Hetero Ring Patents (Class 544/209)
-
Patent number: 5091529Abstract: Herbicidal substituted sulphonylaminoazoles of the formula ##STR1## in which R.sup.1 is optionally substituted alkyl, aralkyl, aryl or heteroaryl,R.sup.2 is hydrogen or --SO.sub.2 --R.sup.1,R.sup.3 is hydrogen, halogen, hydroxyl, mercapto, amino, or an optionally substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino radical,A is CH, nitrogen or,at least one of A, D and E is ##STR2## and the others may be that or CH or nitrogen, and X, Y and Z each is nitrogen or optionally substituted C, and salts thereof.Type: GrantFiled: January 7, 1991Date of Patent: February 25, 1992Assignee: Bayer AktiengesellschaftInventors: Rolf Kirsten, Joachim Kluth, Christa Fest, Ernst Gesing, Klaus-Helmut Muller, Hans-Jochem Riebel, Peter Babczinski, Otto Schallner, Hans-Joachim Santel, Robert R. Schmidt, Harry Strang
-
Patent number: 5091450Abstract: Compounds of the formula (I) ##STR1## in which A.sub.1 is e.g. --O-- or >N--R.sub.1 where R.sub.1 is e.g. hydrogen, methyl, 2,2,6,6-tetramethyl-4-piperidyl or 1,2,2,6,6-pentamethyl-4-piperidyl, A.sub.2 is e.g. a direct bond or --CH.sub.2 --, X.sub.1 and X.sub.3 which can be identical or different are e.g. a group of the formula (IIIa) or (IIIb) ##STR2## in which A.sub.3 and A.sub.4 which can be identical or different are e.g. an >N--R.sub.1 group where R.sub.1 is as defined above, R.sub.3 is e.g. --(CH.sub.2).sub.2-6 -- or --(CH.sub.2).sub.3 --O--(CH.sub.2).sub.2-4 --O--(CH.sub.2).sub.3 -- and R.sub.4 is e.g. hydrogen or methyl, X.sub.2 is e.g. 2-hydroxytrimethylene or a group of the formula (IVa) ##STR3## where R.sub.8 is e.g. a group of the formula (V) ##STR4## m is e.g. zero or 1, n is e.g. a number from 1 to 10, Y.sub.1 is e.g. OH, ONa, OK, a group R.sub.8 or a group --X.sub.1 Z or --X.sub.3 Z with Z being e.g. hydrogen or methyl and Y.sub.2 is e.g.Type: GrantFiled: July 22, 1991Date of Patent: February 25, 1992Assignee: Ciba-Geigy CorporationInventors: Valerio Borzatta, Graziano Vignali
-
Patent number: 5089044Abstract: The invention relates to new substituted pyrimidinyloxy(thio)- and triazinyloxy(thio)acrylic acid derivative of general formula I ##STR1## in which A, G, R.sup.1-3, X and Y have the meanings given in the description, processes for their preparation and their use as herbicides, fungicides and plant growth regulants.Type: GrantFiled: July 19, 1990Date of Patent: February 18, 1992Assignee: Schering AktiengesellschaftInventors: Christoph Harde, Erhard Nordhoff, Anita Kruger, Gabriele Kruger, Gerhard Tarara, Peter Wegner, Nikolaus Heinrich, Clemens Kotter, Gerhard Johann, Richard Rees
-
Patent number: 5085687Abstract: Herbicidal substituted sulphonylaminotriazolinones of the formula ##STR1## in which R.sup.1 represents an optionally substituted radical from the group consisting of alkyl, aralkyl, aryl and heteroaryl,R.sup.2 represents hydrogen or the group --SO.sub.2 --R.sup.1 where R.sup.1 has the abovementioned meaning,R.sup.3 represents hydrogen, halogen, hydroxyl, mercapto, amino or an optionally substituted radical from the group consisting of alkyl, cycloalkyl, aralkyl, aryl, alkoxy, alkenyloxy, alkinyloxy, alkylthio, alkylsulphinyl, alkylsulphonyl, alkenylthio, alkinylthio, aralkoxy, aralkylthio, alkylamino and dialkylamino,R.sup.4 represents hydrogen, halogen, hydroxyl, amino or an optionally substituted radical from the group consisting of alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, alkylamino and dialkylamino,X represents nitrogen or a CH group,Y represents nitrogen or a CR.sup.5 group whereR.sup.Type: GrantFiled: September 17, 1990Date of Patent: February 4, 1992Assignee: Bayer AktiengesellschaftInventors: Klaus-Helmet Muller, Rolf Kirsten, Joachim Kluth, Klaus Konig, Hans-Jochem Riebel, Peter Babczinski, Hans-Joachim Santel, Robert R. Schmidt, Harry Strang
-
Patent number: 5084459Abstract: There is provided a pest control composition containing a compound represented by the formula, ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are the same or different and independently mean a hydrogen atom, a hydrocarbon group which may be substituted or a heterocyclic group which may be substituted and X means an electron attracting group or a salt thereof.The compounds are of minimal toxicity to man, domestic animals and fish and selectively display remarkable control effect on pests.Type: GrantFiled: October 25, 1989Date of Patent: January 28, 1992Assignee: Takeda Chemical Industries, Ltd.Inventors: Hideki Uneme, Isao Minamida, Tetsuo Okauchi, Noriko Higuchi
