From Hydrocarbon Monomer Containing At Least Two Ethylenic Groups, E.g., Butadiene, Etc. Patents (Class 526/335)
  • Patent number: 7354971
    Abstract: The invention concerns hydrous compositions based on polychloroprene and hydroxylamine derivatives, processes for their production and their use as adhesives. The polychloroprene dispersions are stabilized by the addition of hydroxyalkylamine after removal of residual monomer.
    Type: Grant
    Filed: January 10, 2007
    Date of Patent: April 8, 2008
    Assignee: Bayer MaterialScience AG
    Inventors: Rüdiger Musch, Knut Panskus, Andreas Steinert
  • Patent number: 7345128
    Abstract: The present invention relates to a peroxide curable rubber compound comprising at least one elastomeric polymer comprising repeating units derived from at least one C4 to C7 isomonoolefin monomer, at least one C4 to C14 multiolefin monomer and at least one m- or p-alkylstyrene monomer.
    Type: Grant
    Filed: April 29, 2004
    Date of Patent: March 18, 2008
    Assignee: Lanxess Inc.
    Inventors: Rui Resendes, Adam Gronowski
  • Patent number: 7342084
    Abstract: The present invention provides peroxidically crosslinked hydrogenated vinylpolybutadienes which serve for production of technical rubber products and which have very good recovery performance over a wide temperature range.
    Type: Grant
    Filed: September 15, 2006
    Date of Patent: March 11, 2008
    Assignee: LANXESS Deutschland GmbH
    Inventors: Werner Obrecht, Andreas Bischoff
  • Patent number: 7342070
    Abstract: Disclosed are a conjugated diolefin (co) polymer rubber formed from either a conjugated diolefin or a conjugated diolefin and an aromatic vinyl compound, wherein the (co) polymer rubber has a primary amino group and an alkoxysilyl group which are bonded to a (co) polymer chain; a process for producing the same; a rubber composition; a composite; and a tire. The (co) polymer rubber has satisfactory processability, and can give an automotive tire tread having a balance among wear resistance, failure characteristics, low hysteresis loss and wet-skid characteristics.
    Type: Grant
    Filed: September 25, 2002
    Date of Patent: March 11, 2008
    Assignee: JSR Corporation
    Inventors: Keisuke Tsukimawashi, Naokazu Kobayashi, Tsukasa Toyoshima, Toshihiro Tadaki, Kouta Taniguchi
  • Patent number: 7342053
    Abstract: Producing a printed circuit board, by coating a resin composition comprising an aromatic cyanate compound having two or more cyanato groups in a molecule and a radical-polymerizable resin on a circuit substrate, photo-curing the resin composition, and thermally curing the photo-cured resin composition to thereby form an insulation layer, affords an insulation layer with improved surface smoothness and excellent dielectric properties.
    Type: Grant
    Filed: January 28, 2005
    Date of Patent: March 11, 2008
    Assignee: Ajinomoto Co., Inc.
    Inventor: Shigeo Nakamura
  • Patent number: 7335714
    Abstract: The present invention is directed to sulfine control agents for synthesizing polymers via controlled free radical polymerization and to the polymers resulting therefrom. Such polymers include repeat units derived from the controlled free radical polymerization, particularly reversible atom fragmentation transfer (RAFT) polymerization, of at least one vinyl-containing monomer, at least one conjugated diene monomer, or combinations thereof, in the presence of a sulfine compound having the formula: wherein R1 is alkyl, cycloalkyl, substituted alkyl, heteroalkyl, heterocycloalkyl or substituted heterocycloalkyl, and wherein Y is alkyl, cycloalkyl, substituted alkyl, heteroalkyl, heterocycloalkyl, substituted heterocycloalkyl, aryl, substituted aryl, heteroaryl, substituted heteroaryl, alkoxy, amino or thio.
    Type: Grant
    Filed: January 18, 2007
    Date of Patent: February 26, 2008
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Frank James Feher, Viswanath Mahadevan, Dane Kenton Parker
  • Patent number: 7335712
    Abstract: This invention relates to siloxy-functionalized polymers having the silicon of the siloxy group directly bonded to the end of a polymer chain through one or more carbon atoms, processes of producing the polymers, and initiators used to prepare the polymers. The polymers may be rubbery polymers, such as butadiene-styrene polymers, which are commonly used in tires.
    Type: Grant
    Filed: April 21, 2005
    Date of Patent: February 26, 2008
    Assignee: Bridgestone Corporation
    Inventors: Yuan-Yong Yan, David F. Lawson, Christine M. Rademacher
  • Patent number: 7332554
    Abstract: The invention relates to new polymerization processes including diluents including hydrofluorocarbons and their use to produce novel polymers with new sequence distributions. In particular, the invention relates to copolymers of an isoolefin, preferably isobutylene, and a multiolefin, preferably a conjugated diene, more preferably isoprene, with new sequence distributions.
