having a polymerizable double bond; and at least one hydrophilic monomer having one or more polymerizable double bonds, under polymerization conditions sufficient to prepare a copolymer. The copolymer may, in some embodiments, be prepared and used as a latex.
    Type: Grant
    Filed: April 12, 2006
    Date of Patent: December 30, 2008
    Assignee: Baker Hughes Incorporated
    Inventor: Jacqueline Behles
  • Patent number: 7462677
    Abstract: An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
    Type: Grant
    Filed: September 13, 2007
    Date of Patent: December 9, 2008
    Assignee: Bridgestone Corporation
    Inventors: Terrence E. Hogan, William Hergenrother, Yuan-Yong Yan, David Lawson
  • Publication number: 20080300348
    Abstract: The application provides a method of producing a comb polymer comprising the steps of: (a) Providing: (i) a plurality of monomers which are linear, branched or star-shaped, substituted or non-substituted, and have an olefinically unsaturated moiety, the olefinically unsaturated moiety being capable of undergoing addition polymerisation; (ii) an initiator compound; the initiator compound comprising a homolytically cleavable bond. (iii) a catalyst capable of catalysing the polymerisation of the monomer; and (b) Causing the catalyst to catalyse, in combination with the initiator, the polymerisation of a plurality of the monomers to produce the comb polymer. Catalysts and polymers obtainable by the process are also provided. Preferably, the comb polymer is capable of binding proteins and may be produced from monomers which are alkoxy polyethers, such as poly(alkyleneglycol) or polytetrahydrofuran.
    Type: Application
    Filed: August 3, 2006
    Publication date: December 4, 2008
    Inventors: David Haddleton, Francois LeColley, Lei Tao, Giuseppe Mantovani, Adrian Carmichael, Adam Peter Jarvis, Andrew Gregory Steward
  • Publication number: 20080293849
    Abstract: The present invention pertains to a nanocomposite material comprising rubber and a modified layered double hydroxide comprising: a charge-balancing organic ion having a first functional group and a second functional group, wherein at least part of the organic anions is chemically linked to the rubber through the second functional group; and/or a silane coupling agent having at least one alkoxysilane group and at least one reactive group, at least one alkoxysilane group being chemically linked to the layered double hydroxide, at least one reactive group being chemically linked to the rubber. The invention further pertains to a process for preparing the nanocomposite material or a precursor thereof.
    Type: Application
    Filed: December 1, 2006
    Publication date: November 27, 2008
    Applicant: VELPERWEG 76
    Inventors: Robin Winters, Haimo Tonnaer, Elwin Schomaker
  • Publication number: 20080287559
    Abstract: A thermally stable brominated butadiene copolymer, such as brominated styrene/butadiene block copolymer, brominated random styrene/butadiene copolymer or brominated styrene/butadiene graft copolymer, preparation of the brominated butadiene copolymers, use of the brominated butadiene copolymers as a flame retardant additive and polymeric compositions, both foamed and non-foamed, that incorporate a flame-retarding amount of brominated butadiene copolymer.
    Type: Application
    Filed: October 23, 2006
    Publication date: November 20, 2008
    Inventors: Bruce A. King, William G. Stobby, Daniel J. Murray, Anteneh Z. Worku, Inken Beulich, Sheila M. Tinetti, Stephen F. Hahn, Ray E. Drumright
  • Publication number: 20080255314
    Abstract: A dip-forming latex obtained by copolymerization of (a) 50-89.5 weight parts of a conjugated diene monomer, (b) 10-40 weight parts of an ethylenically unsaturated nitrile monomer, (c) 0.5-10 weight parts of an ethylenically unsaturated acid monomer and (d) 0-20 weight parts of other copolymerizable ethylenically unsaturated monomer (the total of these monomers is 100 weight parts), wherein the copolymerization is initiated with a monomer mixture comprising at least 80 wt. % of (a), at least 50 wt. % of (b), 10-90 wt. % of (c) and least 80 wt. % of (d), and thereafter, the remainders of monomers are added to a polymerization system to continue copolymerization. This latex gives a dip-formed article exhibiting good softness of touch, high tensile strength and good retention of close fittingness.
