Element Other Than C,h,o,n, Or Halogen Patents (Class 562/594)
  • Patent number: 4647687
    Abstract: The new halogenated sulphides of the formula ##STR1## in which R.sup.1 to R.sup.8 are identical or different and denote hydrogen or halogen, at least one of the radicals R.sup.1 to R.sup.8 representing halogen,and whereinR.sup.1 and R.sup.2, and/or R.sup.3 and R.sup.4 can optionally form an olefinic bond, andA and B are identical or different and denote nitrile, carboxyl, carboxylate or carboxamide,can be prepared by halogenation of bis-(cyanoethyl) sulphide, or by splitting off hydrogen halide from a halogenated bis-(cyanoethyl) sulphide, or by reacting 3-halogeno-acrylonitriles with sulphides. The new compounds can be active compounds in microbicidal agents.
    Type: Grant
    Filed: December 5, 1984
    Date of Patent: March 3, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Siegfried Oeckl, Gerold Schade, Hans-Georg Schmitt, Wilfried Paulus, Hermann Genth
  • Patent number: 4623535
    Abstract: The compounds represented by the following structural formula (I) ##STR1## wherein m and n are independently 1, 2 or 3; R.sub.1 is an C.sub.8 to C.sub.13 alkyl radical and pharmaceutically acceptable salts thereof have been found to be leukotriene antagonists and useful in the treatment of diseases in which leukotrienes are a factor, such as asthma.
    Type: Grant
    Filed: January 19, 1984
    Date of Patent: November 18, 1986
    Assignee: SmithKline Beckman Corporation
    Inventor: Carl D. Perchonock
  • Patent number: 4595721
    Abstract: Additives for rubber compositions, giving vulcanizates having improved retention of optimum physical properties, are compounds having the formula R-S-B-S-R where B is an organic bridging group and R is an electron-withdrawing group, for example CN, CCl.sub.3, a radical containing an activated methylene group linked to the sulphur atom or the enolic tautomer of a keto-activated methylene group. Also useful as stabilizing agents are oligomeric analogues of such compounds.
    Type: Grant
    Filed: June 4, 1984
    Date of Patent: June 17, 1986
    Assignee: Monsanto Europe, S.A.
    Inventors: Albert F. L. G. Devaux, Philippe G. Moniotte
  • Patent number: 4550193
    Abstract: 2,3-dimercaptosuccinic acid and esters thereof are prepared by reacting sodium thiosulfate with acetylene dicarboxylic acid in the presence of a strong acid and subjecting the resulting alkylthiosulfate to an acid hydrolysis. The 2,3-dimercaptosuccinic acids and esters thereof are useful as an antidote for heavy metal poisoning.
    Type: Grant
    Filed: June 7, 1982
    Date of Patent: October 29, 1985
    Assignee: Johnson & Johnson Baby Products Company
    Inventors: Martin K. O. Lindemann, Elvin R. Lukenbach
  • Patent number: 4533747
    Abstract: The compounds represented by the formula (I) ##STR1## wherein m is 0, 1 or 2; p is 9, 10, 11, 12 or 13; R.sub.1 ' is hydrogen, ##STR2## and R.sub.2 ' is amino, --NHCH.sub.2 CO.sub.2 R.sub.3 ', ##STR3## --NHCH.sub.2 CONH.sub.2 or --OR.sub.3 ' wherein R.sub.3 ' is an alkyl radical containing one to six carbon atoms with the proviso that when m is 0, R.sub.1 ' is hydrogen are chemical intermediates in the synthesis of leukotriene antagonists of the formula (II) ##STR4## wherein m and p, are described above and R.sub.1 is hydrogen, amino or ##STR5## R.sub.2 is hydroxyl, amino, --NHCH.sub.2 CO.sub.2 H, ##STR6## --NHCH.sub.2 CONH.sub.2 ; and X is ##STR7## --CO.sub.2 H or --CH.sub.2 OH which are useful in the treatment of diseases in which leukotrienes are a factor, such as asthma.
