The Chalcogen, X, Is In A -c(=x)- Group Patents (Class 548/261)
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Patent number: 5319090Abstract: Hydrazide functionalized benzotrialzole and oxanilide ultraviolet absorbers (Formulas I and II) useful for stabilizing coreactive or inert polymeric compositions and novel intermediates (Formula III used to make certain types of compounds of Formula I) are disclosed and have the general formulas: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, X, Y, all substituents thereof, and n are set forth in the Summary of the Invention.Type: GrantFiled: May 18, 1993Date of Patent: June 7, 1994Assignee: Elf Atochem North America, Inc.Inventors: Ronald E. MacLeay, Terry N. Myers
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Patent number: 5302704Abstract: Dyes of formula ##STR1## wherein D is the radical of a diazo component of the benzene or naphthalene series or of the heterocyclic series, R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl and R.sub.2 is phenyl or substituted phenyl, give dyeings of good fastness properties on nitrogen-containing or hydroxyl group containing fibre materials.Type: GrantFiled: August 3, 1992Date of Patent: April 12, 1994Assignee: Ciba-Geigy CorporationInventors: Jean-Marie Adam, Thomas Eichenberger
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Patent number: 5300479Abstract: There are provided o-carboxy-(5-oxo-2-imidazolin-2-yl)benzoheterocyclic compounds wherein the fused heterocyclic ring system is a 5-membered ring containing one, two or three nitrogen atoms, derivatives of said benzoheterocyclic compounds and a method for the use therewith to control monocotyledenous and dicotyledenous plant species.Type: GrantFiled: April 27, 1992Date of Patent: April 5, 1994Assignee: American Cyanamid CompanyInventor: Robert F. Doehner, Jr.
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Patent number: 5298380Abstract: Compounds of formula ##STR1## wherein R.sub.1 is hydrogen, alkyl, phenylalkyl or cyclohexyl, R.sub.2 is alkyl, phenylalkyl, cyclohexyl, alkoxy or hydroxyalkoxy, and R.sub.3 is phenyl or substituted phenyl, are very suitable for use as UV absorbers in photographic materials with transparent substrates.Type: GrantFiled: September 1, 1992Date of Patent: March 29, 1994Assignee: Ciba-Geigy CorporationInventor: David G. Leppard
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Patent number: 5274015Abstract: A composition that, when present in a polymer matrix, reduces the deleterious effect of UV light absorption by the polymer is provided, which comprises a sulfur-containing derivative of hydroxyphenylbenzotriazole having the formula of: ##STR1## wherein each X is selected from the group consisting of hydrogen, halogens, cyano, alkyl, phenyl group, biphenyl group, arylthio, amine, ketone, aldehyde, alkoxy, hydroxy, carboxylic acid group, oligomer and combinations thereof and can have carbon atoms up to about 20; n is a whole number from 1 to 5; n' is a whole number from 0 to 4; n" is a whole number from 1 to 2 and each n" can be the same or different; q is an integer from 1 to 10; each Y is selected from the group consisting of --S(O)(O)--, --S(O)--, and --S--; each R can be selected from the group consisting of hydrogen, alkyl group, alkenyl group, aralkyl group, alkaryl group, and combinations thereof and can have 0 to about 10 carbon atoms; each OH group can be at either the 2'- or the 6'-position, or both.Type: GrantFiled: November 24, 1992Date of Patent: December 28, 1993Assignee: Phillips Petroleum CompanyInventors: Paul J. Deslauriers, Darryl R. Fahey, Paritosh K. Das
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Patent number: 5256661Abstract: Certain novel compounds having the structural formula ##STR1## where R.sub.2, R.sub.3 and R.sub.4 are each selected from the group consisting of H and OA; A is H or is selected from the group consisting of hydrocarbyl radicals, e.g. lower alkyl radicals, i.e. methyl, ethyl, propyl, etc., or ##STR2## wherein R.sub.5 is selected from the group consisting of hydrocarbyl radicals, e.g. alkyl and aromatic residues; n is 2 or 3; and R.sub.1 is selected from the group consisting of organic radicals having fused aromatic rings, that is, radicals comprising at least two rings that share a pair of carbon atoms or share a carbon and nitrogen atom are useful for inducing a dopaminergic response and reducing the intraocular pressure in a mammal.Type: GrantFiled: September 28, 1992Date of Patent: October 26, 1993Assignee: Whitby Research, Inc.Inventor: Alan S. Horn