    Type: Application
    Filed: August 3, 2007
    Publication date: October 16, 2008
    Inventors: Hisanori Ota, Shunjin Aihara, Kazumi Kodama
  • Publication number: 20080249262
    Abstract: Copolymers of ethylene and alpha-olefins having (a) a density in the range 0.900-0.940 g/cm3, (b) a molecular weight distribution (Mw/Mn) in the range 3.5 to 4.5, (c) a melt elastic modulus G? (G?=500 Pa) in the range 40 to 150 Pa and (d) an activation energy of flow (Ea) in the range 28-45 kJ/mol. are suitably prepared in the gas phase by use of a supported metallocene catalyst system. The novel copolymers show improved processability and are particular suitable for use in blown film applications.
    Type: Application
    Filed: January 27, 2006
    Publication date: October 9, 2008
    Applicant: Ineos Europe Limited
    Inventor: Choon Kooi Chai
  • Patent number: 7432337
    Abstract: The present invention provides a rubber composition for coating carcass cord improving adhesive property to the carcass cord and further suppressing the crack growth, heat generation and lowering of rubber property, and a carcass cord coated thereby. A rubber composition for coating carcass cord comprising 3 to 10 parts by weight of zinc oxide, 0.5 to 5 parts by weight of resorcin condensate or modified resorcin condensate and 0.5 to 5 parts by weight of partial condensate of hexamethylol melamine pentamethyl ether or partial condensate of hexa methoxy methylol melamine based on 100 parts by weight of a rubber component comprising 40 to 80% by weight of natural rubber or isoprene rubber, 10 to 30% by weight of butadiene rubber and 10 to 40% by weight of styrene butadiene rubber.
    Type: Grant
    Filed: May 2, 2006
    Date of Patent: October 7, 2008
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventor: Tatsuya Miyazaki
  • Publication number: 20080242813
    Abstract: This invention discloses a process for synthesizing a hairy polymer particle which comprises the steps of (1) polymerizing a vinyl aromatic monomer by emulsion polymerization in an aqueous medium to produce core particles, (2) recovering the core particles from the aqueous medium, (3) dispersing the core particles in an organic solvent, (4) adding an organo-lithium compound to the dried core particles in the organic solvent to produce the hairless core initiator, and (5) utilizing the hairless core initiator to initiate the anionic polymerization of a conjugated diolefin monomer in an organic solvent to produce a solution of the hairy polymer particles. The hairy polymer nanoparticles can then be recovered from the organic solvent. These hairy polymer particles are comprised of (1) a core which is comprised of a polymer of a vinyl aromatic monomer and (2) hairs which are polymer chains of a conjugated diolefin monomer, wherein the hairs are covalently bonded to the core.
    Type: Application
    Filed: June 10, 2008
    Publication date: October 2, 2008
    Applicant: The Goodyear Tire & Rubber Company
    Inventors: Lei Zheng, Eric Sean Castner, Thierry Florent Edme Materne
  • Publication number: 20080228253
    Abstract: The invention relates to surface modifying macromolecules (SMMs) having high degradation temperatures and their use in the manufacture of articles made from base polymers which require high temperature processing. The surface modifier is admixed with the base polymer to impart alcohol and water repellency properties.
    Type: Application
    Filed: December 14, 2007
    Publication date: September 18, 2008
    Inventors: Sanjoy Mullick, Richard Witmeyer, Paul Santerre, Weilun Chang
  • Patent number: 7420012
    Abstract: The rubber composition and the material suitable for preparing the rubber composition show high gas-barrier properties and being free from inhibition of vulcanization. The rubber composition is essentially composed of a rubber and a layered mineral filler treated with short chain alkyl ammonium salt.
