Cyclic Alcohol Moiety Patents (Class 560/220)
  • Patent number: 5283360
    Abstract: An unsaturated (meth)acrylic compound of formula: ##STR1## (X.dbd.O, S, NH, NR.sup.3 (R.sup.3 =C.sub.1-12 -alkyl) or O--(CH.sub.2).sub.n (where n=1-16 approximately); R.sup.2 =C.sub.2-20 straight-chain or branched alkyl, monocyclic or polycyclic cycloalkyl or heterocycloalkyl, or alkylaryl hydrocarbon chain, comprising an olefinic double bond in the chain, or at the end of the chain in the case of alkyl or alkylaryl, or an exocyclic or endocyclic olefinic double bond in the case of monocyclic or polycyclic cycloalkyl or heterocycloalkyl; and R.sup.1 =H or C.sub.1-5 -alkyl), is reacted at 10.degree.-60.degree. C. with at least one oxidizing compound (hydrogen peroxide) in the presence of at least one catalyst (alkali metal molybdates and tungstates) and in the presence of at least one phase transfer agent and when R.sup.2 =polycyclic cycloalkyl or hetercycloalkyl, an organic peracid or hydrogen peroxide in the presence of at least one heteropolyacid.
    Type: Grant
    Filed: July 8, 1991
    Date of Patent: February 1, 1994
    Assignee: Atochem
    Inventors: Paul Caubere, Yves Fort, Agnes Ortar
  • Patent number: 5231220
    Abstract: Derivatives (I) of norbornylane and of dimethanodecahydornaphthylane of formula: ##STR1## in which: R is the hydrogen atom when n is equal to 1, orR is the acrylol or methacryloyl radical when n is equal to 0 or 1.Also disclosed are processes for the preparation of the derivatives (I) and their application in obtaining polymers and copolymers.
    Type: Grant
    Filed: May 14, 1992
    Date of Patent: July 27, 1993
    Assignee: Norsolor
    Inventors: Jean Francois Croisy, Paul Grosius
  • Patent number: 5210282
    Abstract: Perfluoro(cycloaliphatic methyleneoxyalkylene) compositions are provided. These compositions comprise perfluoro(cycloaliphatic methyleneoxyalkylene) carbonyl fluoride compounds having (a) a perfluorocycloaliphatic moiety which can have up to two perfluoroalkyl substituents and a perfluoroalkylene substituent, and (b) a perfluoromethyleneoxyalkylene carbonyl fluoride radical, the methylene group of the radical being bonded to a ring carbon atom or the perfluoroalkylene substituent of the moiety and the alkylene group of the perfluoromethyleneoxyalkylene carbonyl fluoride being a perfluoro(methyl)methylene group, a perfluoroisopropyleneoxy(methyl)methylene group, or a poly(perfluoroisopropyleneoxy)perfluoro(methyl)methylene group having up to about 10 perfluoroisopropyleneoxy units.
    Type: Grant
    Filed: June 30, 1992
    Date of Patent: May 11, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Richard M. Flynn, Patricia M. Savu
  • Patent number: 5191032
    Abstract: A heterofunctional macromer represented by the formula: ##STR1## in which R.sub.1 is H or C.sub.1 -C.sub.4 alkyl; R.sub.2 is a (poly) lactone or (poly) ether chain;X.sub.1 is --COO--, --COOCH.sub.2 CH.sub.2 OCO--, --CONHCOO--, --COOCH.sub.2 CH.sub.2 NH--COO-- or ##STR2## X.sub.2 is --O--, --COO-- or --OCO--NH--R.sub.3 --NHCOO-- group; R.sub.3 is C.sub.1 -C.sub.6 alkylene, aromatic or alicyclic group;A is --CH.sub.2 --, --C(CH.sub.3).sub.2 -- or ##STR3## group; and reactive polymers derived from said macromer.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: March 2, 1993
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Mitsuo Yamada, Kei Aoki
  • Patent number: 5157148
    Abstract: Fluorine-containing alicyclic or aromatic cyclic compounds represented by the formula ##STR1## wherein M is a divalent organic group comprising at least one substituted or unsubstituted alicyclic hydrocarbon group or a divalent organic group comprising at least two substituted or unsubstituted aromatic hydrocarbon group, the alicyclic hydrocarbon group or aromatic hydrocarbon group may be linked by O, S or CH.sub.2, or may form a condensed ring, X is ##STR2## Y is H or CH.sub.3, n is zero or a positive number, are useful as an effective component of the adhesive composition.
    Type: Grant
    Filed: October 18, 1990
    Date of Patent: October 20, 1992
    Assignees: Daikin Industries, Ltd., Nippon Telegraph and Telephone Corporation
    Inventors: Akira Ohmori, Yoshiki Shimizu, Motonobu Kubo, Kouzaburou Nakamura, Tohru Maruno, Norio Murata, Hideo Kobayashi
  • Patent number: 5132335
    Abstract: Acrylic and methacrylic esters of substituted 1,2-bis(phenoxy)-3,3,4,4,5,5-hexafluoro-1-cyclopentenes of the formula ##STR1## in which, in each case independently of one another, R.sup.1 and R.sup.2 denote C.sub.1 -to C.sub.4 -alkyl, C.sub.1 - to C.sub.4 -halogenoalkyl or hydrogen,R.sup.3 and R.sup.4 denote (n+1)- or (m+1)-valent, straight-chain or branched hydrocarbon radicals having 2 to 15 carbon atoms, which may optionally contain 1 to 3 oxygen bridges,R.sup.5 and R.sup.6 denote hydrogen or methyl,X represents ##STR2## and n and m denote integers from 1 to 5The ester can be polymerized to form dental fillings, coatings and artificial teeth.
