Subsequent Treatment Process Patents (Class 536/76)
  • Patent number: 4499043
    Abstract: A process for producing a cellulose ester support is described which comprises producing said support from an organic solvent solution of a cellulose ester containing 30 ppm or less alkaline earth metal.
    Type: Grant
    Filed: May 6, 1982
    Date of Patent: February 12, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masao Yabe, Kyoichi Naruo, Kazuhiro Ono
  • Patent number: 4461892
    Abstract: A process for preparing porous, spherical cellulose particles which comprises suspending a cellulose organic ester solution dissolved in a chlorinated hydrocarbon solvent into an aqueous medium to form droplets of the solution, evaporating the chlorinated hydrocarbon solvent in the droplets to form cellulose organic ester spherical particles, and saponifying the cellulose organic ester spherical particles. In the aforesaid process, an acid or alkaki is added and mixed with the cellulose organic ester solution prior to suspending the cellulose organic ester solution into the aqueous medium to control the porosity of the porous, spherical cellulose particles with high reproducibility.
    Type: Grant
    Filed: February 23, 1983
    Date of Patent: July 24, 1984
    Assignee: Chisso Corporation
    Inventors: Masahiko Nishikawa, Hiroaki Ishibashi, Hidenori Furukawa
  • Patent number: 4415734
    Abstract: Secondary cellulose acetate (cellulose diacetate) of improved whiteness is produced by ripening primary cellulose acetate (cellulose triacetate) using a lower aliphatic alcohol instead of an aqueous medium.
    Type: Grant
    Filed: July 12, 1982
    Date of Patent: November 15, 1983
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Hideo Yabune, Manabu Uchida
  • Patent number: 4390691
    Abstract: A process for preparing porous, spherical cellulose particles which comprises suspending a cellulose organic ester solution dissolved in a chlorinated hydrocarbon solvent into an aqueous medium to form droplets of the solution, evaporating the chlorinated hydrocarbon solvent in the droplets to form cellulose organic ester spherical particles, and saponifying the cellulose organic ester spherical particles. In the aforesaid process, an acid or alkali is added and mixed with the cellulose organic ester solution prior to suspending the cellulose organic ester solution into the aqueous medium to control the porosity of the porous, spherical cellulose particles with high reproducibility.
    Type: Grant
    Filed: July 21, 1981
    Date of Patent: June 28, 1983
    Assignee: Chisso Corporation
    Inventors: Masahiko Nishikawa, Hiroaki Ishibashi, Hidenori Furukawa
  • Patent number: 4357295
    Abstract: Removal of haze from plastic articles made of cellulose acetate butyrate, such as light polarizing sunglass lenses made of cellulose acetate butyrate and polyvinyl alcohol, is accomplished by immersing said plastic articles in a substantially water-free bath composition at least 70 weight percent of which comprises an active solvent and a carrier solvent, the former being methyl alcohol, ethyl alcohol, propyl alcohol, butyl alcohol, or any mixture thereof, and the latter being ethylene glycol, glycerol, tricresyl phosphate, butyl phthalate, or any mixture thereof. Preferred values of the relative proportions of the active solvent and the carrier solvent are in the range of 90-5 and 10-95 weight percent, respectively, and more preferably, 80-10 and 20-90 weight percent, respectively.
    Type: Grant
    Filed: July 23, 1981
    Date of Patent: November 2, 1982
    Assignee: Foster Grant Corporation
    Inventors: Theodore A. Haddad, Walter Kondig, Richard A. Phillips
  • Patent number: 4342865
    Abstract: Improved method for bleaching cellulose esters, such as cellulose acetate, cellulose acetate propionate and cellulose acetate butyrate, by adding during the hydrolysis reaction of the cellulose ester at from 80.degree. C. to 150.degree. C. a bleaching agent mixture of hydrogen peroxide and at least one monopersulfate salt selected from the group consisting of sodium, potassium and lithium or mixtures thereof.
    Type: Grant
    Filed: July 27, 1981
    Date of Patent: August 3, 1982
    Assignee: Eastman Kodak Company
    Inventors: Richard J. Brewer, Richard T. Bogan
  • Patent number: 4312980
    Abstract: A solution of cellulose triacetate in a mixed solvent consisting essentially of a chlorinated hydrocarbon with a boiling point lower than that of an aqueous medium and an aliphatic higher alcohol with 6 or more than 6 carbon atoms is suspended into the aqueous medium to form droplets of the above-mentioned solution, and then the chlorinated hydrocarbon in the droplets is removed by evaporation to obtain spherical particles of cellulose triacetate containing the aliphatic higher alcohol. The spherical particles thus obtained are saponified and removed of the aliphatic higher alcohol, to prepare porous cellulose spherical particles.
    Type: Grant
    Filed: July 30, 1980
    Date of Patent: January 26, 1982
    Assignees: Chisso Corporation, Yoshiaki Motozato
    Inventors: Yoshiaki Motozato, Hiroaki Ishibashi
  • Patent number: 4306060
    Abstract: Cellulose acetate is prepared acetylating cellulose at a high temperature of 50.degree.-85.degree. C. and then ripening the acetylated cellulose at a high temperature of 110.degree.-120.degree. C.
    Type: Grant
    Filed: December 15, 1980
    Date of Patent: December 15, 1981
    Assignee: Daicel Chemical Industries, Ltd.
    Inventor: Yoshiyuki Ikemoto
  • Patent number: 4271291
    Abstract: Process for recovering entrained cellulose ester fines from scrubber-coolant water by forming a wet foam containing the fines, floating the wet foam upwardly in a vertically disposed foam flotation column and outwardly along a horizontal straight-line path from which liquid from the wet foam is drained and the fines are introduced in the form of a drier foam into a vessel for subsequent dissolving of the fines, with the horizontal straight-line path being pitched downardly from the horizontal plane.
