From Heterocyclic Reactant Containing As Ring Atoms Oxygen, Selenium Or Tellurium, E.g., Epoxy, Etc. Patents (Class 528/403)
  • Publication number: 20040067388
    Abstract: Disclosed are a polymeric fluorescent substance, which has prolonged service life and high luminescence brightness and, at the same time, has excellent thermal stability and good practicality, a process for producing the polymeric fluorescent substance, and an organic EL element using the polymeric fluorescent substance. The polymeric fluorescent substance is adapted for emission of visible fluorescence in a solid state, comprises at least one type of repeating units represented by chemical formula (1), and has a number average molecular weight of 103 to 108 as determined using polystyrene as a standard.
    Type: Application
    Filed: September 22, 2003
    Publication date: April 8, 2004
    Inventor: Satoshi Suzuki
  • Patent number: 6716311
    Abstract: The invention relates to modified cationic polymers which can be obtained by reacting (a) water-soluble, polymeric compounds containing NH groups with (b) compounds which are at least bifunctional with regard to NH groups, which contain at least one alkyl radical or alkenyl radical having at least 8 C atoms, and which contain, as a functional group, a halohydrin, epoxide, carboxyl, chloroformate or isocyanate group or a halogen atom. The invention also relates to a method for producing the polymers by reacting the compounds of groups (a) and (b), and to the use of the modified cationic polymers during the production of paper as fixing agents for papermaking stock containing interfering substances.
    Type: Grant
    Filed: May 4, 2001
    Date of Patent: April 6, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Jürgen Decker, Norbert Mahr, Anton Esser, Hubert Meixner, Rainer Dyllick-Brenzinger, Martin aus dem Kahmen, Martin Gercke
  • Patent number: 6716788
    Abstract: The present invention relates to a process for the preparation of a double metal cyanide (DMC) catalyst, which process involves: (a) combining an aqueous solution of a metal salt with an aqueous solution of a metal cyanide salt and reacting these solutions; and (b) recovering the DMC catalyst from the reaction mixture, in which process the DMC catalyst is prepared in the presence of from 0.03 to 0.4 mole of alkaline metal compound, based on amount of metal salt. Further, the present invention relates to DMC catalyst obtainable by such process, to DMC catalyst prepared from a metal salt and a metal cyanide salt in which the molar ratio of metal derived from the metal salt to metal derived from the metal cyanide salt is at least 2.25 and to a process for polymerization of alkylene oxides which process involves reacting initiator with alkylene oxide in the presence of at most 15 ppm of DMC catalyst.
    Type: Grant
    Filed: June 10, 2003
    Date of Patent: April 6, 2004
    Assignee: Shell Oil Company
    Inventors: Michiel Barend Eleveld, Robert Adrianus Wilhelmus Grotenbreg, Ronald Van Kempen
  • Publication number: 20040062969
    Abstract: An object of the present invention is to obtain a novel polymeric material capable of forming a solid polymer electrolyte excellent not only in processability, solvent resistance and durability/stability but also in ion conductivity by introducing sulfonic acid group or phosphonic acid group into a polybenzazole compound having excellent properties in view of heat resistance, solvent resistance, mechanical characteristics and the like.
    Type: Application
    Filed: October 28, 2003
    Publication date: April 1, 2004
    Inventors: Yoshimitsu Sakaguchi, Kota Kitamura, Hiroaki Taguchi, Junko Nakao, Shiro Hamamoto, Hiroshi Tachimori, Satoshi Takase
  • Patent number: 6713599
    Abstract: A method of forming a polyol includes the steps of reacting an initiator with an alkylene oxide, and optionally carbon dioxide, in the presence of a double metal cyanide catalyst and a sterically hindered chain transfer agent capable of protonating the growing polyol polymer. The presence of the chain transfer agent reduces the polydispersity of the resultant polyol.
    Type: Grant
    Filed: March 31, 2003
    Date of Patent: March 30, 2004
    Assignee: BASF Corporation
    Inventors: Werner Hinz, Jacob Wildeson, Edward Michael Dexheimer, Raymond Neff
  • Publication number: 20040059058
    Abstract: Epoxy-modified, two-part acrylic structural adhesives characterized by improved T-peel strength are disclosed. These adhesives are not inhibited by oxygen.
    Type: Application
    Filed: September 11, 2003
    Publication date: March 25, 2004
    Inventors: Robin F. Righettini, Jeffrey A. Hatcher
  • Publication number: 20040049007
    Abstract: Disclosed is an oxytetramethylene glycol copolymer, which is obtained by copolymerizing tetrahydrofuran and neopentyl glycol and which has a specific number average molecular weight Mn, a specific molecular weight distribution Mn/Mw, a specific neopentyl glycol copolymerization whole ratio Nw and a specific neopentyl glycol copolymerization partial ratio Nh, and a method for producing the same. Also disclosed is a method for purifying an oxytetramethylene glycol copolymer, which comprises adding a fresh tetrahydrofuran to a reaction mixture comprising an oxytetramethylene glycol copolymer and an unreacted diol, wherein the amount of added tetrahydrofuran is not less than the weight of the unreacted diol contained in the reaction mixture, and distilling off the unreacted diol together with the added tetrahydrofuran.