-
Patent number: 5079361Abstract: Cross-linking reagents which are highly specific for sulphydryl groups and react with thiols at an excellent rate. The essential feature of the reagents is at least one vinyl group conjugated with an armoatic nitrogen heterocycle. Particular examples include vinyl pyridines, vinyl pyrimidines and vinyl triazines.Type: GrantFiled: September 9, 1988Date of Patent: January 7, 1992Assignee: Celltech LimitedInventors: Rikki P. Alexander, Michael A. W. Eaton, Thomas A. Millican, Richard C. D. Titmas
-
Patent number: 5073185Abstract: Compounds of the formula I or their salts ##STR1## wherein R.sup.1 and R.sup.2 denote H, halogen, alkyl, alkenyl, alkynyl or alkoxy, which can be substituted, or denote --(CH.sub.2).sub.n --COOR.sup.11 ;R.sup.3 denotes H, alkyl, alkenyl or alkynyl;R.sup.4 denotes a heterocyclic radical of the formulae ##STR2## where E is CH or N; X is O or S and a, b, c, d, e in each case denote 0, 1 or 2, with the proviso that c+d+e.gtoreq.2, possess excellent herbicidal and plant growth-regulating properties.Type: GrantFiled: March 15, 1990Date of Patent: December 17, 1991Assignee: Hoechst AktiengesellschaftInventors: Lothar Willms, Klaus Bauer, Hermann Bieringer, Helmut Burstell
-
Patent number: 5062882Abstract: Triazine herbicides of the general formula I ##STR1## wherein R.sup.1 and R.sup.2 each independently represent a hydrogen or halogen atom, or an optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, alkoxy, alkenyloxy, alkynyloxy, aryloxy, alkylthio, alkenylthio, alkynylthio, arylthio or amino group, or a formyl, optionally substituted alkylcarbonyl, cyano, carboxy, optionally substituted alkoxycarbonyl, dialkylaminoxy, dialkyliminoxy or azido group;X represents an oxygen or sulphur atom or a group --SO.sub.2 --, --SO--, or --NR.sup.4 --where R.sup.Type: GrantFiled: March 16, 1989Date of Patent: November 5, 1991Assignee: Shell International Research Maatschappij B. V.Inventors: Trevor W. Newton, Alastair McArthur
-
Patent number: 5059689Abstract: Compounds which contain at least one group of the formula I ##STR1## in which X is a group which completes the ring to form a piperidine ring, are effective stabilizers for organic materials against damage by light, oxygen and heat.Type: GrantFiled: January 30, 1989Date of Patent: October 22, 1991Assignee: Ciba-Geigy CorporationInventors: Jean Rody, Gerhard Rytz, Mario Slongo
-
Patent number: 5055578Abstract: A class of fluorescent rare earth chelates and the ligands upon which they are based whose molecular structure incorporates a plurality of substituted arylpyridine diacid units attached to a central template structure is disclosed. These ligands function as efficient energy transfer groups in fluorescent tagging reagents and tracers.Type: GrantFiled: November 5, 1990Date of Patent: October 8, 1991Assignee: Baxter Diagnostics Inc.Inventors: Ron L. Hale, Dennis W. Solas
-
Patent number: 5051421Abstract: Benzo[b]thiophene derivatives of formula ##STR1## their tautomers and salts, in which the index n is 0, 1 or 2, alk is lower alkylene, Ar is phenyl, naphthyl or a monocyclic, five- or six-membered heteroaryl radical, wherein the aromatic radical is unsubstituted or is mono- or poly-substituted by lower alkyl, halo-lower alkyl, halogen and/or by nitro, and the ring A is unsubstituted or is mono- or poly-substituted by lower alkyl, lower alkoxy, lower alkylthio, lower alkanesulfinyl, lower alkanesulfonyl, halo-lower alkyl, halogen and/or by nitro, can be used, for example, as active ingredients in medicaments.Type: GrantFiled: January 18, 1990Date of Patent: September 24, 1991Assignee: Ciba-Geigy CorporationInventor: Pier G. Ferrini
-
Patent number: 5047531Abstract: Piperidine-triazine compounds of the general formula (I) ##STR1## in which R.sub.1 is e.g. hydrogen or methyl, R.sub.2 is e.g. C.sub.2 -C.sub.6 alkylene, R.sub.3 is e.g. a group ##STR2## ##STR3## can be used as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers.Type: GrantFiled: August 2, 1989Date of Patent: September 10, 1991Assignee: Ciba-Geigy CorporationInventors: Giuseppe Cantatore, Graziano Vignali
-
