Abstract: Provided is a corrosion, erosion and wear resistant cemented carbide for high demand applications including, for example, use as a component within oil and gas production. The cemented carbide includes a hard phase and a binder phase. The cemented carbide may include, for example. Ni, Cr and Mo. The binder phase content of the cemented carbide is between 7 to 11 wt %. The WC of the cemented carbide may have an average grain size of from 0.1 to 2 ?m.

Abstract: A cemented carbide comprises particles including a tungsten carbide (WC) as a main component; a binder phase including cobalt (Co) as a main component; and particles including a carbide or a carbonitride of at least one selected from the group consisting of Group 4a, 5a, and 6a elements, or a solid solution thereof, wherein a cubic phase free layer (CFL), in which the carbide or the carbonitride is not formed, is formed from a surface of the cemented carbide to a depth of 5 ?m to 50 ?m.

Abstract: An anvil including a hard phase and a metal matrix in which the hard phase is dispersed, a concentration of the metal matrix phase varying according to a concentration gradient, is disclosed. The anvil may be used in a high pressure press. Methods of making an anvil including forming a hard phase dispersed in a metal matrix phase, a concentration of the metal matrix phase varying according to a concentration gradient, are also disclosed.

Abstract: A lightweight material for decorative parts having a silver metallic color tone is provided. The material includes a sintered body including a main hard phase composed of a solid solution formed of titanium carbonitride and titanium carbide; a main binder phase composed of nickel; a first additive material composed of at least one selected from the group consisting of molybdenum carbide, niobium carbide, tungsten carbide, and tantalum carbide; a second additive material composed of at least one of chromium and chromium carbide; and the balance being incidental impurities. The N content in the sintered body is 2.0% to 6.0% by mass. The color tone of the sintered body satisfies L*=9 to 14, a*=?2 to 3, and b*=?6 to 0, which are values of the L*a*b* color system measured with a spectrophotometric colorimeter.

Abstract: A cutting element for engaging earthern formations having a wear surface formed from a low coefficient of thermal expansion (CTE) composition including a polycrystalline diamond or polycrystalline cubic boron nitride hard phase material and a ductile phase low CTE material formed from an alloy made of Co, Ni, Fe, C, and Mn. The hard phase material is bonded to one another by the ductile phase material to form the low CTE composition.

Abstract: In one aspect, cemented carbide bodies are provided. A cemented carbide body described herein, in some embodiments, comprises a tungsten carbide phase, a binder phase comprising at least one metal of the iron group or an alloy thereof, a solid solution phase of carbides of zirconium and niobium (Zr,Nb)C and cubic carbides in an amount ranging from about 0.5 volume percent to about 6 volume percent.

Abstract: This invention relates to a ceramic and a cermet each having a second phase for improving toughness via phase separation from a complete solid-solution phase and to a method of preparing them. The ceramic and the cermet may have the second phase phase-separated from the complete solid-solution phase, thereby easily achieving a great improvement in toughness and exhibiting other good properties including high strength, consequently enabling the manufacture of high-strength and high-toughness cutting tools, instead of conventional WC—Co hard materials.

Abstract: The invention relates to a hard-metal comprising at least 13 volume % of a metal carbide selected from the group consisting of TiC, VC, ZrC, NbC, MoC, HfC, TaCl WC or a combination thereof, a binder phase comprising one or more of iron-group metals or alloy thereof and 0.1 to 10 weight % Si and 0.1 to 10 weight % Cr and having a liquidus temperature at 1280 degrees C. or lower and 3 to 39 volume % of diamond or cBN grains coated with a protective coating or a mixture thereof and a process for making the hard-metal.

Abstract: A sintered cemented carbide body (e.g., a cutting tool) and a method of making the same. The sintered cemented carbide body includes tungsten carbide, a binder phase of at least one metal of the iron group or an alloy thereof, and one or more solid solution phases. Each one of the solid solution phases has at least one of the carbides and carbonitrides of a combination of zirconium, niobium, and tungsten. The method includes the steps of providing a powder mixture that contains tungsten carbide, a binder metal powder comprising at least one metal of the iron group or an alloy thereof, and at least one of the carbides and carbonitrides of both zirconium and niobium including a powder of the carbides or carbonitrides of zirconium and niobium, forming a green compact of said powder mixture, and vacuum sintering or sinter-HIP said green compact at a temperature of from 1400 to 1560° C.