    Type: Grant
    Filed: February 11, 1991
    Date of Patent: July 21, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Michael Muller, Wolfgang Podszun, Jens Winkel, Michael Negele
  • Patent number: 5105010
    Abstract: Carbodiimide compounds having the following structural formula are claimed: ##STR1## Z being selected from the group consisting of the following moieties: ##STR2## wherein R.sub.1 represents an alkylidene radical;R.sub.2 represents hydrogen or an alkyl radical;R.sub.3 represents an alkyl radical, an aromatic hydrocarbon moiety or a cycloaliphatic hydrocarbon moiety or substituted derivatives thereof;R.sub.4 represents an aromatic hydrocarbon moiety;R.sub.5 represents an alkyl radical; andx is an integer ranging from 1 to 6.Polymers containing moieties of at least two such carbodiimide compounds depending therefrom are also claimed and are useful in the formulation of coating compositions which harden or cure at low temperatures.
    Type: Grant
    Filed: June 13, 1991
    Date of Patent: April 14, 1992
    Assignee: PPG Industries, Inc.
    Inventors: Padmanabhan Sundararaman, James A. Claar, Charles M. Kania
  • Patent number: 5084584
    Abstract: There are disclosed a process for producing an .alpha.-acyloxy-.alpha.,.beta.-unsaturated carbonyl compound represented by the general formula (VI): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.4 are independently hydrogen atoms or substituted or unsubstituted hydrocarbon residues, or R.sub.1 and R.sub.2, when taken together with one another in an optional combination, form a ring, R.sub.3 is a substituted or unsubstituted hydrocarbon residue, and indicates that the configuration may be either E-configuration or Z-configuration, in particular, a 20-acyloxy-17(20)-methylen-21-al-steroid represented by the partial structural formula (II): ##STR2## wherein R is a hydrocarbon residue, and indicates that the configuration of the acyloxy group and the formyl group bonded to the carbon atom at the 20-position may be either E-configuration or Z-configuration, which comprises oxidizing a propargyl ester represented by the general formula (V): ##STR3## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.
    Type: Grant
    Filed: October 9, 1990
    Date of Patent: January 28, 1992
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Kiyoshi Watanabe, Hideaki Kataoka, Kuniaki Goto
  • Patent number: 5041620
    Abstract: A method for producing an optically active 2-cyclopenten-4-one-1-ol ester useful as an intermediate for medicines, agricultural chemicals and represented by the general formula (I), ##STR1## wherein R represents a saturated or unsaturated aliphatic hydrocarbon residue which may or may not be substituted with a halogen atom, and a mark * represents an asymmetric carbon,which comprises bringing a 2-cyclopenten-4-one-1-ol ester represented by the general formula ##STR2## wherein R represents a saturated or unsaturated aliphatic hydrocarbon residue which may or may not be substituted with a halogen atom, into contact with an optically active 1,6-diphenyl-2,4-hexadiyne-1,6-diol derivative represented by the general formula (II), ##STR3## wherein R' represents a halogenated phenyl, lower alkylphenyl, naphthyl or tertiary lower alkyl group, and a mark * represents an asymmetric carbon,in an organic solvent to obtain an optically active cyclopentenone ester complex which is a bound product of the optically active 2-c
    Type: Grant
    Filed: August 4, 1986
    Date of Patent: August 20, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Fumio Toda, Masayoshi Minai
  • Patent number: 5021453
    Abstract: Compounds of formula (I) and (II): ##STR1## are HMG-CoA reductase inhibitors.
    Type: Grant
    Filed: June 6, 1990
    Date of Patent: June 4, 1991
    Assignee: Merck & Co., Inc.
    Inventors: Henry Joshua, Kenneth E. Wilson, Michael S. Schwartz, Ta J. Lee, Gerald E. Stokker
  • Patent number: 5010105
    Abstract: Compounds of Formula (I) and (II): ##STR1## are HMG-CoA reductase inhibitors.
    Type: Grant
    Filed: May 9, 1990
    Date of Patent: April 23, 1991
    Assignee: Merck & Co., Inc.
    Inventor: Ta J. Lee
  • Patent number: 5008436
    Abstract: For filling and forming teeth, novel (meth)acrylic acid derivatives of triisocyanates of the formula ##STR1## wherein R.sup.1 and R.sup.2 are identical or different and stand for hydrogen or a lower alkyl radical,R.sup.3, R.sup.4 and R.sup.5 are identical or different and denote hydrogen or methyl,Y.sup.1 to Y.sup.3 are identical or different and denote divalent straight-chain or branched hydrocarbon radicals of 2 to 15 carbon atoms which may optionally include 1 to 3 oxygen bridges and which may be unsubstituted or substituted by 1 to 4 additional (meth)acryloyloxy radicals,X.sup.1 to X.sup.3 are identical or different and denote --NR.sup.1 -- or --O--, at least one of the radicals X.sup.1 to X.sup.3 denoting --NR.sup.1 --, and the ringsA and B are identical or different and may be aromatic or saturated.