    Type: Grant
    Filed: December 19, 2003
    Date of Patent: February 19, 2008
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Timothy Daniel Shaffer, David Yen-Lung Chung
  • Patent number: 7332555
    Abstract: The invention relates to new polymerization processes including diluents including hydrofluorocarbons and their use to produce novel polymers with new sequence distributions. In particular, the invention relates to copolymers of an isoolefin, preferably isobutylene, and a multiolefin, preferably a conjugated diene, more preferably isoprene, with new sequence distributions.
    Type: Grant
    Filed: December 10, 2004
    Date of Patent: February 19, 2008
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Timothy Daniel Shaffer, David Yen-Lung Chung
  • Publication number: 20080015316
    Abstract: Provided are a propylene polymer compositions comprising a propylene copolymer and a propylene homopolymer polymerized in the presence of the propylene copolymer. The propylene polymer compositions exhibit properties such as broad molecular weight distribution, low crystallinity, high solubles and superior crystallization kinetics and are useful in fast cycle-time processing methods such as injection molding, sheet extrusion, thermoforming, and oriented film fabrication. Also provided is a process for preparing the propylene polymer compositions in the presence of a catalyst and at least two electron donors using sequential or parallel polymerization reaction zones. Finally, articles made from the propylene polymer composition are provided, particularly articles requiring high stiffness, high heat deflection temperature, good fatigue resistance and low temperature impact resistance such as appliance parts.
    Type: Application
    Filed: July 12, 2006
    Publication date: January 17, 2008
    Inventors: Chon-Yie Lin, Stephen Francis Broadbent
  • Patent number: 7319126
    Abstract: Branched synthetic polyisoprenes are described having a macrostructure and a microstructure very similar to those of natural rubber. According to one aspect, these polyisoprenes have an apparent stress F/S0 greater than or equal to 0.4 MPa at a relative elongation ? of 150%, applied to a dumbbell-shaped test specimen consisting of the crosslinkable polyisoprene. According to another aspect, these polyisoprenes fulfill the relationship: Cotan ??0.3761. ?inh+0.15,:??(i) where cotan ? is the cotangent of the loss angle of a sample of said polyisoprene, measured at 130° C. by means of an instrument known by the trade name “RPA2000”, said sample being subjected to shear stress to 10% deformation and at a stress frequency of 0.035 Hz, and where ?inh is the inherent viscosity of said polyisoprene, measured in toluene at 25° C. and at a concentration of said polyisoprene in toluene of 0.1 g/dl.
    Type: Grant
    Filed: April 18, 2005
    Date of Patent: January 15, 2008
    Assignee: Michelin Recherche et Technique S.A.
    Inventors: Philppe Laubry, Fanny Barbotin, Philippe Johnson, Jean-Luc Auger
  • Patent number: 7309748
    Abstract: The present invention discloses a metallocene catalyst component of the formula (I) [(Flu-R?-Cp)2M]?[Li(ether)4]+, wherein Cp is a cyclopentadienyl, substituted or unsubstituted, Flu is a fluorenyl, substituted or unsubstitutted, M is a metal Group III of the Periodic Table, and R? is a structural bridge between Cp and Flu imparting stereorigidity to the component. It further discloses a process for preparing said metallocene catalyst component and its use in controlled polymerisation.
    Type: Grant
    Filed: January 23, 2004
    Date of Patent: December 18, 2007
    Assignee: Total Petrochemicals Research Feluy
    Inventors: Jean-Francois Carpentier, Evgueni Kirillov, Abbas Razavi
  • Patent number: 7304109
    Abstract: The present invention provides a rubber composition, in which abrasion resistance and gripping performance are improved in a balanced manner and bleeding of the components is inhibited, and a tire using the composition. Specifically, the present invention provides a rubber composition comprising (B) 10 to 200 parts by weight of a low molecular weight aromatic vinyl-conjugated diene copolymer having weight average molecular weight of 1.0×103 to 1.0×105 and aromatic vinyl content of 10 to 75% by weight, wherein the hydrogenation ratio of double bonds in the conjugated diene part is 20 to 60%, based on (A) 100 parts by weight of a rubber component containing at least 60% by weight of a styrene-butadiene copolymer having weight average molecular weight of 5.0×105 to 2.
    Type: Grant
    Filed: June 1, 2005
    Date of Patent: December 4, 2007
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Kazuyuki Nishioka, Takahiro Mabuchi, Katsumi Terakawa, Kiyoshige Muraoka
  • Publication number: 20070255024
    Abstract: Supported catalyst systems and methods of forming polyolefins are generally described herein. The polymerization methods generally include introducing an inorganic support material to a reaction zone, wherein the inorganic support material includes a bonding sequence selected from Si—O—Al—F, F—Si—O—Al, F—Si—O—Al—F and combinations thereof, introducing a transition metal compound to the reaction zone and contacting the transition metal compound with the inorganic support material for in situ activation/heterogenization of the transition metal compound to form a catalyst system. The method further includes introducing an olefin monomer to the reaction zone and contacting the catalyst system with the olefin monomer to form a polyolefin.