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Patent number: 5235058Abstract: There is disclosed a 3(5)-hydrazinopyrazole compound represented by the following formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, a hydroxyl group, an alkoxy group, or an aryloxy group, R.sub.2 represents a hydrogen atom or an acyl group, X represents an aryloxy group, an alkoxy group, a heterocyclic oxy group, or an azolyl group, M represents a hydrogen ion or a metal ion, Y represents an acid radical, and n is 0 or a positive number.Type: GrantFiled: September 17, 1991Date of Patent: August 10, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadahisa Sato, Keizo Kumura
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Patent number: 5233047Abstract: Hydrazide functionalized benzotrialzole and oxanilide ultraviolet absorbers (Formulas I and II) useful for stabilizing coreactive or inert polymeric compositions and novel intermediates (Formula III used to make certain types of compounds of Formula I) are disclosed and have the general formulas: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, X, Y, all substituents thereof, and n are set forth in the Summary of the Invention.Type: GrantFiled: May 1, 1991Date of Patent: August 3, 1993Assignee: Elf Atochem North America, Inc.Inventors: Ronald E. MacLeay, Terry N. Myers
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Patent number: 5217983Abstract: (Indol-1'-ylmethyl)-, (Indazol-1'-ylmethyl)-, (Benzimidazol-1'-ylmethyl)-, and (Benzotriazol-1'-ylmethyl)- phenylacetaldehydes as Topical Antiinflammatories.Type: GrantFiled: March 27, 1992Date of Patent: June 8, 1993Assignee: Du Pont Merck Pharmaceutical CompanyInventor: Joseph J. Petraitis
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Patent number: 5206379Abstract: Acylmethoxycarbonylbenzotrizoles with an ester substituent are disclosed which are represented by formula (I): ##STR1## wherein R.sub.1 is an aliphatic oxy group having 1-10 carbons or an aliphatic amino group having 2-10 carbons; R.sub.2 is hydrogen or an aliphatic group having 1-5 carbons; and the group ##STR2## is bonded to a 5- or 6-position of the benzotriazole and which are useful in silver halide photographic sensitive materials, synthesis intermediates therefor, synthesis intermediates for medicines, rust inhibitors for metals and the like.Type: GrantFiled: August 29, 1991Date of Patent: April 27, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Masuji Motoki, Seiji Ichijima, Keiji Mihayashi
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Patent number: 5206378Abstract: Ultraviolet light stabilizers are chemically bound to anhydride containing polymers or copolymers. Polymeric stabilizers are prepared by the reaction of primary amino or hydrazido-substituted UV absorbers with some or all of the anhydride groups of the polymer or copolymer to form pendant stabilizer substituted imide or amic acid groups. The polymer bound stabilizers are not lost from the polymer system by volatilization, migration, or extraction, even at high temperature. The polymer stabilizers of this invention may be used as they are or as concentrates to stabilize other polymer systems.Type: GrantFiled: November 14, 1991Date of Patent: April 27, 1993Assignee: Elf Atochem North America, Inc.Inventors: Ronald E. MacLeay, Terry N. Myers
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Patent number: 5194623Abstract: Novel compounds derived from azlactones act as precursors for photographically active groups. The active groups are released at an appropriate time in the use of photographic and photothermographic systems.Type: GrantFiled: August 31, 1990Date of Patent: March 16, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Larry R. Krepski, Sharon M. Simpson
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Patent number: 5194456Abstract: The novel compound of the formula ##STR1## has been found to be useful as a UV absorber. A novel PMMA material has incorporated therein a UV absorbing amount of the novel UV absorber. Intraocular lenses and contact lenses are produced from PMMA having incorporated therein a UV absorbing amount of the novel UV absorber.Eyeglasses are produced having lenses of a polycarbonate material which has incorporated therein a UV absorbing amount of the novel UV absorbed.Type: GrantFiled: May 22, 1990Date of Patent: March 16, 1993Assignee: Ioptex Research, Inc.Inventor: Amitava Gupta