    Type: Application
    Filed: July 9, 2003
    Publication date: March 11, 2004
    Inventors: Tamotsu Kodama, Haruyuki Minoura, Yoshiyuki Tsunematsu, Toshihiko Fukuzono, Satoshi Furubeppu
  • Patent number: 6699961
    Abstract: A process for the preparation of a DMC catalyst useful in the polymerization of alkylene oxides into polyether polyols, which process having the steps of (a combining an aqueous solution of a metal salt with an aqueous solution of a metal salt with an aqueous solution of a metal cyanide salt and reacting these solutions, wherein at least part of this reaction takes place in the presence of an organic complexing agent, thereby forming a dispersion of a solid DMC complex in an aqueous medium; (b) combining the dispersion obtained in step (a) with a liquid, which is essentially insoluble in water and which is capable of extracting the solid DMC complex formed in step (a) from the aqueous medium, and allowing a two-phase system to be formed consisting of a first aqueous layer and a layer containing the DMC complex and the liquid added; (c) removing the first aqueous layer; and (d) recovering the DMC catalyst from the layer containing the DMC catalyst.
    Type: Grant
    Filed: September 24, 2002
    Date of Patent: March 2, 2004
    Assignee: Shell Oil Company
    Inventors: Michiel Barend Eleveld, Riemer Alberts De Groot, Ronald Van Kempen, Johan Paul Smit
  • Publication number: 20040039153
    Abstract: A copolymer composition including a copolymer having repeat units of structural formula I: 1
    Type: Application
    Filed: June 19, 2003
    Publication date: February 26, 2004
    Inventors: Edmund Elce, Takashi Hirano, Jeffrey C. Krotine, Larry F. Rhodes, Brian L. Goodall, SaiKumar Jayaraman, W. Chris McDougall, Shenliang Sun
  • Publication number: 20040039133
    Abstract: The invention relates to hydroxyl-group-containing polyether amine adducts a) that are obtainable by the reaction of polyglycidyl ethers a1), prepared from polyalkylene ether polyols having an average molecular weight Mw of from 200 to 10,000 and epichlorohydrin, with amines a2) that contain at least two reactive amine hydrogen atoms per molecule, to form polyether amines, and subsequent addition reaction of those polyether amines with epoxy compounds a3) that contain at least one epoxy group per molecule, furthermore to curable compositions comprising an epoxy resin b) and an adduct a) and also to the use of those curable compositions for the manufacture of mouldings, coverings and foamed materials.
    Type: Application
    Filed: May 21, 2003
    Publication date: February 26, 2004
    Inventors: Wolfgang Scherzer, Jorg Volle
  • Publication number: 20040024161
    Abstract: A polymer comprising a region having a conjugated backbone capable of transporting negative charge carriers, which region comprises a plurality of repeat units each comprising a core group which comprises an [Ar′] group substituted with at least one pendant group X and the [Ar′] groups form at least a part of the backbone, wherein each Ar′ comprises an aromatic or heteroaromatic group and each X comprises NAr2 in which each Ar is the same or different and independently comprises a substituted or unsubstituted aromatic or heteroaromatic group and N is conjugated with the backbone.
    Type: Application
    Filed: June 23, 2003
    Publication date: February 5, 2004
    Inventors: Carl Robert Towns, Carl Roberts Towns, Mary Joyce McKiernan
  • Publication number: 20040024165
    Abstract: The composition for optical materials of the present invention contains at least one compound represented by the following Formula 1: 1
    Type: Application
    Filed: March 13, 2003
    Publication date: February 5, 2004
    Inventors: Yuichi Yoshimura, Motoharu Takeuchi
  • Publication number: 20040024172
    Abstract: In a process for preparing polytetrahydrofuran, tetrahydrofuran copolymers, diesters or monoesters of these polymers having a low color number, the polymers obtained by cationic polymerization of tetrahydrofuran are hydrogenated in the presence of a macroporous, supported heterogeneous catalyst comprising at least one metal of subgroups VII [sic] to X [sic] of the Periodic Table of the Elements as active metal.
    Type: Application
    Filed: February 6, 2003
    Publication date: February 5, 2004
    Inventors: Christoph Sigwart, Anton Meier, Michael Hesse, Volkmar Menger, Klaus-Peter Pfaff, Arthur Hohn, Lothar Franz
  • Publication number: 20040014829
    Abstract: Polyols initiated with a first initiator having a relatively high functionality averaging greater than eight and comprising a range of species of different functionality, and optionally a second initiator, having low functionality, i.e. a two to eight nominal functionality initiator molecule. Another aspect of the invention is a process for making the polyol. The invention is also directed to a process for producing polyurethane foam by reacting the polyol of the invention with isocyanates, and the foam produced thereby.