    Type: Grant
    Filed: June 16, 2004
    Date of Patent: September 2, 2008
    Assignee: Bridgestone Corporation
    Inventors: Isao Hagiwara, Naruhiko Mashita, Hiroki Nakano, Katsuhiko Tsunoda
  • Patent number: 7417103
    Abstract: The present invention provides 3,4-isoprene-based polymer with high regioregularity, in particular high tacticity. Specifically, the present invention provides an isoprene-based polymer, including a structural unit represented by Formula (I) in Claims, wherein the isotacticity of an arrangement of the structural units is 99% mmmm or more in terms of pentad content. Further, the present invention provides a production method for the isoprene-based polymer, which comprises polymerizing an isoprene-based compound in the presence of a polymerization catalyst containing a complex represented by the following Formula (A) in Claims.
    Type: Grant
    Filed: March 4, 2005
    Date of Patent: August 26, 2008
    Assignee: Riken
    Inventors: Zhaomin Hou, Lixin Zhang
  • Publication number: 20080194443
    Abstract: The invention relates to comb polymers which comprise, in the main chain, repeating units which are derived from polyolefin-based macromonomers, and repeating units which are derived from low molecular monomers which are selected from the group consisting of styrene monomers having 8-17 carbon atoms, alkyl(meth)acrylates having 1-10 carbon atoms in the alcohol group, vinyl esters having 1-11 carbon atoms in the acyl group, vinyl ethers having 1-10 carbon atoms in the alcohol group, (Di)alkylfumarates having 1-10 carbon atoms in the alcohol group, (Di)alkylmaleates having 1-10 carbon atoms in the alcohol group and mixtures of said monomers. The molar branching degree lies in the region between 0.1-10 mol. % and the comb polymer represents the sum of at least 80 wt.
    Type: Application
    Filed: April 7, 2006
    Publication date: August 14, 2008
    Applicant: ROHMAX ADDITIVES GMBH
    Inventors: Torsten Stohr, Boris Eisenberg, Michael Muller
  • Publication number: 20080182954
    Abstract: This invention relates to a method for producing functionalized cis-1,4-polydienes having a combination of a high cis-1,4-linkage content and a high functionality, the resulting polymers and the vulcanized products containing the polymers. The functionalized cis-1,4-polydienes of the present invention are produced by a method comprising the steps of: (1) preparing a reactive polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst in the presence of less than 20% by weight of organic solvent based on the total weight of monomer, organic solvent, and resulting polymer, where the lanthanide-based catalyst is the combination of or reaction product of (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a halogen-containing compound; and (2) contacting the reactive polymer with a functionalizing agent.
    Type: Application
    Filed: December 27, 2007
    Publication date: July 31, 2008
    Inventors: Steven Luo, Junko Kurazumi, Yoichi Ozawa, Timothy L. Tartamella, Mark Smale
  • Patent number: 7402271
    Abstract: A golf ball comprising a layer made from a liquid rubber composition is disclosed. A castable liquid polybutadiene is the preferred principal rubber component. The molecular weight of the castable liquid polybutadiene is at least about 1,000 and the castable liquid polybutadiene is in a liquid state at room temperature. The castable liquid rubber layer can be a cover layer, a casing layer, an intermediate layer or a core layer.
    Type: Grant
    Filed: December 1, 2004
    Date of Patent: July 22, 2008
    Assignee: Acushnet Company
    Inventor: William E. Morgan
  • Patent number: 7396884
    Abstract: The present invention relates to a composition containing a hydrogenated nitrile-butadiene rubber (HNBR), a peroxide crosslinking system and a resorcinol-formaldehyde resin, to a process for the preparation of the composition, to the use of the composition as an adhesion promoter, and also to a multilayer product containing the composition according to the present invention.