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Patent number: 5190574Abstract: A herbicidal compound of formula (I): ##STR1## in which the dotted line indicates the presence of two double bonds arranged so as to form a fused hetero-aromatic ring system;Py is an optionally substituted pyrazole ring;W is O or NR.sup.1 ; where R.sup.1 is hydrogen or lower alkyl;X is (CH.sub.2).sub.n, CH.dbd.CH, CH(OR.sup.5)CH.sub.2, COCH.sub.2 ;where n is 0, 1 or 2;R.sup.2 and R.sup.3 are independently selected from H, optionally substituted alkyl, alkenyl or alkynyl, halogen, NR.sup.6 R.sup.7, or R.sup.2 and R.sup.3 together with the carbon to which they are attached form an optionally substituted alkenyl or cycloalkyl group;R.sup.4 is CO.sub.2 R.sup.8, CN, COR.sup.8, CH.sub.2 OR.sup.8, CH(OH)R.sup.8, CH(OR.sup.8)R.sup.9, CSNH.sub.2, COSR.sup.8, CSOR.sup.8, CONHSO.sub.2 R.sup.8, CONR.sup.10 R.sup.11, CONHNR.sup.10 R.sup.11, CONHN.sup.+ R.sup.10 R.sup.11 R.sup.12 R.sup.14-, CO.sub.2.sup.- R.sup.15+ or COON.dbd.CR.sup.10 R.sup.11 ;R.sup.15+ is an agriculturally acceptable cation and R.sup.Type: GrantFiled: February 7, 1991Date of Patent: March 2, 1993Assignee: Imperial Chemical Industries plcInventors: David P. J. Pearson, John E. D. Barton, Christopher J. Mathews, David Cartwright, Susan P. Barnett
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Patent number: 5179112Abstract: The invention concerns novel, pharmaceutically useful, amide derivatives of certain benzoheterocyclylalkanoic acids (and related tetrazoles and acylsulphonamides) of the formula I and salts thereof, wherein the radicals R.sup.1, R.sup.2, L, X, Y, Z, A.sup.1, Q, A.sup.2 and M have the meanings set out in the specification. The invention also includes pharmaceutical compositions incorporating a formula I compound or a salt thereof, a process for the manufacture of the said compound, together with intermediates for use in the latter process.Type: GrantFiled: June 6, 1991Date of Patent: January 12, 1993Assignee: ICI Americas Inc.Inventors: Peter R. Bernstein, Frederick J. Brown, Victor G. Matassa, Ying K. Yee
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Patent number: 5162405Abstract: The present invention comprises novel single-functional and mixtures of multi-functional oligomeric performance additive compounds having one or more components of Structure A R1 ? ? ##STR1## (The definitions of R, Z1, Z2, Z3, A1, A2, A3 and y are given in the Summary Section), their uses and polymeric compounds and compositions containing them which have enhanced oxidative stabilities, enhanced ultraviolet (UV) and light stabilites and/or enhanced flame retardance. An example is the bis sulfonic acid bispotassium salt reaction product from an oligomeric caprolactone diol (TONE.RTM. 260), 2-sulfobenzoic acid anhydride and potassium carbonate, and use of this product, at levels up to about 3.0%, in a general purpose bisphenol A polycarbonate resin, to enhance the fire resistance or flame retardance of the polycarbonate resin.Type: GrantFiled: March 22, 1991Date of Patent: November 10, 1992Assignee: ELF Atochem North America, Inc.Inventors: Ronald E. MacLeay, Jose Sanchez, Daryl L. Stein
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Patent number: 5157046Abstract: A method for treating skin disorders in warm-blooded animals, said method comprising administering to said warm-blooded animals an effective amount of an appropriately substituted benzimidazole or benzotriazole which suppresses the metabolism of retinoids. Compositions comprising said compounds and an effective amount of a retinoid.Type: GrantFiled: November 13, 1989Date of Patent: October 20, 1992Assignee: Janssen Pharmaceutica N.V.Inventors: Jean P. F. Van Wauwe, Alfons H. M. Raeymaekers
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Patent number: 5134240Abstract: Novel 4-substituted-4,8-dimethyl-2,3-dioxabicyclo[3.3.1] nonan-7-ones which have a pronounced activity against the causative organism of malaria and can be used for the prevention and control of malaria.Type: GrantFiled: September 10, 1990Date of Patent: July 28, 1992Assignee: Hoffmann-LaRoche, Inc.Inventors: Werner Hofheinz, Gerard Schmid, Harro Stohler