Patent number: 5043443Abstract: Novel aminomethyloxooxazolidinyl arylbenzene derivatives, wherein the aryl includes the phenyl, substituted phenyl, pyridyl, and substituted pyridyl groups, such as (l)-N-{3-[4- (4'-pyridyl)phenyl]-2-oxooxazolidin-5-ylmethyl}acetamide, possess useful antibacterial activity.Type: GrantFiled: July 24, 1990Date of Patent: August 27, 1991Assignee: Du Pont Merck Pharmaceutical CompanyInventors: Randall K. Carlson, Chung-Ho Park, Walter A. Gregory
-
Patent number: 5039799Abstract: The present invention relates to novel piperidine-triazine compounds of the general formula (I) ##STR1## in which R.sub.1 e.g. hydrogen or methyl, .lambda. is e.g. 1 and R.sub.2 and R.sub.3 are e.g. N-(2,2,6,6-tetramethyl-4-piperidyl)-tetrahydrofurfurylamino or 1,2,2,6,6-pentamethyl-4-piperidyloxy.These compounds are effective as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials.Type: GrantFiled: September 20, 1989Date of Patent: August 13, 1991Assignee: Ciba-Geigy CorporationInventors: Guiseppe Cantarore, Valerio Borzatta, Franca Masina
-
Patent number: 5039722Abstract: The new compounds of formula (I) ##STR1## in which R.sub.1 is e.g. hydrogen or methyl, R.sub.2 is e.g. a group --OR.sub.5 or ##STR2## in which R.sub.5 is e.g. 2,2,6,6-tetramethyl-4-piperidyl or 1,2,2,6,6-pentamethyl-4-piperidyl, R.sub.6 and R.sub.7 which are identical or different are e.g. C.sub.1 -C.sub.8 alkyl, tetrahydrofurfuryl, 2,2,6,6-tetramethyl-4-piperidyl or 1,2,2,6,6-pentamethyl-4-piperidyl, or R.sub.6 is also hydrogen, or the group ##STR3## is e.g. 4-morpholinyl, R.sub.3 and R.sub.4 which are identical or different are e.g. hydrogen, methyl, 2,2,6,6-tetramethyl-4-piperidyl or 1,2,2,6,6-pentamethyl-4-piperidyl, m and n are e.g. 3, and X is e.g. --O-- or ##STR4## where R.sub.9 is C.sub.1 -C.sub.8 alkyl, tetrahydrofurfuryl, 2,2,6,6-tetramethyl-4-piperidyl or 1,2,2,6,6-pentamethyl-4-piperidyl, are effective as light stabilizer, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers.Type: GrantFiled: December 21, 1989Date of Patent: August 13, 1991Assignee: Ciba-Geigy CorporationInventors: Giuseppe Cantatore, Valerio Borzatta
-
Patent number: 5034526Abstract: Radiation-sensitive organo-halogen compounds having a photo-labile halomethyl-1,3,5-triazine moiety and at least one sensitizer moiety within one molecule. The compounds of this invention are good photoinitiators, and compositions containing them can be used in printing, duplicating, copying, and other imaging systems.Type: GrantFiled: April 11, 1990Date of Patent: July 23, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventors: James A. Bonham, Mitchell A. Rossman
-
Patent number: 5030729Abstract: Compounds of formula (I) ##STR1## in which R.sub.1 is hydrogen, O.degree., CN, NO, cyanomethyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.12 -alkenyl or C.sub.3 -C.sub.12 -alkynyl subject to the proviso that the carbon atom attached to the nitrogen atom is a primary carbon atom, C.sub.7 -C.sub.12 -aralkyl, C.sub.1 -C.sub.12 -acyl, 2,3-epoxypropyl, OH-monosubstituted C.sub.2 -C.sub.6 -alkyl or 2,3-dihydroxypropyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.18 -cycloalkyl, C.sub.6 -C.sub.18 -aryl or C.sub.7 -C.sub.18 -aryalkyl, R.sub.3 is C.sub.6 -C.sub.18 -aryl or a group of the formula (II) ##STR2## in which R.sub.1 is as defined above, n is an integer from 1 to 4 and R.sub.4 is an organic or inorganic radical of a valency equal to n are useful for stabilizing organic material against oxidative, thermal and/or light induced degradation.Type: GrantFiled: March 1, 1990Date of Patent: July 9, 1991Assignee: Ciba-Geigy CorporationInventors: Giuseppe Cantatore, Valerio Borzatta
-
Patent number: 5026849Abstract: A process is taught for recovering a white reaction product of a cyanuric halide with an amine reactant (white being indicative of the product's high purity), in high yield. In the absence of a solvent for either reactant, the first step comprises reacting the cyanuric halide, as a finely divided solid, with a liquid amine which is to provide a saturated heterocyclic amine group, such as a polysubstituted piperazinone, piperazine, or piperidine as the substituent for each of the three halogen atoms of the cyanuric halide used. This solventless process carried out under essentially anhydrous conditions, with a large molar excess of the amine reactant chosen, not only shortens the long time required to make the desired tri-substitution in a conventional solvent process, but also obviates using a pressurized reactor.Type: GrantFiled: June 9, 1989Date of Patent: June 25, 1991Assignee: The B. F. Goodrich CompanyInventors: George Kletecka, Victor L. Ledesma
