Abstract: A method of producing a sintering powder made from high speed steel and alumina. This sintering powder is sinterable over a broader range of temperatures than conventional high speed steel sintering powders and at lower temperatures, thereby making sintered objects which are crack resistant and also highly wear resistant. Additionally, the sintering powder flows readily when poured into a mold for production of a green object for sintering.

Abstract: A solid particle erosion resistant coating includes angular titanium carbide particles uniformly dispersed through a high chromium iron matrix. In one form, the aggregate comprises, by weight, about 30-50% TiC, about 10-30% Cr, about 1.5-5% C and the balance essentially iron in the form of ferrite. The matrix also includes metallurgically identifiable amounts of high chromium content M.sub.7 C.sub.3 carbides therethrough. The coating does not exhibit austenitic or martensitic structure therethrough. A powder alloy consolidated body also includes a surface adjacent region having a similar TiC and high chromium iron matrix. Further, a method for obtaining the coating includes heating above the austenitization temperature of the matrix alloy and below the melting temperature of iron, and cooling the aggregate so as to attain iron in the form of ferrite in the matrix.

Abstract: A wear resistant sintered alloy consisting essentially of from 2.0% to 3.5% by weight of C, from 0.3% to 0.8% by weight of P, from 0.5% to 3.0% by weight of Mn and remainder Fe. The alloy is sintered in the liquid-phase.

Abstract: A print wire for a printer wire assembly consisting essentially of a very fine and uniform grain size tungsten carbide in a cobalt matrix results in a wire having improved strength.

Abstract: An improved fabrication process for cobalt-enriched cemented carbide substrates is disclosed, in which an article is generally comprised of tungsten carbide, cobalt, and carbides, nitrides or carbonitrides of titanium, tantalum, and niobium, or mixtures thereof. In one aspect of the invention the article is contacted with nitrogen gas and then sintered in the absence of nitrogen gas to form a cobalt-enriched, B-1 phase-depleted zone. The article is then sintered in nitrogen gas to form a B-1 phase enriched layer on the surface of the article. Additionally, a metal oxide wear layer can be provided on the article.

Abstract: This invention relates to a hard alloy comprising two phases: a hard phase consisting of at least one compound having a crystal structure of simple hexagonal MC type (M: metal; C: carbon) selected from the group consisting of mixed carbides, carbonitrides and carboxynitrides of molybdenum and tungsten, and a binder phase consisting of at least one element selected from the group consisting of iron, cobalt and nickel. The hard phase is prepared by carburizing an (Mo, W) alloy obtained by reducing oxides of molybdenum and tungsten with a particle size of at most 1 micron, is composed of coarse particles with a mean particle size of at least 3 microns, and has a uniform molybdenum to tungsten ratio in the particles. The hard alloy has a gross composition within the range of the shaded portion ABCDEA in FIG. 1.

Abstract: A method of manufacturing a cermet having high toughness and high hardness, which exhibits excellent impact resistance and wear resistance when used in cutting tools. A mixed powder is prepared which consists essentially of: titanium nitride, from 25 to 50 percent by weight; titanium carbide, from 10 to 30 percent by weight; at least one selected from the group consisting of tantalum carbide, niobium carbide, and zirconium carbide, from 5 to 25 percent by weight; tungsten carbide, from 10 to 25 percent by weight; and at least one selected from the group consisting of Co and Ni, and Al if required, from 7.5 to 25 percent by weight in total. The above mixed powder is compressed into a green compact. The green compact is sintered in a nitrogen atmosphere under a pressure within a range from 0.1 to 100 torr, and at a temperature within a range from 1400.degree. to 1550.degree. C.

Abstract: A diamond sintered body for tools contains a diamond content in excess of 93 percent and not more than 99 percent by volume and a residue including at least one of a metal or a carbide selected from groups IVa, Va and VIa of the periodic table and an iron group metal of 0.1 to 3 percent by volume in total and pores at least 0.5 percent and not more than 7 percent by volume.

Abstract: Cemented carbide substrates having substantially A or B type porosity and a binder enriched layer near its surface are described. A refractory oxide, nitride, boride, and/or carbide coating is deposited on the binder enriched surface of the substrate. Binder enrichment is achieved by incorporating Group IVB or VB transition elements. These elements can be added as the metal, the metal hydride, nitride or carbonitride.