    Type: Application
    Filed: July 22, 2002
    Publication date: January 22, 2004
    Inventors: Raymond A. Neff, Duane A. Heyman
  • Publication number: 20040014937
    Abstract: A method is provided which biosynthesizes a PHA having an epoxy group on a side chain with improved physicochemical properties. Specifically, a method of producing a polyester containing an epoxy group in a side chain thereof using alkene as a raw material is provided which comprises the steps of bringing alkene into contact with a microorganism having an ability to uptake alkene and convert it to a polyester and allowing the microorganism to convert the alkene into a polyester containing an epoxy group in a side chain thereof. Further, a method of producing a crosslinked polymer is provided which comprises reacting the polyester obtained by the above mentioned method with a diamine compound.
    Type: Application
    Filed: May 2, 2003
    Publication date: January 22, 2004
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Takeshi Imamura, Etsuko Sugawa, Tetsuya Yano, Shin Kobayashi, Tsutomu Honma, Takashi Kenmoku
  • Patent number: 6670033
    Abstract: A process for the formation of a purified anhydrosugar alcohol is disclosed, whereby the resultant purified anhydrosugar alcohol has a purity of at least 99.8% and is substantially colorless. The anhydrosugar alcohol is purified by distillation, recrystallization from methanol, ethanol or ethylene glycol, melt recrystallization, or a combination thereof. Preferably, the purification is by distillation followed by recrystallization from methanol, ethanol or ethylene glycol. A test for determining the purity of the anhydrosugar alcohol is disclosed, wherein the color of the anhydrosugar alcohol after annealing at a temperature of at least 260° C. for at least four hours is examined. Alternatively, purity can be determined by examination of ultraviolet (UV) transmittance of the purified anhydrosugar alcohol at various wavelengths.
    Type: Grant
    Filed: November 27, 2001
    Date of Patent: December 30, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Michael A. Hubbard, Michael Wohlers, Helmut B. Witteler, Edward G. Zey, George Kvakovszky, Thomas H. Shockley, Larry F. Charbonneau, Norbert Kohle, Jochen Rieth
  • Publication number: 20030232964
    Abstract: An epoxy resin that contains, in a molecule, two mesogens coupled by a folded chain, is provided using a method that ensures easy synthesis of such an epoxy resin, and a uniform epoxy resin composition is provided based on this epoxy resin. The epoxy resin includes a major compound having a structure expressed by the Chemical Formula (1), and a method is provided for manufacturing the epoxy resin by reaction of (A) an epoxy resin with one mesogen contained in a molecule and (B) a compound with two elements of active hydrogen contained in a molecule, with the percentage composition of (B) active hydrogen with respect to (A) epoxy group being 0.25 and over, up to and including 0.7.
    Type: Application
    Filed: June 20, 2003
    Publication date: December 18, 2003
    Inventors: Masaki Akatsuka, Yoshitaka Takezawa, Hisashi Morooka
  • Patent number: 6664364
    Abstract: There are herein disclosed a transparent optical material containing at least one selenium atom, a plastic lens comprising the transparent optical material, and methods for preparing them. In addition, there are also disclosed novel selenium-containing compounds represented by the following formulae (1), (2) and (4) which are useful for the transparent optical material and the plastic lens: wherein symbols are as defined in the specification.
    Type: Grant
    Filed: September 19, 2002
    Date of Patent: December 16, 2003
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Koju Okazaki, Mamoru Tanaka, Shiro Honma, Hiroyuki Morijiri, Yoshinobu Kanemura, Masahiko Kusumoto
  • Patent number: 6653486
    Abstract: Photopolymerizable compositions are provided which are the reaction products of a vinyl ether, a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and an electron donor compound. These monomeric/oligomeric compositions may also include epoxides, polyols, spiroorthocarbonates. One embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, a spiroorthocarbonate, and a photoinitiator system. Another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, and a photoinitiator system. Still another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, a spiroorthocarbonate, and a photoinitiator system. Still further, another embodiment of the present invention is certain novel spiroorthocarbonate compounds. Each of these novel spiroorthocarbonate compounds include at least one epoxy group as a substituent.