-
Patent number: 5021558Abstract: Water-soluble fiber-reactive azo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylemthane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dyes which contain once or twice the group of the general formula ##STR1## in which: R.sup.x and R.sup.z are, independently of one another, hydrogen or lower alkyl, which can be substituted by halogen, hydroxyl, cyano, lower alkoxy, lower alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato;W is fluorine, chlorine, bromine, sulfo, phenylsulfonyl or alkylsulfonyl of 1 to 4 carbon atoms;Y is vinyl, .beta.-substituted, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-alkanoyloxyethyl of 2 to 5 carbon atoms in the alkanoyl radical, .beta.-benozoyloxyethyl, .beta.-(sulfobenzoyloxy)ethyl, .beta.-(p-toluenesulfonyloxy)ethyl or .beta.-halogenoethyl.Type: GrantFiled: March 20, 1990Date of Patent: June 4, 1991Assignee: Hoechst AktiengesellschaftInventor: Holger M. Buch
-
Patent number: 5021082Abstract: Herbicidal substituted sulphonylaminoazoles of the formula ##STR1## in which R.sup.1 is optionally substituted alkyl, aralkyl, aryl or heteroaryl,R.sup.2 is hydrogen or --SO.sub.2 --R.sup.1,R.sup.3 is hydrogen, halogen, hydroxyl, mercapto, amino, or an optionally substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino radical,A is CH, nitrogen or,at least one of A, D and E is ##STR2## and the others may be that or CH or nitrogen, and X, Y and Z each is nitrogen or optionally substituted C, and salts thereof.Type: GrantFiled: April 3, 1990Date of Patent: June 4, 1991Assignee: Bayer AktiengesellschaftInventors: Rolf Kirsten, Joachim Kluth, Christa Fest, Ernst Gesing, Klaus-Helmut Muller, Hans-Jochem Riebel, Peter Babczinski, Otto Schallner, Hans-Joachim Santel, Robert R. Schmidt, Harry Strang
-
Patent number: 5011527Abstract: This invention relates to certain heterocyclic sulfonylurea herbicidal compounds, agriculturally suitable compositions thereof and a method of their use.Type: GrantFiled: October 27, 1989Date of Patent: April 30, 1991Assignee: E. I. Du Pont de Nemours and CompanyInventor: Barry A. Wexler
-
Patent number: 5010190Abstract: The invention relates to novel cationic compounds of formula ##STR1## wherein Z is a radical of formula ##STR2## B and B.sup.1 are each independently of the other a radical Z, a cationic radical different from Z or a radical of formula ##STR3## R.sup.1 is unsubstituted C.sub.1 -C.sub.6 alkyl or C.sub.3 -C.sub.4 -alkenyl,R.sup.2 is unsubstituted or substituted C.sub.1 -C.sub.6 alkyl,R.sup.3 and R.sup.4 are each independently of the other hydrogen, unsubstituted or substituted C.sub.1 -C.sub.4 alkyl, unsubstituted or substituted C.sub.1 -C.sub.4 alkoxy, --NO.sub.2, unsubstituted or substituted acylamino, halogen or --CN,R.sup.5 is hydrogen, unsubstituted or substituted C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 alkenyl or aryl,R.sup.6 is hydrogen, unsubstituted or substituted C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 alkenyl or aryl, or R.sup.5 and R.sup.6, together with the linking nitrogen atom, are a heterocyclic radical,X is a sulfur atom or the group ##STR4## wherein R.sup.7 and R.sup.Type: GrantFiled: May 9, 1988Date of Patent: April 23, 1991Assignee: Ciba-Geigy CorporationInventor: Willy Stingelin
-
Patent number: 5006156Abstract: Herbicidal sulphonylaminoazines of the formula ##STR1## in which R.sup.1 represents halogen, cyano, nitro, C.sub.1 -C.sub.2 -alkyl, C.sub.1 -C.sub.2 -halogenoalkyl, C.sub.1 -C.sub.2 -alkoxy, C.sub.1 -C.sub.2 -halogenoalkoxy, C.sub.1 -C.sub.2 -alkylthio, C.sub.1 -C.sub.2 -halogenoalkylthio, C.sub.1 -C.sub.2 -alkylsulphinyl, C.sub.1 -C.sub.2 -halogenoalkylsulphinyl, C.sub.1 -C.sub.2 -alkylsulphonyl, C.sub.1 -C.sub.2 -halogenoalkylsulphonyl, C.sub.1 -C.sub.2 -alkoxy-C.sub.1 -C.sub.2 -alkoxy, di-(C.sub.1 -C.sub.2 -alkylamino)-sulphonyl, N-(C.sub.1 -C.sub.2 -alkoxy)-N-(C.sub.1 -C.sub.2 -alkyl)-aminosulphonyl or C.sub.1 -(C.sub.2 -alkoxy-carbonyl,R.sup.2 and R.sup.3 independently of one another represent hydrogen, halogen, alkyl or halogenoalkyl,n represents the numbers 0 or 1,X represents hydrogen, C.sub.1 -C.sub.2 -alkyl, C.sub.1 -C.sub.2 -halogenoalkyl, C.sub.1 -C.sub.2 -alkyl, cyclopropyl, C.sub.1 -C.sub.2 -alkoxy, C.sub.1 -C.sub.2 -halogenoalkoxy, C.sub.1 -C.sub.2 -alkoxy-C.sub.1 -C.sub.2 -alkoxy, C.sub.1 -C.Type: GrantFiled: November 20, 1989Date of Patent: April 9, 1991Assignee: Bayer AktiengesellschaftInventors: Ernst R. Gesing, Hans-Joachim Santel, Robert R. Schmidt, Harry Strang