Abstract: Disclosed is a decorative silver-colored sintered alloy comprising TiC, Cr.sub.3 C.sub.2 and Ni in amounts of 50 to 98% by weight, 1 to 20% by weight and 1 to 30% by weight, respectively, based on the three components. In this sintered alloy, TiC is present in the form of the dispersed phase of particles and Cr.sub.3 C.sub.2 and Ni are present in the form of a solid solution as the binder phase. This sintered alloy is excellent in the corrosion resistance and is capable of manifesting a mirror surface having a deep silver color.

Abstract: A sintered high vanadium high speed steel with an excellent hardness and ductility of composition C 1.4-6.2%, W+2 Mo (W-equivalent) 10.0-24.0%, Cr 3.0-6.0%, V 8.5-28%, Co less than 17%, the remainder Fe and inevitable impurities, and a method of producing same.It can be produced by the steps of commingling the alloy constituents in the form of pulverulent oxides and carbon powder, heating the mixture in a stream of hydrogen, thereby reducing the mixture by the carbon and hydrogen simultaneously to yield an alloy powder, adjusting the composition and the grain size of the obtained alloy powder, pressing the alloy powder to a compact, sintered the compact in a vacuum, and finally converting the matrix of the sintered body into martensite by heat treatment.

Abstract: An improved diamond compact of the present invention comprises 20 to 85% by volume of diamond grains with a grain size of at least 3 .mu.m and the balance of a binder consisting of 20 to 95% by volume of ultra-fine diamond grains with a grain size of at most 1 .mu.m, at least one member with a grain size of at most 1 .mu.m, selected from the group consisting of carbides, carbonitrides, nitrides, borides of Group 4a, 5a and 6a elements of Periodic Table, solid solutions thereof and mixed crystals thereof and at least one member selected from the group consisting of iron group metals.

Abstract: A highly wear-resistant sintered ferrous alloy which consists essentially of 2.0-8.0% of Cr, 0.1-1.0% of B, 1.0-2.5% of Si, 0.3-1.2% of Mn, 1.2-3.8% of C, by weight, and the balance of Fe. The alloy is produced by compacting and sintering a powder mixture, which is preferably prepared by mixing 75-90 parts by weight of a cast iron powder with 25-10 parts by weight of a Fe--Cr--B--Si alloy powder.

Abstract: In material applications in which besides a high wear resistance also excellent corrosion resistance, strength and toughness are required, conventional hard metal alloys have appeared inadequate. According to the invention a hard metal alloy now exists which fulfils these requirements. It is based on WC-Ni, and the binder phase of nickel is alloyed with low, well adjusted concentrations of above all Cr and Mo.

Abstract: The bond between a hard wear resistant coating of Al.sub.2 O.sub.3 and a cemented carbide substrate is greatly improved by means of a more effective interlayer of TiO. The TiO layer is provided by means of a reduction process from other titanium oxides such as TiO.sub.2.

Abstract: Spinodally-decomposing mixed crystals of zirconium and titanium carbides, possibly including carbonitrides and optionally including one or more carbides of metals of Group Vb of the Periodic Table of the Elements, are used in making sintered hardmetals based on tungsten carbide. One or more iron group metals or alloys, preferably cobalt or a nickel alloy, is or are used as a binder. The sintered hardmetals are made by a 2-stage process, mixed crystal material comprising zirconium and titanium carbides being formed in the first stage and being combined with the binder and tungsten carbide in the second stage. Process variations which encourage spinodal decomposition of the mixed crystal material are also disclosed.

Abstract: The invention relates to a sintered body for use in a cutting tool comprising a cutting edge forming part having particularly high hardness and wear resistance bonded to a supporting member having high plastic deformability, stiffness, transverse rupture strength, thermal conductivity, thermal expansion coefficient, resistance to corrosion, oxidization and the like, and to a method for producing the same. A diamond powder or high pressure form boron nitride powder is placed in contact with preliminarily sintered cermet constituted by carbide crystals chiefly comprising molibdenum in the form of (Mo, W)C bonded by iron group metals, the combined body being sintered at a temperature and pressure under which the diamond powder or high pressure form boron nitride powder is thermodynamically stable so that the sintered body of the diamond or high pressure form boron nitride is bonded to the cermet thereby enabling to obtain a sintered body having the said high properties for use in a cutting tool.