    Type: Grant
    Filed: September 4, 2002
    Date of Patent: November 25, 2003
    Assignee: Curators of the University of Missouri
    Inventors: Cecil C. Chappelow, Charles S. Pinzino, J. David Eick
  • Patent number: 6649733
    Abstract: Latexes are thickened by compounds of the formula: R1—(O—A)a—B1—R2—(B2—R3)d—(B3—(A′—O)b-f—(A′—B4)f—R4—(B5—R5)e)n—B6—(A″O)c—R6 wherein: R1 and R6 are monovalent hydrophobic groups independently selected from the group consisting of an aliphatic group, a substituted aliphatic group, an aromatic group, and a substituted aromatic group; R2 and R4 are independently selected from the group consisting of aliphatic, substituted aliphatic, aromatic, or substituted aromatic radicals, each radical being divalent or trivalent; R3 and R5 are independently selected from hydrogen, lower alkyl and lower aralkyl; B1, B2, B3, B4, B5, and B6 are linking groups independently selected from the group consisting of an oxygen atom (to form the ether linkage —O—), a carboxylate group (to form an ester linkage R2—C(O)—O— and/or R4—C(O)—O—), an amino group (to form
    Type: Grant
    Filed: May 9, 1994
    Date of Patent: November 18, 2003
    Assignee: Cognis Corporation
    Inventors: Michael S. Wiggins, Reuben H. Grinstein
  • Patent number: 6635690
    Abstract: The present invention provides novel compositions prepared from a first oligomer containing reactive functional groups capable of reaction at effective rates (at normal processing temperatures) with a co-reactive second component possessing functionality that is complementary to that of the first oligomer. The compositions may be used as coatings, including hard surface coatings, clear coatings, powder coatings and pattern coatings; as adhesives, including pressure sensitive adhesives and hot melt adhesives; as sealants; as optical coatings; as blown microfibers (BMF); as high refractive index optical materials; as barrier films; in microreplication; as low adhesion backsizes, (LABs) and as release coatings.
    Type: Grant
    Filed: June 19, 2001
    Date of Patent: October 21, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Steven M. Heilmann, Babu N. Gaddam, Ahmed S. Abuelyaman, Duane D. Fansler, Todd D. Jones, Maureen A. Kavanagh, Kevin M. Lewandowski, Michael S. Wendland
  • Patent number: 6630565
    Abstract: Phosphorus-comprising polyol, oligomer derived from this phosphorus-comprising polyol, polymer derived from this oligomer, processes for their preparation and uses of these. The present invention relates to a phosphorus-comprising polyol. The invention also relates to an oligomer derived from this phosphorus-comprising polyol and to the composition comprising this oligomer. The invention also relates to a polymer derived from this oligomer. The invention also relates to processes for the preparation of this phosphorus-comprising polyol, of this oligomer, of this polymer and of this composition. The invention also relates to the uses of this phosphorus-comprising polyol, of this oligomer, of this polymer and of this composition. The composition can be cross-linked by irradiation and exhibits flame-retardant properties.
    Type: Grant
    Filed: September 13, 2001
    Date of Patent: October 7, 2003
    Assignee: UCB, S.A.
    Inventors: Hugues Van Den Bergen, Jean-Claude Vanovervelt
  • Patent number: 6624286
    Abstract: The invention relates to new improved double-metal cyanide (DMC) catalysts for the preparation of polyether-polyols by polyaddition of alkylene oxides on to starter compounds containing active hydrogen atoms, the catalyst comprising a double-metal cyanide compound, an organic complexing ligand and 5-80 wt. %, based on the amount of catalyst, of a polyester. For the preparation of polyether-polyols, the new improved catalysts have significantly shortened induction times and at the same time a greatly increased activity.
    Type: Grant
    Filed: December 5, 2001
    Date of Patent: September 23, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jörg Hofmann, Pramod Gupta, Robert-Joseph Kumpf, Pieter Ooms, Walter Schäfer
  • Publication number: 20030176630
    Abstract: A process for the single-stage preparation of polytetrahydrofuran and/or tetrahydrofuran copolymers having a mean molecular weight of from 650 to 5000 dalton by polymerization of tetrahydrofuran over a heterogeneous acid catalyst in the presence of at least one telogen and/or comonomer selected from the group consisting of alpha,omega-diols, water, polytetrahydrofuran having a molecular weight of from 200 to 700 dalton and cyclic ethers comprises
    Type: Application
    Filed: January 2, 2003
    Publication date: September 18, 2003
    Inventors: Gerd Bohner, Thomas Domschke, Rolf-Hartmuth Fischer, Martin Haubner, Christoph Sigwart, Ulrich Steinbrenner, Christian Tragut
  • Patent number: 6617418
    Abstract: A hyperbranched dendritic polyether, which optionally is further processed, such as further chain extended, chain terminated and/or functionalised. The hyperbranched dendritic polyether is obtained in a process comprising the step of thermally initiated cationic ring-opening polymerisation of at least one oxetane having at least two reactive groups of which at least one is an oxetane group. The thermally initiated ring-opening polymerisation is performed using an effective amount of at least one initiator, such as a thermal onium salt, a Lewis acid and/or a Brønsted acid. The terminal groups in said hyperbranched dendritic polyether are substantially hydroxyl groups and used for said optional further processing.