    Type: Grant
    Filed: May 1, 1990
    Date of Patent: April 16, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Michael Muller, Wolfgang Podszun, Jens Winkel
  • Patent number: 5006622
    Abstract: Branched alkylhydroxycycloalkyl methacrylate monomers, such as t-butylhydroxycyclohexyl methacrylate, are polymerized with hydrophilic monomers and crosslinking agents to produce compositions for shaped biomedical devices, including soft contact lenses. Such copolymers have high oxygen permeability and good mechanical properties.
    Type: Grant
    Filed: April 2, 1987
    Date of Patent: April 9, 1991
    Assignee: Bausch & Lomb Incorporated
    Inventors: Jay F. Kunzler, Gary D. Friends
  • Patent number: 4916255
    Abstract: Methacrylate esters of alcohols having an ether linkage and/or an alicyclic ring can be obtained with no trouble of coloration or polymer formation during the production and for the product. An alcohol having an ether linkage and/or an alicyclic ring is treated with an alkaline substance, and the treated alcohol is caused to react with methyl methacrylate for a transesterification reaction in the presence of an alkaline substance.
    Type: Grant
    Filed: May 16, 1988
    Date of Patent: April 10, 1990
    Assignee: Hitachi, Ltd.
    Inventors: Akihiro Kobayashi, Toshiyuki Fujita, Takayuki Saito, Toshio Akima
  • Patent number: 4906675
    Abstract: An active energy ray-curable composition substantially comprising at least one of (meth)acrylates and oligomers thereof represented by the following general formula (I) ##STR1## wherein R represents a hydrogen atom or a methyl group, X represents an alkylene group in which at least one hydrogen atom may be replaced by a hydroxyl group, m is 0 or an integer of 1 to 4, Y represents a hydrocarbon group having a cyclic hydrocarbon moiety therein, and n is 1 or 2. The composition is useful as an adhesive, particularly as one in the production of optical discs.
    Type: Grant
    Filed: February 10, 1987
    Date of Patent: March 6, 1990
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hajime Inagaki, Kenji Yamane
  • Patent number: 4894181
    Abstract: Carbocyclic compounds of the formula I ##STR1## wherein Q is a benzene or cyclohexane ring or a naphthalene system, X is in each case --CH.sub.2 --(CH.sub.2).sub.p -- where it is also possible for one or two non-adjacent CH.sub.2 groups to be replaced by --O--, --S--, --CO--, --O--CO--, --CO--O-- or --CH.dbd.CH--,p is 0, 1 or 2,A.sup.1 and A.sup.2 independently of one another are each a 1,4-phenylene group which is unsubstituted or monosubstituted or polysubstituted by halogen atoms and/or CH.sub.3 groups and/or CN groups and in which it would also be possible for one or more CH groups to be replaced by N atoms, a 1,4-cyclohexylene group wherein it would also be possible for one or two non-adjacent CH.sub.2 groups to be replaced by --O-- and/or --S--, a piperidine-1,4-diyl group or a 1,4-bicyclo[2.2.2]octylene group,Z is --CO--O--, --O--CO--, --O--, --CH.sub.2 --, --CH.sub.2 O--, --OCH.sub.2 --, --CH.sub.2 CH.sub.2 --, --CHCN--CH.sub.2 --, --CH.sub.2 --CHCN--, --CH.dbd.CH--, --CH.dbd.N--, --N.dbd.CH--, --NO.
    Type: Grant
    Filed: May 16, 1988
    Date of Patent: January 16, 1990
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Klaus Praefcke, Bernd Kohne, Eike Poetsch
  • Patent number: 4874889
    Abstract: 3-Pentenoates are prepared by isomerization of 2-pentenoates to 3-pentenoates by a process in which the 2-pentenoate is treaated with from 0.01 to 0.5 mole of cyclic tertiary amine having a pK.sub.a of >6 per mole of 2-pentenoate at from 50.degree. to 250.degree. C. and the 3-pentenoate is distilled off continuously.
    Type: Grant
    Filed: November 18, 1987
    Date of Patent: October 17, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Rolf Fischer, Franz Merger, Hans-Juergen Gosch
  • Patent number: 4853151
    Abstract: Dispirotetradecanes of the formula I ##STR1## wherein R.sup.1 and R.sup.2 are each independently of each other alkyl containing 1 to 12 carbon atoms wherein one or more non-adjacent CH.sub.2 groups may also be replaced by --O--, --CO--, --CO--O--, --O--CO--, --O--COO-- and/or --CH.dbd.CH-- (trans), one of the radicals R.sup.1 and R.sup.2 also being H, F, Cl, Br, I, CN, NO.sub.2, NCS,A.sup.1 and A.sup.2 are each independently of each other trans-1,4-cyclohexylene wherein one or two non-adjacent CH.sub.2 groups may be replaced by --O-- and/or --S--, or 1,4-phenylene wherein one or more CH groups may also be replaced by N, with it also being possible optionally for A.sup.1 and A.sup.2 to be substituted laterally or axially by F, Cl, CN, CH.sub.3,Z.sup.1 and Z.sup.2 are each independently of each other --C--O--, --O--CO--, --CH.sub.2 CH.sub.2 --, --CH.sub.2 O--, --OCH.sub.2 -- or a single bond,m and n are each 0, 1 or 2,(m+n) 0, 1 or 2,X.sup.1, X.sup.2, X.sup.3 and X.sup.