    Type: Application
    Filed: June 21, 2006
    Publication date: November 1, 2007
    Applicant: Fina Technology, Inc.
    Inventors: Abbas Razavi, Vladimir P. Marin, Margarito Lopez
  • Patent number: 7288612
    Abstract: The invention relates to an initiator composition for anionic polymerization, comprising at least one alkali metal hydride selected from LiH, NaH, and KH, and at least one organylaluminum compound, and to a process for the anionic polymerization of styrene monomers or of diene monomers using the initiator composition.
    Type: Grant
    Filed: April 15, 2003
    Date of Patent: October 30, 2007
    Assignee: BASF Aktiengesellschaft
    Inventors: Philippe Desbois, Christian Schade, Alain Deffieux, Stephane Menoret, Jürgen Demeter
  • Publication number: 20070244285
    Abstract: A rubber roller, for use in an image-forming apparatus, which is formed by molding a rubber composition into the shape of a roller. In the rubber roller, a complex elastic modulus E* of rubber and a surface roughness Rz of the rubber roller satisfy a relationship indicated by an equation (1) shown below; and a hardness change of the rubber is set to not more than five points when the rubber ages at 70° C. for eight days: 7×Ln E*?0.12×Rz+3.0?10 .
    Type: Application
    Filed: March 6, 2007
    Publication date: October 18, 2007
    Inventor: Akira Minagoshi
  • Patent number: 7279531
    Abstract: The present invention is directed to rubbery polymers, such as polybutadiene rubber or styrene-butadiene rubber, that contain tin coupling agents and provide desirable dispersion of carbon black in rubber compounds, such as for use in tire treads. The tin coupling agents are defined by the general formulas (I) (X3Sn)2O or (II) (X3Sn)O—(CH2)n—O(X3Sn), wherein X is a halogen and n is 1 to 20. A method of rubbery polymer synthesis, in one embodiment, involves mixing anionically polymerizable conjugated diene monomers with optional vinyl aromatic and an anionic-polymerization initiator, i.e., an organolithium compound, to form a mixture of living polymers. A tin coupling agent is added to the mixture of living polymers effecting polymerization conditions to form the tin coupled rubbery polymer. Such tin coupled rubbery polymers can be utilized in tire tread rubbers where the rubbery polymers may provide desirable wear properties without substantially sacrificing other performance characteristics.
    Type: Grant
    Filed: March 5, 2007
    Date of Patent: October 9, 2007
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Adel Farhan Halasa, Steven Kristofer Henning, Scott K. Armstrong, Jacob Gerhan
  • Patent number: 7279527
    Abstract: Provided is a method of converting an anionic living end to a protected free radical “living” end in a well-controlled manner, which enables copolymerization by plural mechanisms. The method is particularly useful for copolymerization of anionically polymerizable monomers and free radical polymerizable monomers, and therefore useful for production of PB-g-PS, HIPS, ABS, and MBS etc. Also provided is a reversibly coupled polymer, which, when decoupled, generates “living” free radical for further copolymer chain reaction.
    Type: Grant
    Filed: April 22, 2005
    Date of Patent: October 9, 2007
    Assignee: Bridgestone Corporation
    Inventors: James Harwood, James Oziomek, David F. Lawson, James E. Hall
  • Patent number: 7279540
    Abstract: A precursor composition capable to form a solid-state electrolyte having good ion conductivity and high heat-resistance, by simple curing procedure, comprising; (A) a polymerizable ion pair compound represented by formula I, (B) a cross-linker having two or more unsaturated groups co-polymerizable with the polymerizable ion pair compound (A), and (C) non-polymerizable ion pair compound. Each of R1, R2, R3, R4, R5 and R6 represents hydrogen atom, alkyl or aryl group having 1-12 carbon atoms; and each of R7 and R8 represents alkyl or aryl group having 1-12 carbon atoms.
    Type: Grant
    Filed: July 18, 2005
    Date of Patent: October 9, 2007
    Assignee: Dai-ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Manabu Kikuta, Akiyoshi Hatakeyama
  • Patent number: 7253242
    Abstract: Golf balls comprising thermoplastic, thermoset, castable, or millable materials are presently disclosed. The materials have a rebound height percentage of greater than 60% and are formed from compositions comprising at least one resilient polyamine polydiene and/or polyol polydiene having a number average molecular weight of 1,000-20,000 and an amine or hydroxyl functionality of 1.6-10. The materials also have a 1,4-addition of 30-70% and/or a 1,2-addition of at least 40%. These materials can be used in any one or more portions of the golf balls, such as inner center, core, inner core layer, intermediate core layer, outer core layer, intermediate layer, cover, inner cover layer, intermediate cover layer, and/or outer cover layer.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: August 7, 2007
    Assignee: Acushnet Company
    Inventor: Shenshen Wu
  • Patent number: 7250476
    Abstract: A multi-functional polymer defined by the formula (Q—RnZ—P2—Y where (Q—R)n is a functionality cluster, Q is a functional group, R is a multi-valent organic group, P2 is a long-chain polymer, n is an integer from about 2 to about 10, Y is a proton, a weak functional group, or a selective functional group, and Z is a branch point where the functionality clusters join the long-chain polymer.