-
Patent number: 5003066Abstract: The polyglycidamides are epoxy derivatives of cyclic ureas such as glycouril and aminotriazines such as melamine and guanamines. They are prepared from cyclic ureas and aminotriazines by methylolating with formaldehyde, etherifying with an alcohol, transetheramidizing with acrylamide and epoxidizing with hydrogen peroxide. They are used with polyamines and other epoxy reactive oligomers to provide crosslinkable coating systems which posses solvent, chemical and water resistance and UV stability.Type: GrantFiled: March 29, 1989Date of Patent: March 26, 1991Assignee: Monsanto CompanyInventor: William F. Pfohl
-
Patent number: 4997938Abstract: The novel compounds of the formula (I) ##STR1## in which R.sub.1 is di(C.sub.1 -C.sub.4 -alkyl)amino, C.sub.1 -C.sub.4 -alkoxy, a 5-membered to 7-membered nitrogen containing heterocyclic group with the nitrogen atom bonded to the triazine ring, or a group of the formula (II), ##STR2## R.sub.2 and R.sub.4 which are identical or different are C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, benzyl or 1,2,2,6,6-pentamethyl-4-piperidyl, n is 2 or 3 and, if n is 2, R.sub.3 is a group ##STR3## with R.sub.5 and R.sub.7, which are identical or different, being hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, benzyl or 1,2,2,6,6-pentamethyl-4-piperidyl and R.sub.6 being C.sub.2 -C.sub.12 -alkylene, cyclohexylene, cyclohexylenedimethylene or methylenedicyclohexylene, or R.sub.3 is the divalent radical of a 6-membered to 7-membered heterocyclic compound with two nitrogen atoms which are each bonded to a triazine ring, or, if n is 3, R.sub.3 is a group ##STR4## with R.sub.8 and R.sub.Type: GrantFiled: December 8, 1989Date of Patent: March 5, 1991Assignee: Ciba-Geigy CorporationInventors: Giuseppe Cantatore, Valerio Borzatta, Franca Masina
-
Patent number: 4996218Abstract: Compounds of the general formula (I) ##STR1## and physiologically acceptable salts and solvates thereof, which have .beta..sub.2 -adrenoreceptor stimulant activity. They may be used in the treatment of diseases associated with reversible airways obstruction, such as asthma and chronic bronchitis.In preferred embodiments, Q represents a chlorine atom or a trifluoromethyl group, X represents a C.sub.3-4 alkylene chain, Y a C.sub.1-5 alkylene chain, R, R.sup.1 and R.sup.2 are each preferably a hydrogen atom or a methyl group and Het represents a pyrimidinyl pyrazinyl, triazinyl, thiazolyl, quinolinyl, benzimidazolyl, benzothiazolyl, benzoxazolyl or pyridyl group.Type: GrantFiled: August 10, 1988Date of Patent: February 26, 1991Assignee: Glaxo Group LimitedInventor: Lawrence H. C. Lunts
-
Patent number: 4995901Abstract: Herbicidal sulfonamides having the general formula ##STR1## wherein J, W, R and A are more particularly described herein, such compounds and agricultural compositions containing them being useful as preemergent or postemergent herbicides or both, or as plant growth regulants, including the manner of their use.Type: GrantFiled: January 5, 1990Date of Patent: February 26, 1991Assignee: E. I. du Pont de Nemours and CompanyInventor: Morris P. Rorer
-
Patent number: 4985562Abstract: Radiation-sensitive organo-halogen compounds having a photo-labile halomethyl-1,3,5-triazine moiety and at least one amine-containing moiety within one molecule. The compounds serve the dual purpose of photoinitiation and polymerization acceleration, thereby eliminating the need for the use of two separate compounds. The compounds of this invention are good photoinitiators, and compositions containing them are useful in printing, duplicating, copying, and other imaging systems.Type: GrantFiled: September 7, 1988Date of Patent: January 15, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventors: Mitchell A. Rossman, James A. Bonham
-
Patent number: 4981964Abstract: Oligomeric polyesters and polyamides containing dipiperidyl triazine moieties are effective light stabilizers for synthetic polymers and particularly polyolefins.Type: GrantFiled: December 15, 1988Date of Patent: January 1, 1991Assignee: ICI Americas Inc.Inventors: Richard V. Nelson, John F. Stephen
-