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Patent number: 5132429Type: GrantFiled: November 20, 1990Date of Patent: July 21, 1992Assignee: Shionogi & Co., Ltd.Inventors: Shigeru Narita, Takayasu Kitagawa
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Patent number: 5110585Abstract: The invention relates primarily to quaternized polycyclic compounds having the formula ##STR1## wherein m is an integer having a value of from 1 to 4; R is alkylene having from 3 to 8 carbon atoms and is optionally substituted with C.sub.1 to C.sub.4 alkyl; R.sub.2 together with the quaternary nitrogen, forms a 5 to 14 membered heterocyclic ring, said ring containing at least 2 hetero atoms selected from the group of nitrogen, sulfur and oxygen; R.sub.1 forms a double bond in the heterocyclic ring of the quaternized nitrogen or is alkyl, alkyleneoxyalkyl, alkylhydroxy, aryl, aralkyl, aralkenyl, alkaryl, alkylamidoalkyl and X.sup.- is an anion. The invention also relates to the preparation and use of said quaternized polycyclic compounds.Type: GrantFiled: March 1, 1989Date of Patent: May 5, 1992Assignee: ISP Investments Inc.Inventors: Ratan K. Chaudhuri, David J. Tracy, Robert B. Login, Michael W. Helioff
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Patent number: 5108485Abstract: There are provided o-carboxy-(5-oxo-2-imidazolin-2-yl)benzoheterocyclic compounds wherein the fused heterocyclic ring system is a 5-membered ring containing one, two or three nitrogen atoms, derivatives of said benzoheterocyclic compounds and a method for the use therewith to control monocotyledonous and dicotyledonous plant species.Type: GrantFiled: August 31, 1990Date of Patent: April 28, 1992Assignee: American Cyanamid CompanyInventor: Robert F. Doehner, Jr.
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Patent number: 5104992Abstract: A method of preparing 2-phenylbenzotriazoles expressed by Formula I: ##STR1## (wherein R.sub.1 denotes a hydrogen or chlorine atom, a lower alkyl group having 1 to 4 carbon atoms, a lower alkoxyl group having 1 to 4 carbon atoms, a carboxyl group or a sulfonic acid group; R.sub.2 denotes a hydrogen or chlorine atom, a lower alkyl group having 1 to 4 carbon atoms or a lower alkoxyl group having 1 to 4 carbon atoms; R.sub.3 denotes a hydrogen or chlorine atom, an alkyl group having 1 to 12 carbon atoms, a lower alkoxy group having 1 to 4 carbon atoms, a phenyl group, a phenyl group substituted by an alkyl group having 1 to 8 carbon atoms, a phenoxy group or a phenylalkyl group with an alkyl part having 1 to 4 carbon atoms; R.sub.4 denotes a hydrogen or chlorine atom, a hydroxyl group or an alkoxyl group having 1 to 4 carbon atoms; and R.sub.Type: GrantFiled: April 2, 1990Date of Patent: April 14, 1992Assignee: Chemipro Kasei Kaisha, Ltd.Inventors: Naohiko Fukuoka, Kazunobu Kubota, Kunitoshi Iguchi
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Patent number: 5097041Abstract: There is disclosed a process in which a melt of a 2-aryl-2H-benzotriazole containing colored contaminants, or a solution thereof in an organic nonpolar solvent, is purified by treatment with a strongly acidic synthetic cationic exchange resin.Type: GrantFiled: October 11, 1990Date of Patent: March 17, 1992Assignee: Ciba-Geigy CorporationInventors: Ariane Higel, Sebastian Staubli, Daniel Thibaut, Hans Horisberger
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Patent number: 5071995Abstract: Provided are 2-hydroxyphenylbenzotriazol compounds with excellent ultraviolet absorbability and high thermal stability. They can be used as ultraviolet absorber for any polymer.Type: GrantFiled: September 29, 1989Date of Patent: December 10, 1991Assignee: Kuraray Co., Ltd.Inventors: Tsugunori Kashimura, Tsutomu Miura, Keiji Matsumura
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Patent number: 5066656Abstract: (6,7-dihydro-5H-pyrrolo[1,2-c]imidazolyl-5-yl)- and (5,6,7,8-tetrahydroimidazo[1,5-a]pyridinyl-5-yl) substituted 1H-benzotriazole derivatives, compositions containing the same and methods of treating estrogen dependent disorders.Type: GrantFiled: September 10, 1990Date of Patent: November 19, 1991Assignee: Janssen Pharmaceutica N.V.Inventors: Michael N. Greco, Marcel A. C. Janssen