    Type: Grant
    Filed: February 13, 2004
    Date of Patent: July 8, 2008
    Assignee: LANXESS Deutschland GmbH
    Inventor: Dirk Achten
  • Publication number: 20080153999
    Abstract: The invention related to a process for the polymerization of at least one aliphatic C2-20 or aromatic C4-20 hydrocarbyl mono- or multiolefin in the presence of a catalyst and an aluminum comprising co-catalyst, wherein the catalyst comprises a composition of a metal-organic reagent, a spectator ligand and optionally at least one equivalent of a hydrocarbylating agent. The invention further relates to a polymer obtainable by the process of the invention.
    Type: Application
    Filed: August 3, 2004
    Publication date: June 26, 2008
    Inventors: Edwin Ijpeij, Henricus Arts, Gerardus Van Doremaele, Felix Beijer, Francis van Der Burgt, Martin Zuideveld
  • Patent number: 7385018
    Abstract: The present invention involves a hydrogenated copolymer obtained by hydrogenating a copolymer having a softening point falling in a range of 45 to 55° C. determined by a ball & ring method, wherein the hydrogenated copolymer has a softening point of 85 to 95° C. determined by the ball & ring method, and a hot melt adhesive composition comprising this copolymer hydrogenated product. The hydrogenated copolymer of the present invention has a small weight reduction rate in heating and a good hue after heating. The hot melt adhesive composition comprising the same has excellent fluidity in heating and has a small heating loss and a small change in a hue in heating and has excellent heat stability.
    Type: Grant
    Filed: June 26, 2002
    Date of Patent: June 10, 2008
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Toshihiro Mine
  • Publication number: 20080113146
    Abstract: The present invention pertains to carpet and methods of making and recycling carpet. In one aspect, the carpet includes: a primary backing which has a face and a back surface; a plurality of fibers attached to the primary backing and extending from the face of the primary backing and exposed at the back surface of the primary backing; an adhesive composition backing; and an optional secondary backing adjacent to the adhesive backing. The method of making carpet includes extrusion coating the adhesive composition onto the back surface of a primary backing to form the adhesive composition backing. The method of recycling carpet can recover one or more polymeric carpet components.
    Type: Application
    Filed: November 13, 2007
    Publication date: May 15, 2008
    Inventors: Jeffrey Wright, Kellie Ballew
  • Publication number: 20080114136
    Abstract: The present invention provides 1) a complex comprising a mono-anionictridentate ligand, represented by the following general formula (I); 2) a polymerization catalyst composition, comprising the complex; and 3) a cis-1,4-isoprene polymer, a cis-1,4-butadiene polymer, a cis-1,4-isoprene-styrene copolymer, a cis-1,4-butadiene-styrene copolymer, a cis-1,4-butadiene-cis-1,4-isoprene copolymer, and a cis-1,4-butadiene-cis-1,4-isoprene-styrene copolymer, each of which has high-cis-1,4 content in a micro structure and a sharp molecular-weight distribution.
    Type: Application
    Filed: January 23, 2006
    Publication date: May 15, 2008
    Inventors: Toshiaki Suzuki, Lixin Zhang, Zhaomin Hou
  • Patent number: 7371805
    Abstract: A hydrogenated copolymer obtained by hydrogenating an unhydrogenated copolymer comprising conjugated diene monomer units and vinyl aromatic monomer units, the hydrogenated copolymer containing at least one hydrogenated copolymer block (B) which is obtained by hydrogenating an unhydrogenated random copolymer block comprised of conjugated diene monomer units and vinyl aromatic monomer units, wherein the hydrogenated copolymer has the following characteristics: the hydrogenated copolymer has a content of the vinyl aromatic monomer units of from more than 40% by weight to less than 95% by weight; at least one peak of loss tangent (tan ?) is observed at ?10 to 80° C. in a dynamic viscoelastic spectrum obtained with respect to the hydrogenated copolymer; and substantially no crystallization peak ascribed to the copolymer block (B) is observed at ?20 to 80° C. in a differential scanning calorimetry (DSC) chart obtained with respect to the hydrogenated copolymer.