Abstract: A mixed powder and a sintered body obtained by sintering the mixed powder. The mixed powder includes a solid-solution powder with complete solid-solution phase. The solid-solution powder includes a carbide or a carbonitride of at least two metals selected, including Ti, from metals of Groups IVa, Va and VIa of the periodic table, or a mixture thereof. A mixed cermet powder and a cermet obtained by sintering the mixed cermet powder are also disclosed. The mixed cermet powder includes at least a cermet powder with complete solid-solution phase. The cermet powder includes a carbide or a carbonitride of at least two metals selected, including Ti, from metals of Groups IVa, Va and VIa of the periodic table, or a mixture thereof, and at least one metal selected from the group consisting of Ni, Co and Fe. Also disclosed are a sintered body and a fabrication method of a cermet.

Abstract: A hard alloy material comprising tungsten carbide in an amount of less than 50 weight percent of the material, titanium carbide in an amount of at least about 30 weight percent, and a binder material of cobalt and nickel. In other aspects of the invention, molybdenum and/or chromium are included to further lower the thermal conductivity of the material. The thermal conductivity of the material of the invention is about 12 Watt/m° K. or less.

Abstract: Disclosed is a cemented carbide comprising 5 to 10 mass % of cobalt and/or nickel, and 0 to 10 mass % of at least one selected from a carbide (except for tungsten carbide), a nitride and a carbonitride of at least one selected from the group consisting of metals of groups 4, 5 and 6 of the Periodic Table, the balanced amount of tungsten carbide, a hard phase comprising mainly tungsten carbide particles, and containing ? particles of at least one selected from the carbide, the nitride and the carbonitride, and the hard phase being bonded through a binder phase comprising mainly cobalt and/or nickel, wherein a mean particle size of the tungsten carbide particles is 1 ?m or less, and the cemented carbide having a sea-island structure in which plural binder-phase-aggregated portions composed mainly of cobalt and/or nickel are scattered in the proportion of 10 to 70 area % based on the total area on the surface of the cemented carbide. The cemented carbide is excellent in wear resistance and fracture resistance.

Abstract: A wear part is formed of a diamond-containing composite material with 40 to 90% by volume of diamond grains, 0.001 to 12% by volume of carbidic phase, formed from one or more elements from the group Si, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, B, Sc, Y and lanthanides and 7 to 49% by volume of a metallic or intermetallic alloy with a liquidus temperature<1400° C., the metallic or intermetallic alloy containing the carbide-forming element or elements in dissolved or precipitated form and having a hardness at room temperature>250 HV.

Abstract: The invention relates to a thermal spray feedstock composition that employs free flowing agglomerates formed from (a) a ceramic component that sublimes,(b) a metallic or semi-conductor material that does not sublime and (c) a binder. The invention also relates to a method for preparing the agglomerates and a method for preparing ceramic containing composite structures from the agglomerates.

Abstract: Method of producing a sintered body comprising the steps of mixing one or more powders forming hard constituents with powders forming a binder phase comprising cobalt powder where the cobalt powder comprises cobalt having mainly a fcc-structure defined as the peak height ratio between the Co-fcc(200)/Co-hcp(101) being greater than or equal to about 3/2, as measured between the baseline and maximum peak height, measured by XRD with a 2?/? focusing geometry and Cu-K? radiation. The present invention also relates to a ready-to-press powder comprising cobalt having mainly a fcc-structure and where the cobalt powder has a grain size (FSSS) of from about 0.2 to about 2.9 ?m. The present invention also relates to sintered bodies made according to the method. The sintered bodied according to the present invention have reduced porosity and less crack formation.

Abstract: According to the present invention there is now provided a body cemented carbide provided with at least one wear resistant layer, which body contains a toughness increasing surface zone. Increase in toughness is obtained due to the presence of a surface zone having increased WC grain size and/or increased Co content. The invention is most suitable for WC—Co cemented carbides.