    Type: Grant
    Filed: August 1, 2003
    Date of Patent: July 31, 2007
    Assignee: Bridgestone Corporation
    Inventors: Georg G. A. Böhm, William L. Hergenrother, Christine M. Rademacher
  • Patent number: 7247695
    Abstract: Disclosed is a novel high 1,4-cis polybutadiene-polyurethane copolymer and a preparation method thereof. The present invention provides a high 1,4-cis polybutadiene-polyurethane copolymer represented by the following formula 1 and having an average molecular weight of at least 100,000, and a method for preparing the high 1,4-cis polybutadiene-polyurethane copolymer that includes polymerizing 1,3-butadiene or butadiene derivatives with a catalyst comprising a rare earth compound, a halogen-containing compound and an organoaluminum compound in the presence of a non-polar solvent, to prepare a polybutadiene having a high 1,4-cis content of at least 95%; and then introducing a polyurethane group to the polybutadiene.
    Type: Grant
    Filed: April 19, 2004
    Date of Patent: July 24, 2007
    Assignee: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Gwang Hoon Kwag, Sam Min Kim, Young Chan Jang, Pil Sung Kim, Seung Hwon Lee, Seung Hwa Lee, A Ju Kim
  • Patent number: 7241841
    Abstract: The random, hydrogenated copolymers according to the present invention of unsubstituted conjugated dienes and substituted conjugated dienes, having a glass transition temperature of ??60° C., an enthalpy of fusion of ?100 J/g and a content of residual double bonds in the range from 0 to 80%, are suitable for the production of rubber moldings of all kinds which have good resistance to ageing and high resilience at low temperatures. In particular, various tire components and industrial rubber articles may be mentioned as rubber moldings. The copolymers are also suitable for the rubber modification of brittle thermoplastics.
    Type: Grant
    Filed: May 6, 2005
    Date of Patent: July 10, 2007
    Assignee: Lanxess Deutschland GmbH
    Inventors: Cristina Stere, Werner Obrecht, Udo Sondermann, Gerd Sylvester
  • Patent number: 7241842
    Abstract: A conjugated diene rubber obtained by a process wherein active conjugated diene polymer chains each having an active metal at a polymer chain terminal, which have been obtained by polymerizing a conjugated diene monomer alone, or a conjugated diene monomer and an aromatic vinyl monomer with the aid of an organic active metal in an inert solvent, are allowed to react with a specific polyorganosiloxane capable of reacting with the active metal bonded to the polymer chain terminal. The conjugated diene rubber contains at least 5% by weight of a structure comprising at least three conjugated diene polymer chains bonded through a polyorganosiloxane. The conjugated diene rubber gives, when silica is incorporated therein, a rubber composition having good processability and giving a crosslinked rubber having reduced heat build-up, good wet grip performance and good abrasion resistance.
    Type: Grant
    Filed: June 2, 2003
    Date of Patent: July 10, 2007
    Assignee: Zeon Corporation
    Inventors: Masao Nakamura, Masaaki Komatsu, Kouji Shouya, Kiyonori Umetsu, Takeshi Karato, Takahiko Fukahori
  • Patent number: 7235615
    Abstract: A method is provided for synthesizing a polymer that has highly-functionalized chain-end moieties. The method functionalizes liquid rubber to terminate a metallic or organometallic initiated living polymer. After the living polymer has been terminated with the functionalized liquid rubber, the functionalities on the residue of the liquid rubber are preferably modified to yield more advantageous functionalities.
    Type: Grant
    Filed: February 18, 2004
    Date of Patent: June 26, 2007
    Assignee: The University of Akron
    Inventors: Roderic P. Quirk, Jin-Ping Zhou
  • Patent number: 7220798
    Abstract: Lithium-terminated polymers of one or more conjugated dienes and of one or more mono alkenyl arenes are coupled by reaction with an alkoxy silane coupling agent having the formula Rx—Si—(OR?)y, where x is 0 or 1, x+y=4, R and R? are the same or different, R is selected from aryl hydrocarbon radicals, linear alkyl hydrocarbon radicals and branched alkyl hydrocarbon radicals, and R? is selected from linear and branched alkyl hydrocarbon radicals, such that the resulting polymer composition contains less than about ten weight percent of uncoupled polymer diblock. The polymer compositions are subsequently selectively hydrogenated, and are useful in a variety of compounds and end use applications.