Patent number: 4980350Abstract: Novel hypoglycemic agents having the formula (I) are disclosed.Type: GrantFiled: July 31, 1989Date of Patent: December 25, 1990Assignee: Merck & Co., Inc.Inventors: Malcolm MacCoss, Richard L. Tolman, Arthur F. Wagner
-
Patent number: 4975530Abstract: Intermediates useful for the preparation of fiber-reactive dyes having the formula ##STR1## in which Q is phenyl unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, nitro, cyano, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylsulfonyl, sulfo or trihalomethyl; 1- or 2-naphthyl; or unsubstituted or C.sub.1 -C.sub.4 alkyl, nitro, cyano, C.sub.1 -C.sub.4 alkoxycarbonyl or C.sub.1 -C.sub.4 alkylthio substituted furanyl, thienyl, thiazolyl, oxazolyl, isothiazolyl, benzothiazolyl, benzoisothiazolyl, pyrazolyl, imidazolyl, 1,2,3-triazolyl, 1,2,4-triazolyl, 1,2,4-thiadiazolyl, 1,3,4-thiadiazolyl or 1,3,5-triazinyl, and A.sub.1 and A.sub.2 independently of one another are a radical of the formula ##STR2## in which R.sub.1 and R.sub.2 independently of one another are hydrogen; C.sub.1 -C.sub.4 alkyl unsubstituted or substituted by hydroxyl, sulfo, sulfato, carboxyl, cyano, halogen, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.Type: GrantFiled: November 22, 1989Date of Patent: December 4, 1990Assignee: Ciba-Geigy CorporationInventors: Athanassios Tzikas, Kurt Burdeska
-
Patent number: 4972010Abstract: Disclosed are tris-substituted 1,3,5-triazine compounds having at least one (N-alkyl-p-phenylenediamino) group on the triazine ring. The preferred compositions are tri-substituted with the alkyl p-phenylenediamino group. The preferred compounds may be prepared by reacting N-alkylphenylenediamine with a cyanuric halide.Type: GrantFiled: September 21, 1988Date of Patent: November 20, 1990Assignee: Uniroyal Chemical Company, Inc.Inventors: Edward L. Wheeler, Franklin H. Barrows, Robert J. Franko
-
Patent number: 4968796Abstract: Disclosed is a process for the preparation of a sulphonylisothiourea of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, X, Y, and Z are as defined herein, which comprises reacting a sulphonic acid amide of the formulaR.sup.1 --SO.sub.2 --NH.sub.2, (II)or a metal salt thereof, with an N-heteroaryl-iminodithiocarbonic acid S,S-diester of the formula ##STR2## at a temperature between about 20.degree. C. and 200.degree. C. Intermediates and a process for their preparation are also disclosed.Type: GrantFiled: August 17, 1989Date of Patent: November 6, 1990Assignee: Bayer AktiengesellschaftInventor: Hans-Jochem Riebel
-
Patent number: 4963659Abstract: Reactive dyes which are particularly suitable for the dyeing or printing of cellulose-containing fiber materials by the exhaust process or by the continuous process and give, at a high color yield, dyeings and prints having good fastness properties, having the formula ##STR1## in which D.sub.1 and D.sub.2, independently of one another, are each a radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dye; R.sub.1, R.sub.2, B.sub.1 and B.sub.2, independently of one another, are hydrogen or alkyl having 1 to 4 carbon atoms, which is unsubstituted or substituted by halogen, hydroxyl, cyano, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato; X is fluorine, chlorine, bromine, sulfo, C.sub.1 -C.sub.Type: GrantFiled: March 14, 1989Date of Patent: October 16, 1990Assignee: Ciba-Geigy CorporationInventor: Athanassios Tzikas
-
Patent number: 4957921Abstract: Substituted cyclohexanols are described, as well as methods for the preparation and pharmaceutical composition of same, which are useful as central nervous system agents and are particularly useful as dopaminergic, antipsychotic, and antihypertensive agents as well as for treating hyperprolactinaemia-related conditions and central nervous system disorders.Type: GrantFiled: December 6, 1989Date of Patent: September 18, 1990Assignee: Warner-Lambert CompanyInventors: Bradley W. Caprathe, Juan C. Jaen, Sarah J. Smith, Lawrence D. Wise
-
Patent number: 4956005Abstract: Ortho-Sulfonamide benzenesulfonylureas, such as N-cyclopropyl-N'-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-1,2-benzened isulfonamide, are useful as pre-emergent and post-emergent herbicides.Type: GrantFiled: November 14, 1988Date of Patent: September 11, 1990Assignee: E. I. du Pont de Nemours and CompanyInventor: Donald J. Dumas
-