    Type: Grant
    Filed: August 11, 1987
    Date of Patent: August 1, 1989
    Assignee: Merck Patent Gesellschaft Mit Beschrankfter Haftung
    Inventors: Fritz Vogtle, Wolfgang Calaminus
  • Patent number: 4841005
    Abstract: A tricyclodecane derivative represented by formula (I): ##STR1## wherein R.sup.1 represents a group X.sup.1 O-- or a hydrogen atom;R.sup.2 represents a hydrogen atom when R.sup.1 represents a group X.sup.1 O--, or R.sup.2 represents a group X.sup.1 O-- when R.sup.1 represents a hydrogen atom;wherein X.sup.1 represents a group ##STR2## or a hydrogen atom, wherein X.sup.2 represents a hydrogen atom, a methyl group, or a trifluoromethyl group;R.sup.3 represents a fluoroalkyl group containing from 1 to 21 carbon atoms, an iodine atom, or a hydrogen atom; andR.sup.4 represents an iodine atom or a hydrogen atom when R.sup.3 represents a fluoroalkyl group containing from 1 to 21 carbon atoms, or R.sup.4 represents a fluoroalkyl group containing from 1 to 21 carbon atoms when R.sup.3 represents an iodine atom or a hydrogen atom.
    Type: Grant
    Filed: February 12, 1988
    Date of Patent: June 20, 1989
    Assignee: Daikin Industries, Ltd.
    Inventors: Sinji Tamaru, Motonobu Kubo
  • Patent number: 4788218
    Abstract: Novel compounds having the general formula: ##STR1## wherein: R.sup.1 is hydrogen or an acyl substituent of the formula:--(C.dbd.O)--R.sup.2wherein:R.sup.2 is an alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkylene, haloalkyl, aryl, haloaryl or arylalkylene are described. These compounds have both gonadotropic and antigonadotropic properties depending upon the dosage level, and are therefore useful in therapy in the control of male fertility in mammals, particularly in human beings. These compounds combine gonadotropic, antigonadotropic and androgenic properties in the same compound. Their use with LHRH antagonists on male fertility control is also disclosed.
    Type: Grant
    Filed: April 28, 1986
    Date of Patent: November 29, 1988
    Assignee: SRI International
    Inventors: Masato Tanabe, David F. Crowe, George Detre, Peters, Richard H., Mitchell A.g34 Avery
  • Patent number: 4788327
    Abstract: 4,4'-(Perfluoroisopropylidene)dicyclohexanol or its organic acid ester of the formula ##STR1## wherein R' is hydrogen atom or acyl group having 1 to 10 carbon atoms, is useful as a starting material of a curable resin, cross-linking agent or the like.
    Type: Grant
    Filed: February 19, 1988
    Date of Patent: November 29, 1988
    Assignee: Daiken Industries, Ltd.
    Inventors: Sinji Tamaru, Motonobu Kubo
  • Patent number: 4786427
    Abstract: Use as lubricants, especially for tractive drives, of ester compounds of the general formula I ##STR1## wherein Cb denotes a carboxylic grouping which may be monocarboxylic (MCb) of formula --O--CO--or --CO--O--, dicarboxylic (DiCb) of formula --O--CO--R.sub.4 --CO--O--or --CO--O--R.sub.4 --O--CO--, or tetracarboxylic (TCb) of formula --O--CO--R.sub.5 --CO--O--R.sub.6 --O--CO--R.sub.5 --CO--O--; R.sub.4 represents an optionally substituted alkylene or alkenylene group, a C.sub.5-10 cycloalkylene group, a di-(C.sub.5-10 cycloalkylene) group, or a C.sub.5-10 cycloalkenylene group; R.sub.5 represents an alkylene group and R.sub.6 represents a cycloalkylene group;each group R.sub.3 individually represents a C.sub.1-6 alkyl, C.sub.2-6 alkenyl, C.sub.3-20 mono- or polycycloalkyl group or a hydrogen atom; m and n are each 0 or 1;R.sub.1 represents an optionally substituted C.sub.4-10 tertiary alkyl group or an optionally substituted C.sub.3-8 cycloalkyl or C.sub.6-14 bicyclo or tricycloalkyl group; and R.sub.
    Type: Grant
    Filed: October 22, 1987
    Date of Patent: November 22, 1988
    Assignee: Shell Oil Company
    Inventor: Martin P. Dare-Edwards
  • Patent number: 4780542
    Abstract: The invention relates to the preparation of an ester or an amide from an anhydride with an alcohol or an amine, wherein the anhydride is first prepared by reacting an acid and an alkyl chloroformate in a 100% aqueous medium, that is, 100% water.
