Bicyclo Ring System Having The Hetero Ring As One Of The Cyclos Patents (Class 549/434)
  • Patent number: 4609397
    Abstract: Pyrazole sulfonylureas are useful as pre- and post-emergence herbicides. Typical of this group is 3-[[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]aminosulfonylmethyl]-1,5-di methyl-1H-pyrazole-4-carboxylic acid, ethyl ester.
    Type: Grant
    Filed: December 11, 1984
    Date of Patent: September 2, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Barry A. Wexler
  • Patent number: 4609756
    Abstract: In the preparation of a cinnamic acid by reacting the corresponding benzaldehyde with ketene in the presence of a catalyst, the improvement which comprises using as the catalyst an iron and/or zinc salt of a mono- or di-carboxylic acid with 2 to 20 carbon atoms containing free carboxylic acid and/or anhydride, and then splitting the reaction product in the temperature range from 100.degree. to 250.degree. C. with an acid or basic catalyst.
    Type: Grant
    Filed: October 4, 1985
    Date of Patent: September 2, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Alfons Dorlars, Heinz U. Blank, Herbert Nordt, deceased, Viktor Trescher
  • Patent number: 4600787
    Abstract: Aromatic compounds which contain perfluorinated side-chains bonded via a heteroatom are prepared by treating aromatic compounds, which contain side-chains which are perhalogenated, but only partially fluorinated, and bonded via heteroatom, with a catalyst capable of transferring halogen atoms.
    Type: Grant
    Filed: April 23, 1984
    Date of Patent: July 15, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Albrecht Marhold, Erich Klauke
  • Patent number: 4569928
    Abstract: Novel esters in all possible isomeric forms and mixtures thereof of the formula ##STR1## wherein R is selected from the group consisting of (a) optionally unsaturated alkyl of 1 to 18 carbon atoms and optionally unsaturated cycloalkyl or cycloalkylalkyl of 3 to 8 carbon atoms optionally substituted with at least one member of the group consisting of halogen, --OH, --SH, --OR', --SR', --NO.sub.2, ##STR2## --SO.sub.2 AlK.sub.2, --SO.sub.3 AlK.sub.3, aryl optionally substituted with at least one member of the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --CF.sub.3, --OCF.sub.3, --SCF.sub.3 and ##STR3## R' is alkyl of 1 to 8 carbon atoms, R" and R'" are individually selected from the group consisting of hydrogen and alkyl of 1 to 8 carbon atoms, AlK.sub.1, AlK.sub.2 and AlK.sub.
    Type: Grant
    Filed: October 28, 1983
    Date of Patent: February 11, 1986
    Assignee: Roussel Uclaf
    Inventors: Jean Tessier, Andre Teche, Jean-Pierre Demoute
  • Patent number: 4567280
    Abstract: In a process for producing an iodo-aromatic compound which comprises iodinating an aromatic compound having an electron-donating substituent bonded to the benzene ring with iodine in the presence of a solvent, the improvement wherein about 1/2 to about 10 moles, per mole of iodine added to the reaction system, of nitrogen dioxide (NO.sub.2) is added in the form of NO.sub.2 to the reaction system, and the reaction is carried out in the presence of nitrogen dioxide.
    Type: Grant
    Filed: September 4, 1984
    Date of Patent: January 28, 1986
    Assignee: UBE Industries, Ltd.
    Inventors: Hiroshi Itatani, Mikito Kashima, Yasutaka Tasaki
  • Patent number: 4529729
    Abstract: Piperazine and homopiperazine compounds of the formula: ##STR1## in which: A is a hydrocarbon radical from C.sub.3 to C.sub.5, in a straight or branched chain, which may contain one or two double bonds, and optionally substituted by one or more OH;B is CH or a nitrogen atom;m is 2 or 3;X--Y-- represents --CH.dbd.CH--(CR'R").sub.n - in which n is zero or 1, and R' and R" are hydrogen or methyl;Z is oxygen or sulfur,R is hydrogen, alkyl from C.sub.1 to C.sub.5, cycloalkyl from C.sub.3 to C.sub.7, or phenyl optionally substituted by fluorine, chlorine or alkyl from C.sub.1 to C.sub.5, andT is hydrogen, fluorine, chlorine or alkyl from C.sub.1 to C.sub.5.These compounds and physiologically tolerable acid addition salts thereof may be used as medicines especially in the treatment of all kinds of tissular hypoxia.