    Type: Grant
    Filed: March 7, 1983
    Date of Patent: August 6, 1985
    Assignee: SmithKline Beckman Corporation
    Inventors: John G. Gleason, Ralph F. Hall, Thomas W. Ku
  • Patent number: 4481148
    Abstract: Hydroxyl-containing liquid polymers having an aliphatic polymeric backbone and sulfide linkages near the terminal portions of the polymer molecule are prepared by polymerizing (1) at least one of selected vinylidene monomers having at least one terminal CH.sub.2 .dbd.C< group per monomer molecule, together with (2) at least one hydroxyl-containing disulfide in the presence of (3) ultraviolet radiation.
    Type: Grant
    Filed: March 16, 1981
    Date of Patent: November 6, 1984
    Assignee: The B. F. Goodrich Company
    Inventor: Changkiu K. Riew
  • Patent number: 4448702
    Abstract: The freezing point of an aqueous system is lowered by adding to the system a freezing point lowering quantity of at least one and preferably two or more water soluble salts of dicarboxylic acids having at least three carbon atoms, specifically a dicarboxylic acid selected from the group which consists of adipic, glutaric, succinic and malonic acids, the salt being a sodium, potassium, ammonium or organoamine salt.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: May 15, 1984
    Assignee: Lang & Co., Chemisch-Technische Produkte Kommanditgesellschaft
    Inventor: Gertrude Kaes
  • Patent number: 4385183
    Abstract: This invention is directed to the telomerization of water-soluble monomers in an aqueous phase. More particularly, this invention is directed to a process for the telomerization of water-soluble monomers and water-insoluble telogens in aqueous phase, wherein the water-insoluble telogens are solubilized by the addition of an effectively solubilizing amount of surface-active compounds.
    Type: Grant
    Filed: June 4, 1981
    Date of Patent: May 24, 1983
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Rainer Hofer, Hans-Christoph Wilk, Bernd Wegemund
  • Patent number: 4355183
    Abstract: Inhibition of the formation of color bodies and color-forming materials and other contaminants and/or decolorization of discolored sulfur-containing organic compounds containing divalent sulfur by addition of a small amount of oxalic acid.
    Type: Grant
    Filed: August 8, 1979
    Date of Patent: October 19, 1982
    Assignee: Phillips Petroleum Company
    Inventors: Martin E. Nash, Edward E. Huxley
  • Patent number: 4292326
    Abstract: There is disclosed a composition for the treatment of acne, hyperpigmentary dermatoses or skin hyperpigmentation which contains dicarboxylic acids containing 7 to 13 carbon atoms or certain derivatives thereof that contain reducing functional group or a salt thereof. There are also disclosed methods for preparing mercapto derivatives of these dicarboxylic acids.
    Type: Grant
    Filed: December 1, 1978
    Date of Patent: September 29, 1981
    Inventor: Marcella Nazzaro-Porro
  • Patent number: 4276374
    Abstract: A silver halide photographic emulsion containing the compound represented by the formula (I):R.sub.1 --(X--R.sub.3).sub.m --X--R.sub.2 (I)wherein R.sub.1 and R.sub.2 each represents an alkyl group containing 1 to 5 carbon atoms substituted with two or more substituents selected from --OH, --NHR.sub.4, --COOR.sub.4, --CONH.sub.2, --SO.sub.3 H, --COOM, or --SO.sub.3 M, R.sub.3 represents an alkylene group containing 1 to 4 carbon atoms which may be substituted by --OH, R.sub.4 represents a hydrogen atom or an alkyl group containing 1 to 5 carbon atoms, X represents a sulfur or oxygen atom, provided at least one X is a sulfur atom, m represents 0 or an integer of 1 to 4, and M represents an alkali metal atom.
    Type: Grant
    Filed: May 30, 1979
    Date of Patent: June 30, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Nobuaki Miyasaka, Yoshiharu Fuseya
  • Patent number: 4238408
    Abstract: Novel compounds are provided comprising dicyanosulfinates, dicyanosulfonates and dicyanosulfones as well as process of preparing these compounds. These novel compounds are useful in the preparation of monomers for use in polymers, particularly polymers useful in the fibers and textile industry.