    Type: Grant
    Filed: September 26, 1983
    Date of Patent: October 25, 1988
    Assignee: Montefiore Medical Center
    Inventor: Iraj Lalezari
  • Patent number: 4778915
    Abstract: The invention relates to fluoroacrylic monomers of formula: ##STR1## in which R.sub.f denotes a perfluoroalkyl radical, R is hydrogen or a methyl radical, R' denotes an alkyl or cycloalkyl radical, or --NR'-- denotes a 1, 4-piperazinylene radical, W and Z denote divalent connecting groups, Q is oxygen or sulphur or an --NR"-- group, R" denoting hydrogen an alkyl radical, and A is a C.sub.2 or C.sub.3 alkylene group. The polymers (homo- or copolymers) derived from these monomers may be used for the water-repellency and oil-repellency treatment of various substrates, particularly leather.
    Type: Grant
    Filed: October 16, 1986
    Date of Patent: October 18, 1988
    Assignee: Atochem
    Inventors: Marie-Jose Lina, Andre Dessaint
  • Patent number: 4767883
    Abstract: A cyclohexyleneoxyalkyl acrylate monomer having the structural formula: ##STR1## wherein R is H or CH.sub.3,a is an integer of from 1 to 10 andb is 1 or 2is useful in polymerizable compositions.
    Type: Grant
    Filed: July 24, 1987
    Date of Patent: August 30, 1988
    Assignee: Eastman Kodak Company
    Inventor: Michel F. Molaire
  • Patent number: 4744828
    Abstract: The invention relates to novel (meth)-acrylic acid derivatives of tricyclodecanes of the formula ##STR1## in which R.sup.1 and R.sup.2 are identical or different and denote hydrogen, lower alkyl, lower alkoxy, halogen or trifluoromethyl and R.sup.3 and R.sup.4 are identical or different and represent the groups. ##STR2## in which X is a divalent bridge member comprising the group ##STR3## and Y is a linear or branched hydrocarbon chain which has 2 to 10 carbon atoms and can optionally contain oxygen bridges and is optionally substituted by 1 to 4 acrylate or methacrylate radicals, andR.sup.5 represent hydrogen or methyl andR.sup.6 represents hydrogen, lower alkyl or phenyland to their use in dental compositions.
    Type: Grant
    Filed: June 4, 1986
    Date of Patent: May 17, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jens Winkel, Bruno Bomer, Carlhans Suling, Jurgen Reiners, Wolfgang Podszun
  • Patent number: 4744827
    Abstract: (Meth)-acrylic acid derivatives of tricyclodecanes of the formula ##STR1## in which R.sup.1 and R.sup.2 are identical or different and denote hydrogen, lower alkyl, lower alkoxy, halogen or trifluoromethyl and R.sup.3 and R.sup.4 are identical or different and represent the group ##STR2## wherein X denotes a divalent bridge member from the group ##STR3## and Y denotes a divalent bridge member from the group ##STR4## and wherein R.sup.5 represents hydrogen or methyl and R.sup.6 represents lower alkyl or phenyl, have been found. Dental compositions in which the present (meth)-acrylic acid derivatives of tricyclodecanes are used, exhibit considerably less polymerization shrinkage.
    Type: Grant
    Filed: June 4, 1986
    Date of Patent: May 17, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jens Winkel, Bruno Bomer, Robert Schmitz-Josten, Gerhard Klein, Carlhans Suling, Dieter Arlt
  • Patent number: 4739112
    Abstract: Perfluoropolycycloalkanes are provided. These perfluoropolycycloalkanes are ring assemblies having (a) at least two perfluorinated cyclohexane rings, (b) at least two perfluorinated fused ring systems, or (c) combinations of at least one perfluorinated cyclohexane ring with at least one perfluorinated fused ring system, each perfluorinated ring or fused ring system being directly joined to another perfluorinated ring or ring system by a single bond and the ring assemblies having a total of at least 13 carbon atoms.
    Type: Grant
    Filed: February 1, 1985
    Date of Patent: April 19, 1988
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Patricia M. Savu
  • Patent number: 4736055
    Abstract: Oxime sulfonates of formula I ##STR1## wherein Y is a polymerizable unsaturated group or epoxide group or an --OH, --NHR.sup.5, --COOH, COOR.sup.6, --COCl, --CH.sub.2 Hal, --SO.sub.2 Cl or --NCO group, Z is an (x+y)-valent connecting member, R.sup.1 and R.sup.2 are monovalent organic radicals, m is 0 or 1, x is 1 or 2 and y is 1 or 2, can be converted into polymers which can be thermally or photochemically dissociated to form free sulfonic acid groups. Said polymers can therefore be used as photoresists which can be developed with aqueous alkalis.