    Type: Grant
    Filed: January 25, 2002
    Date of Patent: September 9, 2003
    Assignee: Perstorp AB
    Inventors: Helen Magnusson, Eva Malmstrom, Anders Hult, Nicola Rehnberg
  • Patent number: 6592991
    Abstract: A process is described for preparing structured organic-inorganic hybrid materials, using an amphiphilic block copolymer as template.
    Type: Grant
    Filed: May 24, 2000
    Date of Patent: July 15, 2003
    Assignee: Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V.
    Inventors: Ulrich Bernd Wiesner, Markus Templin
  • Patent number: 6590059
    Abstract: Bioerodible polyorthoesters useful as orthopedic implants or vehicles for the sustained delivery of pharmaceutical, cosmetic and agricultural agents contain hydrogen bonding groups and &agr;-hydroxy acid-containing groups.
    Type: Grant
    Filed: May 11, 2001
    Date of Patent: July 8, 2003
    Assignee: AP Pharma, Inc.
    Inventors: Steven Y. Ng, Jorge Heller
  • Patent number: 6586564
    Abstract: The invention relates to double-metal cyanide (DMC) catalysts for preparing polyether polyols by the polyaddition of alkylene oxides on to starter compounds containing active hydrogen atoms, wherein the DMC catalysts are composed of: a) at least one DMC compound; b) at least one organic complexing ligand which is not a coronand; and c) at least one coronand. The DMC catalysts of the present invention have increased activity compared to known catalysts.
    Type: Grant
    Filed: August 28, 2002
    Date of Patent: July 1, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Walter Schäfer, Jörg Hofmann, Pieter Ooms
  • Publication number: 20030113291
    Abstract: The invention relates to biocidal polymers based on guanidine salts characterized in that they are representatives of a number of polyoxyalkylene guanidines and their salts and are a product of a polycondensation of guanidine salts with diamines which include two amino groups and polyoxyalkylene chains therebetween.
    Type: Application
    Filed: October 31, 2002
    Publication date: June 19, 2003
    Inventors: Oskar J. Schmidt, Andreas Schmidt, Dimitri Toptchiev
  • Patent number: 6576086
    Abstract: Paper, board and cardboard are produced by draining paper stock containing interfering substances in the presence of fixing agents by a process in which the fixing agents used are reaction products which are obtainable by reacting amino- and/or ammonium-containing polymers selected from the group consisting of the polymers containing vinylamine units polyalkylene polyamines polyamidoamines ethyleneimine-grafted polyamidoamines which may be crosslinked, polydiallyldimethylammonium chlorides polymers containing dialkylaminoalkylacrylamide units or dialkylaminoalkylmethacrylamide units and polyallylamines and dicyandiamide and formaldehyde condensates with reactive sizes for paper in a weight ratio of polymer to reactive size of from 15,000:1 to 1:1, and the reaction products thus obtainable are used as fixing agents for water-soluble and for water-insoluble interfering substances in the production of paper, board and cardboard from paper stocks containing interfering substances.
    Type: Grant
    Filed: November 2, 1999
    Date of Patent: June 10, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Roland Ettl, Hubert Meixner, Anton Esser, Rainer Scholz, Norbert Mahr, Ulrich Steuerle, Matthias Höne, Klaus Lorenz
  • Publication number: 20030092879
    Abstract: This invention relates to a process for the preparation of highly-branched polyols by polymerisation of glycidol in the presence of a hydrogen-active starter compound with basic catalysis, wherein glycidol is added in dilute solution and the solvent used for the dilution is continuously distilled off. The polyols thus prepared are colourless, contain as the core unit solely the starter compound used and have polydispersities of less than 1.7.
    Type: Application
    Filed: January 2, 2003
    Publication date: May 15, 2003
    Inventors: Alexander Sunder, Rolf Mulhaupt
  • Patent number: 6559278
    Abstract: The invention relates to a method for continuously or discontinuously producing tetrahydrofuran polymers by homopolymerization of tetrahydrofuran, alkyl-substituted tetrahydrofurans and/or alkylene oxides in the presence of carboxylic acid anhydrides or compounds containing reactive hydrogen using an optionally non-acidified or acid-activated calcined and granular natural amorphous aluminum silicate catalyst. The inventive method provides a means for substantially suppressing the formation of cyclic ethers and for obtaining a polymer with a narrow molecular weight distribution by keeping the concentration of carboxylic acid anhydrides or alkylene oxide constantly below 1 wt. % during polymerization. The catalysts have a long life span and lead to polymers that are characterized by highly uniform properties and a narrow molecular weight distribution even if a fairly impure monomer is used.