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Patent number: 5055587Abstract: A process for preparing a 1H-pyrazolo[5,1-C]-1,2,4-triazole compound represented by the following general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or a substituent group, R.sup.2 represents an alkyl group, an aryl group or a heterocyclic ring group, and X represents a hydrogen atom or a substituent group,which process comprises reacting either an imidic acid ester represented by the following general formula (II): ##STR2## wherein R.sup.2 is as defined above, R.sup.3 represents an alkyl group, and Y represents an acid radical, or an orthoester represented by the following general formula (III):R.sup.2 --C(OR.sup.3).sub.3 (III)wherein R.sup.2 and R.sup.3 are as defined above, with a 5-hydroazino-1H-pyrazole compound represented by the following general formula (IV): ##STR3## wherein R.sup.1 and X are as defined above, Y' represents an acid radical, and n represents O or a positive integer necessary to neutralize the intramolecular electric charge.Type: GrantFiled: March 15, 1989Date of Patent: October 8, 1991Assignee: Fuji Photo Film Co., Ltd.Inventor: Yuki Mizukawa
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Patent number: 5032498Abstract: The novel UV-absorbers are compounds of the formula ##STR1## in which R.sup.1 is, for example, hydrogen, n is one of the numbers 1 or 2 and R.sup.2 is an appropriate monovalent or divalent radical, for example --OH or --O-CH.sub.2 CH.sub.2 --O--. The UV-absorbers are used in particular for stabilising and improving lacquers and photographic material.Type: GrantFiled: August 21, 1990Date of Patent: July 16, 1991Assignee: Ciba-Geigy CorporationInventors: Jean Rody, Mario Slongo
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Patent number: 5030731Abstract: Blocked benzotriazoles of the formula I or II ##STR1## wherein x is 1 or 2, R.sup.1 in the case of x=1 and in the formula II is an acyl group of the formula --CO--R.sup.5, a sulfonyl group of the formula --SO.sub.2 --R.sup.6, a phosphoryl group of the formula --P(O).sub.r (R.sup.14)(R.sup.15), and in the case of x=2 is --CO-- or a diacyl group of the formula --CO--CO-- or --CO--R.sup.7 --CO--, and R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.14 and R.sup.15 have the meanings defined in claim 1, are crypto light stabilizers which can be activated by short-wave irradiation. Their use in coating materials is of interest in cases in which light stabilizers containing the free OH compounds have disadvantages with regard to their application.Type: GrantFiled: October 24, 1989Date of Patent: July 9, 1991Assignee: Ciba-Geigy CorporationInventors: Mario Slongo, Manfred Rembold
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Patent number: 4999433Abstract: Hologenated 2-(2-hydroxyphenyl)-2H-benzotriazoles of the formula ##STR1## in which X is halogen, R.sub.1 is hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.6 cycloalkyl, phenyl or phenyl-C.sub.1 -C.sub.4 alkyl and R.sub.2 is C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.6 cycloalkyl, phenyl, phenyl-C.sub.1 -C.sub.4 alkyl or a group --C.sub.n H.sub.2n --COOR.sub.3, in which n is 0 to 4 and R.sub.3 is hydrogen or C.sub.1 -C.sub.12 alkyl, can be prepared particularly advantageously by catalytic hydrogenation of a corresponding o-nitroazo compound in the presence of a hydrogenation catalyst consisting of 0.1 to 3% of Pt on a support and of an organic amine.Type: GrantFiled: September 26, 1989Date of Patent: March 12, 1991Assignee: Ciba-Geigy CorporationInventors: Helmut Prestel, Klaus Muller
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Patent number: 4996326Abstract: Benzotriazoles of the formula I ##STR1## in which R.sup.1 and R.sup.2 are located in the ortho-position or para-position relative to the OH group and at least one of these substituents in an .alpha.-branched alkyl group containing a polar group M in the .omega.-position are liquid or low-melting compounds which absorb UV light and can be used as stabilizers for organic materials. M can be, for example, an ester or amide group. R.sup.3 can be H, Cl, alkyl, alkoxy or a carboxyl group.Type: GrantFiled: January 12, 1990Date of Patent: February 26, 1991Assignee: Ciba-Geigy CorporationInventors: David G. Leppard, Mario Slongo, Jean Rody