    Type: Grant
    Filed: February 28, 2005
    Date of Patent: May 22, 2007
    Assignee: Kraton Polymers US LLC
    Inventors: Harvey E. Atwood, Robert C. Bening, Mark Hageman, Dale L. Handlin, Jr., Adrie A. van der Huizen, Kimberly A. Johnson, Carl L. Willis
  • Patent number: 7217775
    Abstract: A rubber composition having improved processability and which provides a vulcanized rubber exhibiting excellent wear resistance and good tensile strength to service temperatures of up to about 150° C. The composition comprises (1) a crosslinked polymer particle having as repeat units (a) up to about 25% of a conjugated diene unit, (b) at least 70% of an aromatic vinyl unit, (c) about 15% to about 30% of a crosslinking monomer, and (d) about 0.
    Type: Grant
    Filed: April 20, 2004
    Date of Patent: May 15, 2007
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Eric Sean Castner
  • Patent number: 7214741
    Abstract: The present invention relates to a peroxide curable rubber compound containing at least one elastomeric polymer comprising repeating units derived from at least one C4 to C7 isomonoolefin monomer, at least one C4 to C14 multiolefin monomer, at least one p- or m-alkylstyrene monomer and at least one co-agent.
    Type: Grant
    Filed: August 10, 2004
    Date of Patent: May 8, 2007
    Assignee: Lanxess Inc.
    Inventors: Rui Resendes, Adam Gronowski
  • Patent number: 7211642
    Abstract: A polymer comprises at least two types of monomer units selected from: (1) diethynyl benzene units, (2) triethynyl benzene units, and (3) ester units. After curing, the polymer may form a condensed polyaromatic dielectric having a dielectric constant of at most 2.0 at 1 MHz, an elastic modulus of at least 7.7 GPa, and a hardness of at least 2.0 GPa.
    Type: Grant
    Filed: March 29, 2005
    Date of Patent: May 1, 2007
    Assignee: The Board of Trustees of the Univeristy of Illinois
    Inventors: James Economy, Yongqing Huang
  • Patent number: 7205370
    Abstract: A flower-like nano-particle composition including a poly (alkenylbenzene) core and a poly (conjugated diene) or a poly(alkylene) surface layer is provided. The nano-particles have a mean average diameter less than about 100 nm and are substantially free of chain ends. The nano-particles can be modified via, for example, hydrogenation. The nano-particles can advantageously be incorporated into rubbers, elastomers, and thermoplastics.
    Type: Grant
    Filed: January 12, 2004
    Date of Patent: April 17, 2007
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, Yoichi Ozawa, James E. Hall
  • Patent number: 7199201
    Abstract: The neodymium catalyst system prepared by the technique of this invention can be used in the polymerization of isoprene monomer into synthetic polyisoprene rubber having an extremely high cis-microstructure content and high stereo regularity. This polyisoprene rubber will crystallize under strain and can be compounded into rubber formulations in a manner similar to natural rubber. This invention more specifically discloses a process for the synthesis of polyisoprene rubber which comprises polymerizing isoprene monomer in the presence of a neodymium catalyst system, wherein the neodymium catalyst system is prepared by a process that comprises (1) reacting a neodymium carboxylate with an organoaluminum compound in an organic solvent to produce neodymium-aluminum catalyst component, and (2) subsequently reacting the neodymium-aluminum catalyst component with an elemental halogen to produce the neodymium catalyst system, wherein the neodymium catalyst system is void of nickel-containing compounds.
    Type: Grant
    Filed: November 23, 2005
    Date of Patent: April 3, 2007
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Adel Farhan Halasa, Wen-Liang Hsu, Aaron Michael Ryba, Jin-Ping Zhou, Chad Aaron Jasiunas, Paul Harry Sandstrom
  • Patent number: 7186785
    Abstract: This invention relates to A process for manufacturing a vinyl-rich polybutadiene rubber, comprising polymerizing butadiene in a solvent using a catalyst system comprising an iron-based catalyst as catalyst and a phosphite as ligand, said catalyst system comprising: (A) an organoiron compound; (B) an organoaluminum compound; and (C) a phosphite selected from a group consisting of dialkyl phosphite, trialkyl phosphite, diaryl phosphite, triaryl phosphite and mixtures thereof; wherein, the mole ratio of component B to component A is 5:100; and that of component C to component A is 0.5:10; and 80 wt % of macromolecules of the rubber have a vinyl group.