Abstract: A compact is obtained from a mixed powder of a multi-component system ceramics composed of constitutive elements of at least two metal elements selected from the group consisting of Ti, Al, V, Nb, Zr, Hf, Mo, Ta, Cr, and W, N, and optionally C; and Fe, Ni, Co, or an alloy composed of a constitutive element of at least one metal element of Fe, Ni, and Co. A composite material is prepared by sintering the compact.

Abstract: A ceramic sintered product which comprises a first hard phase containing a nitride of titanium, a second hard phase containing at least one of alumina and zirconia, and a binding phase containing nickel; and a method for producing the ceramic sintered product. The ceramic sintered product is lightweight and exhibits good abrasion resistance in a wet atmosphere, and further can be produced at a low cost.

Abstract: A high-strength and highly-wear-resistant sintered diamond object according to the present invention includes sintered diamond particle having an average particle size of not larger than 2 ?m and a binder phase as a remaining portion. The content of the sintered diamond particle in the sintered diamond object is not smaller than 80 volume % and not larger than 98 volume %. The binder phase contains at least one element selected from the group consisting of titanium and the like, of which content is not smaller than 0.5 mass % and less than 50 mass %, and contains cobalt, of which content is not smaller than 50 mass % and less than 99.5 mass %. A part of the element or the element as a whole is present as carbide particle having an average particle size of not larger than 0.8 ?m. A texture of the carbide particle is discontinuous, and adjacent diamond particles are bound to each other.

Abstract: An earth-boring drill bit having a bit body with a cutting component formed from a tungsten carbide composite material is disclosed. The composite material includes a binder and tungsten carbide crystals comprising sintered pellets. The composite material may be used as a hardfacing on the body and/or cutting elements, or be used to form portions or all of the body and cutting elements. The pellets may be formed with a single mode or multi-modal size distribution of the crystals.

Abstract: The present invention relates to a fine grained WC-Co cemented carbide. By adding an extremely small amount of Ti, V, Zr, Ta or Nb alone or in combinations, a grain refined cemented carbide structure with less abnormal WC-grains has been obtained.

Abstract: Fracture and wear resistant cutting elements are provided. Examples include a cutting element formed of a wear resistant material having a binder composition and a coarse grain size such that the portion of the cutting element formed of the wear resistant material has a fracture toughness of at least about 18 ksi(in)0.5 and a wear number of at least about 1.8. In a particular example, the wear resistant material has a fracture toughness of at least about 20 ksi(in)0.5. A down hole cutting tool incorporating such cutting elements is also provided.

Abstract: According to the present invention there is now provided a body cemented carbide provided with at least one wear resistant layer, which body contains a toughness increasing surface zone. Increase in toughness is obtained due to the presence of a surface zone having increased WC grain size and/or increased Co content. The invention is most suitable for WC—Co cemented carbides.

Abstract: After an alloy powder including W, Cr, at least one of Ti, Zr, and Hf, and at least one of V, Nb, and Ta is produced, the alloy powder, a powdery carbon material, and a catalyst are heat-treated in the presence of a nitrogen gas. The alloy powder is carbonitrided into a multicomponent ceramics powder, and sintered into a sintered body. Alternatively, a powder of a first substance including at least two of Ti, Al, V, Nb, Zr, Hf, Mo, Ta, Cr, and W is molded into a molded body. Then, the surface of the molded body is surrounded by a second substance including a metal element which is not contained in the powder of the first substance, and the molded body is heat-treated in an atmosphere in which N is present. A porous sintered body thus produced is crushed into a multicomponent ceramics powder.

Abstract: The invention proposes a fine grained sintered cemented carbide containing chromium and based on WC and a binder based on Co or CoNiFe, and having at least one additional phase comprising at least one carbide or mixed carbide of tantalum. For improving the high-temperature properties while simultaneously maintaining a good trade-off between hardness and bending strength, it is proposed that the sintered cemented carbide contains approximately 0.3 to 4% Ta, as related to the total mass of the sintered cemented carbide, that the WC has a grain size of between 0.1 and 1.3 ?m, that the binder phase contains the metals W, Cr and Ta, dissolved in solid solution, and that the at least one additional phase comprises a TaC phase visible by optical microscopy. The invention further relates to a powder-metallurgical process for manufacturing the sintered cemented carbide and to the use of the sintered cemented carbide for manufacturing cutting tools having improved high-temperature properties.