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Patent number: 4994197Abstract: Triazole compounds are grafted onto alkyl or alkenyl succinimides by using diisocyanates to effect the coupling. The process is carried out by first reacting a 1,2,3 -triazole with a diisocyanate to produce a triazole substituted urea addition product containing a single unreacted isocyanato group. This intermediate reaction product is then reacted with an alkyl or alkenyl succinimide ashless dispersant prepared from an alkyl or alkenyl succinic acid or anhydride and a polyamine by known methods. The novel composition so produced comprises a multifunctional hydrocarbon fuel or lubricant additive.Type: GrantFiled: December 18, 1989Date of Patent: February 19, 1991Assignee: Mobil Oil CorporationInventors: David A. Blain, Angeline B. Cardis
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Patent number: 4981492Abstract: Disclosed is an additive for lubricant or fuel compositions comprising the boronated reaction product of polyalkenyl-substituted succinimides, aldehydes and triazoles.Type: GrantFiled: December 13, 1989Date of Patent: January 1, 1991Assignee: Mobil Oil CorporationInventors: David A. Blain, Angeline B. Cardis, Ronald J. Poole
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Patent number: 4978787Abstract: A compound of the formula: ##STR1## wherein R is a C.sub.1 -C.sub.5 alkyl group, a C.sub.3 -C.sub.5 alkenyl group, a C.sub.3 -C.sub.5 alkynyl group or a C.sub.3 -C.sub.7 cycloalkyl group, which is useful as a herbicide.Type: GrantFiled: September 11, 1989Date of Patent: December 18, 1990Assignee: Sumitomo Chemical Company, LimitedInventors: Toru Haga, Eiki Nagano, Ryo Sato, Kouichi Morita
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Patent number: 4977155Abstract: Heterocyclic dihydroxyquinoxaline compounds having the formula ##STR1## wherein R.sup.2 is hydrogen, NO.sub.2, NH.sub.2, CN, halogen, or SO.sub.2 NH.sub.2 ; --X--Y--Z-- is selected from --N.dbd.N--N.sup.3 --,--NR.sup.3 --N.dbd.N--,.dbd.N--NR.sup.3 --N.dbd., wherein R.sup.3 is hydrogen, lower alkyl, or CF.sub.3.The invention also relates to a method of preparing the compounds, pharmaceutical compositions thereof, and their use.The compounds are useful in the treatment of indications caused by hyperactivity of the excitatory neurotransmitters.Type: GrantFiled: June 22, 1989Date of Patent: December 11, 1990Assignee: A/S FerrosanInventors: Poul Jacobsen, Flemming E. Nielsen, Tage Honore, Jorgen Drejer
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Patent number: 4973702Abstract: The novel UV-absorbers are compounds of the formula I ##STR1## in which R.sup.1 is, for example, hydrogen, n is one of the numbers 1 or 2 and R.sup.2 is an appropriate monovalent or divalent radical, for example --OH or --O--CH.sub.2 CH.sub.2 --O--. The UV-absorbers are used in particular for stabilising and improving lacquers and photographic material.Type: GrantFiled: February 13, 1989Date of Patent: November 27, 1990Assignee: Ciba-Geigy CorporationInventors: Jean Rody, Mario Slongo
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Patent number: 4950678Abstract: Novel substituted N-(heterocyclic-substituted phenyl)-N'-benzoyl-ureas, processed for producing these compounds, intermediates therefor, compositions thereof and the use of the compounds for the control of pests.Type: GrantFiled: July 27, 1989Date of Patent: August 21, 1990Assignee: Sandoz Ltd.Inventors: Robert L. Carney, John M. Gruber, Alfred S. T. Lui
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Patent number: 4943574Abstract: (1H-azol-1-ylmethyl)substituted benzotriazole derivatives, compositions containing the same, and methods of treating estrogen dependent disorders.Type: GrantFiled: September 28, 1989Date of Patent: July 24, 1990Assignee: Janssen Pharmaceutica N.V.Inventors: Alfons H. M. Raeymaekers, Eddy J. E. Freyne, Josephu L. H. Van Gelder, Marc G. Venet
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Patent number: 4942248Abstract: Tertiary-butyl and tertiary-amyl esters of 1H-benzotriazole-1-carboxylic acids are useful blocking agents for blocking the amino or imino groups of amino acids. The six-membered ring of the blocking agent may be unsubstituted or substituted with one or more minor substituents.Type: GrantFiled: December 1, 1988Date of Patent: July 17, 1990Assignee: PPG Industries, Inc.Inventor: Paul M. Novy