    Type: Grant
    Filed: June 26, 2003
    Date of Patent: May 13, 2008
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Masahiro Sasagawa, Toshinori Shiraki, Shigeki Takayama, Shigeru Sasaki, Katsumi Suzuki, Takahiro Hisasue, Kazuo Moritou
  • Patent number: 7365144
    Abstract: Disclosed herein is a polypropylene composite composition. The polypropylene composite composition comprises 50 to 80% by weight of polypropylene, 6 to 30% by weight of talc, 10 to 30% by weight of a rubber, 3 to 15% by weight of glass bubbles, and 0.5 to 7% by weight of maleic anhydride polypropylene (MAH-PP). According to the composition, the compatibility between the glass bubbles and the polypropylene can be improved, thus enabling effective use of the glass bubbles. Therefore, when the composition is used to produce automotive components, such as automotive interior components, the fuel efficiency of automobiles can be improved due to weight reduction effects of polypropylene composites. In addition, since the composition uses colorless and odorless glass bubbles, it can remove an unpleasant smell generated from conventional interior components using talc and is thus environmentally friendly.
    Type: Grant
    Filed: September 15, 2006
    Date of Patent: April 29, 2008
    Assignees: Hyundai Mobis Co., Ltd., GS Caltex Corporation
    Inventors: Suk Sun Ka, Myoung Seok Kim, Han Seok Song
  • Patent number: 7365143
    Abstract: Disclosed herein is a polypropylene composite composition. The polypropylene composite composition comprises 50 to 80% by weight of polypropylene, 6 to 30% by weight of talc, 10 to 30% by weight of a rubber, 3 to 15% by weight of glass bubbles, and 0.5 to 7% by weight of a coupling agent wherein the coupling agent is a compound represented by Formula 1 below: wherein n is an integer from 1 to 500. According to the composition, the compatibility between the glass bubbles and the polypropylene can be improved, thus enabling effective use of the glass bubbles. Therefore, when the composition is used to produce automotive components, such as automotive interior components, the fuel efficiency of automobiles can be improved due to weight reduction effects of polypropylene composites. In addition, since the composition uses colorless and odorless glass bubbles, it can remove an unpleasant smell generated from conventional interior components using talc and is thus environmentally friendly.
    Type: Grant
    Filed: September 15, 2006
    Date of Patent: April 29, 2008
    Assignees: Hyundai Mobis Co., Ltd., GS Caltex Corporation
    Inventors: Suk Sun Ka, Kwang Seob Shin, Han Seok Song
  • Patent number: 7358313
    Abstract: A rubber composition based on at least (i) an elastomer, (ii) a reinforcing filler and (iii) a thiouronium salt or an analogue of a thiouronium salt of the formula (I) below: A-S—Y—S-A ??(I) in which, A represents a group associated respectively with a molecule HX or an ion X—, X denoting a halogen atom and Z denoting Incorporating the thiouronium salt into the vulcanizable rubber composition makes it possible to substantially reduce the reversion rate of the vulcanized rubber composition.
    Type: Grant
    Filed: December 13, 2004
    Date of Patent: April 15, 2008
    Assignee: Michelin Recherche et Technique S.A.
    Inventors: Christiane Blanchard, Salvatore Pagano
  • Patent number: 7358314
    Abstract: An insulation composition that comprises at least one nitrile butadiene rubber (“NBR”) having an acrylonitrile content that ranges from approximately 26% by weight to approximately 35% by weight and polybenzoxazole (“PBO”) fibers. The NBR may be a copolymer of acrylonitrile and butadiene and may be present in the insulation composition in a range of from approximately 45% by weight to approximately 56% by weight of a total weight of the insulation composition. The PBO fibers may be present in a range of from approximately 3% by weight to approximately 10% by weight of a total weight of the insulation composition. A rocket motor including the insulation composition and a method of insulating a rocket motor are also disclosed.
    Type: Grant
    Filed: August 18, 2005
    Date of Patent: April 15, 2008
    Assignee: Alliant Techsystems Inc.
    Inventors: Himansu M. Gajiwala, David G. Guillot