Abstract: There is disclosed a compositionally graded sintered alloy which comprises: 1 to 40% by weight of a iron group metal; 0.1 to 10% by weight of at least one type of a specific metal element selected from the group consisting of Cr, Au, Ge, Cu; Sn, Al, Ga, Ag, In, Mn and Pb; a hard phase containing, as a main component, at least one compound selected from the group consisting of a carbide, a nitride and a mutual solid solution of a metal(s) which belongs to Group 4 (Ti, Zr, Hf), 5 (V, Nb, Ta) or 6 (Cr, Mo, W) of the Periodic Table; and inevitable impurities, wherein the content of the specific metal element gradually increases from a surface of the sintered alloy toward an inner portion thereof, and a ratio of the average concentration of the specific metal element in a region which is at least 1 mm inside from the surface of the sintered alloy, to the average concentration of the specific metal element in a region between the surface and the position which is 0.

Abstract: The cutting member comprises WC, two or more solid solutions of WC and compounds selected from carbides, nitrides and carbonitrides of metals of the groups 4a, 5a and 6a in the Periodic Table, and at least one metal of the iron group; and at least one of the two or more solid solutions being a solid solution having a high Nb or Zr content, whereby the wear resistance and plastic deformation resistance are improved in case of cutting hardly machinable materials such as stainless steel, thereby making it possible to prolong the service life of the cutting member.

Abstract: An eta-phase-free cemented carbide insert with improved surface hardness and wear resistance containing WC, and possibly cubic phases of a carbide and/or carbonitride, in a binder phase of Co, Ni, Fe or a combination thereof, with a binder phase gradient in the surface and near surface regions, is disclosed. The nominal binder phase content in the insert is 3-20 weight %. The surface, and near surface cobalt content is 50-100% of the binder phase content of the inner portion of the insert. The insert is formed by standard sintering practices, followed by the chemical removal of the binder phase from the surface and near surface regions of the insert. The insert is then heat treated at a temperature of 1300-1350° C. in a carburizing atmosphere, for a time of 5-400 minutes to cause diffusion of the binder phase from the interior into the binder depleted surface regions.

Abstract: There is provided a cemented carbide comprising a hard phase component which comprises a tungsten carbide (WC) and at least one selected from carbides, nitrides and carbonitrides of metals of the groups 4a, 5a and 6a in the periodic table; and a binder phase component comprising at least one of iron-group metals, wherein the surface region of the cemented carbide has 90-98% of the minimum hardness as compared with internal hardness, thereby having high hardness and toughness which is suitable to using as a cutting tool.

Abstract: A corrosion resistant, high strength austenitic stainless steel consisting of 1.0% or less of Si, 2.0% or less of Mn, 0.5% or less of O, 7 to 30% of Ni, 14 to 26% of Cr, 0.3% or less of combination of C and N, at least one element selected from the group consisting of 1.0% or less of Ti, 2.0% or less of Zr and 2.0% or less of Nb, and the balance consisting of Fe and unavoidable impurities, the percentage being given in weight basis; said steel containing carbonitride with a grain size of several to 100 nm dispersed therein; said steel having an average crystal grain size of 1 &mgr;m or less; and said steel containing 90% by volume or more of austenite phase; is excellent in strength and corrosion resistance.

Abstract: A cutting tool insert has a cemented carbide substrate and a coating. The cemented carbide substrate includes 73-93 wt % WC, 4-12 wt % binder phase, and cubic carbide phase with a binder phase enriched surface zone essentially free of cubic carbide phase. The cubic carbide phase includes elements from the groups IVB and VB, with the Ta content on a level corresponding to a technical impurity. Inserts according to the invention exhibit favorable edge strength and thermal shock resistance.