    Type: Grant
    Filed: March 30, 2001
    Date of Patent: May 6, 2003
    Inventor: Herbert Müller
  • Publication number: 20030078328
    Abstract: Novel ultraviolet absorbing compounds that are liquid in nature, are extremely low in color (and thus permit use without the concomitant necessity of adding large amounts of other coloring agents to combat such discoloring), and are highly effective in providing protection in wavelength ranges for which previous attempts at low-color ultraviolet absorbers have failed are provided herein. Such compounds provide such excellent, inexpensive, and beneficial protection from ultraviolet exposure within various media, including, but not limited to, clear thermoplastics. The particular compounds are generally polymeric in nature including various chain lengths of polyoxyalkylenes thereon and are liquid in nature to facilitate handling and introduction within the target media. In addition, such ultraviolet absorbers also exhibit extremely low migratory properties thereby providing long-term protective benefits to the target media as well.
    Type: Application
    Filed: August 21, 2001
    Publication date: April 24, 2003
    Inventors: Mary E. Mason, Xiaodong E. Zhao, Eric B. Stephen
  • Publication number: 20030078329
    Abstract: Novel ultraviolet absorbing compounds that are liquid in nature, are extremely low in color (and thus permit use without the concomitant necessity of adding large amounts of other coloring agents to combat such discoloring), and are highly effective in providing protection in wavelength ranges for which previous attempts at low-color ultraviolet absorbers have failed are provided herein. Such compounds provide such excellent, inexpensive, and beneficial protection from ultraviolet exposure within various media, including, but not limited to, clear thermoplastics. The particular compounds are generally polymeric in nature including various chain lengths of polyoxyalkylenes thereon and are liquid in nature to facilitate handling and introduction within the target media. In addition, such ultraviolet absorbers also exhibit extremely low migratory properties thereby providing long-term protective benefits to the target media as well.
    Type: Application
    Filed: August 21, 2001
    Publication date: April 24, 2003
    Inventors: Xiaodong E. Zhao, Todd D. Danielson, Mary E. Mason, Daniel M. Connor, Eric B. Stephens, Jason D. Sprinkle, Jusong Xia
  • Patent number: 6540942
    Abstract: Nonaqueous compositions comprising at least one product of the reaction between A) a linking agent of formula I R4(Y)3  (I) Wherein each Y group is a halogen atom or one Y group is a halogen atom and two Y groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R4 group to form an epoxy group, and R4 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) a compound of formula II R3(EO)n(PO)m(BO)pX  (II) Wherein R3 is substituted or unsubstituted, saturated or unsaturated, organic oxy or thio group having from 1 to 36 carbon atoms or a primary or secondary amino group having from 1 to 36 carbon atoms; n is a number of from 0 to 50; m is a number of from 0 to 50; p is a number of from 0 to 50; and X is hydrogen, or X can be a mercapto group, an amino group, or a C1-C6 alkylamino group in place of a terminal —OH group, provided that when X is mercapto, amino or a C1-C6 alkylamino, the sum of n, m, and p must be at least 1; and the
    Type: Grant
    Filed: October 15, 2001
    Date of Patent: April 1, 2003
    Assignee: Cognis Corporation
    Inventors: Miguel A. Dones, Ramesh L. Narayan
  • Publication number: 20030060594
    Abstract: Alkoxylated acrylate and methacrylate macromonomers are disclosed that are useful in the preparation of water-reducing additives for concrete, ultraviolet light-curable adhesives, and water-dispersed polyurethanes. The macromonomers are suitably prepared by alkoxylating a hydroxyalkylacrylate or hydroxyalkylmethacrylate in the presence of a DMC catalyst using the continuous addition of starter (CAOS) in order to prevent the formation of by-products during the fabrication of the macromonomer.
    Type: Application
    Filed: July 23, 2002
    Publication date: March 27, 2003
    Applicant: ARCO Chemical Technology, L.P.
    Inventor: Jianzhong Shen
  • Patent number: 6538061
    Abstract: A composition comprising the reaction products of MaMHbMEcDdDHeDEfTgTHhTEiQj where M=R1R2R3SiO1/2; MH=R4R5HSiO1/2; ME=R6R7RESiO1/2; D=R8R9SiO2/2; DH=R10HSiO2/2; DE=R11RESiO2/2; T=R12SiO3/2; TH=HSiO3/2; TE=RESiO3/2; and Q=SiO4/2; where R1, R2, R3, R8, R9 and R12 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms; R4, R5 and R10 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or hydrogen; R6, R7, R11 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or RE; each RE is independently a monovalent hydrocarbon radical containing one or more oxirane moieties having from one to sixty carbon atoms; the stoichiometric subscripts a, b, c, d, e, f, g, h, i, and j are either zero or positive subject to the following limitations: a+b+c>1; b+e+h>1; c+f+i>1; b+e+h>c+f+i
    Type: Grant
    Filed: May 16, 2001
    Date of Patent: March 25, 2003
    Assignee: General Electric Company
    Inventors: Atchara Chaiyawat, Michael J. O'Brien
  • Publication number: 20030050422
    Abstract: The invention relates to new biologically degradable aliphatic copolymers of the polyesteramide or polyesterurethane type. The invention further relates to a method for preparing the copolymers and to products which can be manufactured from the new copolymers.