    Type: Grant
    Filed: February 13, 1979
    Date of Patent: December 9, 1980
    Assignee: Phillips Petroleum Company
    Inventor: Raymond L. Cobb
  • Patent number: 4224457
    Abstract: Process for manufacturing optically active sulfur-containing carboxylic acid which comprises reacting a racemic acid of the formula ##STR1## with an optically active amine to form the amine salt, and then resolving the isomers and recovering the optically active isomer.
    Type: Grant
    Filed: May 4, 1979
    Date of Patent: September 23, 1980
    Assignee: Santen Pharmaceutical Co., Ltd.
    Inventors: Jun-ichi Iwao, Masayuki Oya, Eishin Kato, Toshio Watanabe
  • Patent number: 4177216
    Abstract: The trisubstituted (2,5-dihydroxyphenyl)phosphonium hydroxide inner salts and their hydrolyzed derivatives are novel latent catalysts for promoting reaction between vicinal epoxides and phenols and/or carboxylic acids (or anhydrides). Precatalyzed epoxy resins are easily prepared using such catalysts.
    Type: Grant
    Filed: September 26, 1978
    Date of Patent: December 4, 1979
    Assignee: The Dow Chemical Company
    Inventors: George A. Doorakian, Lawrence G. Duquette
  • Patent number: 4177338
    Abstract: Organic polymer compounds having semi-telechelic olefinic unsaturation, which correspond to the general formula: ##STR1## in which V is the radical of an organic compound containing at least one polymerizable ##STR2## group and another group capable of reacting with the functional groups of organic compounds having radicals represented by W and Y; W is the radical of a chain transfer agent RSH, R being an organic radical having at least one hydroxyl or carboxyl group; X is the radical of an organic compound containing a polymerizable ##STR3## group; Y is the radical of an organic compound containing a polymerizable ##STR4## group and at least one other reactive group selected from hydroxyl, carboxyl, acid anhydride and epoxy groups; y is 0 or a whole number of from 1 to 10; x is the number of moles of X necessary to enable the chain --(X).sub.x --(Y).sub.
    Type: Grant
    Filed: October 24, 1974
    Date of Patent: December 4, 1979
    Assignee: UCB, Societe Anonyme
    Inventors: August Vrancken, Paul Dufour
  • Patent number: 4172207
    Abstract: A process is provided for the preparation of mercaptoalkane 1,2-dicarboxylic acid esters from readily available starting materials such as hydrogen sulfide and unsaturated alkene 1,2-dicarboxylic acid compounds. Isolation of the intermediate mercaptoalkanedicarboxylic acid can be avoided when a mercaptoalkanedicarboxylic acid ester is the desired product.
    Type: Grant
    Filed: February 22, 1977
    Date of Patent: October 23, 1979
    Inventor: Gerry P. Mack
  • Patent number: 4172211
    Abstract: A process for preparing thioethers of mercaptocarboxylic acids by contacting glycolic acid or bromoacetic acid and a mercaptan in the presence of aqueous hydrogen bromide.
    Type: Grant
    Filed: March 31, 1978
    Date of Patent: October 23, 1979
    Assignee: Chevron Research Company
    Inventor: Shigeto Suzuki
  • Patent number: 4161612
    Abstract: A process for preparing thiodiglycolic acid comprises contacting bromoacetic acid, diglycolic acid or glycolic acid and hydrogen sulfide in the presence of aqueous hydrogen bromide.