    Type: Grant
    Filed: July 27, 2004
    Date of Patent: March 6, 2007
    Assignee: Changchun Institute of Applied Chemistry Chinese Academy of Science
    Inventors: Liansheng Jiang, Xuequan Zhang
  • Patent number: 7176262
    Abstract: The hydrogenated vinyl-polybutadienes according to the present invention have degrees of hydrogenation of from 20 to 100%, Mooney viscosities in the range of from 10 to 150 Mooney units (ML 1+4/100° C.), glass transition temperatures (Tg) of ??57° C. and enthalpies of fusion (?H) of ?30 J/g and having a microstructure with a) from 0 to 44 wt. % 1,2-vinyl-butadiene units of the formula b) from 20 to 64 wt. % 1,2-butylene units of the formula c) from 0 to 60 wt. % 1,4-butenylene units of the formula CH2—CH?CH—CH2 and d) from 0 to 60 wt. % 1,4-butylene units of the formula CH2—CH2—CH2—CH2 are outstandingly suitable for the production of rubber molded bodies of any kind, especially for the production of industrial rubber articles and of tires and tire components. The rubber molded bodies produced from the hydrogenated vinyl-polybutadienes according to the present invention have good resistance to ageing and good elasticity at low temperatures.
    Type: Grant
    Filed: May 26, 2004
    Date of Patent: February 13, 2007
    Assignee: Bayer Aktiengesellschaft
    Inventors: Cristina Stere, Werner Obrecht
  • Patent number: 7173084
    Abstract: Use of a polymer as a levelling agent or anti-cratering agent, said polymer comprising at least one fluorinated unit represented by formula 1, (Formula 1) wherein R?1 is a moiety represented by Cn?F2n+1?-(CH2?)m?-, ?Cn?F2n?-(CH2?)m?-, Cn?F2n+1?-(CII2?)m?-(OCII2?CIIR?5)p?-, ?Cn?F2n?-(CH2?m?-(OCH2?CHR?5)p?? Cn?F2n+1?-(CII2?)m?-X-, ACn?F2n?-(CII2?)m?-X-?Cn?F2n?-(CH2?)m?-(OCH2?CHR?5)p?-X or Cn?F2n+1?-(CII2?)m?-(OCII2?CIIR?5)p?-X-; wherein A=H, Cl, Br, I, a C1–12? alkyl or a OC1–12 ?alkyl, wherein 4?n?20,0?m˜?4 and 0?p?20, wherein X is a spacer moiety selected from the group consisting of esters, amides, sulphoamides, mercapto groups, poltyurethane groups and alkyl groups, wherein R?2, is H, a metal moiety, an (alkyl)ammonium moiety or an alkyl group, Cn?F2n+1?-(CII2?)m?-, ACn?F2n?-(CII2?)m?-, Cn?F2n+1?-(CII2?)m?-(OCII2?CIIR?5)p?-, ?Cn?F2n?-(CH2?)m?-(OCH2?CHR?5)p?? Cn?F2n+1?-(CH2?)m?-X-, ?Cn?F2n?-(CH2?)m?-X-, ACn?F2n?-(CH2?)m?-(OCH2?CHR?5)p?-X or Cn?F2n+1?-(CH2?)m?-(OCH2?CHR?5)p?-X-; wherein A=H, Cl, Br, I, C1–12?
    Type: Grant
    Filed: October 8, 2002
    Date of Patent: February 6, 2007
    Assignee: EFKA Additives B.V.
    Inventors: Frank Oliver Heinrich Pirrung, Elizabeth Maaike Loen, Lothar Alexander Engelbrecht, Arend Noordam
  • Patent number: 7163913
    Abstract: A polymer suitable for use as a viscosity index improver for lubricating oil compositions, which is at least one, at least partially hydrogenated linear or star-shaped random copolymer of isoprene and butadiene, in which at least 70 wt. % of the butadiene is incorporated into the polymer as 1,4 units and the weight ratio of isoprene addition product to butadiene addition product in the copolymer is in a range of from about 90:10 to about 70:30.
    Type: Grant
    Filed: July 1, 2003
    Date of Patent: January 16, 2007
    Assignee: Infineum International Limited
    Inventors: Stuart Briggs, Chin Chu
  • Patent number: 7157535
    Abstract: UV curable compositions, polymeric photoinitiators and precursors therefor are described.
    Type: Grant
    Filed: June 18, 2003
    Date of Patent: January 2, 2007
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Donald E. Herr, Ziyi Hu, Charles W. Paul, Robert W. R. Humphreys
  • Patent number: 7153919
    Abstract: An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
    Type: Grant
    Filed: October 30, 2003
    Date of Patent: December 26, 2006
    Assignee: Bridgestone Corporation
    Inventors: Terrence E. Hogan, William Hergenrother, Yuan-Yong Yan, David Lawson
  • Patent number: 7151077
    Abstract: The present invention relates to methods and compositions for treating subterranean formations. More particularly, the present invention relates to polymersomes, viscosifying agents that comprise polymersomes, and associated methods of use. In some embodiments, the present invention discloses methods of treating a section of a subterranean formation that comprises the steps of providing a viscosified treatment fluid that comprises an aqueous-based component, and a viscosifying agent that comprises a polymersome; and treating the section of the subterranean formation. In other embodiments, the present invention discloses methods of viscosifying a treatment fluid, suspending particulates in a treatment fluid, fracturing a subterranean formation, providing sand control in a section of a subterranean formation, and encapsulating treatment fluid additives.