    Type: Application
    Filed: March 29, 2002
    Publication date: March 13, 2003
    Applicant: IsoTis N.V.
    Inventors: Jeroen Mattijs Bezemer, Jan Feijen, Pieter Jelle Dijkstra
  • Patent number: 6531540
    Abstract: A composition comprising the reaction products of MaMHbMEcDdDHeDEfTgTHhTEiQj where M=R1R2R3SiO1/2; MH=R4R5HSiO1/2; ME=R6R7RESiO1/2; D=R8R9SiO2/2; DH=R10HSiO2/2; DE=R11RESiO2/2; T=R12SiO3/2; TH=HSiO3/2; TE=RESiO3/2; and Q=SiO4/2; where R1, R2, R3, R8, R9 and R12 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms; R4, R5 and R10 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or hydrogen; R6, R7, R11 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or RE; each RE is independently a monovalent hydrocarbon radical containing one or more oxirane moieties having from one to sixty carbon atoms; the stoichiometric subscripts a, b, c, d, e, f, g, h, i, and j are either zero or positive subject to the following limitations: a+b+c>1; b+e+h>1; c+f+i>1; b+e+h>c+f+i;
    Type: Grant
    Filed: May 16, 2001
    Date of Patent: March 11, 2003
    Assignee: General Electric Company
    Inventor: Michael J. O'Brien
  • Patent number: 6528616
    Abstract: The invention relates to new double metal cyanide (DMC) catalysts for the production of polyether polyols by polyaddition of alkylene oxides to starter compounds containing active hydrogen atoms, wherein the catalyst contains a) double metal cyanide compounds, b) organic complex ligands different from c), and c) &agr;,&bgr;-unsaturated carboxylic acid esters. The catalysts according to the invention have a significantly improved activity in the production of polyether polyols.
    Type: Grant
    Filed: October 29, 2001
    Date of Patent: March 4, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Pieter Ooms, Jörg Hofmann, Pramod Gupta
  • Patent number: 6525170
    Abstract: A polymerization process for producing highly branched polyesters is disclosed comprising reacting functional groups A and B of multi-functional branching monomer reactants of the formula A—L—Bn, where one of A and B represents an epoxide group, the other of A and B represents an acid chloride group, L represents a linking group between A and B, and n is at least 2. In accordance with a specific embodiment of the invention, branched polyesters are obtained which have a number average molecular weight of at least 1000 and a ratio of weight average molecular weight to number average molecular weight of less than 2. The invention provides a process for producing highly branched polyesters in one reaction step. The invention has the capability of making highly branched structures of high molecular weight and low polydispersity and has the advantages of not requiring multi-step reactions and purification.
    Type: Grant
    Filed: July 31, 2001
    Date of Patent: February 25, 2003
    Assignee: Eastman Kodak Company
    Inventor: Jin-Shan Wang
  • Patent number: 6524606
    Abstract: Bioerodible polyorthoesters useful as orthopedic implants or vehicles for the sustained delivery of pharmaceutical, cosmetic and agricultural agents contain amine functionalities and &agr;-hydroxy acid-containing groups.
    Type: Grant
    Filed: November 16, 2001
    Date of Patent: February 25, 2003
    Assignee: AP Pharma, Inc.
    Inventors: Steven Y. Ng, Jorge Heller
  • Patent number: 6524657
    Abstract: Aromatic aliphatic ether solvents, such as anisole, methylanisole, and phenetole, have been found useful in formulating coating solutions of polymeric dielectric materials and as a clean up solvent in the coating process. A process for forming a dielectric film on a substrate includes depositing a coating solution of a dielectric material in a formulation solvent onto a surface of the substrate and depositing an aromatic aliphatic ether solvent onto an edge portion of the surface of the substrate. The process is used to form films of dielectric materials including arylene ether dielectric polymers, hydridosiloxane resins, organohydridosiloxane resins, spin-on-glass materials, partially hydrolyzed and partially condensed alkoxysilane compositions which are cured to form a nanoporous dielectric silica material, and poly(perhydrido)silazanes.
    Type: Grant
    Filed: May 7, 2002
    Date of Patent: February 25, 2003
    Assignee: Honeywell International Inc.
    Inventors: Oana M. Leonte, Tadashi Nakano, Kelly M. Beres, Kreisler Lau
  • Patent number: 6521719
    Abstract: The present invention relates to multifunctional macromers, to a method for the manufacture thereof and to their use in unsaturated polyester resins as additives to improve mechanical properties of preparations manufactured thereof. The process for the manufacture of multifunctional macromers comprises the following steps: a) reacting a polycarboxylic acid with 2 to 4 carboxylic groups, preferably 3 to 4 carboxylic groups, with glycidyl (meth)acrylate or allyl glycidyl ether, the amount of glycidyl (meth)acrylate or allyl glycidyl ether being at least one mol of glycidyl (meth)acrylate or allyl glycidyl ether per free carboxylic group of formed macromer, and b) reacting the product from step a) with an unsaturated, aromatic or aliphatic anhydride in an amount sufficient to esterify part or all of the free hydroxyl groups of the product from step a).