    Type: Grant
    Filed: March 31, 1978
    Date of Patent: July 17, 1979
    Assignee: Chevron Research Company
    Inventor: Shigeto Suzuki
  • Patent number: 4152515
    Abstract: There are disclosed herein novel builder salts of alkyloxysuccinic acids, alkyloxyhydroxysuccinic acids, alkylthiosuccinic acids, alkylthiohydroxysuccinic acids, and the sulfoxide and sulfone derivatives of the alkylthiosuccinic and alkylthiohydroxysuccinic acids. The new builder compounds can be generally represented as follows: ##STR1## wherein Z is selected from the group consisting of O, S, SO and SO.sub.2 ; X is H or OH; R is an alkyl radical containing from 6 to 30 carbon atoms and M is selected from the group consisting of alkali metal cations, ammonium and substituted ammonium. These new builder compounds can be substituted in detergent compositions for existing builders containing phosphorous or nitrogen without impairing and in some cases improving the efficiency of such detergent compositions.
    Type: Grant
    Filed: April 13, 1977
    Date of Patent: May 1, 1979
    Assignee: Lever Brothers Company
    Inventors: Vincent Lamberti, Mark D. Konort
  • Patent number: 4150242
    Abstract: Lower alkyl bis-(.beta.-carboxyethyl) phosphine oxides are prepared from lower alkyl bis-(.beta.-cyanoethyl) alkyl phosphine by oxidizing the phosphine to cyanoethyl phosphine oxide, hydrolyzing the cyanoethyl phosphine oxide with calcium hydroxide to produce a calcium salt of lower alkyl bis-(.beta.-carboxyethyl) phosphine oxide, and acidifying the calcium salt to produce lower alkyl bis-(.beta.-carboxyethyl) phosphine oxide.
    Type: Grant
    Filed: April 18, 1977
    Date of Patent: April 17, 1979
    Assignee: Monsanto Company
    Inventor: Glenn R. Wilson
  • Patent number: 4149014
    Abstract: Lower alkyl bis-(.beta.-carboxyethyl) phosphine oxides are prepared from tris-cyanoethyl phosphine in a functionally coordinated sequentially ordered process comprising alkylating the tris-cyanoethyl phosphine to a phosphonium salt, dequarternizing the phosphonium salt to a lower alkyl bis-(.beta.-cyanoethyl) phosphine, oxidizing the phosphine to phosphine oxide, hydrolyzing the phosphine oxide with calcium hydroxide to produce a calcium salt of lower alkyl bis-(.beta.-carboxyethyl) phosphine oxide, and acidifying the calcium salt to produce lower alkyl bis-(.beta.-carboxyethyl) phosphine oxide.
    Type: Grant
    Filed: March 23, 1977
    Date of Patent: April 10, 1979
    Assignee: Monsanto Company
    Inventor: Glenn R. Wilson
  • Patent number: 4132735
    Abstract: The present invention relates to a novel class of oligomeric builders for use in detergent compositions. More particularly, the present invention relates to a biodegradable, oligomeric polyacrylate having a molecular weight of greater than about 500 and less than about 10,000, preferably less than about 5000. In the most desirable embodiments at least one end of the oligomer chain is terminated with either a sulfur containing moiety or an hydroxy containing moiety. Preferred cations are alkali metals, ammonium and substituted ammonium.
    Type: Grant
    Filed: February 23, 1978
    Date of Patent: January 2, 1979
    Assignee: Lever Brothers Company
    Inventors: Vincent Lamberti, Chester R. Willis
  • Patent number: 4129510
    Abstract: Sulfur-containing compounds of the formula ##STR1## WHEREIN R is a hydrocarbyl radical; each of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is independently hydrogen or a hydrocarbyl radical; m' is from one to about five; and each A is an alkyl radical containing at least one carboxyl group or functional derivative thereof, are useful as additives in lubricants and fuels.
    Type: Grant
    Filed: April 28, 1976
    Date of Patent: December 12, 1978
    Assignee: The Lubrizol Corporation
    Inventor: Donald M. Smith
  • Patent number: 4125552
    Abstract: Alkyl polysulfides are prepared by reacting alkyl halides with hydrogen sulfide and sulfur in the presence of ammonia or certain monoamines.
    Type: Grant
    Filed: December 29, 1975
    Date of Patent: November 14, 1978
    Assignee: Dow Corning Corporation
    Inventor: John L. Speier