Abstract: There is disclosed a hard alloy which comprises 5 to 50% by volume of a metallic binder phase comprising at least one element selected from cobalt, nickel and iron as a main component, 0 to 40% by volume of a cubic crystal compound comprising at least one compound selected from a carbide, nitride and mutual solid solution of a metal of Group IVB, VB or VIB of the Periodic Table, and the reminder being hexagonal tungsten carbide and inevitable impurities,

Abstract: A matrix powder for the production of components for wear-resistant applications by forming the matrix powder, along with an infiltrant, into a matrix, and and a wear-resistant component produced therefrom are presented. In order to improve mechanical properties, in particular resistance to erosion, it is proposed for at least some of the hard material to be in the form of spheroidal hard-material particles with a particle size of less than 500 &mgr;m.

Abstract: A fracture and wear resistant rock bit is disclosed, which includes a bit body, and at least one roller cone disposed on the bit body adapted such that at least one row of cutting elements disposed on the at least one roller cone defines a gage row. At least one cutting element disposed on the gage row has a fracture toughness of at least 20 ksi (in)0.5 and a wear number of at least 1.5.

Abstract: A method for densification of the surface layer of an optionally sintered powder metal component comprising the steps of: decarburizing the surface layer for softening the surface layer of the component; and densifying the surface layer of the component.

Abstract: A cemented carbide seal ring has at least one hard phase in a binder phase based on Co, Ni and Fe which results in a content Fe, Ni and Cr of less than 50 &mgr;g/l of each in a leach test with deionized water at 85° C. performed according to the requirements of British Standard BS6920: Section 2.6: 1996.

Abstract: A superfine material made by incorporation of an inorganic polymer precursor of a grain growth inhibitor into intermediates useful for the production of superfine materials. The precursor/nanostructured material composite is optionally heat treated at a temperature below the grain growth temperature of the superfine material in order to more effectively disperse the precursor. The composites are then heat treated at a temperature effective to decompose the precursor and to form superfine materials having grain growth inhibitors uniformly distributed at the grain boundaries. Synthesis of the inorganic polymer solution comprises forming an inorganic polymer from a solution of metal salts, filtering the polymer, and drying. Alloying additives as well as grain growth inhibitors may be incorporated into the superfine materials.

Abstract: A cemented carbide insert of a first grade has at least one cutting point consisting of a cemented carbide of a second grade with different composition and/or grain size with an uneven transition zone between the first and second grade.

Abstract: A TiCN-based cermet comprises 5-25 weight % of a binder phase mainly composed of Co and/or Ni, the balance being substantially a hard phase and inevitable impurities, the hard phase being mainly composed of carbide, nitride and/or carbonitride and containing at least Ti and W, the cermet having a cross-section microstructure in which the number of Ti-rich particles having an area of 0.02 &mgr;m2 or more is 1000 or less per a unit area of 1000 &mgr;m2.

Abstract: An sintered iron-based powder metal body with outstandingly lower re-compacting load and having a high density and a method of manufacturing an iron-based sintered component with fewer pores of a sharp shape and having high strength and high density, the method comprising mixing,

Abstract: A superhard filler hardmetal having a superhard material filler, binder metal or matrix and in some instances at least a first hard component is disclosed. The superhard filler hardmetal has a porosity rating of substantially A06, B00, C00 or better and may be essentially pore free, i.e., A00, B00, C00. The superhard filler hardmetal is formed by mechanically mixing a superhard material, in some instances at least a first hard component and a binder metal or matrix precursor, shaping the mixture into a green body and consolidating the green body at a preselected temperature, superatmospheric pressure and time at temperature and time at superatmospheric pressure sufficient to form the superhard filler hardmetal. The consolidation preferably occurs without the formation of a liquid in the body and at least a portion of the time at superatmospheric pressure is at the preselected temperature. Diamond filler and boron nitride filler are examples of superhard materials usable as filler.