    Type: Grant
    Filed: July 28, 1980
    Date of Patent: June 2, 1981
    Assignee: Eastman Kodak Company
    Inventor: Bradley H. Dayvolt
  • Patent number: 4269972
    Abstract: Cellulose diacetate having improved resistance to delustering in hot water is produced by acetylation cellulose in the presence of a catalyst and then hydrolyzing (or ripening) the product to form secondary cellulose acetate; wherein the catalyst in the acetylated mixture is completely neutralized before about the middle of the hydrolysis reaction at the latest and thereafter hydrolysis is carried out at a temperature of about 110.degree. to 120.degree. C. while maintaining the concentration of acetic acid in the reaction mixture at about 67 to 78% by weight based on the total weight of the acetic acid and water, the relation between the hydrolysis temperature and the concentration of acetic acid being defined by the area between and including points A, B, C and D in FIG. 2.
    Type: Grant
    Filed: June 11, 1979
    Date of Patent: May 26, 1981
    Assignee: Daicel Ltd.
    Inventors: Hideo Yabune, Yoshiyuki Ikemoto
  • Patent number: 4249000
    Abstract: Polymers from the group consisting of cellulose and its ester and ether derivatives, of polyvinyl alcohol and its ester derivatives, polymers with vinyl esters and homopolymers and copolymers of acrylates and methacrylates are modified with monofunctional or difunctional cyclic .beta.-ketonic acids or their esters, in particular with succinylsuccinic acid or its ester derivatives. The modified polymers are particularly suitable for obtaining semi-permeable membranes for osmotic separation methods.
    Type: Grant
    Filed: February 21, 1979
    Date of Patent: February 3, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans Batzer, Joel Sinnreich
  • Patent number: 4243776
    Abstract: Biocompatible articles are obtained by treating a polymeric material with a hydrolyzing agent on its surface and covalently binding thereon a biological agent, such as an anti-platelet-aggregation agent.
    Type: Grant
    Filed: June 21, 1978
    Date of Patent: January 6, 1981
    Assignee: Snamprogetti S.p.A.
    Inventors: Walter Marconi, Francesco Pittalis, Francesco Bartoli, Franco Morisi
  • Patent number: 4234528
    Abstract: An asymmetrical ultrafiltration membrane based on cellulose hydrate which may be dried without destructive shrinkage and which has been saponified without reduction in flow-through or separation performance is prepared by adding hydrophobic synthetic silicic acid to a casting solution based on cellulose triacetate optionally partially substituted by cellulose diacetate, and then casting the cellulose acetate membrane and saponifying to the cellulose hydrate form.
    Type: Grant
    Filed: April 10, 1979
    Date of Patent: November 18, 1980
    Assignee: Sartorius GmbH
    Inventors: Dietmar Nussbaumer, Horst Perl
  • Patent number: 4228276
    Abstract: Improved method for preparing cellulose acetate powder, particularly extrusion-grade powder, by direct precipitation, with the precipitation step occurring at a temperature of about 65.degree. C. to about 95.degree. C. and with the coagulating agent subsequently being removed from the resulting liquid powder slurry also at a temperature of about 65.degree. C. to about 95.degree. C.; and the cellulose acetate powder product resulting from the improved method, the powder being particularly adapted to take up plasticizer up to about 50 percent by weight and still flow uniformly without caking or becoming tacky.
    Type: Grant
    Filed: March 26, 1979
    Date of Patent: October 14, 1980
    Assignee: Eastman Kodak Company
    Inventors: Chung-Ming Kuo, Richard T. Bogan
  • Patent number: 4077971
    Abstract: A compound of the formula, wherein R.sub.1 is hydrogen or a halogen atom, R.sub.2 is ##STR1## R.sub.3 is hydrogen, an alkyl group, a cycloalkyl group or an aralkyl group, and n is an integer of 1 or 2, which is useful as ultraviolet absorber.
    Type: Grant
    Filed: August 15, 1975
    Date of Patent: March 7, 1978
    Assignees: Sumitomo Chemical Company, Limited, Kyodo Chemical Company, Ltd.
    Inventors: Taira Fujita, Kondo Yutaka, Nozomi Abe, Takashi Akamatsu
  • Patent number: 4005070
    Abstract: A novel substance, viz., the salt of .beta.-diethylaminoethyl p-aminobenzoate with celluloseglycolic acid has the following general formula: ##STR1## WHERE X STANDS FOR THE DEGREE OF SUBSTITUTION RANGING FROM 75 TO 100n stands for the degree of polymerization ranging from 30 to 120.A method of producing said compound comprises reacting .beta.-diethylaminoethyl p-aminobenzoate with celluloseglycolic acid in an aqueous medium, whereupon the final product is isolated.The aforementioned compound, viz., the salt of .beta.-diethylaminoethyl p-aminobenzoate with celluloseglycolic acid is the active principle of a local anesthetic drug. The proposed drug finds application in medical practive as an anesthetic in infiltration, conduction or spinal anesthesia, as well as in surface anesthesia.
    Type: Grant
    Filed: November 30, 1971
    Date of Patent: January 25, 1977
    Inventors: Milda Jaovna Pormale, Nadezhda Alexandrovna Kashkina, Arvid Janovich Kalninsh, Varvara Nikolaevna Sergeeva, Janis Alexandrovich Surna, Janis Shusters, Modris Jaowich Melzobs, Waldis Danielowich Mikazhan, Indulis Waldowich Purwinsh, Antons Petrowich Skutelis, Martinsh Aleksandrowich Liepinsh