    Type: Grant
    Filed: March 29, 2004
    Date of Patent: December 19, 2006
    Assignees: Halliburton Energy Services, Inc., Princeton University
    Inventors: Robert K. Prud'homme, Lewis R. Norman, Douglas H. Adamson, Mustafa Erhan Yildiz, Ian D. Robb
  • Patent number: 7105613
    Abstract: A process for the manufacture of a baleable lithium carboxylate polymer. The process includes polymerizing at least one conjudated diene in the presence of an organolithium initiator to a substantial completion. Thereafter, the polymerization process is terminated by the addition of carbon dioxide.
    Type: Grant
    Filed: February 4, 2005
    Date of Patent: September 12, 2006
    Assignee: Firestone Polymers, LLC
    Inventors: Daniel F. Graves, David J. Dougherty, Thomas A. Antkowiak
  • Patent number: 7105608
    Abstract: The present invention provides a new copolymer of propylene and a conjugated diene having a carbon-carbon double bond in a side chain, wherein a molar ratio of a total of 1,2-adducts and 3,4-adducts to 1,4-adducts, derived from the conjugated diene, is 100:0. The copolymer is prepared in a process, characterized in that propylene and the conjugated diene are copolymerized in the presence of hydrogen, an organometallic compound comprising a transition metal selected from the group 4 of the periodic table, and at least one Lewis acid.
    Type: Grant
    Filed: September 17, 2004
    Date of Patent: September 12, 2006
    Assignees: Tonen Chemical Corporation, National Institute of Advanced Industrial Science and Technology
    Inventors: Takeshi Ishihara, Ban The Hoang, Hideaki Hagihara, Kenji Tsuchihara, Takeshi Shiono
  • Patent number: 7094849
    Abstract: A method of producing cis-1,4-polydienes, the method comprising the step of contacting conjugated diene monomer with a lanthanide-based catalyst system in the presence of less than 20% by weight of organic solvent based on the total weight of monomer, organic solvent, and resulting polymer, where the lanthanide-based catalyst system is the combination of or reaction product of (a) a lanthanide compound, (b) an organoaluminum hydride, (c) a trihydrocarbylaluminum, and (d) a halogen-containing compound.
    Type: Grant
    Filed: December 15, 2003
    Date of Patent: August 22, 2006
    Assignee: Bridgestone Corporation
    Inventors: Steven Luo, William M. Cole, Yoichi Ozawa
  • Patent number: 7094847
    Abstract: A class of bridged or unbridged metallocene compounds is disclosed, wherein the cyclopentadienyl ligands have two or four adjacent substituents forming one or two alkylenic cycles of from 4 to 8 carbon atoms. These metallocenes are useful as catalyst components for the polymerization of olefins, particularly for the (co)polymerization of ethylene and for the polymerization of propylene.
    Type: Grant
    Filed: March 30, 2001
    Date of Patent: August 22, 2006
    Assignee: Basell Technology Company B.V.
    Inventors: Clyde E. Bishop, Robert L. Jones, Jr., Krishna Raman, Vu Anh Dang, Lin-Chen Yu, Luigi Resconi, Tiziano Dall'Occo, Maurizio Galimberti
  • Patent number: 7091150
    Abstract: The neodymium catalyst system prepared by the technique of this invention can be used in the polymerization of isoprene monomer into synthetic polyisoprene rubber having an extremely high cis-microstructure content and high stereo regularity. This polyisoprene rubber will crystallize under strain and can be compounded into rubber formulations in a manner similar to natural rubber. This invention more specifically discloses a process for preparing a neodymium catalyst system which comprises (1) reacting a neodymium carboxylate with an organoaluminum compound in an organic solvent to produce neodymium-aluminum catalyst component, and (2) subsequently reacting the neodymium-aluminum catalyst component with an elemental halogen to produce the neodymium catalyst system. The present invention further discloses a synthetic polyisoprene rubber which is comprised of repeat units that are derived from isoprene, wherein the synthetic polyisoprene rubber has a cis-microstructure content which is within the range of 98.
    Type: Grant
    Filed: September 16, 2004
    Date of Patent: August 15, 2006
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Adel Farhan Halasa, Wen-Liang Hsu, Aaron Michael Ryba, Jin-Ping Zhou, Chad Aaron Jasiunas, Paul Harry Sandstrom
  • Patent number: 7084228
    Abstract: A cross-linkable or cross-linked rubber composition usable to constitute a tire tread having improved wear resistance, to such a tread and to a tire incorporating this tread. The composition is particularly applicable to tires of passenger-vehicle type. The rubber composition includes a plasticizing resin of number-average molecular weight of from 400 to 2000 g/mol, the resin having units resulting from the polymerization of a monocyclic or bicyclic unsaturated terpene, in a mass fraction of from 70% to 100%, and having a glass transition temperature greater than 50° C. and less than 120° C.