    Type: Grant
    Filed: April 11, 1986
    Date of Patent: April 5, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Kurt Dietliker, Werner Rutsch, Godwin Berner, Max Hunziker, Christopher G. Demmer
  • Patent number: 4716241
    Abstract: Novel cyclopentane derivatives which are useful as an intermediate for the preparation of N-(L-aspartyl)-N'-(2,2,5,5-tetramethylcyclopentanecarbonyl)-R-1,1-diaminoe thane are represented by the formula (I) ##STR1## wherein R.sub.1 is hydrogen and R.sub.2 is cyano, formyl, carbamoyl, alkanesulfonyloxy, or ##STR2## wherein R.sub.3 and R.sub.4 are the same or different and represent alkyl, substituted alkyl or R.sub.1 and R.sub.2 are combined to be methylsulfinylmethylene, acetoxymethylthiomethylene, halomethylthiomethylene, methylthiomethylene, alkoxy-methylene, or --CH.sub.2 --O--.
    Type: Grant
    Filed: February 28, 1986
    Date of Patent: December 29, 1987
    Assignee: Kyowa Hakko Kogyo Co., Ltd.
    Inventors: Takayoshi Yamauchi, Kaneaki Hattori, Shunichi Ikeda, Kentaro Tamaki
  • Patent number: 4707295
    Abstract: Bicyclooctane derivatives of the formula IR.sup.1 --A.sup.1 --A.sup.2 --R.sup.2 IwhereinR.sup.1 and R.sup.2 independently of one another are each an alkyl group which has 1-12 C atoms and in which it is also possible for one or two non-adjacent CH.sub.2 groups to be replaced by O atoms and/or CO groups and/or --O13 CO groups and/or --CO--O groups and/or --CH.dbd.CH-- groups, one of the radicals R.sup.1 and R.sup.2 being also --A.sup.3 --R.sup.3,A.sup.1 is a 1,4-cyclohexylene group which is unsubstituted or substituted in the 1-position and/or 2-position and/or 3-position and/or 4-position by alkyl which has in each case 1-5 C atoms and is unsubstituted or substituted or fluorinated, and in which it is also possible for one or two non-adjacent CH.sub.2 groups to be replaced by one or two different groupings from the group --O--, --CO--, --CH.dbd.CH--, --S--, --SO-- or --SO.sub.2 --, or is substituted by F, Cl, Br, CN and/or CHO,A.sup.2 is a 1,4-bicyclo[2.2.2] octylene group,--A.sup.3 --R.sup.3 is --Cy--R.sup.
    Type: Grant
    Filed: March 24, 1986
    Date of Patent: November 17, 1987
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Ludwig Pohl, Bernhard Scheuble, Andreas Wachtler, Reinhard Hittich, Peter Fuss
  • Patent number: 4663412
    Abstract: Polymers of fluorene containing compounds which form crosslinked networks are found to provide useful negative photoresists which are sensitive in the ultraviolet wavelength range of between about 200 nm to 300 nm. When used in negative photoresist compositions, these fluorene compounds produce a high resolution and thus higher information density in microcircuits manufactured using these photoresists.
    Type: Grant
    Filed: July 2, 1986
    Date of Patent: May 5, 1987
    Assignee: Ecoplastics Limited
    Inventors: James E. Guillet, Anthony E. Redpath
  • Patent number: 4640706
    Abstract: Novel cyclohexenonecarboxylic acid derivatives exhibit herbicidal and plant growth regulating activity.The cyclohexenonecarboxylic derivatives are of the formula I ##STR1## wherein A is an aliphatic or aromatic alcohol, or is an amino group which may be substituted by halogen, lower alkoxy, lower alkylthio, nitro or cyano, or is a heterocyclic amino group which is unsubstituted or substituted,R is C.sub.1 -C.sub.6 alkyl or C.sub.3 -C.sub.6 cycloalkyl, each unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkylthio,R.sub.1 is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 haloalkenyl or C.sub.3 -C.sub.6 alkynyl,B is an aliphatic or aromatic radical or is an aliphatic or aromatic carbonyl or sulfonyl group which may be substituted by halogen, lower alkoxy, lower alkylthio, nitro or cyano.The compounds are suitable for selectively controlling grasses in crops of useful plants.
    Type: Grant
    Filed: March 20, 1985
    Date of Patent: February 3, 1987
    Assignee: Ciba-Geigy Corporation
    Inventor: Hans-Georg Brunner
  • Patent number: 4624980
    Abstract: An N-t-alkyl-N-sec-alkyl secondary amine compound of the formula: ##STR1## wherein X, Y and Z are each independently selected from --H, --OH, or an alkyl group having from 1 to about 15 carbon atoms; and n is an integer of from 3 to about 6.
    Type: Grant
    Filed: March 28, 1985
    Date of Patent: November 25, 1986
    Assignee: Milliken Research Corporation
    Inventors: John W. Rekers, Edward W. Kluger
  • Patent number: 4620028
    Abstract: Compounds having the general formula: ##STR1## wherein X is the 2-(1,7,7-trimethylbicyclo[2.2.1]hept-2-yl)oxy, R is --(CH.sub.2).sub.p -- where p varies from 1 to 3; R' is (CH.sub.2).sub.n -- where n varies from 1 to 7; R" is hydrogen or methyl; and m is 0 to 4.