Patent number: 4954628Abstract: The invention relates to a process for preparing sulphonyl-ureas of the general formula (I) ##STR1## wherein Ar.sub.1 represents a phenyl, naphthyl or thienyl group, the derivatives thereof substituted by C.sub.1-4 alkyl, C.sub.1-4 haloalkyl, (halo)alkoxycarbonyl, (halo)alkyloxy, nitro, cyano groups as well as by halogen atoms,Ar.sub.2 represents a phenyl, pyridyl, pirimidinyl or triazinyl group and the derivatives thereof substituted by C.sub.1-4 (halo)alkyl, C.sub.1-4 (halo)alkyloxy, amino, O-acyl, O-arylsulphonyl, O-(substituted carbamoyl) groups as well as by halogen atoms.Type: GrantFiled: March 2, 1989Date of Patent: September 4, 1990Assignees: Nitrokaelepek, Magyar Tudomanyos Akademia Kozponti Kemiai Kutato IntezeteInventors: Gabor Besenyei, Sandor Nemeth, Laszlo Simandi, Maria Belak, Maria Szabo, Jozsef Dukai, Lajos Nagy, Elemer Tomordi, Csaba Soptei, Erzsebet E. Dioszegine
-
Patent number: 4948889Abstract: A compound selected from the group consisting of compounds of the formula (I) ##STR1## The compounds of the formula (I) are useful as light stabilizers, heat stabilizers, and oxidation stabilizers.Type: GrantFiled: March 14, 1988Date of Patent: August 14, 1990Assignee: Ciba-Geigy CorporationInventors: Giuseppe Cantatore, Franca Masina, Valerio Borzatta
-
Patent number: 4948419Abstract: This invention relates to certain novel pyridine sulfonamide compounds, to compositions containing such compounds, and to a method of use of such compositions to control the growth of undesired vegetation.Type: GrantFiled: February 15, 1989Date of Patent: August 14, 1990Assignee: E. I. du Pont de Nemours and CompanyInventors: Mary A. Hanagan, Barry A. Wexler
-
Patent number: 4946494Abstract: The invention relates to certain 6-amino-substituted 2-pyridinesulfonylureas, intermediates thereof, and compositions and methods of their use.Type: GrantFiled: September 15, 1988Date of Patent: August 7, 1990Assignee: E. I. Du Pont de Nemours and CompanyInventor: Eric D. Taylor
-
Patent number: 4946496Abstract: Certain diazole derivatives are useful as plant growth regulants and as herbicides.Type: GrantFiled: October 28, 1986Date of Patent: August 7, 1990Assignee: E. I. du Pont de Nemours and CompanyInventor: Anthony D. Wolf
-
Patent number: 4941909Abstract: The invention is concerned with novel compounds of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 have the significances given in the description, as well as enol ethers and salts thereof and their manufacture, weed control compositions which contain such compounds as active substances and the use of the active substances or compositions for the control of weeds. The invention is also concerned with certain starting materials which have herbicidal activity and with weed control compositions containing these.Type: GrantFiled: February 14, 1989Date of Patent: July 17, 1990Assignee: Hoffmann-La Roche Inc.Inventors: Jean Wenger, Paul Winternitz, Martin Zeller
-
Patent number: 4936903Abstract: N-Pyridinylsulfonyl-N'-pyrimidinylureas and N-pyridinylsulfonyl-N'-triazinylureas of the formula ##STR1## wherein E is nitrogen or the methine bridge,Z is oxygen or sulfur,R.sup.4 is hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.5 and R.sup.6 are each independently hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.3 -C.sub.6 dialkoxyalkyl, C.sub.1 -C.sub.4 haloalkylthio, C.sub.2 -C.sub.4 -alkoxyalkyl, C.sub.3 -C.sub.6 cycloalkyl or --NR.sup.12 R.sup.13,G is a ##STR2## R.sup.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, trifluoromethyl, trifluoromethoxy, difluoromethoxy, C.sub.1 -C.sub.4 alkyl carbonyl or --COOR.sup.14,R.sup.3 is a ##STR3## group, n is 0, 1 or 2,R.sup.8 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, C.sub.1 -C.sub.4 haloalkyl, nitro, --COOR.sup.14, C.sub.1 -C.sub.4 haloalkoxy, --O--CR.sup.15 R.sup.16 --COOR.sup.14 or --O--CR.sup.15 R.Type: GrantFiled: June 29, 1989Date of Patent: June 26, 1990Assignee: Ciba-Geigy Corp.Inventors: Rolf Schurter, Willy Meyer, Werner Fory
-