Abstract: A method is disclosed for forming roller cutters and also for forming cutting teeth for rolling cutter bits, including cutter inserts, cutter teeth formed in place, or formed separately and welded in place, etc., by powder metallurgy as a densified powder metallurgical composite of at least two varying phases, the composite having a substantially continuous mechanical property gradient therethrough. The gradient is from one region having hardness or wear resistant properties to another region having toughness properties. The method comprises:providing a first powder mixture comprising a major proportion by volume of a powdered refractory compound and a minor proportion by volume of a powdered binder metal or alloy. Providing a second powder comprising a powdered binder metal or alloy or a mixture comprising a powdered refractory material and a powdered binder metal or alloy, present in a lesser proportion by volume than in the first powder.

Abstract: A sintered compact for use in a machining tool comprising 80 to 10 volume % of a high pressure form of boron nitride, and the balance a matrix of at least one binder compound material selected from the group consisting of a carbide, nitride, carbonitride, boride or silicide of IVa and Va transition metal of the periodic table, their mixtures as well as the solid solution of these compounds; the matrix forming a continuous bonding structure in the sintered body.A method of producing the compact comprises preparing a mix of 80 to 10 volume % of a high pressure form of a boron nitride powder with 20 to 90 volume % of at least one powdered binder compound selected from the group consisting of a carbide, a nitride, a carbonitride, a boride and a silicide of a IVa, or a Va metal, mixtures thereof or solid solutions of these compounds, and sintering the mix under pressures more than 20 Kb at temperatures higher than 700.degree. C. for more than 3 minutes.

Abstract: An improvement in a cemented hard metal is disclosed. A molybdenum-tungsten-carbonitride is disclosed having the structure of tungsten carbide wherein the molybdenum and/or tungsten are at least partly substituted for by a metal selected from the group consisting of Cr, Nb, Ta, V, Re and mixtures thereof. The carbonitride may be mixed with a binder metal and sintered in a conventional manner to form a dense, substantially pore-free material.

Abstract: A liquid phase sintered body for brazed joints having a multiplicity of pores, grooves and/or indented patterns formed on a desired surface. The liquid phase sintered body is produced by a method comprising the steps of forming a compact body of a mixture of a hard refractory material, such as carbides, nitrides, oxides, borides and silicides mixed with cementing metal in powder form, placing on the desired surface any one of coarse grains, strands or plates of a metal having a diameter or a thickness over ten times as great as the grain size of the cementing metal, and sintering the compact body under conditions suitable for melting the coarse grains, strands and/or mesh of strands or plates after densification of the compact body has been completed or substantially completed. The metal forming the coarse grains, strands or plates must have a melting point which is more than 50.degree. C.

Abstract: A workpiece of alloy steel is produced by sintering under a nonoxidizing atmosphere a mass of malleable-iron powder admixed with a comminuted complex ferroalloy. The latter, obtained from a molten mixture of several simple high-carbon ferroalloys saturated with graphite, is a blend of at least three nonferrous metals and iron in carbide form, including a complex carbide of formula M.sub.7 C.sub.3 containing iron and manganese with the possible addition of chromium and another carbide of formula M'.sub.2 C/M'C containing molybdenum with the possible addition of vanadium and/or niobium. The carbidically bound carbon amounts to at least 4%, by weight, of the ferroalloy composition and may constitute between 10% and 60% of the carbon of the sinterable powder mixture to which elemental carbon may be added as graphite. As the mass of iron and ferroalloy particles compacted under high pressure is sintered at temperatures between about 1150.degree. and 1300.degree. C.

Abstract: An improvement in a cemented carbide is disclosed. Molybdenum, tungsten and carbon are mixed and heated in a nitrogen containing atmosphere to form a tungsten-molybdenum carbonitride (Mo, W) (C, N) having the structure of tungsten carbide. The molybdenum-tungsten carbonitride is mixed with a binder metal (and, if desired, another hard material) and sintered in a conventional manner to form a dense, substantially pore-free material which is similar in a number of properties to the more expensive tungsten carbide.