    Type: Grant
    Filed: June 20, 1984
    Date of Patent: July 16, 1985
    Assignee: Adir
    Inventors: Gilbert Regnier, Michel Laubie, Jacques Duhault
  • Patent number: 4504483
    Abstract: Fluorine substituted pyridine methyl esters having the formula ##STR1## wherein R represents ##STR2## in which X is chlorine or difluoromethoxy; Y is chlorine or tert-butyl; and Z is a halogen atom, are novel compounds which are useful as insecticides and acaricides.
    Type: Grant
    Filed: August 17, 1982
    Date of Patent: March 12, 1985
    Assignee: Nissan Chemical Industries Ltd.
    Inventors: Kiyomi Ozawa, Masataka Hatanaka, Masayoshi Hirose, Masaki Kudo
  • Patent number: 4438275
    Abstract: Benzyl esters of the formula ##STR1## in which n is 1,2,3,4, or 5,R.sup.2 is hydrogen, C.sub.1-4 -alkyl, cyano or ethynyl,R.sup.3 is radical of a carboxylic acid customary in pyrethroids or pyrethroid-like compounds, andat least one R.sup.1 is fluoroalkoxy or fluoroalkylmercapto, or two together are fluoromethylene- or fluoroethylene-dioxy, and the others, if present, are hydrogen or various radicals,which possess arthropodicidal properties. Various alcohols, amines, aldehydes, halides, and the like, corresponding to the alcohol moieties of the esters are also synthesized.
    Type: Grant
    Filed: July 30, 1981
    Date of Patent: March 20, 1984
    Assignee: Bayer Aktiengesellschaft
    Inventors: Reinhard Lantzsch, Albrecht Marhold, Wolfgang Behrenz, Ingeborg Hammann
  • Patent number: 4427666
    Abstract: 3,5-Dihalogeno-1,2-methylenedioxybenzenes of the formula ##STR1## in which R is hydrogen, halogen, cyano or an optionally substituted alkyl, alkenyl, alkynyl, aralkyl or acyl radical, andX and Y each independently is halogen,which synergize with known arthropodicides.
    Type: Grant
    Filed: June 15, 1982
    Date of Patent: January 24, 1984
    Assignee: Bayer Aktiengesellschaft
    Inventors: Volker Mues, Wolfgang Behrenz
  • Patent number: 4405357
    Abstract: Novel 3-isoxazolidinone compounds and novel hydroxamic acid intermediates from which they are prepared exhibit herbicidal activity to grassy and broad-leaf plant species while leaving legumes, especially soybeans, unaffected. The preparation and herbicidal activity of the compounds is exemplified.
    Type: Grant
    Filed: May 11, 1981
    Date of Patent: September 20, 1983
    Assignee: FMC Corporation
    Inventor: Jun H. Chang
  • Patent number: 4401676
    Abstract: Novel .alpha.-ethynyl- and .alpha.-vinyl 3,4-disubstituted phenylalanines are disclosed. The compounds have pharmaceutical activity.
    Type: Grant
    Filed: June 1, 1977
    Date of Patent: August 30, 1983
    Assignee: Merck & Co., Inc.
    Inventors: Arthur A. Patchett, David Taub
  • Patent number: 4357344
    Abstract: Certain polybutylbenzylphenols and benzyl-3,4-methylenedioxybenzenes are useful for insect control especially as insect chemosterilants and oviposition inhibitors. The benzyl-3,4-methylenedioxybenzenes also find utility as growth inhibitors for mosquito larvae.
    Type: Grant
    Filed: March 29, 1979
    Date of Patent: November 2, 1982
    Assignee: The United States of America as represented by the Secretary of Agriculture
    Inventor: Leonard Jurd
  • Patent number: 4342777
    Abstract: Certain polybutylbenzylphenols and benzyl-3,4-methylenedioxybenzenes are useful for insect control especially as insect chemosterilants and oviposition inhibitors. The benzyl-3,4-methylenedioxybenzenes also find utility as growth inhibitors for mosquito larvae.
    Type: Grant
    Filed: November 5, 1981
    Date of Patent: August 3, 1982
    Assignee: The United States of America as represented by the Secretary of Agriculture
    Inventor: Leonard Jurd
  • Patent number: 4329342
    Abstract: Novel 1-(1,3-dioxolan-2-ylmethyl)-1H-imidazoles and 1H-1,2,4-triazoles wherein the 1,3-dioxolane ring is substituted in the 4- and in the 5-positions, said compounds having useful antimicrobial properties.
    Type: Grant
    Filed: November 3, 1980
    Date of Patent: May 11, 1982
    Assignee: Janssen Pharmaceutica, N.V.
    Inventors: Jan Heeres, Leo Backx, Willy Van Laerhoven, Elmar Sturm