Patent number: 4932997Abstract: N-Heterocyclosulfonyl-N'-pyrimidinylureas and N-heterocyclosulfonyl-N'-triazinylureas of the formula ##STR1## wherein E is nitrogen or the methine bridge,Z is oxygen or sulfur,R.sup.4 is hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.5 and R.sup.6 are each independently hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.3 -C.sub.6 dialkoxyalkyl, C.sub.1 -C.sub.4 haloalkylthio, C.sub.2 -C.sub.4 -alkoxyalkyl, C.sub.3 -C.sub.6 cycloalkyl or --NR.sup.12 R.sup.13,G is a ##STR2## group R.sup.1 is hydrogen, halogen, nitro, C.sub.1 -alkyl, C.sub.1 -C.sub.4 alkoxy, trifluoromethyl, trifluoromethoxy, difluoromethoxy, C.sub.1 -C.sub.4 alkyl carbonyl or --COOR.sup.14,R.sup.2 is a ##STR3## group, R.sup.3 is a ##STR4## Q is oxygen, sulfur or --NR.sup.7 --,A is oxygen, sulfur, --SO--, --SO.sub.2 -- or --(CR.sup.10 R.sup.11).sub.m --,m and n are 0, 1 or 2,R.sup.7 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.Type: GrantFiled: April 3, 1985Date of Patent: June 12, 1990Assignee: Ciba-Geigy CorporationInventors: Rolf Schurter, Willy Meyer, Werner Fory
-
Patent number: 4933451Abstract: The present invention relates to novel bis-piperidyl-triazine compounds with 2 or more triazine rings, to their use as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers, and to the organic materials thus stabilized.Type: GrantFiled: May 22, 1989Date of Patent: June 12, 1990Assignee: Ciba-Geigy CorporationInventors: Giuseppe Cantatore, Valerio Borzatta, Franca Masina
-
Patent number: 4931438Abstract: This invention relates to derivatives of acrylic acid useful as fungicides, to processes for preparing them, to fungicidal compositions containing them, and to methods of using them to combat fungi, especially fungal infections in plants.Type: GrantFiled: June 22, 1989Date of Patent: June 5, 1990Assignee: Imperial Chemical Industries PLCInventors: John M. Clough, Christopher R. A. Godfrey
-
Patent number: 4927930Abstract: The present invention relates to novel piperidyl-triazine compounds with 2 or more triazine rings, to their use as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, and to the organic materials thus stabilized.Type: GrantFiled: May 24, 1989Date of Patent: May 22, 1990Assignee: Ciba-Geigy CorporationInventors: Giuseppe Cantatore, Valerio Borzatta, Franca Masina
-
Patent number: 4925928Abstract: Reactive dyes suitable in particular for dyeing or printing cellulose-containing fiber materials by the exhaust method or by continuous methods and, while giving a high dyeing yield, produce dyes and prints having good fastness properties; having the formula ##STR1## in which D is the radical or a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thiozanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dye, R, B.sub.1 and B.sub.2 are independently of each other hydrogen or alkyl which has 1 to 4 carbon atoms and which can be substituted by halogen, hydroxyl, cyano, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato, X and Y independently of each other are fluorine, chlorine, bromine, sulfo C.sub.1 -C.sub.4 alkylsulfonyl or phenylsulfonyl, A is an amino substituent which contains at least one group of the formula--SO.sub.2 --Z(2)z is .beta.Type: GrantFiled: June 23, 1988Date of Patent: May 15, 1990Assignee: Ciba-Geigy CorporationInventor: Athanassios Tzikas
-
Patent number: 4925927Abstract: Reactive dyes which are particularly suitable for dyeing or printing cellulose-containing fiber materials by the exhaust method or by continuous methods having the formula ##STR1## in which D and D' are each independently of the other a radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dye, R', R", B.sub.1 and B.sub.2 are independently of each other hydrogen or alkyl which has 1 to 4 carbon atoms and which is unsubstituted or substituted by halogen, hydroxyl, cyano, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato, X and Y are independently of each other fluorine, chlorine, bromine, sulfo, C.sub.1 -C.sub.4 -alkylsulfonyl or phenylsulfonyl, B is a direct bond or a radical --CH.sub.2).sub.n or --O--CH.sub.2).sub.n, n is 1 to 6; R is a radical of the formula ##STR2## Z is .Type: GrantFiled: June 27, 1988Date of Patent: May 15, 1990Assignee: Ciba-Geigy CorporationInventor: Athanassios Tzikas
-
Patent number: 4906737Abstract: Fibre-reactive dyes of the formula ##STR1## wherein X is an alkyl or alkoxy group of 1 to 4 carbon atoms, a carboxy group or a halogen atom, each of R.sub.1 and R.sub.2 is independently a hydrogen atom or an alkyl group of 1 to 4 carbon atoms and D is the radical of an organic dye which contains sulpho groups, and the benzene ring A can contain further substituents apart from X and SO.sub.3 H.Type: GrantFiled: August 17, 1988Date of Patent: March 6, 1990Assignee: Ciba-Geigy CorporationInventors: Herbert Seiler, Gert Hegar, Ester Hegar-Zimmerman