    Type: Grant
    Filed: April 15, 2002
    Date of Patent: February 18, 2003
    Assignee: Ashland Inc.
    Inventors: Jukka Tulisalo, Mikael Skrifvars, Karri Airola, Jukka Estamo, Pertti Hietakari
  • Patent number: 6514432
    Abstract: The template-guided synthesis of water-soluble, chiral conducting polymer complexes is described. Synthesis of water-soluble polyaniline complexes is achieved by carefully controlling the experimental parameters such as; acid concentration, ionic strength, monomer/template ratio, total reagent concentration, and order of reagent addition. Chiral (helical) polyaniline complexes can be synthesized by addition of a chiral inducing agent (chiral acid) prior to polymerization, and the polyaniline helix can be controlled by the addition of the (+) or (−) form of the chiral acid. Moreover the quantity of chiral acid and the salt content has a significant impact on the degree of chirality in the final polymer complexes. The polyaniline and the template have been found to be mixed at the molecular level which results in chiral complexes that are robust through repeated doping and dedoping cycles.
    Type: Grant
    Filed: May 31, 2001
    Date of Patent: February 4, 2003
    Assignee: The Regents of the University of California
    Inventors: Hsing-Lin Wang, Patrick A. McCarthy, Sze Cheng Yang
  • Patent number: 6506863
    Abstract: Esters of 3-(2-furyl)-2-propenoic acid with diols having the general formula A2X, in which A is a 3-(2-furyl)-2-propenoate group and X is a C1-C6 alkylene group. The said esters are used as crosslinking agents in processes for crosslinking polymers.
    Type: Grant
    Filed: December 14, 2001
    Date of Patent: January 14, 2003
    Assignee: Basell Poliolefine Italia S.p.A.
    Inventors: Francesco Romani, Vittorio Braga
  • Publication number: 20020198356
    Abstract: In accordance with the present invention, there are provided novel heterobifunctional monomers and uses for the same. Invention compounds have many of the properties required by the microelectronics industry, such as, for example, hydrophobicity, high Tg values, low dielectric constant, ionic purity, low coefficient of thermal expansion (CTE), and the like. These properties result in a thermoset that is particularly well suited to high performance applications where typical operating temperatures are often significantly higher than those at which prior art materials were suitable. Invention compounds are particularly ideal for use in the manufacture of electronic components, such as, for example, printed circuit boards, and the like.
    Type: Application
    Filed: July 22, 2002
    Publication date: December 26, 2002
    Applicant: Loctite
    Inventors: Stephen M. Dershem, Kevin J. Forrestal
  • Patent number: 6492449
    Abstract: The present invention concerns polymers obtained by anionic initiation and bearing functions that can be activated by cationic initiations that are not reactive in the presence of anionic polymerization initiators. The presence of such cationic initiation functions allow an efficient cross-linking of the polymer after moulding, particularly in the form of a thin film. It is thus possible to obtain polymers with well-defined properties in terms of molecular weight and cross-linking density. The polymers of the present invention are capable of dissolving ionic compounds inducing a conductivity for the preparation of solid electrolytes.
    Type: Grant
    Filed: May 7, 2002
    Date of Patent: December 10, 2002
    Assignee: Hydro-Quebec
    Inventors: Christophe Michot, Alain Vallée, Paul-Étienne Harvey, Michel Gauthier, Michel Armand
  • Patent number: 6485819
    Abstract: A copolyester of the reaction product of: (a) one or more aromatic dicarboxylic acids or an ester thereof; (b) one or more aliphatic dicarboxylic acids or an ester thereof; and (c) isosorbide. The polyesters are useful to form articles of increased biodegradability.
    Type: Grant
    Filed: December 19, 2000
    Date of Patent: November 26, 2002
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Richard Allen Hayes
  • Patent number: 6482918
    Abstract: There are herein disclosed a transparent optical material containing at least one selenium atom, a plastic lens comprising the transparent optical material, and methods for preparing them. In addition, there are also disclosed novel selenium-containing compounds represented by the following formulae (1), (2) and (4) which are useful for the transparent optical material and the plastic lens: wherein symbols are as defined in the specification.
    Type: Grant
    Filed: August 23, 2001
    Date of Patent: November 19, 2002
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Koju Okazaki, Mamoru Tanaka, Shiro Honma, Hiroyuki Morijiri, Yoshinobu Kanemura, Masahiko Kusumoto