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Patent number: 4940812Abstract: Process for the introduction of functional or functionalizable substituents para to the amino group in 2-aminophenols and 3-aminophenols. The process proceeds in one step, with substitution occurring selectively at the position para to the amino group. Consequently, the reaction is surprisingly straightforward, with very little or no contamination by isomeric by-products. The process comprises reaction of (a) an aminophenol having an open para position to the amino function, with (b) an unhindered non-enolizble aldehyde, and (c) a thiol or sulfinic acid which acts as a nucleophile. In preferred embodiments, the process is conducted at a temperature of from about 50.degree. C. to about 100.degree. C., and in the presence of a polar solvent. The reaction is promoted by an acid having sufficient acidity to protonate the amino group of the aminophenol. Preferably, the acid promoter is a mineral acid, and it is present in an amount at least substantially equivalent to the amount of aminophenol reactant.Type: GrantFiled: July 17, 1989Date of Patent: July 10, 1990Assignee: Eastman Kodak CompanyInventors: Philip T. S. Lau, Danny R. Thompson
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Patent number: 4904800Abstract: A compound of the formula: ##STR1## wherein R is a C.sub.1 -C.sub.5 alkyl group, a C.sub.3 -C.sub.5 alkenyl group, a C.sub.3 -C.sub.5 alkynyl group or a C.sub.3 -C.sub.7 cycloalkyl group, which is useful as a herbicide.Type: GrantFiled: April 14, 1988Date of Patent: February 27, 1990Assignee: Sumitomo Chemical Company LimitedInventors: Toru Haga, Eiki Nagano, Ryo Sato, Kouichi Morita
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Patent number: 4898944Abstract: Precursors for the preparation of fiber-reactive triphendioxazine dyestuffs correspond to the general formulas: ##STR1## in which Y' is a vinyl, a beta-hydroxyethyl or an ethyl group which contains in the beta-position a substituent which can be eliminated by an alkali;T is an optionally substituted alkyl (e.g.Type: GrantFiled: October 27, 1988Date of Patent: February 6, 1990Assignee: Hoechst AktiengesellschaftInventors: Gunther Schwaiger, Hartmut Springer, Walter Helmling
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Patent number: 4895954Abstract: Water-soluble triphendioxazine compounds which have fiber-reactive properties as dyestuffs, which afford deep and fast dyeings on fiber materials, such as wool and, in particular, cellulose, and which correspond to the formula (1) ##STR1## in which: n is the number 0 or 1;Y is the vinyl group or an ethyl group containing, in .beta.-position, a substituent which can be eliminated by means of an alkali;Q.sup.1 and Q.sup.2 both represent a benzotriazole radical which can also be additionally substituted in the benzene nucleus by alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, halogen, carboxy or sulfo;B is --O--, --S--, --NH-- or --N(R')-- wherein R' is optionally substituted alkyl having 1 to 6 carbon atoms;W.sup.1 and W.sup.2 both represent a divalent, optionally substituted aliphatic, cycloaliphatic, aliphatic-cycloaliphatic, araliphatic or aromatic-carbocyclic radical, it being possible for the aliphatic radicals to be interrupted by hetero groups --O--, --S--, --SO.sub.Type: GrantFiled: October 28, 1988Date of Patent: January 23, 1990Assignee: Hoechst AktiengesellschaftInventors: Gunther Schwaiger, Hartmut Springer, Walter Helmling
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Patent number: 4874803Abstract: The present invention comprises reaction products resulting from the reaction of hydrazido-substituted or certain amino-substituted polymer stabilizers and cyclic dianhydrides, as well as the use of such products. The polymer stabilizers of the invention are useful for protecting a large variety of synthetic polymeric organic materials from the degradative effects of heat, light and oxygen. Some of the modifiers are flame retardants and many are metal deactivators in addition to their primary activity.Type: GrantFiled: September 21, 1987Date of Patent: October 17, 1989Assignee: Pennwalt CorporationInventors: Arthur L. Baron, Terry N. Myers, Jerome Wicher