    Type: Grant
    Filed: May 28, 1985
    Date of Patent: October 28, 1986
    Assignee: SCM Corporation
    Inventors: C. Rodney Gorman, James M. Evans, Sean G. Traynor
  • Patent number: 4613680
    Abstract: Angelic acid or esters thereof which are useful as perfume materials are prepared by isomerizing tiglic acid or an ester thereof with an organic sulfinic acid as the catalyst, and novel esters of angelic acid represented by the formula ##STR1## wherein R represents 3-hexenyl, 3-methyl-2-butenyl, 3-methyl-3-butenyl, 3-methyl-2-pentenyl, 3-methyl-4-pentenyl, CH.sub.3 (CH.sub.2).sub.l - (in which l is an integer from 5 to 9), cyclopentyl, cyclohexyl, 2-methylpentyl, .alpha.-methylbenzyl, neryl or furfuryl are provided as part of said esters of angelic acid.
    Type: Grant
    Filed: February 24, 1984
    Date of Patent: September 23, 1986
    Assignee: Toray Industries, Inc.
    Inventors: Masanobu Naruto, Hisao Kondo, Go Hata
  • Patent number: 4612386
    Abstract: Carboxylic acid esters are produced by the reaction of a carboxylic acid halide with a carbonate ester in the presence of an initiator. The reaction of a dicarboxylic acid dihalide and a bis(alkyl carbonate) ester produces a polymeric polyester.
    Type: Grant
    Filed: December 17, 1981
    Date of Patent: September 16, 1986
    Assignee: The Dow Chemical Company
    Inventor: James M. Renga
  • Patent number: 4609491
    Abstract: Novel odorant substances of the formula: ##STR1## wherein: one of the three dotted lines represents an optional bond,R.sup.1 represents hydrogen, an alkyl group of one to four carbons or an alkenyl group of two to four carbons,R.sup.2 represents hydrogen or methyl,R.sup.3 represents hydrogen or methyl, provided thatR.sup.2 and R.sup.3 are never both hydrogen, and novel fragrance compositions containing same.
    Type: Grant
    Filed: May 23, 1983
    Date of Patent: September 2, 1986
    Assignee: Givaudan Corporation
    Inventor: Hanspeter Schenk
  • Patent number: 4594448
    Abstract: Esters of vinylcarboxylic acids having the formula (I): ##STR1## wherein R is H, or methyl. The esters of the present invention are useful as monomers which can be used to prepare polymers which are used to prepare dental materials.
    Type: Grant
    Filed: August 9, 1985
    Date of Patent: June 10, 1986
    Assignee: Rohm GmbH Chemische Fabrik
    Inventor: Heinz-Juergen Hohage
  • Patent number: 4556729
    Abstract: A novel diacrylate or dimethacrylate characterized in that diols having two allyloxy groups in a molecule are esterified with acrylic acid, methacrylic acid or their derivatives, and represented by the following structural formula: ##STR1## wherein R denotes acryloyl or methacryloyl group, and a method for manufacturing the same.
    Type: Grant
    Filed: July 9, 1984
    Date of Patent: December 3, 1985
    Assignee: Sanyo-Kokusaku Pulp Co., Ltd.
    Inventors: Motonobu Kubo, Kazumi Honda
  • Patent number: 4532050
    Abstract: Described is a genus of compounds defined according to the structure: ##STR1## hereinafter termed "norbornyl esters" wherein R.sub.1, R.sub.2 and R.sub.3 represent methyl or hydrogen with the proviso that at least one of R.sub.1, R.sub.2 and R.sub.3 is hydrogen as well as uses thereof in augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfume compositions, colognes and perfumed articles (including, but not limited to, solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair preparations and perfumed polymers). Also described is a novel process for preparing such norbornyl esters.
    Type: Grant
    Filed: August 24, 1984
    Date of Patent: July 30, 1985
    Assignee: International Flavors & Fragrances Inc.
    Inventor: Mark A. Sprecker
  • Patent number: 4515931
    Abstract: Compositions comprising polyfunctional acrylate monomers of the formula ##STR1## wherein R.sup.1 is an aliphatic or alicyclic radical having about 20-40 carbon atoms, R.sup.2 is hydrogen or methyl, and n is from 2 to 4, at least about 40% of said monomers containing alicyclic R.sup.1 moieties, may be polymerized to form polymers useful as dielectrics for capacitors. Illustrative polyfunctional acrylates are those prepared from a diol which is the reduction product of linoleic acid dimer, or from condensation products of fatty acids such as linoleic acid with such materials as acrylic acid.
    Type: Grant
    Filed: December 19, 1983
    Date of Patent: May 7, 1985
    Assignee: General Electric Company
    Inventors: Daniel R. Olson, Timothy W. O'Donnell
  • Patent number: 4474806
    Abstract: Sulfonyl or carbonyl derivatives of inositols are found to be effective phospholipase C inhibitors and thereby potent anti-inflammatory and analgesic agents. These inositol derivatives are prepared by condensation of a protected inositol with a substituted sulfonic or carboxylic acid derivative followed by removal of protecting groups.
    Type: Grant
    Filed: May 10, 1982
    Date of Patent: October 2, 1984
    Assignee: Merck & Co., Inc.