Abstract: A ball for a ball-point pen is provided comprising cemented carbide of WC—Cr3C2—Co where VC is contained as a solid solution in the Cr3C2—CO phase which is a binder of WC particles and wherein the mean diameter of the WC particles is in the range of from about 0.3 to about 0.5 &mgr;m. In one embodiment of the invention, a portion of the Cr3C2—VC—CO phase exposed on the surface of the ball comprises a plurality of concave recesses.

Abstract: The invention relates to an abrasive tool comprising a support body and at least one abrasive element connected thereto. Said abrasive element has an abrasive grain which is joined by a sintered metal. The sintered metal used for joining is copper-coated iron and is alloyed with metal borides, metal carbides and/or metal silicides and also with tin.

Abstract: In a cemented carbide, at least one compound 3 including a carbide, a nitride or carbo-nitride of at least one component selected from IVa, Va and VIa group elements or a solid solution thereof exists in at least some WC crystal grains 1. Preferably the compound 3 is in the form of compound grains 3 comprising a carbide, a nitride or a carbo-nitride of Ti, Zr, Hf or W or a solid solution thereof, having an average grain diameter smaller than 0.3 &mgr;m. The compound grains make up at most 10% of the cross-sectional area of the WC crystal grains that contain the compound grains, while at least 10% of the total cross-sectional area of the cemented carbide is made up of such WC crystal grains that contain the compound grains.

Abstract: The present invention relates to method of making a cemented carbide insert, comprising a cemented carbide substrate and a coating. The substrate contains WC and cubic carbonitride phase in a binder phase based of Co and/or Ni and has a binder phase enriched surface zone essentially free of cubic phase. The binder phase enriched surface zone prevails over the edge. By sintering in an atmosphere essentially consisting of nitrogen the thickness of the binder phase enriched zone can be controlled.

Abstract: A method comprising incorporation of an inorganic polymer precursor of a grain growth inhibitor into superfine materials or intermediates useful for the production of superfine materials. The precursor/nanostructured material composite is optionally heat treated at a temperature below the grain growth temperature of the superfine material in order to more effectively disperse the precursor. The composites are then heat treated at a temperature effective to decompose the precursor and to form superfine materials having grain growth inhibitors uniformly distributed at the grain boundaries. Synthesis of the inorganic polymer solution comprises forming an inorganic polymer from a solution of metal salts, filtering the polymer, and drying. Alloying additives as well as grain growth inhibitors may be incorporated into the superfine materials.

Abstract: A diamond sintered body having high wear resistance, chipping resistance, shock resistance and thermal conductivity is provided. The diamond sintered body includes sintered diamond particles and a sintering aid as the remainder. The content of the sintered diamond particles is at least 80% by volume and less than 99% by volume. The sintered diamond particles have a particle size in the range from at least 0.1 &mgr;m to at most 70 &mgr;m. The sintered diamond particles next to each other are directly bonded. The sintering aid includes at least one kind selected from tungsten, iron, cobalt and nickel. The percentage of the tungsten in the sintered body is in the range from at least 0.01% by weight to at most 8% by weight.

Abstract: The present invention discloses a sintered cemented carbide alloy with excellent corrosion and oxidation resistance. The alloy comprises 70-98 weight-% hard material essentially comprising WC in a monophase binder phase. It has been found that by the use of submicron WC the corrosion and oxidation resistance can be improved compared to known corrosion and oxidation resistant cemented carbide alloys.

Abstract: A hard magnetic material contains Co as a main component, at least one element Q of P, C, Si and B, and Sm, and an amorphous phase and a fine crystalline phase. The texture of the hard magnetic material contains 50% by volume or more of fine crystalline phase having an average crystal grain size of 100 nm or less, and has a mixed phase state containing a soft magnetic phase and a hard magnetic phase. Further, anisotropy is imparted to the crystal axis of the hard magnetic phase.

Abstract: A composite body of a microwave sintered composition of a cermet or hard metal as a modified surface layer which can promote the microwave sintering and can be of a thickness of 0.01 to 1 mm with a density gradually decreasingly inwardly or a thickness up to 1 mm and having locally distributed compacts therein or which can be a layer of a thickness of 1 to 10 mm of a substantially pure metal or which can have a binder metal removed to a depth of about half the grain thickness of a hard material such as WC.