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Patent number: 4863802Abstract: Novel coating compositions contain a radiation polymerizable acrylic monomer or oligomer and an ultraviolight-light absorbing effective amount of a UV-absorbing multimeric benzotriazole compound.Type: GrantFiled: December 31, 1987Date of Patent: September 5, 1989Assignee: General Electric CompanyInventors: James E. Moore, Arnold Factor, Peter M. Miranda
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Patent number: 4859725Abstract: A compound of formula I ##STR1## in which R to R.sub.5 are organic radicals, for use as a light stabilizer in polymeric systems.Type: GrantFiled: August 23, 1988Date of Patent: August 22, 1989Assignee: Sandoz Ltd.Inventor: Lajos Avar
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Patent number: 4859692Abstract: The invention concerns novel, pharmaceutically useful, amide derivatives of certain benzoheterocyclylalkanoic acids (and related tetrazoles and acylsulphonamides) of the formula I and salts thereof, wherein the radicals R.sup.1, R.sup.2, L, X, Y, Z, A.sup.1, Q, A.sup.2 and M have the meanings set out in the specification. The invention also includes pharmaceutical compositions incorporating a formula I compound or a salt thereof, a process for the manufacture of the said compound, together with intermediates for use in the latter process.Type: GrantFiled: April 16, 1986Date of Patent: August 22, 1989Assignee: ICI Americas Inc.Inventors: Peter R. Bernstein, Frederick J. Brown, Victor G. Matassa, Ying Kwong Yee
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Patent number: 4853471Abstract: The novel UV-absorbers are compounds of the formula ##STR1## in which R.sup.1 is, for example, hydrogen, n is one of the numbers 1 or 2 and R.sup.2 is an appropriate monovalent or divalent radical, for example --OH or --O--CH.sub.2 CH.sub.2 --O--. The UV-absorbers are used in particular for stabilising and improving lacquers and photographic material.Type: GrantFiled: November 12, 1987Date of Patent: August 1, 1989Assignee: Ciba-Geigy CorporationInventors: Jean Rody, Mario Slongo
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Patent number: 4851542Abstract: N.sub.1 -substituted 1H-benzotriazole hydroxyethyl sulfone compounds, a process for their preparation and their use for the preparation of dyestuffs. Compounds of the general formula ##STR1## in which R is hydrogen or alkyl which has 1 to 6 carbon atoms and can be substituted by hydroxy, sulfo, carboxy, phosphono and/or cyano, W denotes a divalent, optionally substituted aliphatic radical, (C.sub.5 -C.sub.10)-cycloaliphatic radical which is optionally substituted by alkyl, aliphatic-(C.sub.5 -C.sub.8)-cycloaliphatic radical which is optionally substituted by alkyl, optionally substituted araliphatic radical or optionally substituted aromatic carbocyclic radical, it being possible for the aliphatic radicals in W to be interrupted by hetero groups of the formulae --O--, --S--, --SO.sub.Type: GrantFiled: July 23, 1987Date of Patent: July 25, 1989Assignee: Hoechst AktiengesellschaftInventors: Gunther Schwaiger, Hartmut Springer
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Patent number: 4835167Abstract: The present invention provides new tricyclic benzotriazoles of the general formula: ##STR1## wherein Z is a hydrogen atom or an acyl radical, Y is an oxygen or sulphur atom or two hydrogen atoms and X is an oxygen or sulphur atom or a >CR.sub.1 R.sub.2 or >NR.sub.3 group, R.sub.1 is a hydrogen atom or an alkyl, alkenyl or cycloalkyl radical, R.sub.2 is a hydrogen atom or an alkyl, alkenyl or cyano group or a carbonyl group substituted by a hydroxyl, alkyl, alkoxy, amino, alkylamino, dialkylamino or hydrazino group or R.sub.2, together with R.sub.1, represents a cycloalkylene radical or R.sub.1 and R.sub.2 together form an alkylidene or cycloalkylidene radical and R.sub.3 is a hydrogen atom or an alkyl radical; the tautomers thereof and the physiologically acceptable acid-addition salts thereof with inorganic and organic acids.Type: GrantFiled: August 3, 1987Date of Patent: May 30, 1989Assignee: Boehringer Mannheim GmbHInventors: Wolfgang Von Der Saal, Walter-Gunar Friebe, Alfred Mertens, Bernd Muller-Beckmann, Gisbert Sponer
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Patent number: 4835284Abstract: This invention relates to a method for preparing 2-phenylbenzotriazoles having the formula I, ##STR1##Type: GrantFiled: January 27, 1988Date of Patent: May 30, 1989Assignee: Chemipro Kasei Kaisha, Ltd.Inventor: Shuichi Seino