    Inventors: Thomas R. Beattie, Shu S. Yang
  • Patent number: 4474982
    Abstract: 1-Halomethyl-2-alkoxyethyl acrylates and methacrylates useful for making acrylate and methacrylate polymers and copolymers. Preferred monomers are used to prepare fluorochemical copolymers which impart oil and water repellency to cellulosic materials and textile fibers. The fluorochemical copolymers are derived (by weight) from about 1 to 30% of the preferred monomers, 60 to 80% fluorochemical acrylate, 1 to 15% glycidyl acrylate or methacrylate, 1 to 6% of certain cationic acrylates or methacrylates, and 0 to 20% vinylidene chloride.
    Type: Grant
    Filed: October 13, 1982
    Date of Patent: October 2, 1984
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Richard D. Howells
  • Patent number: 4438278
    Abstract: Compounds useful in making crosslinkable polymers having the formula (I): ##STR1## wherein R is hydrogen or methyl; R.sup.1 is cyano or ##STR2## wherein R.sup.2 is alkyl; Z is --X--R.sup.3 --X--or ##STR3## wherein each --X-- is --O-- or --NR.sup.4 --, provided at least one --X-- is --NR.sup.4 -- wherein R.sup.4 is hydrogen or alkyl, R.sup.3 is divalent hydrocarbon and D.sub.1 and D.sub.2 together are the carbon atoms necessary to complete a 5 to 7 membered ring. These compounds can be homopolymerized or copolymerized with each other or with other polymerizable ethylenically unsaturated monomers to give crosslinkable polymers. Such polymers can be purified by conventional purification techniques such as dialysis, diafiltration, ultrafiltration without losing their capability of crosslinking. The resulting purified polymers are particularly useful in photographic materials as gelatin extenders, binders or polymeric color couplers.
    Type: Grant
    Filed: April 19, 1982
    Date of Patent: March 20, 1984
    Assignee: Eastman Kodak Company
    Inventors: Ignazio S. Ponticello, Kenneth R. Hollister, Richard C. Tuites
  • Patent number: 4435316
    Abstract: Described is a genus of compounds defined according to the structure: ##STR1## hereinafter termed "norbornyl esters" wherein R.sub.1, R.sub.2 and R.sub.3 represent methyl or hydrogen with the proviso that at least one of R.sub.1, R.sub.2 and R.sub.3 is hydrogen as well as uses thereof in augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfume compositions, colognes and perfumed articles (including, but not limited to, solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair preparations and perfumed polymers). Also described is a novel process for preparing such norbornyl esters.
    Type: Grant
    Filed: July 8, 1982
    Date of Patent: March 6, 1984
    Assignee: International Flavors & Fragrances Inc.
    Inventor: Mark A. Sprecker
  • Patent number: 4426505
    Abstract: New polymers are disclosed comprising recurring units of the formula ##STR1## wherein R is hydrogen or lower alkyl containing from 1 to 5 carbon atoms, L is a divalent linking group, and each X is independently chloro or bromo. The polymers are capable of providing a relatively high index of refraction in combination with a relatively high Abbe number and can be utilized as raw materials in the manufacture of plastic optical articles or elements such as lenses or prisms and in the manufacture of optical films and coatings.
    Type: Grant
    Filed: February 25, 1982
    Date of Patent: January 17, 1984
    Assignee: Polaroid Corporation
    Inventor: Richard A. Minns
  • Patent number: 4377707
    Abstract: Halogenated dicyclopentyl ethers or thioethers of alkylene glycol mono(meth) acrylate or mono (meth) propionates are prepared. The dihalo compounds having (meth) acrylic functionality are useful to prepare thermosetting or thermoplastic resins with built in fire retardency. The tetrahalo compounds are useful fire retardant additives in the manufacture of polymeric foams.
    Type: Grant
    Filed: December 17, 1981
    Date of Patent: March 22, 1983
    Assignee: The Dow Chemical Company
    Inventors: Clinton J. Boriack, Hans R. Friedli
  • Patent number: 4374263
    Abstract: The invention relates to an esterification process employing as a heterogeneous catalyst an inorganic oxide, e.g. silica, to which there is bonded by reaction with surface hydroxyl groups a sulphonic acid-functionalized silane.
    Type: Grant
    Filed: October 24, 1980
    Date of Patent: February 15, 1983
    Assignee: The British Petroleum Company Limited
    Inventors: Ronald D. Hancock, Robert Mackison
  • Patent number: 4370497
    Abstract: The present invention relates to the use of telluroxides as mild and selective oxidizing agents serving to oxidize certain functions, notably >C.dbd.S groups, in the presence of other relatively easily oxidized functions which remain unaffected; telluroxides of interest as oxidizing agents include, for example, compounds of the formula: ##STR1## wherein R and R.sup.1, which may be the same or different, each represent an optionally substituted aryl or heterocyclic group; or R and R.sup.1 together with the tellurium atom therebetween represent a heterocyclic ring, which may contain one or more further heteroatoms, and which may carry substituents and/or fused aromatic rings.
    Type: Grant
    Filed: August 7, 1980
    Date of Patent: January 25, 1983
    Inventors: Derek H. R. Barton, Steven V. Ley, Clive A. Meerholz