    Type: Grant
    Filed: January 31, 2005
    Date of Patent: August 1, 2006
    Assignee: Michelin Recherche et Technique S.A.
    Inventors: Gérard Labauze, Samuel Mathieu
  • Patent number: 7067594
    Abstract: A carboxylic derivative composition derived from a carboxylated isobutylene-polyene copolymer having n ranging from about 200 to about 10,000, said copolymer having thereon from about 0.8 to about 7 moles per mole of copolymer of groups derived from at least one ?,?-unsaturated carboxylic acid or reactive equivalent thereof, reacted with at least one of (a) amines characterized by the presence within their structure of at least one condensable H—N< group, (b) alcohols. (c) reactive metals or reactive metal compounds, and (d) a combination of two or more of any of (a) through (c), the components of (d) having been reacted with the carboxylated isobutylene-polyene copolymer simultaneously or sequentially, in any order. Also, a process for preparing carboxylic derivative compositions, additive concentrates and lubricating oil compositions containing the carboxylic derivative compositions and methods for increasing the viscosity index of lubricating oil compositions.
    Type: Grant
    Filed: June 21, 2001
    Date of Patent: June 27, 2006
    Assignee: The Lubrizol Corporation
    Inventor: Christopher J. Kolp
  • Patent number: 7048023
    Abstract: The invention is directed to a pneumatic tire having at least one component comprising a vulcanizable rubber composition, wherein the vulcanizable rubber composition comprises, based on 100 parts by weight of elastomer (phr), from about 30 to 100 phr of high trans random SBR, and from about zero to about 70 phr of at least one additional elastomer, wherein the high trans random SBR comprises from about 3 to about 30 percent by weight of styrene.
    Type: Grant
    Filed: May 10, 2004
    Date of Patent: May 23, 2006
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: James Robert Herberger, Sr., Kenneth Allen Bates, John Joseph Andre Verthe
  • Patent number: 7038000
    Abstract: There is provided a process for the copolymerisation of propylene with at least one C4-20 ?-olefin or C4-20 diene in a reaction medium in the presence of a catalyst system at a temperature of greater that 80° C. or at a temperature and pressure above the critical temperature and pressure of the reaction medium. Under such conditions, comonmer incorporation is higher than under standard conditions.
    Type: Grant
    Filed: May 3, 2002
    Date of Patent: May 2, 2006
    Assignee: Borealis Technology OY
    Inventors: Torvald Vestberg, Pirjo Jaaskelainen, Paivi Pitkanen, Kauno Alastalo
  • Patent number: 7034095
    Abstract: A bicyclic conjugated diene polymer obtained by polymerizing a monomer (M) comprising at least one kind of bicyclic conjugated diene monomer represented by formula (I), and a bicyclic conjugated diene copolymer obtained by copolymerizing monomer (M) with at least one kind of unsaturated compound other than said monomer: wherein, R1 to R6 are the same or different and are each hydrogen, halogen, or alkyl or halogenated alkyl of 1 to 20 carbon; n and m are each an integer of from 0 to 10; X1, X2, Y1 and Y2 are the same or different from each other and are each hydrogen, halogen or alkyl or halogenated alkyl of 1 to 20 carbon; and, when m or n is 2 or more, each of mX1's, mX2's, nY1's and nY2's are the same or different.
    Type: Grant
    Filed: February 14, 2003
    Date of Patent: April 25, 2006
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Saisuke Watanabe, Teppei Tsujimoto, Shuichi Tajima
  • Patent number: 7019095
    Abstract: An ethylene-vinyl alcohol copolymer, represented by the formula (1): wherein n represents a number in the range of 15 to 15,000, and a method of producing an ethylene-vinyl alcohol copolymer wherein an 1,4 -polybutadiene is hydroborated in non-gel state in a solvent, followed by oxidation to be hydroxylated so as to derive an ethylene-vinyl alcohol copolymer represented by the formula (1): wherein n represents a number in the range of 15 to 15,000.
    Type: Grant
    Filed: August 20, 2002
    Date of Patent: March 28, 2006
    Assignee: Nihon University, School Juridical Person
    Inventors: Takashi Sawaguchi, Shoichiro Yano, Toshiki Hagiwara, Yoshihiro Chishima, Yuko Akutsu
  • Patent number: 7008899
    Abstract: A catalyst composition that is the combination of or the reaction product of ingredients comprising (a) a lanthanide compound, (b) an organoaluminum hydride, and (c) a tin halide compound.
    Type: Grant
    Filed: August 11, 2003
    Date of Patent: March 7, 2006
    Assignee: Bridgestone Corporation
    Inventors: Steven Luo, Michael W. Hayes, Jeffery M. Hawkins