Abstract: A sintered compact for use in a cutting tool and a method of producing the same are disclosed. The compact comprises 95 to 20 volume % of diamond finer than one micron in size and the balance binder also finer than one micron selected from the group of WC, (MoW)C, WC base cemented carbide and (MoW)C base cemented carbide.The method comprises pulverizing a diamond powder by using cemented carbide balls and a pot having a cemented carbide lining, mixing the diamond powder with a powder abraded from the balls and pot to produce a powder mix finer than one micron containing 95 to 20 volume % of diamond, heat-treating the powder mix in vacuum so as to degas, and hot-pressing the powder mix under high pressure at high temperature within the stable range of diamond.

Abstract: Method for hard-facing metal substrates is disclosed using a hard facing material consisting essentially of combined vanadium, tungsten and carbon and from about 5 to about 40% by weight of chromium carbide with up to 15% by weight in the aggregate of cobalt, iron, molybdenum and nickel.

Abstract: A tungsten carbide-base sintered alloy is disclosed, which has a compact three-phase structure consisted of a grain phase of a metal carbide composed mainly of tungsten carbide, a grain covering layer phase of a complex carbo-nitride of titanium and a metal element composed mainly of tungsten in the metal carbide, and a bonding phase composed mainly of nickel and which exhibits very high hardness and high-wear-resistance properties.

Abstract: Cobalt or cobalt alloy composite materials reinforced with continuous silicon carbide fibers, which have a high tensile strength, a low elongation, a high Young modulus and a high tensile strength at a high temperature, are produced by filling spaces in piles of the continuous silicon carbide fibers containing 0.01%-30% by weight of free carbon with melted or powdery metallic cobalt or cobalt alloy and integrating the said fibers with the said metal.

Abstract: The alloy of the invention is of the type wherein 30-70% by volume of hard components are homogeneously dispersed in a matrix of binder metal (Fe, Co or Ni). The hard components are carbides or carbonitrides and/or borides of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and/or W. The mean grain size of the hard component particles is between 0.01 and 1.0 micron and their grain size distribution, represented by the standard deviation S, in which S.sup.2 .ltoreq.(M/1+1.5 M.sup.z).sup.2 .mu.m.sup.2, not more than 15% of the grains are larger than 1.2 microns.

Abstract: The present invention relates to a hard cemented carbonitride alloy for cutting tools, which comprises 97 to 75% by weight of a hard phase and 3 to 25% by weight of a binder metal, the hard phase consisting of metallic components of titanium as a main component, 5 to 40% by weight of one or more of tungsten and molybdenum and 3 to 40% by weight of tantalum and non-metallic components of carbon and nitrogen, the proportion of nitrogen being 5 to 40% by weight of the non-metallic components and the binder metal being at least one element selected from the group consisting of iron, cobalt and nickel.

Abstract: A cemented carbide metal alloy containing auxiliary metal having one or more finely dispersed carbide phases and process for making the same.The invention relates to a cemented carbide metal alloy containing auxiliary metal with one or more finely dispersed carbide phases and a process for making such carbide metal alloy.

Abstract: Highly active catalysts, suitable for use in hydrogenation and other reactions, are prepared from an alloy of one or more of the Group VIII transition metals with yttrium or a rare earth metal. The alloy is ground to the desired particle size and is thereafter reacted with a gas containing carbon monoxide and hydrogen to form an intimate physical admixture of the Group VIII metal or its corresponding carbide with the oxide of yttrium or the rare earth metal.

Abstract: This invention relates to a cemented carbonitride alloy in which the hard phase consists of[(Group IVa metal).sub.A (Group Va metal).sub.B (Group VIa metal).sub.C ]-(C.sub.X N.sub.Y).sub.Zwherein A, B, C, X and Y are respectively mole fractions, Z is a mole ratio of the metalloid components to the metal components and there are among A, B, C, X, Y and Z the relations ofA + B + C = 1, X + Y = 1,4a + 5b + 6c + 4xz + 5yz .gtoreq. 8.6,0.05 .ltoreq. y .ltoreq. 0.50 and 0.85 .ltoreq. Z .ltoreq. 1.0.the hard phase is combined by at least one binder metal from the iron group and there are in the alloy structure WC phase and the hard phase having the crystal structure B1 and containing Ti in a proportion of at least 20 atomic percent to the metallic atoms.

Abstract: Cemented carbide articles produced by tape casting a slurry of ingredients including organic resins and plasticizers, forming the cast tape into a desired shape and firing the tape, are improved by eliminating carbonaceous residue-forming ingredients from the organic portion of the slurry, resulting in reduced porosity of the fired article.